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1 ...........................................................................
1.1 1 ......................... ................................ ................................ ................................
1.2 1 ....................................... ................................ ................................
1.3 Methanol Institute 2 .................... ................................
1.4 2 .................................. ................................ Methanol Institute
1.5 2 .............................. ................................ ................................ ................................
1.6 3 .......................... ................................ ................................ ................................
5 .....................................................
2.1 5 ...................... ................................ ................................ ................................
2.2 ( ) 7 .................................. ................................ ................................
2.2.1
2.2.2
2.2.2.1
2.2.2.2
2.2.2.3
2.3.2
2.3.3
2.4.1
2.4.2
2.4.3
2.4.4
2.4.5
19 ............................................................
3.1 19 ............................. ................................ ................................ ................................
3.1.1
3.1.2
3.1.3
ii
3.2.2
3.2.3
( ) 20 ......................... ................................
3.2.4
3.2.5
25 ...................................................................
4.1 25 ....................... ................................ ................................ ................................
4.1.1
4.1.2
4.1.3
4.1.4
4.1.5
4.1.5.1
4.1.5.2
4.1.5.3
4.2.1.1
4.2.2
4.2.3
4.2.4
4.2.5
4.3.2
32 ......................................... ................................
4.3.2.1
4.3.2.2
4.4.1
4.4.2
4.4.3
4.4.4
iii
: 35 ..................................
5.1 36 ........................ ................................ ................................ ................................
5.2 37 ...................................... ................................ ................................
5.3 37 .................. ................................ ................................ ................................
5.4 37 ........................ ................................ ................................ ................................
5.5 38 .................................... ................................ ................................ ................................
5.6 38 ................................ ................................ ................................ ................................
5.7 38 ........................ ................................ ................................
5.8 39 ....................... ................................ ................................ ................................
5.9 39 ...................................... ................................ ................................
5.10 39 .............................. ................................ ................................ ................................
5.11 40 .......................... ................................ ................................
5.12 40 ................... ................................ ................................ ................................
5.13 41 ..................................... ................................ ................................
5.14 41 ........................ ................................ ................................ ................................
5.15 41 ................... ................................ ................................ ................................
5.15.1 "" 42 ...................................... ................................ ................................
5.15.2 "" 42 ...................................... ................................ ................................
5.15.3 42 .................... ................................ ................................
5.15.4 43 ...................... ................................ ................................
45 ...............................................................
6.1 46 ...................................... ................................ ................................
6.1.1
6.1.1.1
6.1.1.2
6.3.1
6.3.2
6.3.2.1
6.3.2.2
6.3.2.3
6.4.1
- 50 ...................................... ................................
6.4.2
- 50 ........................................ ................................
6.4.3
- 51 .......................... ................................
53 ................................................................
7.1 53 ............................ ................................ ................................ ................................
7.2 54 ........................................ ................................ ................................
7.3 55 ............... ................................ ................................ ................................
7.3.1 56 ................................... ................................ ................................
7.4 56 ....................... ................................ ................................
7.5 56 ............................ ................................ ................................
7.6 57 ................................ ................................ ................................
7.7 57 ................................... ................................ ................................
7.7.1 57 ...................... ................................ ................................ ................................
59 .................................................
8.1 59 ......................................... ................................ ................................
8.1.1 60 ..................................... ................................ ................................
8.1.2 61 ........................ ................................ ................................
8.1.3 61 ................... ................................ ................................ ................................
8.1.4 61 ...................................... ................................ ................................
8.2 61 ................................ ................................ ................................ ................................
8.3 62 .............................. ................................ ................................ ................................
8.4 62 ............................. ................................ ................................ ................................
8.4.1 63 ........................................ ................................ ................................
8.4.2 63 ..................... ................................ ................................ ................................ .
8.4.3 63 ............................ ................................ ................................
8.4.4 63 ................................. ................................ ................................
8.4.5 63 ................ ................................ ................................ ................................
65 .........................................................................
9.1 65 ......................................... ................................ ................................
9.2 66 .................... ................................ ................................ ................................
