16 Chuyen de On Thi Dai Hoc

Chu Anh Tun -
- 0935166002
Trng THPT s 1 Ngha Hnh
Lu hanh noi bo Thang 1 nam 2013
16 chuyn n thi i hc, cao ng 2012 - 2013
Trang 1
Chu Anh Tun -
- 0935166002
Chuyn 1:
CU TO NGUYN T, BNG TUN HON CC NGUYN T
Cu 1. Cu hnh electron ca nguyn t Mg (Z = 12) l 2 2 6 2 1 2 2 6 2 2 2 6 1 2 2 6 A. 1s 2s 2p 3s 3p . B. 1s 2s 2p 3s . C. 1s 2s 2p 3s . D. 1s 2s 2p . Cu 2. Cu hnh electron lp ngoi cng ca nguyn t kim loi kim th l 2 2 2 1 2 1 A. ns np . B. ns np . C. ns . D. ns . Cu 3. Cu hnh electron lp ngoi cng ca nguyn t nguyn t Al (Z = 13) l 2 1 1 2 2 3 2 2 B. 3s 3p . C. 3s 3p . D. 3s 3p . A. 3s 3p . Cu 4.Cng thc chung ca cc oxit kim loi nhm IIA l A. RO2. B. R2O3. C. R2O. D. RO. Cu 5.Cng thc chung ca oxit kim loi thuc phn nhm chnh nhm I l A. RO2. B. R2O3. C. R2O. D. RO. Cu 6.Cng thc chung ca oxit kim loi thuc phn nhm chnh nhm II l A. RO. B. R2O3. C. R2O. D. RO2. Cu 7.Dy cc hiroxit c xp theo th t tnh baz gim dn t tri sang phi l B. Mg(OH)2, Al(OH)3, NaOH. A. Mg(OH)2, NaOH, Al(OH)3. C. NaOH, Al(OH)3, Mg(OH)2. D. NaOH, Mg(OH)2, Al(OH)3. Cu 8.Hai kim loi u thuc nhm IIA trong bng tun hon l A. Sr, K. B. Be, Al. C. Ca, Ba. D. Na, Ba. 2 2 6 1 Cu 9.Nguyn t kim loi c cu hnh electron 1s 2s 2p 3s l A. Li (Z = 3). B. Mg (Z = 12). C. Na (Z = 11). D. K (Z = 19). Cu 10.S electron lp ngoi cng ca cc nguyn t kim loi thuc phn nhm chnh nhm II l A. 1. B. 3. C. 4. D. 2. Cu 11.S electron lp ngoi cng ca nguyn t kim loi kim l A. 2. B. 1. C. 3. D. 4. Cu 12.Tnh baz ca cc hiroxit c xp theo th t gim dn t tri sang phi l A. NaOH, Mg(OH)2, Al(OH)3. B. NaOH, Al(OH)3, Mg(OH)2. D. Mg(OH)2, Al(OH)3, NaOH. C. Mg(OH)2, NaOH, Al(OH)3. Cu 13.Trong bng tun hon cc nguyn t ha hc, kim loi kim thuc nhm A. IVA. B. IIIA. C. IA. D. IIA. Cu 14. Cho cc hiroxit: NaOH, Mg(OH)2, Fe(OH)3, Al(OH)3. Hiroxit c tnh baz mnh nht l A. Al(OH)3. B. Fe(OH)3. C. NaOH. D. Mg(OH)2. Cu 15.Dy cc kim loi c xp theo chiu gim dn tnh kh l: A. K, Zn, Cu. B. Cu, K, Zn. C. K, Cu, Zn. D. Zn, Cu, K. 3+ Cu 16.St (Fe) s 26 ca bng tun hon cc nguyn t ha hc. Cu hnh electron ca ion Fe l 6 1 4 2 3 5 A. [Ar]3d . B. [Ar]4s 3d . C. [Ar]4s 3d . D. [Ar]3d . Cu 17.Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc nguyn t tng dn theo th t A. Y < M < X < R. B. M < X < Y < R. C. R < M < X < Y. D. M < X < R < Y. Cu 18.Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA, nguyn t Y nhm VA. Cng thc ca hp cht to thnh t 2 nguyn t trn c dng l B. X3Y2. C. X2Y5. D. X2Y3. A. X5Y2. 2 2 6 2 6 1 Cu 19.Nguyn t ca nguyn t X c cu hnh electron 1s 2s 2p 3s 3p 4s , nguyn t ca nguyn t Y c cu 2 2 5 hnh electron 1s 2s 2p . Lin kt ho hc gia nguyn t X v nguyn t Y thuc loi lin kt A. cng ho tr. B. ion. C. cho nhn. D. kim loi. Cu 20. Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l: B. HF, Cl2, H2O. C. O2, H2O, NH3. D. H2O, HF, H2S. A. HCl, O3, H2S. Cu 21. Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l A. phi kim v kim loi. B. kim loi v kim loi. C. kh him v kim loi. D. kim loi v kh him. Cu 22. Lin kt ho hc gia cc nguyn t trong phn t H2O l lin kt A. cng ho tr phn cc. B. ion. C. cng ho tr khng phn cc. D. hiro.
16 chuyn n thi i hc, cao ng 2012 - 2013 Trang 2
Chu Anh Tun -
- 0935166002
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2 6 1 2 2 6 2
Cu 23.Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l: 1s 2s 2p 3s ; 1s 2s 2p 3s ; 2 2 6 2 1 1s 2s 2p 3s 3p . Dy gm cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l: A. Z, X, Y. B. Y, Z, X. C. Z, Y, X. D. X, Y, Z. 2+ 2 6 Cu 24.Anion X v cation Y u c cu hnh electron lp ngoi cng l 3s 3p . V tr ca cc nguyn t trong bng tun hon cc nguyn t ha hc l: A. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). B. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). C. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 3, nhm IIA (phn nhm chnh nhm II). D. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). + 2 2 6 Cu 25. Dy gm cc ion X , Y v nguyn t Z u c cu hnh electron 1s 2s 2p l: + + + + A. Na , Cl , Ar. B. Na , F , Ne. C. Li , F , Ne. D. K , Cl , Ar. Cu 26.Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu tng ca in tch ht nhn nguyn t th A. tnh kim loi tng dn, m in tng dn. B. tnh kim loi tng dn, bn knh nguyn t gim dn. C. tnh phi kim gim dn, bn knh nguyn t tng dn. D. m in gim dn, tnh phi kim tng dn. Cu 27. Bn knh nguyn t ca cc nguyn t:3Li, 8O, 9F, 11Na c xp theo th t tng dn t tri sang phi l A. F, Na, O, Li. B. F, Li, O, Na. C. F, O, Li, Na. D. Li, Na, O, F. Cu 28. Hp cht trong phn t c lin kt ion l A. NH4Cl. B. H2O. C. HCl. D. NH3. Cu 29. Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l: A. P, N, O, F. B. P, N, F, O. C. N, P, O, F. D. N, P, F, O. 2+ 2 2 6 2 6 6 Cu 30. Cu hnh electron ca ion X l 1s 2s 2p 3s 3p 3d . Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc A. chu k 4, nhm VIIIA. B. chu k 4, nhm IIA. C. chu k 4, nhm VIIIB. D. chu k 3, nhm VIB. Cu 31.Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: A. K, Mg, Si, N. B. N, Si, Mg, K. C. K, Mg, N, Si. D. Mg, K, Si, N. Cu 32.Pht biu no sau y l ng? A. Photpho trng c cu trc tinh th nguyn t. B. Kim cng c cu trc tinh th phn t. C. Nc thuc loi tinh th phn t. D. th rn, NaCl tn ti di dng tinh th phn t. Cu 33.Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th A. bn knh nguyn t v m in u tng. B. bn knh nguyn t tng, m in gim. C. bn knh nguyn t v m in u gim. D. bn knh nguyn t gim, m in tng. 26 26 Cu 34.Nhn nh no sau y ng khi ni v 3 nguyn t: 13X,5526Y, 12Z? A. X v Y c cng s ntron. B. X, Z l 2 ng v ca cng mt nguyn t ho hc. C. X v Z c cng s khi. D. X, Y thuc cng mt nguyn t ho hc. Cu 35.Cc cht m phn t khng phn cc l: B. Cl2, CO2, C2H2. C. HCl, C2H2, Br2. D. NH3, Br2, C2H4. A. HBr, CO2, CH4. 2+ 3+ Cu 36.Cu hnh electron ca ion Cu v Cr ln lt l 7 2 1 2 9 3 A. [Ar]3d 4s v [Ar]3d 4s . B. [Ar]3d v [Ar]3d . 7 2 3 9 1 2 C. [Ar]3d 4s v [Ar]3d . D. [Ar]3d v [Ar]3d 4s . Cu 37. Pht biu no sau y l sai? A. Tinh th nc , tinh th iot u thuc loi tinh th phn t. B. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ho tr. C. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht. D. Tt c cc tinh th phn t u kh nng chy v kh bay hi. Cu 38.Cu hnh electron ng ca nguyn t Cu (Z = 29) l: 2 2 6 2 6 10 1 2 2 6 2 6 9 2 A. 1s 2s 2p 3s 3p 3d 4s B. 1s 2s 2p 3s 3p 3d 4s 2 2 6 2 6 1 10 2 2 6 2 6 2 9 C. 1s 2s 2p 3s 3p 4s 3d D. 1s 2s 2p 3s 3p 4s 3d Cu 39.Cu hnh electron lp v ngoi cng ca mt ion l 2p6. Cu hnh electron ca nguyn t to ra ion l:
Chu Anh Tun -
- 0935166002
A. 1s2 2s2 2p5. B. 1s2 2s2 2p4. C. 1s2 2s2 2p6 3s1. D. Tt c u c th ng. Cu 40.Cho ba nguyn t c cu hnh electron ln lt l: X: 1s22s22p63s1 ; Y: 1s22s22p63s2 ; Z: 1s22s22p63s23p1. Hiroxit ca X, Y, Z xp theo th t tng dn tnh baz l: A. XOH < Y(OH)2 < Z(OH)3 B. Y(OH)2 < Z(OH)3 < XOH D. Z(OH)2 < Y(OH)3 < XOH C. Z(OH)3 < Y(OH)2 < XOH Cu 41.Cho cc cht sau: HCl, NaCl, LiCl, NH4Cl, HF. S cht m phn t ch gm lin kt cng ho tr l: A. 1 B. 3 C. 4 D. 2 Cu 42.Cho cc nguyn t v ion sau: Na, Na+, Mg2+, Mg, Al, Al3+, F-, O2-. Th t gim dn theo bn knh nguyn t l:
2+ 2+ + 3+ 2+ 23+ 2+ + 3+ 2+ + 3+ 22-
A. Na >Mg >Al >O >F >Na >Mg >Al
B. Mg >Al >Na >O >F >Mg >Al >Na
C. Na >Mg >Al >Na >Mg >Al >O >F D. Na >Mg >Al >O > F >Na > Mg >Al Cu 43.Cho cu hnh e ca ion X2+ l:[Ar] 3d4 cu hnh ca nguyn t X l: A. [Ar] 3d6. B. [Ar] 4s13d5. C. [Ar] 3d44s2 D. [Ar] 3d54s1. 2+ 2 2 6 2 6 4 Cu 44.Cho cu hnh e ca ion X l:1s 2s 2p 3s 3p 3d cu hnh ca nguyn t X l: A. 1s22s22p63s23p64s23d6 B. 1s22s22p63s23p64s13d5 C. 1s22s22p63s23p63d44s2 D. 1s22s22p63s23p63d54s1 2Cu 45. Cho ion X (Z=16) .Vy cu hnh electron ca nguyn t X l 2 2 6 2 A. 1s 2s 2p 3s 3p4 B. 1s22s22p63s23p6 C. 1s22s22p63s23p5 D. 1s22s22p63s23p2 Cu 46. phn cc lin kt trong cc cht CH4 , NH3 , H2O , HF tng dn t tri sang phi theo trt t no sau y A. CH4 , NH3 , H2O , HF B. H2O , NH3 , CH4 , HF C. HF , H2O , NH3 , CH4 D. NH3 , CH4 , HF , H2O Cu 47.Ha tan st kim loi trong dung dch HCl. Cu hnh electron ca cation kim loi c trong dung dch thu c l B. [Ar] 3d6 C. [Ar] 3d54s1 D. [Ar] 3d44s2 A. [Ar] 3d5 Cu 48.Kt lun no biu th ng v kch thc ca nguyn t v ion? A. Na < Na+, F > F-. B. Na < Na+, F < F-. C. Na > Na+, F > F-. D. Na > Na+, F < F-. Cu 49.Trong 20 nguyn t u tin ca bng tun hon, c bao nhiu nguyn t c 2 electron c thn trng thi c bn A. 2 B. 4 C. 5 D. 6. Cu 50.Trong cu hnh electron ca nguyn t nguyn t M, phn lp electron c mc nng lng cao nht l 3d7. V tr ca nguyn t M trong bng tun hon l: A. Chu k 3, nhm VII.B B. Chu k 3, nhm VIII.B C. Chu k 4, nhm VII.B D. Chu k 4, nhm VIII.B Cu 51.X l nguyn t c 12 proton, Y l nguyn t c 17 electron.Cng thc hp cht hnh thnh gia hai nguyn t ny c th l ? D.XY B.XY2 C.X2Y A.X2Y3 Cu 52.X v Y l 2 kim loi thuc nhm A. Bit ZX + ZY = 32 v ZX < ZY. Kt lun ng l A. tnh kim loi ca X > Y B. nng lng ion ha I1 ca X < Y C. X v Y u c 2e lp ngoi cng D. bn knh nguyn t ca X > Y 63 65 Cu 53.Trong t nhin, nguyn t ng c hai ng v l Cu v Cu. Nguyn t khi trung bnh ca ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v 63Cu l A. 50%. B. 54%. C. 73%. D. 27%. Cu 54. Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l (bit s hiu nguyn t ca nguyn t: Na = 11; Al = 13; P = 15; Cl = 17; Fe = 26) A. Na v Cl. B. Al v Cl. C. Al v P. D. Fe v Cl. Cu 55. Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c s khi l 35. S hiu nguyn t ca nguyn t X l A. 23. B. 15. C. 18. D. 17. Cu 56. Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l A. NaF. B. AlN. C. MgO. D. LiF. Cu 57. Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m Rc ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l A. P. B. As. C. N. D. S. 2 4 Cu 58. Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns np . Trong hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong oxit cao nht l A. 27,27%. B. 60,00%. C. 40,00%. D. 50,00%. 3+ Cu 59. Mt ion M c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l 6 1 3 2 5 1 6 2 A. [Ar]3d 4s . B. [Ar]3d 4s . C. [Ar]3d 4s . D. [Ar]3d 4s .
