V sao cao su c tnh n hi ?

a. Phn t khi ln.

b. C lin kt i.
c. Cc mt xch c cu trc cis lp th iu ha.
d. Khng c nhiu tp cht.
/a : C v do cc phn t trong qu trnh vn ng
chen i chen li, to nn chui cao phn t khng
cn dng ng thng c na, m l un khc, hn
na nhiu phn t xon vo nhau ta nh mt cun
si khng cun theo quy tc. Khi ta dng lc ko
thng n th ko ra c, nhng khi lc ko khng
cn th n li thu li theo nguyn dng. l l do v
sao cao su c tnh n hi.
1. Cao su Buna N c tnh khng du tt l v :
a. Cu trc cis lp th iu ha ln.
b. C nhiu cht ph gia b sung.
c. Do acrylonitrine.
d. C lin kt i.
/a C v vic gn cc acrylonitrine vo sn cc
copolymer butadien lm tng kt hp tt gia tnh
cht c hc v tnh khng vi s trng n trong du.
C th iu chnh tnh khng du v khuynh hng
ng cng nhit thp d dng bng cch thay i
hm lng acrylonitrile trong khong 25-40 %.
2. Trong 1kg go cha 81% l tinh bt s c bao nhiu
mt xch

a. 6,022.

b. 6,022.

c. 3,011.

d. 3,011.

/a l D . Ta tnh khi lng tinh bt c trong 1kg
go ri tm khi lng cc mt xch , t y tm ra
c s mt xch.
3. Khng nhsau y ng haysai ?
(I) Khilng polimer thu c trong phn ng
trnghp lun lunbngtng khilng nguyn
liusdng.( H=100%).
(II) Khi lng polimer thu c trong phn ng
trng ngng lun lun bng tng khi lng nguyn
liu s dng ( H=100%).
a. I ng II sai b. I ng II ng c. I sai II ng
d.C 2 cng sai.
/a l A v trong phn ng trng ngng sn phm
tch ra cn c nc.
4. Cao su nhn to u tin c tng hp t:
a. 2,3 dimetyl butadien
b. 1,4 dimetyl butadien
c. A v B u ng
d. A v B u sai.
/a l A
5. Xenlulo nitrat ( nitroxenlulo ) c tm thy vo nm
no :
a. 1846 b.1910 c.1920 d.2010
/a l A
6. Hm lng hydrocacbon trung bi2h trong cao su l
bao nhiu ?
a. 92% b.80% c. 100% d.92% n 95%
/a l D
7. T s gia carbon v hydrogen c Faraday xc
nh vo nm no?
a. 1846 b.1926 c.1826 d.1870
/a l C
8. Vo nm no con ngi mi tng hp c mt
polyisoprene?
a. 1945 b.1955 c.1965 d.1975
/a l B
9. H cy cao su no thch hp vi t ngho , khng
chu ng c thi tit thay i?
a. Apcynaceae b.Funtuania c.Manihot
d.Moraceae
/a l C
Cu 1: Phn loi polyme theo tnh cht gm:
A. Polyme t nhin, polyme trng hp, polyme trng
ngng.
B. Polyme mch cacbon, polyme d mch, polyme t
nhin.
C. Polyme nhit do, elastome, polyme nhit rn.
D. Polyme tinh th, polyme v nh hnh, polyme d
mch.
ChnpnC.
Cu 2: Lin kt cp nguyn t gm:
A. Lin kt kim loi, lin kt tnh in, lin kt ha tr.
B. Lin kt hydro, lin kt ion, lin kt kim loi.
C. Lin kt hydro, lin kt kim loi, lin kt van der
Waals.
D. Lin kt kim loi, lin kt ha tr, lin kt ion, lin kt
th cp.
Chn p n D.
Cc lin kt cp nguyn t bao gm:
- Lin kt kim loi.
- Lin kt ha tr.
- Lin kt ion.
- Lin kt th cp: lin kt van der Waals, lin kt
hydrogen.
Cu 3: Trong c ch bn ca vt liu siu phn t th
gng km cha bao nhiu nguyn t th bn nht?
A. 3 B.4 C.5 D.6
Chn p n C. Hiu ng gng km ph thuc vo s
lng v kch thc ca gng km. Gng km cha 5
nguyn t l bn nht.
Cu 4: ng dng ca Calixarenes:
A. Xc tc chuyn pha, phn tch cc ion, dng trong k
thut MRI, kt hp vi mt s ng v phng x
iu tr ung th.
B. Tng hp cc ct phn tch HPLC.
C. Phn lp ng v phng x v phn tch ha cht.
D. Tt c u ng.
Chn p n D.
Calixarenes c ng dng trong:
- Xc tc chuyn pha: Cho 18- crown- 6 vo trong phn
ng gia NaCN v propyl bromide trong dung mi
chloroform th n s to phc vi Na trong mi
trng nc sau di chuyn vo mi trng CHCl
3
.
Bc tip theo phc s c thay th bi gc CN
-
v
Br
-
v nc chuyn ra ngoi.
- Tng hp cc ct phn tch HPLC, gc gn vo s to
nn nhng tng tc khc nhau i vi nhng cht
khc nhau i vi nhng cht khc nhau trong dung
dch cn phn tch nn thi gian lu khc nhau. Vd:
Nhng polymer gn 15-crown-5 vo tch nhng mu
c cha Cl
-
, Br
-
, F
-
, I
-
, SO
4
2-
.
- Phn lp ng v phng x: ch chn lc nhng hp
cht c kch thc ph hp, ng bng kch thc
vng Macro. Dng p- tertbutyl calix [8] arene thu hi
ng v phng x Cesium trong cht thi
- Phn tch cc ion: calyx[4] arene tch ion Fe
3+
ra khi
dung dch cha cc ion khc: Cu
2+
, Ni
2+
v Co
2+
.
- Trong MRI, xc nh cc m bt thng trong c th.
- Cc nguyn t phng x kt hp vi macro cyclic s
lm tng chn lc i vi nhng m lnh.
Cu 5: - cyclodextrin cha bao nhiu phn t
glucose:
A. 6 B.7 C.8 D.Khng
xc nh c.
Chn p n B.
Cu 6: Polime X c phn t khi l 420000 v h s
trng hp l 15000. Vy X l
A. PE. B. PP.
C. PVC D. Teflon.
a
a
a
2
= 4.r
Chn p n A.
Phn t khi ca monomer l : 420000/15000
= 28.
Vy monomer l CH
2
=CH
2
(M = 28)
Do polymer X l polyetylen (PE).
Cu 7: Mt mc xch ca polime X gm C, H, N. H
s polime ha ca polime ny l 500 v c phn t
khi l 56500. X ch c 1 nguyn t N. Mt xch ca
polime X l
A. NH (CH
2
)
5
CO B.
NH (CH
2
)
6
CO
C. NH (CH
2
)
10
CO D.
NH CH(CH
3
)CO
Chn p n A.
Phn t khi ca monomer l: 56500/500 = 113 , v
monomer l : -NH-(CH
2
)
5
CO-
Cu 8: Cng thc sau y c tn gi l :

A. Cryptand- 2,2,2.
B. Cryptand- 2,2,1.
C. Cryptand- 1,1,2.
D. Cryptand- 1,1,1.
Chn p n A.
Cryptand c c tn l Cryptand- m,m,n. Nhn trn
cng thc ta thy m=2 v n=2 nn n c tn l
Cryptand- 2,2,2.
Cu 9. C my phng php chnh sn xut CNTs?
A. 3 B.4 C.5 D.6
Chn p n B.
C 4 phng php chnh sn xut CNTs:
- Phng h quang in.
- Bo mn bng laser.
- Ngng t hi ha hc.
- Phn hy CO di p sut cao.
Cu 10: C my loi copolymer?
A. 2 B.3 C.4 D.5
Chn p n C.
C 4 loi copolymer l:
- Copolyme u n
- Copolyme khi
- Copolyme ngu nhin
- Copolyme ghp.
Cu 1:
TnhkhilngringcatinhthNi,bit Ni
kttinhtheomngtinhthlpphngtmmtvbnknhc
a Ni l 1,24
.Tnhthtchkhnggiantrngtrongmnglitinhthca
Ni?

A. 4,52 v 26
B. 9,04 v 26
C. 4,52 v 74
D. 9,04 v 74
0
A
Gii:
cm
r
a
8
8
10 . 507 , 3
2
10 . 24 , 1 4
2
4

= =
Khilngringcatinhth
( )
3
23
3
8
/ 04 , 9
10 . 02 , 6 10 . 507 , 3
7 , 58 4
cm g
N V
A n
a c
=

Bnknhnguynt Ni r = 1,24.10
-8
cm
Thtchnguynttrong cs:
V
nguynt
= snguynttrong cs x thtchnguynt
=
( )
3 23
3
8 3
10 . 19 , 3 10 . 24 , 1 14 , 3
3
4
4
3
4
4 cm r

= = t
Thtch cs:
( )
3 23
3
8 3
1
10 . 31 , 4 10 . 507 , 3 cm a V

= = =
Thtchkhnggiantrngtrongmnglitinhthca Ni:
(V
1
- V
nguynt
).100 / V
1
= (4,31.10
-23
3,19.10
-
23
).100/4,31.10
-23
= 26%
Cu 2:
Tnh s phi tr v khi lng ring ca tinh th CuCl
bit rng:
r
Cu
+ = 0,87 ; r
Cl
-= 1,84 ; M
Cu
= 63,5 g/mol; M
Cl
= 35,5 g/mol.
A. 4 v 2,065
B. 6 v 2,065
C. 6 v 4,13
D. 4 v 4,13
Ta c 473 . 0
84 . 1
87 . 0
= =
anion
cation
r
r

Nh vy s phi tr bng 6, c cu trc tng t
NaCl.





S ion Cl
-
trongmt cs: 8.1/8 + 6.1/2 = 4
S ion Cu
+
trongmt cs: 12.1/4 + 1.1 = 4
SphntCuCltrongmt csl 4.
Chiudicnh mngcs:
( ) ( ) cm r r a
Cl Cu
8 8 8
10 . 42 , 5 10 . 84 , 1 10 . 87 , 0 2 2

= + = + =
+

Khi lng ring ca CuCl l:
( )
( )
3
23
3
8
/ 13 , 4
10 . 02 , 6 10 . 42 , 5
5 , 35 5 , 63 4
cm g
N V
A n
a c
=

+
=

Cu 3:
tnghp250kg PVCthcn V m
3
khthinnhin
(ktc). Gitrca V l: (bit CH
4
chim 80%
thtchkhthinnhinvhiusutcacqutrnhl50%)
A.358,4
B.448
C.286,7
D.224
Gii:
CH
4
--> C
2
H
2
--> C
2
H
3
Cl --> PVC
0
A
0
A
Na
Cl
32-------------100%---------------62,5
X--------------50%----------------250
gi X lkhilngca CH
4
cndng =>
kg 256
50
100
5 , 62
250 32
=

MtrongkhthinnhinCH
4
chim80%=>smolkhthin
nhin=
3
448 448000 4 , 22 20000 20000
80
100
16
256000
m lit mol = = = =

Cu 4:
tnghp 120kg
polymetylmetacrylatvihiusutcaqutrnhhoestel
60% vqutrnhtrnghpl 80%
thcnlngaxitvrul:
A. 215kg axitv 40kg ru
B. 85kg axitv 40kg ru
C. 215kg axitv 80kg ru
D. 85 kg axitv 80 kg ru
Gii:
Sphnng:
------86----------------32-------------------------------------
-------------------------- 100
------X-----------------Y-----------------------48%---------
---------------------------120
Hiusutcacqutrnhl 0,6x0,8= 0,48
Gi X v Y
lnltlkhilngcaaxitvancolcndng ta c:
kg X 215
48
100
100
86 120
=

=
kg Y 80
48
100
100
32 120
=

=
Cu 5: Phtbiunosauylng:
A. Cao sulhpcht polymer ckhnngnhi
B. Cao
suthinnhinlhpchtcaophntckhaithcchyut
cyHevea brasiliensis. Monomer l izoprene C
5
H
8
.
C. Cao sunhntoctothnhnhphnngtrnghpcc
monomer isoprene.
D. C 3 trnung.
Cu 6:
Mu trong c th ngi c mu v cha
hemoglobin (cht vn chuyn oxi cha st). Mu ca
mt s ng vt nhuyn th khng c mu m c
mu khc v cha kim loi khc (X). T bo n v (
mng c s) lp phng tm din ca tinh th X c
cnh bng 6,62.10
-8
cm. Khi lng ring ca nguyn
t ny l 8920 kg/m
3
. Xc nh nguyn t X v phn
trm th tch nguyn t chim trong 1 n v t bo?
A. St v 74%
B. ng v 26%
C. St v 26%
D. ng v 74%
Gii:
T bo n v lp phng tm din nn s nguyn t
trong t bo n = 4 c cnh a = 6,62.10
-8
cm.
Bn knh nguyn t: 4r = a 2 r = 1,276.10
-8
cm.
Th tch b chim bi cc nguyn t
( )
3 23
3
8 3
10 . 48 , 3 10 . 276 , 1
3
4
4
3
4
4 cm r V

= = = t t
Th tch 1 mng c s
3 23 3
1
10 . 7 , 4 cm a V

= =
Khi lng mol phn t:
mol g
n
N V
M
A
/ 1 , 63
4
10 . 02 , 6 10 . 7 , 4 8920
23 23
1
=

=

=

Vy X l ng.
Phn trm th tch ng trong 1 n v t bo =
% 74
10 . 7 , 4
10 . 48 , 3
23
23
=

Cu 7:Cng ngh nano ng dng trong sn phm
kem chng nng s dng loi ht no?
A. Ion bc
B. CeO
2

C. TiO
2
v ZnO
D. Tt c cc loi trn
Cu 8: Ai l ngi u tin bit n cao su?
A. Antonio de Herrera
B. Christophe Colomb
C. Bourchadat
D. La Condamine
Cu 9: Loi cy cao su c a chung nht l loi
no?
A. Sapium
B. Euphorbia
C. Hevea brasiliensis
D. Castilloa elastica
Cu 10:CutrctinhthNaClthucloino?
A. Lpphngtmth
B. Lpphngtmkhi
C. Lcphngxpcht
D. Cththayitytheoiukin
1. Vt liu siu phn t c s gng kim (nguyn t) bao
nhiu th s to nn phc bn nht:
a. 3
b. 4
c. 5
d. 6
Chn c. 5 gng kim. Mc d s gng kim cng ln
th s cng bn nhng c 5 gng kim th s to c
phc bn nht.
2. Nng lng lin kt cng ha tr l bao nhiu:
a. 150-300 kcal/mol.
b. 125-300 kcal/mol.
c. 25-200 kcal/mol.
d. <10 kcal/mol.
Chn cu b
3. Trong hai cu trc ha hc ca cao su, th cu trc 2
cho sn phm c trng l g:
a. Acetyl ethanol v ethanal
b. Axetone v ethanal
c. Acetyl ethanol v axetone
d. Khng c p n no ng.
Chn cu a
4. Tnh d dn in ca graphene. 1 tm l 1m
2
c in
tr 45
Ta c R
T
= 45 , l = 1m, tnh ?
a. 6,25.10
6
(s/m)
b. 6,5.10
8
(s/m)
c. 6.10
8
( s/m)
d. 6,25. 10
7
(s/m)
Chn d v
R
T
= (1/( .A).l
Ta li c A= 1.0.335.10
-9
= 0,335.10
-9
m
2
0,335.10
-9
m: chiu dy ca grapheme.
Tng ng: 45= (1/( .0,355.10
-9
).1
Suy ra: = 6,25.10
7
(1/ .m) = 6,25.10
7
(s/m).
5. Cy cao su c phn thnh bao nhiu h thc vt:
a. 2 b.3 c.4 d.5
Chn d h gm: euphorbiceae, moraceae,
apocynaceae, asclepiadaceae v composeae.
6. Tnh ch s n ca polystyrene, bit phn t khi l
25480.
a. 240 b.245 c.250 d.255
Chn b v:
Cng thc ca polystyrene l (C
8
H
8
)
n
c khi lng
phn t l 104.
Suy ra n= 25480/104= 245.
7. Lai polymer no c s dng lm mng bao thc
phm:
a. Saran
b. Polypropylene.
c. Homopolymer (vinyl chloride_ vinylidene chloride).
d. C a v c u ng
Chn cu d v saran l tn thng mi ca
Homopolymer (vinyl chloride_ vinylidene chloride).
8. Phn ng trng hp din ra trong dng bao nhiu
bc v l cc bc no.
a. 2 bc: 1.phn ng pht trin mch, 2. Phn ng ng
mch.
b. 3 bc : 1.cht khi mu, 2. Pht trin mch, 3.
Phn ng ng mch.
c. 3 bc: 1. Pht trin mch , 2. Khi mu, 3. Phn ng
ng mch.
d. 2 bc: 1. Khi mu, 2. Pht trin mch.
Chn cu b
9. Hng mng ca hng A l:
a. [100] b.[111] c.[122]
d.[121]
Chn cu a.
10. Ta m c 32 ht/ 1 inch vung trn 1 hnh chp
phng i X300. Hi s kch thc ht theo ASTM
(n).
a. 8,15 b. 8,16 c.8,18 d.8,81
Chn cu c
V : nu ta m 32 ht /1 inch vung ti phng i
300 th ti phng i 100 ta s c:
N = (300/100)
2
.16 = 2
n-1

Tng ng log144 = (n-1).log2
2,16 = (n-1).0,301
Suy ra : n = 8,18
1.Ngi ta tin hnh ng trng hp etylen v
isopren thu c polime X. t chy hon ton 39
gam X cn 90,72 lt oxi(ktc). T l s mt xch
etylen : isopren?
a. 2:3 b.1:2 c.
1:3 d. 3:2
p n: a
Gii thch: polime X c dng: (C
2
H
4
)
x
(C
5
H
8
)
y

nO
2
= 4,05mol
Gi a, b l s mol CO
2
v H
2
O sinh ra
=>
n
O
2
=2a + b = 4,05*2 ;
m
polymer=12a + 2b = 39 =>
a = 2,85 ; b = 2,4
=>

<=>


=0,59375 => x : y = 2 : 3
2.Alternating copolymer l loi polymer c cu
trc
a. u n b.khi c.
ngu nhin d.nhnh
p n: a
Gii thch: V Alternating copolymer c cu trc nh
sau -A-B-A-B-A-A-B-A-B-A-B-A-B-A-B- rt l u
n
3. phn tn cacbon nanotubes vo nc cn
iu kin no sau y:
a. Cho ngun sng siu m c nng lng ln
b. Cn s h tr ca cht phn tn(thng l cht hu
c)
c. C hai u ng
d. C hai u sai
p n: c
Gii thch:Cacbon nanotubes khng tan trong nc
nhng n c th phn tn u trong nc khi tha cc
iu kin sau:
-Cho ngun sng siu m c nng lng ln
-Cn s h tr ca cht phn tn(thng l cht hu
c)
4. Than ch gm nhng tm cacbon hnh lc gic
xp chng ln nhau nh lin kt
a. van der waals b. ion c.
cng ha tr d. ha tr
p n: a
Gii thch:Than ch hay cn gi l graphit gmg
nhng tm cacbon hnh lc gic xp chng ln nha
nh lin kt van der waals (slice 3, chng vt liu
nano)
5. Ngi ta lm phim chp nh t hn hp no?
a. polyvinyl alcol v xenlulose nitrat b. polyeste v
polyuretan
c. xenlulose nitrat v long no d.long
no v polyuretan
p n: c
Gii thch: xenlulose nitrat l cht do c tnh n
hi, d tan trong dung mi thch hp v d to hnh
di tc dng ca ca nhit v p sut.
6.Cu to mch ca amilopectin thuc loi mch
no?
a. mch khng phn nhnh b.mch phn
nhnh
c. mch mng li d. loi mch
khc
p n: b
Gii thch:Amilopectin v amilose l hai thnh phn
chnh c trong tinh bt, amilose thuc loi mch
thng, khng phn nhnh; nhng amilopectin l loi
mch phn nhnh.

7.Teflon l loi polymer c cng thc cu to l (-
CF
2
-CF
2
-)n. Phn t khi ca on polymer teflon
ny l 21300. Vy s mt xch ca loi polymer ny
l:

a. 245 b. 213 c.
267 d. 225
p n: b
Gii thch:
m
(-CF2-CF2-)n=100n=21300 n=213
Vy s mt xch ca on teflon l 213
8.Khi t chy mt polymer sinh ra t phn ng ng
trng hp isopren(C
5
H
8
) vi acrilonitrin(C
3
H
3
N) bng
lng oxy va th thu c hn hp kh cha
58,33%CO2 v th tch. Vy t l mt xch gia
isopren v acrilonitrin trong polymer trn l:
a. 1:3 b. 1:2 c.
2:1 d. 3:2
p n: a
Gii thch:t
n
(C
5
H
8
)=x;
n
(C
3
H
3
N)=y
C5H85CO2+4H2O
C3H3N3CO2+1,5H2O+0,5N2
Ta c (5x+3y)/(9x+5y)=0,5833 y=3x x:y=1:3
9. dn in ca cacbon nanotubes so vi dn
in ca kim loi thng thng l:
a. dn in ca cacbonnaotubes ln gp 10
5
ln so
vi kim loi
b. dn in ca cacbonnaotubes ln gp 10
2
ln so
vi kim loi
c. dn in ca kim loi ln gp 10
2
ln so vi
cacbonnaotubes
d. dn in ca kim loi ln gp 10
5
ln so vi
cacbonnaotubes
p n: a
Gii thch:Trch t bng cu trc v tnh cht ca
CNTs (slice 38 ca chng vt liu nano).
10.Kiu trng hp no ca isopren cho ra cao su?
a. kiu trng hp C1-C4 b. kiu trng
hp C2-C3
c. kiu trng hp C1-C2 d. kiu trng
hp C3-C4
p n: a
Gii thch:CTCT ca isopren l CH2=C(CH3)-
CH=CH2
V isopren c 2 ni i nn c 3 kiu trng hp nh
sau:
-Trng hp C1-C2 th c polymer (-CH2-
C(CH3)(CH=CH2)-)n
-Trng hp C3-C4 th c polymer(-
(CH2=C(CH3))-CH-CH2-)n
-Trng hp C1-C4 th c polymer(-CH2-C(CH3)-
CH-CH2-)n l cao su
Cu 1. Lin kt trong mnh tinh th mui n l lin kt:
A. Lin kt hydro. B. Lin kt cng ha tr C.
Lin kt ion D. Lin kt kim loi
Cu 2. u khng phi l ng dng ca vt liu siu phn
t:
A. Phn lp ng v phng x v tinh ch ha cht.
B.ng dng trng y hc v m phm.
C. ng dng trong k thut ha phn tch.
D.ng dng trong thc phm
Cu 3. T nilon-6,6 l sn phm ca phn ng trng
ngng gia:
A. HOOC-(CH
2
)
4
-NH
2
v
6
2 2
( ) OO H N CH C H
B.
2 4
OO ( ) OO H C CH C H v
2 2 4 2
( ) H N CH NH
C.
2 4
OO ( ) OO H C CH C H v
2 2 6 2
( ) H N CH NH
D.
2 6
OO ( ) OO H C CH C H v
2 2 6 2
( ) H N CH NH
Cu 4.: Lin kt no trong vt liu siu phn t chim
nng lng ln nht:
A Lin kt ion ion. B Lin kt ion
lng cc.
C Lin kt lng cc lng cc D Lin
kt hidro.
Cu 5. Polime c cc tnh cht vt l no sau y?
Polime:
A. cc cht rn khng bay hi
B. Hu ht khng tan trong nc
C. Khng c im nng chy c nh
D. Tt c cc tnh cht trn u ng
Cu 6. Cao su c nhng tnh cht vt l no sau y:
A. Tnh n hi
B. Khng thm nc v kh
C. Cht chu mi mn
D. Cht cch in tt
E. Tt c cc tnh cht trn
Cu 7: Polime c cu trc mng khng gian (mng
li) l:
A. PE B. amilopectin C. PVC
D. nha bakelit
Cc cht cn li mch thng
Cu 8. T c sn xut t xenluloz l:
A. t nilon6,6. B.
t visco.
C. t tm, t axetat. D.
t capron, t enang.
Cu 9. nh vc ng dng ch yu ca polime:
A. Cht do. B. Cao su. C. T
tng hp. D C 3 trn
Cu 10: Polivinyl clorua c cng thc l
A. (-CH
2
-CHCl-)
n
. B. (-CH
2
-CH
2
-)
n
. C. (-CH
2
-CHBr-)
n
.
D. (-CH
2
-CHF-)
n
.
1 .tnh mt nguyen t khi ca Mng tinh th lp
phng tm din

S qu cu trong mt c s : 6. 1/2 + 8. 1/8 =
4
Tng th tch qu cu

Th tch ca mt c s a
3

a
3

a.0.68 b.0.74 c.0.62
d.0.8
2 . Tnh khi lng ring ca tinh th Ni, bit
Ni kt tinh theo mng tinh th lp phng tm din v
bn knh ca Ni l 1,24 .
Gii:

a=
; P = 0,74
Khi lng ring ca Ni:
=9,04 (g/cm
3
)
a.7.8(g/cm3) b.9.04(g/cm3)
c.8.896(g/cm3) d.6.325(g/cm3)
3.chn cu sai:
a. Phn ng trng hp l phn ng kt hp
nhiu monome ca cng mt cht to thnh polyme.
b. Phn ng trng ngng l phn ng kt hp
nhiu monome to thnh polyme v mt sn phm
ph (ch yu l nc)
c. Phn ng trng-cng hp l phn ng kt hp
nhiu monome ca hai hay nhiu cht to thnh
polyme
d. Cc monome kt hp vi nhau thnh mt monome
chnh nh phn ng th
ap an :d
4.chon cu ng
a
a
a
2
= 4.r
3
4
4. .
3
r t
3
4 2
4. .( )
3 4
a t
0
A
a
a
a 2 = 4.r
0
4 4.1, 24
3, 507( )
2 2
r
A = =
8 3 23
3.58, 7.0, 74
4.3,14.(1, 24.10 ) .6, 02.10

= = = 74%
a. Tnh cht ha hc ca mt loi polymer ph thuc
rt nhiu vo kch thc hay di ca chui
polymer.
b. Polyme cha ch c mt loi monome n v lp
li c gi l polyme n
c. trng hp l s mt xch c bn trong phn t
polyme
d.tinh bt ,xelulozo,protein v t visco l polyme t
nhin
ap an:c
5.graphene l ?
a. graphene l tm phng dy bng mt lp nguyn t
ca cc nguyn t ccbon
b. graphene l mt tm phng than ch tch ra c
nguyn t
c. Graphen l mt dn tinh th hnh t ong ca cc
nguyn t ccbon.
d.tt c u ng
d/a :d
6. cao su ..
a. Cao su l mt loi vt liu polyme va c bn
c hc cao v kh nng bin dng n hi ln.
b. Cao su l mt loi nha c tnh n hi, c lm
bng m ly t mt vi loi cy gc Chu
M hoc Chu Phi.
c. khng tan trong nc nhng tan trong mt s cht
lng khc
d.a,b,c ng d/a :d
7.chn cu sai
a.ngun gc cy cao su l t nam m
b.cao su ch trng c vng nhit i v cn nhit
c. Cao su t nhin thng c ch bin t nha cy
cao su
d. cao su nhn to thng ch bin t than , du
m.
d/a: b
8 chn cau ng
a. Cao su styren-butaien l vt liu c bn cho phn
ln cc loi cao su tng hp.
b. Cao su styren-butaien c n nh km trong cc
mi trng axt hu c v v c cng
nh baz hay nc v ru
c. Sau khi polyme ha th styren-butaien vn dng
lng c lu ha v tr thnh cht rn.
d. C ba du sai
9.cao su nhan to u tin
a.c tng hp c b.l 2,3 dimetyl-butadien
c.1890 d.phc v cho thng mi
dap an c
10.cac ng dng ca vt liu siu phn t
a. phn lp ng v phng x b.xc tc c.tng hp ha
cht d. tt c trn.
Dap an d
Cu 1 : Hy tnh hm lng ( phn trm khi lng )
nhm cui ( end group ) ca polystyren c khi lng
phn t l 150 000. Gi s rng nhm phenyl ( C6H5-
) l nhng nhm cui ca mi phn t polymer trung
bnh.
A.0.001 B.0.01
C.0.0001 D.0.1
Cu 2 : Poly(hexamethylene adipamide) ( Nylon-6,6)
c tng hp bng phn ng trng ngng gia
hexamethylenediamine v axit adipic theo t l mol
1:1. Tnh hm lng polymer cha 1 nhm acid bit
rng mc polymer ha l 440.
A.99548(g/mol) B.54985(g/mol)
C.99458(g/mol)
C.59854(g/mol)
Cu 3 : Gi s rng mi lin kt mng to ra trong
qu trnh lu ha cha trung bnh 2 phn t lu
hunh. Tnh hm lng ca lu hunh trong cao su
thin nhin c lu ha cha 50% lin kt mng.
A.19% B.91%
C.39% D.93%
Cu 4 : Mt cao su cha 60% butadien, 30% isopren,
5% lu hunh v 5% carbon en. Nu mi lin kt
mng cha 2 phn t lu hunh.Tnh thnh phn lin
kt mng hnh thnh trong qu trnh lu ha?
A.0.506 B.0.01
C.0.101 D.0.605
Cu 5 : Mi phn t polymer c ng rn c dng
hnh cu, ng knh 1cm, khi lng ring l
1g/cm
3
. Hy tnh khi lng mol ca mi phn t
polymer.
A.3.025 x 10
24
(g/mol) B.3.025
x10
25
(g/mol)
C. 3.15x10
23
(g/mol) D.2.15
x10
25
(g/mol)
Cu 6 : Cht no di y khng th s dng trc
tip tng hp cao su:
A. clopren B.
isopren
C.divinyl D.
propilen
Cu 7 : Ngi ta tng hp PVC trong thc t theo s
sau : CH4->C2H2->C2H3Cl->PVC. tng hp
375g PVC theo s trn th cn bao nhiu kh thin
nhin ( ktc ). Gi s CH4 chim 80% th tch kh
thin nhin v hiu sut ca c qu trnh l 40%.
A.835(m
3
)
B.845(m
3
)
C.840(m
3
)
D.850(m
3
Cu 8 : Trng ngng Urea-formaldehyde thu c m
kg polymer v 10.6kg nc vi hiu sut 80%. Xc
nh gi tr ca m.
A.35.46(kg) B.36.45(kg)
C.34.56(kg)
D.36.54(kg)
Cu 9 : phthalic anhydride c bao nhiu nhm chc
ca monomer sau phn ng vi methyl methacrylate :
A.0 B.1
C.2 D.3
Cu 10 : Monomer styren cha 0.02% khi lng
cht khi mo l benzoyl peroxide. Gi s rng hiu
sut hot ng ca cht khi mo l 100% v phn
ng kt thc mch bng cch kt hp cc chui
polymer n l. Nu trng thi cui tn ti 22%
monomer khng phn ng, hy tnh mc phn ng
polymer ha trung bnh.
A.8090 B.9080
C.9900
D.8080
BI GII:
Cu 1: Khi lng mol ca nhm phenyl = 6x12 +
5x1 = 77g/mol
Phn trm khi lng ca nhm cui = (2x77g/mol) /
(150 000g/mol) = 0.001
Cu 2:Khi lng mol ca mi mt xch = 226g/mol
v n=440
Khi lng mol trung bnh mi phn t polymer =
440x226 + 18 = 99458g/mol
Vy, khi lng mi phn t polymer cha 1 axit l
99458 g/mol
Cu 3: Khi lng mol ca isopren (C5H8) = 5x12 +
8x1 = 68(g/mol)
Vi mi lin kt mng ( cha 2 phn t lu hunh ) s
kt ni 2 n v isopren li vi nhau.
Do , hm lng lu hunh = 0.5x32g/( 0.5x32g +
68g) = 0.19 tng ng 19%
Cu 4: Khi lng mol butadien (C4H6) = 54g/mol,
Khi lng mol isopren ( C5H8) = 68g/mol
Mi phn t lu hunh tng ng vi mi lin kt
mng trn mi mt xch.
Do , hm lng lin kt mng =(5g/(32g/mol))/(
(60g/(54g/mol) + 30g/(68g/mol) )= 0.101 hay 10.1%
Cu 5: Khi lng mol = Khi lng/S mol = (Th
tch)x(Khi lng ring)x(S avogadro) =
(3.14x1(cm
3
)/6)x(1g/cm
3
)x(6.02x10
23
mol
-1
) =
3.15x10
23
g/mol )
Cu 7: Khi lng mol monomer vinyl clorua l
62.5g/mol
p dng bo ton i vi nguyn t C, ta c :
S mol CH4 = 2x s mol PVC = 2x(375/62.5) = 12
kmol
Hiu sut 40% v CH4 chim 80% kh thin nhin
nn th tch cn c l :
12 x (100/40) x (100/80) x 22,4 = 840 (m
3
)
Cu 8: Cng thc ca Urea-formaldehyde l (-HN-
CO-NH-CH2-)n
Khi lng mol mi mt xch = 72g/mol v S mol
nc = 10.6kg/(18g/mol) = 600 mol
Nu hiu sut 100% th khi lng ca polymer to
thnh = 72x600 = 43200g
Do hiu sut l 80% nn gi tr ca m = 43200x80% =
34560g = 34,56(kg)
Cu 9: Gi s c 1000g styren.Ta c
Khi lng mol ca styren ( C8H8 ) = 8x12 + 8x1 =
104g/mol
Khi lng mol ca cht khi mo ( (C6H5CO)2O2 )
= 242g/mol
Hm lng ca cht khi mo = 1000x0.02% = 0.2g
S mol cht khi mo = 0.2g/(242g/mol) = 8.26x10
-4

mol
Mi mol cht khi mo tng ng vi mi mol
polymer nh hnh bng phn ng kt thc mch ghp
i.
Do , s mol polymer hnh thnh = 8.26x10
-4
mol
Styren phn ng = (100 - 22) x 1000g / 100 = 780g
S mol styren phn ng = 780g/(104g/mol) = 7.5 mol
Mc polymer ha DP = 7.5mol/(8.26x10-4mol) =
9080
Cu 1: Cao su buna c sn xut bng phn ng
trng hp:
a. CH
2
=CH-CH=CH
2
C mt Na
b. CH
2
=CH-CH=CH
2
c mt S
c. CH
2
=CH-CH=CH
2
c mt P
d. CH
2
=CH-CH=CH
2
C mt Mg
Cu 2: Qu trnh lu ha cao su: un nng 150
0
C
hn hp cao su v:
a. Cl
2.
b. S

c. Na

d. H
2
Cu 3: Polimer c phn ng:
a. Phn ct mch polime
b. Gi nguyn mch polime
c. Pht trin mch polime
d. C A,B,C
Cu 4: Lnh vc ng dng ch yu ca polymer:
a. Cht do
b. Cao su
c. T tng hp
d. C a,b,c
Cu 5: tng tnh chu nhit cho cht do, ngi
ta thm vo:
a. Bt amiang
b. Bt kim loi
c. Than mui
d. Bt graphit.
Cu 6: Nhng vt liu c kh nng b bin dng
khi chu tc dng ca nhit, ap sut v vn gi
c s bin dng khi thi tc dng, c gi
l:
a. Polime
b. Cht do
c. Cao su
d. T
Cu 7: Polime no c cu trc mng khng gian?
a. Cao su thin nhin
b. Cao su buna
c. Cao su lu ha
d. Cao su pren
Cu 8: Polime no khng tan trong mi dung mi
v bn vng nht v mt ha hc:
a. PVC
b. Cao su lu ha
c. Teflon
d. T nilon
Cu 9: Polime no c th tham gia phn ng cng:
a. Polietilen
b. Cao su t nhin
c. Teflon
d. Thy tinh hu c
Cu 10: Nhng polime thin nhin hoc tng hp
c th ko thnh si di v mnh gi l:
a. cht do
b. cao su
c. t
d. si
Cu 1 c im no sau y khng ph hp khi ni
v tnh cht ca Polime
A./ Cc monome tham gia phn ng trng ngng phi
cha t nht hai nhm cht trong phn t
B./ Trong giai oan khi mo ca phn ng trng hp
cc gc t do tng tc vi monome to thnh gc t
do mi
C./ im ging nhau gia phn ng trng hp v
trng ngng l khi to thnh Polime t cc
monome c to ra sn phm ph l hp cht phn
t thp
D./Phn ng trng ngng xy ra theo tng bt v
Polime khng to ra ngay lp tc m i hi thi gian
ko di
Cu 2 Phn ng trng hp c khi mo bng
phng php no sau y
A./ S dng cc cht c phn ng thnh gc t do
B./ S dng nhit hoc tia t ngoi tc ng ln
monome
C./ S dng cc tia phng x chiu ln monome
D./Tt c cc trn
Cu 3Theo phn loi ca vt liu Nano th kiu vt
liu Composile c ngha l:
A./ l cc ht rn nn trong phm vi 1-1000nm c th
l khng tin th, l khi kt t ca cc vi tinh th hoc
vi n tinh th
B./ l bt c vt liu rn no c kch thc Nonomet;
ba chiu=>ht; hai chiu => mng mng; mt
chiu=> dy mng
C./ l vt liu lai hp tnh v c/ ha c
D./ l ht rn ngha l n tinh th c kch thc
Nanomet
Cu 4 Trong phn ng ch to Epetaxi graphene t
SIC th tnh cht no sau y l ph hp
A./ cht lng cao, gi cao. ng dng trong dng
c in t transitor tn s cao.
B./ cht lng cao, gi trung bnh. ng dng trong
dng c sinh hc, dng c in t v quang hc
C./ cht lng thp, gi thp.ng dng: mc in, dng
c sinh hc, lp ph dn in
D./ cht lng cao, gi cao.ng dng:nghin ca vo
to mch
Cu 5 Khi lu ha cao su buna ngi ta thu c 1
loi cao su lu ha trong lu hunh chim 1,876%
v khi lng. T l s mt xch cao su b lu ha v
khng b lu ha l:
A. 1 : 20 B. 1 :21 C. 1 : 30 D. 1 : 31
Gii:
Gi x,y ln lc l s mc xch cao su b la ha v
khng la ha.
M la hunh chim 2% v khi lng nn ta c
ph ng trnh sau:

=> 30.02 = 1.34y =>

Cu 6 : un nng 90g propanol vi H
2
SO
4
m c
170
o
C. Ly ton b lng anken to ra sau phn ng
tng hp cht do. Bit rng hiu sut phn ng
tch nc v phn ng trng hp ln lt l 60%
v100%. Khi lng cht do thu c l:
A. 37,8g B. 63g C. 105,4g
D. 54g
Gii: Ta c s mol C
3
H
8
O = 90/60 = 1.5 (mol)
Phng trnh p: CH
3
-CH
2
- CH
2
-OH => CH
2
=CH-
CH
3

1.5 mol 1.5mol
V hiu xut 60% => s mol CH
2
=CH-CH
3
l
1.5x0.6 = 0.9 (mol )
Phng rnh p to ra cht do l: n CH
2
=CH-CH
3

=>-( CH
2
=CH-CH
3
)
n
-
0.9 0.9
=> khi lng tnh c l: 0.9x42 = 37.8g
Cu 7: Cho cng thc cu to sau:
s

o o
o o
s
A./ 18-cromn-6
B./ Diaza-18-crown-6
C./ Miathina-6-crown
D./ Dithia-18-crown-6
Cu 8: Tn loi cy cao su no sau y c a
chun nht.
A./ Hevea brasiliensis
B./ Mani hot glaziovii]
C./ Fians elastic
Cu 9: Phng php co m cao su no sau y l
ph hp nht.
A./ Ngi ta co v thn cy t chiu cao 1m cch
mt t, co theo dng xon c na chu vi thn t
tri sang phi vi dc l 30
0
, 1-2 ngy/1ln
B./ Ngi ta co v thn cy t chiu cao 1m cch
mt t, co theo dng xon c nguyn chu vi thn
t tri sang phi, 3-4ngy/1ln
C./ Ngi ta co v thn cy t chiu cao 1m cch
mt t, co theo dng xon c hai na chu vi thn
t tri sang phi, 2-3 ngy/1ln
D./ C A v B ng
Cu 10 :Trong phng php loi Ion kim loi khi
mcrocyclic, giai on thm thuc th oxy ha kh
th xc tc no tham gia trong phng trnh sau l ph
hp.
[Co(Sepulchrate)]
3+
=> (1)? [Co(Sepulchrate)]
2+
=>
(2)? H
2
Sepulchrate
6+

A./ (1)Zn
2+
, (2) KCN, HCl
B./ (1) Zn
2+
, (2) LiOH, HCl
C./ (1) Cu
2+
, LiOH, HCl
D./ (1) Cu
2+
, CH
2
O, NH
3
.
Cu 1:Polime no c tnh cch in tt ,bn c lm
ng dn nc ,vi che ma, vt liu in?
A:Cao su thin nhin
B: polivinyl clorua
C :Polietylen
D: thy tinh hu c
Cu 2: Dng Poli vinyl axeta c th lm vt liu no
sau y:
A: Cht do
B: Cao Su
C: T
D: Keo dn
Cu 3:Khi tin hnh ng trng hp CH
2
=CH-
CH=CH
2
v CH
2
=CH ta thu c mt

CN
loi cao su cha 8,696% N v khi lng. Tnh t l
s mol ca CH
2
=CH-CH=CH
2
v CH
2
=CH .
CN
A. 2:1 B. 1:2
C. 2:3 D. 3:2
Gii. Gi t s mol ca CH
2
=CH-CH=CH
2
v
CH
2
=CH trong cao su l x:y
CN
%N=

.100%=8,696%
x:y= 2:1
Cu 4: Poli (metyl metacrylat) v nilon-6 c to
thnh t cc monomer tng ng l:
A: CH
3
-COO-CH=CH
2
v H
2
N-[CH
2
]
5
-COOH
B: CH
2
=C(CH
3
)-COOCH
3
v H
2
N-[CH
2
]
6
-COOH
C: CH
2
=C(CH
3
)-COOCH
3
v H
2
N-[CH
2
]
5
-COOH
D: CH
2
=CH-COOCH
3
v H
2
N-[CH
2
]
6
-COOH
Gii: n H
2
N[CH
2
]
5
COOH xt,t
0
,p ( HN-[CH
2
]
5
-
CO )
n
+ H
2
O
Axit -aminocaproic nilon-6
CH
3
n CH
2
=C-COOCH
3
xt,t
0
,p ( CH
2
-C )
n
CH
3
COOCH
3
Cu 5: Ngi ta a ht g vo bng ,bng y lm
tng mch tch khng khun:
A : Ht Nano Ag
B : Ht Nano ZnO
C : Ht Nano TiO
2
D : Ht Nano AlSiO
2
Cu 6: Cho mp B ct h trc ta xyz ln lc ti
x=2/3 ; y=1/3 ; z= 1. Tm ch s Miller.
A: 362 B: 623 C: 326 D:
263
Gii : mp B ct cc trc x,y,z ti 2/3; 1/3; 1
- Nghch o li ta c : (3/2,3,1)
- Quy ng mu s (3,6,2)
- Ch s Miller 362
Cu 7: D on cu trc tinh th ca hp cht CaCl
2
:
A: ZnS
B: NaCl
C: CsCl
D: Tt c u sai
Gii: Ta c

=0.552
Trong trng hp ny s phi tr = 6
S dng cu trc NaCl
Cu 8:Cho polimer X c khi lng phn t 504000
h s trng hp n=1200. Hi X c cu to nh th
no?
A: ( CH
2
CH
2
)
n

B: ( CH
2
-CH )
n
CH
3
C: ( NH-[CH
2
]
5
-CO )
n
D: Tt c u sai
Gii: M
mc xch
=

=42
X l : ( CH
2
-CH )
n

CH
3
Cu 9: Phn ng trng hp lm phn ng:
A: Cng hp lin tip phn t nh (Monome) ging
nhau thnh phn t ln( polime)
B: Cng hp lin tip t cc phn t nh ( Monome)
ging nhau thnh mt phn t ln (Polime) v gii
phng phn t nh.
C: Cng hp lin tip gia cc phn t nh
(Monome) ging nhau hoc gn ging nhau thnh
mt phn t ln polime
D: Cng hp lin tip t cc phn t nh ( Monome)
thnh mt phn t ln (Polime) v gii phng phn t
nh.
Cu 10: Loi cao su no sau y l kt qu ca phn
ng ng trng hp:
A. Cao su buna
B. Cao su buna-N
C. Cao su isoprene
D. Cao su clopen

Cu 1. Polime X l sn phm ng trng hp ca
stiren v 1 anken Y. Phn t khi ca X l
198000dvC c t l s mt xch ca stiren : Y l 3:2.
Mt khc t 39,6g X cn 87,36 lt O2 (dktc). Tng
s phn t stiren v Y to nn 1 phn t X
A.2400 B.2500
C.2600 D.2800
Gii
X = [(C
8
H
8
)
3
(C
n
H
2n
)
2
]
a


C
2n+24
H
4n+24
+ (3n+30)O
2
---> (2n + 24)CO
2
+ (2n +
12)H
2
O
(28n + 312)___(3n + 3)
__ 39.6 _______3.9

--> n = 3 --> X = [(C
8
H
8
)
3
(C
3
H
6
)
2
]
a


M
X
= (104*3 + 42*2)a = 198000 --> a = 500

--> Tng s phn t stiren v Y to nn 1 phn t X =
(3 + 2)*500 = 2500
Cu 2: Cht no sau y c kh nng trng hp thnh
cao su . Bit rng khi hir ha cht thu c
isopentan?
A. CH3-C(CH3)=CH=CH2 B. CH3-CH2-CCH
C. CH2=C(CH3)-CH=CH2 D. Tt c u sai
Cu 3: Cho cc polime sau: poli stiren; cao su
isopren; t axetat; t capron; poli(metyl metacrylat);
poli(vinyl clorua); bakelit. Polime s dng sn xut
cht do gm.
A. polistiren; xenluloztri axetat; poli(metyl acrylat).
B. polistiren; xenluloztri axetat; poli(metyl
metacrylat); bakelit
C. polistiren; poli (metyl metacrylat); bakelit,
poli(vinyl clorua)
D. polistiren; poliisopren; poli(metyl metacrylat);
bakelit
Cu 4: Phn t polime bao gm s lp i lp li ca
rt nhiu cc
A. monome B. an mch
C. nguyn t D. mt xch
Cu 5: T c tng hp t xenluloz c tn l
A. t axetat. B. t poliamit.
C. polieste. D. t visco.
Cu 6: Tnh c kh ca mng tinh th lp phng
tm khi
A.55% B.58%
C.65% D.68%
Gii:
Trong mng lp phng tm khi:
+mi t bo mng c 2 qu cu (8.1/8 (nh)+ 1(tm))
+thng s mng: a=4R/
3

c kht: P=2.4/3.Pi.R
3
/ a
3
= 68%

Cu 7 Thy phn 86 gam poli(vinyl axetat) iu
ch poli(vinyl ancol) thu c 48,2 gam polime. %
khi lng ca polime cha b thy phn l.
A.20% B.8%
C.25% D.10%
Gii
Ta c : n
(vinyl axetat)
=

1 mol
gi x l s mol p
44x + 86(1-x) = 48,2
=> x = 0,1
=> H= 10%
Cu 8: un 248 gam hn hp X gm phenol v
fomandehit (t l mol 1 : 1), xc tc axit thu hn hp
X gm polime v 1 cht trung gian l o-
hidroxibenzylic (Y). Loi b polime, cho Y phn ng
va dung dch Br2 thu 28,2 gam kt ta. Hiu sut
ca phn ng to ra polime l.
A. 90% B. 95%
C. 85% D. 80%
Gii:
Ta c : n(phenol) = n(fomandehit) = 2 mol
n(kt ta)= 0,1 mol = n(o-hidroxibenzylic)
sp ch thu c 2 cht => s mol ca phenol p l 1,9
=> H=95%
Cu 9: phn bit da tht v da gi lm bng PVC,
ngi ta thng dng phng php n gin l
A. t th B. thu phn. C. ngi. D. ct.

Cu 10: Nha rezit l mt loi nha khng nng
chy. to thnh nha rezit, ngi ta un nng ti
nhit khong 150oC hn hp thu c khi trn cc
cht ph gia cn thit vi
A. novolac. B. PVC.
C. rezol. D. thu tinh hu c.
Cu 1: st alpha kttinhtheomnglpphngtmkhi.
Xcnhbnknhnguyntsttrongst alpha
bitttrngcanbng 7,86. Cho Fe = 55,8 g/mol.
A. 0,397 nm
B. 0,497 nm
C. 0,597 m
D. 0,697 m
pn: B
V
c
= a
3
= (4/R)
3

Ta c

Suyra R = 4,97 10
-8
cm = 0,497 nm.
Cu 2: CutrcmngMonocliniccthtch mngl
A. a
3
B.abc C.abcsin
D0,866a
2
c
pn: MngtinhthMonoclinicc 2 gcbng 90
o
v 1
gckhc 90
o

VypnC
Cu 3: CbaonhiuphngphptnghpGraphene:
A. 2 B.3 C.4 D.5
pn: C, bnphngphplngngnghahc,
tchlpchc, epetaxigraphenetSiC, lprpphn t.
Cu 4:
Tngicahpchthahcccngthcnhhnhbndi
l:

A. 4-aminobenzo-15-crown-5 B.5'-aminobenzo-
15-crown-5
C.3-aminobenzo-15-crown-5
D.aminobenzo-15-crown-5
pn: A,
Cu 5: Khilngphntcathytinhhuc
(polimetylmetaacrylat) l 25000 dvc,
smtxchcaphntthytinhhucl:
A. 166 B. 250 C. 183 D. 257
pn: Khilngmtmtxchl 100dvc,
nnsmtxchl 25000/100 = 250. Cu B
Cu 6: Mtdngtnilonc 63,68% cacbon, 12,38%
nito, 9,8% hidro, 14,4% oxy, vkhilng.
Cngthcthcnghimcanilonl:
A. C
5
H
9
NO B. C
6
H
11
NO C.
C
6
H
10
N
2
O D. C
6
H
11
NO
2

pn: C:H:N:O =63,68/12:9,8/1:12,38/14:14,4/16 =
5,3:9,8:0,88:0,9 6:11:1:1
Nncngthcthcnghiml C
6
H
11
NO, pn B.
Cu 7: Htnanonocthmvokemdng da:
A. ZnO B. Fe C. FeO D. Zn
pn: B sung
vokemchngZnOhocTiOckhnngchngtiacctm
gyungth da. pncu A
Cu 8: Graphenbng nano (GNRs) l:
A. Vtliu nano 0 chiu
B. Vtliu nano 1 chiu
C. Vtliu nano 2 chiu
D. Vtliu nano 3 chiu
pn : C
Cu 9 : t chy hon ton m gam cao su isopren
c lu ha bng khng kh va (cha 20% O
2
v
80% N
2
), lm lnh hn hp sau phn ng ngng t
ht hi nc th thu c 1709,12 lt hn hp kh
(ktc). ng kh ny lm ny tc dng va ht vi
dung dch cha 0,1 mol Br
2
. Xc nh m
A.159,6gam B.159,4gam C.141,1gam D. 141,2
gam
pn:
Ta c: n
hh kh
= 76,3 mol
SO
2
+ Br
2
+ 2H
2
O --> H
2
SO
4
+ 2HBr
=> nSO
2
= 0,1mol
Gi x l s mol C
5
H
8

C
5
H
8
+ 7O
2
--> 5CO
2
+ 4H
2
O
=> nO
2
= 7x => nO
2
ban u = (7x + 0,1) => nN
2
=
4(7x + 0,1)
=> 28x + 0,4 + 5x = 76,2 => x = 75,8/33
=> m = 68*75,8/33 + 3,2 = 159,4 gam
pn: B
Cu 10:
Tcapronccngthcphnttrnghpchtnosauy:
A. Nilon 6
B. Nilon 6,6
C. Nilon 7
D. Ttcusai
pn: u c cng thc C
6
H
11
NO l cog thc ca t
capron v nilom 6. p n A
1) S mc xch c trong 10,2g poliisopren l

A. 9,03.10
22
B.
9,03.10
21

C.9,03.10
26
D.
6,02.10
23

Gii:
Ctct: CH
2
=C-CH=CH
2

CH
3

Khi lng mol 1 monomer isoprene = 68
S mc xch = (khi lng / khi lng mol). S
Avogadro
= (10,2 / 68).6,02.10
23

=9,03.10
22
2) Trng ngng axit c-aminocaproic thu c m kg
polimer v 12,6kg nc vi hiu sut phn ng 90%.
Gi tr ca m l:

A. 71,19 B. 79,1
C.91,7 D.
90,4
Gii:
Ptpu: nH
2
N(CH
2
)
5
COOH (HN-(CH
2
)
5
-CO)
n
+
nH
2
O
S mol nc:

= 0,7 mol
s mol polimer =

Khi lng mol polimer:
M = 113n
Khi lng axit c-aminocaproic:
m = M.n = 113n x

= 79,1 g
3) Cao su lu ha cha 2% lu hunh.Gi s lu hunh
tn ti di dng cu ni isunfua(-S-S-) bng cch
thay th cc nhuyn t H trong nhm nguyn t
metylen trong mch cao su.s mt xch trung bnh ca
isopren c trong mt cu ni isunfua l bao nhiu:

A. 42 B.44
C.46 D.48

gii :
Ptpu

C
5n
H
8n
+S
2
>C
5n
H
8n
2S
2


Ta c : 32.258n+30=0,02=> n = 46

4) Cho 1,05 gam cao su Buna-S p va ht vi 0,8 gam
brom trong CCl
4
.T l mt xch buta-1,3-ien v stiren
trong cao su lf bao nhiu?
A)2:3 B) 3:2
C)1:3 D)3:1
Gii:
gi n v m ln lt l s mt xch ca butadien v
stiren
Ct: (CH
2
CH=CHCH
2
)
n
(CHCH
2
)
m
+
nBr
2
-->sp
|C
6
H
5

tac n
Br2
=5.10
3

=> n
caosu
=

=>

(54n+104m)=1,05
0,27 + 0,52(m:n) = 1,05
=> t l m:n = 3:2
=> t l n:m = 2:3
5) St thay i t Bcc sang Fcc 9100 C. nhit
ny, bn knh nguyn t ca st trong hai cu trc l
1,258 A
0
(Bcc) v 1,292 A
0
(Fcc). Tnh % th tch
thay i.
A. -0.8% B. 0.8%
C.8.0% D. -8.0%
Gii:
C s tnh : 4 nguyn t Fe, hoc 2 c s ca Fe
(Bcc) (n / c s =2 hoc 1 c s ca Fe (Fcc) (n /
c s =4)
i vi Bcc:
V
o
= 2a
3
= 2.[

]
3
= 49,1 A
3

i vi Fcc:
V
1
= a
3
= [

]
3
= 48,7 A
3

AV =

.100% =

.100% = -0,8%
6) Tnh mt phng trn (100), (111), ca Pb (Fcc)Mt
phng = s nguyn t / 1 n v din tch (mm
2
)

A. 8,2.10
10
nguyn t/mm
2
B. 8,2.10
11
nguyn t/mm
2

C.8,2.10
12
nguyn t/mm
2
D. 8,2.10
13
nguyn t/mm
2

Mt phng (Planar density: PD) =



Gii: T ph lc r
Pb
= 1,750 A
o

a
Pb
=

= 4,95 A
o

n
s
(100) =

. 4 + 1 = 2 (nguyn t)
S = a
2

PD(100) =

= 8,2.10
12
(nguyn t/mm
2
)
7) ng (Fcc) c bn knh nguyn t l 1,278 A
o
. Tnh
khi lng ring ca Cu(g/cm
3
)
A. 8,98 B.
8,89
C.9,89 D.
9,98
Gii:
Trong Fcc, r =

a =

= 3,61 A
o

S nguyn t / 1 c s = 4
Khi lng ring =




=



Khi lng nguyn t = nguyn t lng(g/mol) / s
nguyn t trong 1 mol
S nguyn t trong 1 mol = s Avogadro = 6,02.10
23
Khi lng ring d
Cu
= 4 (63,5/(6,02.10
23
) ) /
(3,61.10
-8
)
3
= 8,98 g/cm
3

8) Tnh s nguyn t / c s ca CaF2 (s Ca2+, F-)
Tnh khi lng 1 c s.
A. 4mol v 5,2.10
-22
g B.
4mol v 5,2.10
22
g
C.4 mol v 5,2.10
-25
g D. 4
mol v 5,2.10
25
g
gii:

.8 +

.6 = 4(mol)

= 8
Khi lng 1 c s =

= 5,2.10
-22
g
9) Tnh mt thng ca nguyn t theo phng [110]
ca Cu (Fcc).
A. 3,9.10
10
B.
3,9.10
9

B.3,9.10
8
D.
3,9.10
7
Gii:
Mt thng = s nguyn t / chiu di (cm)
LD =

= 3,9.10
7
nguyn t/cm
10)Khi lng phn t ca thy tinh hu c (poly
metylmetacrylat) l 25000 dvC. S mc xch trong
phn t thy tinh hu c l:
A. 166 B.
250
C.183 D.
257
Gii:
Cng thc ca thy tinh hu c l: CH
3


( CH
2
C )
n
COOCH
3

Khi lng phn t 1 monomer: M = 100
S mc xch: n = 25000:100 = 250
1. Trong cu trc vt liu xp cht, trt t c khuynh
hng nng lng lin kt nh th no?
a. Tng
b. Gim
c. Khng i
d. C th tng hoc gim
2. Loi lin kt no c nng lng lin kt nh nht?
a. Ion
b. Ha tr
c. Kim loi
d. Th cp
3. C nhng kiu sai lch mng tinh th no?
a. im
b. ng
c. Mt
d. C a, b, c u ng.
4. Khi lng ring ca cao su t nhin l
A. 713B. 813C. 913 D. 1013
5. Vit Nam ng th my v sut khu cao su?
A. 2 B. 3 C. 4 D. 5
6. Tn gi ca cht sau y l g:

a. Diaza-18-crown-6
b. Diaza-6-crown-18
c. Dithia-18-crown-6
d. Dithia-6-crown-18
7. C nhng loi vt liu nano no:
a. Khng chiu
b. Mt chiu
c. Hai chiu
d. C a, b, c
8. Tn gi ca polyme sau:


a. Polysiloxan
b. Polyeste
c. Polyuretan
d. Polyvinyl clorua
9. Polyme sau c dng mch hnh g:

a. Hnh sao
b. Hnh thang
c. Hnh cy
d. Hnh rng lc
10. Phn ng no l phn ng trng ngng:
a.

b.

c.

d.
1.Dy polime no sau y khng th trc tip iu
ch bng phn ng trng hp?
A. Cao su buna,cao su isoprene,cao su cloropren,cao
su buna S
B. PE,PVC,thy tinh hu c,polystiren,t capron
C.Nilon 6,6,t axetat,t tm,tinh bt,polyvinyl
ancol
D. PVA,t capron,cao su buna N, polypropilen
Gii thch:
Nilon 6,6 c tng hp t phn ng trng ngng
t adipic acid v 1,6 Hexanediamine
T axetat ,t tm c tng hp t mt s polime
thin nhin
Polyvinyl ancol c tng hp t qu trnh thy phn
polyvinyl acetat
2. Cao su t nhin l polime ca isoprene cn cao su
nhn to(cao su buna) l polime ca buta-1,3-
dien.Chn pht biu ng:
(1) Cao su thin nhin c tnh n hi hn cao su
Buna
(2) Cao su thin nhin c cu tc ng u hn cao su
Buna
(3) C th ci tin tnh cht c hc ca cao su Buna
A. (1) B. (1),(2) C. (2)
D. (1),(2),(3)
3.Trng hp hon ton vinyclorua ta thu c PVC c
khi lng phn t l 7,525.10
22
. S mc xch CH
2

CH Cl trong PVC l bao nhiu:
A. 12,04 x 10
20
B. 12,04 x
10
21

C. 12,04 x 10
22
D.12,04 x
10
23

Gii thch:
Gi n l s mc xch ca CH
2
CH Cl trong PVC
ta c cng thc vinylclorua:
H
2
C = CH Cl vi phn t lng M = 62,5 vC
Cng thc PVC : (-CH
2
-CHCl-)
n
vi khi lng phn
t 7,525.10
22

Suy ra n =

= 12,04 . 10
20

4.Poly etylen c trng hp t etylen.Hi 280g
polyetylen trng hp c bao nhiu phn t etylen:
A. 5. 6,02.10
23
B. 10.6,02.10
23


C. 15.6,02.10
23
D. 12.6,02.10
23

Gii thch:
Ta c s mol polyetylen = 280/28 = 10 mol
Suy ra s phn t etylen c trng hp =
10.6,02.10
23

5.Clo ha PVC c mt loi t clorin 63,96%
Clo.Trung bnh mt phn t Cl
2
tc dng c vi:
A. 2 mc xch PVC B. 3 mc
xch PVC
C. 4 mc xch PVC D. 5 mc
xch PVC
Gii thch:
Gi n l s mc xch Clorua chim 63,96%
S mc xch phn t Cl
2
tc dng c =

=> n = 6
Vy c 1 phn t Clo tc dng c 3 mc xch PVC
6. C 5,688g cao su buna S phn ng va ht vi
3,462g Br
2
.Hi t l mc xch butadien v styren
trong cao su buna S l bao nhiu:
A. 1/3 B. C. 2/3
D. 3/2
Gii thch:
Gi a l mol ca cao su buna S v c cng thc [ (-
CH
2
CH=CH CH
2
- )
n
] hay C
4
H
6
vi M = 54
V b l mol ca styrene c cng thc CH
2
=CH
C
6
H
5
hay C
8
H
8
vi M = 104
Ta c:
54a + 104b = 5,688
M n
C4H6
= n
Br2
= 3,462/160 = 0,02 = a
Vy n
C8H8
= 0,04 = b
Suy ra t l mc xch butadien v styren trong cao su
buna S l:
a/b = 0,02/0,04 =1/2
7. Khi trng ngng 8.5 g acid aminoacetic vi hiu
sut 80%,ngoi aminoacid d ta cn thu c m g
polime v 1,44g nc.Ga tr m l:
A. 7,296 B. 6,405 C. 5,360
D.9,121
Gii thch:
Ta c
8,5 g acid aminoacetic -> m g
polime + 1,44g nc
Vi hiu sut l 80% => 8,5* 80% = m + 1,44
m = 5,360g
8. Chn phng n ng: Thuc tnh khc bitc bn
ca ng nano l
A. Nu nguyn t Carbon c cun trn v pha
mp ng nano mang tnh cht kim loi cn khi cun
lch khng ng tm ng nano mang tnh cht bn
dn.
B.Nu nguyn t Carbon c cun trn v pha mp
ng nano mang tnh cht bn dn cn khi cun lch
khng ng tm ng nano mang tnh cht kim loi.
C. ng nano c nhiu thuc tnh c bn khc nhau ty
thuc vo cch thc chng c cun trn nh th
no.
D. A v C ng
(Eric Stach, gio s v vt cht ca Trng i hc
Purdue, gii thch v nano)
9.S dch b hp th trong cc vt liu nano do:
A.Do hiu ng kch thc
B.Do in t b giam cm trong khng gian hn ch
C. Thay i v ph nng lng v mt trng thi
D. Tt c u ng
10.Chn cu ng: chc nng ca cc pha trong cu
trc vt liu composite
A. Pha lin tc gi l vt liu nn (matrix), thng
lm nhim v lin kt cc pha gin on li.
B.Pha gin on c gi l ct hay vt liu tng
cng (reinforcement) c trn vo pha nn lm
tng c tnh, tnh kt dnh, chng mn, chng xc...
C.Pha lin tc,pha gin on u trn vo pha nn
tng c tnh, tnh kt dnh, chng mn, chng xc...
D. Av B ng
1/ Trng ngng hexametyleniamin 1,16 tn H
2
N-
(CH
2
)
6
-NH
2
v 1,6 tn axit aipic HOOC-(CH
2
)
4
-
COOH thu c bao nhiu kg t nilon bit hiu sut
phn ng l 85%. Cc phng n la chn.
A. 2352 kg
B. 2074 kg
C. 2108 kg
D. 1921 kg
H
2
N-(CH
2
)
6
-NH
2
+ HOOC-(CH
2
)
4
-COOH H
2
N-
(CH
2
)
6
-NH-OC-(CH
2
)
4
-COOH +H
2
O
n
H2N-(CH2)6-NH2
= 1,16*1000/116 = 10 (mol)
n
HOOC-(CH2)4-COOH
= 1,6*1000/146 = 10,95 (mol)
so snh s mol gia H
2
N-(CH
2
)
6
-NH
2
v HOOC-
(CH
2
)
4
-COOH
ta thy s mol H
2
N-(CH
2
)
6
-NH
2
t hn m t l s mol
phn ng l 1:1 nn H
2
N-(CH
2
)
6
-NH
2
phn ng ht.
M %H= 85%.
=>m H
2
N-(CH
2
)
6
-NH-OC-(CH
2
)
4
-COOH=
10*244*85/100 = 2074kg
2/ Tm ch s Miller ca mt mng bit n ct trc x
ti 1/4, y ti 2, z ti 1.
A. 812
B. 411
C. 811
D. 412
Ct cc trc x, y, z ti 1/4, 2, 1
Nghch o ( 4, 1/2, 1)
Quy ng kh mu (8,1,2)

3/ chn lc ca vng phi t 18 vi ion kim loi
trung tm no cao nht

A. Na
+

B. K
+

C. NH
4
+

D.
Ca
2+



4/ Clo ho cao su isopren (C5H8)n thu c mt t
clorin cha 20,821% clo v khi lng, trung bnh 1
phn t clo phn ng k mt xch trong mch isoporen.
Gi tr ca k l
A. 1
B. 2
C. 3
D. 4

Gi x l s mt xch b 1 phn t clo cng vo:

(C
5
H
8
)x+Cl
2
>(C
5
H
8
)xCl + HCl
--->35,5/(68x+35,5-1) =0,20821
---> x = 2
Vy trung bnh 1 phn t clo phn ng 2 mt xch


5/ Mch polymer PVC c 300 mt xch th khi lng
mol p.t l bao nhiu ?

A. 12500
B. 18750
C. 18500
D. 12750

62,5*300 = 18750 dvC

6/ S phi tr ca NaCl:
A. 2
B. 4
C. 6
D. 8
7/ S phi tr cng ln th
A. Mng tinh th cng dy c
B. Mng tinh th cng t
C. Mng tinh th d b ph v
D. C 3 p n trn u sai
8/Trong s cc loi t sau:
(1) [-NH-(CH
2
)
6
-NH-OC-(CH
2
)
4
-CO-]
n

(2) [-NH-(CH
2
)
5
-CO-]
n

(3) [C
6
H
7
O
2
(OOC-CH
3
)
3
]
n
.
T nilon-6,6 l
A. (1). B. (1), (2), (3).
C. (3). D. (2).
9/ Polivinyl clorua (PVC) c iu ch t kh thin
nhin theo s cc qu trnh chuyn ha v hiu
sut nh sau:
Metan Axetilen Vinyl clorua
PVC
hiu sut 15% 95%
90%
Cn bao nhiu m
3
kh metan(o ktc ) iu ch
c mt tn PVC.
A. 23168 m
3
B. 22983 m
3

C. 22620 m
3

D. 22800 m
3

nPVC=
1000 1000
16000
62, 5

=
(kmol)
nPVC = 2 nCH
4
nCH
4
= 8000 (kmol)
V
CH4
=
8000 90 95 15 22, 4
22983, 4
100 100 100

=

(m
3)
10/ Trng hp 11,2 lt C
2
H
4
( ktc ).Hiu sut phn
ng l 90% th khi lng polyme thu c l:
A. 12,6gam
B. 10,3gam
C. 14,3gam
D. 8,3gam
nC
2
H
4
= 11,2/22,4 = 0,5 (mol)
m
polymer
= 0,5*0,9*28 = 12,6g
1. Trng hp 1 mol etilen iu kin
thch hp th thu c bao nhiu gam polime
A. 14g B. 28g C. 56g D.
21g
2. Cao su lu ha c tnh cht hn hn
cao su th v?
A. C khi lng phn t ln hn.
B. C cu to mch thng xon li.
C. C cu to mng khng gian.
D. C cu to dng trn v trt t.
3. Trong cng iu kin th tch th cu
trc vt liu no c khi lng nng nht:
A. Thp B. Nhm C. Titan
D. Carbon
4. Khi t vt liu ion vo 1 in trng
th cc ion s di chuyn nh th no ( nhit
thng) :
A. Cng chiu
B. Ngc chiu
C. C A,B u ng
D. C A,B u sai
5. Ch ra u khng phi l polime :
A. Amiloz B. Xenluloz C. Thy tinh hu
c D. Lipit
6. Cu trc tinh th ca cc kim loi kim th l:
A. Lp phng n gin
B. Lp phng tm khi
C. Lp phng tm din
D. Lp phng tm dy
7. ac iem cau tao cua monome tham gia
phan ng trung hp la
A. Co lien ket kep.
B. Co s lien hp gia cac lien ket kep
C. Co t hai nhom chc tr len
D. Co hai nhom chc au mach phan ng
vi nhau
8. Trong cac nhan xet di ay, nhan xet
nao sai :
A. Mot so chat deo la polime nguyen chat.

B. a so chat deo, ngoai thanh phan c
ban la polime con co cac thanh phan khac.
C. Mot so vat lieu compozit ch la polime
D. Vat lieu compozit cha polime va cac
thanh phan khac.
9. Khi phn tch cao su thin nhin ta c monome
no sau y:
A. Isopren B. Butadien-1,3 C.
Butilen D. Propilen
10. : Cht khng c kh nng tham gia phn ng trng
hp l :
A. isopren. B. toluen. C.
propen. D. stiren
1, khung thp c khi lng 8kg, khi lng ring
ca thp l 7,8g/cm
3
c th tch khung:
A,1025.5 cm
3
B,1025.6 cm
3
C,1025.7cm
3

D,1025.8 cm
3
2, th xp grapheme c th pht hin NH
3
v NO
2

nhy:
A,20ppm B,25ppm C,30ppm D,35ppm
3, fullerenls tan t trong dung mi no?
A,benzene B,toluene C,nc D hexan
4,tnh h s polime ha n ca polymer
polyvinylclorua c phn t khi l 35000:
A 560 B,650 C,570 D,750
5,mt loi cao su lu ha cha 3% lu hunh. Hi c
bao nhiu mc xch isoprene c 1 cu ni disunfua -S-
S-, gi thit rng S thay th cho H nhm metylen
trong mch cao su:
A,12 B,13 C,14 D,15
6, trong phn ng trng hp gc t do th qu trnh
styrene polymerization s lp li my ln cho n khi
tt c cc nhm monomer c tiu th tri qua
mt phn ng chm dt?
A.mt ln B.hai ln C.ba ln D. nhiu
ln
7,chn cng thc ng:
A,E=(-e
2
)/4
2

B,E=(-e
2
)/4 C,E=(e
2
)/4
D,E=(e
2
)/4 r
2
8,c bao nhiu cp phn t:
A,5 B,4 C,3 D,2
9,ta m c c 21 ht trn 1 inch vung trn mt
hnh chp phng i 200, hi s kch thc ht
no theo ASTM?
A,7.38 B,7.39 C,7.40 D,7.41
10,vai tr ca lin kt H
2
:
A,thc y to ra hnh dng ph hp cho phn
ng ng vng din ra
B,bn ha sn phm sau cng bng vic ti a ha lc
y gia cc cp e
C,thc y phn ng th i nhn trn phn t
D, lm cng nhng phn t mch di
Bi gii:
cu 1:
th tich khung =8000/7.8=1025.6 cm
3

cu 4:
n=35000/62.5=560
cu 5:
gi x l s mc xch isoprene:
32/(68*x-2+64)=0.03
Suy ra x=15
cu 9:
N=(200/100)
2
*21= 2
n-1

Log84 =(n-1)*log2
1.924=(n-1)*0.301
Suy ra:n=7.39
Cu 1. Danh php ca Cryptands bt buc:
A. Gia phn t Nit v Oxy phi c 2 phn t
CH
2

B. Gia phn t Nit v Oxy phi c 3 phn t CH
2

C. Cu A v B u ng
D. C A v B u sai
Cu 2. Nhng thnh phn thuc cu to phi cao su l
g ?
A. m , cht chit rt acetone
B. m , cht chic rt acetone, tro
C. m , cht chit rt acetone, tro, protein
D. B v C u sai
Cu 3. Thnh phn c trong cu to ca phi cao su c
th lm tng s pht trin ca vi khun lm nh hng
n tnh cht hydrocarbon cao su nu hm lng qu
cao:
A. m
B. Tro
C. Protein
D. Cht chic rt protein
Cu 4. Hy chn nhng cu ng v tinh khit ha
hydrocarbon cao su
(A). Cao su sng cha 95%- 98% hydrocarbon cao su
(B). cao su kh, cht ha tan tt hydrocarbon l:
benzen, tetrachloro carbon, cc loi xng, chloroform
(C). Theo phng php Harries, tinh khit ha cao su
ngi ta thng dng nht l benzen
(D). Phng php Harries thc hin nh sau:

Cao su kh( ct thnh mnh nh)
dung dch

cao su kt ta v tip tc chic rt acetone.
(E). latex, cht bn ( protein) bm vo cao su c
tm thy b mt cc tiu cu.
(F). Phng php m c ha c s dng latex
l phng php ly tm hay kem ha.
(G). Cho vo latex cht hot ng b mt nh mui
kim ca axit bo di dng dung dch nc thi
protein ri khi b mt cc tiu cu cao su v thc
hin nhit cao.
A. (B), (D), (E), (F)
B. (A), (D), (E), (G)
C. (B), (C), (E), (G)
D. (A), (D), (F), (G)
Gii thch: Cu (A) sai v cao su sng cha 92%- 95%
hydrocarbon cao su. Cu (C) sai v theo phng php
Harries, tinh khit ha cao su ngi ta thng dng
nht l acetone. Cu (G) sai v thi protein ri khi b
mt cc tiu cu cao su v thc hin nhit
thng.
Cu 5. Ni A v B cho thch hp:

A B
1. Latex cao su dng
dung dich:

2. Latex dng dch
gi:

3. Latex dng nh
tng:


a.Cc protein, phytosterol,
cht mu, tannin, enzyme.
b.Cc amidon, lipid, tinh
du, nha, sp,
polyterpenic.
c.Nc, cc mui khong,
axit, cc mui hu c,
gluxit, hp cht phenolic,
alcaloic trng thi t do
hay trng thu dung dch
mui.