9.3 66 ......................................... ................................ ................................
9.4 66 .................................. ................................ ................................
9.5 66 ........................ ................................ ................................ ................................
9.6 67 ....................... ................................ ................................ ................................
9.7 67 ....................................... ................................ ................................
10
68 ............................................
10.1 (68 ........... ................................ )Responsible Care
10.2 68 .................................. ................................ ................................
10.3 69 ................................... ................................ ................................
10.3.1 :1 70 .......................... ................................ ................................
10.3.2 :2 70 ....................... ................................
10.3.3 :3 70 ............ ................................ ................................
10.3.4 :4 70 .................... ................................ ................................
10.3.5 :5 70 ................................. ................................ ................................
10.3.6 :6 70 .............................. ................................ ................................
10.3.7 :7 70 ................. ................................ ................................
10.3.8 :8 71 .......... ................................ ................................ ................................
10.3.9 :9 71 ............. ................................ ................................
10.3.10 :10 71 .......................... ................................ ................................
10.4 (71 ...................................... ................................ )Responsible Distribution
10.5 72 ................................. ................................ ................................ ................................
10.5.1 72 ........................................ ................................ ................................
10.5.2 72 ................ ................................ ................................ ................................
vi
11
74 .......................................................
11.1 74 .............................. ................................ ................................
11.2 75 ............................ ................................ ................................
11.3 75 .................................... ................................ ................................
11.4 75 .......................... ................................ ................................
11.5 76 ................................. ................................ ................................
11.6 76 ........................................ ................................ ................................
11.7 77 ....................................... ................................ ................................
12
79 .................................................................................
12.1 79 ...................... ................................ ................................
13
91 ..............................................................................
13.1 91 ............................ ................................ ................................ ................................
97 .................................................
A.1 97 ............................. ................................ ................................ ................................
A.2 97 ................................... ................................ ................................ ................................
/ 99 ..........................................
B.1 99 ................... ................................ ................................ ................................
B.1.1
B.1.2
B.1.3
B.2.2
B.2.3
vii
C
109 ...................................................................................
C.1 107 ......................................... ................................ ................................
C.2 110 ................... ................................ ................................
C.3 114 ........................................ ................................
117 ....................................................................
viii
Responsible Care ( American Chemistry Council )
.
Responsible Care .
Responsible Distribution .
ix
1
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NFPA-325, Guide to Fire Hazard Properties of Flammable Liquids, Gases and
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.NFPA 30A, Code for Motor Fuel Dispensing Facilities and Repair Garages, 2008
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NEC, Chapter 5, Articles 500-504, 2008. These articles define requirements for
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11.1
1. Alliance Technical Services, Inc. 2007. Use of Methanol as a Transportation Fuel.
Prepared for Methanol Institute. November.
2. ALTENER Energy Framework Programme. 2003. Technical and Commercial
Feasibility Study of Black Liquor Gasification with Methanol/DME Production as
Motor Fuels for Automotive Uses BLGM. Ekbom, Tomas, et al. European
Commission. Contract No. 4.1030/Z/01-087/2001 .
3. American Conference of Governmental Industrial Hygienists, 2001. Methanol
Documentation for the Threshold Limit Value.
4. American National Standards Institute/Underwriters Laboratories (ANSI/UL) 1203
Explosion-proof and Dust-Ignition-proof Electrical Equipment for Use in Hazardous
(Classified) Locations.
5. American National Standards Institute/Underwriters Laboratories (ANSI/UL) 913
Intrinsically Safe Apparatus and Associated Apparatus for Use in Class I, II, and II
Division 1, Hazardous Locations.
6. American Petroleum Institute (API). 1986. Storage and Handling of GasolineMethanol/Cosolvent Blends at Distribution Terminals & Service Stations. API
Recommended Practice 1627. First Edition. August.
7. American Society for Testing Materials (ASTM). 2007. D 5797-07. Standard
Specification for Fuel Methanol (M70M85) for Auto Spark Ignition Engines.
September.
8. Armour, M.A. Hazardous Laboratory Chemicals: Disposal Guide, CRC Press,
1991, ISBN 0-8493-0265-X.
