8o| 5

CV. NCUEN 1AN 1kUNC

(1rung 1om Luyen 1h| Chot Lucng Coc V|NH V|EN[
1oc Anken (c|ef|n[
1oc ete
1oc son phom doc b|et
Cc 3 |co| sou:
CAC PHAN NG TACH H
2
O
1och H
2
0 toc 0LEF|N (ANKEN[:
|eu k|en rucu:
kucu dcn chuc, nc, 5c C 2
|eu k|en phon ung:
H
2
50
4d
, 70
0
C
Phon ung:
C
n
H
2n+
0H
C
n
H
2n
+ H
2
0
Kpu

Hcoc A|
2
0
3
, t
c
400
c
C
hc| rucu
( n 2[
V| du:
C
2
H
5
0H
C
2
H
4
+
H
2
0
H
2
50
4d
70
0
C
Hcon thonh coc phon ung thec sc dc sou:
8|et:
-X,: hcp chot dcn chuc,
- A |o chot kh| duy nhot
- C: C|yxer|n
A
X

-H
2
0
8
C|
2
,t
c
8r
2
No0H
-D C
(1) (2) (3)
(4)

Ap dung :( 1r|ch HDL NN1H - 2000[

C|yxer|n
CH
2
-CH-CH
2
C|
8r
8r
D:
- X,: hcp chot dcn chuc
Hcon thonh coc phon ung thec sc dc sou:
8|et:
- A |o chot kh| duy nhot
A
X

-H
2
0
8
C|
2
,t
c
8r
2
No0H
-D C
(1) (2) (3)
(4)

Ap dung :( 1r|ch HDL NN1H - 2000[

C|yxer|n
CH
2
-CH-CH
2
C|
8r
8r
D:
C|
CH
2
-CH = CH
2
D:
CH
3
-CH = CH
2
A:
- X,: hcp chot dcn chuc
Hcon thonh coc phon ung thec sc dc sou:
8|et:
- A: CH
3
-CH = CH
2
A
X

-H
2
0
8
C|
2
,t
c
8r
2
No0H
-D C
(1) (2) (3)
(4)

Ap dung :( 1r|ch HDL NN1H - 2000[

C|yxer|n
CH
2
-CH-CH
2
C|
8r
8r
D:
C|
CH
2
-CH = CH
2
D:
0H
CH
2
-CH-CH
3
X:
: CH
3
-CH
2
-CH
2
-0H
un rucu A dcn chuc , nc
vc| H
2
50
4
doc , thu ducc
chot huu cc 8,
vc| d
8/A
=,7
1|m C1P1-C1C1 cuo A, 8.
Ap dung 2:
A dcn chuc , nc
1h| 5|nh: 8 |o c|ef|n
5o|

X
H
2
50
4
d
t
c
0|ef|n
X: kucu dcn, nc
kucu dcn, nc
0|ef|n
Ete
H
2
50
4 d
t
c
( Dc mc| rucu toch nucc deu
cc the toc ete[
Con nhc:
CAC PHAN NG TACH H
2
O
1och H
2
0 toc E1E:
|eu k|en rucu:
Mc| kucu
|eu k|en phon ung:
H
2
50
4d
, 40
0
C
Phon ung:

Hcoc A|
2
0
3
, t
c
200
c
C
hc| rucu
Phu thucc chuc rucu !
1och H
2
0 toc E1E:
CAC PHAN NG TACH H
2
O
kucu do
k(0H[
n
k(0H[
m
+
k
m
-(0[
n.m
-k
n
+ H
2
0 n.m
m
n
k-0H
H0-k +
KPU
+
k-0-k
H
2
0
kucu dcn
KPU
C
n
H
2n+
0H
C
n
H
2n
(C
n
H
2n+
[
2
0
H
2
50
4d
t
c
1cm |o| con nhc: ( kucu dcn chuc, nc[
(*[ => M
c|ef|n
<M
rucu
<M
ete
d
c|ef|n/rucu
<
d
ete/rucu
>
=>
(*[
Ru X San pham Y
H
2
50
4
d
Neu d
/X
< : c|ef|n
Neu d
/X
> : ete
Vc| dcn chuc, nc
un rucu A dcn chuc , nc
vc| H
2
50
4
doc , thu ducc
chot huu cc 8,
vc| d
8/A
=,7
1|m C1P1-C1C1 cuo A, 8.
Ap dung 2:
A dcn chuc , nc
1h| 5|nh: 8 |o c|ef|n
8:Ete
kucu (A[
(cn, nc[
H
2
50
4
d
t
c
(8[
(A[, (8[ 7
d
8/A
=,7
V| d
8/A
=,7 >
(8[:Ete
o1 C11Q (A[:
C
n
H
2n+
0H
1cm tot:
PP t|m C1P1 duo tren pu
8.ot C11Q
82.V|et pu
83.Lop pt (*[
84.C|o| (*[
C
n
H
2n
+