A. 1-b, 2-c, 3-a
B. 1-c, 2-a, 3-b
C. 1-c, 2-b, 3-a
D. 1-a, 2-c, 3-b
Cu 6. Trong quy trnh ch bin tng qut sn phm
c bn l cao su, nc ta khng c gai on no sau
y:
A. Giai on ha do cao su
B. Giai on nh hnh hn hp v nh hnh s b
C. Giai on kh gel ha
D. Giai on lu ha
Gii thch: v nc ta c kh hu nhit i, m giai
on kh gel ha ch p dng cho cc nc c kh hu
lnh.
Ngm vo
benzen
trong 1 thi
gian
rt tng git
Vo cn
Cu 7. im khc bit ca my nhi loi kn so vi
my loi h trong giai on ha do cao su bng
phng php ha do c hc l:
A. My nhi loi kn nhit do xy ra trn 110oC, ph
bin hin nay l 150-180oC
B. Vn tc 2 trc t 20-60 vng\pht, cng sut ng c
in 200CV-1500CV
C. My nhi loi kn th c 2 trc nhn
D. C A v B
E. C A, B v C
Gii thch: Cu C sai v my nhi loi kn th c 2 trc
c ng k xon nm trong 1 bung kn.
Cu 8. Trong quy trnh ch bin tng qut sn phm
c bn l cao su, giai on quan trng sn phm
t cc tnh cht c l ha tnh quy nh l :
A. Nhi trn
B. nh hnh
C. Lu ha
D. Gii nhit
Cu 9. Trong cc phng php chnh sau: php o
nht, php o thm thu, php siu ly tm v khuch
tn nh sng, phng php no thng dng nht
o phn t khi cao su ?
A. Php o thm thu, php siu ly tm
B. Php o thm thu, o nht
C. Khuch tn nh sng, o nht
D. Khuch tn nh sng, php siu ly tm
Cu 10. y l ng phn trans ca polyisopren, hy
cho bit v tr ni i no th hin ng phn trans ?
1 2 3
4

A. Ni i s 1 B.Ni i s 2
C.Ni i s 3 D.Ni i s 4
Gii thch: Ni i s 3 th hin ng phn trans v
v tr ny 2 nhm th hai pha khc nhau ca lin kt
i.
Cu 1. Loi lin kt no sau y khng nh hng?
a. Lin kt ion, lin kt ha tr
b. Lin kt ion, lin kt kim loi
c. Lin kt kim loi, lin kt th cp
d. Lin kt ha tr, lin kt th cp
Gii thch: Chn b
Lin kt ion: Khng nh hng (ceramic)
Lin Kt ha tr: nh hng (bn dn, ceramic,
chi polymer)
Lin kt kim loi: Khng nh hng (kim loi)
Lin kt th cp: nh hng (tng tc mch, tng
tc phn t)
Cu 2. Tnh mt nguyn t khi lp phng tm
th (APF) hnh nh sau:

a. APF = 0.21 b. APF = 0.39 c. APF = 0.68 d.
APF = 0.86
Gii thch: Chn c
V mi cnh khi lp phng ABCDEFGH c di
bng a nn :



Cu 3. D on cu trc tinh th ca hp cht CaO,
bit rng bn knh ion (nm) ca
cation Ca2+ bng 0.1 nm, ca anion O2- bng 0.140
nm?
a. S phi tr = 3; cu trc NaCl
b. S phi tr = 4; cu trc ZnS
c. S phi tr = 6; cu trc NaCl
d. S phi tr = 8; cu trc CsCl
Gii thch: Chn c

nm trong khong
0.414 0.732 nn c s phi tr = 6 v c cu trc
NaCl.
Cu 4. Vit phng trnh phn ng tng hp Tetrathio
Macrocyle?
Tr li :


Cu 5. Vit phng trnh tng hp Calixarenes?
Tar li:

Cu 6. Khi nim no sau y v polymer chnh xc
nht?
a. Polymer l nhng hp cht c phn t khi trung
bnh do nhiu n v nh (gi l
mt xch) lin kt vi nhau.
b. Polymer l nhng hp cht c phn t khi rt ln
do nhiu n v trung bnh (gi
l mt xch) lin kt vi nhau.
c. Polymer l nhng hp cht c phn t khi rt ln
do nhiu n v nh (gi
l mt xch) lin kt vi nhau. d. Polymer l nhng
hp cht c phn t khi rt ln do nhiu n v ln
(gi l mt
xch) lin kt vi nhau.
Gii thch: Chn c
Polime l nhng hp cht c phn t khi rt ln do
nhiu n v nh (gi l mt
xch) lin kt vi nhau.V d:
do cc mt xch NH [CH2]6 CO lin kt vi
nhau
to nn. H s n c gi l h s polime ha hay
polime ha. Cc phn t to nn
tng mt xch ca polime c gi l monomer.
Cu 7. Vit phng trnh tng hp PVC (poli vinyl
clorua)?
Tr li:

Cu 8. Phn ng trng hp l g? iu kin ca phn
ng trng hp?
Tr li:
- Trng hp l qu trnh kt hp nhiu phn t nh
(monome), ging nhau hay tng t
nhau thnh phn t rt ln (polime)
- iu kin cn v cu to ca monome tham gia phn
ng trng hp phi c l:
+ Lin kt bi. V d: CH2 = CH2, CH2 = CHC6H5
+ Hoc vng km bn: V d:
Cu 9. Phn ng trng ngng l g? iu kin ca
phn ng trng ngng?
Tr li:
- Trng ngng l qu trnh kt hp nhiu phn t nh
(monome) thnh phn t ln
(polime) ng thi gii phng nhng phn t nh
khc (nh H2O)
- iu kin cn c phn ng trng ngng l: cc
monome tham gia phn ng trng
ngng phi c t nht hai nhm chc c kh nng
phn ng to c lin kt vi nhau
Cu 10. Cao su lu ha c 2% lu hunh v khi
lng. khong bao nhiu mt xch
isoprene c mt cu isunfua S-S- ?
a. 43 b. 44 c. 45 d. 46
Gii thch: Chn d
(C5H8)x (C5H8)x 2H + 2S
Suy ra, x = 46
Cu 1.nhnghacngnghnano?
Cng ngh nano l cng ngh x l vt cht mc
nanomet (nv c gim i 1 t ln(10-9). Cng
ngh nano tm cch ly phn t n nguyn t nh
lp rp ra nhng vt to kch c bnh thng s
dng, y l cch lm t nh n to khc vi cch lm
thng thng t trn xung di, t to n nh.
Cu 2.Ti sao vt liu nano li c cc tnh cht th
v?
Tnh cht th v ca vt liu nano bt ngun t kch
thc ca chng rt nh b c th so snh vi cc
kch thc ti hn ca nhiu tnh cht ha l ca vt
liu. Ch l vn kch thc thi th khng c g
ng ni, iu ng ni l kch thc ca vt liu
nano nh c th so snh vi cc kch thc ti
hn ca mt s tnh cht. Vt liu nano nm gia tnh
cht lng t ca nguyn t v tnh cht khi ca vt
liu. i vi vt liu khi, di ti hn ca cc tnh
cht rt nh so vi ln ca vt liu, nhng i vi
vt liu nano th iu khng ng nn cc tnh cht
khc l bt u t nguyn nhn ny.
Cu 3.Ccphngphpchtovtliunano?
Cc vt liu nano c th thu c bng bn phng
php ph bin, mi phng php u c nhng im
mnh v im yu, mt s phng php ch c th
c p dng vi mt s vt liu nht nh m thi.
- Phng php ha t (wet chemical)
- Phng php c hc (mechanical)
- Phng php bc bay
- Phng php hnh thnh t pha kh (gas-phase)

Cu 4.Thnol phngphphat (wet
chemical)?
Bao gm cc phng php ch to vt liu dng trong
ha keo (colloidal chemistry), phng php thy
nhit, sol-gel, v kt ta. Theo phng php ny, cc
dung dch cha ion khc nhau c trn vi nhau
theo mt t phn thch hp, di tc ng ca nhit
, p sut m cc vt liu nano c kt ta t dung
dch. Sau cc qu trnh lc, sy kh, ta thu c cc
vt liu nano.

u im ca phng php ha t l cc vt liu c
th ch to c rt a dng, chng c th l vt liu
v c, hu c, kim loi. c im ca phng php
ny l r tin v c th ch to c mt khi lng
ln vt liu. Nhng n cng c nhc im l cc hp
cht c lin kt vi phn t nc c th l mt kh
khn, phng php sol-gel th khng c hiu sut cao.

Cu 5.Thnol phngphpchc (mechanical).?
Bao gm cc phng php tn, nghin, hp kim c
hc. Theo phng php ny, vt liu dng bt c
nghin n kch thc nh hn. Ngy nay, cc my
nghin thng dng l my nghin kiu hnh tinh hay
my nghin quay. Phng php c hc c u im l
n gin, dng c ch to khng t tin v c th ch
to vi mt lng ln vt liu. Tuy nhin n li c
nhc im l cc ht b kt t vi nhau, phn b kch
thc ht khng ng nht, d b nhim bn t cc
dng c ch to v thng kh c th t c ht c
kch thc nh. Phng php ny thng c dng
to vt liu khng phi l hu c nh l kim loi.

Cu 6.Thnol phngphpbcchy.?
Gm cc phng php quang khc (lithography), bc
bay trong chn khng (vacuum deposition) vt l, ha
hc. Cc phng php ny p dng hiu qu ch
to mng mng hoc lp bao ph b mt tuy vy
ngi ta cng c th dng n ch to ht nano
bng cch co vt liu t . Tuy nhin phng php
ny khng hiu qu lm c th ch to quy m
thng mi.\

Cu 7.Thnol phngphphnhthnhtphakh
(gas-phase).?
Gm cc phng php nhit phn (flame pyrolysis),
n in (electro-explosion), t laser (laser ablation),
bc bay nhit cao, plasma. Nguyn tc ca cc
phng php ny l hnh thnh vt liu nano t pha
kh. Nhit phn l phng php c t rt lu, c
dng to cc vt liu n gin nh carbon, silicon.
Phng php t laser th c th to c nhiu loi
vt liu nhng li ch gii hn trong phng th nghim
v hiu sut ca chng thp. Phng php plasma mt
chiu v xoay chiu c th dng to rt nhiu vt
liu khc nhau nhng li khng thch hp to vt
liu hu c v nhit ca n c th n 9000 C.

Phng php hnh thnh t pha kh dng ch yu
to lng carbon (fullerene) hoc ng carbon, rt nhiu
cc cng ty dng phng php ny ch to mang
tnh thng mi.

Cu 8.Ccdngvtliunano?
Y dc l th trng ln nht tiu th vt liu nano,
cc ng dng ht nano dn truyn thuc (drug
delivery) n mt v tr no trn c th l mt
trong nhng v d v ng dng ca ht nano. Trong
ng dng ny, thuc c lin kt vi ht nano c
tnh cht t, bng cch iu khin t trng ht
nano c nh mt v tr trong mt thi gian di
thuc c th khuych tn vo cc c quan mong
mun.
- Y dc: Ht nano.
- Ha cht v vt liu cao cp: ng nano.
- Cng ngh thng tin, vin thng : Vt liu xp nano
.
- Nng lng: ng nano.
- T ng ha: Chm lng t.
- Hng khng v tr: Vt liu cu trc nano.
- Dt: Si nano.
- Nng nghip: Ht cha ht nano (capsule).
Cu 9. Sicarbon l g?
Si cacbon l vt liu c bn rt cao, l loi si
cha t nht 90% nguyn t cacbon c kim sot
cht ch trong qu trnh nhit phn si nguyn liu
ban u. Cn si graphite l si c trn 99% nguyn
t cacbon. C nhiu loi si khc nhau dng lm
nguyn liu sn xut si cacbon nh si
polyacrylonitrile (PAN), si xenlulo (viscose rayon,
cotton), du m, than hoc mt s loi si
phenolic.
Hin nay, si cacbon c ng dng rng ri trong
hng khng, gii tr, cng nghip v giao thng,
composite. Composite si cacbon l ti u v bn,
cng, nh v khng nt, nhit cao, tr ha cht,
gim xc.

Cu 10. Nu s b v chch sn xut si carbon?
Si cacbon c sn xut bng cch nhit phn c
kim sot cc si hu c chn trn nhm loi oxy,
nit, hydro to thnh si cacbon. C tnh si
cacbon cng cao khi tng cu trc tinh th v mc
nh hng si, cng nh gim cc khuyt tt trn
si. Cch tt nht c c si cacbon nh hng
cao l chn si nguyn liu nh hng cao, sau
duy tr mc nh hng ny trong qu trnh n
nh v cacbon ha.
Cu 1 Cu no di y l sai:
A. Lin kt ion c nng lng lin kt nh v c c
im khng nh hng
B. Lin kt th cp c nng lng lin kt nh nht v
c c im l tng tc mch
C. Lin kt ion c nng lng lin kt ln v c c
im khng nh hng
D. c im ca lin kt th cp l tng tc phn t
Chn cu A
V nng lng lin kt ca lin kt ion ln. Bng sile
27/75 chng 1
Cu 2,Pht biu no di y sai?
A. Vt liu nano c ch to bng 2 phng php l
bottom-up v top-down
B. Phng php top-down ngi ta thng dng cc
phng php nh sol gel,hon nguyn bc bay,phn
x...
C. Phng php top-down l phng php o gt t
khi phn t ln n cu trc nano
D. Cu A v C ng
Chn cu B v phng php bottom-up mi c cc
phng php

Cu 3.tn gi ng ca hai cht sau l:

A. 1,8 diamino-3,6-ioxaoctane v 1,8 diclo-1,8dioxa-
3,6dioxaoctan
B. 1,8 diamino-3,6-ioxaoctane v 2,6 diclo-1,8dioxa
C. 1,8 diamino-1,8-ioxaoctane v 1,8 diclo-1,8dioxa
D. 1,9 diamino-3,6-ioxaoctane v 1,8 diclo-1,8dioxa
Chn cu A y l bi tp trang slide 14 chng 2
thy tng cho lm.
Cu 4, Tng hp c poli vinyl ancol ngi ta s
dng phng php no sau y
A. Phn ng trng ngng
B. Phn ng thy phn
C. Phn ng to cu ni gia cc chui polime nhm to
mch di
D. Phn ng thy phn nhm chc este ngoi mch
polime
Chn cu D

Cu 5 nilion 66 c tng hp t nhng cht no?
A. Acid acetic v 1,6- Dihexane diamine
B. Acid acetic v 1,6- Hexane diamine
C. Acid Adipic v 1,6- Dihexane diamine
D. Acid Adipic v 1,6- Hexane diamine
Chn cu D



Cu 6 c c poli vinyl ancol ngi ta tng hp
t cht no
A. Vinyl clorua
B. Vinyl acetat
C. Vinyl ancol
D. Vinyl sunfua
Chn cu B



Cu 7.Tn gi cht sau y l:
A. 18-crown-6
B. Diaza-18-crown-6
C. Disunfua-18-crown-6
D. Dithia-18-crown-6
Chn cu D trong slide 34 chng 2 gio trnh ca
thy

Cu 8. Cu pht biu no v tng quan nng lng
lin kt v c tnh vt liu di y l sai?
A. Vt liu ceramic c lin kt nng lng ln v nhit
nng chy ln.
B. Vt liu kim loi c nng lng ni bin i v nhit
nng chy trung bnh.
C. Vt liu ceramic c lin kt nng lng nh v nhit
nng chy ln,
D. Vt liu kim loi c nng lng ni bin i v modul
ko trung bnh
Chn cu C
Bi hc slide 26 chng 1

Cu 9, tm pht biu ng
A. S phi tr l s lng nguyn t cch u gn nht
mt nguyn t cho,s phi tr cng ln mng tinh
th cng rng.
B. S phi tr l s lng nguyn t cch u gn nht
mt nguyn t cho,s phi tr cng ln mng tinh
th cng dy c.
C. Tinh th bn khi tt c cc anion xung quanh cch xa
cation trung tm
D. C ba cu trn u ng.
Chn cu B
p n slide 61 chng 1

Cu 10. Pht biu no di y l ng?
A. c im ca lin kt ion l nh hng
B. c im ca lin kt th cp l lin khng nh
hng v c nng lng lin kt nh nht
C. c im ca lin kt th cp l lin nh hng v
c nng lng lin kt ln nht
D. c im ca lin kt kim loi l khng nh hng.
Chn cu D
p n c trong slide 23 chng 1

CU 1. Hy ghi ch (), S (sai) vo cc [ ]
mi cu sau:
a. Polime l hp cht c phn t khi ln [ ]
b. Nhng phn t nh c th tham gia phn ng
to polime gi l monomer [ ]
c. H s n mc xch trong cng thc polime gi l
h s trng hp. [ ]
d. Polime c th c cu to mch khng nhnh, c
nhnh hoc mng li. [ ]
e. Polime c nhiu ng dng lm cc vt liu
khc nhau cn c vo tnh cht vt l ca n nh tnh
do, tnh n hi, tnh bm dnh, tnh ko si dai
bn [ ]
p n: 1. a. ; b. ; c.S; d. ; e.
CU2.Phn t trung bnh ca poli(hexametylen
adipamit) ch t nilon -6,6 l 30 000 vC, ca
cao su t nhin l 105 000 vC. Hy tnh s mt
xch (tr s n) gn trong cng thc phn t ca
mi loi polime trn.
Gii
S mc xch ca poli(hexametylenadipamit) l :
30000
133
226
n = ~ (mc xch)
S mt xch ca cao su t nhin l
105000
1544
68
n = = (mt xch)
CU 3. Trnh by cch phn bit cc mu vt liu
sau:
a. PVC (lm vi gi da) v da tht
b. T tm v t axetat
Gii
a.t hai mu t gi v t tht sau p ln b
mt ngn la mt phu lc c tm dung dch AgNO
3
.
Nu mu th no c kt ta trng th l PVC ( lm
da gi)
PVC + O
2
HCl +..
HCl + AgNO
3
AgCl + HNO
3

Mu th c mi kht nh tc chy, l da tht
b. T tm khi chy c mi kht nh tc chy, cn
t axetat th khng.
CU 4.
a. Vit cc phng trnh ha hc ca cc phn
ng iu ch cc cht theo s sau:
- Stiren polistiren
- Axit - aminoentantic (H
2
N-
[CH
2
]
6
COOH polienantamit (nilon-7)
b. iu ch 1 tn mi loi polime trn cn
bao nhiu tn polime mi loi, bit rng hiu sut
ca hai phn ng trn l 90%
A.1026 B.1386 C.1260 D.1368
Gii
a..T Stiren polistiren
0
,
6 5 2 6 5 2
( ( ) )
t xt
n
nC H CH CH CH C H CH =
T Axit - aminoentantic (H
2
N-[CH
2
]
6
COOH
polienantamit (nilon-7)
0
,
2 2 6 2 6 n
[ ] OOH ( [ ] O-)
t xt
nH N CH C HN CH C


0
,
6 5 2 6 5 2
( ( ) )
t xt
n
nC H CH CH CH C H CH =
104n 104n
1 tn 1 tn
Khi lng stiren cn dng l m = 1 tn
V H=90% nn
1.90
0, 9
100
m= = (tn)= 900 (kg)
0
,
2 2 6 2 6 n
[ ] OOH ( [ ] O-)
t xt
nH N CH C HN CH C

145n 127n
m=? 1 tn
Khi lng ca axit - aminoentantic cn dng l
1.145
1,14
127
n
m
n
= = (tn)
V H= 90% nn
1,14.90
1, 026
100
m = = (tn ) = 1026
(kg)
Chn cu A
CU 5.Cao su lu ha c 2% lu hunh. Hy tnh
xem c bao nhiu mt xch isoprene c mt cu i
sunfua S-S-, gii thit rng S thay th cho H
cu metylen trong mch cao su.
A.38 B.40 C.46 D.50
Gii
Mi cu i sunfua (-S-S-) c khi lng 64 vC ;
Mi monome isopren (C
5
H
8
) c khi lng l 68. Mi
cu i sunfua (-S-S-) thay 2H, nn tng khi lng
on mch polime cha mt cu i sunfua l :
62 + 68n, trong thnh phn S l 2%, ta c biu
thc :
64 2
62 68 100 n
=
+
n =
6400 124
68 2

= 46
C khong 46 mt xch isopren cha 1 cu i
sunfua.
Chn cu C
CU 6: ng trng hp etilen v isopren thu c
polime X. t 39g X cn 90,72 lt O2 (dktc). T l
s mt xch etilen : isopren l:
A. 1:2 B. 2:3 C. 1:3 D. 3:2
Gii
T l s mt xch etilen : isopren = k --> X =
(C
2
H
4
)
k
C
5
H
8

C
2k+5
H
4k+8
+ (3k + 7)O
2
--> (2k + 5)CO
2
+ (2k +
4)H
2
O
(28k + 68) (3k + 7)
39 4.05
--> k = 2/3
--> Chn B
CU7: Polime X l sn phm ng trng hp ca
stiren v 1 anken Y. Phn t khi ca X l
198000dvC c t l s mt xch ca stiren : Y l 3:2.
Mt khc t 39,6g X cn 87,36 lt O2 (dktc). Tng
s phn t stiren v Y to nn 1 phn t X l:
A.3600 B.4500 C.2500 D.2400
X = [(C
8
H
8
)
3
(C
n
H
2n
)
2
]
a


C
2n+24
H
4n+24
+ (3n+30)O
2
---> (2n + 24)CO
2
+ (2n +
12)H
2
O
(28n + 312) (3n + 30)
39.6 3.9
--> n = 3 --> X = [(C
8
H
8
)
3
(C
3
H
6
)
2
]
a

M
X
= (104*3 + 42*2)a = 198000 --> a = 500
--> Tng s phn t stiren v Y to nn 1 phn t X =
(3 + 2)*500 = 2500
Vy chn cu C
CU 8 : t chy hon ton 1 lng cao su buna-
N vi lng khng kh va , thy to 1 hn hp
kh nhit trn 127
o
C m CO
2
chim 14,1% v
th tch.T l s mt xch butaien v vinyl xyanua
trong polime ny l? (bit khng kh chim 20%
O
2
v 80% N
2
v th tch)
A. 3:4 B. 1:2 C. 2:3 D. 2:1
Gii
Cng thc cao su buna N: x C
4
H
6
+ y C
3
H
3
N -->
C
(4x+3y)
H
3(2x+y)
N
y
,
C
(4x+3y)
H
3(2x+y)
N
y
+ (5,5x +3,75y ) O
2
---> (4x +
3y) CO2 + 1,5(2x+y) H2O + 0,5y N
2
.
Th tch hh kh sau khi chy 127
o
C = mol CO
2
+
mol H2O + mol N
2
+ mol N2/kk = 4x + 3y + 3x+1,5y
+ 0,5y + 22x + 15y = 29x + 20y
==> mol CO2 = 4x + 3y = 0,141*(29x + 20y) ===> x
= 2y ===> cu D
CU 9. Clo ha PVC thu c mt loi t clorin
c 66,18% clo v khi lng .Trung bnh 1 phn t
clo phn ng vi k mc xch trong mch PVC.Gi
tr ca k l
A.1 B.2 C.3 D.4
Gii
Gi n l s mc xch cn tm
Ta c :
- PVC :C
2n
H3
n-1
Cl
n+1

- T Clorin : C
2n
H3
n-1
Cl
n+1

Theo bi ta c % m Cl l
6618 , 0
5 , 34 5 , 62
5 , 35 5 , 35
=
+
+
n
n



---> chn B .
CU 10. C 5.668 gam cao su buna-S phn ng
va ht vi 3,462 gam brom trong CCl. Hi t l
mt xch butadien v stiren trong cao su bunaS l
bao nhiu?
A. 1/3 B. 1/2 C. 2/3 D. 3/5
Gii
Ta c:

















---> chn B
1. Khung km c khi lng 10kg, khi lng ring
cua km l 7000kg/m
3
. Hi th tch khung km l bao
nhiu?
A. 1428cm
3
B. 700cm
3
C.
1253cm
3
D. 1428m
3

p n:A.Th tch khung km l:
V=10(kg)/7000(kg/m
3
)=0.001428m
3
=1428cm
3

2. Trong lin kt cng ha tr , ti sao li dng chung
electron?
A. Do electron cn thiu B. Do lc ht tnh in
C. To cu hnh bn vng ca kh him D.
C 3 trn
p n: L loi lin kt bng cp electron chung
hnh thnh gia cc nguyn t ging nhau hay
khng khc nhau nhiu v m in. Chng s
dng cc electron lm thnh cp electron dng
chung cho c 2 nguyn t, khi chng cng c
c cu hnh bn vng ca kh him, lin kt ny
gi l lin kt cng ho tr - mi cp dng chung
to thnh mt lin kt.
3. Khi t vt liu ion vo 1 in trng, nu tc
di chuyn ca ion chm th:
A. Vt liu dn in tt B. Vt liu dn in km
C. Vt liu cch in D. Khng th kt lun
p n: B
4. iu kin c lin kt ion:
A. C s chnh lch m in ln B. in tch khc nhau
C. Gia kim loi vi phi kim D. C 3 trn
p n: A
5. Mt nguyn t khi lp phng:
A. 0.52 B. 0.68 C. 0.74 D. Mt s khc
p n: A
6. Ch s Miller ca mt phng Ct cc trc x, y v z
ti 1/3, 2/3 & 1 l:
A. (632) B. (633) C. (634) B. (635)
p n: A

7. S phi tr cng ln th:
A. Mng tinh th cng dy c B. Mng tinh th cng mng
p n: A
8. Vt liu nano l vt liu:
A. C kch thc nano B. C kch thc phn t
nano
C. C kch thc nguyn t nano D. C 3 trn
p n: A
9. Cng dng ca vi nano l:
A. Chng xc B. Chng bc x cc tm
C. Khng khun D. C 3 trn
p n: B
10. Cc phng php ch to vt liu nano?
A. C c B. o gt C.
Nghin, cn, n D. C 3 trn
p n: D
Cu 1: C 5,699 cao su buna -S phn ng ht vi
3,462 g brom trong CCl
4
. hi t l mc xch gia
butadien v stiren trong cao su buna-S l bao nhiu?
A- 1/3
B- 1/2
C- 2/3
D- 3/5
Chn B- Gi thch
Gi a,b ln lt l s phn t butadien v stiren
PTPU l
(CH2-CH=CH-CH2)a(-CH2-CH-)b +aBr2->(CH2-
CHBr-CHBr-CH2)a(-CH2-CH-)b
|
|
C6H5
C6H5
Ta c: 5,699/(54a+104b)= 3,462160a
724,892a=360,048b
2a=b a/b = => Cu B
Cu 2: Phn ng lu ha cao su thuc loi phn ng
A- Gi nguyn mch polime
B- Gim mch polime
C- ipolime ha
D- Tng mch polime
Chn D
Cu 3: Kt lun no sau y khng hon ton ng ?
A- Cao su l nhng polime c tnh n hi
B- Vt liu compozit c thnh phn chnh l polime
C- nilon-6,6 thuc loi t tng hp
D- t tm thuc loi t thin nhin
Chn B

Cu 4: t chy hon ton m gam cao su isopren
c lu ha bng khng kh va (cha 20% O
2
v
80% N
2
), lm lnh hn hp sau phn ng ngng t
ht hi nc th thu c 1709,12 lt hn hp kh
(ktc). ng kh ny lm ny tc dng va ht vi
dung dch cha 0,1 mol Br
2
. Xc nh m
A- 150,93g
B- 155,93g
C- 159,39g
D- 160,39g
p n C Gii thch:
Ta c: n
hh kh
= 76,3 mol, phng trnh phn ng:
SO
2
+ Br
2
+ 2H
2
O --> H
2
SO
4
+ 2HBr
=> n
SO2
= 0,1mol
Gi x l s mol C
5
H
8

phng trnh phn ng: C
5
H
8
+ 7O
2
--> 5CO
2
+ 4H
2
O
=> nO
2
= 7x => nO
2
ban u = (7x + 0,1) => nN
2
=
4(7x + 0,1)
=> 28x + 0,4 + 5x = 76,2 => x = 75,8/33
=> m = 68 x 75,8/33 + 3,2 = 159,39 gam
Cu 5: Chn cu sai
A- Phn ng trng ngng khc vi phn ng trng hp
B- Trng hp 1,3 butadien c cao su buna l sn phm
duy nht
C- iu kin phn t tham gia phn ng trng hp l
trong cu to phi c lin kt i, lin kt 3 hay vng
khng u
D- iu kin phn t tham gia phn ng trng hp l
trong cu to phi c 2 nhm nh chc c kh nng
tham gia phn ng ngng t.
Chn cu C
Cu 6: Cc polyme sau (-CH
2
CH
2
-)n, (-CH
2
CH
= CH CH
2
-)n, (-NH CH
2
-CO-)n cng thc ca cc
monome khi trng ngng hoc trng ngng to ra
cc polyme trn ln lt l:
A- CH
2
=CH
2
, CH
3
-CH=C=CH
2
, NH
2
-CH
2
-COOH
B- CH
2
=CH
2,
CH
2
=CH-CH=CH
2
, NH
2
-CH
2
-COOH
C- CH
2
=CH
2,
CH
3
-CH=CH-CH
2,
NH
2
-CH
2
-CH
2
-COOH
D- CH
2
=CH
2,
CH
3
-CH=CH-CH
2
, NH
2
-CH
2
-COOH
Chn B- Gii thch
CH
2
= CH
2
(- CH CH -)
n
+ nH
2
CH
2
=CH-CH=CH
2
(- CH
2
CH=CH- CH
2
-)
n
+ nH
2
NH
2
-CH
2
-COOH (- NH

CH
2
CO-)
n
+
nH
2
O
Cu 7: Pht biu no sau y khng ng ?
A- Polime l hp cht c phn t khi ln do nhiu mt x
ch lin kt vi nhau to nn
B- Nhng phn t nh c lin kt i hoc vng km bn
c gi l monome.
C- H s n mt xch trong cng thc polime gi l h s t
rng hp
D- Polime tng hp c to thnh nh phn ng trng h
p hoc phn ng trng ngng
Chn B
Cu 8: Chn pht biu ng
A-
H s trng hp l s n v mt xch monome trong
phn t polime, h s
trng hp c th xc nh chnh xc.
B-
Do phn t khi ln hoc rt ln, nhiu polime khn
g tan hoc kh tan trong
cc dung mi thng thng.
C-
Polime c cu trc mng li khng gian l dng ch
u nhit km nht.
D- Tt c u ng.
Chn D
Cu 9: Trng hp 5,6 lt C2H4 (ktc), nu hiu sut
phn ng l 90% th khi lng polime thu c l
A- 4,3 gam
B- 7,3 gam
C- 5,3 gam
D- 6,3 gam.

