CH TO V S DNG CHT LNG T CoOFe2O3 X L NC BN

Nguyn Khnh Dng1, Hunh Th Thu H2 1 Trng H Cng nghip TP. HCM, 2 Trng H Cn th TM TT Cht lng t CoOFe2O3 c ch to theo phng php ng kt ta, c kch thc ht c nanomt, t tnh mnh, c kh nng lm lng ng nhanh v trit cc cht bn trong nc nh cc tp v c, hu c, cc kim loi nng c hi nh As, Pb, Zn, Fe, Ni Cng trnh ny m t phng php thc nghim ch to cht lng t CoOFe2O3 , kho st cu trc, tnh cht ca n bng ph nhiu x tia X, chp nh TEM, SEM, o t ph thuc t trng, nht v t trng ca cht lng. Vt liu ch to c s dng tch lc cc kim loi nng trong nc t hiu qu cao. ABSTRACT CoOFe2O3 solution is made by method of together precipitation. It has the size of
Nanometer nucleus, strong magnetic and is able to accumulate quickly and completely water sewage such as inorganic and organic complex matter, and harmful heavy metals such as As, Pb, Zn, Fe,

Ni This research describes experiment method to make solution from CoOFe2O3, investigates its structure, characteristics by X-ray diffraction, photographs it by TEM, SEM, and measures magnetic dependence magnetization, viscosity and density of the solution. The material is used to and fitlit heavy metals in water effectively. I. GII THIU Trong nhiu nm gn y cht lng t rt c quan tm nghin cu do chng cha cc ht vt liu t c kch thc c nanomt, c th ng dng rt hiu qu trong khoa hc k thut, c bit l trong y sinh hc, mi trng [1,2,3]. Trong lnh vc mi trng, lu nay ngi ta thng s l nc bn bng cc bin php ha hc nh pha ha cht c th to phn ng vi cc cht bn thnh cht kt ta lng ng xung ri tch lc loi b, hay cc phng php vt l nh lc qua cc mng thm thu ch cho nc i qua, hay chng ct, lm bay hi nc ri cho chng ngng t li Cc phng php ny thng kh tn km, mt nhiu thi gian v i khi hiu qu khng trit . Gn y vi vic ch to ra cht lng t ferit, ngi ta hng ti vic ng dng chng lng ng nc bn bng c ch tnh in v hp ph, c kh nng lng ng trit v nhanh chng hn, hiu qu hn. Cng trnh ny trnh by vic ch to cht lng t CoOFe2O3 bng phng php ng kt ta, xc nh cu trc v tnh cht ca vt liu ny v s dng chng lng

ng kim loi nng trong nc. Cc ht ferit t CoOFe2O3 c cu trc lp phng spinel vi hng s mng a = 8,4 (c xc nh t ph tia X), kch thc ht trung bnh 25 30 nm (xc nh t nh SEM), t ha bo ha v lc khng t kh ln: MS = 50 57 emu/g; HC = 830 1700 Oe (o bang t k mu rung v my o ng cong t tr). Cc ht nano t ny c ph ngoi bng axit Oleic v ha ln vo cn long, nc. II. THC NGHIM Phng php c s dng ch to ht t nano ferit CoOFe2O3 l ng kt ta. Nguyn liu u vo gm FeCl3.6H2O, CoCl2.6H2O, NaOH, NH4OH, c cn theo t l xc nh, c khuy u trong my khuy t nhit khong 80OC, pH = 6 trong vng 30 pht thc hin phn ng kt ta: CoCl2.6H2O + 2(FeCl3.6H2O) + 8NaOH = CoFe2O4 + 8NaCl + 22H2O Sau lng ng ch phm, gn sch nc ri ra sch bng nc ct nhiu ln loi b tp cht, quay ly tm tch hon ton nc, cui cng sy kh bt ta c bt t CoFe2O4. Tip cc ht nano t c ph bng axit oleic tng cng hot tnh b mt, trnh oxy ha v kt t, sau c ha trn trong cn long, ta thu c cht lng t. Ch phm s c kho st cu trc tinh th bng ph nhiu x tia X, xc nh kch thc, hnh dng ht bng chp nh TEM, SEM, kim tra tnh cht t bng vic o t nh t k mu rung VSM. ng dng cht lng t c ch to vo vic lng ng tp cht v kim loi nng ta ly mt lng nh cht lng t (ty theo nng tp cht m c lng cht lng nhiu hay t) pha vo nc bn, khuy u ri dng nam chm vnh cu (hoc nam chm in) t di thng nc bn ht cc ht t c tp cht bm vo, ri xung. Nu kt hp phn chua vi cht lng t th s lm lng ng tp cht v kim loi nng trong nc nhanh hn v trit hn (xem hnh 1)

Cc cht bn trong nc phi sau thi gian di mi lng ng

Al2(SO4)3 to thy phn to keo Al(OH)3 ko cc cht bn lng ng xung di

Ht nano t tnh gip keo Al(OH)3 lm lng ng cht bn nhanh hn khi dng mt t trng ngoi.