9. ASTM International. 2004. ASTM E 681-04. Standard Test Method for Concentration
Limits of Flammability of Chemicals (Vapors and Gases). American National
Standards Institute (ANSI.)
10. Becker, C.E., Methanol Poisoning. The Journal of Emergency Medicine. Volume 1:
pp. 51-58.
11. California Energy Commission. 1996. Methanol Fueling System Installation and
Maintenance Manual. Transportation Technology and Fuels Office. March.
91
92
31. Jim Jordan & Assoc., LLP. 2004. U.S. Methanol Overview 2003 Demand and
Production. Prepared for the Methanol Institute. June 2.
32. Kavet, R., Nauss, K. 1990. The Toxicity of Inhaled Methanol Vapors. Toxicology. 21
(1): 21-50.
33. Kuchta, Joseph M. Investigation of Fire and Explosion Accidents in the Chemical,
Mining, and Fuel-Related Industries - A Manual. U.S. Department of the Interior
Bureau of Mines Bulletin 680.
34. Malcolm-Pirnie, Inc. 1999. Evaluation of the Fate and Transport of Methanol in the
Environment. Prepared for the American Methanol Institute. January.
35. Marchetti, C. 1980. On Energy Systems in Historical Perspective, International
Institute for Applied Systems Analysis, Laxenburg, Austria, Prepared for the 1980
Bernard Gregory Lecture, CERN, Geneva, Switzerland, November 13.
36. Methanex Corporation. 2003. Corporate Manual. Container Filling Best Practice.
Document #CR3RC250.
37. Methanex Corporation. 2005. Methanol Material Safety Data Sheet (MSDS).
www.methanex.com/products/documents/MSDS_USenglish.pdf
38. Methanex Corporation. 2006. Technical Information and Safe Handling Guide for
Methanol. Version 3.0. September .
39. Methanol Fuel Cell Alliance. 2002. Joint Position Document. September.
40. Motorola Corporation, Cell Phone Usage At Gasoline Stations, 1999. Doc. No.
SF27489.000 BOTO 1299 CMO3. by Exponent Failure Analysis Associates, 149
Commonwealth Drive, Menlo Park, CA 94025, December.
41. National Advisory Committee (NAC) for Acute Exposure Guideline Levels (AEGLs)
for Hazardous Substances. 2004. Final Meeting-32 Highlights. U.S. Department of
Labor. Washington, D.C. April 19-21.
42. National Electrical Code (NEC). 2008. NFPA 70. Chapter 5, Special Occupancies.
Hazardous Locations, Classes I, II, and III Divisions 1 and 2. National Fire Protection
Association.
43. National Fire Protection Association (NFPA), 2008. U. S. Vehicle Fire Trends and
Patterns. Ahrens, Marty, July.
44. National Fire Protection Association (NFPA). 1994. No. 325, Guide to Fire Hazard
Properties of Flammable Liquids, Gases and Volatile Solids .
45. National Fire Protection Association (NFPA). 2008. NFPA 30, Flammable and
Combustible Liquids Code.
46. National Fire Protection Association (NFPA). 2008. NFPA 30A, Code for Motor Fuel
Dispensing Facilities and Repair Garages.
47. National Toxicology Program Center for the Evaluation of Risks to Human
Reproduction (NTP-CERHR, 2003). NTP-CERHR Monograph on the Potential
Human Reproductive and Developmental Effects of Methanol. NIH Publication No.
04-4478. September.
48. New Jersey Dept. of Health and Senior Services. 2002. Hazardous Substances Fact
Sheet Methyl Alcohol. Revision. April.
49. Olah, G.A., Goeppert, A., Prakash, G.K.S. 2006. Beyond Oil and Gas: The Methanol
Economy: Wiley-VCH Publishers .
93
50. Organization for Economic Cooperation and Developments (OECD). 2003. Guiding
Principles for Chemical Accident Prevention, Preparedness, and Response..
51. Perrys Chemical Engineers Handbook, 6th Edition, 1984. McGraw-Hill Book
Company, San Francisco .
