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TRNG I HC CNG NGHIP TP.

H CH MINH
TRUNG TM CNG NGH HA

MN TIU LUN: HA HU C

Ti: Phng php iu ch axit, cc dn xut ca axit v aminoaxit

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</ Kf Nt nhiu ng*i bhEng Xit n axit hgu c haxit cacXox"Kici ha" amino axit K gj nhng th,c Na hk c/ th^ l t\ng gmp v #n deng nh gim K axit axLtic, axit oomic tNong bin vng ha" XBt ngkt K axit gKutamic$ %/i thLo cch bhoa hkc thj Jxit cacXox"Kic K cc h[p cht hgu c tNong phQn tn c/ nh/m cacXox"K hT<pp8i Ki n bt tN,c tip v7i gqc h"dNocacXon$ 8a" n/i cch bhc axit cacXox"Kic K dn xut ca hidNocacXon bhi tha" th 0 homc mBt vi ngu" n tn 8 Xrng nh/m cacXox"Ks ctn Jmino axit K h[p cht t`p ch]c ch]a hai nh/m ch]c K amino v axit tNong phQn tn hidNo cacXon m`ch h@, m`ch vtng ha" thm Ko`i XLnRoit ha" thm d_ vtngH0I$ PhEng chu K #n deng Km XBt ngkt ha" gim m hai axit tN n ctn nhiu hgu =ch bhc tNong cuBc #qng cvng nh nghi n c]u bhoa hoc$ <hwng h`n v axit cacXox"Kic: Jxit axLtic cvng [c #n deng tNong #!n xut thuqc nhuBm bhc nhau cht Ki-u, n7c hoa v Na"on, cht Km Eng te tNong #!n xut cao #us Jxit hgu c [c #n deng cho vi-c chuxn X_ ca nhiu Ko`i thuqc nh a#piNin, phLnacLtins Jxit hgu c [c #n deng tNong th,c phxm, ; uqng K`nhs Jxit Xyo cao hn [c #n deng tNong #!n xut x phtng$ ' amino axit: Jxit amin K c,c bz Wuan tNkng cho #, t;n t`i ca #, #qng v ch{ng c/ mBt vai tNt Wuan tNkng tNong tNao Zi cht ca mBt #inh v|t, thiu aminoTaxit tim X_ tn cEng, Bt Wuc v cao hu"t p,$$ axit amin c/ tNong th_t K[n, #ga, pho mt, nho, da hu, #{p K, bhoai Kang, cAn tQ" v g`o$ Jxit cacXox"Kic v amino axit c/ #}n tNong cc Ko`i th,c phxm, ; d~ng ha" ; uqng nhng ^ c/ [c cc cht / thj ph!i d~ng cc phng php tZng h[p t\ cc cht bhc nhau @ phtng th= nghi-m ha" tNong cEng nghi-p$ <h=nh vj cc axit [c ]ng deng nhiu tNong cuBc #qng m hEm na" tEi c|p n cc phng php iu ch axit, aminoaxit v dn xut ca n/ do cc nh bhoa hkc nghi n c]u ^ tZng h[p n n cc cht phec ve *i #qng con ng*i v mec =ch nghi n c]u bhoa hkc$

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Jminoaxxit KaV hGp chQDt taGo chDc chDa hai nhoDm chDc amin vaV axit tNong phQn tF hiddNocacXon maGch hF, maGch voVng ha" thm KoaGi XLnRoit ha" thm diG voVng$ +ong aminoaxxit phEF Xi Dn nhQDt tNong tG nhi n KaV aminoaxit maGch hF:

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2EGt phng phaDp chung thVng duVng F tEFng hGp aminoaxxit KaV taDc duGng dQn xuQDt haKogLn vDi ammoniac KQD" d:

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PhaFn Dng tN n duVng F tEFng hGp caDc aminoaxit nh , S, ,tV dan xuQDt haKogLn tng Dng:

+ong duVng F tEFng hGp caDc STaminoaxxit thuQGn KGi hn vj t=nh XaR cuFa amino axxit hiVnh thaVnh nhoF hn tiDnh XaRo cuFa taDc nhQn Xan QVu nhi Vu$ :

<aDc haKogLn axit thVng i Vu ch D X(Vng haKogLn hoDa axit bhi coD P ho(Gc X(Vng phng phaDp tEFng hGp L#tL maKonic:

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Phng php tqt hn K d~ng ph!n ]ng anb"K h/a:

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a#tL naV" d anb" hoDa tNong bi Vm ha" hGp chQDt cacXon"K , STcha no$ ThuF" phQn caF hai nhoDm L#tL vaV phtaKimit tNong axit maGnh NEVi LcacXox"K hoDa$ +aFn phQFm thu Gc KaV STaminoaxit NaxLmic hoDa:

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S Taminoaxxit thu Gc bhi taDc duGng ST h"ddNox"nitNin vaV ammoniac F taGo thaVnh aminonitNin NEVi thuF" phQn cho ST amoniaxxit$

PhaFn Dng coD th F ti Dn haVnh tNong hEn hGp anLhit, ammoniac vaV 8<%thLo phaFn Dng +tNichLN Wua giai oaGn hiVnh thaVnh STamonitNin:

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TNong WuaD tNiVnh tEFng hGp caDc hGp chQDt Wuang hoaGt, ngVi ta thu Gc hEn hGp caDc hGp chQDt NaxLmic vaV 6$ uaD tNiVnh taDch Xi Gt caDc hGp chQDt naV" thaVnh caDc hGp chQDt tinh bhi Dt daGng ha" 6 KaV mEGt WuaD tNiVnh h Dt #Dc bhoD bhan, thVng g(Gp tNong WuaD tNiVnh tEFng hopcac# h"ddNox"axit vaV aminoaxit$ 2EGt tNong caDc phng phaDp taDch ha" phQn giaFi aminoaxit KaV #G hiVnh thaVnh muEDi EVng phQn ia$ %hoDm amino chu" Fn thaVnh nhoDm amit bhEng coD tiDnh chQDt Kng tiDnh, thVng duVng cKoNua XLnRo"K:

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ung d_ch N[u Kolng tNBn v7i Acetobacter v gig @ ni thong bh=, m #f t`o Na gim tNong vtng vi thng$ <c phng php #!n xut gim cEng nghi-p, ng*i ta t(ng tqc B ph!n ]ng Xrng cch cung cp nhiu Ex" cho vi bhuxn$ <c KE gim Au ti n [c #!n xut Xrng phng php K n mLn c/ th^ K Ki tNong Wu tNjnh Km N[u vang$ %u hm N[u nho [c K n mLn @ nhi-t B Wu cao, acLtoXactLN #f pht tNi^n Kn n nm mLn c/ mmt t, nhi n tNong nho$ 'j nhu cAu gim cho mec =ch xm th,c, " t, v v- #inh gia t(ng, nhgng ng*i Xn N[u nho hkc nhanh ch/ng cch #n deng cc v|t Ki-u vE c bhc ^ #!n xut gim tNong cc 9M

thng h n/ng tN7c bhi nho l ch=nh v #}n #ng ^ #!n xut N[u vang$ Phng php n" ch|m, tu" nhi n, bhEng ph!i K{c no cvng thnh cEng, bhi nhgng ng*i Xn N[u bhEng hi^u Wu tNjnh n"$ 2Bt tNong nhgng cEng ngh- thng m`i hi-n `i Au ti n K phng php nhanh homc phng php ]c, l [c ]ng deng @ ]c n(m 019M$ TNong phng php n", Wu tNjnh K n mLn di&n Na tNong mBt thp Xkc Xrng g Xo homc than$ <c cht cung cp c;n [c cung cp t\ tN n unh thp, v bhEng bh= #`ch [c cung cp t\ d7i K n Xrng thEng bh= t, nhi n homc Xn qi Ku$ 'i-c cung cp bhEng bh= [c c!i thi n tNong Wu tNjnh n" Km gi!m X7t th*i gian iu ch gim t\ vi thng ctn vi tuAn$ %g" na", hAu ht gim [c #!n xut tNong cc th~ng ^ ngAm [c ptto 8Nomatba v 8LinNich aXnLN #n deng Au ti n n(m 0O4O$ TNong phng php n", N[u [c K n mLn thnh gim tNong X;n [c !o Ki n tec, v Ex" [c cung cp Xrng cch thZi Xkt bh= Wua dung d_ch$ +n deng cc ]ng deng hi-n `i ca phng php n", gim ch]a 0: axit axLtic c/ th^ [c u cht tNong vtng 94 gi*, th|m ch= `t [c B gim 93 tNong vtng 53 gi*$
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$Jxit axLtic K mBt cht ph!n ]ng [c d~ng ^ #!n xut cc h[p cht h/a hkc$ 6[ng #n deng Ni ng K K7n nht K ^ #!n xut momonLN vin"K axLtat, tip thLo K #!n xut axLtic anh"dNit v L#tLN$ 6[ng axit axLtic d~ng ^ #!n xut gim K Nt nh #o v7i @ tN n$ M2'209 K1'E8 *39,*, dng deng ch "u ca axit axLtic K #!n xut monomL vin"K axLtatL$ dng deng n" ti u the bho!ng 43 n 4: #!n K[ng axit axLtic tN n th gi7i$ Ph!n ]ng c/ #, tham gia ca Lt"KLnv7i Ex" v cht x{c tc K paKKadi$