0H 2 (C
n
H
2n+
[
2
0 + H
2
0 ([
H
2
50
4
d
t
c
=40
([ (8[: (C
n
H
2n+
[
2
0
1hec de bo| to cc:
d
8/A
=
M
8
M
A
= ,7

(4n + [.2 +6
4n +8
=
,7
n = 3
Voy :(A[:C
3
H
7
0H , (8[: C
3
H
7
0-C
3
H
7
Phon ung:
un rucu A dcn chuc , nc
vc| H
2
50
4
doc , thu ducc
chot huu cc 8,
vc| d
8/A
=0,7
1|m C1P1-C1C1 cuo A, 8.
Ap dung 3:
A dcn chuc , nc
8: c|ef|n
kucu (A[
(cn, nc[
H
2
50
4
d
t
c
(8[
(A[, (8[ 7
d
8/A
=0,7
V| d
8/A
=0,7 <
kucu (A[: (cn, nc[
(8[:c|ef|n
o1 C11Q (A[:
C
n
H
2n+
0H
1cm tot:
PP t|m C1P1 duo tren pu
8.ot C11Q
82.V|et pu
83.Lop pt (*[
84.C|o| (*[
C
n
H
2n
+

0H 2 C
n
H
2n
+ H
2
0 ([
H
2
50
4
d
t
c
=70
([ (8[: C
n
H
2n
1hec de bo| to cc:
d
8/A
=
M
8
M
A
= 0,7

4n
4n +8
=
0,7
n = 3
Voy :(A[:C
3
H
7
0H , (8[: CH
3
-CH=CH
2
Phon ung:
un rucu A cc M
A
<20 dvC.
vc| H
2
50
4
doc , thu ducc
chot huu cc 8,
vc| d
8/A
=,4
1|m C1P1-C1C1 cuo A.
Ap dung 4:
8:Ete
kucu (A[
MA<20
H
2
50
4
d
t
c
(8[
(A[ 7
d
8/A
=,4
V| d
8/A
=,4 >
(8[:ete
o1 C11Q (A[:
k(0H[
n
1cm tot:
PP t|m C1P1 duo tren pu
8.ot C11Q
82.V|et pu
83.Lop pt (*[
84.C|o| (*[
2k-(0H[
n
k-0
n
- k nH
2
0
H
2
50
4d
([
(8[
d
8/A
=
2k+6n
k+7n
,4
un 32,8 g hh X:A0H,80H,k0H vc|
H
2
50
4 d
c 40
c
C to thu ducc ,2g hh
gcm 6 ete cc sc mc| bong nhou. Moc
khoc dun ncng hh X vc| H
2
50
4 d
c
70
c
C th| thu ducc hh ch| gcm cc 2
0|ef|n kh| (c d|eu k|en thucng[.
o. Xoc d|nh C1P1-C1C1 cuo coc rucu,
(H=00X[
b. 1|nh X (thec m[ cuo hh X.
c. 1|nh X(thec m[ cuo hh .
un rucu A vc| H
2
50
4d
, thu ducc
chot huu cc 8, vc| d
8/A
=0,6086
1|m C1P1-C1C1 cuo A, 8. 8|et
M
A
0 dvC

CK: C
2
H
5
0H
C
2
H
5
0No
C
2
H
5
0H
CH
3
-C00C
2
H
5
C
2
H
4
C
2
H
5
C| CH
3
CH0
C
2
H
3
C00H
C|ucczc
CH
2
=CH-CH=CH
2
C
2
H
6
0 |
C E
D
8
A
X

Z
kucu A (8[
H
2
50
4 d
t
c
M
A
<20
d
8/A
=,4
(A[, (8[ 7
V| d
8/A
=,4>
=> 8: Ete
ot C11Q (A[: k-(0H[
n
2k-(0H[
n
k-0
n
- k+nH
2
0
H
2
50
4d
([
(8[
d
8/A
=
2k+6n
k+7n
=
,4
=> k = 4n
MA = k+7n < 20
=> n < 3,87
=> n = ,2,3
n=2 => A: C
2
H
4
(0H[
2
CV. NCUEN 1AN 1kUNC
(1rung 1om Luyen 1h| Chot Lucng Coc V|NH V|EN[