Chn D- Gii thch:
n
C2H4
= 5,6/22,4 = 0,25 mol
=> m
C2H4
= 0,25 x 28 = 7g
Phn ng t hiu sut 90% => m = 7 x 0,9 = 6,3g

Cu 10: T 5 tn C
2
H
4
c cha 30% tp cht c th
iu ch bao nhiu tn PE ? ( Bit hiu sut phn ng
l 90% )
A- 2,93 tn
B- 3,93 tn
C- 4,93 tn
D- 5,93 tn
Chn A - Gii thch: Ta c phn ng trng hp ca
PE
nCH
2
=CH
2
(-CH CH -)
n
+ nH
2

5 tn C
2
H
4
c cha 30% => C
2
H
4
tinh khit:
m
C2H4
= 5 x 0,7 = 3,5 tn = 3,5x10
6
g
n
C2H4
= 3,5x10
6
/ 28 = 125x10
3
mol
n
C2H4
= n
PE
= 125x10
3
mol m
PE
125x10
3
. 26 =
325x10
4
g = 3,25 tn
Do hiu sut phn ng ch t 90% nn khi lng PE
l:
m
PE
= 3,25. 0,9= 2,93 tn
1. Phng php tng hp khung kim loi c my hiu
ng:
A. 1
B. 2
C. 3
D. 4
2. Vt liu ceramic gm nhng lin kt no:
A. Lin kt kim loi v cng ha tr
B. Lin kt cng ha tr v ni th cp
C. Lin kt ion v kim loi
D. Lin kt ion v cng ha tr
3. Phng php tng hp siu phn t:
A. Phng php tng hp hu c trc tip v gin
tip
B. Phng php tng hp hu c v v c
C. Phng php tng hp hu c trc tip v
khung kim loi
D. Phng php tng hp hu c, v c v khung kim
loi
4. T nhn to viscoza c tng hp u tin vo
nm no:
A. 1846
B. 1892
C. 1910
D. 1920
5. Cao su nhn to u tin c tng hp t:
A. Ethylen
B. Vinyl clorua
C. 2,3-dimetyl butadien
D. Styrene
6. Theo phng php tng hp c bao nhiu loi
polyme:
A. 2
B. 3
C. 4
D. 5
7. Copolymers c s dng trong mng bao thc
phm ?
A. Saran
B. Vitone
C. SBR
8. ABSCc bc trong phn ng trng hp l:
A. Khi mu, phn ng ng mch, pht trin b mt
B. Pht trin b mt, khi mu, phn
ng ng mch
C. Phn ng ng mch, pht trin
b mt, khi mu
D. Khi mu, pht trin b mt,
phn ng ng mch
9. Trong cc phng php phn tch tnh cht ca
CNTs th phng php u d TGA l phng
php:
A. Chp bn ngoi
B. Chp xuyn vo bn trong
C. Phn tch nhit trng lng
D. Phn tch trng lng
10. Trong vi nano c cha cc ht nano:
A. lSiO
2

B. ZnO
C. Ag
D. TiO
2

1. Mc ch ca phng php tng hp vt liu l g?
a- To s ngng t gia 2 phn t c nhm chc thch
hp.
b- Ti a ha sn phm c dng vng.
c- Ti thiu ha phn ng polymer ha cnh tranh.
d- C a, b, c.
Tr li: chn d. Mc ch to s ngng t gia hai
phn t c nhm chc thch hp, ti a ha sn phm
c dng vng v ti thiu ha cc phn ng polymer
ha cnh tranh.
2. Hon thnh phn ng sau:





tr li:






3. Chn cu ng nht.
Phn ng sau c tin hnh pha long no?

a- Phn ng tin hnh pha long cao.
b- Phn ng tin hnh pha long trung bnh.
c- Phn ng tin hnh pha long thp.
d- Phn ng tin hnh pha long trung bnh v thp.
Tr li: chn cu d- Phn ng tin hnh pha
long trung bnh v thp.
4. Lin kt ion xy ra gia ion m v ion dng, xy
ra km theo s chuyn di electron v cn phi c
mt s?
a- Cn bng
m in.
b- Lc ht ca
cc ion tri du
c- Chnh lch m in
d- ng ng gia cc ion.
Tr li: chn cu c- Chnh lch m in
5. Nng lng lin kt no trong cc lin kt sau thp
nht?
a- Lin kt ion
b- Lin kt cng ha tr
c- Lin kt kim loi
?????
d- Lin kt Van der Waals
Tr li: chn cu d- lin kt Van der Waals: < 10
kcal/mol
6. Chn pht biu ng nht v chc nng sinh l
ca latex:
a- Cht ngoi tit, ngun t dng ca cy.
b- Lun chuyn dng cht, bo v cy chng cc
thng tn
c- Ni lu tr nc v nhiu cht khc, c c s
dng vo nhng hot ng sinh l mnh nht ca cy.
d- Tt c cc chc nng trn.
Tr li: chn cu d
7. 4 ging cy chnh thuc h Euphorbiacae l?
a- Hevea, Manihot, Ficus, Castilloa.
b- Hevea, Manihot, Sapium, Ficus.
c- Hevea, Sapium, Euphorbia, castilloa.
d- Hevea, Manihot, Sapium, Euphorbia.
Tr li: chn cu d- Hevea, Manihot, Sapium,
Euphorbia.
8. kch sn m, tng cng ti lp v ngi ta
thng dng cht p c cht kch hot mui ca?
a- Acid 2,4 dichlorophenoxy acetic.
b- Acid 2 chloroethyphosphoric
c- Acid 2,4 dichloroethyphosphoric
d- Hn hp ca acid 2,4 dichlorophenoxy acetic, acid
chloroethyphosphoric.
Tr li: chn cu d- hp ca acid 2,4
dichlorophenoxy acetic, acid chloroethyphosphoric.
9. Cc phng php chnh dng o phn t khi
cao su l:
a- Php o thm thu, php o nht.
b- Php o thm thu, php o nht, php siu ly tm,
khuch tn nh sng.
c- Khch tn nh sng, php o nh.
d- Php siu ly tm, php o nht, php o thm thu.
Tr li: chn cu b- Php o thm thu, php o
nht, php siu ly tm, khuch tn nh sng.
10. S sp xp ca cc nguyn t v ion ng vai tr
quan trng trong vic xc nh .. ?
a- Cu trc vi m ca vt liu.
b- Tnh cht c trng ca vt liu.
c- Cu trc vi m v tnh cht c trng ca vt liu.
Cu 1: Graphenemtlpchthychnhxckhilp
SiO
2
cdychnhxcbng:
A. 310 nm B.315 nm C.320 nm
D.325 nm
pn : B
Cu 2: Graphenetrongchtnnpolimer(
polyvinylalcohol ) (PVA)
ccnggpbaonhiulntnhn?
A. 9 ln B.10 ln C.11 ln
D.12 ln
pn : B
Cu 3: ng than nanocbnchcl :
A. 1000 GPa B.1020 GPa C.1220
GPa D.1400 GPa
pn : A
Cu 4: Cbaonhiu lien kt cpnguynt :
A. 3 B.4 C.5 D.6
pn : B
+ Linktkimloi
+ Linkthatr
+ Linkt ion
+ Linktthcp : van der waals, lien kt
Cu 5: Cao su sng(haycao su th ) l :
A. Cao su chaluha B.Cao su thinnhin
C.Cao su tnghp D.Cao su luha
pn : A
Cu 6 : Teflon l tnca 1 loipolimerdnglm :
A. Keodn
B. Cao su tnghp
C. Chtdo
D. Keotnghp
pn : C
Cu 7 : Polimer X cphntkhi l 280000
vhstrnghp n = 10000.Vy X l :
A. (-CH
2
-CH
2
-)
n

B. (-CF
2
-CF
2
-)
n

C. (-CH
2
-CH(Cl)-)
n

D. (-CH
2
-CH(CH
3
)-)
n

pn :

Khilng 1 mcxchbng = 280000/10000=28
Vypolimer l : (-CH
2
-CH
2
-)
n

Cu 8 : Cao su buna ccngthccuto l :
A. [-CH
2
-C(CH
3
)=CH-CH
2
-]
n

B. [-CH
2
-CH=CH-CH
2
-]
n

C. [-CH
2
-CCl=CH-CH
2
-]
n

D. [-CH
2
-CH=CBr-CH
2
-]
n

pn : B
Cu9 :Bnchtcasluhacaosul :
A. Gimgithnhcaosu
B. Lmcaosudnkhun
C. Tocunidisunfuagipcaosuccutomngkhnggian
D. Tocaosunhhn
pn : C
Cu10 :Cngthcbndicgitnnhthno:

A. N,N'-Dibenzyl-1,4,10,13-tetraoxa-5,16-
diazacyclooctadecane
B. N,N'-Dibenzyl-1,4,8,13-tetraoxa-7,16-
diazacyclooctadecane
C. N,N'-Dibenzyl-4,13-diaza-18-crown-6
D. N,N'-Dibenzyl-4,13-diaza-16-crown-6
pn: C
d- p n khc
Cu 1 : H cao su no khng c li ch v sn xut
cao su?
A. Asclpiadaceae B.
Funtuania
C. Moracae D.
Composes
p n ng l A
Cu 2: Nng lng lin kt kim loi ph thuc vo
nguyn t ln no ?
A. Kim cng B. Bismuth
C.Tungsten D. Thy ngn
p n ng l C
Loi lin
kt
Nng lng lin
kt
c im
Ion Ln Khng nh hng
(ceramic)
Ha tr Ty thuc vo
nguyn t
- Ln :Kim cng
- Nh :Bismuth
nh hng (bn
dn. ceramic, chui
polymer)
Kim loi Ty thuc vo
nguyn t
- Ln :Tungsten
- Nh: Thy ngn
Khng nh hng
(kim loi)
Th cp Nh nht nh hng :
- Tng tc mch
(polymer)
- Tng tc phn t
Cu 3 : Phn ng tng hp cao su di y l
phn ng tng hp ca cao su no

A. Cao su buna B. Cao su buna-S
C.Cao su buna-N D. Cao su isoprene
p n ng l D
Cu 4: Phng php lin quan n dng chy kh
hydrocarbon trn mt cht xc tc lm nng
trc, phn ly kh to thnh cc ng nano carbon
l phng php?
A. H quang in B. Bo
mn bng laser
C.Ngng t hi ha hc D. Phn
hy CO di p sut cao
p n ng l C
Cu 5 :Tn gi ca t c tng hp t axit
aminoetanoic
A. T enang B. T nylon 6
C.T olon D. T lapsan
n n ng l A
Cu 6: Tnh cht no khng phi l tnh cht vt l
ca polymer?
A. Tnh do B. Nhit nng chy thp
C.Khng tan trong dung mi thng.D. Tnh bn dn
p n ng B
Nhit nng chy : khng c nhit nng chy
xc nh.
Cu 7:Ta m c 16 ht trn 1 inch vung trn
1 hnh chp phng i x300. Hi y l s kch
thc ht no theo ASTM.
A. 7.17 B.
8.17
C.9.17
D. 10.17
p n ng l B
Nu ta m 16 ht trn inch vung ti phng i
300 th ti phng i 100 ta s c :
N = (300/100)
2
.16 = 144x(ht/(inch-vung))=2
n-1

Log 144= (n-1)log2
7.17= (n-1)
n= 8.17
Cu 8:Phn ng no c thi gian phn ng di i
vi cc polymer c phn t ln, c phn ng ng
mch.
A. Phn ng trng hp
B. Phn ng trng ngng
C. C hai u ng
D. C hai u sai
p n ng l D
- i vi phn ng trng ngng : c thi gian phn ng
di i vi cc polymer c phn t ln, khng c
phn ng ng mch.
- i vi phn ng trng hp : c thi gian phn ng
di i vi cc monomer c phn t ln, c phn ng
ng mch.
Cu 9:Lm th no o chn lc?
A. Chn lc ca mt macrocycle cho mt ion kim loi
c bit l t l khng i rng buc ca n cho
rng ion kim loi, so vi cc ion kim loi khc.
B. Cho mt macrocycle c chn lc cho ion kim
loi, n phi hin th lin kt mnh m hn n
so vi cc ion kim loi khc.
C. A ng, B sai
D. C hai u ng
p n ng l D
Cu 10: Gi tn cng thc sau :

A. Benzo -18-crown- 6 B.
Benzo 16-crown-8
C.Dibenzo-18-crown-6
D. Dibenzo-16-crown-8
p n ng l C
Cu 1: Nu lm lnh cao su sng di nhit bnh
thng, sc ko dn ca n s :
A. Tng ln B. Gim xung
C. Khng thay i D. Tng ri gim
Cu 2 : t trng ca cao su lu ha tnh theo cng
thc : vi D t trng cao su lu ha, P khi
lng v V th tch cao su lu ha.
A. D =V/P B. D = V*P
C. D = P/V D. D = P
2
/V
Cu 3 : iu kin Nhit ha do cao su :
A. Nhit 150 200
o
C B. p
sut kh tri
C. Thi gian 24h D. C A,
B v C
Cu 4 : Tnh cht trc tip ca cao su sng bao gm :
A. Tnh cht bn ngoi B. Tnh cht bn
trong
C. Kh nng lu ha D. A v B
Cu 5: Khi trng ngng a gam axit aminoaxetic vi
hiu sut 80%, ngoi aminoaxit d ngi ta cn thu
c m gam polime v 2,88 gam nc. Gi tr ca m
l:
A. 7,296 B. 11,40 C. 11,12
D. 9,120
Cu 6: Nha phenol-fomanehit c iu ch bng
cch un nng phenol (d) vi dung dch no sau
y?
A. CH
3
CHO trong mi trng axit B. CH
3
COOH
trong mi trng axit
C. HCOOH trong mi trng axit D. HCHO trong
mi trng axit
Cu 7: Phn ng lu ha cao su thuc loi phn ng
A. Gi nguyn mch polime B. Gim mch
polime
C. ipolime ha D. Tng mch
polime
Cu 8: Buta-1,3-ien l monome tng hp cao su
buna. T nguyn liu no khng th trc tip c
monome ?
A. C
2
H
5
OH B. CH
3
-CH
2
-CH
2
-CH
3

C. CH
3
COONa D. CH
2
=CH-COONa
Cu 9: Cy cao su thuc loi no cung cp lng cao
su thin nhin nhiu nht trn th gii:
A. Manihot glaziovii B. Ficus elastica

C. Hevea brasiliensis D. Kok-saghyz
Cu 10: Sn phm trng hp ca buta-1,3-ien vi
CH
2
=CH-CN c tn gi thng thng:
A. Cao su B. Cao su buna
C. Cao su buna-N D. Cao su buna-S
1. CycaosuutincnhpvongDngl do
aiavo?
a) J.B Louis Pierre.
b) Hancock.
c) Goodyear.
d) BcsYersin.
2. CycaosuutincnhpvongDngctrng
nino?
a) ngYm(BnCt).
b)SuiDu (NhaTrang).
c) ThocmvinSiGn.
d) ninCexotiLcNinh.
3. CcgingFuntumia, Landolphia,
HancorniaDyerathuchno?
a) Euphorbiacea.
b) Apocynaceae.
c) Ficus.
d) Aselepiadaceae.
4. GingHeveabrasiliensislloicycaosuthchhpviloi
tnhthno?
a) Phnhiu, su, dthotnc, chua (pH=4-4,5)
b) Phnhiu, cn, dthotnc, chua (pH=4-4,5)
c) Phnhiu, su, dthotnc, chua (pH=3,5-5)
d) Phnhiu, cn, dthotnc, chua (pH=3,5-5)
5. Tisaothuhoch latex
caosuchpdngcycaosuHeveabrasiliensis?
a) Latex cacynycnhtcao.
b) Vnngsutthuhoch latex tcaohnccloicykhc.
c) Vkhaithc latex tcynytxyrasc -
skchsnmhncccycaosukhc
d) Latex cacynycnhtthp do cychthng
latex
thucloimchphnnhnhvtnggiaovinhau.
6. Dngccnthitcacngnhndngcomcaosugmn
hngg?
a) Con dao, gingnhiungnchaccloicaosu,
cixln 20-50 ltcmtay, bnh dung dch
NH
3
cmtay.
b) Con dao, gingnhiungnchaccloicaosu,
cixln 20-50 lt.
c) Con dao, gingnhiungnchaccloicaosu, xln
20-50 lt, bnhng dung dchxphng.
d) Con dao, gingnhiungnchaccloicaosu,
cixln 20-50 ltcmtay, bnhngnc.
7. Tmracusaitrongnhngcusau:
a) uhalmtphnngquantrngnhtcacaosusng.
b) Ta cththchinc Sluha
mkhngcnphicnhitthamgiavdngchtkhcvil
uhunh.
c) Tetrachloroquinonev N-
phenolquinoneiminecdngluhacaosucscch
u ma sttt.
d) Thomas Hancock
vtnhkhmphsluhatronglnlmrimtm
ucaosuthoaluhunhvolsi.
8. nhnghahthngniitinhp?
a) Lmththngctobihainiicchnhaubim
tnin.
b) Lmththngctobibaniilintip.
c) Lmththngctobihainiilintip.
d) pnkhc.
9. Tnhchtnocacaosucbitnhtviccloivtliukh
c?
a) Tnhdo.
b) Tnhnhi.
c) Tnhdnin.
d) Tnhdnnhit.
10. Cbaonhiuphngphpophntcaosu?
a) 3
b) 4
c) 5
d) 2
Tiliuthamkho:TpschKhoahckthutcngngh
caosuthinnhin caKsNguynHuTr.
1 Trong phng php tng hp polymer, c
bao nhiu c ch phn ng trng hp gc t do
a/ 1 b/2 c/3
d/4
Gii:
Chn c
Gm cc bc c bn sau :
Bc khi mu : t mt cht hot ha, phn ng gia
mt nhm hot ha vi mt phn t polyme cho ra
mt cht trung gian hot ha.
y phn t benzoyl peroxide s phn ly di tc
dng ca tc nhn nh sng, nhit , s i vo phn
ng ( y l tc nhn gy hot ha).

Bc pht trin mch : l phn ng gia cht trung
gian vi mt monomer to ra mt phn t di hn,
cha mt trung tm hot ha mi, y trung tm
hot ha u mch :

Bc ng mch : bao gm gia hai phn t cha
trung tm hot ha cho ra mt nhm phn t khng
hot ha na

Ngoi ra, vi mt phn t hon chnh, gp mt nhm
phn t ang pht trin, n s ly gc t do ca nhm
ang pht trin , to cho mnh mt trung tm hot ha
mi. Sau phn t tm thm mt gc polymer t do
v to nn mt phn t c mch nhnh.

2 phn lp 2 ng v phng x C
60
v C
70

ta s dng phng php no sao y
a s dng butylcalix8 tch 2 ng v phng x
C
60
v C
70
.
b s dng p-t-butylcalix8 tch 2 ng v phng
x C
60
v C
70
.
c s dng p-t-butylcalix8 tch 2 ng v phng
x C
60
v C
70
. Sau dung Ch3Cl tch C
60
ra ra
khoi phn ng tao phc.
d tt c u sai
Gii :
Chn c
u tin, ta s dng p-t-butylcalix[8] tch 2 ng
v phng x C
60
v C
70
.
Phn ng to phc s xy ra gia p-t-butylcalix[8] v
ng v phng x C
60
theo t l 1:1, ng v phng x
C
70
khng tham gia phn ng. Tch c ng v
phng x C
70

Hn hp phc cn li cho phn ng vi CH
3
Cl, ta s
tch c C
60
, thu hi calid [8].

3 Da vo gin , cho bit

chn lc ca nguyn t bt u t :
a nguyn t th 9 chn lc cao nht v tr 21
b nguyn t th 9 chn lc cao nht v tr 18
c nguyn t th 12 chn lc cao nht v tr 21
d nguyn t th 12 chn lc cao nht v tr 18
Nhn xt :
Chn d
chn lc bt u t vng 12 nguyn t tr ln v
vng c chn lc cao nht v tr vng 18 nguyn
t.
4 Da vo gin , a ra nhn xt

Da vo gin . chn lc cao nht ca iti xy ra
nhm no ?
a/ nhm [2.1.1] b/ nhm [2.2.1] c/
nhm [2.2.2] d/ nhm [3.2.2]
Gii
Nhn xt : da trn h s og K, chn lc gim,
bn gim.
nhm [2.1.1] chn lc cao nht i
+
v thp
nht Cs
+
.
nhm [2.2.1] chn lc cao nht Na
+
v thp
nht Cs
+
.
nhm [2.2.2] chn lc cao nht K
+
v thp
nht i
+
.
nhm [3.2.2] chn lc cao nht Rb
+
v thp
nht i
+
.
Ta chn cu a
5 Da vo hnh v minh ha pha di, cho bit y
l ng dng no ca vt liu siu phn t
a tng hp ha cht b xc tc c k thut ha
phn tch d phn lp ng v


Gii :
Chn b
C ch : ta thy NaCN trong mi trng nc s
khng phn ng vi propyl bromide trong mi trng
chloroform.
Ta thm vo 18-crown-6, n s to phc vi Na v
chuyn t mi trng nc vo mi trng
chloroform
Phn ng th gc Br vi gc CN, v chuyn pha qua
mi trng nc.
6 Tnh lng C
6
H
5
CO)
2
O
2
cn thit sn
xut 1 kg polyethylene c khi lng trung bnh l
4 gmol. it rng mi phn ng cho ra 2 gc
t do v mi gc t do s khi mu phn ng cho ra 1
chui polyethylene. Gi thit c 4 cht khi mu
hot ng hiu qu.
a/ 0,76552 g b/0,72655g c/0,75526g d/
0,75625 g
Gii :
Gi thit phn ng t hiu sut 100%.
S mol ca polyethylene l 1000/400000 = 0.0025 (
mol)
Ta c n
benzoyl peroxide
= . n
polyehtylene
= 0,0025/2 =
0,00125 mol.
Khi lng ca [(C
6
H
5
CO)
2
O
2
] l : m
gt
= 0,00125 .
242 = 0,3025 g.
Theo yu cu bi ton hiu sut t c l 40%
Nn m
tt
= 0,3025. 100/40 = 0,75625 g
Chn cu d
7 Trng ngng acid - amino caproic thu
c m kg polymer v 14,4 kg
2
vi hiu sut
8, gi tr m l
a/ 111kg b/112kg c/113kg
d/114kg
Gii :
Phng trnh phn ng :

Gi thit phn ng t hiu sut l 100%.
S mol ca H
2
O thu c l : n
H2O
= (14,4.1000)/18
= 800 mol.
S mol ca polymer thu c l : 800/n mol.
Khi lng ca polymer l m
lt
= (800/n). 113.n =
90400 g.
Ta c hiu sut thu c l 80%. Nn khi lng ca
m l :
m
tt
= 90400/0.8 = 113000 g = 113 kg.
chn C
8 Trng hp ethylene thu c PE. nu t chy
hon ton PE ta thu c 22g C
2
. s
polymer l
A. 150 B.250 C.350 D.450
- S mol CO
2
:
22000
500
44
mol =
- H s polymer cng chnh l S mol PE ( s mol PE
bng 1/2 s mol CO
2
) : 500/2 = 250
- Chn cu B
9 T 18 ml dung dch ancol etylic 33,33
D ,69 gml iu ch c bao nhiu g PE
hiu sut 1.
a/ 22,5 g b/ 52,2 g c/22 g d/25,2g
Gii :
Vi hiu sut 100% ta c :
Khi lng ca dung dch l m
dd
= 0,69.180 = 124,2
g
Ta thy C% = (m
ct
/m
dd
).100%
Nn m
ct
= (33,33.124,2)/100 = 41,4 g
S mol ancol l n = 41,4/46 = 0,9 mol.
S mol ca PE l : n
PE
= n
ancol
=0,9 mol.
Khi lng PE l m = 0,9.28 = 25,2 g.
Chn D
1 Tnh h s polyme ha ca mt PE, bit
khi lng trung bnh l : 17640 g/mol.
a/ 610 b/620 c/630
d/640
Gii :
Phn t khi ca mt polyme l 28n.
H s polyme ha l n = 17640/28 = 630.
Chn c
Cu 1: Tnh khi lng trung bnh ca mt phn t
cao su poli isopren, bit s mt xch trung bnh l
7000?
A. 45600 B. 47653 C.
47600 D. 48920
Gii: Monome ca cao su poli isopren l isopren
Klpt ca isopren = 68dvC
=> khi lng trung bnh ca mt phn t cao su poli
isopren = 68.7000 = 47600 dvC
p n C
Cu 2: Mt polime X c xc nh c phn t khi
l 39026,5 vC vi h s trng hp to nn polime
ny l 625. Polime X l?
A. PP B. PVC C.
PE D. PS
Gii : Klpt ca monome l 39026,5/625 = 62,5dvC
=> l PVC
p n B
Cu 3 : Nu t chy ht m (g) PE cn 6720 lt oxi
(ktc). Gi tr m v h s trng hp polime ln lt
l ?
A. 2,8kg ; 100 B. 5,6kg ; 100 C.
8,4kg ; 50 D. 4,2kg ; 200
Gii:
(C
2
H
4
)n + 3n O
2
2n CO
2
+ 2nH
2
O
S mol ca O
2
l 300mol => s mol ca (C
2
H
4
)n l
100/n mol
=>khi lng m = 28n.100/n =2800(g) => n = 100
p n A
Cu 4: em trng hp 5,2g stiren, hn hp sau phn
ng cho cc dng vi 100ml dung dch brom 0,15M
sau tip tc cho thm KI d vo th c 0,635g
Iot. Hiu sut ca phn ng trng hp l?
A. 75% B. 25%
C. 80% D. 90%
Gii:
S mol Br
2
= 0,015 mol; s mol I
2
= 0,0025 mol
Br
2
+ CH(C
6
H
5
) =CH
2
(d sau phn ng trng hp)
vi t l 1:1
2KI + Br
2
(d sau phn ng trn) I
2
+ 2KBr
S mol Br
2
d = 0,0025 mol
S mol ca Br
2
phn ng =s mol styren d = 0,015-
0,0025 = 0,0125 mol
Khi lng styren tham gia phn ng trng hp l :
5,2-(0,0125.104) = 3,9(g)
Hiu sut = (3,9.100)/5,2 = 75%
p n A
Cu 5: C 2,834g cao su buna S phn ng va ht
vi 1,731g Br
2
. T l s mt xch butadien : stiren
trong loi polime trn l?
A. 1:2 B. 2:1
C. 1:1,5 D. 1,5:1
Gii: c 1 phn t Br
2
s phn ng vi 1 mt xch cao
su Buna trong cao su Buna S.
s mol ca Br
2
= s mol ca cao su Buna = 1,731/160
= 0,01081875 mol.
=> khi lng ca cao su Buna trong polime l =
0,01081875 x 54 = 0,5842 (g)
=> khi lng ca styren trong polime l = 2,834
0,5842 = 2,2497875 (g)
=> s mol ca mt xch styren l = 2,2497875/104 =
0,0216325 (mol)
=> T l s mt xch butadien : stiren trong loi
polime trn l 0,01081875: 0,0216325 = 1:2 =>p n
A

Cu 6: Mt loi polietylen c phn t khi l 50000.
H s trng hp ca loi polietylen xp x
A. 1230 B. 1529 C. 92D.
1786
Gii: monome capolietylen l C
2
H
4

=> H s trng hp ca loi polietylen = 50000/28
= 1785,7 (mt xch)
Cu 7: Mt on t enang ( tc nilon -7) c khi
lng l 4216,4mg. S mt xch ca on t l
A. 200.10
20
mt xch B. 199.10
20
mt xch. C. 10
22

mt xch. D.Kt qu khc.
Gii :
Monome ca T enang c klpt = 127 dvC
S mt xch = 6,023.10
23
* s mol mt xch =
(4216,4.10
-3
/127)* 6,023.10
23
=
199.10
20
. p n B

Cu 8: PVC c iu ch t kh thin nhin (CH
4

chim 95% th tch kh thin nhin) theo s chuyn
ha v hiu sut ca mi giai on nh sau:
. Mun tng hp 1 tn PVC cn bao nhiu m
3
kh
thin nhin ( ktc).
A. 5589.B. 5883. C. 2941.
D. 5880.
Gii:
V
kh thin nhin
= (

) =
5883246 lt = 5883 m
3
p n B
Cu 9: iu ch c 2,5 tn polistiren cn dng
bao nhiu tn stiren? Bit hiu sut t 50%
A. 4 B. 5 C. 6 D.
Kt qu khc.
Gii:
hiu sut qu trnh t 50%=> khi lng stiren l
2,5.100/50 = 5 (tn)
p n B
Cu 10: Phn ng trng hp l phn ng:
A. Cng hp lin tip phn t nh (Monome) ging
nhau thnh mt phn t ln (Polime)
B. Cng hp lin tip phn t nh (Monome) ging
nhau thnh mt phn t ln (Polime) v gii phng
phn t nh
C. Cng hp lin tip phn t nh (Monome) thnh
mt phn t ln (Polime) v gii phng phn t nh
D. Cng hp lin tip phn t nh (Monome) ging
nhau hoc gn ging nhau thnh mt phn t ln
(Polime).
p n D
Cu 1: Khung xe p c th c ch to t
cc loi vt liu sau: thp (khi lng ring: 7.8
g/cm
3
), nhm (khi lng ring: 2.7 g/cm
3
), titan
(khi lng ring: 4.5 g/cm
3
) v si Cacbon (khi
lng ring: 1.85 g/cm
3
). Hi khi lng ca khung
xe lm t loi vt liu no nh nht? Bit rng khung
xe bng thp c khi lng 14 kg v cu trc ging
nhau.
A. Titan B. Nhm C.
Thp D. Si Cacbon
Gii thch: Ta c cng thc tnh khi lng:
M
1
=
1
xV
M
2
=
2
xV
hiu sut 15% hiu sut 95% hiu sut 90%
Metan axetilen vinylclorua PVC
Do cu trc cc loi vt liu l ng nht (th tch V
khng i) nn:

Theo bi ta bit c gi tr
1
=7.8 M
1
= 14 kg v
ln lt thay gi tr
2
vo t s va c ta c:
M
nhm
= 4.85 kg, M
Titan
= 8.08 kg v M
si C
= 3.32 kg.
Vy khung xe ch to t si Cacbon l nh nht.
Cu 2: Ti sao t trng ca cc vt liu bng
kim loi khc nhau th khc nhau?
A. Sp xp cu trc trong vt liu B.
Cu trc vt liu xp h
C. Cu trc vt liu xp cht D. Cu
to t nguyn t nh
Gii thch: Vt liu bng kim loi c cu trc cng t
kht th khi lng ring cng ln v t trng cng ln.

Cu 3: S thay i th hnh s dn n thay
i iu g trong cc loi vt liu?
A. Th tch mng tinh th B. Tnh cht vt liu C.
C tnh D. C A,B v C
Gii thch: Mt nguyn t kim loi hay mt hp cht
ha hc c th tn ti hai hay nhiu dng cu trc tinh
th - th hnh.
Th tch vt liu thay i do s chuyn dng th hnh
qua qu trnh thay i nhit hay p sut.
S khc bit v cu trc, c bit l cc l trng trong
mng tinh th dn n kh nng ha tan cc nguyn
nguyn t khc vo trong mng tinh th. Do , tnh
cht ca vt liu ph thuc kh cht ch vo cc dng
th hnh.
Cu 4: tng hp Sepulchate, mt hp cht
siu phn t, ngi ta thng s dng phng php
tng hp khun kim loi. Thng thng cc imine rt
nhy b thy phn v phn ng th i nhn, l 2 phn
ng khng mong mun xy ra, vy ti sao trong
trng hp ny ngi ta vn p dng c phng
php ny sn xut Sepulchate.
A. Co
3+
khng lm phi t imine phn cc nh H
+
.
B. Lin kt Co(III)-N rt bn, ngn cn phn ng th
i nhn xy ra.
C. Cc phi t imine lin kt cht vi nhau.
D. C A, B ng.
Gii thch: V nguyn t trung tm l ion kim loi
Co
3+
nn lin kt rt bn vi ion N
3-
v cc phi t
imine lin kt vi nhau bng lin kt yu (lc tng
tc t momen lng cc trong phn t khng phn
cc) v ch ging nh cc trng hp thng gp
khc.
Cu 5: Pht biu no sau y sai khi ni v
chn lc ca vng phi t vi kim loi trung tm ca
h Cryptand?
A. Cc Cryptand trung bnh cho chn lc r rt vi
kim loi kim v kim th khc nhau.
B. Kch thc 3-D to cu trc km bn hn so vi 2-
D.
C. . Khong trng gia vng c tnh cht cng
trnh s co gin khi kt hp cation ln hn hay nh
hn.
D. Cc Cryptand ln (v d Cryptand [3-2-2]) cho
chn lc khng r rt i vi cc ion kim loi.
Gii thch: To ra l cu trc 3-D bn hn so vi 2-D
v vng macrocyclic dng 3-D s gi cht c cht
cha ng bn trong hn so vi dng 2-D.
Cu 6: Pht biu no sau y sai khi ni v
cng dng ca vt liu Nano?
A. Cc ht nano c cho vo bn trong thy tinh to
ra knh t sch, l loi knh khi c nh sng mt tri
chiu vo th cc ht nano c cung cp nng lng
thc hin s b gy lin kt b mt v lm mt i cc
phn t hu c nm trn b mt knh.
B. Nano Ag thng c s dng trong cc my git
do cc ion Ag c tnh khng khun, cc ion ny kha
t bo h hp ca vi khun lm chng khng th h
hp c v cht.
C. Cc ht nano ZnO v TiO c b sung vo kem
chng nng nh cc ht ny c kh nng chng li tia
cc tm (UV) gy ung th da.
D. Cc ht AlSiO
2
c b sung vo polymer ta s
c vt liu c tnh chng xc dng trong bo v
chng bong trc v try xc cho t, xe my, knh
mt,
Gii thch: Cu B sai v c mt s t chc x l
cht thi phn i vic s dng nano Ag trong my
git. Trong mi trng nc, l mi trng c xem
l rt nhy cm nano Ag c th nguy him khi tip
xc vi Ag. c bit khi s dng qu ngng cho
php v nng cao, nano Ag s c c tnh cao v
mt mi trng v sc khe.
Cu 7: Pht biu no sau y ng khi ni v
phng php sn xut vt liu nano 1 chiu?
A. C 4 phng php sn xut vt liu nano 1 chiu
l: Phng h quang in, Bo mn bng laze, Ngng
t hi ha hc v Phn hy CO di p sut cao.
B. Phng php phng h quang in th in cc
Cacbon c t trong bung cha y kh Ne v
c phng in vi hiu in th cao s thu c
loi a lp.
C. Khi s dng phng php bo mn bng laze th
c th tng hp c c 3 loi: n, kp v a lp.
D. Khi s dng phng php phn hy CO p sut
cao th cho dng kh CO cng vi xc tc Fe dng bt
vo bung c p sut cao v nhit t 1000-1100
0
C.
Gii thch: phng php phng h quang in th
bung cha cha y kh He. Cn phng php bo
mn bng laze ch tng hp c vt liu nano n
lp. V vi phng php phn hy CO p sut cao
th xc tc Fe phi dng phc (c 2 vng 5 cnh 2
pha).
Cu 8: Vt liu nano 2 chiu-Graphene c
ng dng lm g?
A. Ch to mn hnh cm ng, tm pht sng, pin mt
tri, c th thay th indium-thic-oxide (ITO) r tin
v bn hn trong lnh vc nng lng.
B. Ch to phi thuyn v my bay trong lnh vc ch
to cng c.
C. Ch to transistor siu nh hot ng rt hiu qu
trong lnh vc in t.
D. C A, B, C ng.
Gii thch: Graphene l mt cht dn cc mng, rt
bn v mt c hc, trong sut v do. dn ca n
c th bin i trn mt ngng ln hoc bng cch
pha tp cht ha hc, bng tc dng ca in trng
nn c th ng dng trong nhiu lnh vc.
Cu 9: tng hp cc polymer ngi ta
dng 2 phng php l: trng hp v trng ngng.
Khi ni v phn ng trng hp iu no sau y
khng ng?
A. Phn ng trng hp cn 1 cht khi mu bt
u phn ng. Khi trung tm hot ha c hnh
thnh th cc monomer s nhanh chng to thnh
polymer.
B. Khi lng phn t tng nhanh trong qu trnh
phn ng ang xy ra.
C. kt thc phn ng thu c polymer theo yu
cu cn c phn ng ng mch.
D. Thi gian phn ng di i vi cc monomer c
khi lng phn t ln v mch polymer di.
Gii thch: tng hp nn polymer trong trng
hp dng phn ng trng hp th thi gian ca phn
ng ko di ch khi cc monomer c khi lng phn
t ln.
Cu 10: iu kin ca phn ng tng hp
Tetrathiomacroycle l:
A. Gi cho nng ca sn phm na vng ca
Dibromopropane t do trong dung dch mc thp
trong sut thi gian phn ng.
B. Gim kh nng ngng t ca sn phm na vng
vi dibromopropane n mc ti thiu.
C. Cn nhiu thi gian cho sn phm na vng cun
li v sa cha li theo hnh dng thch hp cho s
hnh thnh y sn phm ng vng.
D. C A, B, C ng.
Gii thch: Vic tng hp Tetrathiomacroycle l
khng d dng v d xy ra cc phn ng ph khng
mong mun, v th ta cn iu chnh tt c cc iu
kin trn ti a ha lng sn phm mong mun.
Cu 1: Mt vt liu c cho l cng hn kim cng,
l pht hin mi v hnh dng ca Cacbon, l dng
hnh cu rng C60 l tn gi ca vt liu no sau y?
A. Quantum dot C. Graphene
B. Cacbon nanotubes D. Fullerenes
p n chnh xc l cu D. Graphene l vt liu
nano hai chiu; Cacbon nanotubes l vt liu nano
mt chiu; Quantum dot v Fullerenes l vt liu nano
khng chiu, trong Quantum dot c dng hnh kiu
li v v, cn Fullerenes ch c cu trc v rng.
Cu 2: Mt vt liu mi ang c nghin cu gn
y, c cc nh khoa hc cho rng n cn cng hn
c Graphene v kim cng nhng li mm do hn c
ADN. l vt liu no di y?
A. Cacbon nanotubes C.
Cacbyne
B. Cacbon siu cng D.
Hydrocacbon
p n chnh xc l cu C. Theo tnh ton ca cc
nh nghin cu thuc trng i hc Rice Unicersity
(M), cng ca Carbyne cao hn bt k loi vt
liu no m con ngi tng bit n. Carbyne c
cu thnh t mt chui cc nguyn t Carbon lin kt
li vi nhau theo lin kt n v ba hoc lin kt i
ko di lin tc. Vi cu trc ny, mc vng chc
ca Carbyne cao hn c kim cng ln Graphene v
cng hn gp i bt c loi vt liu cng no m con
ngi tng bit n. Tuy c cng cao nh vy
nhng Carbyne li mm do ging nh mt si DNA
v c tnh phn ng cc k cao.
Cu 3: Nh khoa hc no chnh minh cao su thin
nhin l mt hn hp polymer Isoprene (C
5
H
8
)
n
?
A. Bouchardat C.
Condamine v Fresneau
B. Christophe Colomb D. Hatti
p n chnh xc l cu A.
Gai thch:
ng Christophe Colomb l ngi Chu u u tin
bit n cao su trong ln hnh trnh thm him sang
chu M ln th hai.
Con ngi bit n li ch v cng dng ca cao su
nh hai nh bc hc Condamine v Fresneau.
Hatti l tn ca mt qun o thuc chu M.
Cu 4:iu no sau y KHNG ng v phn ng
trng hp:
A. Cht khi mu l Benzoyl peroxide.
B. Sau phn ng khng cn cht khi mu
C. Khi lng phn t tng rt nhanh trong sut qu
trnh
D. C phn ng ng mch
p n chnh xc l cu B. Sau phn ng khng cn
cht khi mu l s nhn bit ca phn ng trng
ngng.
Cu 5:Konstantin Novoselov v Gio s Andre Geim
tch thnh cng siu vt liu Graphene t u.
A. Kim cng C. than ch
B. Kim loi D. tro
p n chnh xc l cu C. H ly mt ming bng
dnh v dn n ln mt ming graphite, cht liu dng
lm rut bt ch. Bng dnh lm trc ra nhng mng
cacbon dy nhiu lp. Nhng bng cch dng i dng
li ming bng dnh, cc mng cacbon ngy mt
mng hn c th c bc ra, trong c mt s
mng cui cng ch dy c mt lp. Cc nh chp
hin vi xc nhn ci mt ngi khng th nhn
thy.
Cu 6:Loi cy cao su thin nhin cung cp 95 97%
cao su thin nhin trn th gii thuc h no di
y:
A. Euphorbiacae C.
Apocynacae
B. Moracae D.
Asclpiadacae
p n chnh xc l cu A. H Euphorbiacae c
tt c 4 ging cy chnh l; Hevea, Manihot, Sapium
v Euphorrbia. Hevea brasilliensis l 1 trong 9 loi
cy thuc ging Havea c a chun nht hin nay
cung cp cho th gii 95 97% cao su thin nhin
cho th gii.
Cu 7: Graphene l tn gi cho vt liu nano hai
chiu do hai nh khoa hc ngi Php ly t u?
A. Tro v hu t ene C. Than
ch v hu t ene
B. Kim cng v hu t ene D. Kim
loi v hu t ene
p n chnh xc l cu C. Theo hai nh khoa hc
Konstantin Novoselov v Andre Geim th tn gi
Graphene c ghp t graphit (than ch) v hu
t -ene, trong chnh than ch l do nhiu tm
graphene ghp li.
Cu 8: Gio s Andre Geim v Tin s Konstantin
Novoselov c vinh danh Gii Nobel Vt l 2010
v gi?
A. Graphene C. Quantum
dot
B. Fullerenes D. Cacbon
nanotubes
p n chnh xc l cu A. Cu B v C l tn ca
mt vt liu nano khng chiu. Cu D l nano mt
chiu. v cu A l vt liu nano hai chiu, y l tm
Cacbon ch dy bng mt nguyn t. Graphene c
mnh danh l vt liu c tng lai, v n khng ch
mng cha tng c m n cn cng hn c kim
cng v khng thm i vi cc loi kh, c tnh
nng dn in v nhit cc tt.
Cu 9:Mt trong nh tim nng ng dng quan trng
ca vt liu siu phn t hin nay l g?
A. Tng hnh C.
A v B sai
B. Siu thu knh D.
A v B ng
p n chnh xc l cu D.
i tng ca siu vt liu l vic b cong sng in
t theo mun ca mnh khi i qua mi trng siu
vt liu. B cong ng i nh sng l s kin bnh
thng trong thin nhin khi nh sng i vo mi
trng c chit sut khc nhau nh s khc x gia
nc v khng kh, trong lng knh, hay gia khng
kh nng v lnh gy o nh trn mt ng. Ta nhn
thy vt v c s phn x ca nh sng t vt n mt
ta. Vic lm "tng hnh" mt vt chng qua l vic b
cong ng i ca sng in t xung quanh vt
khin cho s phn x n ngi quan st khng xy
ra, do vt tng hnh.
Cu 10: Bn cht ca cao su SO v cao su GE
l g?
A. phn cc C.
Kch thc ht
B. Phn t khi D. A
B C u ng.
p n chnh xc l cu A. Ngm cao su sng vo
mt dung mi, cao su sng s n; k n s t tch
ra mt phn tan v mt phn khng tan, hin tng
c bit thy r vi dung mi ether etylen. Phn tan
gi l cao su sol v phn khng tan gi l cao su
gel.
Cu 1: Cunosauyng:
ANhngpolymeclinktitrongmachcththamg
ianhngphnngctrngcalinkti.
B
uhunhtrongcaosuluhalmtnggincacaosu.
C Phnngtrngngngcnchtkhimotrongsnphm.
D Phnngtrnghpkhilngphnttngchm.