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'in"K axLtatL c/ th^ [c poK"mL h/a t`o thnh poK"vin"K axLtat homc thnh cc poK"mL bhc ]ng deng tNong #n v cht bt d=nh$ Ob' 3@Y, 9;,9 <c L#tL ch=nh #!n xut t\ axit axLtic [c #n deng ch "u Km dung mEi cho m,c, #n vcht ph$ <c L#tL nh Lth"K axLtat, nTXut"K axLtat, i#oXut"K axLtat, v pNop"K axLtat, ch{ng [c #!n xut mBt cch mc Xi-t Xrng ph!n ]ng c/ x{c tc t\ axit axLtic v N[u tng ]ng:

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Tu" nhi n,hAu ht L#tL axLtat [c #!n xut t\ acLtaKdLh"t Xrng ph!n ]ng Ti#hchLnbo$ Th m vo /, cc LtL axLtat [c #n deng Km cc dung mEi ^ Ko`i X nitNocLKKuKo#L, #n acN"Kic, vycTni, v cht tx" g$ Au ti n, gK"coK monoLtL [c t`o Na t\ Lt"KLnL oxit homc pNop"KLn oxit v7i N[u, #au / ch{ng [c L#tL h/a v7i axit axLtic$ )a #!n phxm ch=nh K Lt"KLn gK"coK monoLt"K LtL axLtat haaJi, Lt"KLn gK"coK monoTXut"K LtL axLtat ha)Ji, v pNop"KLn gK"coK monoTmLt"K LtL axLtat hP2Ji$ dng deng n" ti u the bho!ng 0: n 93 #!n K[ng axit axLtic th gi7i$ <c LtL axLtat, v= de nh aaJ, [c cho K c/ h`i qi v7i #]c bhL #inh #!n con ng*i$ A39,17 *'$E<>1, +!n phxm tch phQn tn n7c t\ hai phQn tn axit axLtic t`o thnh mBt phQn tn gki K axLtic anh"dNit$ +!n xut axLtic anh"dNit tN n th gi7i K mBt ]ng deng ch=nh chim bho!ng 9: n M3 #!n K[ng axit axLtic ton cAu$ JxLtic anh"dNit c/ th^ [c #!n xut tN,c tip XrngcacXon"K h/a mLtanoK t\ axit, v cc nh m" #!n xut thLo cEng ngh- <ativa c/ th^ [c iu chunh ^ #!n xut anh"dNit$

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JxLtic anh"dNit K mBt cht acLt"K h/a m`nh$ 'j v|", ]ng deng ch=nh ca n/ K t`o cLKKuKo#L acxtat, mBt cht d-t tZng h[p cvng [c d~ng tNong phim chep !nh$ JxLtic anh"dNit cvng K mBt cht ph!n ]ng d~ng ^ #!n xut a#piNin, hLNoin, v cc h[p cht bhc$ G1Y0 d`ng gim, cc dung d_ch axit axLtic hn;ng B bhqi K[ng ca axit 4 n 01i [c d~ng tN,c tip Km gia v_, v cvng Km cht tNBn Nau v tNong cc th,c phxm bhc$ Gim (n htaXKL vinLgaNi thj Kolng hn h4 n 1i, tNong bhi Ko`i gim tNBn thng m`i thj n;ng B cao hn$ 6[ng axit axLtic d~ng Km gim bhEng chim tu K- K7n tN n th gi7i, nhng K mBt ]ng deng nZi ting v [c d~ng t\ Nt KQu$ LZ0 <@'( 0-1 Jxit axLtic X(ng K mBt dung mEi pNotic phQn c,c tqt nh c|p @ tN n$ %/ th*ng [c d~ng Km dung mEi ti bt tinh cho cc h[p cht hgu c tinh bhit$ Jxit axLtic tinh bhit [c d~ng Km dung mEi tNong vi-c #!n xut axit tLNLphthaKic hTPJi, mBt ngu" n Ki-u thE ^ #!n xut poK"Lt"KLn tLNLphthaKat hPaTi$ %(m 9335, bho!ng 93 axit axLtic [c d~ng ^ #!n xut TPJ$ Jxit axLtic th*ng [c d~ng Km dung mEi cho cc ph!n ]ng Ki n Wuan n cacXocation, nh NiLdLKT<Naot# aKb"Kation$ '= de, mBt giai o`n tNong #!n xut Kong nlo tZng h[p thng m`i Ki n Wuan n #, ti #p xp agnLNT 2LLNLin ca t`o amoLn i#oXoNn"K axLtats @ Q" axit axLtic /ng vai tNt v\a K dung mEi, v\a K cht i nhQn ^ gig caNXocation ti #p xp$ Jxit axLtic K dung mEi t, chkn bhi gi!m mBt nh/m nit aN"K t`o aniKin Xrng cch #n deng cacXon mang paKKadi$ 95