52. SAE Cooperative Research Program. 1991. A Discussion of M85 (85% Methanol)
Fuel Specifications and Their Significance. September.
53. SAE International. 1990. Summary of the Fire Safety Impacts of Methanol as a
Transportation Fuel. May.
54. SIDS-OECD. 2004. SIDS Initial Assessment Report -- Methanol. Draft. Prepared by
BASF AG. Reviewed by USEPA. October.
55. Stegink, L.D., et. al. 1981. Blood Methanol Concentrations in Normal Adult Subjects
Administered Abuse Doses of Aspartame. Journal of Toxicology and Environmental
Health. 7: 281-290.
56. 3M Respirator Selection Guide. 2008.
57. U.S. Department of Defense. (DOD). Standard Practice DOD-HDBK-263,
Electrostatic Discharge Control Handbook for Protection of Electrical and Electronic
Parts, Assemblies, and Equipment (excluding Electrically Initiated Explosive
Devices.)
58. U.S. National Institute of Standards and Technology (NIST). Chemistry WebBook.
http://webbook.nist.gov/chemistry./
59. U.S. Occupational Safety and Health Administration (OSHA). Hazardous Waste
Operations and Emergency Response (HAZWOPER). Code of Federal Regulations
(CFR) Title 29 section 1910.120 .
60. U.S. Occupational Safety and Health Administration (OSHA). Process safety
management of highly hazardous materials. Code of Federal Regulations (CFR) Title
29 Section 1910.119 .
61. U.S. Department of Health and Human Services (USDHHS). 2002. Communicating in
a Crisis: Risk Communication Guidelines for Public Officials. Washington, D.C .
62. U.S. Environmental Protection Agency (USEPA). 1994. Chemical Summary for
Methanol, prepared by Office of Pollution Prevention and Toxics. EPA 749-F-94013a, August.
63. U.S. Environmental Protection Agency (USEPA). 1994. Methanol Fuels and Fire
Safety. Fact Sheet OMS-8. Office of Mobile Sources. August.
64. U.S. Environmental Protection Agency (USEPA). 2003. Considerations in Risk
Communication: A Digest of Risk Communication as a Risk Management Tool.
Technology Transfer and Support Division, National Risk Management Research
Laboratory, Office of Research and Development. March.
65. Underwriters Laboratories (UL), 1604 - Electrical Equipment for Use in Class I and II,
Division 2, and Class III Hazardous (Classified) Locations.
66. Uniform Fire Code, 1997. Article 52, Motor Vehicle Fuel-Dispensing Stations.
67. Vermillion, B.; Nguyen, P.; Tsan, E.; Herz, R. (Project Advisor). 2001. Feasibility
Study of Methanol As Transportation Fuel. March 18.
http://chemelab.ucsd.edu/methanol01/Feasibility.htm
68. XCellsis, Inc. 2002. Methanol Fuel Quality Specification Study for Proton Exchange
Membrane Fuel Cells. Final Report. Prepared for AQMD. February.
94
69. Cameron, I. Methanex CIBC World Markets. 2010. Whistler Institutional Investor
Conference. January 21.
(http://www.methanex.com/investor/documents/CIBCJan21WhistlerConferenceFINAL.pdf
70. 5th Methanol Markets & Technology Conference. 2010. Muscat, Oman. February 23.
71. ICIS News. 2010., January 4. (www.icis.com)
72. MMSA Global Methanol Supply and Demand Balance. 2005-2010.
(www.methanol.org.)
73. Mogens, H.; van Loosdrecht, M. C. Biological Wastewater Treatment: Principles,
Modeling and Design, IWA Publishing, 2008.
74. Horan, N.J.; Lowe, P.; Stentiford, E. I. 1994. Nutrient Removal from Wastewaters,
CRC Press.
75. Spellman, F.R. 2009. Handbook of Water and Wastewater Treatment Plant
Operations, CRC Press.