Hnh 1: Lng ng cht bn trong nc bng cht lng t

III. KT QU V BNH LUN Cc ht nano t ferit CoOFe2O3 c cu trc tinh th dng lp phng spinel (xc nh t ph nhiu x tia X) vi hng s mng a = 8,4 , kch thc ht c 14 nm (hnh 2 v 3), rt ph hp vi cu trc ca ferit Co kinh in, bit t lu [4].

Hnh 2: Ph nhiu x tia X ca CoFe2O4 [5]

Hnh 3: nh SEM bt nano ferit CoFe2O4 [5]

Cc tnh cht t ca ht t ferit CoOFe2O3 c ch to c gi tr kh tt: t bo ha MS = 50 57 emu/g, lc khng t HC = 828 1751 Oe, rt thch hp cho vic s dng ch to cht lng t dng trong y sinh hc, mi trng v nhiu lnh vc khc (bng 1 v hnh 4). Bng 1: T tnh ca cc ht nano t ferit CoFe2O4 vi ch cng ngh khc nhau [5] M u HA4 HA8 HA12 Nng NaOH (mol/l) 1 2,5 3,5 Nhit (0C) 90 90 90 Ms (emu/g) 57 51 50,5 Hc (Oe) 881 895 920 Ghi ch Sc N2 Sc N2 Sc N2

Hnh 4: ng cong t ph thuc t trng t ha ca mt s ht nano t ferit CoFe2O4 [5] Cht lng t ferit tng hp c gm cc ht nano t CoFe2O4 c kch thc trung bnh t 25 30 nm, cht ph Oleic v cht lng mang ethanol c t l ph hp, c t ha bo ha cao 41 emu/g, nht 13,62 cst, t trng 0,893 g/ml v c nhng tnh nng vt l khc p ng yu cu t ra ca mt cht lng t (bng 2). Bng 2: T tnh ca mt s cht lng t c tng hp [5]. M u Dung mi Nhit (0C) Ms (emu/g) Hc(Oe) 780 n-hexan (30 %) 80 27 HL4 n-hexan 80 21 1450 HL8 41 1294 ethanol 80 HL12 y cho thy vai tr ca dung mi (cht lng mang ht t) rt quan trng : vi ethanol nh, c linh ng cao t lm gim t tnh ca cc ht t ha trn trong . ng dng cc ht nano t CoFe2O4 v cht lng t tng hp c vo vic x l nc bn v nc b nhim kim loi nng c hi nh asen, ch, km, niken, st vi hiu qu rt cao, nhiu mu t hiu sut kh 100% (xem bng 3). iu li ch khc na l sau khi s l nc bn, c kim loi nng, c hi ta vn c th thu hi cc ht t ti s dng bng cch tc pha lng (nc sch) ra khi pha rn (ht nano t hp ph tp cht). Ht nano t s c ra sch bn, sy kh ri dem dng li. T y cho thy cc ht nano t CoFe2O4 c kh nng lm lng ng (kh) kh trit tt c cc kim loi nng, c hi c trong nc. C ch kh tp cht y l nh lc tng tc tnh in v tnh hp ph ca cc ht nano t. Bng 3: Kt qu s l nc c cc kim loi nng bng cht lng t CoFe2O4 [5] K hiu Loi Thi Nng Nng Nng Hiu Ch T m u tiu m u trng gian sut sau phn lng lng trc x l chun kh tch x l (mg/l) (mg/l) ( %) (mg/l) HLPb HLFe HLZn HLNi HLAs Pb Fe Zn Ni As Lng Lng Lng Lng Lng 0,15 T 0,15 T 0,15 T 0,15 T 0,15 T 24 h 17 h 24 h 24 h 24 h 41,3 15,1 17,3 6,4 5,4 KPH* KPH* KPH* KPH* 0,038 0,015 0,015 3 0,1 0,01 100 100 100 100 99,3

Ghi ch: KPH* = khng pht hin VI. KT LUN Cht lng nano t ferit CoFe2O4 c ch to c t tnh tt, c kh nng ng dng trong cc lnh vc Y sinh hc, khoa hc k thut v i sng. Trong cng trnh ny th nghim dng cht lng t CoFe2O4 lng ng cc kim loi nng ha ln trong nc t hiu qu cao c v mt k thut cng nh kinh t. Hon ton c th trin khai quy trnh cng ngh ny p dng vo thc t. V. TI LIU THAM KHO [1]. B.M Berkowsky, Magnetic Fluids Engineering Applications, Oxford university press (1993). [2]. Stuart W. Charles, The preparation of Magnetic Fluids, in Ferrofluids-Magnetically Controllable Fluids and Their Applications, edited by S.Odenbach, Springer (2002). [3]. P. Tartaj, M . P . Morales, etal, The preparation of magnetic nanoparticles for application in biomedicine, J. phys. D. Appl. Phys. 36, (2003), R182. [4]. J. Smit and H.P.J. Wifin, Ferrites, Physical Properties of ferrimagnetit Oxides in relation to their technical applications, Philips Techical Library (1959). [5]. Hunh Th Thu H, Ch to v kho st tnh cht ca cht lng t ferit CoFe2O4 , Lun vn Thc s Vt l, 2008.