Cu 2:
Nhnxttnhchtvtlchungcapolymenodiykh
ngng:
AHuhtlnhngchtrnkhng bay hi.
B
Huhtpolymeungthictnhdotnhnhivcth
kothnhsidai, bn.
C asnngchy
mtkhongnhitrnghockhngnngchymbphn
hykhiunnng.
D askhng tan trong dung
mithngthng,mts tan trong dung
mithchhptothnh dung dchnht
Cu 3:Muniuchcaosubunangi ta
dngnguynliusnctrongtnhin.Nguynliul :
A itdum
B it than ,vi
C ittinhbt, xenlulozo
D Ttcung .
Cu 4:
Mcchcaphnngtnghpvtliusiuphnt:
A Tocsngngtca 2
phntcccnhmchcthchhp.
B Tiahalngsnphmcdngvng.
C Tithiuhascnhtranhphnng oxy ha.
D C 3 trn.
Cu 5: T 4 tn C2H4 ccha 30%
tpchtcthiuchbaonhiutnPE ?
(Bithiusutphnngl 90%)
A. 2,55 B. 2,8 C. 2,52
D.3,6
Bigii :
Phnng CH
2
= CH
2
(CH
2
CH
2
)
n
Nguynliucha 30% tpchtphnng 70%.
Stn PE ciuch : 4 x 70% x 90% = 2.52 tn
Cu 6:Khilngcamtonmcht nilon-6,6l
27346 vCvcamtonmchtcapronl 17176 vC.
Slngmtxchtrongonmch nilon-
6,6vcapronnutrnlnltl
A. 113 v 152.
B. 121 v 114.
C. 121 v 152.
D. 113 v 114.
Bigii:
Phntkhicanilon 6,6l 226 smtxchl 27346
: 226 = 121 mtxch
Phntkhicatcapronl113 smtxchl17176 :
113 =152 mtxch
Cu 7: % kimloiccutrctinhth:
A 70%
B 80%
C 90%
D 95%
Cu 8: Cngthcsaulca :

A Dibenzo- 18 crown 6 B
Benzo- 18 crown 6
C 18 crown 6
D Benzo 12 crown 4
Cu 9: cngthcsauctngilg

A p tert butylcalix[4]arene
B p tert butylcalix[5]arene
C p tert butylcalix[6]arene
D 1,8 Diamino- 3, 6 - dioxaoctane
Cu 10:ng dung novtliusiuphntsauylsai:
A Lmctphntchtrong HPLC.
B Lmxctctrongiuchcaosu.
C Chunon MRI.
D Phnlpngvphngxtinhchhacht.
Cu 1. Lin kt ha hc trong phn t NaCl c to
thnh l do:
A. Hai ht nhn nguyn t ht electron rt mnh.
B. Obitan nguyn t ca Na v Cl xen ph ln
nhau.
C. Mi nguyn t nhng hoc thu electron tr
thnh ion tri du ht nhau.
D. Nguyn t natri nhng 1 electron tr thnh
ion dng, nguyn t clo nhn 1 electron tr thnh
ion m, 2 ion ny ht nhau bng lc ht tnh in to
phn t NaCl.
p n: D
Cu 2. Phng php tng hp khun kim loi tri qua
hiu ng no sau y?
A. Hiu ng nhit ng lc hc cn bng ha hc
dch chuyn v phi to ra macrocyclic ligand thng
qua vic hnh thnh phc kim loi
B. Hiu ng ng lc hc a phn t tc cht n
gn nhau v tr thch hp cho phn ng ha hc c
th xy ra
C. A ng, B sai
D. C A, B u ng
p n: D
Cu 3. in tr tm 2D graphene 1m
2
c in tr
42. dn in graphene l?
A. 6,2.10
7
S.m
-1
B. 7,1.10
7
S.m
-1
C. 8,5.10
7

S.m
-1
D. 9,6.10
7
S.m
-1

Gii:
Ta c:
Tit din chu lc: A = l * 0,335 nm =
0,335.10
-9
(m
2
)
M R =

=> =

= 7,1.10
7
S.m
-1

Chn p n B
Cu 4. Dng cu trc no ca {4,7,13,21,24-hexaoxa-
1,10-diazabicyclo[8.8.8]hexacosane} trong cc cu
trc sau y l ng:
A.
B.




C.
Gii: V {4,7,13,21,24-hexaoxa-1,10-
diazabicyclo[8.8.8]hexacosane} chnh lcryptand
2.2.2 nn c cu trc lp n C
Cu 5. Nhm vt liu c ch to t polime trng
ngng l:
A. T axetat,T nilon-6,nha PVC
B. Cao su ,nilon-7,t nitron
C. T lapsan,t nitron,nha PE
D. T nilon-6,T nilon-6,6,nha PPF
Chn p n D
Cu 6. Ti nilon dng trong sinh hot hng ngy c
ch to ch yu t cht no?
A. Poli (Vinyl axetat)
B. Poli Stiren
C. Poli Etilen
D.Poli (Metyl metacrylat)
Chn p n C
Cu 7. Polyme X l sn phm ng trng hp ca
stiren v 1 anken Y. Phn t khi ca X l 198000
dvC c t l s mc xch ca stiren : Y l 3:2. Mt
khc t 39,6 g X cn 87,36 lt O
2
(ktc). Tng s
phn t stiren v Y to nn 1 phn t X l:
Polime X l sn xixhs phm ng trng hp ca
stiren v 1 anken Y. Phn t khi ca X l 198000
dvC c t l s mt xch ca stiren : Y l 3:2. Mt
khc t 39,6g X cn 87,36 lt O2 (dktc). Tng s
phn t stiren v Y to nn 1 phn t X l:
A. 2500 B. 3500 C. 4500
D. 5500
Gii:
X =
[(C
8
H
8
)
3
(C
n
H
2n
)
2
]
a
C
2n
+ 24H
4n
+ 24 +
(3n+30)O
2
---> (2n +
24)O
2
+ (2n +
12)H
2
O
(28n + 312) (3n + 3)
39,6 3,9
--> n = 3 --> X = [(C
8
H
8
)
3
(C
3
H
6
)
2
]
a
MX = (104*3 + 42*2)a = 198000 --> a = 500
--> Tng s phn t stiren v Y to nn 1 phn t X =
(3 + 2)*500 = 2500
Chn p n A
Cu 8. Polyme CH
2
CH c tn l:
OCOCH
3 n

A. Poli(metyl acrylat) B.
Poli(vinyl axetat)
C. Poli(metyl metacrylat) D.
Poli acrilonitrin
Chn p n B
Cu 9. Sn phm trng hp propen CH
3
- CH = CH
2
l:
A. ( CH
3
CH CH
2
)
n
B.
( CH
2
CH - CH
2
)
n

C. ( CH
3
CH = CH
2
)
n
D.
CH
2
CH

CH
3
n
D.
Chn p n D
Cu 10. T nilon 6,6 thuc loi:
A. T nhn to B. T bn tng hp C. T tng
hp D. T thin nhin
Chn p n C
Cu1: Hyinxctcthchhpvodu ?

A. NaOCH
2
CH
3
,
B. NaOCH
2
CH
3
, CH
3
CH
2
OH
C. NaOCH
2
CH
3
, CH
2
OH
D. NaOCH
2
CH
3
, CH
3
CH
2
CH
2
OH
pn: B
Cu 2:Hichs miller ca 1 mtmng
dibngbaonhiu?

A. 131 C. 1634
B. 431 D. 1243
Cchgii:
Ta c : ctcctrc x, y v z lnltti 1/4 , 3/4, 1.
Nghcholi ta c (4,4/3,1).
Quyngmus ta c (12,4,3).
Vychs miller l: (1243)
Vypnngl D
Cu 3:Tnhh s polymehacamt PE,
bitkhilngtrungbnh l : 10920 g/mol.
A. 390 C. 341
B. 364 D. 400
Gii :
Phnt khicamtpolyme l 28n.
H s polymeha l n = 10920/28 = 390.
Vypnng l A.
Cu 4: nnglnglinktcnghatrtrongvtliu l
baonhiu ?
A. 150-300 C. 25-200
B. 125-300 D. <10
pn : B
Cu 5:iuch caosubunangi ta c th
thchintheos sau :
C
2
H
5
OH buta 1-3- d9ien cao su buna
Hiusutlnlt l 80%, 50%. Tnhkhilng C
2
H
5
OH cnly iuch 27g cao su buna.
A. 115 C. 57,5
B. 187,75 D. 46
Gii :
Gi thitphnngthiusut l 100% cho 2
chuiphnng.
S mol cacao su buna c c l : n = 27/54 = 0,5
mol.
Ta thy n
C2H5OH
= 2.n = 1 mol.
Khilngca C
2
H
5
OH l m
lt
= 1.46 = 46 g.
Thct hiusutcaccchuilnlt l 80%, 50%.
m
tt
= 46/(0,8.0,5) = 115 g.
vypnngl A
Cu 6:Ccphnt polystyrene c chia lm 4
nhmtrongminhmphntkhibngnhau.
Phntkhicanhmnylnltl 20000, 25000,
30000,35000. Tnhphntlngtrungbnhs
n
M ?
A. 27500 C. 22000
B. 110000 D. 25000
Gii:
Sphnmolcaminhmtrong 4 nhml 1/4.

35000
4
1
30000
4
1
25000
4
1
20000
4
1
+ + + =
n
M =
27500
Vyphntlngtrungbnhscamul 27500
pnngl A.
Cu 7:
imkhcbitgiaphnngtrngngngvphnngtrn
ghpl:
Trongphnngtrngngng.
A. Khngcnchtkhimu. C. c A, B
usai.
B. Khngcphnngktthc. D. c A, B
ung.
pnngl D.
Cu 8:
ngdngchuynivtchtrnnglngcavtliunano
l:
A. Chuyninnglngcthnhnnglnginvngcl
i
B. Chuyninnglngtthnhnnglnginvngcl
i
C. Chuyninnglngtthnhnnglngnhit
(tnhit).
D. C A, B, C ung.
pnngl: D.
Cu 9:Trngngng acid - amino caproic thu c m
kg polymer v 15,3kg H
2
O vihiusut 90%, gi tr m
l ?
A. 106722,2 C. 106,7222
B. 96050 D. 96,050
Gii :
Phngtrnhphnng :

Gi thitphnngthiusut l 100%.
S molca H
2
O thuc l : n
H2O
= (15,3.1000)/18 =
850 mol.
S molca polymer thuc l : 850/n mol.
Khilngca polymer l m
lt
= (850/n). 113.n =
96050 g.
Ta c hiusutthuc l 90%. Nnkhilngca m
l :
m
tt
= 96050/0.9 = 106722,2g = 106,7222 kg.
vypnngl C.
Cu 10: T 200 ml dung dchancoletylic 35% (D =
0,69 g/ml) iuch cbaonhiu g PE ( hiusut
100%).
A. 48,3 C. 14,7
B. 29,4 D.58,8
Gii :
Vihiusut 100% ta c :
Khilngcadungdch l m
dd
= 0,69.200 = 138 g
Ta thy C% = (m
ct
/m
dd
).100%
Nnm
ct
= (35.138)/100 = 48,3 g
S mol ancol l n = 48,3/46 = 1,05 mol.
S mol ca PE l : n
PE
= n
ancol
=1,05 mol.
Khilng PE l m = 1,05.28 = 29,4 g.
Vypnng l B.
Cu 1 Khi h nhit xung di nhit bnh
thng th l tnh cao su thay i:
A. Sc chu ko dn ca n gim xung.
B. Nu nhit <-80
0
C th cao su mt ht tnh n hi
(gel ha).
C. dn cng tng.
D. C 3 p n trn u sai
Chn p n B
Nu h nhit xung di nhit bnh thng th
sc chu ko dn tng ln. Nu nhit <-80
0
C th
cao su mt ht tnh n hi (gel ha).
Nhit Sc chu ko dn
(kg/cm
2
)
dn
-185 536 0
-80 380 50
0 88 1000
20 31.7 1250
40 19 1450

Cu 2 Cu trc mng tinh th t phng Tetragonal
c
A. a=b=c v ===90
0
B. a=bc
v ===90
0

C. a=b=c v ===60
0
D. a=bc
v ===60
0

Chn p n B
Da vo hnh trn
ta thy a=bc v ===90
0

Cu 3 ng dng ca cyclodextrins
A. Gia tng kh nng ha tan
B. Gim tnh bin ng ca hp cht , nh hot ng
ca hp cht
C. iu khin s phng thch ca thuc.
D. C A,B,C u ng.
Chn p n D
V Cyclodextrins c ng dng gia tng kh nng ha
tan, gim tnh bin ng ca hp cht , nh hot
ng ca hp cht, iu khin s phng thch ca
thuc.
Cu 4 Cu no khng ng khi ni v Quantum dot ?
A. m kt t cc nguyn t, phn t c kch thc
nh t 1-10 nm.
B. Khng c tnh cht khi.
C. Quantum dot cn c gi l nano tinh th.
D. C cu trc kiu li v
Chn p n B
V Quantum dot l m kt t cc nguyn t, phn t
c kch thc nh t 1-10 nm. Quantum dot cn
c gi l nano tinh th, thng c cu trc kiu li
v. Tnh cht ni bt ca QD l gia tnh cht khi l
tnh cht ca phn t ring l.
Cu 5 Mt on cao su ban u da 28 cm, sau khi tc
dng mt lc ko, dy cao su di thm 5 cm. Vy
bin dng t i ca dy cao su l:
A. 0.015
B. 0.15
C. 1.5
D. 15
Chn p n B
Ta c cng thc
0
33 28
0.15
33
l l
l
c

= = =
Trong :
l l chiu di khi ko
l
0
l chiu di ban u
Cu 6 nh ngha chnh xc khi ni v Polymer
A. L nhng phn t ln
B. Cha nhng n v nh
C. Cc n v nh lin kt vi nhau
D. Tng hp c 3 trn
Chn cu D
Polymer l phn t ln bao gm nhiu phn t
monomers kt hp li vi nhau
Cu 7 Mc Polymer ha Polystyren c 26000
(g/mol)
A. 250
B. 260
C. 270
D. 280
Chn p n A
Polystyren c cng thc l C
8
H
8
M=104
Polymer ha
26000
250
104
n = =
Cu 8 c im ca phn ng trng hp ion?
A. Xy ra theo th t
B. Polymer c kch thc khng ng u
C. Phn ng ng mch
D. Ch xut hin khi thm 1 cht kt thc mch
Chn p n D
Phn ng trng hp ion xy ra cng 1 lc, ch xut
hin khi thm 1 cht kt thc mch, chui polymer
ng nht.
Cu 9 T 1 tn C
2
H
4
c cha 10% tp cht c th
iu ch bao nhiu PE vi hiu sut 90%?
A. 180 kg
B. 108 kg
C. 810 kg
D. 801 kg
Chn p n C
T 1 tn C
2
H
4
c cha 10% tp cht nn ch c 900
kg C
2
H
4
nguyn cht, hiu sut phn ng 90% nn ta
c lng Polyethylen l 900 0,9 810 = kg
Cu 10 S khc bit ca phn ng trng ngng so vi
phn ng trng hp l:
A. Khng cn cht khi mu, khng c phn ng ng
mch.
B. Thi gian phn ng di i vi monomer c khi
lng ln.
C. Trung tm hot ha c khi mu, cc monomer
c cng vo to thnh 1 phn t c khi lng
ln.
D. C A, B, C u ng.
Chn cu D
L thuyt so snh s khc bit ca phn ng trng
ngng so vi phn ng trng hp chapter 4 Vt liu
polymer th hin.
Cu 1: Thp l vt liu c kh nng bin dng do tt
v
a. trng thi nng khng ph thuc vo thnh phn
cacbon
b. trng thi nng ph thuc vo thnh phn cacbon
c. trng thi ngui khng ph thuc vo thnh phn
cacbon
d. trng thi nng ln trng thi ngui khng ph
thuc vo thnh phn cacbon
cu 2: cc tnh cht c l ca n tinh th theo cc
phng khc nhau l khng ging nhau. Tnh cht
ny gi l:
a. tnh ng hng
b. tnh d hng
c. tnh v hng
d. tnh d trc
Cu 3: Polime thin nhin: tinh bt (C
6
H
10
O
5
)n;
cao su isopren (C
5
H
8
)
n
; t tm (-NH-R-CO-)
n
.
Polime c th c coi l sn phm trng ngng l
A. Tinh bt (C
6
H
10
O
5
)
B. Tinh bt (C
6
H
10
O
5
); cao su isopren (C
5
H
8
)
n
.
C. Cao su isopren (C
5
H
8
)
n
D. Tinh bt (C
6
H
10
O
5
); t tm (-NH-R-CO-)
n
Chn p n D.
Cu 4: T 100lt dung dch ru etylic 40
o
( khi
lng ring ca ru nguyn cht D=0,8g/ml )c th
iu ch lng cao su buna l (hiu sut H=75%).
A. 14,087kg
B. 18,783kg
C. 28,174kg
D. Kt qu khc.
m
ru
=
40 100 0,8
32
100

=
kg
2C
2
H
5
OH C
4
H
6

mC
4
H
6
=
32 54 0, 75
14, 087
2 46

=

kg
Cu 5: Nhit phn 1m
3
hn hp A gm
butan,but1en v but2en ngi ta thu c
buta1,3ien vi hiu sut 80% (theo s mol). Hy
tnh khi lng cao su buna (C
4
H
6
) thu c t hn
hp kh trn, bit rng phn ng trng hp t hiu
sut 90%
A. 1635,7
B. 1735,7
C. 1835,7
D. 1985,7
Gi cng thc chung ca hn hp A l C
4
H
n

nC
4
H
6
= nA
mC
4
H
6
=
1000 0.8 0.9 54
1735, 7
22, 4

=
kg
Cu 6.Polyme no khng tan trong mi dung mi v
bn vng nht
A. PVC B. Cao su lu ha C. Teflon D.
T nilon
Chn p n C
Cu 7: Chn cu sai
A. S phi tr cng ln mng tinh th cng dy c
B. Tinh th bn khi tt c cc anion chm c vo
cation trung tm.
C. Cation thng c bn knh nguyn t < anion th t s
bn knh <1
D. S phi tr cng nh mng tinh th cng dy c
Cu 8: khung thp c khi lng 8kg, khi lng
ring ca thp l 7,8g/cm
3
c th tch khung:
A,1025.5 cm
3
B,1025.6 cm
3
C,1025.7cm
3

D,1025.8 cm
3
th tich khung =8000/7.8=1025.6 cm
3

Cu 9: th xp grapheme c th pht hin NH
3
v
NO
2
nhy:
A,20ppm B,25ppm C,30ppm D,35ppm
Cu 10: chn cng thc ng:
A . E=(-e
2
)/4
2

B . E=(-e
2
)/4
C. E=(e
2
)/4
D. E=(e
2
)/4 r
2

1. Khng nn git qun o nilon, len, t tm bng
x phng c kim cao, khng nn git bng
nc qu nng hoc l i qu nng l do:
a Trong nilon, len, t tm c nhm chc cacboxyl
trung ho bi kim v nilon, len, t tm u km bn
vi nhit.
b Trong nilon, len, t tm l hp cht lng tnh nn
b trung ho bi kim v nilon, len, t tm u km
bn vi nhit
c Trong nilon, len, t tm c lin kt peptit d b
thu phn trong mi trng kim v nilon, len, t
tm u km bn vi nhit.
d a, b v c u sai
2. Nhn xt no sau y ng:
a Cht do l nhng vt liu c kh nng bin dng
khi chu tc dng ca nhit, p sut v vn gi c
s bin dng khi thi tc dng.
b T l nhng polime c th ko thnh si di v
mnh
c Vt liu thuc cao su l b bin dng khi c lc tc
dng (p, nn ko, v.v...) v tr li dng ban ukhi
lc thi tc dng
c C a, b v c u ng.
3. Loi polime no sau y c cu trc mch
nhnh:
a. Amilopectin
b Nha PS
c Nha PP
d C a, b v c
4. iu no sau y khng ng khi ni v polime:
a cc polime khng tan trong dung mi hu c
b Cc polime khng c nhit nng chy xc nh,
do mt polime l hn hp nhiu phn t c khi
lng phn t khc nhau.
c Cc polime khng bay hi, do khi lng phn t
ln v lc lin kt gia cc phn t ln.
d Poliisopren c tnh n hi, polistiren c tnh do,
nilon-6,6 l t tng hp l nhng si di, mnh v
mn mi.
5. Tn gi ca cng thc sau:

a.Nha phenol-fomandehit
b. Nha bakelt
c. Nha do
d. Polystiren
6. Khi nim v lch s hnh thnh ca vt liu
nano 2 chiu
a. Graphite (than ch) gm nhng tm carbon hnh lc
gic xp chng ln nhau lin kt nh lc van der
Waals.
b. Mi tm lc gic gm mt lp nguyn t carbon
hp thnh mt mng hnh lc gic (kiu t ong), gi
l graphene.
c. L cht liu kt tinh hai chiu tht s u
tin.Khong cch gia hai lp graphene trong than ch
l 0,34 nm, c 1 mm than ch c 3 triu lp graphene.
d. C a, b, c u ng.
7. Kch thc ht cao su trong dch latex ?,
a. Khong 0,05-3
b.Khong 0.04-0.05
c. Khong 2-3
d.Khong 3-5

8. Dng Graphene no c bn cao nht?
a. Graphen (3%)/PVA
b. Graphen/CNT/PVA(15:15:70)
c. Graphen paper
d. Graphen Ca
2+
9. Khng nn thu hoch cao su vo thi im no
trong nm?
a. Ma xun
b. Ma h
c. Lc cy rng l
d. Ma ng
gii thch: thu hoch vo thi gian ny th cy s cht
10. Cy cao su c trng Vit Nam t nm
no?
a. 1880
b. 1886
c. 1877
d. 1870
1.Tng quan nng lng lin kt v c tnh vt
liu?
a. Vt liu ceramic (lin kt ion v cng ha tr)
- Nng lng lin kt ln
- Tm, E ln, h s gin n nhit nh
b. Kim loi (lin kt kim loi)
- Nng lng ni bin i
- Tm v E v h s gin n nhit trung bnh
c. Vt liu polymer (lin kt cng ha tri v ni th
cp)
- Tnh cht theo hng xem xt, ni th cp chim u
th
- T v E nh, h s gin n nhit ln
d. C a, b, c u ng
2.S phi tr v sp xp tinh th ion?
a. S phi tr (coordination number): l s lng
nguyn t cch u gn nht mt nguyn t
cho. S phi tr cng ln mng tinh th cng dy
c.
b. Do nguyn t kim loi cho i electron, cation
thng c bn knh nguyn t < anion t s, bn
knh < 1 mi cation cn nhiu anion ln cn.
c. Tinh th bn khi tt c cc anion xung quanh chm
c vo cation trung tm.
d. C a, b, c u ng
3.S sp xp ca cc nguyn t v ion ng vai tr
nh th no?
a. Xc nh cu trc vi m v tnh cht c trng
ca vt liu.
b. Phn loi vt liu da vo s sp xp canguyn
t/ion
c. M t s sp xp trong cc vt liu c cutrc tinh
th da trn cc thng s mng.
d. Khng c vai tr ng k
4. Lin kt kim loi l g?
a. Lin kt kim loi to thnh do nguyn t cho cc
electron lp ngoi cng dng chy electron.
b. Tng tc m -dng ca ht nhn electron gi
cutrc kim loi n nh.
c. C a v b u sai.
d. C a v b u ng
5. Cy cao su c th chu hn c bao lu?
a. 4 5 thng b. 5 6 thng c. 6 7 thng d. khng
c kh nng chu hn
6.hm lng phn kh trong m cao suc gi tr t
?
a. 28-40% b. 50-70% c. 20-30% d. 10-50%
7. C my loi cu trc mng tinh th?
a. 8 b. 7 c. 6 d. 5
gii thch:
- mng lp phng (cubic)
- t phng (Tetragonal)
- Orthorhombic
- Rhombohedral
- Hexagonal
- Monoclinic
- Triclinic
8. Dng th hnh v chuyn dng l g
a. Dng th hnh l s tn ti hai hay nhiu dng cu
trc tinh th ca cng mt nguyn t hay mt hp
cht ha hc.
b. S chuyn i dng th hnh ny sang dng khc
gi l s chuyn dng th hnh. Cc yu t dn n
chuyn dng th hnh thng gp l p sut v nhit
.
c. S khc bit v cu trc, c bit l cc l trng
trong mng tinh th dn n kh nng ha tan cc
nguyn t khc vo trong mng tinh th.
d. S thay i dng th hnh thng dn n s thay
i th tch mng tinh th v c tnh.
e. tt c cc trn
9. Hm lng hydrocacbon trung bnh trong cao
su
a. 80 85% b. 85 90% c. 92 95% d. 75
80%
10. phn bit gia da tht vi da nhn to (ch t
PVC) hoc phn bit gia len, t tm vi t nhn to
(t visco, t axetat) bng cch n gin l:
a Th vo ru etylic
b em t
c Th vo nc
d C ba cch trn u c
Cu 1: Cho s sau: CH
4
X Y Z cao su
buna. Tn gi ca X, Y, Z trong s trn ln lt l:
A. Axetilen, etanol, butadien
B. Andehit axetit, etanol, butadien
C. Axetilen, vinylaxetilen, butadien
D. Etilen, vinylaxetilen, butadien.
Cu 2: un nng vinyl axetat vi kim iu kin
thch hp, ta thu c sn phm trong c:
A. Ancol vinylic
B. Ancol
C. Andehit axetic
D. Axeton
Cu 3: pht biu no sau y ng:
A. Tinh bt l polime mch khng phn nhnh.
B. Aminoaxit l hp cht a chc
C. ng trng hp l qu trnh c gii phng nhng
phn t nh
D. Tt c u sai
Cu 4:Cht no di y khng th trc tip
tng hp c cao su?
A. ivinyl B. Isopren C. Clopren D. But-2-
en
p n D
Cu 5: Trong cc cht sau y cht no khng phi
l polime?
A. Tristearat glixerol B. Nha
bakelit
C. Cao su D. Tinh bt
p n A
Cu 6: T lapsan thuc loi
A. T axetat
B. T Visco
C. T polieste
D. T poliamit
p n : D
Cu 7 : Tnh h s polyme ha ca mt PE, bit khi
lng trung bnh l : 14560 g/mol.
A. 500 C. 540
B. 520 D. 430
p n B
Phn t khi ca mt polyme l 28n.
H s polyme ha l n = 14560/28 = 520.
Cu 8 : Trong cc polyme c cng mc xch sau,
polyme no c .khi lng phn t ln nht :
A. Poli( vinyl axetat) C. T capron
B. Thy tinh hu c D. Polistiren
p n B
Cu 9 : Polyme no sau y khng b thy phn trong
mi trng kim ?
A. PVA (Poly vinyl axetat) C. T nilon-6,6
B. T capron D. Cao su thin
nhin
p n D
Cu 10: cc polime c kh nng lu ha l
A. Cao su buna
B. Polisopren
C. Cao su buna S
D. Tt c u ng
1. C th iu ch PVC bng phn ng trng hp
monome no sau y
A) CH2=CHCH2Cl
B) CH3=CHCH2
C) CH3CH2Cl
D) CH2=CHCl
Gii
PVC : poli vinyl clorua
2CH4 --( 1500C , lm lnh nhanh )--> CH CH +
3H2
CH CH + HCl --> CH2 = CHCl
nCH2 = CHCl (xc tc, nhit , p sut) -> (- CH2 -
CHCl -)n
2. Trong cc polymer sau th polymer no c th
dng lm cht do:
A) Nha PE
B) Thy tinh hu c
C) Nha PVC
D) Tt c u ng
3. Cc phn t cu mu polystyrene c th chia
thnh 5 nhm trong gii hn phn t khi vi cc
s cho mi nhm phn t. S phn t khi ca
nhm l 5000, 10000, 20000, 25000, 40000. Tnh s
phn t khi trung bnh

n

A) 5000
B) 50000
C) 10000
D) 15000
Li gii:
S phn mol ca 1 nhm trong 5 nhm phn t l

Vy

n
=

Cu 4: Trong s cc loi t sau. T thuc loi
poliamit l
[- NH-(CH2)6-NH-CO-(CH2)4-CO -]n (1); [- NH-
(CH2)5-CO -]n (2); [- C6H7O2(OOCCH3)3 -]n (3)
A) (1), (2), (3)
B) (2), (3)
C) (1), (2)
D) (1), (3)
Gii
T polyamit c 2 loi si
Si polyamit-6,6 : [- NH-(CH2)6-NH-CO-(CH2)4-
CO -]n c a t t exanmetyleamin v axit adipic
Si polyamit- 6: [- NH-(CH2)5-CO -]n c to ra t
aprolactam
4. Cht no di y khng th trc tip tng hp
cao su
A) ivinyl
B) Isopren
C) Cloropren
D) But-2-en
5. Cht no sau y l nguyn liu sn xut t viso
A) Caprolactam
B) Xenlulozo
C) Vinyl axetat
D) Alanyn
6. t chy hon ton 1 lng polyetilen, sn phm
chy ln lt cho i qua bnh (1) ng H2SO4 c
v bnh (2) ng Ca(OH)2 dung dch d thy khi
lng bnh (1) tng m gam, bnh (2) thu c 100g
kt ta. Vy m c gi tr l :
A) 36gam
B) 9gam
C) 18gam
D) 54gam
Li gii:
ng nc sinh ra s c H2SO4 hp th
ng ta sinh ra l CaCO3
S mol CaCO3 : n=

CH2CH2 +3O2 -> 2CO2 +2H20
1mol -> 1mol
C02 +Ca(0H)2 -> CaCO3 +H20
1mol ---------- 1 mol
Vy ga tr m =1 *18= 18gam
7. Ch ra iu sai:
A) Bn cht cu to ca t nilon l polyamit
B) T nilong, t tm , len rt bn vng vi nhit
C) Bn cht cu to ha hc ca si bng l xenlulozo
D) Qun o,nilon, len, t tm khng nn git vi x
phng c kim cao
8. Hp cht c cng thc cu to l [-0-(CH2)2-OOC-
C6H4-CO-]n c tn l
A) T nilon
B) T elang
C) T capron
D) T dacron
9. Hy cho bit polyme no c cu trc mch phn
nhnh
A) PVC
B) Xenlulozo
C) Amilopectin
D) Cao su Isopren
Cu 1. Polimer c tng hp t phn ng trng hp
:
A. t tm.
B. t capron.
C. t nilon.
D. c A, B, C.

Cu 2. nh vc ng dng ch yu ca polimer :
A. Cht do.
B. Cao su.
C. T tng hp.
D. C A, B, C.

Cu 3.Polimer no c cu trc mng khng gian ?
A. Cao su thin nhin.
B. Cao su buna.
C. Cao su lu ho.
D. Cao su pren.

Cu 4. Cc polimer
A. khng c nhit nng chy xc nh v d bay
hi.
B. khng c nhit nng chy xc nh v kh
bay hi.
C. c nhit nng chy xc nh v kh bay hi.
D. c nhit nng chy xc nh v d bay hi.
Cu 5. c im cu to ca monomer tham gia phn
ng trng hp l :
A. C lin kt kp.
B. C s lin hp cc lin kt kp.
C. C t hai nhm chc tr ln.
D. C hai nhm chc u mch phn ng c vi
nhau.
Cu 6. c im cu to ca monomer tham gia phn
ng trng ngng ?
A. C hai nhm chc tr ln.
B. C hai nhm chc khc nhau.
C. C hai nhm chc ging nhau.
D. C hai nhm chc ging nhau hoc khc nhau.
Cu 7. Cu to iu ho l kiu cu to m cc mt
xch trong mch polimer ni vi nhau c trt t theo
kiu :
A. u ni vi ui.
B. u ni vi u.
C. ui ni vi ui.
D. u ni vi u, ui ni vi ui.
Cu 8. Vi cng thc no sau y khng phi l cht
do?
A. (-CH
2
-C(CH
3
)=CH-CH
2
-)
n
B. (-CF
2
-CF
2
-)
C. (-CH
2
-CHCl-)
n

D. (-CH
2
-C(CH
3
)-(COOCH
3
)-CH
2
-)
n
Cu 9. Nhn xt no sau y ng?
A. Cht do l nhng vt liu c kh nng bin dng
khi chu tc dng ca nhit, p sut v vn gi c
s bin dng khi thi tc dng.
B. T l nhng polymer c th ko thnh si di v
mnh.
C. Vt liu thuc cao su l b bin dng khi c lc tc
dng (p, nn ko,..) v tr li ban u khi lc thi
tc dng.
D. C A, B v C u ng.