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Chu Anh Tun -
- 0935166002
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Cu 60. Khi lng ring ca canxi kim loi l 1,55 g/cm . Gi thit rng, trong tinh th canxi cc nguyn t l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi tnh theo l thuyt l A. 0,155 nm. B. 0,185 nm. C. 0,196 nm. D. 0,168 nm. Cu 61. Trong t nhin clo c hai ng v bn: Cl35 chim 24,23% tng s nguyn t, cn li l Cl37. Thnh phn % theo khi lng ca Cl37 trong HClO4 l A. 8,56%. B. 8,79%. C. 8,92%. D. 8,43%. Cu 62.Gi s H c 3 ng v, S c 1 ng v, O c 3 ng v. S phn t H2SO4 c th c l: A. 72 B. 90 C. 378 D. kt qu khc Cu 63.Hai nguyn t X v Y thuc cng mt chu k v hai nhm A lin tip c tng s ht proton l 25. Vy v tr ca X v Y trong bng h thng tun hon l: A. chu k 3, nhm IIIA v IVA. B. chu k 3, nhm VIA v VIIA. C. chu k 3, nhm IIA v IIIA. D. chu k 2, nhm VIIA v VIIIA. Cu 64.Nguyn t X c hai ng v, c t l s nguyn t ca ng v I v II l 27/23. Ht nhn ca X c 35 proton. ng v I c 44 ntron, ng v II c nhiu hn ng v I l 2 ntron. Nguyn t khi trung bnh ca nguyn t X l: A. 79,2 B. 78,9 C. 79,92 D. 80,5 Cu 65.Nguyn t nguyn t X c tng s ht (p, n, e) l 76, trong s ht mang in nhiu hn s ht khng mang in l 20 ht. Cu hnh electron nguyn t nguyn t X l: A. 1s22s22p63s23p63d54s1 B. 1s22s22p63s23p63d44s2 C. 1s22s22p63s23p64s13d5 D. 1s22s22p63s23p64s23d4 Cu 66.Phn t RnX c 82 ht proton. Tng s ht proton, electron, ntron trong nguyn t R v X ln lt l 122 v 24. S hiu nguyn t R l: A. 37 B. 38 C. 40 D. 42 Cu 67.Tng s ht c bn trong ion X2- l 50 v trong X2- c s ht mang in gp 2,125 ln s ht khng mang in. S ht proton, notron, electron trong X l A. 16, 16, 18 B. 16, 16, 16 C. 17, 17, 16 D. 17, 16, 17 Cu 68.Trong t nhin Cu c 2 ng v 29Cu65 v 29Cu63. Khi lng nguyn t trung bnh ca Cu l 63,54. Bit MCl = 35,5. Thnh phn % v khi lng ca 29Cu63 trong CuCl2 l A. 12,64% B. 26,77% C. 27,00% D. 34,18%
Chuyn 2:
PHN NG OXIHA-KH CN BNG, TC PHN NG
Phn 1. L THUYT PHN NG OXIHO - KH. Cu 1. Cho phn ng: a Fe + b HNO3 c Fe(NO3)3 + d NO + e H2O. Cc h s a, b, c, d, e l nhng s nguyn, n gin nht. Tng (a+b) bng A. 5. B. 6. C. 4. D. 3. Cu 2. Phn ng thuc loi phn ng oxi ho - kh l A. CaCO3 + 2HCl CaCl2 + CO2 + H2O. + Cu. B. Zn + CuSO4 ZnSO4 C. MgCl2 + 2NaOH Mg(OH)2 + 2NaCl. D. CaO + CO2 CaCO3. Cu 3. S oxi ha ca crom trong hp cht Cr2O3 l A. +2. B. +3. C. +6. D. +4. Cu 4. Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn xy ra 2+ A. s oxi ha Fe v s oxi ha Cu. B. s kh Fe v s oxi ha Cu. 2+ 2+ 2+ C. s kh Fe v s kh Cu . D. s oxi ha Fe v s kh Cu . Cu 5. Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O. Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l A. 23. B. 27. C. 31. D. 47. Cu 6. Cho cc phn ng sau: a) FeO + HNO3 (c, nng) b) FeS + H2SO4 (c, nng) c) Al2O3 + HNO3 (c, nng) d) Cu + dung dch FeCl3 e) CH3CHO + H2 f) glucoz + AgNO3 (hoc Ag2O) trong dung dch NH3 g) C2H4 + Br2 h) glixerol (glixerin) + Cu(OH)2
Chu Anh Tun -
- 0935166002
Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l: A. a, b, c, d, e, h. B. a, b, d, e, f, g. C. a, b, c, d, e, g. D. a, b, d, e, f, h. Cu 7. Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 6. C. 5. D. 7. Cu 8. Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s A. nhn 12 electron. B. nhn 13 electron. C. nhng 12 electron. D. nhng 13 electron. Cu 9. Cho cc phn ng sau: 4HCl + MnO2 MnCl2 + Cl2 + 2H2O. 2HCl + Fe FeCl2 + H2. 14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O. 6HCl + 2Al 2AlCl3 + 3H2. 16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O. S phn ng trong HCl th hin tnh oxi ha l A. 2. B. 4. C. 1. D. 3. Cu 10. Cho cc phn ng: 2H2S + SO2 3S + 2H2O Ca(OH)2 + Cl2 CaOCl2 + H2O 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O . 4KClO3 t KCl + 3KClO4 O3 O2 + O S phn ng oxi ho kh l A. 4. B. 3. C. 2. D. 5. + 2+ 2+ 3+ 2+ 2Cu 11. Cho dy cc cht v ion: Cl2, F2, SO2, Na , Ca , Fe , Al , Mn , S , Cl . S cht v ion trong dy u c tnh oxi ho v tnh kh l A. 5. B. 6. C. 4. D. 3. 2+ Cu 12. Cho dy cc cht v ion: Zn, S, FeO, SO2, N2, HCl, Cu , Cl . S cht v ion c c tnh oxi ha v tnh kh l A. 6. B. 5. C. 4. D. 7. Cu 13. Thc hin cc th nghim sau: (II) Sc kh SO2 vo dung dch H2S. (I) Sc kh SO2 vo dung dch KMnO4. (III) Sc hn hp kh NO2 v O2 vo nc. (IV) Cho MnO2 vo dung dch HCl c, nng. (V) Cho Fe2O3 vo dung dch H2SO4c, nng. (VI) Cho SiO2 vo dung dch HF. S th nghim c phn ng oxi ho - kh xy ra l A. 6. B. 5. C. 3. D. 4. Cu 14. Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp c xy ra phn ng oxi ho - kh l A. 3. B. 4. C. 6. D. 5. Cu 15. Cht no sau y ch th hin tnh kh trong cc phn ng oxi ha - kh ? A.H2S B.HNO3 C.Cl2 D.O3 Cu 16. Cho cc phn ng sau : 4. St(TT) oxit + dung dch HNO3 1. St t oxit + dung dch HNO3 2. St (TTT) oxit + dung dch HNO3 5. HCl + NaOH 3. Mg( kim loi ) + HCl 6. Cu + dung dch H2SO4 c nng Phn ng oxi ha kh l : A.1,3,4,6 B.1,3,4 C.1,2,3,4 D.3,4,5,6 Cu 17. Chn phng n ng, phn ng khng thuc loi oxi ha kh l: A. Phn ng thy phn B. Phn ng th C. Phn ng kt hp D. Phn ng phn hy Cu 18. Mi cht v ion trong dy sau va c tnh kh, va c tnh oxi ho:
o
3+
2+
2+
2+
A. SO2, S, Fe . B. Fe , Fe, Ca, KMnO4. C. SO2, Fe , S, Cl2. Phn 2. CN BNG HO HC, TC PHN NG. Cu 19. Cho phng trnh ho hc ca phn ng tng hp amoniac N2 (k) + 3H2 (k)
t o , xt p
D. SO2, S, Fe , F2.
2NH3 (k)
D. gim i 2 ln.
Khi tng nng ca hiro ln 2 ln, tc phn ng thun A. tng ln 2 ln. B. tng ln 8 ln. C. tng ln 6 ln. Cu 2.Cho cc cn bng ho hc: (1)N2(k) + 3H2(k) 2NH3(k) (3)2SO2 (k) + O2 (k) 2SO3 (k)
(2)H2(k) + I2(k) 2HI (k) (4)2NO2 (k) N2O4 (k)

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Khi thay i p sut nhng cn bng ha hc b chuyn dch l:
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A. (1), (2), (4). B. (2), (3), (4). C. (1), (3), (4). Cu 3. Hng s cn bng ca phn ng xc nh ch ph thuc vo A. p sut. B. nng . C. cht xc tc. Cu 4. Cho cc cn bng sau: (1) 2SO2(k) + O2(k) 2SO3(k)
D. (1), (2), (3). D. nhit .
(2) N2(k) + 3H2(k) 2NH3(k)
(4) 2HI (k) H2 (k) + I2(k) (3) CO2 (k) + H2 (k) CO (k) + H2O (k) Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l A. (2) v (4). B. (3) v (4). C. (1) v (3). D. (1) v (2). Cu 5. Cho cc cn bng sau: (1) H2(k) + I2(k) 2HI (k) (3) HI(k) 1/2H2(k) + 1/2I2(k) (2) 1/2H2(k) + 1/2I2(k) HI(k) (4) 2HI(k) H2(k) + I2(k)
(5) H2(k) + I2(r) 2HI(k) nhit xc nh, nu KC ca cn bng (1) bng 64 th KC bng 0,125 l ca cn bng A. (3). B. (2). C. (4). D. (5). Cu 6. Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k) CO2 (k) + H2 (k) H < 0 Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H2; (4) tng p sut chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l: A. (1), (4), (5). B. (2), (3), (4). C. (1), (2), (3). D. (1), (2), (4). Cho cn bng ho hc: PCl (k) PCl (k) + Cl (k); >0 Cu 7. 5 3 2 Cn bng chuyn dch theo chiu thun khi A. tng nhit ca h phn ng. B. thm Cl2 vo h phn ng. C. tng p sut ca h phn ng. D. thm PCl3 vo h phn ng. Cu 8. Cho phn ng: Br2 + HCOOH 2HBr + CO2. Nng ban u ca Br2 l a mol/lt, sau 50 giy nng Br2 cn li l 0,01 mol/lt. Tc trung bnh ca phn -5 ng trn tnh theo Br2 l 4.10 mol/(l.s). Gi tr ca a l A. 0,014. B. 0,016. C. 0,018. D. 0,012. Cu 9. Cho cn bng ha hc: N2(k) + 3H2(k) 2NH3(k). H < 0. Cn bng trn chuyn dch theo chiu thun khi A. tng nhit ca h phn ng. B. tng p sut ca h phn ng. C. gim p sut ca h phn ng. D. thm cht xc tc vo h phn ng. Cu 10. Cho phn ng: H2 (k) + I2 (k) 2HI (k) nhit 430C, hng s cn bng KC ca phn ng trn bng 53,96. un nng mt bnh kn dung tch khng i 10 lt cha 4,0 gam H2 v 406,4 gam I2. Khi h phn ng t trng thi cn bng 430C, nng ca HI l A. 0,151M. B. 0,225M. C. 0,275M. D. 0,320M. Cu 11. Cho cn bng ho hc: 2SO2(k) + O2(k) 2SO3(k); phn ng thun l phn ng to nhit. Pht biu ng l: A. Cn bng chuyn dch theo chiu nghch khi gim nng SO3. B. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng. C. Cn bng chuyn dch theo chiu thun khi tng nhit . D. Cn bng chuyn dch theo chiu nghch khi gim nng O2. Cu 12. Cho cn bng ho hc: N2(k) + 3H2(k) 2NH3(k); phn ng thun l phn ng to nhit. Cn bng ho hc khng b chuyn dch khi A. thay i p sut ca h. B. thay i nhit . C. thm cht xc tc Fe.
D. thay i nng N2.
Cu 13. Cho cn bng sau trong bnh kn: 2NO2(k) N2O4(k). (mu nu ) (khng mu) Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c A. H > 0, phn ng ta nhit. B. H < 0, phn ng ta nhit. C. H > 0, phn ng thu nhit. D. H < 0, phn ng thu nhit. Cu 14. Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 ( ktc). Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l A. 2,5.10-4 mol/(l.s). B. 1, 0.10-3 mol/(l.s). C. 5, 0.10-5 mol/(l.s). D. 5, 0.10-4 mol/(l.s). Cu 15. Cho cn bng: 2SO2(k) + O2(k) 2SO3(k). Khi tng nhit th t khi ca hn hp kh so vi H2 gim
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i. Pht biu ng khi ni v cn bng ny l: A. Phn ng thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit . B. Phn ng thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit . C. Phn ng nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit . D. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit . Cu 16. Xt cn bng: N2O4(k) 2NO2(k) 25 C. Khi chuyn dch sang mt trng thi cn bng mi nu nng ca N2O4tng ln 9 ln th nng ca NO2 A. gim 3 ln. B. tng 9 ln. C. tng 3 ln. D. tng 4,5 ln. Cu 17. Cho cc cn bng sau: (I) 2HI (k) H2(k) + I2(k); (II) CaCO3(r) CaO (r) + CO2(k); (IV) 2SO2(k) + O2(k) 2SO3(k). (III) FeO (r) + CO (k) Fe (r) + CO2 (k); Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l A. 3. B. 1. C. 4. D. 2. Cu 18. Cho cn bng ho hc: H2(k) + I2(k) 2HI (k); H > 0. Cn bng khng b chuyn dch khi A. tng nhit ca h. B. tng nng H2. C. gim nng HI. D. gim p sut chung ca h. Cu 19. Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10 lt. Nung nng bnh mt thi o gian 830 C h t n trng thi cn bng: CO (k) + H2O (k) CO2(k) + H2(k). (hng s cn bng KC = 1). Nng cn bng ca CO, H2O ln lt l A. 0,008M v 0,018M. B. 0,018M v 0,008M. C. 0,012M v 0,024M. D. 0,08M v 0,18M. Cu 20. Cho cn bng ho hc sau: 2SO2 (k) + O2 (k) 2SO3 (k); H < 0. Cho cc bin php: (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4) dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo chiu thun? A. (2), (3), (5). B. (2), (3), (4), (6). C. (1), (2), (4). D. (1), (2), (4), (5). Cu 21. Cho cc cn bng ho hc: H2 (k) + I2 (k) 2HI (k) (2) N2 (k) + 3H2 (k) 2NH3 (k) (1) 2NO2 (k) N2O4 (k) (4) 2CO(k) + O2 (k) 2CO2 (k) (3) Khi thay i p sut nhng cn bng ho hc khng b chuyn dch l: A. (2) B. (1), (3), (4). C. (1), (2). D. (2), (3), (4) Cu 22. Cho cn bng ha hc: aA + bB cC + dD 1050C s mol cht D l x mol cn 1800C s mol cht D l y mol. Bit x > y v (a + b) > (c + d). Cc cht trong cn bng u pha kh. Kt lun ng l A. Phn ng thun thu nhit v lm gim p sut B. phn ng thun ta nhit v lm tng p sut C. phn ng thun thu nhit v lm tng p sut D. phn ng thun ta nhit v lm gim p sut Cu 23. Cho cn bng N2 (k) + 3H2(k) 2NH3(k) + Q. C th lm cn bng dung dch v pha to thm NH3 bng cch: A. H bt nhit xung B. Thm cht xc tc C. H bt p sut xung D. H bt nng N2 v H2 xung Cu 24. Cho cn bng sau thc hin trong bnh kn: CO(k) + H2O(k)CO2(k) + H2(k) H<0. Khi tng p sut th cn bng s: A. chuyn dch theo chiu nghch B. khng chuyn dch C. chuyn dch theo chiu thun D. dng li ngay Cu 25. Cho CO2 li t t vo dung dch cha KOH v Ca(OH)2, c th xy ra cc phn ng sau: 2. CO2 + Ca(OH)2 CaCO3 + H2O K2CO3 + H2O 1. CO2 + 2KOH 3. CO2 + CaCO3 + H2O Ca(HCO3)2 4. CO2 + K2CO3 + H2O 2KHCO3 Th t cc phn ng xy ra l: A. 1, 2, 3, 4. B. 1, 2, 4, 3. C. 2,1,4,3. D. 2, 1, 3, 4. Cu 26. Cho phn ng sau: H2O (k) + CO (k) H2 (k) + CO2(k) o 700 C hng s cn bng l K = 1,873. Bit rng hn hp u gm 0,300 mol H2O v 0,300 mol CO trong bnh 10 lt 700oC. Nng ca H2O v CO trng thi cn bng ln lt l: A. 0,01267M B. 0,01733M C. 0,1267M D. 0,1733M Cu 27. Cho phng trnh X + Y Z + T . Ngi ta trn 4 cht X, Y, Z, T mi cht 1 mol vo bnh kn th khi cn bng c thit lp, lung cht T l 1,5 mol.Hng s cn bng ca phn ng l bao nhiu trong cc s di y: A.8 B.9 C.10 D.7
o
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Cu 28. Hin nay, khi gi nhin liu t du m tng cao th vic s dng cc nhin liu thay th l rt cn thit. Trong cng nghip, iu ch kh than t, mt loi nhin liu kh, ngi ta thi hi nc qua than ang nng . Phn ng ho hc xy ra nh sau: C (r) + H2O (k) CO(k) + H2 (k) H = 131kJ. iu khng nh no sau y l ng? A. Tng nng hiro lm cn bng chuyn sang chiu thun. B. Tng p sut chung ca h lm cn bng khng thay i. C. Dng cht xc tc lm cn bng chuyn sang chiu thun. D. Tng nhit ca h lm cn bng chuyn sang chiu thun. Cu 29. Khi ha tan SO2 vo H2O c cn bng sau: SO2 + HOH
H2SO3 (1);
H2SO3 H+ +HSO3- (2);
