n tp HIROCACBON

Cu 1. Dy cc cht u tham gia phn ng trng hp l:

A. etilen, etan, xiclopentan, butan
B. propen, buta-1,3-ien, stiren, isopren
C. etilen, benzen, but-1-en, toluen
D. Pent-1-en, isopren, propan, benzen
Cu 2. Ch dng mt dung dch no sau y phn bit 3 cht lng sau: benzen, toluen, stiren
A. HCl
B. Br2
C. KMnO4
D. NaOH
Cu3 . Hp cht hu c sau c tn gi l: CH3-CH=C(CH3)-CH=CH2
A. 3-metylpent-1,3- ien
B. 3- metylpent-2-en
C. 2-metylbuta-1,3- ien
D. 2- metylpent-2-en
Cu 4. Thc hin phn ng cng theo t l mol 1:1 gia 2-metylbuta-1,3-ien vi HBr th c th thu c
ti a bao nhiu sn phm khc nhau?
A. 6
B. 3
C. 4
D. 5
Cu 5. t chy hon ton mt mol hn hp gm ankin X v ankaien Y thu c 5 mol kh CO2. Lng
oxi cn dng l:
A. 4 mol
B.7 mol
C. 8 mol
D. 6 mol
Cu 6.Ba hidrocabon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp 2 ln
phn t khi ca X. t chy 0,02 mol Y, sn phm chy cho hp th hon ton vo 200 ml dd Ca(OH)2
0,2 M th thu c s gam kt ta l:
A. 3,0 gam
B. 4,8 gam
C. 4,0 gam
D. 2,0 gam
Cu 7. Cho cc cht sau vo dd HCl: CaC2, CaCO3, Al4C3, Al, FeO, C2H2, C6H6. S trng hp c kh
thot ra l:
A. 4
B. 5
C. 3
D. 2
Cu 8. Cho 39 gam mt hidrocacbon thm X tc dng ht vi Br2 lng t l 1:1 c xc tc Fe v un nng
th thu c 78,5 gam sn phm. CTPT ca X l:
A. C9H12
B. C7H8
C. C8H10
D. C6H6
o
Cu 9. Dy cc cht no sau y khi cho tc dng vi H2 d ( Ni, t ) u cho mt sn phm ging nhau:
A. but-1-en, propen, isopren, but-1-in
B. but-2-en, xiclobutan, but-1-in, buta-1,3- ien
C. isopren, but-2-en, xiclopropan, buta-1,3- ien
D. propen, xiclopentan, butan, etilen
Cu 10. Dn hn hp kh X gm 0,12 mol C2H2 v 0,18 mol H2 i qua ng s ng bt Ni nung nng, thu
c kh Y. Dn Y vo bnh ng lng d dung dch Br2 v cn li kh Z i ra. t chy hon ton Z ri
cho sn phm chy vo bnh ng nc vi trong d thu c 12 gam kt ta v khi lng bnh tng
thm 8,88 gam. Khi lng bnh ng Br2 tng:
A. 1,64 gam
B. 1,42 gam
C. 1,4 gam
D. 1,8 gam
Cu 11.t chy hon ton a gam hirocacbon X. Hp th ton b sn phm chy vo bnh ng dung
dch Ca(OH)2 d, to ra 4 gam kt ta , ng thi khi lng bnh ng dung dich Ca(OH)2 sau phn ng
c khi lng tng 2,66 gam.. Gi tr ca a l:
A. 0,56 gam
B.0,58 gam
C. 0,3 gam
D. 0,6 gam
Cu 12. Cho hirocacbon X phn ng vi dd br2 theo t l mol 1:1 thu c cht hu c Y ( cha 69,57 %
brom v khi lng). Khi X tc dng vi HCl th thu c 2 sn phm hu c khc nhau. Tn gi ca X
l:
A. 2- metylbut-2-en
B. but-2-en
C. pent-2-en
D. propen
Cu 13. Crackinh 17,4 gam butan thu c hn hp X gm 5 hirocacbon. t chy hn hp X ri cho
ton b sn phm chy qua bnh ng dung dch Ca(OH)2 d. Khi lng kt ta thu c l:
A. 80 g
B. 120 g
C. 60 g
D. 100 g
Cu 14. phn bit propen, propin, propan. Ngi ta dng cc thuc th no y:
A. dd AgNO3/NH3 v Ca(OH)2
B. dd Br2v KMnO4
C. dd AgNO3/NH3 v dd Br2
D. dd KMnO4/ kh H2
Cu 15. t chy 8,96 lt ( ktc) hn hp X gm 2 olefin A, B ng ng k tip th thy khi lng CO 2
ln hn khi lng H2O l 39 gam. Cng thc phn t ca A, B l:
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C3H6 v C5H10.
D. C4H8 v C5H10.