Cu 10. Nhng polimer thin nhin hoc tng hp c
th ko thnh si di v mnh, gi l
A. cht do. B. cao su. C. t. D. Si.
Cu 1: Hy d on cu trc tnh th hp cht Al
2
O
3

A. S phi tr 8, cu trc CsCl
B. S phi tr 6, cu trc CsCl
C. S phi tr 4, cu trc ZnS
D. S phi tr 8, cu trc CsCl
Chn C
Gii

= 0.378571
Trng hp ny s phi tr l 4, cu trc ZnS
Cu 2: Sai lch mng tinh th c my loi
A. 3 Sai lch im, sai lch ng, sai lch mt.
B. 2 Sai lch im, sai lch ng.
C. 4 Sai lch im, sai lch ng, sai lch vng, sai
lch tm.
D. 3 Sai lch im, sai lch ng, sai lch tm.
Chn A (l thuyt chng 1)
Sai lch mng tinh th c 3 loi
Cu 3. Xc nh ch s Miler c my bc
A. 4 bc nu khng c phn s v s m
B. 4 bc nu c phn s phi thm bc quy ng mu
s
C. 4 bc nu c s m th thm du gch trn u cho
s m
D. C A,B,C ng
Chn D (l thuyt chng 1)













Cu 4: K tn cc ng dng ca vt liu siu phn t
A. Tng hp ha cht, xc tc,ng dng trong k thut
ha phn tch.
B. Tng hp ha cht, xc tc, phn lp ng v phng
xa, tinh ch ha cht.
C. Tng hp ha cht, xc tc,ng dng trong m phm,
y hc.
D. Tng hp ha cht, xc tc,ng dng trong k thut
ha phn tch, phn lp ng v phng xa, tinh ch
ha cht, ng dng trong m phm, y hc.
Chn D (l thuyt chng 2)
Cu 5: Xc nh tn ca cht sau :

A. Cryptand-2.2.2
B. Cryptand-2.1.2
C. Cryptand-1.2.2
D. Cryptand-3.2.2
Chn A
Gii thch
m=2
m=2
n=2

Cu 6: Vt liu nano khng chiu?
A. C 3 chiu u c kch thc nano, v d: dy
nano,ng nano
B. Khng c chiu c kch thc nano
C. C 3 chiu u c kch thc nano,v d: m nano,
hat nano
D. C 3 u sai
Chn C v vt liu nano l nhng vt liu c t nht 1
chiu c kch thc nanomet, vt liu nano khng
chiu l nhng vt liu khng c chiu t do no cho
nguyn t, c 3 chiu u c kch thc nano.
Cu 7: Polime no c cu trc mch nhnh.
A. Cao su buna, amilopectin
B. Amilozo, polistriren
C. Amilopectin, glycogen
D. Polietilen, amilozo
Chn 1 mt phng
Xc nh im ct ca mt
phng vi 3 trc
Tm ta giao im trn 3
trc, nghch o
C phn s

Quy ng mu
Thm du gch trn
u cho s m
B mu v c b ba (h,k,l),
tng ng (x, y,z)
Chn C
Gii thch
Polime c 3 dng cu trc
Mch thng do cc mt xch lin kt thnh chui di
khng phn nhnh.
Mch nhnh do cc mt xch lin kt thnh chui di,
phn nhnh.
Mch mng li gia cc polime c cu ni bn
vng.
Cu 8: Nu t chy m(g) PE cn 6720 lt oxi (ktc).
Gi tr m v h s trng hp ln lt l
A. 2.8kg ;100
B. 5.6kg ;100
C. 8.4kg; 50
D. 4.2kg;50
Chn A
Gii thch
Gi n l h s trng hp

=300

+ 3n O
2
2nCO
2
+
2nH
2
O

=100 n=100

= 100*28=2.8kg
Cu 9: Tm cu ng trong cc cu sau:
A. Phn t polyme do nhiu phn t nh (gi l mc
xch) to nn
B. Cao su lu ha l polime thin nhin ca isopren
C. Polime v mt xch phn t ch l 1
Chn B
Gii thch
Polyme l nhng hp cht c phn t khi rt ln do
nhiu n v nh gi l mt xch lin kt vi nhau.
Cc phn t to nn tng mt xch ca polime gi l
monome.
Cu 10: c im ca monome tham gia phn ng
trng ngng
A. Phi c lin kt bi
B. Phi c nhm NH
2

C. Phi c 2 nhm chc tr ln
D. Phi c nhm OH
Chn C
Gii thch
Phn ng trng ngng l phn ng kt hp nhiu phn
t nh monome thnh phn t ln polime ng thi
gii phng nhng phn t khc.
iu kin cn phn ng trng ngng xy ra l
monome tham gia phn ng trng ngng phi c t
nht 2 nhm chc c kh nng phn ng to c
lin kt vi nhau.
Cu 1: Vt liu X c cu trc mng FCC, c khi
lng ring l 1.71 g/cm
3
, bn knh nguyn t 0.143
nm. Hi X l :
A. Cu
B. Fe
C. Al
D. Mg
Gii:
Ta c: trong cu trc FCC c 4 nguyn t trong mt
mng c s v V=a
3
=(2 R)
3
.

Suy ra:

Chn Al
Cu 2: D on cu trc tinh th Al
2
O
3
, vi bn knh
ca Al
3+
l 0.053 nm, O
2-
l 0.14 nm.
A. S phi tr l 6 ging cu trc ca NaCl
B. S phi tr l 4 ging cu trc ca ZnS
C. S phi tr l 6 ging cu trc ca ZnS
D. S phi tr l 4 ging cu trc ca NaCl
Gii:
Ta c: t s

T l ny nm trong khong 0.225 0.414 nn c s
phi tr l 4, ging cu trc ZnS.
Cu 3: sn xut 100 nha poly etylene ngi ta
cn bao nhiu C
2
H
5
OH, vi hiu sut tng phn ng
l 80%.
A. 256.7 kg
B. 265.7 kg
C. 625 kg
D. 652 kg
Gii:
Ta c m C
2
H
5
OH -> m CH
2
=CH
2
-> (-CH
2
-CH
2
-)
m

S mol ca PE:

S mol ca etylene vi hiu sut 80%

S mol ca C
2
H
5
OH vi hiu sut 80% l

mol

kg
Cu 4: Trong nghin cu c hc ca graphene th
graphene c bn so vi thp gp bao nhiu ln v
dn in so vi Cu l:
A. Gp 100 ln thp, gp 10 ln Cu
B. Gp 10 ln thp, gp 100 ln Cu
C. Gp 100 ln thp, gp 100 ln Cu
D. Gp 100 ln thp, gp 10 ln Cu
Cu 5: Tnh mc polymer ha ca t lapsan c
khi lng phn t l 100416 vtc.
A. 523
B. 532
C. 521
D. 512
Gii:
Ta c cng thc ca lapsan (-CO-C
6
H
4
CO-O-C
2
H
4
O-
)
n


M
lapsan
=192n suy ra n= M
lapsan
/192=100416/192=523
Cu 6: Trong cc mng sau, mng no c tt c
cc gc l 90
o
.
A. Cubic, tetragonal, orthorhambic, hexagonal,
mnoclinic
B. Orthorhambic, hexagonal, mnoclinic
C. Cubic, tetragonal, orthorhambic, hexagonal
D. Cubic, tetragonal, orthorhambic

Gii:
mng Cubic, tetragonal, orthorhambic th tt c cc
gc iu bng 90
o
.
mng hexagonal c 2 gc 90
o
v 1 gc 120
o

mng mnoclinic c 2 gc 90
o
v 1 khc 90
o

Cu 7: trong phn ng thy phn tinh bt thnh
glucose cn bao nhiu nc thu c, 5kg glucose,
bit sau phn ng thinh bt d.
A. 0.5 kg
B. 1 kg
C. 0.57 kg
D. 0.25 kg
Gii:
Ta c phn ng ( C
6
H
10
O
5
)
n
+ nH
2
O
nC
6
H
12
O
6

n
g
=m
g
/M
g
=5000/180=27.77mol
suy ra n
H2O
= n
g

suy ra m
H2O
= n
H2O
*M
H2O
=27.77*18=500 g
Cu 8: Mt mt ct trc x, y, z ln lc ti , 2,

.
hi ch s Miller ca mt ct l:
A. (0,1/2,2)
B. (0, 1, 4)
C. (0 2)
D. (0 1 4)
Gii:
Ta c Mt mt ct trc x, y, z ln lc ti , 2,

,
Nghch o li ta c (0,1/2,2),
Quy ng mu s ta c (0, 1, 4)
Suy ra ch s Miller l (0 1 4).
Cu 9: Cht no trong cc cht sau c hnh thnh
bng lin kt cng ha tr:
A. NaCl, H
2
Se, CH
4,
SiO
2,
CaF
2

B. H
2
Se, CH
4,
SiO
2,
CaF
2

C. H
2
Se, CH
4,
SiO
2

D. NaCl, CH
4,
SiO
2,
CaF
2

Gii:
Ta c NaCl c hnh thanh bng lin kt kim loi
,

CaF
2
c hnh thanh bng lin kt ion.
Cu 10: Lin kt ca nguyn t kim cng l:
A. Lin kt cng ion, c nng lng lin kt ln
B. Lin kt cng ion, c nng lng lin kt nh
C. Lin kt cng ha tr, c nng lng lin kt ln
D. Lin kt cng ha tr, c nng lng lin kt nh
Cu 1 : ng dng ca Calixarenes trong ngnh ht
nhn l:
A. Nguyn liu xc tc trong phn ng bom ht nhn
B. Tng ng v phng x nguyn t
C. Thu hi cht thi phng x.
D. Tt c u ng
p n C.
Gii thch: l thuyt slice 49 chng Vt liu siu
phn t
Cu 2: trong y hc, Calixarenes c dng trong:
A. Chp tia X
B. H tr m lasik
C. Chp MRI
D. Tt c u ng
p n C.
Gii thch: l thuyt silce 53 chng vt liu siu
phn t
Cu 3: v sao Calixarenes c dng chp MRI:
A. V lm tng tn hiu cng hng v tng tng
phn
B. Do Calixarenes d tm v r
C. V lm tng tn hiu cng hng v gim tng
phn
D. V lm gim tn hiu cng hng v gim tng
phn
p n A
Gii thch: phn ng dung y hc ca Calixarenes slice
53 chng vt liu siu phn t
Cu 4: ch s K cho ta c ch bn ca vt liu siu
phn t, vy :
A. K cng ln th cng km bn
B. K cng ln th cng bn
C. K khng nh hng
p n A
Gii thch : l thuyt slice 25 chng chng vt liu
siu phn t
Cu 5: Calixaren c bn c to ra t cht no vi
HCHO:
A. Butanol
B. Phenol
C. Terbutin phenol
D. Butadien
p n C.
Gii thch: l thuyt slice 35 chng vt liu siu
phn t
Cu 6: : Calixaren c cu trc phn t khng gian
dng hnh g?
A. Hnh nn
B. Hnh cu
C. Hnh chic cc
D. Hnh lp phng
p n C
Gii thch: l thuyt slice 36 chng vt liu siu
phn t
Cu 7: ng dng no di y l ca Calixaren
A. Ha tan cht thi hu c
B. Loi Thy ngn ra khi mi trng c ln thy ngn
C. Ha tan mui cu vng
D. Loi lu hunh ra khi mi trng c ln lu hunh
p n B
Gii thch : l thuyt slice 42 chng vt liu siu
phn t
Cu 8: Trong cc cu di y, khi no th vt liu
siu phn t s bn nht:
A. ng knh macrocycle ln hn ng knh ion kim
loi
B. ng knh macrocycle nh hn ng knh ion kim
loi
C. ng knh macrocycle nm trn ng knh ion kim
loi
D. ng knh macrocycle nm trng vi ng knh
ion kim loi
p n D.
Gii thch: l thuyt slice 29 chng vt liu siu
phn t.
Cu 9: Calixaren c th tch c ion no di y:
A. Ag
+

B. Pb
2+

C. H
+

D. Cu
2+

p n D
Gii thch: l thuyt slice 50 chng vt liu siu
phn t.
Cu 10: Do u m cylodextrins c ng dng lm
thuc trong y hc:
A. L mt cht c ch trong qu trnh troa i cht c th
ngi
B. Khng c, r
C. Gii phng chm thuc
D. Cu B v C ng
E. Tt c u ng
p n D
Gii thch: l thuyt slice 55 chng vt liu siu
phn t.
Cu 1. Tnh ton khi lng khung xe p qua cc
loi vt liu sau : Nhm ( khi lng ring l
2,7g/cm
3
) Titan ( khi lng ring l 4,5g/cm
3
) .Bit
khung thp nng 20kg v c khi lng ring l 7,8
g/cm
3
.
A. nhm 6,5kg v titan 9kg
B. nhm 6,92kg v titan 11,54kg
C. nhm 7kg v titan 11kg
D. nhm 11,54kg v titan 6,92kg
Tr li :
Ta tnh th tch ca khung thp l : V = m/ = 20 x
1000/ 7,8 = 2564,1 (cm
3
)
T ta tnh c khi lng khung xe qua cc vt
liu nhm v titan nh sau :
- Khi lng khung nhm l : m
nhm
= V.
Nhm
=
2564,1 x 2,7= 6923,07g = 6,92307kg.
- Khi lng khung Titan l: m
titan
= V.
titan
= 2564,1 x
4,5= 11538,45g = 11,54kg.

Chn p n B

Cu 2. Polime no sau y c dng phn nhnh?
A. Polivnylclorua
B. Amilo pectin
C. Polietylen
D. Polimetyl metacrylat
Chn p n B
y l hnh nh v polime amilopectin :

Cu 3. Khi trng ngng 30g Glyxin, thu c mg
polime v 2,88g nc. Gi tr ca m l?
A. 12g
B. 11,12g
C. 9,12g
D. 27,12g
Tr li :
nH2NCH2COOH>[HNCH2CO]n+nH
2O
mol glyxin = mol H2O
s mol glyxin dng a = 30/75 = 0,4 mol
s mol H
2
O thu c = 2,88/18 = 0,16 mol
==> hiu sut phn ng = 0,16*100/0,4 = 40%
==> khi lng glyxin phn ng = 30*0,4 = 12g
khi lng polyme = 12 - 2,88 = 9,12g.
Chn p n C
Cu 4. T si axetat c sn xut t:
A. Visco
B. Vinyl axetat
C. Axeton
D. Este ca xenluloz v axit axetic
Chn p n D
Cu 5. Thc hin phn ng iu ch t axetat t
xenluloz (t l mt xch xenluloz triaxetat v
xenluloz iaxetat trong hn hp l 1 : 1). Bit rng
c 162 gam xenluloz ngi ta iu ch c 213,6
gam t axetat. Vy hiu sut chuyn ha l :
A. 85%
B. 74,16%
C. 75.16%
D. 80%
Tr li
xenlulozo---->taxetat.[C6H7O2(OCOCH3)3]
162---->288
m(xenlulozo)=(213,6*162)/288=120,15(g)
H=(120,15*100)/162=74,16%
Chn p n B.

Cu 6. Phn ng trng hp l phn ng:
A. Cng hp lin tip phn t nh (Monome) ging
nhau thnh mt phn t ln (Polime)
B. Cng hp lin tip phn t nh (Monome) ging
nhau thnh mt phn t ln (Polime) v gii phng
phn t nh
C. Cng hp lin tip phn t nh (Monome) thnh
mt phn t ln (Polime) v gii phng phn t nh
D. Cng hp lin tip phn t nh (Monome)
ging nhau hoc gn ging nhau thnh mt phn
t ln (Polime).
Gi :
nh ngha: Trng hp l phn ng cng hp lin tip
nhiu phn t nh (monome) to thnh phn t ln
(polime). Phn ng trng hp khng gii phng cc
sn phm ph phn t nh, cc mt xch c s l c
cng thnh phn vi monome ban u.
Cu 7. tng hp 120kg poli(metyl metacrylat) vi
hiu sut ca qu trnh ho este l 60% v qu trnh
trng hp l 80% th cn lng axit v ru l:
A. 235kg v 90kg
B. 90kg v 235kg
C. 215kg v 80kg
D. p n khc
Tr li :
CH2=C(CH3)-COOH + CH3OH --60%->
CH2=C(CH3)-COOCH3 ----80%--> poli metyl
metacrylat
Khi lng acid cn dng l : m
acid
= 120x86/100 x
100/60 x 100/80 = 215kg.
Khi lng ru cn dng l : m
ru
= 120x32/100 x
100/60 x 100/80 = 80kg .

Chn p n C

Cu 8. Tm cu ng trong cc cu sau :
A. phn t polime do nhiu phn t nh (gi l
mt xch) lin kt vi nhau to nn
B. monome vad mt xch trong phn t polime
ch l mt
C. si Xenluloz c th b depolime ha khi b
un nng
D. cao su lu ha l polime thin nhin ca
isopren
Cu 9. t chy hon ton m gam cao su isopren
c lu ha bng khng kh va (cha 20% O
2
v
80% N
2
), lm lnh hn hp sau phn ng ngng t
ht hi nc th thu c 1709,12 lt hn hp kh
(ktc). ng kh ny lm ny tc dng va ht vi
dung dch cha 0,1 mol Br
2
. Xc nh m.
A. 159,6 gam
B. 159,4 gam
C. 141,1 gam
D. 141,2 gam

Tr li : Ta c: n
hh kh
= 76,3 mol

SO
2
+ Br
2
+ 2H
2
O --> H
2
SO
4
+ 2HBr

=> nSO
2
= 0,1mol

Gi x l s mol C
5
H
8


C
5
H
8
+ 7O
2
--> 5CO
2
+ 4H
2
O

=> nO
2
= 7x => nO
2
ban u = (7x + 0,1) => nN
2
=
4(7x + 0,1)

=> 28x + 0,4 + 5x = 76,2 => x = 75,8/33

=> m = 68*75,8/33 + 3,2 = 159,4 gam
Chn p n B
Cu 10. Polime no c th tham gia phn ng cng?
A. Polietilen
B. Cao su t nhin
C. Teflon
D. thy tinh hu c
Cu 1: c im cu to ca monomer tham gia phn
ng trng hp l:
a. C lin kt kp
b. C s lien hp cc lin kt kp
c. C t hai nhm chc tr ln
d. C hai nhm chc u mch phn ng c vi nhau
p n A
Cu 2: in cc t v cm t thch hp cho sn vo
cc khong trng trong cc cu sau:
Polime l nhng cht c .. rt ln, do nhiu.. lin
kt vi nhau ta nn. Polime gm 2 loi polime thin
nhin v polime.. , polime thng l ., khng
bay hi, hu ht .trong nc v cc dung mi thng
thng bn vng trong t nhin.
a. Mt xch
b. Khng tan
c. Cht lng
d. Phn t khi
e. Tng hp
f. Cht rn
p n: d-a-e-f-b
Cu 3: c im cu to ca monomer tham gia phn
ng trng ngng l:
a. C hai nhm chc tr ln
b. C hai nhm chc khc nhau
c. C hai nhm chc ging nhau
d. C hai nhm chc ging nhau hoc khc nhau

p n A
Cu 4: hai cht no di y tham gia phn ng trng
hp vi trng ngng vi nhau to t nilon -6,6:
a. Acid picric v etylen glycol
b. Acid piric v hexametylendiamin
c. Acid adipic v hexametylendiamin
d. Acid glutamic v hexametylendiamin

nH
2
N-[CH
2
]
6
-NH
2
+nHOOC-[CH
2
]
4
-COOH -> -(NH-
[CH
2
]
6
-NH-CO-[CH
4
]-CO)- +2nH
2
O

p n C
Cu 5: phn t khi trung bnh ca PVC l 750.000.
vy h s polymer ha ca PVC l:
a. 12.000 b.15.000 c.24.000
d25.000
M=62,5
H s = 750.000/M=12000
p n A
Cu 6: iu ch 100g thy tinh hu c th cn bao
nhiu gr ru metylic v bao nhiu gr acid metacrylic,
bit hiu sut qu trnh t 80%:
a. Acid 68.8g, ru 25,6g
b. Acid 86g , ru 32g
c. Acid 107,5g , ru 40g
d. Acid 107,,5g ru 32g
Gii:
CH
3
OH+ CH
2
=C(CH
3
)COOH ->
CH
2
=C(CH
3
)COOCH
3
+ H
2
O
n
thy tinh hu c
=1mol
n
ru
=n
acid
=1*5/4=1.25 mol
m
ru
=40g v m
acid
=107,5 g
p n C
Cu 7 : polietilen c trng hp t etilen. Hi 280
gr polietilen trng hp c bao nhiu phn t
etilen ??
a. 5. 6,02. 10^23
b. 10. 6,02. 10^23
c. 15. 6,02. 10^23
d. Khng xc nh c
S phn t etilen =n. s avogaro=280/28 *
6,02.10^23=10*6,02.10^23 phn t
Dp n B
Cu 8 : mt on mch PVC c khong 1000 mc
xch. Hy xc nh s lng ca on mch :
a. 62.500 dvc
b. 625.000 dvc
c. 125.000 dvc
d. 250.000 dvc
S lng l : M*1000=62,5*1000=62500
Dp n A
Cu 9 : ch to nha rezol, ngi ta lm :
a. un nng hn hp phenol v fomandehit theo t l 1 :2
c xc tc kim
b. un nng hn hp phenol v fomandehit theo t l 1 :2
c xc tc acid
c. un nng hn hp phenol v fomandehit theo t l
1 :1,2 c xc tc kim
d. un nng hn hp phenol v fomandehit theo t l
1 :1,2 c xc tc acid
p n C
Cu 10 : iu ch cao su buna, ngi ta c th
thc hin theo s bin ha sau :
ancol etylic-> butadien-1,3-> cao su buna
Trong H
1
= 50%, H
2
=80%
Tnh khi lng ru cn ly c th iu ch c
5,4g cao su buna theo s trn
a. 23g
b. 46g
c. 11.5g
d. 34.5g
Dp n A
T vit pt -> n
cao su buna
= 0.1 mol
n
ru
=0.1 5/4 .4=0.5 mol
m
ru
=23g
Cu 11 :trng ngng acid c-aminocaproic thu c m
gr polyme v 12,6g nc vi hiu sut 90%. Vy m
bng bao nhiu ??
a. 71,19g b.79,1 g c.91,7 g
d.90,4 g
Gii :
H
2
N-[CH
2
]
5
COOH-> -(NH-[CH
2
]
5
-CO)- +H
2
O
n
nc
=0,7 mol
H=90% ->m
polyme
=0,7*113=79.1g
p n B
Cu 12: nha rezit c iu ch bng cch no??
a. un nng nha rezol 150
o
C to mng khng
gian
b. un nng nha novolac 150
o
C to mng khng
gian
c. un nng nha novolac vi lu hunh 150
o
C to
mng khng gian
d. un nng nha rezol vi lu hunh 150
o
C to
mng khng gian
p n A
1.khi nim ng v polime l :
A. polime l hp cht c to thnh t cc phn t
ln.
B.polime l hp cht c to thnh t cc phn t c
phn t khi nh hn
C.Polime l sn phm duy nht ca phn ng trng
hp hay trng ngng
D.polime l hp cht cao phn t gm n mc xch to
thnh
2.polime c tng hp t etilen. Hi 280g polietilen
dc trng hp t ti thiu bao nhiu etilen.
A.3,01 .10^24 B.6,02.10^24 C.6,02 .10^23
D.10
3. cho sn phm khi trng hp 1 mol etilen iu
kin thch hp tc dng va vi 16g Brom. Hiu
sut trng hp v khi lng PE thu c l :
A.80%;22,4 g B.90%;25,2g C.20%;25,2 g
D.10% ;28g
4.tin hnh phn ng trng hp 5,2 g stiren, sau phn
ng ta thm vo 400ml dung dch nc Brom
0,125M, khuy u cho phn ng xy ra hon ton
thy d 0,04mol Br. Khi lng polime sinh ra l :
A.4,16g B.5,2 g C.1,02g D.2,08 g
5.hai cht no sao y tham gia phn ng trng ngng
vi nhau to nilon 6,6.
A. Acid Adipic v etilen glycon
B.Acid pucric v hexametyleniamin
C. Acid Adipic v hexametyleniamin
D.Acid Glutamic v hexametyleniamin
6.sp xp cc vt liu theo bn tng dn:
A. ng than nano, thp, graphene, polymethyl
methacrylate, kim cng
B. ng than nano, polymethyl methacrylate,
thp,graphene, kimcng
C. thp, ng than nano ,polymethyl methacrylate,
kimcng,graphene
D.polymethyl methacrylate,thp,ng than
nano,graphene,kimcng
7.tnh khi lng ring ca 1m vung graphene bit
rng graphene c ng sut ct l 42N/m. dy ca
mt lp Graphene l ng knh ca nguyn t
cacbon v bng 0,335 nm.
A.1,41 x10
6
mg/m
2
B.1,25x10
6
mg/ m
2

C . 4,2 x 10
6
D.3,35x 10
6

8.mt mt phng song song vi trc Z v ct trc ox
v oy ln lt ti ta l 2,3. Ch s Miner ca mt
phng l :
A.(2,3,0) B.(3,2,0) C.(

,0 )
D.(

,0)
9.tnh cht no sau dy khng phi ca graphene
A.graphene hu nh trong sut v ch hp th 2,3%
cng nh sng.
B.Graphen dn nhit tt hn ng
C.Graphene c kh nng dn in
D.Graphene c bn cao hn kim cng
10.tnh cht ca xiclodextrin gip cho sn phm c
cha n c tnh cht .chn cu tr li sai :
A. t ht m
B.n nh tnh cht khi c s thay di nhit , nh
sng , PH
C. loi b cholesterol ra khi cc sn phm thc phm
D.loi b nhng mi khng mong mun ra khi sn
phm thc phm.
11. khi lp phng tm th c my nguyn t trn
mt mng :
A.1 B.2 C. 3 D.4
BI GII:
1.B
2.
khi lng phn t polyetilen l 280 g
khi lng 1 monomer ca polyetilen l : (CH
2

CH
2
) :28
s phn t etilen cn s dng l : 280/18 =10 (phn t
)
3.s mol Brom :
n
Br = 16/80 = 0.2 (mol)= s mol
etilen cn d .
Ta c s mol eti len tham gia phn ng l :1-
0,2 =0,8.
Vy hiu sut l : %H =

x 100% = 80%
Khi lng PE thu c l : 28 x 80% =22,4 (g)
p n A.
4.s mol Brom l :
n
Br =CM x V =0,125 x 0,4 = 0,05
(mol)
S mol Brom tham gia phn ng vi styren d l :
n
Br
pu
=0,05 0,04 = 0,01 (mol) = s mol styren d
sau khi phn ng trng ngng.
S mol stiren l :
n
C
8
H
8
= 5,2 /104 =0,05 (mol)
S mol stiren tham gia trng ngng : 0,05 0,01
=0,04 (mol) = s mol polystiren
Khilng polystiren thu c l : 0,04 x 104 = 4,16
(g)
p n : A
5.C
6.A
7.ta c: ng sut ct l kt qu khi lc tc ng ln
sn phm m gy ra bin dng trt ca vt liu trn
mt mt phng song song vi hng tc ng ca lc
p vo. Cng thc tnh ng sut ct trung bnh l:

vi
= ng sut ct
F = lc tc dng
A = din tch mt ct ngang
Ta c :42N = 4,2Kg
Din tch mt ct ngang l : m
2
Khi lng ring ca graphene l : = m/S = 4,2/1
=4,2kg/ m
2
=4,2 x 10
6
(mg/ m
2
)
8. mt mt phng song song vi trc Z nn coi nh
ct z ti v cng v ct trc ox v oy ln lt ti ta
l 2,3.
1/x=1/2; 1/y =1/3; 1/z = 0
qui ng mu s : 1/x =3/6 ; 1/y =2/6; 1/z = 0
(3,2,0)
9.D 10.A 11.B
Cu1:Pht biu no sau y l ng.
A. Ancol o-hiroxibenzylic l sn phm trung gian
trong qu trnh iu ch nha novolac t phenol v
fomanehit.
B. T nilon-6,6 thuc loi t poliamit, iu ch bng
phn ng ng trng hp cc monome tng ng.
C. T visco, t xenluloz axetat, t nitron cng thuc
loi t nhn to.
D. Cao su buna-S thu c khi cho cao su buna tc
dng vi lu hunh.
Tr li: B sai v nilon-6,6 iu ch bng phn ng
ng trng ngng.
C sai v t nitron l t tng hp ch khng phi t
nhn to
D sai v cao su buna - s thu c khi cho cao su buna
tc dng vi Stiren ch khng phi lu hunh
cn nu khng mun i vng m chn trc tip lun
th
Da vo c ch suy ra, ban u l c ch cng
nucleophin (AN), ging kiu phn ng ngng t
croton( cng ri li tch), sau mi polime ha, xc
tc l axit hoc bazo, vi xc tc khc nhau th c ch
cng s khc nhau. (ci c ch ny ni th di dng,
c giy v mt ) nhng m ni chung th giai on
u n s to dn xut metylol bao gm c o-
hidroxibenzylic v p-hidroxibenzylic => A ng
Cu 2: Khi t chy mt polime sinh ra t phn ng
ng trng hp isopren vi acrilonitrin bng lng
oxi va thu c hn hp kh cha 58,33% CO2
v th tch. T l mt xch isopren vi acrilonitrin
trong polime trn l:
Bi son cu hi n tp [Type the document title]

85

A. 1:3
B. 1:2
C. 2:1
D. 3:2
Tr li:t nC
5
H
8
=x,nC
3
H
3
N=y.
Pt t chy :
C
5
H
8
->5C0
2
+4H
2
O
C
3
H
3
N->3CO
2
+ 1,5H
2
O +0,5N
2

ta c: (5x+3y)/(9x+5y)=0,5833
->y=3x
Cu 3: iu ch 53,46 kg xenlulozo trinitrat(hiu
sut 60%) cn dng V lt axit nitric 94,5%( D=1,5
g/ml) phn ng vi xenlulozo d. gi tr ca V l
A. 60 B. 24 C.
36 D. 40
D thy V = 53,46 : 297. 3 . 63: 0,945 : 1,5 : 0,6 =
40 lit
Chn D
Cu 4: ng trng hp etilen v isopren thu c
polime X. t 39g X cn 90,72 lt O2 (dktc). T l
s mt xch etilen : isopren l:
A. 1:2
B. 2:3
C. 1:3
D. 3:2
Tr li : T l s mt xch etilen : isopren = k --> X
= (C
2
H
4
)
k
C
5
H
8


C
2k+5
H
4k+8
+ (3k + 7)O
2
--> (2k + 5)CO
2
+ (2k +
4)H
2
O
(28k + 68)__ (3k + 7)
___ 39 _____ 4.05

--> k = 2/3 -->(B)

Cu 5: Polime X l sn phm ng trng hp ca
stiren v 1 anken Y. Phn t khi ca X l
198000dvC c t l s mt xch ca stiren : Y l 3:2.
t khc t 39,6g X cn 87,36 lt O2 (dktc). Tng s
phn t stiren v Y to nn 1 phn t X l: /:
2500
X = [(C
8
H
8
)
3
(C
n
H
2n
)
2
]
a


C
2n+24
H
4n+24
+ (3n+30)O
2
---> (2n + 24)CO
2
+ (2n +
12)H
2
O
(28n + 312)___(3n + 3)
__ 39.6 _______3.9

--> n = 3 --> X = [(C
8
H
8
)
3
(C
3
H
6
)
2
]
a


M
X
= (104*3 + 42*2)a = 198000 --> a = 500

--> Tng s phn t stiren v Y to nn 1 phn t X
= (3 + 2)*500 = 2500
Cu 6: X l 1 loi cao su khi tc dng vi dung dch
HCl d thu c sn phm cha 57,258% clo. X
l:A. Cao su Buna
B. Cao su isopren
C. Cao su clopren
D. Cao su Buna - S.
Tr li :Ta c phn ng ca HCl vi Cao su l phn
ng cng
Nu trong X khng c Clo

%Cl = 35,5X+36,5
X = 25,5 loi

Nu trong X c Clo
% Clo = 35,5(x+1)X+36,5
x=1 X = 87,5 $-(CH_2-CCl=CH-CH_2)- : cao
su Clopren (C)
Cu 7: Cao su lu ha cha 2%S. Tnh xem,
khong bao nhiu mt xch isopren c mt cu ni
iunsua -S-S-, gi thit S thay th cho H nhm
metylen trong mch cao s
Tr li : Ta c cng thc ca cao su
isopren (C5H8)n.
(C5H8)n+2SC5nH8n2S2
==> mS=64
khi lng cao su = 68n + 62
==> %S =6468n+62=0,02 ==> n = 46
Bi son cu hi n tp [Type the document title]

86

Cu 8: Khi tin hnh ng trng hp buta- 1,3- ien
v stiren thu c 1 loi polime l caosu buna- S.
em t 1 mu cao su ny ta nhn thy s
mol O2 tc dng bng 1,325 ln s mol CO2 sinh
ra. Mt khc khi cho 19,95 gam mu cao su ny lm
mt mu ti a m gam brom. Gi tr ca m l:
A.36,00.
B. 42,67.
C. 39,90.
D. 30,9
A. Tr li: Ta gi CTPT ca polimer nh
sau (C4H6)nC8H8
Phn ng t chy
: C4n+8H6n+8+(5,5n+10)O2(4n+8)CO2+(3n+4)
H2O
Theo 5,5n+104n+8=1,325n=3
Trong 19,95g cao su c n=0,075(mol) vit phn ng
ra th c nBr2=3ncaosum=36g.(A)

1. Thnh phn chnh ca nha bakelit l:
A- Polistiren.
B- Poli(vinyl clorua).
C- Nha phenolfomanehit.
D- Poli(metyl metacrilat).

2. Nha phenolfomanehit c cu trc:
A- Mch thng.
B- Mch nhnh.
C- Mch khng phn nhnh.
D- Mng khng gian.
3. Nha phenolfomanehit c iu ch bng
cch:
A- un nng phenol vi fomanehit ly d,
xc tc baz.
B- un nng fomanehit vi phenol ly d,
xc tc baz.
C- un nng fomanehit vi phenol ly d,
xc tc axit.
D- un nng phenol vi fomanehit ly d,
xc tc axit.
4. T ho hc l t:
A- C sn trong thin nhin.
B- c sn xut t polime thin nhin
nhng c ch bin thm bng con
ng ho hc.
C- c ch bin bng phng php ho
hc.
D- c sn xut t nhng polime tng hp.
5. c im cu to ca t:
A- Gm nhng phn t polime mch thng.
B- Gm nhng phn t polime sp xp song
song dc theo mt trc chung.
C- Gm nhng phn t polime xon li vi
nhau.
D- C A, B, C.
6. T nitron thuc loi t:
A- Poliamit.
B- Polieste.
C- Vinylic.
D- Thin nhin.
7. Polime no c cu trc mch thng ?
A. Xenlulozo (chn)
B. Amilopectin
C. Cao su luu hoa
D. Ca a,b,c
8. c im cu to ca nonome tham gia phn ng
trng hp:
A. C lien kt kp (chn)
B. C s lien hp gia lien kt kp
C. C t 2 nhm chc tr ln
D. C 2 nhm chc u mch
9. Polime no c tnh cch in tt,bn c dng lm
ng che nc,vi che ma
a. Cao su thin nhin
b. Thy tinh hu c
c. Polivynylclorua (chn c)
d. Polietilen
10. Poliisopren khng tham gia phn ng:
a. epolime ha
b. Tc dng vi dd br
c. Tc dng vi dd NAOH (chn)
d. u hunh
1. Th no l ng v phng x:
a. C cng s proton v norton.
b. Cng s proton, nhng khc s Norton
c. C s khi bng nhau
d. C s khi khc nhau
2. Cht c 18 cnh v s oxi c tn gi l g?
a. 18_ crown 6
b. i benzo_18 crown6
c. 6_crown 18
Bi son cu hi n tp [Type the document title]

87

d. Khng c p n no .
3. Trong cyclodextrin c chia lm 3 th nhm
_cyclodextrin c my glucose?
a. 6
b. 7
c. 8
d. 9
4. C my phng php sn xut Carbon
nanotubes ( CNTs) v k tn cc phng php ?
a. 2 phng php: phng h quang in v ngng t
hi ha hc
b. 3 phng php : phng h quang in, ngng t hi
ha hc v bo mn bng laser
c. 4 phng php : phng h quang in, bo mn
bng laser, ngng t hi ha hc v phn hy
CO di nh sang cao.
d. 1 phng php : phng h quang in
5. Ging cy tiu biu v quan trng, chim 90-97%
trn ton th gii l?
a. Hevea braailiensis
b. Manihot
c. Sapium
d. Euphorbia
6. Hy trnh by phng php chnh dng xc nh
phn t khi ca cao su:
a. Php o thm thu
b. Php o nht v php siu ly tm
c. Khuch tn nh sng
d. C 3 phng n trn
7. C my cch phn loi polymer
a. 2 phng php : phn loi theo phng php tng
hp v theo cu to ha hc
b. 3 phng php : phn loi theo phng php tng
hp, theo cu to ha hc v theo tnh cht
c. 4 phng php : phn loi theo phng php
tng hp, theo cu to ha hc, theo tnh cht v
theo lnh vc ng dng.
d. Ch c 1 phng php duy nht l theo cu trc
ha hc
8. Vitone c tng hp t monomer no?
a. Hexafluoropropene v vinylidene fluoride
b. Styrene v 1,3- butadiene
c. Isobutylene v isoprene
d. Khng th tng hp c cht trn
9. Cryptands 211 c chn lc cao nht i vi ion
no?
a. Na
+

b. K
+

c. Rb
+

d. Li
+

10. Mt cryptands c : n=1, m=2. Cryptands c tn gi
l g?
a. Cryptands 221
b. Cryptands 212
c. Cryptands 112
d. Cryptands 121
1. Cryptands c kch thc trung bnh cho chn lc
r nht i vi:
A. Kim loi kim v kim loi kim th
B. Lim loi lng tnh
C. Kim loi ha tr I
D. Kim loi ha tr II
p n: A. Cryptands c kch thc trung bnh cho
chn lc r nht i vi Kim loi kim v kim
loi kim th
2. KOCH
3
phn ng vi o- and m-dichlorobenzene khi
c mt:
A. 18-crown-6
B. Dithia-18-crown-6
C. Diaza-18-crown-6
D. 12-crown-4
p n: A. KOCH
3
phn ng vi o- and m-
dichlorobenzene khi c mt 18-crown-6
3. Dng Frenkel v dng Schottky thuc dng sai lch
no:
A. Sai lch mng tinh th
B. Sai lch im
C. Sai lch ng
D. Sai lch mt
p n: . Dng Frenkel v dng Schottky
thuc dng sai lch im.
4. Mt mt mng ct 3 trc x, y, z ln lt ti 1/2, 3/2,
1. Ch s Miller l:
A. 132
B. 623
C. 221
D. 621
Bi son cu hi n tp [Type the document title]

88

p n: . 623
Ct 3 trc x, y, z ti 1/2, 3/2, 1.
Nghch o li ta c (2, 2/3, 1)
Quy ng mu s (6, 2, 3)
Ch s Miller l (623)
5. K hiu phng l:
A. L cc s nguyn nh nht ng vi ta ca
nguyn t u tin i qua gc ta v vung gc
vi phng cho
B. L cc s nguyn nh nht ng vi ta ca
nguyn t u tin i qua gc ta v song song
vi phng cho
C. L cc s nguyn ln nht ng vi ta ca
nguyn t u tin i qua gc ta v vung gc
vi phng cho
D. L cc s nguyn ln nht ng vi ta ca
nguyn t u tin i qua gc ta v vung gc
vi phng cho
p n: . K hiu phng l cc s nguyn nh
nht ng vi ta ca nguyn t u tin i qua
gc ta v song song vi phng cho
6. i vi lin kt ha tr, nng lng lin kt:
A. Ln
B. Nh
C. Trung bnh
D. Ty thuc vo nguyn t
p n: D. i vi lin kt ha tr, nng lng lin
kt ty thuc vo nguyn t.
7. Thnh phn chnh ca T lapsan l:
A. Poly (etylen terephtalat)
B. Poliacrionitrin
C. Policaproamit
D. Poli (vinylaxetat)
p n A. Thnh phn chnh ca T lapsan l:
Poly (etylen terephtalat)
8. Thnh phn chnh ca T olon l:
A. Poly (etylen terephtalat)
B. Poliacrionitrin
C. Policaproamit
D. Poli (vinylaxetat)
p n: A. Thnh phn chnh ca T olon l:
Poliacrionitrin
9. Thnh phn chnh ca T olon l:
E. Poly (etylen terephtalat)
F. Poliacrionitrin
G. Policaproamit
H. Poli (vinylaxetat)
p n: A. Thnh phn chnh ca T olon l:
Poliacrionitrin
10. Phn ng tng hp T lapsan l:

A.