HSO3- H+ + SO32- (3); nng SO2 thay i th no khi: Thm dung dch NaOH v thm dung dch HCl; A. [SO2] u tng B. [SO2] u gim C. [SO2] khng thay i D. [SO2] gim; [SO2] tng 2NH3(k) c ng dng quan trng trong cng Cu 30. Phn ng tng hp amoniac 2N2(k) + 3H2(k) nghip ho cht. T amoniac, ngi ta sn xut phn m, axit nitric, thuc n Hi tc ca phn ng tng hp amoniac s tng bao nhiu ln nu tng nng hiro ln 2 ln khi nhit ca phn ng c gi nguyn ? A. 8 ln. B. 4 ln. C. 16 ln. D. 2 ln. Cu 31. Phn ng tng hp amoniac 2N2(k) + 3H2(k) 2NH3(k) c ng dng quan trng trong cng nghip ho cht. T amoniac, ngi ta sn xut phn m, axit nitric, thuc n Hi tc ca phn ng tng hp amoniac s tng bao nhiu ln nu tng p sut ln 2 ln khi nhit ca phn ng c gi nguyn? A. 8 ln. B. 36 ln. C. 32 ln. D. 16 ln. Cu 32. Trong bnh kn dung tch 1 lt, ngi ta cho vo 5,6 gam kh CO v 5,4 gam hi nc. Phn ng xy ra l: CO + H2O CO2 + H2. 850oC hng s cn bng ca phn ng trn l KC = 1 ( K =
[CO 2 ][ H 2 ] ) . S mol ca [CO ][H 2O ]
CO v H2O khi t n cn bng ha hc ln lt l A. 0,2 v 0,3. B. 0,08 v 0,2. C. 0,12 v 0,12. D. 0,08 v 0,18. Cu 33. Trong cc phn ng di y phn ng no s chuyn di theo chiu thun khi gim nhit hoc tng p sut. A. COCl2 (k) CO (k) + Cl2 (k);H = +113 KJ B. CO (k) + H2O (k) = CO2 (k) + H2 (k) H = - 41,8 kJ C. 2SO3 (k) 2SO2 (k) + O2 (k); H = +192 kJ D. 4HCl (k) + O2 (k) 2H2O (k) + 2Cl2 (k)H = -112,8 kJ Cu 34. Xt cn bng: N2O4 (k) 2NO2 (k) 25oC. Khi chuyn dch sang mt trng thi cn bng mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2 A. tng 9 ln. B. tng 3 ln. C. tng 4,5 ln. D. gim 3 ln. Cu 35. Khng nh no sau y lun ng ? A. Khi tng nng cht phn ng, tc phn ng tng. B. Khi tng b mt cht phn ng, tc phn ng tng. C. Khi tng p sut, tc phn ng tng. D. Khi c mt cht xc tc, tc phn ng tng. Cu 36. Yu t khng nh hng n s chuyn dch cn bng : CaCO3 (r) CaO (r)+CO2(k) , H>0. A. nng CaCO3. B. p sut. C. nhit . D. nng CO2. Cu 37. Yu t no sau y khng nh hng n s chuyn dch cn bng : A. Nhit . B. Xc tc. C. p sut. D. Nng . Cu 38. Cho phn ng : 2NO + O2 2NO2.Khi tng nng cc cht ln 3 ln th tc phn ng thun v tc phn nghch tng ln bao nhiu ln. A. 9 ln v 3 ln. B. 36 ln v 12 ln. C. 27 ln v 9 ln. D. 18 ln v 6 ln. Cu 39. Cn bng ho hc l 1 cn bng ng v : A. trng thi cn bng phn ng thun vn xy ra. B. trng thi cn bng vn xy ra phn ng. C. trng thi cn bng phn ng khng dng li m phn ng thun v nghch vn xy ra, nhng vi tc bng nhau. D. trng thi cn bng phn ng nghch vn xy ra. Cu 40. Tc phn ng A (k) + B(k) C (k) tng ln bao nhiu ln, nu gi nng cc cht phn ng khng i khi tng nhit phn ng t 398oC ln 448oC, bit tc phn ng tng ln 2 ln khi nhit tng ln 10oC. A. 32 ln. B. 64 ln. C. 16 ln. D. 10 ln. Cu 41. tng tc phn ng thun ca p : 2NO + O2 2NO2. Ta cn phi :
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A. Gim nng NO. B. Tng p sut. C. Tng nng ca NO2. D. Gim nng ca O2. Cu 42. Cho cn bng : 2NO2 N2O4 , H < 0. Nhng bnh ng hn hp gm 2 kh trn vo nc th : A. mu nu nht dn. B. hn hp c mu khc. C. mu nu m dn. D. hn hp gi nguyn mu khng i. Cu 43. Chn pht biu ng. A. Cht xc tc l cht lm tng tc phn ng, nhng cn li sau khi phn ng kt thc. B. Cht xc tc l cht lm thay i tc phn ng. C. Cht xc tc s khng cn khi phn ng kt thc. D. Cht xc tc l cht lm tng hoc lm gim tc phn ng. Cu 44. Khi ho tan SO2 v nc ta c cn bng : SO2 + H2O HSO3- + H+. Cn bng chuyn dch theo chiu thun khi. A. thm Br2. B. thm NaOH. C. thm H2SO4 long. D. thm HCl. Cu 45. Cho phn ng : A (k) + B(k) C (k). Khi tng p sut ln 2 ln, tc phn ng tng: A. 4 ln. B. 16ln. C. 2 ln. D. 8 ln. Cu 45. Cho phn ng : H2 + I2 (hi) 2 HI (k). S chuyn dch cn bng phn ng ph thuc vo : A. th tch bnh phn ng. B. nhit ca phn ng. C. p sut ca h. D. hm lng cht xc tc. Cu 47. tng tc ca phn ng nung vi ngi ta dng bin php. o A. Cho mn nh bt vo l. B. Tng nhit phn ng (nung t cao). C. xy l kn trnh gi. D. Cho nhiu tng to vo l. Cu 48. Xt phn ng : 2SO2 (k) + O2 (k) 2 SO3 (k) , H <0. thu c nhiu SO3 ta cn: A. gim nhit . B. tng nhit . C. thm xc tc. D. gim p xut. Cu 49. Nng ca SO2 v O2 trong h 2SO2 (k) + O2 (k) 2 SO3 (k) tng ng l 4 mol/l v 2 mol/l . Khi t n trng thi cn bng c ti 80% SO2 phn ng. Vy hng s cn bng ca phn ng l : A. 40. B. 32. C. 25. D. 10. Cu 50. Xt cn bng sau trong mt bnh kn nhit cao v khng i: C(r) + CO2 (k) 2CO (k) . H < 0. Phn trm theo th tch ca hn hp kh trng thi cn bng l ( bit rng chng c t khi so vi khng kh bng 1). A. 75% CO2 v 25% CO. B. 50% CO2 v 50% CO. C. 33,33% CO2 v 66,7% CO. D. 6,25% CO2 v 93,75% CO. Cu 51. Thc hin phn ng H2SO4 + Na2S3O3 S+ SO2+ H2O + Na2SO4 2 nhit khc nhau. Cc 1 nhit thng, cc 2 50oC. Hin tng thu c l : A. Lu hunh xut hin 2 cc bng nhau. B. Lu hunh xut hin cc 2 sm hn. C. Bt kh xut hin cc 1 sm hn. D. Lu hunh xut hin cc 1 sm hn. Cu 52. Trong 1 bnh kn, nhit khng i, cho 256g kh SO2 v 64g kh O2. Khi cn bng kh SO2 cn li bng 20% lng ban u. Nu p sut ban u l 1,5 atm th p sut lc cn bng l: A. 1,2atm. B. 1,4atm. C. 1,3atm. D. 1,1atm. Cu 53. Cho phn ng 2A (k) + B2 (K) 2AB (k). c thc hin bnh kn, khi tng p sut ln 2 ln th tc phn ng thay i nh th no? A. Tc phn ng tng 8 ln. B. Tc phn ng tng 16 ln. C. Tc phn ng tng 32 ln. D. Tc phn ng gim Cu 54. Nng ca H2 v hi Br2 trong h H2 (k) + Br2 (k) 2 HBr (k) tng ng l 1,5 mol/l v 1 mol/l . Khi t n trng thi cn bng c ti 90% Br2 phn ng. Vy hng s cn bng ca phn ng l : A. 0,034. B. 30. C. 54. D. 900. Cu 55. Cho 11,2 gam st tc dng H2SO4 (4M) nhit thng, mun tc phn ng tng ln cn: A. Thay bng dung dch H2SO4 2M B. Tng nhit phn ng. C. Tng th tch dung dch H2SO4 4M ln gp i. D. Gim th tch dung dch H2SO4 4M xung mt na. Cu 56. Xt phn ng 2SO2 + O2 2SO3 trng thi cn bng nng ca SO2, O2 v SO3 ln lt l: 0,2 mol/l; 0,1 mol/l; 1,8 mol/l. Khi nn th tch hn hp gim xung 3 ln, cn bng ho hc s chuyn dch v pha: A. Chiu thun B. Khng xc nh c. C. Khng nh hng n cn bng ho hc. D. Chiu nghch. Cu 57. Xt phn ng : a A + b B c C + d D. Tc tc thi ca phn ng trn c tnh theo biu thc: d c c b a d a b A. v = k. C D .CC . B. v = k. CC .CB . C. v = k. C A .CD . D. v = k. C A .CB . Cu 58. Cho phn ng A (K) + B(K) C(K), nu gi nng cc cht phn ng khng i trong cc th nghim sau: Th nghim 1: Thc hin phn ng trn 398oC phn ng dng li giy th 96. Th nghim 2: Thc hin phn ng trn 448oC phn ng dng li giy th 3. Khi tng nhit ln 10oC, tc phn ng tng: A. 2 ln. B. 3 ln. C. 4 ln. D. 5 ln.
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Cu 59. Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l 0,3M v o 0,7M. Sau khi phn ng tng hp NH3 t trng thi cn bng t C, H2 chim 50% th tch hn hp thu c. o Hng s cn bng KC t C ca phn ng c gi tr l A. 3,125. B. 0,500. C. 0,609. D. 2,500. Cu 60. Khng nh no sau y khng ng ? A. Cc cht t rn (than, ci) c kch thc nh s d chy hn. B. Nu thc phm trong ni p sut nhanh chn hn so vi khi nu nhit thng. C. Nu thc phm trn ni cao ( p sut thp ) thc phm nhanh chn hn. D. Nht ca ngn la axetilen chy trong oxi cao hn nhiu so vi chy trong khng kh.
Chuyn 3:
BI TP LIN QUAN N DUNG DCH AXIT HCl, HNO3, H2SO4
Phn 1. TNH AXIT CA CC DUNG DCH Cu 1. Cho 0,02 mol Na2CO3 tc dng vi lng d dung dch HCl th th tch kh CO2 thot ra ( ktc) l A. 0,672 lt. B. 0,336 lt. C. 0,224 lt. D. 0,448 lt. Cu 2. Cho 10 gam hn hp gm Fe v Cu tc dng vi dung dch H2SO4 long (d). Sau phn ng thu c 2,24 lt kh hiro ( ktc), dung dch X v m gam cht rn khng tan. Gi tr ca m l (Cho H = 1, Fe = 56, Cu = 64) A. 5,6 gam. B. 6,4 gam. C. 4,4 gam. D. 3,4 gam. Cu 3. Cho 15 gam hn hp bt kim loi Zn v Cu vo dung dch HCl (d). Sau khi phn ng xy ra hon ton, thu c 4,48 lt kh H2 (ktc) v m gam kim loi khng tan. Gi tr ca m l A. 8,5. B. 2,2. C. 2,0. D. 6,4. Cu 4. Cho 5,6 gam Fe tc dng vi dung dch HCl (d) thu c th tch kh H2 ( ktc) l (Cho H = 1, Fe = 56) A. 6,72 lt. B. 1,12 lt. C. 2,24 lt. D. 4,48 lt. Cu 5. Cho 8,9 gam hn hp bt Mg v Zn tc dng vi dung dch H2SO4 long (d), thu c 0,2 mol kh H2. Khi lng ca Mg v Zn trong 8,9 gam hn hp trn ln lt l A. 1,2 gam v 7,7 gam. B. 1,8 gam v 7,1 gam. C. 2,4 gam v 6,5 gam. D. 3,6 gam v 5,3 gam. Cu 6. Ho tan 5,4 gam Al bng mt lng dung dch H2SO4 long (d). Sau phn ng thu c dung dch X v V lt kh hiro ( ktc). Gi tr ca V l (Cho H = 1, Al = 27) A. 6,72 lt. B. 4,48 lt. C. 2,24 lt. D. 3,36 lt. Cu 7. Ha tan 6,5 gam Zn trong dung dch axit HCl d, sau phn ng c cn dung dch th s gam mui khan thu c l (Cho H = 1, Zn = 65, Cl = 35,5) A. 14,96 gam. B. 13,6 gam. C. 20,7 gam. D. 27,2 gam. Cu 8. Ho tan m gam Fe trong dung dch HCl d, sau khi phn ng kt thc thu c 4,48 lt kh H2 ( ktc). Gi tr ca m l (Cho Fe = 56, H = 1, Cl = 35,5) A. 5,6. B. 11,2. C. 1,4. D. 2,8. Cu 9. Khi lung K2Cr2O7 cn dng oxi ho ht 0,6 mol FeSO4 trong dung dch c H2SO4 long lm mi trng l (Cho O = 16, K = 39, Cr = 52) A. 24,9 gam. B. 29,4 gam C. 59,2 gam. D. 29,6 gam Cu 10. Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch cha m gam mui. Gi tr ca m l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Zn = 65) A. 8,98. B. 7,25. C. 10,27. D. 9,52. Cu 11. Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung dch Y l (Cho H = 1; Mg = 24; Cl = 35,5; Fe = 56) A. 15,76%. B. 24,24%. C. 28,21%. D. 11,79%. Cu 12. Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2 ( ktc). Th tch dung dch axit H2SO4 2M cn dng trung ho dung dch X l A. 60ml. B. 150ml. C. 75ml. D. 30ml. X l kim loi thuc nhm IIA. Cho 1,7 gam hn hp gm kim loi X v Zn tc dng vi lng d dung Cu 13. dch HCl, sinh ra 0,672 lt kh H2( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung dch H2SO4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l A. Ca. B. Mg. C. Ba. D. Sr. Cu 14. Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc).C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l A. 48,8. B. 42,6. C. 47,1. D. 45,5.
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Cu 15. Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H2SO4 0,28M thu c dung dch X v 8,736 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l A. 25,95 gam. B. 103,85 gam. C. 77,86 gam. D. 38,93 gam. Cu 16. Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 ( ktc). Gi tr ca V l A. 3,08. B. 4,48. C. 3,36. D. 2,80. Cu 17. Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu c dung 2+ 3+ dch Y c t l s mol Fe v Fe l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn mt thu c m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu c m2 gam mui khan. Bit m2 m1 = 0,71. Th tch dung dch HCl dng l A. 240 ml. B. 80 ml. C. 320 ml. D. 160 ml. Cu 18. Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O2, n khi cc phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn ng vi cht rn X l A. 600 ml. B. 400 ml. C. 800 ml. D. 200 ml. Cu 19. Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100 ml dung dch X cn dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong oleum trn l A. 23,97%. B. 32,65%. C. 37,86%. D. 35,95%. Cu 20. Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H2SO4 (d), thu c dung dch cha 7,5 gam mui sunfat trung ho. Cng thc ca mui hirocacbonat l A. Mg(HCO3)2. B. Ca(HCO3)2. C. Ba(HCO3)2. D. NaHCO3. Cu 21. Cho 3,16 gam KMnO4 tc dng vi dung dch HCl c (d), sau khi phn ng xy ra hon ton th s mol HCl b oxi ha l A. 0,16. B. 0,05. C. 0,02. D. 0,10. Cu 22. ho tan hon ton 6,4 gam hn hp gm kim loi R (ch c ha tr II) v oxit ca n cn va 400 ml dung dch HCl 1M. Kim loi R l A. Ba. B. Ca. C. Be. D. Mg. Cu 23. Chia hn hp 2 kim loi c ho tr khng i lm 2 phn bng nhau. Phn 1 tan ht trong dung dch HCl to ra 1,792 lt H2 (kc). Phn 2, nung trong oxi thu c 2,84 gam hn hp oxit. Khi lng hn hp 2 kim loi ban u l: A. 2,2 gam B. 3,12 gam C. 2,4 gam D. 1,56 gam Cu 24. Cho 1,04 gam hn hp 2 kim loi tan hon ton trong H2SO4 long d thy c 0,672 lt kh thot ra iu kin tiu chun. Khi lng hn hp mui sunfat khan thu c l: A. 3,92gam. B. 1,68gam. C. 0,46gam. D. 2,08gam. Cu 25.Cho 1,53 gam hn hp Mg, Zn, Cu vo dung dch HCl d thot ra 448 ml kh (kc). C cn hn hp sau phn ng ri nung khan trong chn khng thu c mt cht rn c kl l: A. 2,95 g B. 3,95 g C. 2,24 g D. 1,83 g Cu 25. Cho 11,1 gam hn hp hai mui sunft trung ho ca 2 kim loi kim hai chu k lin tip tan hon ton trong dung dch HCl d thu c 2,24 lt kh SO2(kc). Hai kim loi l: A. Li,Na. B. Na,K. C. K,Cs. D. Na, Cs. Cu 26. Cho 2O gam hn hp kim loi M v Al vo dung dch H2SO4 v HCl ( s mol HCl gp 3 ln s mol H2SO4 ) th thu c 11,2 lt H2 (kc) v vn cn d 3,4 gam kim loi . Lc ly phn dung dch ri em c cn thu c m gam mui khan . Tnh m ?( S = 32 ; O = 16 , Cl = 35,5) A.57,1 gam B.75,1 gam C.51,7 gam D.71,5 gam Cu 27. Cho 40g hn hp gm Au, Ag, Cu, Fe, Zn tc dng vi O2 d nung nng thu c 46,4g hn hp cht rn X. Th tch dung dch HCl 2M ti thiu phn ng va vi X l A. 0,4 L B. 0,5 L C. 0,35 L D. 0,8 L Cu 28. Cho 6,94 gam hn hp FexOy v Al ha tan trong 100 ml dung dch H2SO4 1,8M, sinh ra 0,672 lt H2 (kc). Bit lng axit ly d 20% so vi lng cn thit phn ng. FexOy l: A. FeO B. Fe3O4 C. Fe2O3 D. Khng tm c Cu 29. Cho 8,00 gam canxi tan hon ton trong 200 ml dung dch hn hp HCl 2M v H2SO4 0,75M thu c kh H2 v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l: A. 22,2 B. 25,95 C. 22,2 m 25,95 D. 22,2 m 27,2 Cu 30. kh hon ton 6,4 gam mt oxt kim loi cn 0,12 mol kh H2. Mt khc ly lng kim loi to thnh cho tan hon ton trong dung dch H2SO4 long th thu c 0,08 mol H2. Cng thc oxit kim loi l: A. CuO. B. Al2O3. C. Fe3O4. D. Fe2O3. Cu 31. em oxi ha hon ton 11,2 lt SO2 (kc) ri ha tan ton b sn phm vo 21O g dung dch H2SO4 1O% thu c dung dch A . Tnh nng % ca dung dch A ( cho S =32 , O = 16 , H = 1 ) .