Cu 16. iu ch thuc n TNT ngi ta cho toluen tc dng vi HNO3 c ( c H2SO4 c xc

tc)theo t l mol tng ng l:
A. 1: 1
B. 3: 1
. C. 1: 3
D. 1:2
Cu 17. Hn hp X gm hai hirocacbon A, B thuc loi ankan, anken hoc ankin. t chy hon ton
6,72 lt (ktc) kh X c khi lng l m gam, v cho tt c sn phm chy hp th hon ton vo bnh
ng nc vi trong d, thy khi lng bnh tng thm 46,5 gam v c 75 gam kt ta. Nu t l khi
lng ca A v B l 22:13, th s gam cht A trong m gam X l
A. 4,4.
B. 4,5.
C. 5,6.
D.6,6.
Cu 18. Nitro ha benzen thu c 2 hp cht nitro X, Y hn km nhau mt nhm NO 2. t chy
hon ton 2,3 gam hn hp X, Y thu c CO 2, H2O v 0,224 lt N2 (ktc). Cng thc phn t ca X,
Y l
A. C6H5NO2 v C6H4(NO2)2.
B. C6H4(NO2)2 v C6H3(NO2)3.
C. C6H5NO2 v C6H3(NO2)3.
D. khng xc nh c.
Cu 19. Crckinh 5,8 gam C4H10 thu c hn hp sn phm X gm H2 v 6 hirocacbon. t chy 1/2
hn hp X th lng H2O thu c l
A. 13,5 gam.
B. 9 gam.
C. 6,3 gam.
D. 4,5 gam.
Cu 20. Cht no sau y thng c dng kch thch hoa qu nhanh chn:
A. Al3C3
B. CaC2
C. CaCO3
D. SiO2
Cu 21. un nng 5,8 gam hn hp A gm C2H2 v H2 trong bnh kn vi xc tc thch hp sau phn
ng c hn hp kh X. Dn hn hp X qua bnh ng dung dch Br 2 d thy bnh tng ln 1,4 gam
v cn li hn hp kh Y. t chy hn hp kh Y thu c 8,8 gam CO 2. Th tch ca hn hp kh Y
ktc l:
A. 13,44 lt.
B. 11,2 lt.
C. 16,8 lt.
D. 17,92 lt.
Cu 22. Ngi ta iu ch PVC t kh thin nhin theo s sau:
CH4C2H2 CH2=CHCl (-CH2-CHCl-)n
Tnh th tch kh thin nhin ( ktc) cn dng iu ch c 12,5 tn PVC, bit rng hiu sut ca
ton b qu trnh iu ch PVC l 90% v metan chim 95% th tch kh thin nhin:
A.8,48 m3
B. 10,48 m3
C. 9,96 m3
11,4 m3
Cu 23. ng trng hp buta-1,3- ien vi stiren thu c polime c tn no sau y:
A. Polistiren
B. Cao su buna
C. Cao su buna-S
D. Cao su buna-N
Cu 24. phn bit 2 cht lng l but-1-in v but-2-in ngi ta dng thuc th no sau y:
A. dd Br2
B. dd KMnO4
C. dd AgNO3/NH3
D. dd HBr
Cu 25. Cho cc phn ng sau:
(1) CH4 + Cl2 CH3Cl+ HCl
(2) C2H4 + Br2 C2H4Br2
(3) C2H2 + HCl CH2=CHCl
(4) C4H6 + O2 CO2 + H2O
(5) C2H4 + H2O C2H5OH
(6) CH2=CH2 + O2 CH3CHO
(7) CH3COONa + NaOH Na2CO3 + CH4
Phn ng no l phn ng oxi ha kh:
A. (1), (2), (4),(6), (7)
B. (1), (2), (3),(6)
C. (1), (2),(6), (7)
D.(1), (2), (5),(3), (7)
Cu 26. Cho toluen tc dng vi Br2 lng c nh sng th thu c sn phm c tn ;
A. o- bromtoluen
B. benzylbromua
C. p- bromtoluen
D. m-bromtoluen
Cu 27. Mt hirocacbon thm X hc c kh nng phn ng vi H2 theo t l mol 1:4, nhng ch phn
ng vi dung dch Br2 theo t l mol 1:1. Tn ca X l:
A. benzen
B. toluen
C. Sitren
D. etylbenzen
Cu 29. X l hn hp kh gm 2 hidrocacbon.t chy hon ton 0,5 lt hn hp X cho 0,75 lt CO2 v
0,75 lt hi H2O ( cc th tch kh o cng iu kin) CTPT ca 2 hirocacbon l:
A. CH4 v C2H2
B. C2H4 v C2H2
C. C2H6 v C2H2
D. C3H8 v C3H4
Cu 30 . Cho cc phn ng sau
X + H2O C2H5OH,
Y + H2 X ,
X + O2 Z,
Y + H2O Z
Vy X, Y, Z ln lt l:
A. CH4, C2H2, HCHO
B. CH4, C2H2, CH3CHO

C. C2H4, C2H2, CH3CHO

D. C2H2, C2H6, CH3CHO

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