CC PHNG PHP GII BI TP HA HC PH THNG Vn

NH LUT BO TON IN TCH

I- PHNG PHP GII Nguyn tc:
Trong dung dch tng in tch dng bng tng in tch m.T suy r tng s! mo" int tch dng bng tng s! mo" in tch dng. #$t dung dch g%m c&c ion' ( )on dng' +* ( ,-*'mo"./0*b ( ,y*'mo"./1*c ( ,2*'mo"..... ( b ( c ( ( )on m' + 3 3 ,- 3 'mo"./03 3 ,y 3 'mo"./1 3 3 ,2 3 'mo".....
* * *

45 d6ng 780T7T t c' -*

(y*b* (2*c* (...9- 3

(y 3 b 3 (2 3 c 3 (...

II- VN DNG
A- BI TP MU Bi 1:Trong m:t dung dch ch; mo" 1 3(/ b mo" <g3(/ c mo" 1"=/ d mo" >?@3=. 8A5 biBu th;c m!i Cu n h giD E bE c FG d HiIi' 45 d6ng 780T7T t c' 3 ( 3b 9 c ( 3d Bi 2: <:t dung dch ch; JEJ3 mo" 1u3(/ JEJK mo" L(/ - mo" 1"= FG y mo" >?@3=. Tng Mh!i "Nng c&c mu!i t n trong dung dch "G OE@KOg. TPm - FG yQ HiIi' 45 d6ng 780T7T t c' - ( 3y 9 3.JEJ3 ( JEJK 9 JEJR ,*. VG mmu!i 9 3EUVO ,3. HiIi h ,*. FG ,3. c' - 9 JEJK/ y 9 JEJ3. Bi 3: Kt qu xc nh nng mol ca cc ion trong mt dung dch ghi bng d i y: on !a" #a$" !%&' #l' (#%&' )* mol +,++,+. +,+. +,+/ +,+$(0i 1t qu 2 3ng hay 4ai5 67i 4ao5 Gii: 8o i9n t:ch ca mt ion trong dd b;ng t:ch ca i9n t:ch <= 4* mol ca n2, n>n ta c2: " 6?ng i9n t:ch d@ng l=: A".BC+,+- " A"$BC+,+. D " +,+E " 6?ng i9n t:ch m l=: A'.BC+,+. " A'.BC+,+/ " A'.BC+,+$- D ' +,+E-C Fi tr tuy9t *i ca i9n t:ch d@ng 1hc i9n t:ch mC GHy 1t qu tr>n l= 4aiC Bi 4:8ung dch I chJa cc ion !a": a molK (#%&': b molK #%&$': c molK )%/$': d molC LM t7o ra 1t ta ln nhNt ngOi ta dPng .++ ml dd QaA%(B$ nng x molRlC SHT biMu thJc t:nh x thUo a <= bC Gii: (#%&'" %(' #%&$' " ($% K Qa$" " #%&$' Qa#%& K Qa$" " )%/$' Qa)%/ b b 8ung dch 4au Thn Jng chV c2 !a ": a molC GW bo to=n i9n t:ch n>n cXng Thi c2: a mol %('C LM tc dYng <i (#%&' cZn b mol %('CK GHy 4* mol %(' do QaA%(B$ cung cNT l= Aa " bB mol 6a c2:

KOEO- ( UTy 9

ion

nSn' T@.JEJ3 ( KU.JEJK ( KOEO- ( UTy 9 OE@KO

a" b b n Da" b molRl <= nng $ Qa %( xD $ Da" $ +,. +,$

Bin son: Ho ! N"# N$ %

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CC PHNG PHP GII BI TP HA HC PH THNG B-BI TP T+ GII Bi 1: = mo" W ( E b mo" 1 3( E c mo" X1?K E d mo" 1"= 8A5 biBu th;c "iSn h giD E bE cE d trong dung dch ch; Bi 2: = mo" L ( Eb mo" YZK( Ec mo" >? 3= 8A5 biBu th;c "iSn h giD E bE cE d trong dung dch ch; @ Ed mo" 1" Bi : <:t dung dch c ch; c&c ion YZ3(' JE* mo"/ +"K(' JE3 mo"/ 1"=' - mo"/ )%/$': y molC 0i[t Mhi c\ c]n dung dch thu Nc @TEU g m cht r^n Mh n. TPm -E y. Bi !: <:t dung dch ch; JEKU g m L(E JEO@ g m +"K(E *EU3 g m )%/$' < [ ion !%&'C W[u c\ c]n dung dch thP thu Nc b o nhiSu g m mu!i Mh nQ Bi ": _ung dch + ch; JE3K g m ion W (/ JE*3 g m <g3(/ JEKOO g m 1"= F Gm g m ion )%/$'C W[u c\ c]n dung dch thP thu Nc b o nhiSu g m mu!i Mh nQ Bi #: = 3= 3= mo" W ( Eb mo" WX ( _ung dch + ch; @ Ec mo" X1?K Ed mo" 1? K /Z mo" >? @ . ThSm ,c(d(Z. mo"

0 ( ?X ) 3 FGo dung dch +E un nng Nc M[t t` 0E dung dch # FG Mh a duy nht c mbi Mh i. Tnh s! mo" mci cht trong M[t t` 0E Mh a FG mci ion trong dung dch # thZo E bE cE dE Z. 1hd dbng dung dch X1" E 0 ( ?X ) 3 FG Cue tm c thB 5hn bit Nc c&c ion nGo trong dung dch +. Bi $: <:t dung dch ch; JEJ3 mo" 1u 3(E JEJKmo" L(E - mo" 1"= FG y mo" >?@3=. Tng Mh!i "Nng c&c mu!i t n c trong dung dch "G OE@KOg m. H tr c` - FG y "fn "Nt "GQ A. 0,03 v 0,02 0. JEJO FG JEJ* 1. JEJ* FG JEJK _. JEJ3 FG JEJO K( 3( = 3= Bi %: _ung dch + ch; c&c ion +" 9JET mo"E YZ 9JEKmo"E 1" 9 mo"E >?@ 9 b mo". 1\ c]n dung dch + thu Nc *@JERg m. Hi& tr c` FG b "fn "Nt "GQ A. 0,6 v 0,9 0. JEU FG JET 1. JEK FG JEO _. JE3 FG JEK Bi &: _ung dch # c ch; c&c ion 1 3(E +"K(E 1"=. 7B M[t t` h[t ion 1"= trong *JJ m" dd # cfn dbng RJJm" dd ch; ion +g( c n%ng : "G *<. 1\ c]n dung dch # thu Nc KOEOOg m mu!i. Tnh n%ng : mo" c&c c tion tng ;ng trong dung dch #. +. JE@ FG JEK 0. JE3 FG JEK 1. * FG JEO D. 2 v 1. Bi 1': <:t dung dch ch; 3 c tion "G YZ3( JE* mo"/ +"K( JE3 mo" FG 3 nion 1"= - mo"/ >?@3= y mo". Lhi c\ c]n dung dch thu Nc @TEUg m cht r^n Mh n. - FG y c gi& tr "GQ +. -9JEJ3E y9JEJK 0. -9JEJKE y9JEJK 1. -9JE3E y9JEK _. -9JEKE y9JE3 ( 3( = Bi11: Trong m:t dung dch ch; mo" W E b mo" 1 E c mo" X1?K FG d mo" 1"=. 0iBu th;c "iSn h trong dung dch "GQ +. ( 3b 9 3c ( d 0. ( 3b 9 3c ( 3d C. a + 2b = c + d _. 3 ( 3b 9 3c ( d

Bin son: Ho ! N"# N$ %

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