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A.32% B. 28% C.24% D. 16% Cu 32. Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l: A. V = 11,2(a + b). B. V = 11,2(a - b). C. V = 22,4(a + b). D. V = 22,4(a - b). Cu 33. Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l (cho Fe = 56) A. 20. B. 40. C. 60. D. 80. Cu 34. Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l (cho H = 1, O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65) A. 4,81 gam. B. 6,81 gam. C. 3,81 gam. D. 5,81 gam. Cu 35. Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA (phn nhm chnh nhm II) tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l (cho Be = 9, Mg = 24, Ca = 40, Sr = 87, Ba = 137) A. Mg v Ca. B. Sr v Ba. C. Ca v Sr. D. Be v Mg. Cu 36. Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l A. 50 ml. B. 75 ml. C. 57 ml. D. 90 ml. Cu 37. ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,08. B. 0,18. C. 0,23. D. 0,16. Cu 38. oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH, lng ti thiu Cl2 v KOH tng ng l A. 0,03 mol v 0,08 mol. B. 0,03 mol v 0,04 mol. C. 0,015 mol v 0,08 mol. D. 0,015 mol v 0,04 mol. Cu 39. Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 7,80. B. 8,75. C. 6,50. D. 9,75. Cu 40. Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l A. Li. B. K. C. Na. D. R Cu 41. Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H2 ( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l A. 4,48 lt. B. 3,92 lt. C. 1,68 lt. D. 2,80 lt. Cu 42. Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l A. 97,80 gam. B. 88,20 gam. C. 101,68 gam. D. 101,48 gam. Cu 43. Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO40,5M, thu c dung dch X. C cn dung dch X, thu c hn hp gm cc cht l A. K3PO4v KOH. B. KH2PO4 v K2HPO4. C. KH2PO4v H3PO4. D. KH2PO4 v K3PO4. Cu 44. Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng khng i, thu c cht rn Z l A. hn hp gm BaSO4 v FeO. B. hn hp gm Al2O3 v Fe2O3. C. Fe2O3. D. hn hp gm BaSO4 v Fe2O3. Cu 45. Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2l A. 0,015. B. 0,030. C. 0,010. D. 0,020. Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y tc dng ht vi lng d Cu 46. dung dch HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l A. natri v magie. B. kali v canxi. C. kali v bari. D. liti v beri. Cu 47. Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn ng l A. 1,008 lt. B. 1,344 lt. C. 2,016 lt. D. 0,672 lt. Cu 48. Ha tan hon ton 2,45 gam hn hp X gm hai kim loi kim th vo 200 ml dung dch HCl 1,25M, thu c dung dch Y cha cc cht tan c nng mol bng nhau. Hai kim loi trong X l A. Mg v Sr. B. Mg v Ca. C. Be v Ca. D. Be v Mg.
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Cu 49. Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta A. Fe(OH)2 v Cu(OH)2. B. Fe(OH)2, Cu(OH)2 v Zn(OH)2. C. Fe(OH)3. D. Fe(OH)3 v Zn(OH)2. Cu 50. Ho tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch H2SO4 (long, rt d), sau khi cc phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 100ml dung dch KMnO4 0,1M. Gi tr ca m l A. 1,24. B. 3,2. C. 0,96. D. 0,64. Cu 51. t m gam bt st trong kh oxi thu c 7,36 gam cht rn X gm Fe ;Fe2O3;FeO; Fe3O4. ha tan hon ton hn hp X cn va ht 12O ml dung dch H2SO4 1M. to thnh O,224 lt kh H2 ktc. Tnh m: ( Fe = 56 , S = 32 , O = 16 , H = 1 ) A.5,6 gam O ,O8 gam B.1 C.7,6 gam D.6,7 gam Cu 52. Ho tan 36 gam hn hp ng v oxit st t ( dng bt) theo t l mol 2 : 1 bng dung dch HCl d, phn ng xong thu c dung dch X v cht rn Y. ( Fe = 56, Cu = 64, O = 16 ). Khi lng cht rn Y bng A. 12,8 gam. B. 6,4 gam. C. 23,2 gam. D. 16,0 gam. Cu 53. Ha tan ht 26,43 gam hn hp bt gm Mg, Al, Al2O3 v MgO bng 795 ml dung dch hn hp gm HCl 0,5M v H2SO4 0,75M (va ). Sau phn ng thu c dung dch X v 4,368 lt kh H2 ( ktc). C cn dung dch X thu c khi lng mui khan l A. 95,92 gam B. 88,18 gam C. 86,58 gam D. 100,52 gam Cu 54. Ha tan hon ton 3,26 gam hn hp gm Na2O, MgO, Al2O3 trong 200 ml HNO3 aM (va ) sau phn ng, thu c 4,34 gam hn hp mui nitrat. Gi tr ca a l : A. 0,1M B. 0,2M C. 0,3M D. 0,25M Cu 55. Ha tan hon ton 3,6 gam hn hp X gm 2 mui cacbonat trung ha (ca 2 kim loi A, B k tip nhau trong phn nhm chnh nhm II) bng dd HCl, kh sinh ra c hp th hon ton bi 3 lt dd Ca(OH) 0,015M th
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thu c 4 gam kt ta. Hai kim loi A, B l: A. Be, Mg B. Mg, Ca C. Be, Mg hoc Mg, Ca D. Mg, Ca hoc Sr, Ba Cu 56. Ha tan hon ton 4 gam hn hp MCO3 v M'CO3 bng dung dch HCl d thy thot ra V lt kh iu kin tiu chun. Dung dch thu c em c cn c 5,1 gam mui khan. Gi tr ca V l: A. 1,12 lt B. 1,68 lt C. 2,24 lt D. 3,36 lt Cu 57. Ho tan hon ton 9,0 gam hn hp X gm bt Mg v bt Al bng dung dch H2SO4 long, d thu c kh A v dung dch B. Thm t t dung dch NaOH vo B sao cho kt ta t ti lng ln nht th dng li. Lc kt ta, em nung trong khng kh n khi lng khng i thu c 16,2 gam cht rn. Th tch kh A thu c iu kin tiu chun l: A. 11,2 lt B. 10,08 lt C. 8,4 lt D. 5,04 lt Cu 58. Ho tan hon ton a gam hn hp X gm Fe v Fe2O3 trong dung dch HCl thu c 2,24 lt kh H2 (kc) v dung dch B. Cho dung dch B tc dng dung dch NaOH d, lc ly kt ta, nung trong khng kh n khi lng khng i thu c 24 gam cht rn. Gi tr ca a l: A. 13,6 gam B. 17,6 gam C. 21,6 gam D. 29,6 gam Cu 59. Hn hp X gm Cu v Fe3O4 nng 9 gam. Cho X vo dung dch HCl d thy cn 1,6 gam Cu khng tan. Khi lng Fe3O4 trong X l A. 7,4 g B. 5,8 g C. 2,32g D. 3,48 g Cu 60. Mt hn hp X gm M v oxit MO ca kim loi y. X tan va trong 0,2 lt dung dch H2SO4 0,5M cho ra 1,12 lt H2 (kc). Bit khi lng ca M trong hn hp X bng 0,6 ln khi lng ca MO trong hn hp y. Kim loi M, khi lng M v MO trong X l: A. Mg; 1,2 gam Mg v 2 gam MgO B. Ca; 2 gam Ca v 2,8 gam CaO C. Ba; 6,85 gam Ba v 7,65 gam BaO D. Cu; 3,2 gam Cu v 4 gam CuO Cu 61. Ngm mt thanh kim loi M c khi lng 50 gam trong dung dch HCl. Sau phn ng thu c 336 ml H2 (kc) v thy khi lng l kim loi gim 1,68% so vi ban u. Kim loi M l: A. Mg B. Al C. Si D. Fe Cu 62. Oxi ha hon ton p gam Kim loi X th thu 1,25p gam oxit . Ha tan mui cacbonat ca kim loi Y bng mt lng va dung dch H2SO4 9,8% th thu c dung dch mui sunfat c nng 14,18% . Hi X,Y l kim loi g ?( Cu = 64 , Zn = 65 , Mg = 24 , Fe = 56 ) A. Cu v Fe B. Al v Fe C. Cu v Zn D. Zn v Mg Phn 2. TNH OXIHO CA CC DUNG DCH AXIT HNO3, H2SO4. Cu 63. Ho tan 22,4 gam Fe bng dung dch HNO3 long (d), sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 8,96. B. 4,48. C. 2,24. D. 3,36. Cu 64. Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4c, nng n khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4. B. MgSO4 v FeSO4. C. MgSO4 v Fe2(SO4)3. D. MgSO4, Fe2(SO4)3 v FeSO4.
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Cu 65. Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l A. 10,52%. B. 19,53%. C. 12,80%. D. 15,25%. Cu 66. Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn ng xy ra hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5 ). Gi tr ca a l A. 11,0. B. 8,4. C. 11,2. D. 5,6. Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d dung dch HNO3. Sau khi cc Cu 67. phn ng xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam mui khan. Kh X l A. N2O. B. NO. C. NO2. D. N2. Cu 68. Ho tan hon ton 13,00 gam Zn trong dung dch HNO3 long, d thu c dung dch X v 0,448 lt kh N2 (ktc). Khi lng mui trong dung dch X l A. 37,80 gam. B. 28,35 gam. C. 39,80 gam. D. 18,90 gam. Cu 69. Cho 0,01 mol mt trong cc cht: Fe, Fe3O4, FeS, Cu, S, FeO, Ag tc dng vi dung dch H2SO4 c, nng d thy thot ra V lit kh SO2 (sn phm kh duy nht ktc). Nu V = 0,112 th s cht ph hp l A. 4 B. 6 C. 5 D. 3 Cu 70. Cho 1,28g Cu vo 100 ml dung dch gm NaNO3 0,15M v H2SO4 0,2M, sau khi phn ng xy ra hon ton thu c kh NO duy nht c th tch (kc) l A. 0,3 lit. B. 0,336 lit C. 0,112 lit D. 0,224 lit Cu 71. Cho 1,35g hn hp gm Cu, Mg, Al tc dng ht vi dung dch HNO thu c hn hp kh gm 0,01
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mol NO v 0,04 mol NO2. Khi lng mui to thnh trong dung dch: A. 5,69 gam B. 5 gam C. 6 gam D. 5,5 gam Cu 72. Cho 1,92 gam Cu v 100 ml dd cha ng thi KNO3 0,16 M v H2SO4 0,4 M, sinh ra kh NO v dd A. Th tch (lt) dd NaOH 0,5 M ti thiu kt ta ton b ion Cu2+ trong dd A l: A. 0,12 B. 0,128 C. 0,112 D. 0,096 Cu 73. Cho 13,5 g nhm tc dng va vi 2,2 lt dd HNO3 thu c hn hp kh NO v NO2 c t khi so vi H2 l 19,2. Nng mol ca dd axit ban u l A. 0,68 M B. 0,05 M C. 0,86 M D. 0,9 M Cu 74. Cho 18,5 gam hn hp gm Fe v Fe3O4 tc dng vi 200 ml HNO3 long, un nng. Sau khi phn ng thu c 2,24 lt NO duy nht (kc), dung dch D v cn li 1,46 gam kim loi. Nng ca dung dch HNO3 l: A. 5,1M B. 3,5M C. 3,2M D. 2,6M Cu 75. Cho 2,0 gam Fe v 3,0 gam Cu vo dung dch HNO3 long thu c 0,448 lt kh NO duy nht v dung dch X. Khi lng mui khan thu c sau khi c cn dung dch X l: A. 5,4 gam. B. 6,24 gam C. 17,46 gam D. kt qu khc Cu 76. Cho 2,7 gam Al tc dng va vi dung dch cha NaNO3 v NaOH thu c V lt kh (kc). Gi tr ca V l: A. 0,84 lt B. 1,68 lt C. 11,2 lt D. 22,4 lt Cu 77. Cho 20 gam Fe tc dng vi HNO3 , thu c V lt kh NO duy nht (kc) v 3,2 gam cht rn. Gi tr ca V l: A. 0,896 lt B. 2,24 lt C. 4,48 lt D. 6,72 lt Cu 78. Cho 5,8 gam mui FeCO3 tc dng vi dung dch HNO3 va , thu c hn hp kh cha CO2, NO v dung dch X. Cho dung dch HCl d vo dung dch X c dung dch Y, dung dch Y ny ha tan c ti a m gam Cu, sinh ra sn phm kh NO duy nht. Gi tr ca m l: A. 9,6 gam B. 11,2 gam C. 14,4 gam D. 16 gam Cu 79. Cho 8,4 gam Fe tc dng vi dung dch HNO3 long. Sau khi phn ng xy ra hon ton thu c kh NO, dung dch A v cn li 2,8 gam cht rn khng tan. C cn dung dch A thu c m gam mui khan. Gi tr ca m l: A. 11,8 gam B. 18 gam C. 21,1 gam D. 24,2 gam Cu 80. Cho a mol Cu kim loi tan hon ton trong 120ml dung dch X gm HNO3 1M v H2SO4 0,5M (long) thu c V lt kh NO duy nht (kc). Tnh V? A. 14,933a lt. B. 12,32a lt. C. 18,02a lt. D. Kt qu khc. Cu 81. Cho hn hp gm 0,15 mol CuFeS2 v 0,09 mol Cu2FeS2 tc dng vi dung dch HNO3 d thu c dung dch X v hn hp kh Y gm NO v NO2. Thm BaCl2 d vo dung dch X thu c m gam kt ta. Mt khc, nu thm Ba(OH)2 d vo dung dch X, ly kt ta nung trong khng kh n khi lng khng i thu c a gam cht rn. Gi tr ca m v a l:
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A. 112,84g v 167,44g B. 112,84g v 157,44g C. 111,84g v 157,44g D. 111,84g v 167,44g Cu 82. Cho m gam Al tc dng hon ton vi NaOH d sinh ra a mol kh H , cn nu cho cng lng Al ny vo
2
dd HNO3 long d th thu c b mol kh N2 (sn phm kh duy nht). Quan h gia a v b l: A. a = 2b B. a = 5b C. a = 2,5b D. a = B Cu 83. Cho m gam Fe tc dng hon ton vi dung dch cha 0,42 mol H2SO4 c nng, thu c dung dch ch cha 28,56 gam mui v kh SO2. Gi tr m l: A. 8,4 gam B. 7,84 gam C. 11,2 gam D. 23,52 gam Cu 84. Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (kc) phn ng l A. 2,016lt. B.1,00lt. C. 0,672lt. D.1,344lt. Cu 85. Cho m gam hn hp Cu, Fe, Al tc dng hon ton vi dung dch HNO3 long d thu c (m+31)g mui nitrat. Nu cng cho m gam hn hp kim loi trn tc dng vi oxi c cc oxit CuO, Fe O , Al O th khi lng
2 3 2 3
oxit l: A. (m+48)gam B. (m+32)gam C. (m+4)gam D. (m+16)gam Cu 86. C mt loi qung pirit cha 96% FeS2. Nu mi ngy nh my sn xut 100 tn H2SO4 98% v hiu sut iu ch H2SO4 l 90% th lng qung pirit cn dng l : A. 69,44 tn B. 68,44 tn C. 67,44 tn D. 70,44 tn. Cu 87. kh hon ton 3,04 gam hn hp Y (gm FeO, Fe3O4, Fe2O3) th cn 0,05 mol H2. Mt khc ho tan hon ton 3,04 gam hn hp Y trong dung dch H2SO4 c th thu c th tch kh SO2 (sn phm kh duy nht) iu kin tiu chun l: A. 224ml. B. 448ml. C. 336ml. D. 112ml. Cu 88. em nung hn hp A, gm hai kim loi: x mol Fe v 0,15 mol Cu, trong khng kh mt thi gian, thu c 63,2 gam hn hp B, gm hai kim loi trn v hn hp cc oxit ca chng. em ha tan ht lng hn hp B trn bng dung dch H2SO4 m c, th thu c 0,3 mol SO2. Tr s ca x l: A. 0,7 mol B. 0,5 mol C. 0,6 mol D. 0,4 mol Cu 89. Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt ( ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l (cho H = 1, N = 14, O = 16, Fe = 56, Cu = 64) A. 5,60. B. 4,48. C. 3,36. D. 2,24. Cu 90. Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,04. B. 0,12. C. 0,06. D. 0,075. Cu 91. Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3 (d), thot ra 0,56 lt ( ktc) NO (l sn phm kh duy nht). Gi tr ca m l (cho O = 16, Fe = 56) A. 2,32. B. 2,52. C. 2,22. D. 2,62. Cu 92. Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l (cho Cu = 64) A. V2 = V1. B. V2 = 1,5V1. C. V2 = 2,5V1. D. V2 = 2V1. Cu 93. Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56) A. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. C. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. D. 0,12 mol FeSO4. Cu 94. Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 38,72. C. 34,36. D. 49,09. Cu 95. Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 0,672. B. 1,792. C. 0,448. D. 0,746. Cu 96. Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l A. 6,52 gam. B. 13,32 gam. C. 8,88 gam. D. 13,92 gam. Cu 97. Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh
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ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 10,5. B. 12,3. C. 11,5. D. 15,6. Cu 98. Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 0,8 lt. B. 1,0 lt. C. 1,2 lt. D. 0,6 lt. Cu 99. Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l A. NO v Mg. B. N2O v Fe. C. N2O v Al. D. NO2 v Al. Cho 6,72 gam Fe vo 400 ml dung dch HNO 1M, n khi phn ng xy ra hon ton, thu c kh NO Cu 100. 3 (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l A. 1,92. B. 3,84. C. 0,64. D. 3,20. Cu 101. Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 240. B. 120. C. 360. D. 400. Cu 102. Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 38,34. B. 106,38. C. 97,98. D. 34,08. Cu 103. Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l A. 151,5. B. 108,9. C. 137,1. D. 97,5. Cu 104. Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 17,8 v 2,24. B. 17,8 v 4,48. C. 10,8 v 2,24. D. 10,8 v 4,48. Cu 105. Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l A. 21,95% v 0,78. B. 78,05% v 2,25. C. 21,95% v 2,25. D. 78,05% v 0,78. Cu 106. Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l A. 0,06 v 0,02. B. 0,06 v 0,01. C. 0,03 v 0,01. D. 0,03 v 0,02. Cu 107. Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l A. 58,0. B. 48,4. C. 54,0. D. 52,2. Cu 108. Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2 : 5), thu c mt sn phm kh duy nht v dung dch ch cha mui sunfat. S mol electron do lng Fe trn nhng khi b ho tan l A. 2x. B. 3x. C. y. D. 2y. Cu 109. Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 6,72. B. 8,96. C. 4,48. D. 10,08. Ho tan hon ton 2,44 gam hn hp bt X gm Fe O v Cu bng dung dch H2SO4c nng (d). Sau Cu 110. x y phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 13,11%. B. 39,34%. C. 26,23%. D. 65,57%. Cu 111. Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ho tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,12. B. 0,16. C. 0,14. D. 0,18. Cu 112. Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra.Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 0,112 lt v 3,750 gam. B. 0,112 lt v 3,865 gam. C. 0,224 lt v 3,750 gam. D. 0,224 lt v 3,865 gam. Cu 113. Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn ng xy ra hon ton (sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi lng mui khan thu c l
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A. 19,20 gam. B. 22,56 gam. C. 20,16 gam. D. 19,76 gam. Cu 114. un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v +5 NO2 (khng c sn phm kh khc ca N ). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l A. 50,4. B. 40,5. C. 44,8. D. 33,6. Cu 115. Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht +5 ca N ). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l A. 4. B. 3. C. 1. D. 2. Cu 116. Dung dch A cha (0,02 mol Fe(NO3)3 v 0,3 mol HCl) c kh nng ho tan c Cu vi khi lng ti a l: A. 7,2 gam. B. 5,76gam. C. 6,4 gam. D. 9,6gam. Cu 117. Ha tan 0,1 mol FeCO3 vo dung dch HNO3 long (va ) thu c dung dch X v hn hp kh gm CO2 v NO (sn phm kh duy nht). Thm H2SO4 long d vo X th dung dch thu c c th ha tan ti a s gam Cu l A. 6,4 B. 25,6 C. 32 D. 3,2 Cu 118. Ha tan 1O gam hn hp mui khan FeSO4 v Fe2(SO4)3 . Dung dch thu c phn ng hon ton vi 1,58 gam KMnO4 trong mi trng axit H2SO4 . Thnh phn % theo khi lng ca Fe2(SO4)3 trong hn hp ban u ? (Fe = 56 . K = 39 , S = 32 , O = 16 , Mn = 55 , H = 1) A.76% B. 24% C. 38% D. 62% Cu 119. Ho tan 45,9 gam kim loi M bng dung dch HNO3 long thu c hn hp kh gm 0,3 mol N2O v 0,9 mol NO. Kim loi M l: A. Mg B. Fe C. Al D. Zn Cu 120. Ha tan 5,6g Fe bng dd H2SO4 long d thu c dd X. Dd X phn ng va vi V ml dd KMnO4 0,5M. Gi tr ca V l A. 80 B. 40 C. 20 D. 60 Cu 121. Ha tan ht 17,84 gam hn hp A gm ba kim loi l st, bc v ng bng 203,4 ml dung dch HNO3 20% (c khi lng ring 1,115 gam/ml) va . C 4,032 lt kh NO duy nht thot ra (kc) v cn li dung dch X. em c cn dung dch X, thu c m gam hn hp ch gm ba mui khan. Gi tr ca m l: A. 54,28 gam B. 51,32 gam C. 45,64 gam D. 60,27 gam Cu 122. Ho tan ht m gam hn hp gm FeO, Fe2O3 v Fe3O4 bng HNO3 c , nng thu c 4,48 lt kh NO2 (kc). C cn dung dch sau phn ng c 145,2 gam mui khan. Gi tr ca m l: A. 35,7g. B. 46,4g. C. 15,8g. D. 77,7g. Cu 123. Ha tan ht m gam hn hp gm FeO, Fe2O3, Fe3O4 bng HNO3 c nng thu c 4,48 lt kh NO2 (kc). C cn dung dch sau phn ng c 142,2 gam mui khan. Gi tr m l: A. 46,6 gam B. 35,7 gam C. 15,8 gam D. 77,7 gam Cu 124. Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l A. 21,95% v 2,25. B. 78,05% v 2,25. C. 21,95% v 0,78. D. 78,05% v 0,78. Cu 125. Ho tan hon ton 12 gam hn hp X gm Fe v Cu bng dung dch HNO3 d, kt thc th nghim thu c 6,72 lt (kc) hn hp kh B gm NO v NO2 c khi lng 12,2 gam. Khi lng mui nitrat sinh ra l: A. 30,6 gam B. 39,9 gam C. 43,0 gam D. 55,4 gam Cu 126. Ha tan hon ton 25,6 g cht rn X gm Fe, FeS, FeS2 v S bng dung dch HNO3 d thy thot ra V lit kh NO (sn phm kh duy nht, ktc) v dung dch Y. Thm Ba(OH)2 d vo Y thu c 126,25 g kt ta. Gi tr ca V l A. 17,92 B. 19,04 C. 24,64 D. 27,58 Cu 127. Ho tan hon ton 6,48 gam Al vo V lt dung dch HNO3 1M (ly d 25% so vi lng cn thit) th thu c 1,568 lt kh X duy nht ktc v dung dch Y. C cn cn thn dung dch Y thu c 52,72 gam cht rn khan. Th tch ca dung dch HNO3 ban u l A. 0,9 B. 1,125 C. 1,25 D. 1,1 Cu 128. Ha tan hon ton hn hp 2 kim loi Fe v Cu vo dd HNO3 c nng th thu c 22,4 lt kh mu nu. Nu thay HNO3 bng dd H2SO4 c nng th th tch kh SO2 l: A. 11,2 lit B. 2,24 lit C. 33,6 lit D. 22,4 lit
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Cu 129. Ha tan hon ton hn hp A gm 0,04 mol FeCO3 v 0,02 mol FeS2 bng dd HNO3 c, nng, dd thu c sau phn ng tc dng vi dd Ba(OH) d c kt ta X, ly X em nung n khi lng khng i c m
2
gam cht rn Y. Gi tr ca m l: A. 4,8 B. 14,12 C. 9,46 D. 8,4 Cu 130. Ha tan hon ton hn hp FeS v FeCO bng dd HNO c hn hp kh E gm 2 kh X v Y c t
3 3
khi so vi hidro bng 22,85. X, Y ln lt l: A. CO2, N2O B. N2, CO2
C. NO, CO2
1 2
D. NO2, CO2
2 4
Cu 131. Ha tan hon ton hn hp gm cc kim loi M (ha tr II) v M (ha tr III) trong dung dch H SO HNO3 long th th tch kh NO (kc) thu c l:
m c nng thu c 6,72 lt kh SO2 (kc). Nu cng ha tan ht hn hp kim loi ni trn trong dung dch A. 2,24 lt B. 6,72 lt C. 1,12 lt D. 4,48 lt Cu 132. Ha tan hon ton m gam hn hp rn A gm Ag, Cu trong dung dch cha hn hp axit HNO3 v H2SO4 thu c dung dch B cha 19,5 gam hn hp mui v hn hp kh X (gm 0,05 mol NO v 0,01 mol SO2). Gi tr ca m l: A. 9,24 gam B. 9,75 gam C. 15,44 gam D. 17,36 gam Cu 133. Ho tan hn hp Fe, Fe2O3 bng dung dch H2SO4 long d thu c dung dch X v 3,36 lit H2 (kc). Ly 1/10 dung dch X tc dng vi dung dch KMnO4 0,1 M. Th tch dung dch KMnO4 cn dng l: A. 30 ml B. 60 ml C. 50 ml D. 300 ml Cu 134. Hn hp A gm 0,04 mol Al v 0,06 mol Mg. Nu ha tan hon ton hn hp ny trong HNO3 thu c 0,03 mol sn phm X do s kh ca N+5. Nu ha tan hon ton hn hp A trong H2SO4 c, nng cng thu c 0,03 mol sn phm Y do s kh ca S+6. X v Y ln lt l A. NH4NO3 v H2S B. NO2 v SO2 C. NO2 v H2S D. NO v SO2 Cu 136. Hn hp X gm (Fe, Fe2O3, Fe3O4, FeO) vi s mol mi cht l 0,1 mol, ho tan ht vo dung dch Y gm (HCl v H2SO4 long) d thu c dung dch Z. Nh t t dung dch Cu(NO3)2 1M vo dung dch Z cho ti khi ngng thot kh NO. Th tch dung dch Cu(NO3)2 cn dng v th tch kh thot ra ( ktc) l: A. 50ml; 2,24 lt. B. 50ml; 1,12 lt. C. 25 ml; 1,12 lt. D. 500ml; 22,4 lt. Cu 137. Hn hp X gm 3 oxit c s mol bng nhau: FeO, Fe2O3, Fe3O4. Cho m gam hn hp X tc dng vi dung dch HNO3 (d), thu c dung dch Y. Cho Y tc dng vi dung dch NaOH long (d), thu c 6,42 gam kt ta mu nu . Gi tr ca m l: A. 4,80 B. 2,32 C. 1,60 D. 4,64 Cu 138. Hn hp X gm Fe v Cu c t l tng ng l 4:7 v khi lng. trung ha hon ton 24,64 gam X cn dng ti thiu V lit dung dch HNO3 nng a1 M (nu sn phm kh ch c NO2) v cng cn V lit dung dch HNO3 a2 M (nu sn phm kh ch c NO). Ki t l T = a1 : a2 l: A. 1 T 1,5. B. T = 1,5. C. 1,5 T 2. D. T = 2. Cu 139. Hn hp X gm hai kim loi Cu v Ag. Ha tan hon ton m gam hn hp X trong dung dch cha 2 axit HNO3, H2SO4 thu c dung dch Y cha 7,06 gam mui v hn hp kh Z cha 0,05 mol NO2 v 0,01 mol SO2. Gi tr ca m l: A. 2,58 gam B. 3,00 gam C. 3,06 gam D. 3,32 gam Cu 140. Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l A. 0,03 v 0,02. B. 0,06 v 0,01. C. 0,03 v 0,01. D. 0,06 v 0,02. Cu 141. Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 1,2 lt. B. 1,0 lt. C. 0,6 lt. D. 0,8 lt.
Chuyn 4:
IN LI pH CA DUNG DCH BI TP LIN QUAN N BAZ
Cu 1. Ba dung dch sau c cng nng mol/l: H2SO4; Na2SO4; NaHSO4. pH ca chng tng theo th t: A. Na2SO4; NaHSO4; H2SO4 B. Na2SO4; H2SO4; NaHSO4 D. H2SO4; NaHSO4; Na2SO4 C. NaHSO4; H2SO4; Na2SO4 Cu 2. Cc hp cht trong dy cht no di y u c tnh lng tnh? A. Cr(OH)3, Pb(OH)2, Mg(OH)2. B. Cr(OH)3, Zn(OH)2, Mg(OH)2. C. Cr(OH)3, Fe(OH)2, Mg(OH)2. D. Cr(OH)3, Zn(OH)2, Pb(OH)2. Cu 3. Cho 3 dung dch sau c cng nng mol/l: NaHCO3, NaOH, Na2CO3, pH ca chng tng theo th t:
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A. NaOH; NaHCO3; Na2CO3 B. NaOH; Na2CO3; NaHCO3 C. NaHCO3; Na2CO3; NaOH D. Na2CO3; NaOH; NaHCO3 Cu 4. Cho 4 dung dch: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng tc dng c vi c 4 dung dch trn l A. BaCl2. B. NH3. C. KOH. D. NaNO3. Cu 5. Cho 4 phn ng: Cc phn ng thuc loi phn ng axit - baz l (1) Fe + 2HCl FeCl2 + H2 (2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O (3) BaCl2 + Na2CO3 BaCO3 + 2NaCl (4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4 . A. (3), (4). B. (2), (4). C. (1), (2). D. (2), (3). Cu 6. Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (2), (1), (3). B. (2), (3), (1). C. (1), (2), (3). D. (3), (1), (2). Cu 7. Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 4. B. 1. C. 2. D. 3. Cu 8. Cho cc cp cht sau y tc dng vi nhau: Cp cht khng xy ra phn ng l (1) Cl2 + O2 (2) H2S + O2 (3) H2S + Pb(NO3)2 (4) Cl2 + NaOH (5) dung dch NH3 + dung dch AlCl3 (6) dung dch Br2 + FeSO4 (7) dung dch KI + FeCl3 (8) dung dch NaAlO2 + dung dch AlCl3 (9) CuS + HCl c (10) dung dch NaHCO3 + dung dch Ba(OH)2 A. 1, 9 B. 2, 6 C. 1, 9,8 D. 6, 9 Cu 9. Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 7. B. 4. C. 6. D. 5. Cu 10. Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tc dng c vi dung dch NaOH long nhit thng l A. 4. B. 5. C. 3. D. 6. Cu 11. Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4(2), HCl (3), KNO3(4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (3), (2), (4), (1). B. (2), (3), (4), (1). C. (4), (1), (2), (3). D. (1), (2), (3), (4). Cu 12. Cho cc dung dch sau: NaHCO3 (X1) ; CuSO4 (X2) ; (NH4)2CO3 (X3) ; NaNO3 (X4) ; MgCl2 (X5) ; KCl (X6). Nhng dung dch khng to kt ta khi cho Ba vo l: A. X1, X4, X5 B. X1, X4, X6 C. X1, X3, X6 D. X4, X6. Cu 13. Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 2. B. 3. C. 1. D. 4. Cho cc phn ng ha hc sau: Cu 14. (1) (NH4)2SO4 + BaCl2 (3) Na2SO4 + BaCl2 (5) (NH4)2SO4 + Ba(OH)2 (2) CuSO4+ Ba(NO3)2 (6) Fe2(SO4)3 + Ba(NO3)2 (4) H2SO4 + BaSO3 Cc phn ng u c cng mt phng trnh ion rt gn l: A. (2), (3), (4), (6). B. (1), (3), (5), (6). C. (3), (4), (5), (6). D. (1), (2), (3), (6). Cu 15. Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH? A. 5. B. 2. C. 3. D. 4. Cu 16. Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3. B. 4. C. 5. D. 2. Cu 17. Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dy c tnh cht lng tnh l A. 2. B. 3. C. 4. D. 5. Cu 18. Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11 (saccaroz), CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l A. 2. B. 4. C. 5. D. 3. Cu 19. Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong dy to thnh kt ta khi phn ng vi dung dch BaCl2 l A. 2. B. 4. C. 6. D. 3. Cu 20. Cho dy cc cht: NaOH, NaCl, NaNO3, Na2SO4. Cht trong dy phn ng c vi dung dch BaCl2 l A. NaNO3. B. Na2SO4. C. NaOH. D. NaCl. Cu 21. Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l A. 1. B. 3. C. 4. D. 2.