B.


C.

D.
p n: . Phn ng tng hp T lapsan
(axit terephtalic v etylenglicol)

Cu 1: Vt liu Quantum dot l vt liu nano
khng chiu kiu no?
A. OD
B. QD
C. QO
D. OQ
n n: A
Cu 2: Cu no di y l cc ng dng ca vt
liu nano?
Bi son cu hi n tp [Type the document title]

89

A. Dc liu. bnh xt cn trng, m phm thm
xu, vt liu chng nc
B. Dn xut dc liu, cht lm sch ty u b
bi, vi Nano, vt liu chng nc
C. Dc liu, knh t sch, bng , linh kin
in t, kem chng nng
D. Dn cut dc liu, bng , bnh xt cn
trng, kem chng nng
p n: B
Cu 3: Phng php no di y dng ch
to vt liu nano?
A. Ha hc
B. Vt l
C. C hc
D. Tt c u ng
p n: D
Cu 4: PS l loi polymer c tng hp t cng
thc no di y?
A. C
2
H
3
Cl
B. C
8
H
8

C. C
2
H
4

D. C
2
H
4
O
n n: B
Cu 5: c im ca phn ng khu mch
polymer l g?
A. To ra cc cu ni gia cc chui polimer,
thng l nhm metylen.
B. Nhm to thnh cc mch di hn.
C. Nhm to thnh mng li khng gian.
D. Tt c cc cu trn.
p n: D
Cu 6: C bao nhiu lc lin kt gia cc nguyn
t v ion?
A. 2
B. 3
C. 4
D. 5
p n: C (Lin kt kim loi, lin kt ion, lin kt
cng ha tr, lin kt th cp (lin kt Van der
Waals, Lin kt hydro)).
Cu 7: Trong cc trng hp di y trng
hp no lm nng lng lin kt trong vt liu
gim?
A. Vt liu c tnh nh hng
B. Cu trc ri rc, phn b ngu nhin
C. Cu trc xp cht trt t
D. C A v C
p n: D
Cu 8: Vt liu no l v nh hnh?
A. Nc, thy tinh
B. Polymer, thy tinh soda
C. Thy tinh soda
D. Polymer nc
p n: B
Cu 9: Lin kt no l ca vt liu siu phn t?
A. Lin kt tnh in, lin kt ion-ion, lin kt
hidro
B. Lin kt tnh in, lin kt lng cc. lin kt
ng trc.
C. Lin kt tnh in, lin kt hidro, lin kt ion-
lng cc.
D. Lin kt tnh in, lin kt hidro, lin kt
ng trc.
p n: D
Cu 10: Cng thc no l ca t nilon 6?
A. (NH-[CH
2
]
6
-CO)n
B. (NH-[CH
2
]
5
-CO)n
C. (NH-[CH
2
]
6
-CH
2
)n
Bi son cu hi n tp [Type the document title]

90

D. (NH-[CH
2
]
5
-CH
2
)n
p n: A
Cu1: Cc htnanonocavobng, bng y t
(kcquno) chngnhimtrng?
a. ZnO
b. Ag
c. AlSiO
2

d. CeO
2

pn: b. Ag
Cc htnano Ag cavobng, bng y t(
kcquno) s lmtngmnh tin khngkhun do cc
ion bc c tc dngkha cc tboh hp ca vi
khunlmchtngtchng.
Cu 2:QD (Quantum Dot) lg?
a. mktt cc nguynt/phnt c kchthcnh ~
1-10nm.
b. C cutrckiuliv c dnghnhcu.
c. Lmtsiunguynt hay nanotinhth.
d. C 3 trn.
pn: d. c 3 trn
Quantum dotlhtnanortnh, c kchthc ~1-
10nm, cncgilnguynt nhn to,
siunguynt hay nguynt quantum
dot.uimnibtcanl c
ththayithayikchthchnhdng, cngnhs
lng electron trong n. C cutrcli v, VD:
QD CdSe/ZnSvicutrcli v c dnghnhcu,
liltinhthbndnCdSecbaobilpvlbndnZ
ns, ngknhli t 2 ti 10nm, v vdy t 0,5 ti
4nm. QD c thchtosao cho
mtsquangphtiuvinhiumuscm ta
mongmun.
Cu 3: Trong 1 kg go c cha 81% tinhbt c
baonhiumtxch?
a. 3 x 10
23

b. 4 x 10
21

c. 3 x 10
21

d. 3 x 10
24

pn: d. 3 x 10
24

81% tinhbt = 810g
Smtxch =

Cu 4: Tnhmtthtchcanhm, cho r = 0,143nm,
A = 27g/mol, cutrc FCC.
a. 8,89g/cm
3

b. 5,5g/cm
3

c. 2,7g/m
3

d. 3,4g/m
3

pn: c. 2,7g/m
3

mngcstheocutrc FCC c 4 nguynt.
Thtch maa5ng cstheobnknhnguynt R
V = a
3
=(2

Nn ta c

Cu 5: sphitrca Fe
2
O
3
lbaonhiu?
a. 3
b. 4
c. 5
d. 6
pn: c. 5

Vysphitr = 5.
Bi son cu hi n tp [Type the document title]

91

Cu 6: Tenanltngikhccachtno sau y?
a. Nilon - 6,6
b. Nilon -7
c. Polieste
d. Poliamit
pn: b. nilon - 7
Cu 7: cngthcno sau ylng?
a. Sepulchrate = sep = 1,3,6,8,10,12,16,19-
octaazabicyclo[6.6.6]eicosane
b. Sepulchrate = sep = 1,3,6,8,10,13,17,19-
octaazabicyclo[6.6.6]eicosane
c. Sepulchrate = sep = 1,3,6,8,10,13,16,19-
octaazabicyclo[6.6.6]eicosane
d. Ttcusai.
Cu 8: c myphngphptnghp vt liu
siuphnt?
a. 1
b. 2
c. 3
d. 4
pn: b.2 phngphptnghphuc v
phngphptngkhunkimloi.
Cu 9: tc ngtimnca cc htnano ENPs l?
a. Thihathnkinhnh Alzheimer v Parskinson.
b. Gy tc ngti cc cquankhugic trong no.
c. Tc nglnqutrnhngmu, hnhthnh cc u ht.
d. a,bung.
pn: d. a,bung.
Cu 10: cc ht CeO
2
b sung vodu diesel nhm?
a. gimkhthichi.
b. tngmctiu th nng lng.
c. c a v b ung
d. c a v b usai
e. pn: a. gimkhthichi. b sung
CeO
2
voduddieselnhmlmxc tc
gimkhthichi v gimmctiu th nng lng
lnti 10 % ( Envirox
TM
).


1.t chy ht 1 lng polietilen , sn phm chy
ln lt cho i qua bnh 1 ng H
2
S0
4
c v bnh 2
ng dung dch Ca(OH)
2
d thy khi lngbnh 1
tng m gam , bnh 2 c 100 g kt ta ,m bng bao
nhiu ?
A.18 B. 32 C. 36 D. 48
Gii:
nCO2 = 1 nH2O = 1
m = 18
2.Khi thy phn 500g mt plipeptit thu c 170g
alanin. Nu polipeptit c khi lng phn tl
50000 th c bao nhiu mt xch ca alanin ?
A. 175 B.170 C. 191 D.210
Gii
500(g) polipeptit ---------> 170(g) alanin
50000 (vc) ---------> ? (vc)
Khi lng phn t ca alanin ngvi 50000(vc)
ca polipeptit: (50000*170)/500= 17000 (vc)
Gi s mt xch ca alanin l x : (C
2
H
7
O
2
N)x <=>
89x= 17000 x =17000/89 = 191
=> p n C
3.Trng ngng hexametyleniamin 1,232 tn H
2
N-
(CH
2
)
6
-NH
2
v 1,460 tn axit aipic HOOC-(CH
2
)
4
-
COOH thu c bao nhiu kg t nilon bit hiu sut
phn ngl 90%. Cc phng n la chn.
a.2692 kg b.2186 kg c.2232 kg d.2034
kg
Bi son cu hi n tp [Type the document title]

92

Gii:
H
2
N-(CH
2
)
6
-NH
2
+ HOOC-(CH
2
)
4
-COOH
---> H
2
N-(CH
2
)
6
-NH-OC-(CH
2
)
4
-COOH +2 H
2
O

nH
2
N-(CH
2
)
6
-NH
2
= (1,232 *
1000)/116=10,62(mol).
nHOOC-(CH
2
)
4
-COOH = (1,460 *
1000)/146=10(mol)
so snh s mol gia nH
2
N-(CH
2
)
6
-NH
2
v nHOOC-
(CH
2
)
4
-COOH ta thy s mol nHOOC-(CH
2
)
4
-
COOH t hn m t l s mol phn ngl 1:1
nnnHOOC-(CH
2
)
4
-COOH phn ng ht.
M %H= 90%.
=>mH
2
N-(CH
2
)
6
-NH-OC-(CH
2
)
4
-COOH
=(10*(116+146-18*2))/100=2034(kg)

ti c ti 2 gc chc------>2H
2
O
4.Cho cc t sau: t nilon 6, t lapsan, poli(vinyl
axetat), t nilon-7, polistiren, PVC. S polime tc
dng c vi dung dch NaOH long, nng l:
A. 2 B.3 C.5 D.6
Gii:
iu kin phn ng NaOH long nng l xy ra
phn ng thy phn nn chn t nilon 6, t lapsan,
poli(vinyl axetat), t nilon-7,PVC. Chn p n C
5.Poli ( hexametylen adipamit) c iu ch
bng phn ng trng ngng gia :
A.Hexametylen v acid adipic
B.Hexametylen iamin v acid adipic
C.Hexametylen v acid dipic
D.Hexametylen va acid dipic
Gii:
Polime( hexametylen adipamit) hay nilon 6,6 c
iu ch t Hexametylen va acid dipic. Chn p n
D
6.Khi trn polime vi cht n thch hp thu c
vt liu c bn, chu nhit tng ln so vi
polime thnh phm. l g ?
A. Keo dn B. Compozit C. Nha do D. Cao
su
Gii:
Compozit c c khi trn polime vi cht n
thch hp thu c vt liu c bn, chu
nhit. tng ln so vi polime thnh phm. Chn
p n B.
7.Phn t trung bnh ca poli(hexametylen
adipamit) iu ch t nilon 66 l 30000 vC, ca
cao su t nhin l 105000 vC. Hy tnh s mc
xch ( tr s n) gn trong cng thc phn t ca mi
loi polime trn ?
A. 128 v 1634 B.130 v 1522 C.133 v 1544
D.135 v 1601
Gii:
S mc xch ca poli(hexametylen adipamit) l:
n = 3000/226 = 133 mc xch
S mc xch ca cao su t nhin l:
n = 105000/68 = 1544
Bi son cu hi n tp [Type the document title]

93

Chn p n C
8.Vt liu polime hnh si di v mnh c di
nht nh gi l g ?
A.T B.Cao su C.PVC D.Keo dn
Gii:
Theo nh ngha th Vt liu polime hnh si di v
mnh c di nht nh l t. Chn p n A
9.C bao nhiu vt liu c ch to t polime thin
nhin : t visco, t tm, nha bakelit, keo dn g, t
tm, phim nh ?
A.2 B.3 C.4 D.5
Cc loi vt liu c ch to t polime thin nhin
gm: t visco, t tm, phim nh.
Chn p n B
10.Nha Rezol c c khi un nng Phenol v
Fomandehit theo t l no :
A. 1:1 B.1:1,1 C.1:1,2 D.1:1,3
Gii:
Nha Rezol c c khi un nng Phenol v
Fomandehit theo t l 1:1,2 c xc tc kim. Chn
p n C.
Cu 1. Phn t trung bnh ca poli(hexametylen
adipamit) iu ch t nilon -6,6 l 45000 vc,
ca cao su t nhin l 115000 vc. Hy tnh s mt
xch (tr s n) gn trong cng thc phn t ca mi
polime trn.
Gii
S mt xch ca poli(hexametylen adipamit) l
n =
4500
199
226
= (mt xch)
S mt xch ca cao su t nhin l
n =
115000
1691
68
= (mt xch).
Cu 2. iu ch 800 kg polistiren cn bao nhiu
tn Stiren, bit rng hiu sut phn ng ca phn
ng l 80%.
A. 640 kg B. 700 kg
C. 650 kg D. 740 kg
Gii
nC
6
H
5
CH = CH
2
(-CH-(C
6
H
5
)-CH
2
-)
n
104n 104n
800 kg 800 kg
Khi lng stiren cn dng l m = 800 kg
V H =80 % nn
m =
800 80
640
100

= kg.
Cu 3. Cho s chuyn ha sau: CH
4


C
2
H
2

C
2
H
3
Cl PVC. tng hp 150kg PVC theo s
trn th cn V( m
3
) kh thin nhin ( ktc). Gi
tr ca V l (bit CH
4
chim 90% th tch kh thin
nhin v hiu sut c qu trnh l 60%)
A. 358,4
B. 448,0
C. 199,1
Bi son cu hi n tp [Type the document title]

94

D. 224,0
Gii
S phn ng:
2CH
4
C
2
H
2
C
2
H
3
Cl (C
2
H
3
Cl)
n

2.16 kg 62,5n kg
x = ? kg 150 kg
x =
2 16 150 100
128
62, 5 60
n
n

= kg
V
CH4
=
128
22, 4
16
= 179,2 m
3

V
kh thin nhin
=
100
179, 2
90
= 199,1 m
3

Cu 4. Polime c cu trc mng khng gian (mng
li) l
A. PE.
B. Amilopectin.
C. PVC.
D. Nha bakelit.
Gii
PE, PVC: mch thng.
Amilopectin: mch phn nhnh.
Nha bakelit: mng khng gian (mng li).
Cu 5. Pht biu no sau y l ng?
A. Trng hp stiren thu c poli(phenol-fomanehit).
B. Trng ngng buta- 1,3- ien vi acrilonitrin c xc
tc Na c cao su buna-N
C. Poli(etylen terephetalat) c iu ch bng
phn ng trng ngng cc monome tng ng.
D. T visco l t tng hp.
Gii
Trng hp stiren thu c polistiren (PS) loi
p n A.
ng trng hp buta- 1,3- ien vi acrilonitrin
(CH
2
=CHCN) c xc tc Na thu c cao su
bunaN oi p n B.
Poli(etylen terephetalat) c iu ch bng phn
ng trng ngng cc monome tng ng l
etylenglicol v axit terephtalic.
T visco l t bn tng hp (t nhn to) loi p
n D.
p n C.
Cu 6. Nhn xt v tnh cht vt l chung ca polime
no di y khng ng?
A. Hu ht l nhng cht rn, khng bay hi.
B. a s nng chy mt khong nhit rng,
hoc khng nng chy m b phn hy khi un
nng.
C. a s khng tan trong cc dung mi thng
thng, mt s tan trong dung mi thch hp to
dung dch nht.
D. Hu ht polime u ng thi c tnh do, tnh
n hi v c th ko thnh si dai, bn.
Cu 7. Sp xp th t thch hp tng ng vi cc
khong trng di y :
Bi son cu hi n tp [Type the document title]

95

Polime l nhng cht c..rt ln, do nhiu..lin
kt vi nhau to nn. Polime gm 2 loi polime
thin nhin v polime.., polime thng l..,
khng bay hi, hu ht..trong nc v cc dung
mi thng thng bn vng trong t nhin.
g. Mt xch
h. Khng tan
i. Cht lng
j. Phn t khi
k. Tng hp
l. Cht rn
A. d-a-e-f-b B. d-a-b-f-e
A. d-e-a-f-b D. d-a-e-b-f
Cu 8. Trng ngng acid c-aminocaproic thu c
m(g) polyme v 18,9g nc vi hiu sut 95%. Vy
m bng bao nhiu ?
b. 91,19g
c. 99,1 g
d. 101,7 g
e. 118,65 g
Gii
H
2
N[CH
2
]
5
COOH (NH[CH
2
]
5
CO) + H
2
O
n H
2
O = 1,05 mol
H = 95% m
polyme
= 1, 05 113 = 118,65 g.
Cu 9. iu ch 200g thy tinh hu c th cn
bao nhiu (g) ru metylic v bao nhiu (g) acid
metacrylic, bit hiu sut qu trnh t 90%:
e. Acid 122,01 g; ru 67,92 g
f. Acid 145,23 g; ru 70,01g
g. Acid 177,5 g; ru 71,04 g
h. Acid 190,92 g; ru 71,04g
Gii:
CH
3
OH + CH
2
=C(CH
3
)COOH
CH
2
=C(CH
3
)COOCH
3
+ H
2
O
n
thy tinh hu c
= 2 mol
n
ru
= n
acid
=
100
2
90
= 2,22 mol.
m
ru
= 71,04 g v m
acid
= 190,92 g.
Cu 10. Cc cht u khng b thy phn trong
dung dch H
2
SO
4
long, nng l
A. T capron; nilon-6,6; polietylen.
B. Poli (vinyl axetat); polietilen, cao su buna.
C. Nilon-6,6; poli(etylen-terrphtalat); polistiren.
D. Polietylen; cao su buna; polistiren.
Gii
+ T capron; nilon-6,6; thuc loi poliamit d b thy
phn trong mi trng axit loi p n A.
+ Poli (vinyl axetat) thuc loi polieste d b thy
phn trong mi trng axit loi p n B.
+ Nilon-6,6; thuc loi poliamit; poli(etylen-
terrphtalat) thuc loi polieste d b thy phn trong
mi trng axit loi p n C.
Cu 1: ch ra iu ng:
A. Polime l hp cht cao phn t
B. C. Polime l hp cht c kch thc phn t rt ln
C. Polime l hp cht m phn t gm nhiu mt xch
lin kt vi nhau.
D. D. Tt c u ng
Cu 2: hp cht no di y khng tham gia phn
ng trng hp?
Bi son cu hi n tp [Type the document title]

96

A. Axit aminoenantoic
B. B. Caprolactam
C. C. Metyl metacrylac
D. D. Buta-1,3-ien
Cu 3: t 150 kg metacrylat c th iu ch c m
kg thy tinh hu c(Plexiglas) vi hiu sut 90%.
Gi tr ca m l:
A. 135n B. 150 C.135
D. 150n
Cu 4: pht biu no sau y l ng?
A. T Visco l t tng hp
B. Trng hp buta-1,3-d9ien vi stiren c mt Na
c cao su buna-S
C. Trng hp stiren thu c poli(phenol-fomanehit)
D. Nilon-6,6 c iu ch bng phn ng trng hp
cc monome tng ng


Cu 5: khi H
2
SO
4
m c ri vo qun o bng vi
si bng, ch vi b en li do c sn phm to
thnh l
A. Cacbon.
B. S
C. PbS.
D. H
2
S
Cu 6: thy tinh plexiglas l polime no sau y?
A. Polymetyl metacrylat (PMM).
B. Polyme axetat (PVA).
C. Polimmetyl acrylat (PMA).
D. Tt c u sai.
Cu 7: cho cc polime sau: t tm, si bng, si
ay, t enang, t visco, nilon-6,6 , t axetat. S
polime c ngun gc xenluloxzo l:
A. 2
B. 3
C. 4
D. 5
Cu 8: c th phn bit cc dng lm bng da
tht v nhn to (PVC) bng cch no sau y?
A. So snh kh nng thm nc ca chng, da tht
d thm nc hn.
B. So snh mm mi ca chng, da tht mm mi
hn da nhn to.
C. t hai mu da, mu tht cho mi kht, cn da nhn
to khng cho mi kht.
D. Dng dao ct ngang hai mu da, da tht vt ct b
x, cn da nhn to th nhn bng.
Cu 9: un nng vinyl axetat vi kim iu kin
thch hp, ta thu c sn phm trong c:
E. Ancol vinylic
F. Ancol
G. Andehit axetic
H. Axeton
Cu 10: t lapsan thuc loi
E. T axetat
F. T Visco
G. T polieste
H. T poliamit
Cu hi 1: Ngoi ng dng lm thuc n th
xenlulonitrat cn c s dng lm g ?
A. Nha
B. Sp hoc nn
C. Sn
D. m phim chp nh( long no)
p n: D
Cu hi 2: Cao su nhn to u tin c tng hp
t cht no v u?
A. Polyvinyl clorua( Anh)
B. Axeton( Nga)
C. 1,2 dimetyl Butadien (c)
D. 2,3 dimety butadien (c)
p n: D
Cu hi 3: Australia, polymer c s dng nhiu
nht trong ngnh g?
A. in
B. Bao gi
Bi son cu hi n tp [Type the document title]

97

C. Xy dng
D. ni tht
p n: B (bao gi chim n 61% nm 1999)
Cu hi 4: Cc loi polymer thng dng c
thng mi ha:
A. PVA, PE, butadien
B. PVC, PVA, tinh bt
C. Protein, tinh bt, cao su buna
D. PVC, PE, nylon 6,6.
p n : D


Cu hi 5 : Trong cc cht ny : PVC, PE, PPF,
epoxi, poly metyl metacrylat. Cht no thng
s dng lm cht do :
A. PVC, PE, PVA
B. Tr epoxi
C. Tr PVC, PE
D. Tt c u ng.
p n :B( epoxi l cht keo dn, khng s dng
lm cht do)
Cu hi 6 : C my cch phn loi polymer ?
A. 2
B. 3
C. 4
D. 5
p n : C
Cu hi 7 : Polimer di mch ngoi nguyn t C th
cn cc nguyn t no na ?
A. Cl, Na, K
B. O,N,S
C. F,Br,I
D. Cs,O,S
p n : B

Cu hi 8 : Tc nhn cho phn ng cch mch
polymer l ?
A. Aixt, NaOH, nc
B. KaOH, p sut, nhit
C. Nc, nhit, nh sng, axit
D. Tt c ng
p n: C
Cu hi 9: Cc loi cao su thng dng t polymer:
A. Cao su buna, cao su buna-s
B. Cao su buna-N
C. Cao su isopren
D. Tt c cc loi trn
p n: D
Cu hi 10: Polymer c to nn nh lin kt no?
A. Cng ha tr
B. in kt ion
C. in kt hidro
D. in kt phi tr
p n: A
Bi 1: Ni kt tinh theo mng tinh th lp phng
tm mt v bn knh ca Ni l 1,24 . Khi lng
ring ca tinh th Ni l
A. 7,02 (g/cm
3
) B. 10,02 (g/cm
3
)
C. 8,04 (g/cm
3
) D. 9,04 (g/cm
3
)
li p n D

a=
;
P = 0,74
Khi lng ring ca Ni:
= 9,04
(g/cm
3
)
p n ng l p n D
Bi 2: c kht ca mng tinh th lp phng
tm khi l
A. 0,54 B. 0,58 C. 0,64
D. 0,68
li p n D

0
A
a
a
a 2 = 4.r
0
4 4.1, 24
3, 507( )
2 2
r
A = =
8 3 23
3.58, 7.0, 74
4.3,14.(1, 24.10 ) .6, 02.10

Bi son cu hi n tp [Type the document title]

98

S qu cu trong mt c s : 1 + 8.1/8 = 2
Tng th tch nguyn t trong c s

Th tch ca mt c s a
3

a
3

Vy p n ng l p n D.
Cu 3: Ch s Miller trong hnh di y l bao
nhiu?

A. (632) B. (123) C. (321)
D. (236)
li p n A
Mt phng ct trc x,y v z ti 1/3, 2/3 1.
Nghch o li ta c (3, 3/2, 1).
Quy ng mu s (6,3,2)
Ch s Miller l (632)
Vy p n ng l p n A.
Cu 4: Cng thc cu to sau y c tn gi l

A. Crytand 1,1,1 B. Crytand 1,2,1 C.
Crytand 2,1,2 D. Crytand 2,2,2
li p n D
Cch gi tn nh sau: Crytand m,m,n

Da vo m v n ta c tn gi ca cht trn l
Crytand 2,2,2 p n ng l p n D.
Cu 5: Cho phn ng tng hp vi pha long
cao nh sau:
3
4
2. .
3
r t
3
4 3
2. .( )
3 4
a t
= = = 68%
Bi son cu hi n tp [Type the document title]

99


Hy cho bit X c tn gi l
A. 1,2,10,3-tetraoxa-7,16-diazacyclooctadecane-
6,17-dione
B. 1,3,10,3-tetraoxa-7,16-diazacyclooctadecane-
6,17-dione
C. 1,4,10,3-tetraoxa-7,16-diazacyclooctadecane-
6,17-dione
D. 1,6,10,3-tetraoxa-7,16-diazacyclooctadecane-
6,17-dione
li p n C
Cu 6: Graphene c ng sut ct l 40 N/m. ng
sut ko l 340 N/m.
dy ca 1 lp graphene l ng knh ca
nguyn t cacbon l S
1
= 0,33 nm. Thp c ng sut
ct trong ngng 250 1200 MPa = 0,25 1,2.10
9

N/m
2
.
Sc bn ca Graphene (N/m
2
) so vi bn ca
thp chnh lch nhau nh bao nhiu ln?
A. 111 B. 121
C. 131 D.141
li p n B
ng sut ct ca graphene =
11 2
9
1
40
1, 21.10 /
. 1.0,33.10
P P
N m
S l S

= = =
(1)
ng sut ct ca thp = 0,25 1,2.10
9
N/m
2
Chn = 1.10
9
N/m
2

(2)
Vy ng sut ct ca graphene so vi ng sut ct
ca thp l:

11
9
(1) 1, 21.10
121
(2) 1.10
k = = = (ln)
p n ng l p n B
Cu 7: in tr tm 2D graphene 1m
2
c in tr
30O. dn in ca graphene l
A. 10
6
B. 10
7
C. 10
8

D. 10
9

li p n C
Ta c cng thc
1
.
T C
R l R
A o
= + (*)
Vi R
T
= 0, R
T
= 30 O, l = 1m
Thay s vo cng thc (*) ta c
.
T
l
R
A o
=
8
9
1
1
10 (1/ )
. . 30.1.0,33.10
T
l
m
R l S
o

= = = O
Vy p n ng l p n C.
X
Bi son cu hi n tp [Type the document title]

100

Cu 8: Poli (metyl metacrylat) v nilon-6 c to
thnh t cc monome tng ng l
A. CH
3
-COO-CH=CH
2
v H
2
N-[CH
2
]
5
-COOH
B. CH
2
=C(CH
3
)-COOCH
3
v H
2
N-[CH
2
]
6
-COOH
C. CH
2
=C(CH
3
)-COOCH
3
v H
2
N-[CH
2
]
5
-COOH
D. CH
2
=CH-COOCH
3
v H
2
N-[CH
2
]
6
-COOH
li p n C
Cu 9: Polime no sau y c to thnh bng
phn ng trng ngng?
A. (CH
2
CH
2
)
n

B. (OCH
2
CH
2
)
n

C. (OCH
2
CH
2
CO)
n

D. (CH
2
CH=CHCH
2
)
n

li p n C
Cu 10: Khi lng ca mt on mch t nilon
6,6 l 27346 vC v mt on t Capron l 17176
vC. S lng mc xch c trong on t nilon 6,6
v t Capron nu trn l
A. 113 v 152 B. 121 v 152 C. 131 v 114
D. 112 v 114
li p n B
Cu to ca cc t ng vi mt mc xch:
- Nilon 6,6: -HN(CH
2
)
6
NHCO(CH
2
)
4
CO-
C
12
H
22
O
2
N
2
c M = 226
S mc xch = 27346 : 226 = 121
- T capron: -HN(CH
2
)
5
CO-
C
6
H
11
ON c M = 113
S mc xch = 17176 : 113 = 152
Vy p n ng l p n B.
Cu 1: H s polymer l g? V sao phi dng h
s polymer trung bnh. Tnh h s polymer ha
ca PE, PVC v xenluloz bit rng chng ln
lt l 420000; 250000; 1620000.
A. 15000, 4000, 10000
B. 4000, 10000, 15000
C. 12000,5000,10000
D. p n khc
Tr li:
H s polymer l s mc xch gc monomer trong
phn t polymer
V polymer l hn hp phc tp gm nhiu polymer
cng loi nhng h s polymer ho ca chng khc
nhau nn ta phi t trng bng h s polymer trung
bnh n
H s trung bnh ca nha PE l
420000
15000
28
n = =
PVC (-CH2-CHCl-)n l :
250000
4000
62.5
n = =
Xenluloz ( C6H10O5) l :
1620000
10000
162
n = =
Chn cu A
Cu 2: Da vo gin , a ra nhn xt ?

Bi son cu hi n tp [Type the document title]

101

Da vo gin . chn lc cao nht ca K
xy ra nhm no ?
A. nhm [2.1.1]
B. nhm [2.2.1]
C. nhm [2.2.2]
D. nhm [3.2.2]
Gii
Nhn xt : da trn h s og K, chn lc gim,
bn gim.
nhm [2.1.1] chn lc cao nht i
+
v thp
nht Cs
+
.
nhm [2.2.1] chn lc cao nht Na
+
v thp
nht Cs
+
.
nhm [2.2.2] chn lc cao nht K
+
v thp
nht i
+
.
nhm [3.2.2] chn lc cao nht Rb
+
v thp
nht i
+
.
Cn cu C
Cu 3: Da nhn to (PVC) c iu ch t kh
thin nhin (CH4). Nu hiu sut ca ton b
qu trnh l 20% th iu ch 1 tn PVC phi
cn 1 th tch metan l
A. 3500 m
3

B. 3560m
3

C. 3584 m
3

D. 4560 m
3

Gii :
- S mol ca PVC :
1000
16( )
62.5
PVC
n mol = =
- V hiu sut qu trnh l 20% nn tac s mol ca
metan l:
16*100
80( )
20
mol = =
- S mol ca metan bng 2 ln so vi s mol ca
PVC: n= 80*2= 160 ( mol)
- Th tch ca metan l V= 160*22,4 = 3584 m
3

Chn cu C
Cu 4: iu ch caosu buna ngi ta c th
thc hin theo s sau:

Tnh khi lng ru etylic cn thit iu ch
c 54 gam caosu buna theo s ?
A. 92 g
B. 184 g
C. 115 g
D. 230 g
- S mol ca caosu buna
54
1
54
n mol = =
- S mol ca butadien-1,3 vi hiu sut 80%:
1*100
1.25
80
n mol = =
- S mol ca ru etylic vi hiu sut 50%:
1.25*2*100
5
50
n mol = =
- Khi lng ru etylic: m=5*46=230 g
Chn cu D


Cu 5: T 200 ml dung dch ancol etylic
33.33% (D 0.69 g/ml) iu ch c bao
nhiu g PE ( hiu sut 100%).
A. 22,5 g
B. 25 g
C. 28 g
D. 28.5 g
Gii :
Vi hiu sut 100% ta c :
Khi lng ca dung dch l m
dd
= 0.69*200 = 138
g
Bi son cu hi n tp [Type the document title]

102

Ta thy % *100
ct
dd
m
C
m
=
Nn
33.33*138
45.99
100
ct
m g = =
S mol ancol l n = 45.99/46 = 1 mol.
S mol ca PE l : n
PE
= n
ancol
= 1 mol.
Khi lng PE l m = 1*28 = 28 g.
Chn C

Cu 6: Pht biu no sau y l ng.
A. Ancol o-hiroxibenzylic l sn phm trung gian
trong qu trnh iu ch nha novolac t phenol v
fomanehit.
B. T nilon-6,6 thuc loi t poliamit, iu ch bng
phn ng ng trng hp cc monome tng ng.
C. T visco, t xenluloz axetat, t nitron cng
thuc loi t nhn to.
D. Cao su buna-S thu c khi cho cao su buna tc
dng vi lu hunh.
Tr li:
B sai v nilon-6,6 iu ch bng phn ng ng
trng ngng.
C sai v t nitron l t tng hp ch khng phi t
nhn to
D sai v cao su buna - s thu c khi cho cao su
buna tc dng vi Stiren ch khng phi lu hunh
Cu A ng


Cu 7: T 4 tn C
2
H
4
c cha 30% tp cht c
th iu ch bao nhiu tn PE? Hiu sut qu
trnh phn ng l 90%.
A. 2.55
B. 2.8
C. 2.52
D. 3.2
- ng C
2
H
4
nguyn cht trong 4 tnc cha 30%
tp cht l:
4*70
2.8
100
= tn
- S mol ca C
2
H
4
bng s mol PE:
2.8
0.1
28
mol =
- Khi lng PE vi hiu sut phn ng l 90% :
0.1*28*90
2.52
100
= tn
- Chn cu C

Cu 8: Trng hp propylen thu c PP. nu
t chy hon ton PP ta thu c 26400g CO
2
.
H s polymer l
B. 100
C. 200
D. 300
E. 400
- S mol CO
2
:
26400
600
44
mol =
- H s polymer cng chnh l S mol PP ( s mol PP
bng 1/3 s mol CO
2
) : 600/3 = 200
- Chn cu B

Cu 9: T 13kg axetilen c th iu ch c
bao nhiu kg PVC ( hiu sut phn ng 80%)
A. 62.5
B. 31.25
C. 25
D. 24.5
- S mol ca axetilen :
13
0.5
26
mol =
- S mol PVC bng s mol axetilen: 0.5 mol
- Khi lng PVC vi hiu sut 80%:
0.5*62.5*80
25
100
kg =
- Chn cu C

Cu 10: iu ch c 2.5 tn polystiren cn
bao nhiu tn stiren? Hiu sut 50%
A. 4
B. 5
C. 6
Bi son cu hi n tp [Type the document title]

103

D. p n khc
- Khi lng stiren :
2.5*100
5
50
= tn
- Chn cu B
Cu 1
Thc nghim cho bit pha rn, vng ( Au) c
khi lng ring l 19,4 g/cm
3
v c mng li lp
phng tm din. di cnh ca mng n v l
4,070.10
-10
m. Khi lng mol nguyn t ca vng
l: 196,97 g/cm
3
.Tnh phn trm th tch khng gian
trng trong mng li tinh th ca vng.
A. 13 B.48
C.26 D.52
Chn C
Gii:
S nguyn t trong mt c s
8*1/8 +6*1/2 = 4
Bn knh nguyn t vng :
4*r = a r = a /4 = 1,435.10
-8
cm
Th tch b chim bi cc nguyn t:
V
nguyn

t
= 4/3.t.r
3
= 4.4/3.3,14.(1,435.10
-8
)
3
= 5.10
-
23
cm
3
.
Th tch 1 n v:
V
1
= a
3
= (4,070.10
-8
)
3
= 6,742.10
-23
cm
3
.
Phn trm th tch khng gian trng:
(V
1
- V
nguyn

t
).100 / V
nguyn t
= 26%.
Cu 2
Xc nh ch s Miller ca mt i qua cc nt 200,
010 , 001 cu mng lp phng P.
A.(122) B.(111) C.(112) D.(211)
Chn A
Gii:
Mt mng i qua cc nt 200,010,001. Cc nt ny
nm trn cc trc ta .
A= 2
B= 1
C =1
Lp t s