76. FCTec. Fuel Cell Basics: Direct Methanol Fuel Cells (DMFC).
(http://www.fctec.com/fctec_types_dmfc.asp)
77. Crawley, G. 2007. Fuel Cell Today, Direct Methanol Fuel Cells (DMFC). August.
78. Dpreview.com. 2004. Toshibas Methanol Fuel Cell. June 24.
(http://www.dpreview.com/news/0406/04062401toshibafuel.asp)
79. PC World Magazine. 2009. Toshiba Launches Methanol Fuel Cell Charger. Oct 22.
(http://www.pcworld.com/article/174113/toshiba_launches_methanol_fuel_cell_charg
er.html)
80. Methanol Fuel Cell Alliance. 2002. Joint Position Document. Sep 15.
(http://www.methanol.org/Energy/Resources/Fuel-Cells/MFCA-overall-documentfrom-09_06.aspx)
81. GE Position Paper. 2001. Feasibility of Methanol as Gas Turbine Fuel. February 13,
2001. (http://www.methanol.org/Energy/Resources/Fuel-Cells/GE-White-Paper.aspx)
82. De Corso, S. M.; Clark, A. S. Editors. 1983. American Society of Testing and
Materials, Stationary Gas Turbine Alternative Fuels: STP 809 .
83. Popular Science. 1975. Alcohol Power: Can it Help you Meet the Soaring Cost of
Gasoline? April.
84. Kontogeorgis, G. M., Folas, G. K. 2009. Thermodynamic Models for Industrial
Applications, pp 306-316. John Wiley and Sons.
85. Barden, A. J.; Powers, M. D.; Karklis, P. 1996. The Pipeline Pigging Conference,
Evaluation of Pipeline-drying Techniques, Jakarta, Indonesia. May 27-30. (Organized
by the Pipe Line & Gas Industry and Pipes and Pipelines International with the
support of the Australian Pipeline Industry Association)
86. Methanol Institute. 2010. Methanol Institutes Comments on the Draft Toxicological
Review of Methanol (IRIS). March 15. (http://www.methanol.org/Health-AndSafety/Safety-Resources.aspx)
87. U.S. Environmental Protection Agency (USEPA). 2009. Draft IRIS Toxicological
Review of Methanol. December.
95
88. Pimentel, D.; Patzek, T.W. 2005. Ethanol Production Using Corn, Switchgrass, and
Wood; Biodiesel Production Using Soybean and Sunflower. Natural Resources
Research, Vol. 14, No. 1, March.
89. Lonza, L.; Hass, H.; Maas, H.; Reid, A.; Rose, K. D. 2011. EU renewable energy
targets in 2020: Analysis of scenarios for transport. JEC Biofuels Programme. JRC
Scientific and Technical Reports. EUR24770 EN 2011.
90. Carbon Recycling International. 2011. The CO2 to Liquid Fuels Company. Methanol
Facts, July. (http://www.methanol.org/Environment/Renewable-Methanol.aspx)
91. BioMCN and Bio-Methanol. 2011. Methanol Facts, July.
(http://www.methanol.org/Environment/Renewable-Methanol.aspx.)
92. CHEMREC. 2011. CHEMREC Gasification Technology Turns Pulp and Paper Mills
into Biorefineries. August. (www.chemrec.se.)