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Cu 22. Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi lng d dung dch Ba(OH)2 to thnh kt ta l A. 5. B. 3. C. 4. D. 1. Cu 23. Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 7. B. 5. C. 4. D. 6. Cu 24. Cho dung dch Ca(OH)2 vo cc ng dung dch Ca(HCO3)2 thy c A. kt ta trng sau kt ta tan dn. B. bt kh bay ra. kt ta trng xut hin. C. D. bt kh v kt ta trng. Cu 25. Cho dung dch KHSO4 vo lng d dung dch Ba(HCO3)2 phn ng to ra: A. kh CO2, cht khng tan BaSO4, phn dung dch c K2SO4 v H2O B. kh CO2, cht khng tan BaSO4, phn dung dch c cha KHCO3 v H2O C. khng c phn ng ha hc xy ra D. to hai cht khng tan BaSO4, BaCO3, phn dung dch cha KHCO3, H2O Cu 26. Cho dung dch Na2CO3 vo dung dch Ca(HCO3)2 thy A. khng c hin tng g. B. c kt ta trng. C. c kt ta trng v bt kh. D. c bt kh thot ra. Cu 27. Cho dung dch NaOH d vo hn hp dung dch (NaCl, CuCl2, AlCl3, MgCl2) thu kt ta nung n khi lng khng i c hn hp rn X. Cho kh CO d i qua X nung nng, phn ng xong thu c hn hp rn E. Cc cht trong E l: A. MgO, Cu B. Mg, Cu C. Mg, CuO D. Al, Cu, Mg Cu 28. Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25oC, Ka ca CH3COOH l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25oC l A. 1,00. B. 4,24. C. 2,88. D. 4,76. Cu 29. C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l A. 1. B. 3. C. 4. D. 2. Cu 30. C 4 ng nghim c nh s theo th t 1, 2, 3, 4. Mi ng nghim cha mt trong cc dung dch AgNO3, ZnCl2, HI, Na2CO3. Bit rng: - Dung dch trong ng nghim 2 v 3 tc dng c vi nhau sinh ra cht kh; - Dung dch trong ng nghim 2 v 4 khng phn ng c vi nhau. Dung dch trong cc ng nghim 1, 2, 3, 4 ln lt l: A. ZnCl2, HI, Na2CO3, AgNO3. B. AgNO3, Na2CO3, HI, ZnCl2. C. AgNO3, HI, Na2CO3, ZnCl2. D. ZnCl2, Na2CO3, HI, AgNO3. Cu 31. C cc th nghim sau: (I) Nhng thanh st vo dung dch H2SO4 long, ngui. (II) Sc kh SO2 vo nc brom. (III) Sc kh CO2 vo nc Gia-ven. (IV) Nhng l nhm vo dung dch H2SO4c, ngui. S th nghim xy ra phn ng ho hc l A. 2. B. 1. C. 3. D. 4. Cu 32. C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l A. 2. B. 3. C. 4. D. 5. Cu 33. C th phn bit 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l A. giy qu tm. B. Zn. C. Al. D. BaCO3. Cu 34. nh gi ng gi tr pH ca cc dung dch mui sau: Ba(NO3)2 (1) , Na2CO3 (2) , NaHSO4 (3) , CH3-NH2 (4) , Ba(CH3COO)2 (5) A. 1,2 c pH = 7 B. 4, 5 c pH >7 C. 2, 3, 5 c pH < 7 D. 1, 5 c pH >7 Cu 35. Dy gm cc cht u tc dng c vi dung dch HCl long l: A. KNO3, CaCO3, Fe(OH)3. B. FeS, BaSO4, KOH. C. Mg(HCO3)2, HCOONa, CuO. D. AgNO3, (NH4)2CO3, CuS. Cu 36. Dy gm cc cht in li yu l A. Na2SO3, NaOH, CaCl2, CH3COOH. B. H2S, H3PO4, CH3COOH, Cu(OH)2. C. BaSO4, H2S, CaCO3, AgCl. D. CuSO4, NaCl, HCl, NaOH. Cu 37. Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l: A. Mg(OH)2, Al2O3, Ca(HCO3)2. B. NaHCO3, ZnO, Mg(OH)2. C. NaHCO3, MgO, Ca(HCO3)2. D. NaHCO3, Ca(HCO3)2, Al2O3. Cu 38. Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt dung dch l: A. Ag+ , Na+ , NO3- ,Cl- . B. H+ , Fe3+ , NO3- ,SO42- .C. Al3+ , NH4+ , Br-,OH- . D. Mg2+ , K+ ,SO42- , PO43Cu 39. Dy gm cc ion cng tn ti trong mt dung dch l:
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2+ + 2+ 2+ +

+ +
A. Al , PO43-, Cl-, Ba . B. K , Ba , OH-, Cl-. C. Ca , Cl-, Na , CO32-. D. Na , K , OH-, HCO3-. Cu 40. nh gi s nhim kim loi nng trong nc thi ca mt nh my, ngi ta ly mt t nc, c c ri thm dung dch Na2S vo thy xut hin kt ta mu vng. Hin tng trn chng t nc thi b nhim bi ion 2+ 2+ 2+ 2+ A. Fe . B. Cd . C. Cu . D. Pb . Cu 41. Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng? A. in li ca axit fomic s gim khi thm dung dch HCl. B. Khi pha long dung dch trn th in li ca axit fomic tng. C. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4. D. in li ca axit fomic trong dung dch trn l 14,29%. Cu 42. Dung dch no sau y c pH > 7? A. dd NaCl. B. dd CH3COONa. C. dd NH4Cl. D. dd Al2(SO4)3. Cu 43. Dung dch no sau y phn ng c vi dung dch Na2CO3 to kt ta? A. NaCl. B. CaCl2. C. KNO3. D. KCl. Cu 44. Ho tan 5 mui: NaCl (1), NH4Cl (2), AlCl3 (3), Na2S (4), C6H5ONa (5) vo nc thnh 5 dung dch, sau cho vo mi dung dch mt mu giy qu tm. Hin tng xy ra l: A. 1,2 khng i mu B. 2,3 qu tm ho C. 3,5 qu tm ho xanh D. 1,4 qu tm ho xanh Cu 45. Ho tan hon ton hn hp Na2O, BaCl2, NaHCO3, NH4Cl c s mol bng nhau vo H2O ri un nh. Sau khi kt thc phn ng thu c dung dch cha mt cht tan. Cht l: A. NH4Cl B. NaOH C. BaCl2 D. NaCl Cu 46. Ho tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dung dch X v cht rn Y. Sc kh CO2 n d vo dung dch X, sau khi cc phn ng xy ra hon ton thu c kt ta l A. Fe(OH)3. B. Al(OH)3. C. K2CO3. D. BaCO3. Cu 47. Hn hp no sau y vi s mol thch hp khng th ha tan hon ton trong nc d ? A. Al, NaNO3, NaOH B. K2S, AlCl3, AgNO3 C. Cu, KNO3, H2SO4 D. Na, Al, Zn Cu 48. Hn hp rn X cha cc cht Na O, NH Cl, NaHCO v BaCl vi s mol mi cht u bng nhau. Cho X
2 4 3 2
vo nc ly d, un nng. Dung dch thu c cha A. NaCl, NaOH C. NaCl, NaOH, BaCl2
B. NaCl, NaHCO3, NH4Cl, BaCl2 D. NaCl
Cu 50. Hn hp X cha Na2O, NH4NO3, NaHCO3 v Ba(NO3)2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d ) un nng, dung dch thu c c cha : A. NaNO3 B. NaNO3, NaOH, Ba(NO3)2 C. NaNO3 , NaOH D. NaNO3, NaHCO3 , NH4NO3 , Ba(NO3)2 Cu 51. Ion CO32- cng tn ti vi cc ion sau trong mt dung dch: B. Cu2+, Mg2+, Al3+ C. Fe2+, Zn2+, Al3+ D. Fe3+, HSO4A. NH4+, Na+, K+ Cu 52. Khi cho dung dch Ca(OH)2 vo dung dch Ca(HCO3)2 thy c A. bt kh v kt ta trng. B. bt kh bay ra. C. kt ta trng xut hin. D. kt ta trng sau kt ta tan dn. Cu 53. Mi phn t v ion trong dy sau va c tnh axit, va c tnh baz A. HSO -, ZnO, Al O , HCO -, H O, CaO B. NH +, HCO -, CH COO-.
3+ C. ZnO, Al2O3, HCO3-, H2O. D. HCO3-, Al2O3, Al , BaO. + 2+ 2+ Cu 54. Mt cc nc c cha cc ion: Na (0,02 mol), Mg (0,02 mol), Ca (0,04 mol), Cl (0,02 mol), HCO3 (0,10 mol) v SO42 (0,01 mol). un si cc nc trn cho n khi cc phn ng xy ra hon ton th nc cn li trong cc A. c tnh cng tm thi. B. c tnh cng ton phn. C. c tnh cng vnh cu. D. l nc mm. Cu 55. Mt dung dch cha cc ion sau: Na+, Mg2+, Ca2+, Ba2+, H+, Cl-. Mun tch c nhiu cation m khng a ion l vo dung dch, ta c th cho dung dch tc dng vi cc cht no trong cc cht sau y: A. dung dch K2CO3 B. dung dch Na2SO4 C. dung dch NaOH D. dung dch Na2CO3 2+ 2+ 2Mt mu nc cng cha cc ion: Ca , Mg , HCO3 , Cl , SO4 . Cht c dng lm mm mu nc Cu 56. cng trn l A. NaHCO3. B. HCl. C. Na2CO3. D. H2SO4. Cu 57. Nhn bit 5 l mt nhn: KNO3, Cu(NO3)2, FeCl3, AlCl3, NH4Cl ch bng A. dd NaOH. B. dd AgNO3. C. dd Na2SO4. D. dd HCl. Cu 58. Pht biu no sau y khng ng? A. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng. B. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng. C. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh. D. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht. 4 2 3 3 2 4 3 3
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Cu 59. Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung dch A. NaHS. B. Pb(NO3)2. C. AgNO3. D. NaOH. Cu 60. Th nghim no sau y c kt ta sau phn ng? A. Thi CO2n d vo dung dch Ca(OH)2. B. Cho dung dch NH3n d vo dung dch AlCl3. C. Cho dung dch NaOH n d vo dung dch Cr(NO3)3. D. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). Cu 61. Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, KHSO4, Na2SO4. B. NaCl, Na2SO4, Ca(OH)2. C. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. D. HNO3, NaCl, Na2SO4. Cu 62. Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l A. Na2CO3, C6H5ONa, CH3COONa. B. KCl, C6H5ONa, CH3COONa. C. Na2CO3, NH4Cl, KCl. D. NH4Cl, CH3COONa, NaHSO4. Cu 63. Trng hp no sau y khng xy ra phn ng ho hc? A. Sc kh Cl2vo dung dch FeCl2. B. Sc kh H2S vo dung dch FeCl2. C. Sc kh H2S vo dung dch CuCl2. D. Cho Fe vo dung dch H2SO4 long, ngui. Cu 64. Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y c pH l A. 4. B. 3. C. 2. D. 1. Cu 65. Cho a lt dung dch KOH c pH = 12,0 vo 8,00 lt dung dch HCl c pH = 3,0 thu c dung dch Y c pH =11,0. Gi tr ca a l A. 0,80. B. 0,12. C. 1,60. D. 1,78. o Cho dung dch X cha hn hp gm CH COOH 0,1M v CH COONa 0,1M. Bit 25 C, Kaca Cu 66. 3 3 -5 o CH3COOH l 1,75.10 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 C l A. 2,88. B. 4,24. C. 4,76. D. 1,00. Cu 67. Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l A. 2. B. 1. C. 6. D. 7. Cu 68. Dung dch axit fomic 0,46% ( D = 1g /ml) c pH = 3. in li ca axit fomic bng A. 1% B. 4,6% C. 1,3% D. 10% Cu 69. Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li) A. y = x + 2. B. y = 2x. C. y = x - 2. D. y = 100x. Cu 70. Dung dch NH3 0,1 M c in li bng 1%. pH ca dung dch NH3 bng: A. 10,5 B. 11,0 C. 12,5 D.13,0 Cu 71. Dung dch NH3 v dung dch NaOH c cng nng mol, pH ca 2 dung dch tng ng l x v y. Gi thit c 100 phn t NH3 th c 1 phn t in li. Quan h gi x v y l A. y = x 2 B. y = 2x C. y = x + 2 D. y = 100x Cu 72. Dung dch X gm CH3COOH 1M (Ka= 1,75.10-5 ) v HCl 0,001M. Gi tr pH ca dung dch X l A. 2,43. B. 2,55. C. 1,77. D. 2,33. Cu 73. Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l (Cho H = 1; O = 16; Cl = 35,5; K = 39) A. 0,25M. B. 0,5M. C. 1M. D. 0,75M. Cu 74. Thm 0,1 mol CH3COONa vo 1,0 lt dung dch CH3COOH 0,1M thu c dung dch X. Bit hng s -5 in li ca CH3COOH l Ka = 1,8.10 ; th tch dung dch thay i khng ng k. Dung dch X c gi tr pH l: A. 13 B. 9,26 C. 4,74 D. 1 Cu 75. Thy phn hon ton 13,75g hp cht PCl3 thu c dung dch X gm 2 axit. Trung ha X cn th tch dung dch NaOH 0,1M l A. 4 L B. 3 L C. 6 L D. 5 L Cu 76. Tng s ht (phn t v ion) ca axit fomic HCOOH c trong 10 ml dung dch axit 0,3M (cho bit in li ca HCOOH trong dung dch l 2%) l: 23 23 20 20 A. 18,42.10 C. 18,42.10 D. 18,06.10 B. 6,02.10 Cu 77. Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l A. 1. B. 2. C. 7. D. 6. Cu 78. Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu
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c 200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H ][OH ] = 10 ) A. 0,12. B. 0,03. C. 0,30. D. 0,15. Cu 79. Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l A. 12,8. B. 13,0. C. 1,0. D. 1,2. Cu 80. Trn 250 ml dung dch hn hp gm HCl 0,08M v H2SO4 0,01M dung dch vi 250 ml dung dch Ba(OH)2 a M , thu c m gam kt ta v mt dung dch c pH = 12. Gi tr ca a v m ln lt l A. 0,06 v 0,5825 B. 0,06 v 3,495 C. 0,015 v 3,495 D. 0,015 v 0,5825 Cu 81. Trn 250 ml dung dch hn hp gm HCl 0,08M v H2SO4 0,01M vi 250 ml dung dch NaOH a mol/l, c 500ml dung dch c pH = 12. Gi tr ca a l A. 0,10M B. 0,12M C. 0,14M D. 0,13M Cu 82. Trn 4OO ml dung dch HCl O,5M vi 1OO ml dung dch KOH 1,5M thu c 5OO ml dung dch X . Tnh pH ca dung dch X ? A.pH=1 B.pH=2,5 C.pH=3 D.pH=2 Cu 83. Cho 300 ml dung dch NaHCO3 x (M) v Na2CO3 y (M). Thm t t dung dch HCl z (M) vo dung dch trn n khi bt u c kh bay ra th dng li thy ht t (ml). Mi lin h gia x, y, z, t l: A. z.t = 150 xy B. z.t = 100 xy C. z.t = 300 y D. z.t = 300 xy Cu 84. Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l A. 39,4. B. 15,5. C. 17,1. D. 19,7. + 2+ Cu 85. Cho dung dch X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl-; 0,006 mol HCO3- v 0,001 mol 2+ NO3-. loi b ht Ca trong X cn mt lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l A. 0,180. B. 0,120. C. 0,222. D. 0,444. Cho m gam NaOH vo 2 lt dung dch NaHCO nng a mol/l, thu c 2 lt dung dch X. Ly 1 lt Cu 86. 3 dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m tng ng l A. 0,07 v 3,2. B. 0,14 v 2,4. C. 0,08 v 4,8. D. 0,04 v 4,8. Cu 87. Cho t t dd cha a mol HCl vo dd cha b mol Na2CO3 ng thi khuy u, thu c V lt kh (kc) v dd X. Khi cho d nc vi trong vo dd X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l A. V = 22,4(a - b). B. V = 11,2(a + b). C. V = 22,4(a + b). D. V = 11,2(a - b). + + 22Cu 88. C 5OO ml dung dch X cha Na , NH4 , CO3 v SO4 . Ly 1OO ml dung dch X tc dng vi lng d dung dch HCl thu 2,24 lt kh (kc) . Ly 1OO ml dung dch X cho tc dng vi lng d dung dch BaCl2 thy c 43 gam kt ta . Ly 1OO ml dung dch X tc dng vi lng d dung dch NaOH thu 4,48 lt kh NH3 ( ktc). Tnh tng khi lng mui c trong 5OO ml dung dch X: ( Na = 23 , N = 14 , C =12 , O = 16 , S =32 , Ba = 137 ). A.43,1 gam O ,8 gam B.119 gam C.86,2 gam D.5 Cu 89. tc dng ht vi dung dch cha 0,01 mol KCl v 0,02 mol NaCl th th tch dung dch AgNO3 1M cn dng l A. 20 ml. B. 10 ml. C. 30 ml. D. 40 ml. Cu 90. Dung dch A cha cc ion Na+ (a mol); HCO - (b mol); CO 2- (c mol); SO 2-(d mol). to kt ta ln
3 3 4
nht, ngi ta phi cho dung dch A tc dng vi 100ml dung dch Ba(OH)2 nng x mol/l. Biu thc tnh x theo a v b: A. x = (a+b)/0,1 B. x = (a+b)/0,2 C. x = (a+b)/2 D. x = a + b Cu 91. Dung dch E cha cc ion Mg2+, SO42-, NH4+, Cl-. Chia dung dch E ra 2 phn bng nhau: Cho phn (I) tc dng vi dung dch NaOH d, un nng, c 0,58 gam kt ta v 0,672 lit kh (kc). Phn (II) tc dng vi dung dch BaCl2 d, c 4,66 gam kt ta. Tng khi lng cc cht tan trong dung dch E bng (Mg = 24, Ba = 137, S = 32, O = 16, Na = 23,H = 1, Cl = 35,5) A. 6,11g. B. 3,055g. C. 5,35g. D. 9,165g. Cu 92. Dung dch X cha axit HCl a mol/l v HNO3 b mol/l. trung ho 20 ml dung dch X cn dng 300 ml dung dch NaOH 0,1 M. Mt khc ly 20 ml dung dch X cho tc dng vi dung dch AgNO3 d thy to thnh 2,87 gam kt ta. ( Ag = 108, Cl = 35,5 ). Gi tr ca a, b ln lt l: A. 1,0 v 0,5 B. 1,0 v 1,5 C. 0,5 v 1,7 D. 2,0 v 1,0 2+ + Dung dch X cha cc ion: Ca , Na , HCO v Cl-, trong s mol ca ion Cl- l 0,1. Cho 1/2 dung dch Cu 93. 3 X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m l A. 7,47. B. 9,21. C. 8,79. D. 9,26. 3+ 2Cu 94. Dung dch X cha cc ion: Fe , SO4 , NH4+, Cl . Chia dung dch X thnh hai phn bng nhau:
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- Phn mt tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; - Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi) A. 7,46 gam. B. 3,73 gam. C. 3,52 gam. D. 7,04 gam. Cu 95. Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 2,24. B. 4,48. C. 1,12. D. 3,36. + Cu 96. Dung dch X c cha: 0,07 mol Na ; 0,02 mol SO42- v x mol OH-. Dung dch Y c cha ClO4-, NO3- v y mol H+; Tng s mol ClO4- v NO3- l 0,04. Trn X v Y c 100ml dung dch Z. Dung dch Z c pH (b qua s in li ca H2O) l A. 12. B. 13. C. 2. D. 1. + 3+ Cu 97. Dung dch X gm 0,1 mol H , z mol Al , t mol NO-3 v 0,02 mol SO2-4. Cho 120 ml dung dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l A. 0,012 v 0,096. B. 0,120 v 0,020. C. 0,020 v 0,012. D. 0,020 v 0,120. 2+ 2+ Cu 98. Dung dch Y cha Ca 0,1 mol , Mg 0,3 mol, Cl 0,4 mol , HCO3 y mol. Khi c cn dung dch Y ta thu c mui khan c khi lng l A. 37,4g. B. 49,8g. C. 25,4g. D. 30,5g. Cu 99. Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 10,8. B. 57,4. C. 28,7. D. 68,2. Cu 100. Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung dch X bi dung dch Y, tng khi lng cc mui c to ra l A. 14,62 gam. B. 12,78 gam. C. 13,70 gam. D. 18,46 gam. 2+ + Cu 101. Mt dung dch cha 0,02 mol Cu , 0,03 mol K , x mol Cl- v y mol SO42-. Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l (Cho O = 16; S = 32; Cl = 35,5; K = 39; Cu = 64) A. 0,03 v 0,02. B. 0,05 v 0,01. C. 0,01 v 0,03. D. 0,02 v 0,05. Cu 102. Mt dung dch c cha 2 cation l Fe2+: 0,1 mol v Al3+: 0,2 mol v 2 anion l Cl-: x mol v SO42-: y mol. Bit rng khi c cn dung dch thu c 46,9 gam cht rn khan. Gi tr ca x l: A. 0,5 B. 0,4 C. 0,3 D. 0,2 Cu 103. Mt dung dch c cha 4 ion gm Ma+: 0,1 mol; K+: 0,3 mol; NO3-: 0,35 mol v Cl-: 0,25 mol. Bit rng khi c cn dung dch thu c 47,875 gam cht rn khan. Ion Ma+ l: A. Fe3+ B. Fe2+ C. Mg2+ D. Al3+ Cu 104. Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3 0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l A. 0,015. B. 0,030. C. 0,010. D. 0,020. Cu 105. Trn 100 ml dung dch A (gm KHCO3 1M v K2CO3 1M) vo 100 ml dung dch B (gm NaHCO3 1M v Na2CO3 1M) thu c dung dch C. Nh t t 100 ml dung dch D (gm H2SO4 1M v HCl 1M) vo dung dch C thu c V lt CO2 (kc) v dung dch E. Cho dung dch Ba(OH)2 ti d vo dung dch E th thu c m gam kt ta. Gi tr ca m v V ln lt l A. 4,3 gam v 1,12 lt. B. 3,4 gam v 5,6 lt. C. 82,4 gam v 2,24 lt. D. 43 gam v 2,24 lt. Cu 106. Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l A. 1,182. B. 2,364. C. 1,970. D. 3,940. Cu 107. Cho 0,54 gam Al vo 40 ml dung dch NaOH 1M, sau phn ng hon ton thu c dung dch X. Cho t t dung dch HCl 0,5M vo dung dch X thu c kt ta. thu c lng kt ta ln nht cn th tch dung dch HCl 0,5M l A. 110ml. B. 90ml. C. 70ml. D. 80ml. Cu 108. Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu c dung dch Y v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt ta. Gi tr ca x l A. 0,8. B. 0,9. C. 1,2. D. 1,0. Cu 109. Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l (cho H = 1, O = 16, Al = 27) A. 2. B. 2,4. C. 1,8. D. 1,2. Cu 110. Cho 200 ml dung dch hn hp gm NaOH 0,5M v Ba(OH)2 0,1M vo 100 ml dung dch hn hp H2SO4 0,2M v Al2(SO4)3 0,15M th khi lng kt ta thu c l
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A. 6,22g B. 7g C. 4,66g D. 62,2g Cu 111. Cho 200 ml dung dch NaOH vo 200 ml dung dch 200 ml dung dch AlCl3 2M, thu c mt kt ta, nung kt ta n khi lng khng i c 5,1 gam cht rn. Nng mol/lt ca dung dch NaOH l: A. 1,5 M v 7,5 M B. 1,5 M v 3M C. 1M v 1,5 M D. 2M v 4M Cu 112. Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 7 : 4. B. 4 : 3. C. 3 : 4. D. 3 : 2. Cu 113. Cho a mol AlCl3 tc dng vi dung dch cha b mol NaOH. T s a/b sau phn ng c kt ta l: A. 1/3 B. 1/4 C. > 1/4 D. < 1/4 Cu 114. Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l A. 0,45. B. 0,05. C. 0,35. D. 0,25. Cu 115. Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l (cho C = 12, O = 16, Ba = 137) A. 0,032. B. 0,06. C. 0,04. D. 0,048. Cu 116. Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M, thu c dung dch X. Coi th tch dung dch khng thay i, nng mol ca cht tan trong dung dch X l A. 0,4M. B. 0,6M. C. 0,2M. D. 0,1M. Cu 117. Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dung dch hn hp gm NaOH 0,1Mv Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l A. 11,82. B. 17,73. C. 9,85. D. 19,70. Cu 118. Ho tan 0,54 gam Al trong 0,5 lt dung dch H2SO4 0,1M thu c dung dch A. Thm V lt dung dch NaOH 0,1 M cho n khi kt ta tan tr li mt phn. Nung kt ta thu c n khi lng khng i ta c cht rn nng 0,51 gam. ( Al = 27, Na = 23, O = 16, S = 32, H = 1) V c gi tr l: A. 1,1 lt B. 0,8 lt C. 1,2 lt D. 1,5 lt Cu 119. Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l A. 20,125. B. 12,375. C. 22,540. D. 17,710. Cu 120.Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X. Cho ton b X tc dng vi 200 ml dung dch Ba(OH)2 1M, sau phn ng thu c m gam kt ta. Gi tr ca m l A. 54,4. B. 46,6. C. 7,8. D. 62,2. Cu 121. Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l A. 11,3 v 7,8. B. 8,3 v 7,2. C. 8,2 v 7,8. D. 13,3 v 3,9. Cu 122. Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch KOH 2M vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c 2a gam kt ta. Gi tr ca m l A. 24,15. B. 16,10. C. 17,71. D. 32,20. Cu 123. Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l A. 2,568. B. 1,560. C. 4,128. D. 5,064. Cu 124. Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l (Cho H = 1; O = 16; Na = 23; Al = 27; S = 32; K = 39; Ba = 137) A. 1,59. B. 1,95. C. 1,17. D. 1,71. Cu 125. Trn 100 ml dung dch Al2(SO4)3 1M vi 700 ml dung dch NaOH 1M thu c kt ta E. Lc tch kt ta E em nung ti khi lng khng i ta thu c cht rn c kl l: A. 10,2 g B. 20,4 g C. 2,55 g D. 5,10 g Cu 126. Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l A. a : b < 1 : 4. B. a : b > 1 : 4. C. a : b = 1 : 5. D. a : b = 1 : 4. Cu 127. X l dung dch AlCl3 , Y l dung dch NaOH 2M . Thm 15O ml dung dch Y vo cc cha 1OOml dung dch X , khuy u ti phn ng hon ton trong cc c 7,8 gam kt ta . Thm tip 1OO ml dung dch Y , khuy u ti kt thc cc phn ng thy trong cc c 1O,92 gam kt ta Nng CM ca dung dch X bng A.1,6M B.3,2M C.2M D.1M
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Chuyn 5:
BI TP IN HA, PIN IN
Cu 1. Trng hp no di y thanh Fe b n mn nhanh hn ? A. thanh Fe ngoi khng kh m B. qun dy Zn ln thanh Fe v ngoi khng kh kh C. qun dy Zn ln thanh Fe v ngoi khng kh m D. qun dy Cu ln thanh Fe v ngoi khng kh m. Cu 2. Cho cc kim loi: Na, Mg, Fe, Al; kim loi c tnh kh mnh nht l A. Fe. B. Al. C. Na. D. Mg. Cu 3. Cho cc kim loi: Ni, Fe, Cu, Zn; s kim loi tc dng vi dung dch Pb(NO3)2 l A. 3. B. 4. C. 1. D. 2. Cu 4. Cho dy cc kim loi: Mg, Cu, Fe, Ag. Kim loi trong dy c tnh kh mnh nht l A. Mg. B. Ag. C. Fe. D. Cu. Cu 5. Dy gm cc ion c sp xp theo th t tnh oxi ha gim dn t tri sang phi l: 3+ 2+ + + 3+ 2+ 2+ 3+ + + 2+ 3+ A. Al , Cu , K . B. K , Al , Cu . C. Cu , Al , K . D. K , Cu , Al . Cu 6. Dy gm cc kim loi c xp theo th t tnh kh tng dn t tri sang phi l A. Fe, Mg, Al. B. Mg, Fe, Al. C. Al, Mg, Fe. D. Fe, Al, Mg. Cu 7. bo v v tu bin lm bng thp, ngi ta thng gn vo v tu (phn ngm di nc) nhng tm kim loi A. Cu. B. Zn. C. Pb. D. Ag. Cu 8. ho tan hon ton hn hp gm hai kim loi Cu v Zn, ta c th dng mt lng d dung dch A. AlCl3. B. HCl. C. CuSO4. D. AgNO3. 2+ Cu 9. kh ion Cu trong dung dch CuSO4 c th dng kim loi A. Ba. B. Na. C. K. D. Fe. 3+ 2+ Cu 10. kh ion Fe trong dung dch thnh ion Fe c th dng mt lng d A. kim loi Ba. B. kim loi Mg. C. kim loi Ag. D. kim loi Cu. Cu 11. Th t mt s cp oxi ho - kh trong dy in ho nh sau: 2+ 2+ 3+ 2+ Fe /Fe; Cu /Cu; Fe /Fe . Cp cht khng phn ng vi nhau l A. dung dch FeCl2 v dung dch CuCl2. B. Fe v dung dch FeCl3. C. Fe v dung dch CuCl2. D. Cu v dung dch FeCl3. Cu 12. Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hu trc l A. 3. B. 1. C. 4. D. 2. 2+ 2+ 2+ 2+ 2+ Cu 13. Cho cc ion kim loi: Zn , Sn , Ni , Fe , Pb . Th t tnh oxi ho gim dn l 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ A. Sn > Ni > Zn > Pb > Fe . B. Zn > Sn > Ni > Fe > Pb . 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ C. Pb > Sn > Fe > Ni > Zn . D. Pb > Sn > Ni > Fe > Zn . Cu 14. Cp cht khng xy ra phn ng ho hc l A. Cu + dung dch FeCl3. B. Fe + dung dch HCl. C. Cu + dung dch FeCl2. D. Fe + dung dch FeCl3. Cu 15. Dy gm cc ion u oxi ha c kim loi Fe l 2+ 2+ + 3+ 2+ + 2+ 3+ 3+ 2+ 2+ + A. Cr , Cu , Ag . B. Fe , Cu , Ag . C. Cr , Au , Fe . D. Zn , Cu , Ag . Cu 16. Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn A. st ng vai tr anot v b oxi ho. B. km ng vai tr anot v b oxi ho. + C. st ng vai tr catot v ion H b oxi ha. D. km ng vai tr catot v b oxi ha. 3+ 2+ Cu 17. Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp Fe /Fe ng trc cp + Ag /Ag): 3+ + 2+ 2+ 3+ 2+ + 2+ + 3+ 2+ 2+ + 2+ 3+ 2+ A. Fe , Ag , Cu , Fe . B. Fe , Cu , Ag , Fe . C. Ag , Fe , Cu , Fe . D. Ag , Cu , Fe , Fe . Cu 18. Cho cc phn ng xy ra sau y: (1) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag (2) Mn + 2HCl MnCl2 + H2 Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l + 2+ + 3+ 2+ + + 3+ + 3+ + 2+ 2+ + 3+ + A. Ag , Mn , H , Fe . B. Mn , H , Ag , Fe . C. Ag , Fe , H , Mn . D. Mn , H , Fe , Ag . Cu 19. Tin hnh bn th nghim sau: - Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; - Th nghim 2: Nhng thanh Fe vo dung dch CuSO4; - Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; - Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l
Chu Anh Tun -
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A. 4. B. 1. C. 2. D. 3. Cu 20. Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l: A. I, II v III. B. I, II v IV. C. I, III v IV. D. II, III v IV. Cu 21. Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe2O3 + CO (k), (3) Au + O2(k), (4) Cu + Cu(NO3)2(r), (5) Cu + KNO3(r), (6) Al + NaCl (r). Cc trng hp xy ra phn ng oxi ho kim loi l: A. (1), (3), (6). B. (1), (4), (5). C. (2), (5), (6). D. (2), (3), (4). Cu 22. Cho cc phn ng sau: Fe + 2Fe(NO3)3 3Fe(NO3)2 AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag Dy sp xp theo th t tng dn tnh oxi ho ca cc ion kim loi l: + 2+ 3+ + 3+ 2+ 2+ 3+ + 2+ + 3+ A. Ag , Fe , Fe . B. Ag , Fe , Fe . C. Fe , Fe , Ag . D. Fe , Ag , Fe . 2+ Cu 23. Bit rng ion Pb trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th A. c Pb v Sn u khng b n mn in ho. B. ch c Pb b n mn in ho. C. ch c Sn b n mn in ho. D. c Pb v Sn u b n mn in ho. Cu 24. Cho cac cht v ion sau: Cl2, Cl-, MnO4-, H2O2, Al3+, SO2, CO2, NO2, Fe, Fe2+, S v Cr3+. Dy gm tt c cc cht v ion va c tnh oxi ha, va c tnh kh l A. SO2, CO2, H2O2, Fe2+, MnO4B. MnO4-, Al3+, Fe, SO2, Cl-, Cl2, Cr3+ 2+ 3+ C. Cl , Fe , S, NO2, Al , CO2 D. SO2, NO2, Fe2+, Cl2, H2O2, S, Cr3+ .Kt lun no sau y khng ng: Cu 25. Cho cc gi tr th in cc chun: 0 E Cu 2+ / Cu = 0,34; E 0 = 0, 78 Zn 2+ / Zn A. Cu2+ c tnh oxi ho mnh hn Zn2+. B. Cu2+ c tnh oxi ho yu hn Zn2+. 2+ 2+ C. Chiu phn ng: Zn + Cu Cu +Zn . D. Cu c tnh kh yu hn Zn Cu 26. Cho hn hp bt gm Fe v Cu vo dung dch AgNO3 d thu c dung dch X. Trong dung dch X cha B. Fe(NO3)2, Cu(NO3)2, AgNO3 A. Fe(NO3)3, Cu(NO3)2, AgNO3 C. Fe(NO3)2, Cu(NO3)2 D. Fe(NO3)3, Cu(NO3)2 Cu 27. Cho mt mu Zn vo cc ng dung dch H2SO4 long thy c kh hiro thot ra, thm vo cc vi git dung dch CuSO4. Bn cht v hin tng sau khi thm dung dch CuSO4 l: A. n mn ho hc, kh hiro thot ra tng B. n mn ho hc, kh hiro thot ra gim C. n mn in ho, kh hiro thot ra tng D. n mn in ho, kh hiro thot ra gim Cu 28. C hai tha st nh nhau, mt chic gi nguyn cn mt chic b vn cong cng t trong iu kin khng kh m nh nhau. Hin tng xy ra l: A. C 2 chic tha u khng b n mn B. C 2 chic tha u b n mn vi tc nh nhau C. Chic tha cong b n mn nhiu hn D. Chic tha cong b n mn t hn Cu 29. Kt lun no sau y khng ng? A. Cc thit b my mc bng kim loi khi tip xc vi hi nc nhit cao c kh nng b n mn ha hc. B. Mt ming v hp lm bng st ty (st trng thic) b xy st tn bn trong, trong khng kh m th thic b n mn trc. C. Ni thanh Zn vi v tu thy bng thp th v tu thy s c bo v. D. vt bng thp ngoi khng kh m th vt s b n mn in ha. Cu 30. Kt lun no sau y khng ng? A. Cc thit b my mc bng kim loi tip xc vi hi nc nhit cao c kh nng b n mn ho hc. B. p tm km vo mn tu thu lm bng thp (phn ngm di nc) th v tu thu c bo v. C. vt bng thp ra ngoi khng kh m th vt b n mn in ho. D. hp lm bng st ty(st trng thic) b xy xt, trong khng kh m b n mn in ho th thic s b n mn trc. Cu 31. Mt hn hp X gm Mg v Fe, tch c kim loi Fe ra khi hn hp, bng cch cho hn hp X tc dng ln lt vi cc dung dch: A. FeCl2, CuSO4 B. HCl, NaOH C. FeCl3, FeCl2 D. Zn(NO3)2, NaOH Cu 32. Mt thanh Zn ang tc dng vi HCl nu thm vi git CuSO4 th: A. Lng bt kh H2 bay ra nhiu hn B. Lng bt kh H2 bay ra khng i C. Lng bt kh bay ra t hn D. Khng c bt kh bay ra Cu 33. Ngi ta nhn thy ni cc mi hn kim loi d b r (g, mau h) hn so vi kim loi khng hn, nguyn nhn chnh l: A. Do ni mi hn thng l hai kim loi khc nhau nn c s n mn in ha hc B. Do kim loi lm mi hn khng chc bng kim loi c hn C. Do kim loi ni mi hn d b n mn ha hc hn D. Do mi hn kim loi b b oxi ha v b t nng. Cu 34. Tin hnh bn th nghim sau: - Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; - Th nghim 2: Nhng thanh Fe vo dung dch CuSO4;
Chu Anh Tun -
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- Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; - Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l A. 3. B. 2. C. 4. D. 1. Cu 35. Trong pin in ha Zn-Cu, qu trnh kh trong pin l B. Zn Zn2+ + 2e. C. Zn2+ + 2e Zn. D. Cu Cu2+ + 2e. A. Cu2+ + 2e Cu. Cu 36. Cho bit phn ng oxi ho - kh xy ra trong pin in ho Fe - Cu l: 2+ 2+ 0 2+ 0 2+ Fe + Cu Fe + Cu ; E (Fe /Fe) = - 0,44 V, E (Cu /Cu) = + 0,34 V. Sut in ng chun ca pin in ho Fe - Cu l A. 0,78 V. B. 0,92 V. C. 1,66 V. D. 0,10 V. 2+ 2+ 2+ 2+ 3+ Cu 37. Th t mt s cp oxi ho - kh trong dy in ho nh sau: Mg /Mg; Fe /Fe; Cu /Cu; Fe /Fe ; + 3+ Ag /Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe trong dung dch l: + 2+ 2+ A. Fe, Cu, Ag . B. Mg, Fe, Cu. C. Mg, Cu, Cu . D. Mg, Fe , Ag. Cu 38. Cho bit th t t tri sang phi ca cc cp oxi ho - kh trong dy in ho (dy th in cc chun) nh 2+ 2+ 2+ 3+ 2+ + sau: Zn /Zn; Fe /Fe; Cu /Cu; Fe /Fe ; Ag /Ag. 2+ Cc kim loi v ion u phn ng c vi ion Fe trong dung dch l: 2+ + 2+ 3+ A. Ag, Cu . B. Zn, Ag . C. Zn, Cu . D. Ag, Fe .