Quy ng mu s (1,2,2)
Ch s Miller l (122)
Cu 3
phn loi polyme ta da vo
A. Theo ngun gc
B. Theo ngun gc, phn ng polime ha
C. Theo ngun gc, cu to
D. Theo ngun gc, cu to, phn ng polime ha
Chn D
Theo ngun gc : polime t nhin ,tng hp, nhn
to.
Theo phn ng polime ha: polime trng hp,
polime trng ngng
Theo cu to : cu to iu ha v khng iu ha.
Bi son cu hi n tp [Type the document title]

104

Cu 4
Calixarenes c ng dng trong cc lnh vc no ?
A. Ttrong tng hp ha cht, xc tc
B. Trong k thut ha phn tch,phn lp ng v
phng x, tinh ch ha cht
C. Trong m phm, y hc
D. Tt c cc lnh vc trn
Chn D.
Cu 5
Tnh khi lng ring (mg/m2) ca grapheme c a
= 0,23 nm.
A. 0.2 B.0,29 C. 0,4 D. 0,56
Chn B
Gii:
1 nguyn t C nng = 12/ (6,02310
23
) = 9,9210
-
24
(g)
Xc nh nguyn t C c trong mt c s : c 2
nguyn t C trong mt c s
m = n M = 2 9,9210
-24
= 3,985 10
-23
(g)
S : din tch mt c s = 6 S
0
; S
0
din tch
tam gic u
S =

= 13,7410
-20
(m
2
)
khi lng ring d =

= 0,29
mg/m
2

Cu 6
Polymer c bao nhiu dng mch cu trc
A.1 B.2 C.3
D.4
Chn C
Cu trc mch thng, mch nhnh v mch khng
gian .
Cu 7
Khi Clo ha PVC thu c mt loi t Clorin cha
66,6% Clo. Xc nh s mc xch trung bnh tc
dng vi 1 phn t Clo.
A. 2 B.3 C.4
D.5
Chn A : 2 mc xch
Gii:
CTPT ca PVC :
(CH
2
-CH-Cl)
n
= (C
2
H
3
Cl)
n
= C
2n
H
3n
Cl
n

Gi x l s mc xch tc dng vi mt phn t Clo.
Ta c :
C
2x
H
3x
Cl
x
+ Cl
2
C
2x
H
3x-1
Cl
x+1
+ HCl
%Cl =

100 = 66,6 %
=

100 = 66,6%
Gii ra x = 2 .Vy c khong 2 mc xch tc dng
vi mt phn t Clo.
Bi son cu hi n tp [Type the document title]

105

Cu 8
Pht biu no sau y ng:

A. Polime dng sn xut t phi c mch khng
phn nhnh, sp xp song song dc theo mt trc
chung, xon li vi nhau, to thnh si di, mnh v
mm mi

B. T nhn to c sn xut t nhng polime tng
hp nh poliamit, t polieste

C. T visco, t xenluloz axetat u l t t nhin

D. Cao su v keo dn tng hp c cu trc phn t
ging nhau
Chn A
Cu 9
S mc xch c trong 1kg nha PVC l :
A.1000 B.2000 C. 9,636810
24
D. 9,636810
25
Chn C
Gii:
Nha PVC c CTPT l (C2H3Cl)n = 62,5
S mc xch l :
n =

1000 6,02310
23
= 9,636810
24

Cu 10
Cao su buna c cn xut t xenlulozo chim 50%
g theo s iu ch sau :
Xenlulozo

glucozo

etanol

buta 1,3-dien

cao su buna
Hiu sut ca mi giai on c cho nh trn s
. sn xut 1 tn cao su th cn bao nhiu tn
g.
A.0,486 B.3 C.
9,25 D.18,5
Chn D
Gii:
Theo s iu ch ta c t l :
1 (C
6
H
10
O
5
)n 1 (C
4
H
6
)n
S mol cao su buna = 1/54
Theo t l suy ra s mol ca (C
6
H
10
O
5
)n = 1/54
Khi lng ca xenlulozo = (1/54) 162 = 3 (tn)
V xenlulozo l cht tham gia phn ng v chim
50% trong g nn khi lng g cn dng l :
Khi lng g = 3/(0,6 0,8 0,75 0,9 0,5) =
18,5 (tn)
Cu 1: Dng v tnh (clone) l g?
A. L nhng dng cao su cho m thp, ch thu
hoch m 1 ln /nm.
B. Vt liu nhn ging cao su v tnh, nhng
dng v tnh chn lc a vo sn xut gi l
ging cao su.
C. Vt liu nhn ging cao su v tnh, nhng dng
v tnh c a vo sn xut gi l ging cao su.
Bi son cu hi n tp [Type the document title]

106

D. L nhng dng cao su cho m cao, thu hoch
nhiu ln trong nm
A: chn cu B
Cu 2: nh danh dng v tnh nh th no?
A. Thng qua hnh thi dng cy, cu trc tn, c
im l, v ht.
B. Bng ch th phn t hoc cu trc di truyn.
C. Thng qua tn gi.
D. Thng qua hnh thi dng cy, cu trc tn,
c im l, v ht.Bng ch th phn t hoc
cu trc di truyn.
A: cu D
Cu 3: Cc c im nhn dng ging cy cao su
non gm cc ch tiu no?
A. Tng l, l cht gia, cung l.
B. Tng l, l cht gia, cung l,cnh g ghp.
C. Tng l, l cht gia, cung l,cnh g ghp,mu
m hoc biu hin bnh.
D. C 3 u sai
A: cu C
Cu 4: Cy cao su trn th gii thuc vo my h
thc vt?
A. 3
B. 4
C. 5
D. 6
A: cu C
Cu 5: Cy cao su thuc h no?
A. Euphorbiaceae
B. Moraceae
C. Apocynaceae
D. Composeae.
A: A
Cu 6: Dng th hnh l g?
A. L s tn ti nhiu cu trc tinh th ca cng 1
nguyn t.
B. L s tn ti hai hay nhiu cu trc tinh th
ca cng 1 nguyn t hay mt hp cht ha hc.
C. L s tn ti hai hay nhiu cu trc tinh th ca
cng 1 nguyn t hay mt hp cht ha hc cng
1 iu kin.
D. L s tn ti hai hay nhiu cu trc tinh th ca
cng 1 nguyn t hay mt hp cht ha hc cc
iu kin khc nhau.
A: cu B
Cu 7: Cc yu t dn n chuyn dng th hnh l?
A. Nhit v p sut.
B. Nhit v nng
C. Nhit v nh sng.
D. Nhit .
A: cu A
Bi son cu hi n tp [Type the document title]

107

Cu 8: S thay i dng th hnh thng ko theo
nhng thay i g?
A Thay i v th tch mng tinh th.
B Thay i v c tnh.
C Thay i v th tch mng tinh th v c tnh.
D Khng dn theo thay i g ng k.
A: cu C
Cu 9 : Chu k kinh t ca cy cao su cng nghip.
A. 15 nm trong thi gian u t thit k c bn
5-7 nm.
B. 20 nm trong thi gian u t thit k c bn
5-7 nm.
C. 25 nm trong thi gian u t thit k c bn
5-7 nm.
D. 30 nm trong thi gian u t thit k c
bn 5-7 nm.
A: cu D
Cu 10: Dng bi, ngun gc ti bc Mexico, mc
trn cc cao nguyn 2.000m, thch hp vi t c
vi d thot nc l ging cao su no?
A. Guayule
B. Ficus
C. Manihot
D. Castiloa
A: cu A
1. C bao nhiu phng php tng hp Polymer
a. 3 b. 4 c. 2
d. 5
p p a
2. Khi lng phn t ca thu tinh hu c ( poly
metyltacrylat ) l 25.000 vC. S mc xch trong
phn t hu c l:
a. 116 mc xch b. 250 mc xch c. 183 mt
xch d. 257 mc xch
Giai: CTCT


Ta c : 100n=25000dvC suy ra n=250 mc xch
p n b
3. T lapsan c tng hp t 2 hp cht no
a. Axit terephtalic v etylen glicol
b. Axit terephtalic v etylen
c. Axit terephtalic v acrilonitrin
p n a
4. Danh php ca hp cht ny l g

a. Benzo- 12- crown-4
b. Benzo 12- crown- 3
c. 12- crown-4
d. 12 crown -3
p n a
Bi son cu hi n tp [Type the document title]

108

5. Pht biu no sao y l ng nht khi ni v nng
lng lin kt ca cc loi lin kt
a. Nng lng lin kt ca lin kt ion ln, c nh
hng
b. Nng lng lin kt ca lin kt ha tr nh, c nh
hng
c. Nng lng lin kt ca lin kt ion ln, khng nh
hng
d. Nng lng lin kt ca lin kt ha tr ty thuc
vao nguyn t, c nh hng
p n d
6. Dy polymer ny c gi l

a. Copolymer ngu nhiu
b. Copolymer iu n
c. Copolymer khi
p p c
7. t chy hon ton m gam cao su isopren c
lu ha bng khng kh va (cha 20% O
2
v
80% N
2
), lm lnh hn hp sau phn ng ngng
t ht hi nc th thu c 1709,12 lt hn hp kh
(ktc). ng kh ny lm ny tc dng va ht vi
dung dch cha 0,1 mol Br
2
. Xc nh m
A. 159,6 gam
B. 159,5 gam
C. 141,1 gam
D. 141,2 gam
Ta c: n
hh kh
= 76,3 mol

SO
2
+ Br
2
+ 2H
2
O --> H
2
SO
4
+ 2HBr

=> nSO
2
= 0,1mol

Gi x l s mol C
5
H
8


C
5
H
8
+ 7O
2
--> 5CO
2
+ 4H
2
O

=> nO
2
= 7x => nO
2
ban u = (7x + 0,1) => nN
2
=
4(7x + 0,1)

=> 28x + 0,4 + 5x = 76,2 => x = 75,8/33

=> m = 68*75,8/33 + 3,2 = 159,39 gam
p n b

8. Phn ng lu ha cao su thuc loi phn ng
a. Gi nguyn mch polime b.
Gim mch polime
c. ipolime ha d. Tng
mch polime
p n d
9. Mt loi cao su lu ho cha 2% lu hunh.Hi c
bao nhiu mt xch isopren c mt cu ni isunfua-
S-S-,gi thit rng lu huyhf thay th H nhm
metylen trong mch cao su
A,54
B,46
C,24
D,63
gi n l s mt xch isopren v x l s cu ni
isunfua (mi cu ni c 2 S)
Bi son cu hi n tp [Type the document title]

109

=> c 2x phn t S
(C
5
H
8
)n+2xS>C
5
nH
8
n2xS2x+xH
2

ta c:
==>64x10068n+62x=2 ===> n = 46,15x
vi x = 1 cu ni isunfua => n = 46 ====> cu
BVit CTCT ca cc hp cht sau y
a. Cao su buna:.
b. Cao su buna S:....
c. Cao su isopren:.
Cu 1:Chncutrlingnt
A.
CcCryptandtrungbnhchochnlckhngrrtvik
imloikimvkimthkhcnhau.
B.Kchthc3-D tocutrckmbnhn so vi 2-D.
C. Khongtrnggiavngctnhcht cng
trnhs co ginkhikthpcationlnhn hay
nhhn.
D. CcCryptandln (vdCryptand [3-2-2])
chochnlckhngrrtivicc ion kimloi.
E. Cu C,Dng
Giithch:Toralcutrc 3-D bnhn so vi 2-D
vvngmacrocyclic dng 3-D
sgichtcchtchangbntronghn so
vidng 2-D.
Cryptandtrungbnhschochnlcrrtvikimloiki
mvkimthkhcnhau.(Cryptand[2.2.2]
cchnlcvi Kali, Cryptand2.2.1]
cchnlcviNatri).
Cu
2:Stayithhnhsdnntayiiugtrongc
cloivtliu?
A. Thtchmngtinhth B. Tnhchtvtliu
C. Ctnh D. C A,B& C
Giithch:Mtnguyntkimloi hay
mthpchthahccthtntihai hay
nhiudngcutrctinhth - thhnh.
Thtchvtliuthayi do schuyndngthhnh qua
qutrnhthayinhit hay psut.
Cu3:Chncutrlingnt
Nhkhoahcnochto, tinhlc,
nhndngvmtctrngcalp grapheme
A.Kobayashi Makoto &MasukawaToshihide
B. Andre Geim&Konstantin Novoselov
C.AlbertFert& Peter Grunberg
D.SergeHaroche& David J. Winelan
Cu4:Vtliunano 2 chiu-
Gapenecngdnglmg?
A. Chtomnhnhcmng, tmphtsng, pin
mttri, cththayth indium-thic-oxide (ITO)
rtinvbnhntronglnhvcnnglng.
B. Chto phi thuynvmy bay
tronglnhvcchtocngc.
C. Chto transistor
siunhhotngrthiuqutronglnhvcint.
D. C A, B, C ng.
Bi son cu hi n tp [Type the document title]

110

Giithch:Graphenelmtchtdnccmng,
rtbnvmtchc, trongsutvdo.
dncancthbinitrnmtngnglnhocbn
gcchphatpchthahc,
bngtcdngcaintrngnncthngdngtrongn
hiulnhvc.
Cu 5.Chncutrlingntvtnhchtca
grapheme
A. Graphenekhngckhnngdnin
B. Graphenednnhittthnng 10 ln.
C. Graphenelmtchtdntrongsut,
nnncthdngtrongccngdngnhmnhnhcm
ng, tmphtsngv pin mttri
D. B,Cng.
Giithch:Graphenelloivtliuckhnngdnin,
dnnhitrtttxpx 5000Wm
-1
K
-1
vhunh
grapheme trongsutchhpth 2.3%
cngnhsng, clpvibc song
trongvngquanghc.
Cu 6:tnghpSepulchate,
mthpchtsiuphnt, ngi ta
tngsdngpngpptnghpkhunkimloi.
ngtngcc imine
rtnhybthyphnvphnngthinhn, l 2
phnngkhngmongmunxyra,
vytisaotongtnghpnyngi ta
vnpdngcpngppnysnxutSepulch
ate.
A. Co
3+
khnglmphit imine phnccnh H
+
.
B. LinktCo(III)-N rtbn,
ngncnphnngthinhnxyra.
C. C A,B sai
D. C A, B ng.
Giithch:Vnguynttrungtml ion kimloi
Co
3+
nnlinktrtbnvi ion N
3-
vccphit imine
linktvinhaubnglinktyu
(lctngtctmomenlngcctrongphntkhngph
ncc) vchgingnhcctrnghpthnggpkhc.
Cu7:Chncutrling, nylon 11
ccngthcnsau

Numcslngtrungbnhcatrnghp polymer
lX
n
, cho nylon l 100 v M
w
= 120.000.
Hiaphntn polymer lbaonhiu?
A. 6.3 B. 7.56 C. 6.56 D. 6.5
Gii
Chng talu rngX
n
v
nxcnhslngtngtchohaithcthkhcnhau.
Mctrnghpvimtphntl n.
Nhngmtkhilngpolymebaogmhngtriuphnt
, mitrongscmtmctrnghpnhtnh.
X
n
ltrungbnhcaccphnt:

N: tngsphnttrongkhi polymer
Bi son cu hi n tp [Type the document title]

111

M
r
: khilngphntcaminvlpli
n
i
: sphntthi
M
n
= X
n
*M
r
= 100(15+14*10+28) = 18300
aphntn polymer l:
M
w
/M
n
= 120000/18300 = 6.56
Cu8.Cho bittncngthcdiy?

A. Cryptand-2.1.2 B. Cryptand-2.2.1 C.
Cryptand-1.2.2 D. Ttcusai
Giithch

TncaCyptandctheotht m trcv n
sau.Nnngvicngthctrnl Cyptand-2.2.1.
Cu9.Tnhphntlngtrungbnhscaca nylon
nu 95%
canhmchcnngpnng?Chncutrlingn
ht?

A. 2260 & 3200 B. 2230 & 3240 C. 2260 & 3140
D.2260 & 3240
Gii

Nylon 6, M
0
=113
M
n
=113/(1-0.95) = 2260
Nylon 6,12, M
0
=324/2=162
M
n
=162/(1-0.95) = 3240
Cu10.Hychobitphntkhicacc polymer
bndinuchobiths polymer hal
1000?Chnpnngnt?

Bi son cu hi n tp [Type the document title]

112

A. 1.18*10
5
& 2.54*10
4

B. 11.8*10
4
& 2.54*10
5

C. 1.18*10
4
& 2.54*10
5

D. 1.18*10
5
& 25.4*10
5

Gii


Khilngcatng monomer =
14+13+6*12+4+15=118
M
w
=118*1000=1.18*10^5

Khilngcatng monomer =
16+6*12+4+42+6*12+4+16+28=254
M
w
= 254*1000=2.54*10^5
Cu 1: ng trng hp etilen v isopren thu c
polime X. t 39g X cn 90,72 lt O2 (dktc). T l
s mt xch etilen : isopren l:
A. 1:2 _______B. 2:3_________C. 1:3 _______D.
3:2
Bi lm
T l s mt xch etilen : isopren = k --> X =
(C
2
H
4
)
k
C
5
H
8


C
2k+5
H
4k+8
+ (3k + 7)O
2
--> (2k + 5)CO
2
+ (2k +
4)H
2
O
(28k + 68)__ (3k + 7)
___ 39 _____ 4.05

--> k = 2/3 --> chn p n B

Cu 2: Polime X l sn phm ng trng hp ca
stiren v 1 anken Y. Phn t khi ca X l
198000dvC c t l s mt xch ca stiren : Y l 3:2.
Mt khc t 39,6g X cn 87,36 lt O2 (dktc). Tng
s phn t stiren v Y to nn 1 phn t X l:
A.1500 .1750 C.2000
D.2500.
X = [(C
8
H
8
)
3
(C
n
H
2n
)
2
]
a


C
2n+24
H
4n+24
+ (3n+30)O
2
---> (2n + 24)CO
2
+ (2n +
12)H
2
O
(28n + 312)___(3n + 3)
__ 39.6 _______3.9

--> n = 3 --> X = [(C
8
H
8
)
3
(C
3
H
6
)
2
]
a


M
X
= (104*3 + 42*2)a = 198000 --> a = 500

--> Tng s phn t stiren v Y to nn 1 phn t X
= (3 + 2)*500 = 2500
Chn p n:D
Cu 3: kt lun no sau y khng hon ton ng:
A. Cao su l nhng polime c tnh n hi
B. Vt liu compozit c thnh phn chnh l polime
C. Nilon-6,6 thuc loi t tng hp
D. T tm thuc loi t thin nhin
Bi son cu hi n tp [Type the document title]

113

p n :B v vt liu compozit l tng hp ca hai
hay nhiu vt liu khc nhau l cc s ngn,cc
si di n,si di kp.
Cu 4: Polime trng hp b nhit phn hay quang
phn nhit thch hp thnh cc on nh v
cui cng thnh monome ban u, gi l phn ng:
A.Trng hp B.ng trng hp C.Gia
trng hp D.Polime ha
p n: C v ch c phn ng gii trng hp mi
lm cho cc polime b nhit phn thnh cc monome
ban u.
Cn trng hp l t nhng monome tng hp
polime ngc vi gii trng hp,cn ng trng hp
l trng hp cc monome hon ton ging nhau v
phn ng polime th cng khng th.
Cu 5: Trong cc nhn xt di y, nhn xt no
khng ng?
A. Cc polime khng bay hi
B. a s cc polime kh ha tan trong cc dung mi
thng thng
C. Cc polime khng c nhit nng chy xc nh
D. Cc polime u bn vng di tc dng ca axit
p n :D v polime b thy phan di tc dng ca
axit
Cu 6: Pht biu no sau y khng ng?
A. Polime l hp cht c phn t khi ln do nhiu
mc xch lin kt vi nhau to nn.
B. Nhng phn t nh c lin kt i hoc vng km
bn c gi l monome
C. H s n mc xch trong cng thc polime gi l h
s trng hp
D. Polime tng hp c to thnh nh phn ng trng
hp hoc phn ng trng ngng
p n: B v monome hp cht ca n phn ln l
khng no vi phn t khi tng i nh v cu trc
n gin,c kh nng to thnh polime ch khng
phi l nhng phn t nh c lin kt i u c
goi l monome m l 1 phn ln
Cu 7 : C ch ca phn ng trng hp tri qua
my bc?
A.2 bc B.3 bc C. 4 bc D.5
bc
p n: B. 3 bc l:
Bc 1: l khi mu gm phn ng cc cht hot
ha (cht khi mu) vi 1 phn t monome cho
ra 1 cht hot ha trung gian
Bc 2: Tng mch: bao gm nhm phn ng vi
monome mi to thnh 1 phn t di hn vi 1
trung tm hot ha mi u mch
Bc 3: Phn ng ng mch: bao gm phn ng
ca 1 phn t ln c cha gc hot ha vi 1 nhm
hot ha cho 1 phn t polyme khng hot ha

Cu8: Trong cc phn ng sau phn ng no thuc
loi phn ng gi nguyn mch polime?
A. A,B B.A,C C.B,C .D. A.D

A. Poli(vinyl axetat) (PVA) tc dng vi dung dch
NaOH:
Bi son cu hi n tp [Type the document title]

114

B. Phn ng thy phn polieste:

C.S lu ha cao su:
Khi hp nng cao su th vi lu hunh th thu c
cao su lu ha. cao su lu ha, cc mch polime
c ni vi nhau bi cc cu SS (cu isunfua)

D.Cao su thin nhin tc dng vi HCl:


Cao su hiroclo ha
p n: D
Cu 9: polime no c cu trc mch phn nhnh ?
A. Polietilen, amilozo B. polietilen, glicogen
C.cao su lu ha, nha bakelit
D.glicogen, amilopectin
p n : D
V cu A th c polietien ,amilozo thuc dng
khng phn nhnh nn loi, cu B cng c
polietilen thuc khng phn nhnh, cu C th thuc
dng mng mch li nn chon p n D
Cu10: Tnh cht no sau y l tnh cht ng
nht ca polime
A. Hu ht l cht rn, khng bay hi c nhit nng
chy xc nh
B. Cc polime u tan trong dung mi hu c
C. Tt c cc polime u c tnh do, tnh dai,tnh n
hi v d ko si
D. C 3 p n trn u ng
p n: A v
Cu B sai l ch c mt s polime tan c,cu C
cng ch c a s thi ch khng phi tt c
Cu 1: TrongHiunggngkim,
nusgngkimcnglnthvtliucng ..
A: Cngbn.
B: Cngyu.
C: chaipntrnusai.
pn: A
Cu 2:Cchcaphnngtrngngnggmmybc?
A: 4 B: 3 C: 2 D: 1
pn: B
Bc 1: phnngkhimu: phnngnhmhotha(
chtkhimuvi 1 phnt polymer chora 1
nhmtrunggianhotha.
Bc 2: Tngnhanh.
Baogmphnngnhmhothavi 1 monomer
tothnh 1
phntdihnvchatrungtmhothami.
Bc 3:
Phnngngmchbaogmphnngcamtphntl
nvi 1 nhmhothacho 1 phnt polymer
khnghotha.
Cu 3: Homopolymerclmtnhng polymer
nhthno ?
A: ngnht (gingnhau).
Bi son cu hi n tp [Type the document title]

115

B: 2 polymer khcnhau.
C: 3 polymer khcnhau.
D :C 3 pntrnusai.
pn : A
Cu 4: Hnhpca KOH vi dicyclohexyl-18-
crown-6 cthdngthyphn ester
trongmitrng .
A: 18-crown-6
B: Benzen
C :Toluen
D: C 3 pntrnusai.
pn : B
CU 5: so
snhgiaphnngtrnghpvphnngtrngngngth
ta thy :
PhnngtrnghpcnAcnphnngtrngngng
thkhngcncht A
VychtA cgilg ?
A: Chtphimu
B: chtcphntln
C: ChtKhimu( chthotha)
D: ttcusai
pn: C
PHN NG TRNG HP PHN
NG TRNG
NGNG
Cnchtkhimu
Vd : cht benzoyl peroxide
Khngcnchtkh
imu

Khitrungtmhothachnht
hnhthstothnhcc polymer
ln
Cc monomer
stothnhccph
ntnh
Khilngphnt tang
rtnhanh
Khilngphnt
tang rtchm
Khngcphnngngmch Cphnngng
mch
Thigianphnngdichkhicc
polymer
ckhilngphntln
Thigianphnng
diivicc
monomer v
polymer
ckhilngphn
tln
Cu 6: chtnoldngthhnhcbitca carbon ?
A: fullerenes B: acetylene
C: chloroform D: ttcusai
pn: A
Cu 7: cpchtdngtnghpbuna-s
lcpchtnosauy:
A :CH
2
=CH-CH=CH
2
v C
6
H
5
-CH=CH
2
.
B:CH
2
=C(CH
3
)-CH=CH
2
v C
6
H
5
-CH=CH
2

C: CH
2
=CH-CH=CH
2
vluhunh
D: CH
2
=C(CH
3
)-CH=CH
2
v CH
3
-CH=CH
2

pn:cu A
Cu 8:Phtbiunosauyng ?
A: caosubuna-s lsnphmngtrnghpca buta-
1,3- dienvanatri
B caosubuna-S lsnphmngtrnghpca buta-
1,3- dienvstiren
C :caosubuna-N lsnphmcaphnngtrngngng.
Bi son cu hi n tp [Type the document title]

116

pn:C
Cu 9: nhnvohnhbndilcchca :
NaCNkhngphnngvi Propyl bromide trong
chloroform , khicho18- Crown-6 tophcvi
Na
+
trongmitrngncvchuynxungmitrng
chloroform sauxyraphnngthBromvo crown
sauchuyn qua mitrngnc.vy18- Crown-
6cvaitrg ?

A: chtxctc
B: chthotngbmt.
C: c 2 pntrnusai
pn : A
Cu 10: Hynutnhchtca Fullerenes?(chng 3:
vtliuNaNo)
A: Cth tan ttrong 1 s dung mitolunen, carbon
disulfide
Nhngchnglikncnnkhitrongncchngst
othnhccht, cckhiccos 250-350nm.
B: Khicshindinca Fullerenes
trongncthslmphnr AND
C: Fullerenes tngtcchiuxvibcsng = 3pm,
(1999).Chngthucvtliunanokhngchiu
D: Ttcpntrn
pn: D
1. T nilon- 6,6 l:
A . Axit adipic v hexametytendiamin C.
Glixin v alanin
B. Poliamit ca aminocaproic D.
Polyeste ca axit adipic v etylen glycol
p n: A
-NH(CH
2
)
6
- NH-CO-(CH
2
)
4
CO-
2. Cao su Buna c sn xut bng phn ng trng
hp no sau y?
A. CH
2
=CH-CH=CH
2
c mt ca Na C. A
v B u ng
B. CH
2
=CH-CH=CH
2
c mt ca S D. A
v B u sai
p n: A
Na
CH
2
=CH-CH=CH
2
( CH
2
-CH=CH-CH
2
)
3. Phn ng lu ha cao su thuc loi phn ng no
sau y?
A. Gi nguyn mch polymer C.
Gim mch polymer
B. ipolymer ha D.
Tng mch polymer
p n: D
Cu ni (S-S) gip ni cc monomer li vi nhau
nn lm tng mch polymer.
4. Polymer X trong phn t ch cha C, H v c th c
O. H s trng hp ca phn t X l 1800, phn t
khi l 122400. Vy X l:
A. Cao su isoprene C. PVA (
polyvinyl axetat)
B. PE (polyetylen) D. PVC (
polyvinyl clorua)
p n: C
Bi son cu hi n tp [Type the document title]

117

Ta c M
X
= 122400/1800 = 86 ( (-CH(OCOCH3)-
CH2-)
n
Polyvinyl axetat)
5. Trng hp hon ton 16.8g etylen thu c
polyetylen. S mt xch CH
2
-CH
2
- c trong lng
PE trn l:
A. 3,456.10
23
C. 5,238.10
23

B. 3,614.10
23
D. 7,862.10
23

p n: B
n= (16,8/28).6,023.10
23
= 3,614.10
23
6. Trong t nhin latex c th tn ti bao nhiu dng
khc nhau?
A. 3 C. 4
B. 2 D. 1
p n: A
Trong t nhin latex c th tn ti 3 dng sau y:
- Dung dch
- Dung dch gi
- Nh tng
7. Kch sn latex s dng hn hp bao gm my cht?
A. 3 C. 5
B. 2 D. 4
p n: B
Hn hp gm: ENTREN v acid 2,4 D
8. C my loi cu trc ca CNTs?
A. 1 C. 3
B. 2 D. 4
p n: B
C 2 loi cu trc ca CNTs l: zigzac v gh bng.
9. Graphene mt lp ch thy c khi lp SiO
2
dy
bao nhiu?
A. 215nm C. 315nm
B. 515nm D. 415nm
p n: C
10. ngha ca Youngs Modulus l g?
A. Cho bit bin dng ca vt liu.
B. L kh nng linh ng ca vt liu.
C. dn in ca vt liu.
D. Cho bit cng chu lc ca vt liu trong
khong chu lc.
p n: D
Cu 1: Qu trnh lu ha cao su: un nng 150
o
C
hn hp cao su v: (p n C)
A. Cl
2
B.Na C.S D.H
2

Cu 2: Polymer no c tng hp t phn ng
trng hp: (p n B)
A. Cao su lu ha
B. Cao su buna
C. T nilon
D. C A, B, C
Cu 3: Chn pht biu ng trong cc cu sau:
(p n A)
A. Vt liu nano kiu 2D bao gm cc mng siu
mng, lp, mt, tm c kch thc nano theo 2 chiu
khng gian.
B. Vt liu nano kiu 3D c kch thc nano theo 3
chiu khng gian.
C. Nanocomposite l vt liu ch c 1 chiu thang o
nanomet (<100nm)
D. Nanopolymer thuc kiu vt liu nano 0D.
Cu 4: Nhn xt no sau y v tnh cht cao su l
sai: (p n B)
A. Cao su c th tham gia cc phn ng cng (H2, Cl2,
HCl,) v c th tc dng vi lu hunh.
B. Cao su t nhin tan trong nc v cc dung mi
thng thng
C. Trong xng, benzene, dicloetan cao su b trng
phng ln v tan chm
Bi son cu hi n tp [Type the document title]

118

D. Cao su t nhin c tnh n hi (tuy cha tt nn
cn phi lu ha), khng thm nc, khng kh,
cch in cch nhit tt.
Cu 5: Vt liu nano khng chiu: (p n A)
A. C 3 chiu u c kch thc nano
B. Hai chiu c kch thc nano
C. Mt chiu c kch thc nano
D. C 3 chiu u t do
Cu 6: Pht biu no sau y l sai v lin kt ca
vt liu siu phn t: (p n D)
A. Lc lin kt phn tn thu c t momen lng cc
trong phn t khng phn cc
B. Nhng lin kt ny a s l lin kt yu
C. L nhng lin kt quan trng bao gm nhng phc
cht nm gia phn t khng phn cc
D. Nhng lin kt ny a s l lin kt mnh
Cu 7: Mt on mch PMM c 1000 mc xch.
Hy xc nh khi lng ca on mch : (p n
C)
A. 62500 dvC
B. 86000 dvC
C. 100000 dvC
D. 250000 dvC
Bi gii:
Ta c cng thc ca PMM ( poly
(metylmethacrylate)) l:

Vy khi lng ca mch PMM cn tm l:
m=(khi lng 1 mc xch)*1000
=100*1000 = 100000dvC
Cu 8: Hng mng theo 3 hng A, B, C (nh
hnh v ) l: (p n A)

A. A=[100], B=[111], C=[

2]
B. A=[

00], B=[

], C=[12

]
C. A=[100], B=[111], C=[122]
D. A=[

00], B=[111], C=[

2]
Bi gii:
Hng A:
- 2 im l 1,0,0 v 0,0,0
- 1,0,0 - 0,0,0 = 1,0,0 A=[100]
Hng B:
- 2 im l 1,1,1 v 0,0,0
- 1,1,1 - 0,0,0 = 1,1,1 B=[111]
Hng C:
- 2 im l 0,0,1 v ,1,0
- 0,0,1 ,1,0 = -1/2, -1, 1 C=[

2]
Cu 9: cho chui phng trnh sau: (p n D)
Bi son cu hi n tp [Type the document title]

119

(1) v (2) l:
A. (1) benzene, (2) LiALH
4

B. (1) LiAlH
4
, (2) Benzene
C. (1) benzene, (2) B
2
H
6

D. C A v C u ng
Cu 10: Dithia-18-crown-6 c cng thc l: (p n
B)
A.
B.
C.
D.

1. CNTs l loi vt liu nano:
A. 1 chiu B. 2 chiu C. Khng xc nh
D. Khng chiu
CNTs l vt liu nano 1 chiu. (Chng 3)
Chn cu A.
2. Chn cu ng. S phi tr cng nh th mng tinh
th:
A. Cng tha tht B. Cng dy c C. Cng
vng chc D. Khng thay i
S phi tr l s lng nguyn t cch u gn nht
mt nguyn t cho. iu c ngha khi s phi
tr cng nh th s lng nguyn t cch u mt
nguyn t cho trc cng t nn mng tinh th cng
tha tht. (Chng 1)
Chn cu A.
3. Polymer no c tng hp t phn ng trng hp:
A. Cao su lu ha B. Cao su buna C. T
lapsan D.C 3 polymer
Cao su lu ha l polymar c khu mch bng
lu hunh. (Theo
http://vi.wikipedia.org/wiki/L%C6%B0u_h%C3%B
3a)
Cao su buna c trng hp t buta-1,3-dien
Bi son cu hi n tp [Type the document title]

120

T apsan c trng ngng t axit terephtalic v
etylenglicol.(Chng 4)
Chn cu B
4. Cu no sau y ni ng v Polymer c khi lng
phn t siu cao:
A. C M = 3.000.000 5.000.000
B. Cha 10.000 18.000 monomer
C. Vit tt l UHMW PE
D. Thng s dng lm cc bnh rng, dy ai trong
cc thit b.
UHMW PE cha ti 100.000 monomer
Chn cu B.
5. Hevea brasiliensis l loi cy c chiu cao:
A. Ti 60m
B. Khong 6-15m
C. Khong 20-40m
D. 25m
Hevea brasiliensis c chiu cao t 20-40m.
Chn cu C.
6. Vt liu nano c pht hin nm 1985 l
A. CNTs B. Graphene C. Fullerenes D.
Quantum dot
Fullerenes c pht hin nm 1985 bi Kroto,
Smalley v Curl
Chn cu C
7. Tnh h s polymer ha ca Teflon ( -CF
2
-CF
2-
)
n
c
phn t khi l M=3500
A. 35 B. 34 C. 36 D. 38
Phn t khi ca mt monomer CF
2
-CF
2
l:
M
monomer
= 24+(19*4) = 100.
H s polymer ha n = M
polymer
/M
monomer
= 3500/100
= 35.
Chn cu A.
8. Mt polymer X c phn t khi l 336000 v h s
trng hp l 8000. X l:
A. PE B. PP C. PVC
D.Teflon
Ly M
polymer
/n = 336000/8000 = 42
P.P (CH
2
-CH(CH
3
))
Chn cu B
9. Trng hp hon ton 12,5gam vinylclorua c Z
gam PVC. S mt xch c trong Z gam PVC l:
A. 1,204.10
22
B. 12,04.10
23
C.12,04.10
22

D. 1,204.10
20

Theo nh lut bo ton khi lng th m
vinylclorua
=
m
PVC
= 12,5g
n
mt xch
= n
momomer
= 12,5/62,5= 0,2 mol
S mt xch =6,022.10
23
* s mol mt xch
=6,022.10
23
*0,2 = 1,204.10
23
= 12,04.10
22

Chn cu C
10. Tnh lng benzoyl peroxide (C
6
H
5
CO
2
)O
2
cn
thit sn xut 1tn nha PE c khi lng trung
bnh l 200.000 g/mol. Bit rng mi phn t
benzoyl peroxide cho ra 2 gc t do v mi gc t
do khi mo cho ra mt chui PE. Gi thit rng ch
c 50% cht khi mo hot ng hiu qu.
Bi son cu hi n tp [Type the document title]

121

A. 1kg B. 1,12 kg C. 11,2 kg D.1,21 kg
S mol ca PE trong 1 tn PE l
n
PE
= 1000.000/200.000 = 5 mol
Nu hiu sut l 100% th:
n
benzoyl peroxide
= 0.5 n
PE
= 2,5 mol
m
benzoyl peroxide
= 2,5*242 = 605 g
Vi hiu sut 50%:
m
benzoyl peroxide
= 2*605 = 1210 g = 1,21 kg.
Chn cu D