93. Manwaring, R. et al., Chem. Ind., 1973, p. 172.
96
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Section 1910.38 Employee Emergency
( Plans and Fire Protection Plans 1910.38
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Section 1910.120 Hazardous Waste
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Section 1910.132 to 139 Personal
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Section 1910.146 Confined Space Entry
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107
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Section 1910.151 -- First Aid/Medical Service
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Section 1910.331 to 335 Electrical Safety
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Section 1910.1000 Air Contaminants
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Section 1910.1200 Hazard Communication
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108
Part 172 Hazardous Materials Table,
Special Provisions, Hazardous Materials
Communications, Emergency Response
( Information, and Training Requirements
- 172
)
Part 173 Shippers, General Requirements
( for Shipments and Packaging - 173
)
( Part 174 Carriage by Rail - 174
)
( Part 176 Carriage by Vessel - 176
)
( Part 177 Carriage by Public Highway
- 177 )
( Part 178 Specifications for Packaging
- 178 )
( Part 179 Specifications for Tank Cars
- 179 )
Part 180 Continuing Qualifications and
( Maintenance of Packaging - 180
)
Part 190 Pipeline Safety Program
( Procedures - 190
)
Part 191 Transportation of Natural and
Other Gas by Pipeline: Minimum Federal
( Safety Standards - 192
:
)
Part 192 Transportation of Natural and
Other Gas by Pipeline: Minimum Federal
( Safety Standards - 192
:
)
Part 195 Transportation of Hazardous
( Liquids by Pipeline - 195
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109
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200-6596
UN 1230
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115
D
D ()2011-1998
D.1
{ (})8/12/2011
//
6/3/2005
2/17/2006
9,600
5/7/2006
6/23/2006
117
//
7/7/2006
7/14/2007
8/21/2007
8/25/2007
5/18/2008
8/15/2008
8/27/2008
9/15/2008
9/30/2008
2/9/2009
5/24/2009
6/15/2009
7/19/2009
9/24/2009
10/15/2009
118
//
12/2/2009
7/25/2010
10/6/2010
7/30/2011
7/21/2010
4/13/2006
6/19/2007
9/19/2007
2/14/2011
7/12/1998
12/14/1998
1/29/2003
10/13/2004
5/2/2005
10/24/2005
119
//
11/10/2005
2/28/2006
4/20/2006
8/30/2006
8/27/2007
1/4/2008
2/8/2008
10/3/2008
6/15/2009
1/24/2010
500
2/22/2010
9/21/2010
10/14/2010
160,000
MeOH
2/3/2011
1.5
-
120
//
6/14/2011
7/5/2011
7/18/2011
12/7/2000
2/7/2005
1,092 -
10/15/2007
7/16/2011
1/25/2006
1,932 ( 630
) .
4,200 -
10/8/2007
1/18/2008
1/17/2000
3/15/2001
10/12/2011
8/22/2002
2/13/2003
121
//
3/22/2003
4/5/2003
6/13/2003
7/13/2003
10/8/2005
10/22/2005
1/27/2006
7/30/2006
8/15/2006
10/9/2006
10/10/2006
1/5/2007
50
9/2/2007
12/27/2007
122
//
11/12/2009
6,800
- MeOH
6/13/2011
7/4/2011
-
()
1/11/2006
D.2
6/2/2001
Environmental
Alternatives
http://www.rebelwolf.com/essn/ESSN-Jul2005.pdf
2/16/2002
5/6/2002
6/22/2002
7/6/2002
MeOH
MeOH
http://biodieselmagazine.com/articles/830/fire-destroys.american-biofuels-facility-in-bakersfield-calif
7/13/2003
MeOH
http://www.cdc.gov/mmwr/preview/mmwrhtml/mm5545a3.htm
http://www.fox12idaho.com/Global/story.asp?S=5162251&nav
=menu439_2
123
8/20/2003
8/24/2003
5/17/2004
8/14/2004
8/26/2004
9/14/2004
9/29/2004
2/8/2005
5/23/2005
6/14/2005
7/18/2005
9/23/2005
10/14/2005
12/1/2005
http://www.chitowndailynews.org/Chicago_news/OSHA_launc
hes_investigation_at_plant_that_exploded,30103
124
7/24/2006
.MeOh
10/5/2006
7/29/2007
7/20/2006
4/12/2002
6/18/2003
9/18/2003
MeOH
MeOH
MeOH
MeOH
http://www.heraldsun.com.au/news/victoria/man-critical-afterfactory-explosion/story-e6frf7kx-1225934873475
http://www.wkrn.com/story/15181803/bio-diesel-plantdestroyed-in-fire?clienttype=printable
http://www.komonews.com/news/local/98960929.html
2/13/2007
7/11/1994
12/13/1994
1/28/1999
150 -
MeOH
.
