CNG TY TNHH QUC T CUC SNG CAO

Copyright @ 2009 - 2010 GioCaoDiem.com

Bi kim tra 1 tit - phn anken TRNG THPT CHUYN CHU VN AN CHNH THC
M :01

Ch nht, 09/01/2011 | 08:41:57 AM

KIM TRA 1 TIT

PHN: ANKEN- ANKIN H v tn HS:..Lp:.. Phn 1: TRC NGHIM KHCH QUAN (5 im) Cu 1: Trong phng th ngim etilen c iu ch bng cch no sau y? A. Cracking butan B. Tch nc t etanol C. Tch HCl t etylclorua D. Tch hiro t etan Cu 2: Cao su bana l sn phm trng hp ca cht no sau y? A. CH2=CH-CH=CH2 B.CH2=C(CH3)CH=CH2 C. CH2 =C=CH-CH3 D.CH2=CH-C6H5 Cu 3: Cho mt hn hp kh X gm hidrocacbon A v kh oxi d vo bnh kn ri t chy , sau lm lnh hn hp kh thu c , thy th tch gim 33.3% so vi th tch hn hp thu c.Nu dn hn hp kh tip tc qua dung dch KOH th tch gim 75% s cn li. CTPT ca A l: A. C3H6 B. C3H4 C.C2H6 D.C4H4 Cu 4: Hn hp X gm mt olefin M v H2 c phn t khi trung bnh 10.67 i qua Ni nung nng thu c hn hp Y c t khi hi so vi H2 l 8. Bit M phn ng ht. CTPT ca M l: A. C3H6 B. C5H10 C.C4H8 D.C2H4 Cu 5: hidro isopentan thu c hidrocacbon X . X tc dng vi A2O/NH3 v t chy sinh ra s mol H2O gp 3 ln s mol X chy. La chn CTCT ph hp ci X: A.CH2=CH-C(ba)CH B. CH(ba)CH C. CH2=C(CH3)-C(ba)CH D.CH3CH(CH3)-C(ba) CH Cu 6: Isopren c th cng Br2 theo t l mol 1:1 to ra bao nhiu ng phn cu to? A. 3 B. 2 C. 4 D.5 Cu 7: Hn hp Z gm 0.15 mol CH4; 0.09 mol C2H2 v 0.2 mol H2. Nung nng hn hp Z vi Ni xc tc thu hn hp Y. Cho Y qua dd nc brom d thu c hh kh A c t khi so vi hiddro l 8. tng khi lng bnh brom l 0.82 g . S gam C2H6 trong A l: A. 2.7g B. 1.8 g C. 180 g D.27.2 g Cu 8: t chy hh X gm 2 hirocacbon mch h ( thuc dy ng ng ankan, anken, ankin) thu c nCO2< nH2O . hn hp X c th gm: A. 2 ankan B. 1 ankan, 1 ankin C. 1 anken, 1 ankan D.A,B,C u ng Cu 9: Cho 2-metylpropen p vi brom nhit cao thu c sn phm hu c X. CTCT ca X l: A.(CH3)2CBrCH2Br B. (CH3)2CHCH2Br C.(CH3)2CBrCH3 D.CH2Br(CH3)C=CH2. Cu 10: C 4 hp cht A,B,C,D c CTPT ln lt l CnHn ; CmH2n; CmH m+n; C3nH m+n. Tng khi lng phn t ca chng l 210 vC. Bit rng B c phn ng vi A2O./NH3 . Vy B l: A. axetilen B. propin C. vinylaxetilen D. but 1 - in

Phn 2 : T LUN ( 5im) Bi 1: Trong mt tinh du chanh c cht limolen C10H16: a) Hidro ha limolen thu c mentan C10H20. Vit phng trnh p v CTCT ca mentan. b) Cho limolen tc dng vi H2O(H+ xc tc)thu c tecpinhidrat C10H20O2 dng lm thuc ho. Vit phng trnh p v CTCT ca tecpinhidrat. Bi 2: Hn hp X gm H2,mt anken A , mt ankin B.Cho hn hp X qua mt lng d dd AgNO3 trong dung dch amoniac thu c 1.61 g kt ta . Hn hp Y thot ra ngoi c th tch bng 90% th tch hh X. Nung X vi xc tc thch hp s hiro ha xy ra hon ton th thu c hh Z ch gm 2 cht kh , c th tch bng 70% th tch ca X . T khi hi ca Z so vi hiro l 9. a) Tnh th tch hn hp X ( KTC) v xc nh CTCTph hp ca A v B. b) Vit cc pt chuyn ha qua li gia A v B ( ng vi CTCT tm c). Bi 3: 1. Cn bng PTP sau: a) etilen + KMnO4 , nng b) 3-anlylxiclohexen -1 + K2Cr2O7 + H2SO4 2. Xc nh cu trc ca mi cht E( C10H16) khng cha nhm ankyl no, c kh nng hp th hiddro theo t l mol 1:1 v khi b ozon phn to ra ixeton i xng F(C10H16O2). -------------------------------------------HT----------------------------------------------