BI TP IN HA HC

Dng 1: S pin
1. Thit lp hai pin in:
- Trong pin in th nht ng l catot
- Trong pin in th hai ng l anot
Vit cc phng trnh phn ng xy ra ti cc in cc v trong pin
2. Vit s cc pin in tng ng vi tng phn ng:
a/ 2Ag+(dd) + Cu(r) 2Ag(r) + Cu2+(dd)
b/ 2Fe2+(dd) + Cl2(k) 2Fe3+(dd) + 2Cl-(dd)
c/ Cl2(k) + H2(k) 2H+(dd) + 2Cl-(dd)
d/ Zn(r) + 2AgCl(r) Zn2+(dd) + 2Cl-(dd) + 2Ag(r)
Dng 2: Th in cc tiu chun
3. Hai in cc tan tiu chun Magie v ng c rp thnh mt pin in.
a/ Vit s pin v phn ng xy ra trong pin
b/ Tm sc in ng ca pin
0
0
Bit ECu / Cu = 0,34V v EMg / Mg = -2,363V
2+

2+

4. Trong s nhng cp cht di y, cp no c phn ng trng thi chun ?

a/ Cu(r) + 2HCl(dd 1M) CuCl2(dd 1M) + H2(k, 1atm)
b/ Mg(r) + 2AgNO3(dd 1M) Mg(NO3)2(dd 1M) + 2Ag(r)
0
Bit ECu

2+

/ Cu

= 0,34V , EMg

2+

/ Mg

= -2,363V,

0
E Ag
+
/ Ag

= 0,799V

Dng 3: Phng trnh Nernst

5. Vit biu thc ca phng trnh Nernst cho cc qu trnh sau:
a/ Zn2+(dd) + 2e Zn(r)
b/ Mg(r) - 2e Mg2+
c/ Cr2O72 (dd) + 6Fe2+(dd) + 14H+(dd) 2Cr3+(dd) + 6Fe3+(dd) + 7H2O(l)
d/ Zn(r) - 2H+(dd) Zn2+(dd) + H2(k)
6. Tm sc in ng ca pin in c s :
Sn(r) Sn (0,15M ) Ag (0,17 M ) Ag (r )
= -0,136V ; E 0
= 0,799V
E0
2+

Sn 2 + / Sn

Ag + / Ag

7. Mt pin in rp bi cc nhm nhng trong dung dch Al(NO 3)3 0,01M vi cc bc nhng trong
dung dch AgNO3 2M. Tm sc in ng ca pin.
= -1,662V
E 0Ag / Ag= 0,799V ; E 0
+

Al3 + / Al

8. 250C, mt in cc tan magie tiu chun c rp vi mt in cc tan km:

Mg(r) Mg ( dd1M ) Zn (dd ) Zn( r )
2+
Nng Zn phi bng bao nhiu nguyn t c sc in ng 1,6V ?
E 0Mg / Mg= -2,363V ;
E 0Zn / Zn = -0,763V
2+

2+

2+

2+

9. Cho axit HCl tc dng vi dung dch K 2Cr2O7, phn ng s din ra theo chiu no nu nh cc
cht u trng thi chun? Nu tng nng ion H+ hai ln, phn ng s din ra theo chiu no?
Bit Cr2 O72 + 14H+ + 6e- 2Cr3+ + 7H2O E0 = 1,33V
Cl2 + 2e- 2Cl- E0 = 1,36V
2
Bit Cr2 O7 ( dd ) + 14H+(dd) + 6e- 2Cr3+(dd) + 7H2O(l) E0Cr2 O72 /Cr3+ = 1,33V
E0Cl2 /2Cl- = 1,36V
Dng 4: Hng s cn bng
10. Tnh hng s cn bng K ca phn ng
a/ Sn(r) + 2Ag+(dd) Sn2+(dd) + 2Ag(r)
b/ Zn2+(dd) + 2H2(k) Zn(r) + 2H+(dd)
0
Bit ESn

2+

/ Sn

= -0,136V ,E Ag

/ Ag

0
= 0,799V , EZn

2+

= -0,763V

/ Zn

Dng 5: S in phn
11. Tin hnh in phn 200ml dung dch AgNO 3 trong mt bnh in phn hai cc than ch cho
n khi catot bt u xut hin bt kh th ngng. trung ha dung dch thu c cn phi dng
ng 500ml dd KOH 0,4M
a/ Tm nng mol ca dung dch AgNO3 ban u
b/ Sau in phn khi lng catot tng hay gim bao nhiu gam?
c/ Tm th tch kh thot ra 54,460C, 760mmHg
d/ Khi lng dung dch tng hay gim bao nhiu gam?
12. Cho dng in qua hai bnh in phn mc ni tip: bnh (1) cha dung dch AgNO 3, bnh (2)
cha dung dch Bi(NO3)3. Bnh (1) c 0,9 gam Ag thot ra catot. Cho bit s gam Bi thot ra
catot bnh (2). Bit MBi = 209
13. C hai bnh in phn mc ni tip. Bnh (1) cha dung dch 0,3725 gam mui ca mt clorua
kim loi kim. Bnh (2) cha dung dch CuSO 4. Sau mt thi gian catot bnh (2) c 0,16 gam kim
loi bm vo, bnh (1) mui clorua b in phn va ht dung dch cha mt cht tan vi pH = 13.
a/ Tnh th tch dung dch trong bnh (1)
b/ nh tn kim loi kim (Cl = 35,5)