-
-
-
http://www.evesun.com/printedition/pdfs/2007-09-19.pdf
Eos
Eos
http://www.whiotv.com/news/26854632/detail.html
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
125
10/12/2000
5/1/2001
10/23/2001
11/9/2001
.
-
Angarsk
Petrochemical
2/27/2002
4/19/2002
8/29/2002
8/26/2003
1/3/2004
2/7/2004
MeOH
MeOH
-
-
MeOH
-
-
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://ctifhazmat.gasilci.org/modules/news/article.php?storyid=36
http://www.icis.com/Articles/2005/10/24/1015565/russiasangarsk-methanol-plant-hit-by-explosion.html
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
Eos
10/2/2004
Eos
Eos
http://www.koreanpress.net/news/view.asp?msection=1&ssect
ion=2&idx=598
Eos
Eos
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
126
6/14/2005
-
" "
http://blog.chron.com/newswatchenergy/2010/09/marinerinvolved-in-13-gulf-accidents-since-06-seven-with-violations/
1/23/2006
2/21/2006
9/20/2006
-
-
MeOH
-
http://firenews.net/index.php/news/news_article/20100126_ne
ws_four_alarm_fire_at_local_catawba_plant/
10/13/2006
2/2/2007
6/13/2007
-
MeOH
-
7/4/2007
7/17/2007
12/6/1996
2/6/2001
-
-
DS-11
http://uk.reuters.com/article/2010/02/22/petronas-fireidUKSGE61L0E520100222
http://www.newsandsentinel.com/page/content.detail/id/11872
0/W-Va--DEP-investigates-methanol-spill-in-river.html?isap=1&nav=5071
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.journal-advocate.com/sterlinglocal_news/ci_17283330
http://www.nola.com/business/index.ssf/2011/06/firefighting_cr
ews_enter_new_i.html
http://www.saunalahti.fi/ility/PI1127.htm
http://www.yourhoustonnews.com/pearland/news/article_c2b4f
932-615c-5066-92d5-56efd0921d0b.html
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.dec.state.ak.us/spar/perp/response/sum_fy05/0502
17301/050217301_index.htm
127
10/14/2003
DS-16 D
http://www.dec.state.ak.us/spar/perp/response/sum_fy08/0710
15301/071015301_index.htm
7/15/2007
1/24/2002
BP
MeOH
http://www.msnbc.msn.com/id/43795063/ns/us_newsenvironment/t/methanol-spill-reported-bp-alaska-oil-field/
10/7/2003
1/17/2004
1/16/1996
3/14/1997
MeOH
10/11/1997
8/21/1998
2/12/1999
3,000
MeOH
http://www.ohio.com/news/students-burned-in-lab-fire-settle1.87719
Eos
Eos
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://info.tse.fi/dagob/documents/Dangerous%20Goods%20R
elated%20Incidents%20and%20Accidents%20in%20the%20B
altic%20Sea%20Region%20PDF%20final.pdf
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
128
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://info.tse.fi/dagob/documents/Dangerous%20Goods%20R
elated%20Incidents%20and%20Accidents%20in%20the%20B
altic%20Sea%20Region%20PDF%20final.pdf
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
129
3/21/1999
4/4/1999
6/12/1999
7/12/1999
10/7/2001
10/21/2001
1/26/2002
7/29/2002
8/14/2002
10/8/2002
10/9/2002
1/4/2003
9/1/2003
12/26/2003
MeOH
CSX
11/11/2005
6/12/2007
7/3/2007
1/10/2002
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
Eos
8,000
30
Eos
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.fireworld.com/incident_logs/incident_log2.php?tabl
e=incidents&cmd=search&mode=normal&month=08&year=20
11&submit=List
http://www.local830.org/index.cfm?zone=/unionactive/view_art
icle.cfm&HomeID=144049&page=200920Incident20Archive
http://www.wtnh.com/dpp/news/fairfield_cty/tanker-carryingmethanol-closes-i-95-northbound-in-stamford
http://www.globaltimes.cn/NEWS/tabid/99/articleType/ArticleVi
ew/articleId/664422/2-truckers-killed-in-fiery-crash.aspx
Eos
130
E
E
131