Jxit axLtic X(ng [c #n deng tNong h/a phQn t=ch ^ 7c t=nh cc cht c/ t=nh bim "u nh cc amit hgu c$ Jxit axLtic X(ng c/ t=nh XaR "u hn n7c, vj v|" amit ]ng xn nh mBt XaR m`nh tNong dung d_ch axit tNung Xjnh n"$ +au / n/ c/ th^ [c chuxn B Xrng cch #n deng mBt dung d_ch axit axLtic X(ng ca mBt axit Nt m`nh nh axit pLNcKoNic$ CQ7 c'( <i'( [$Q7 <c axit axLtic Kolng cvng [c d~ng t`o B chua nh$ '= de nh tNong Wu" mE gia jnh, n/ [c d~ng Km cht tx" cmn vEi t\ vti n7c v m un n7c$ <c dung d_ch axit axLtic X(ng Kolng c/ th^ [c d~ng tNong cc phtng th= nghi-m KQm #ng ^ dung gi!i cc h;ng cAu cvng nh m X`ch cAu$ 2Bt ]ng deng KQm #ng bhc K dung gi!i cc h;ng cAu, m c/ th^ Km m* cc thnh phAn Wuan tNkng bhc tNong n7c ti^u bhi phQn t=ch d7i b=nh hi^n vi$

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m. LI BrT
<Eng ngh- ch Xin cc axit ng" cng [c ch{ do vai tNt cvng nh K[i =ch tNong cuBc #qng ng" cng nhiu$ TN n th gi7i c/ Nt nhiu nh m" #!n xut h/a cht mi n(m cho hng tY tn, 2 [c xLm K n7c #!n xu K7n nht, #au / dn TNung uqc$ 'i-t %am c/ bho!ng 93 nh m" #!n xut cc Ko`i h/a cht, ph!i b^ n nh ;ng %ai, 'i-t TNj, Ph{ Thk, Ph{ 2, Pho!ng U: axit axLtic [c #!n xut cEng nghi-p [c d~ng ^ #!n xut thLo phng php cacXon"K h/a mLtanoK$ Pho!ng 0: ctn K`i [c #!n xut t\ cc phng php tha" th bhc$ TZng #!n K[ng axit axLtic gim 7c t=nh bho!ng : tNi-u tn>n(m, bho!ng nna tNong #q / [c #!n xut @ 8oa Pz$ +!n K[ng @ chQu u bho!ng 0 tNi-u tn>n(m v ang gi!m, tNong bhi / %h|t )!n #!n xut bho!ng 3,U tNi-u tn>n(m$ Pho!ng 0,: tNi-u tn [c ti ch hng n(m, nQng tZng #!n K[ng tN n th_ tN7ng th gi7i K n 5,: tNi-u tn>n(m$ 8ai nh #!n xut axit axLtic gim K7n nht K <LKanL#L v <Eng t" h/a )P$ <c nh #!n xut K7n bhc nh 2iKKLnnium <hLmicaK#, +tLNKing hLmicaK#, +am#ung, aa#tman, v +vLn#b atanoKbLmi ' hi-n na" phng php phZ Xin iu ch axit tNong phtng th= nghi-m K oxi h/a ancoK X|c nht v anLhit, i t\ dn xut haKogLn$TNong cEng nghi-p [c iu ch t\ mLtanoK [c cho K phng php hi-n `i nht$ TZng h[p dn xut ca axit ng*i ta i t\ L#tL v aminoaxit i t\ amin h/a cc haKogLn axit $ %g*i ta d,a vo phng php c/ t=nh hi-n `i p deng cho #!n xut cEng nghi-p, =t tqn bym ^ tZng h[p axit / K i t\ mLthanoK$

91

mI. TsI LIU THAM BHnW


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