0 EMg 2+ Mg 0 = 2,37V ; EZn 2+
Cu 39. Cho bit: Pin in ho c sut in ng chun bng 1,61V c cu to bi hai cp oxi ho - kh 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ A. Zn /Zn v Cu /Cu. B. Pb /Pb v Cu /Cu. C. Zn /Zn v Pb /Pb. D. Mg /Mg v Zn /Zn. Cu 40. Cho gi tr th in cc chun ca mt s cp oxi ha - kh: 2+ 2+ 2+ 2+ Cp oxi ha/kh E (V)M /M = -2,37; E (V)X /X = -0,76; E (V)Y /Y = -0,13; E (V)Z /Z = + 0,34.Phn ng no sau y xy ra? 2+ 2+ 2+ 2+ 2+ 2+ 2+ 2+ A. X + Z X + Z. B. Z + M Z + M. C. Z + Y Z + Y. D. X + M X + M. Cu 41. Trong pin in ha Zn-Cu, qu trnh kh trong pin l 2+ 2+ 2+ 2+ A. Cu + 2e Cu. B. Zn Zn + 2e. C. Zn + 2e Zn. D. Cu Cu + 2e. Cu 42. Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4v in cc Cu nhng trong dung dch CuSOSau mt thi gian pin phng in th khi lng A. in cc Zn gim cn khi lng in cc Cu tng. B. in cc Zn tng cn khi lng in cc Cu gim. C. c hai in cc Zn v Cu u gim. D. c hai in cc Zn v Cu u tng. o o o o Cu 43. Cho sut in ng chun E ca cc pin in ho: E (Cu-X) = 0,46V; E (Y-Cu) = 1,1V; E (Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l A. Y, Z, Cu, X. B. X, Cu, Z, Y. C. Z, Y, Cu, X. D. X, Cu, Y, Z. Cu 44. Cho sut in ng chun ca cc pin in ho: Zn-Cu l 1,1V; Cu-Ag l 0,46V. Bit th in cc chun o o o E Ag+/ Ag = +0,8V. Th in cc chun E Zn2+/Zn v E Cu2+/ Cu c gi tr ln lt l A. -1,46V v -0,34V. B. +1,56V v +0,64V. C. -1,56V v +0,64V. D. -0,76V v +0,34V. Cu 45. Cho cc th in cc chun: EoAl3+/Al = -1,66V, EoZn2+/Zn = -0,76V, EoPb2+/Pb = -0,13V, EoCu2+/Cu = 0,34V. Trong cc pin sau y, pin no c sut in ng chun ln nht? A. Pin Al - Zn. B. Pin Pb - Cu. C. Pin Zn - Pb. D. Pin Zn - Cu. Cu 46. Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. B. u sinh ra Cu cc m. C. Phn ng cc dng u l s oxi ho Cl-. D. Phn ng xy ra lun km theo s pht sinh dng in. Cu 47. Trong qu trnh hot ng ca pin in ho Zn - Cu th 2+ A. khi lng ca in cc Zn tng. B. nng ca ion Cu trong dung dch tng. 2+ C. khi lng ca in cc Cu gim. D. nng ca ion Zn trong dung dch tng. 2+ + Cu 48. Bit th t dy in ha: Fe /Fe < 2H /H2 < Cu2+/Cu < Fe3+/Fe2+.Phn ng no l sai trong s cc phn ng sau y ? A. Fe + 2Fe3+ 3Fe2+ B. Fe2+ + 2H+ Fe3+ + H2 2+ 2+ C. Fe + Cu Fe + Cu D. Cu + 2Fe3+ Cu2+ + 2Fe2+ 0 Cu 49. Cho 3 kim loi X, Y, Z bit E ca 2 cp oxiho -kh X2+/X = -0,76V v Y2+/Y = +0,34V. Khi cho Z vo dung dch mui ca Y th c phn ng xy ra cn khi cho Z vo dung dch mui X th khng xy ra phn ng. Bit E0 ca pin X Z = +0,63V th E0 ca pin Z -Ybng.
Zn
0 = 0, 76V ; EPb 2+
Pb
0 = 0,13V ; ECu 2+
= +0,34V .
Cu
Chu Anh Tun -
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A. +1,73V B. +0,47V C. +2,49V D. +0,21V Cu 50. Cho sut in ng chun Eo ca cc pin in ho: Eo(Cu-X) = 0,46V; Eo(Y-Cu) = 1,1V; Eo(Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l A. Y, Z, Cu, X. B. X, Cu, Z, Y. C. Z, Y, Cu, X. D. X, Cu, Y, Z. Cu 51. Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4 v in cc Cu nhng trong dung dch CuSO4. Sau mt thi gian pin phng in th khi lng A. in cc Zn gim cn khi lng in cc Cu tng. B. in cc Zn tng cn khi lng in cc Cu gim. C. c hai in cc Zn v Cu u gim. D. c hai in cc Zn v Cu u tng. Cu 52. Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l A. 2,16. B. 5,04. C. 2,88. D. 4,32. Cu 53. Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc phn ng xy ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l A. 1,08 v 5,43. B. 8,10 v 5,43. C. 1,08 v 5,16. D. 0,54 v 5,16. Cu 54. Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200 ml dung dch AgNO3 1M cho n khi phn ng xy ra hon ton. Lc dung dch, em c cn thu c 18,8 gam mui khan. Kim loi M l A. Zn. B. Fe. C. Mg. D. Cu. Cu 55. Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO4 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi. Phn trm v khi lng ca Fe trong hn hp ban u l A. 37,58%. B. 43,62%. C. 56,37%. D. 64,42%. Cu 56. Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l (cho Fe = 56, Cu = 64, Zn = 65) A. 12,67%. B. 90,27%. C. 82,20%. D. 85,30%. 2+ + Cu 57. Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu v 1 mol Ag n khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn? A. 2,0. B. 1,5. C. 1,8. D. 1,2. Cu 58. Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l A. Zn(NO3)2 v Fe(NO3)2. B. Fe(NO3)2 v AgNO3. C. Fe(NO3)3 v Zn(NO3)2. D. AgNO3 v Zn(NO3)2. Cu 59. Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO3 0,1M v Cu(NO3)2 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l A. 2,16. B. 2,80. C. 4,08. D. 0,64. Cu 60. Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,72 gam. B. 1,40 gam C. 0,84 gam. D. 2,16 gam. Cu 61. Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha 0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l A. 16,53. B. 12,80. C. 12,00. D. 6,40. Cu 62. Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 (long, d), sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l A. 58,52%. B. 48,15%. C. 41,48%. D. 51,85%. Cu 63. Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l A. 5,12. B. 3,84. C. 5,76. D. 6,40. Cu 64. Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l A. 29,25. B. 32,50. C. 20,80. D. 48,75. Cu 65. Cho 0,04 mol bt Fe vo dung dch cha 0,07 mol AgNO3. khi phn ng hon ton th khi lng cht rn thu c l A. 8,49 gam B. 7,56 gam C. 8,64 gam D. 7,84 gam Cu 66. Cho 6,48 gam bt kim loi nhm vo 100 ml dung dch hn hp Fe2(SO4)3 1M v ZnSO4 0,8M. Sau khi kt thc phn ng, thu c m gam hn hp cc kim loi. Tr s ca m l:
Chu Anh Tun -
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A. 14,5 gam B. 16,4 gam C. 15,1 gam D. 11,2 gam Cu 67. Cho 8,3gam hn hp (Fe, Al) vo 1 lt dung dch CuSO4 0,21 M phn ng hon ton thu c 15,68g cht rn B gm 2 kim loi. % theo khi lng ca Al trong hn hp l: A. 32,53% B. 53,32% C. 50% D. 35,30% Cu 68. Cho hn hp rn A gm 5,6 gam Fe v 6,4 gam Cu tc dng vi 300 ml dung dch AgNO3 2M n phn ng hon ton. Khi lng cht rn thu c l: A. 32,4 gam B. 43,2 gam C. 54,0 gam D. 64,8 gam Cu 69. Cho m gam Fe vo 100 ml dung dch Cu(NO3)2 th nng ca Cu2+ cn li trong dung dch bng 1/2 nng ca Cu2+ ban u v thu c mt cht rn A c khi lng bng m+0,16 gam. Bit cc phn ng xy ra hon ton. Khi lng Fe v nng (mol/l) ban u ca Cu(NO3)2 : A. 1,12 gam v 0,3M B. 2,24 gam v 0,2 M C. 1,12 gam v 0,4 M D. 2,24 gam v 0,3 M. Cu 70. Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l (cho Fe = 56, Cu = 64, Zn = 65) B. 12,67%. C. 82,20%. D. 85,30%. A. 90,27%. Cu 71. Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l A. 17,0 gam. B. 19,5 gam. C. 13,1 gam. D. 14,1 gam. Cu 72. Cho x mol Al v y mol Zn vo dung dch cha z mol Fe2+ v t mol Cu2+. Cho bit 2t < 3x. iu kin dung dch thu c 3 loi ion kim loi l (Cho cc phn ng xy ra hon ton). A. y < z -1,5x + t B. y < z 3x + t C. y < 2z 3x + 2t D. y < 2z + 3x t Cu 73. Ho tan 0,72 gam bt Mg vo 200 ml dung dch hn hp AgNO3 0,15 M v Fe(NO3)3 0,1 M. khuy u n khi phn ng hon ton thu c m gam cht rn. Gi tr cu m l A. 3,52 B. 3,8 C. 1,12 D. 4,36 Cu 74. Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l B. 28,7. C.10,8. D.68,2. A. 57,4. Cu 75. Mt hn hp X gm 6,5 gam Zn v 4,8 gam Mg cho vo 2OO ml dung dch Y gm Cu(NO3)2 O,5Mv AgNO3 O,3M thu c cht rn A . Tnh khi lng cht rn A ? A. 21,06gam B. 20,16gam C.16,2 gam D. 26,1 gam Cu 76. Ngm mt vt bng Cu c khi lng 10g trong dung dch AgNO3. Khi ly vt ra th c 0,01 mol AgNO3 tham gia phn ng. Khi lng ca vt sau khi ly ra khi dung dch l A. 10,76g B. 10,67g C. 10,35g D. 10,25g Cu 77. Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,40 gam. B. 2,16 gam. C. 0,84 gam. D. 1,72 gam.
Chuyn 6:
BI TP IN PHN
Cu 1. Khi in phn dung dch NaCl (cc m bng st, cc dng bng than ch, c mng ngn xp) th + A. cc m xy ra qu trnh kh ion Na v cc dng xy ra qu trnh oxi ho ion ClB. cc m xy ra qu trnh oxi ho H2O v cc dng xy ra qu trnh kh ion Cl . + C. cc dng xy ra qu trnh oxi ho ion Na v cc m xy ra qu trnh kh ion ClD. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ho ion Cl- . Cu 2. in phn dung dch CuSO4 vi in cc dng bng ng,trong sut qu trnh in phn thy mu xanh lam ca dung dch khng i. iu ny chng t A. Thc cht l in phn nc ca dung dch nn mu dung dch khng thay i B. S in phn thc t khng xy ra, c th do mt ngun in C. Lng ion Cu2+ b oxi ho to Cu bm vo catot bng vi lng Cu ca anot b kh D. Ion Cu2+ ca dung dch b in phn bng vi lng ion Cu2+ do anot tan to ra Cu 3. Dy no sau y gm tt c cc kim loi u c th iu ch bng cch in phn dung dch? A. Mg, Fe, Cr, Ni. B. Al, Fe, Cu, Ag. C. Ba, Ca, Na, Al. D. Cu, Zn, Pb, Ag. Cu 4. Mun m ng ln mt vt bng st bng phng php in ha th phi tin hnh in phn vi in cc g v dung dch no sau y? A. cc m l ng, cc dng l Fe, dd mui st. B. cc m l Cu, cc dng l Fe, dd mui ng. C. cc m l Fe, cc dng l Cu, dd mui st. D. cc m l Fe, cc dng l Cu, dd mui ng.
Chu Anh Tun -
- 0935166002
Cu 5. Pht biu no l ng trong cc pht biu sau? A. Khi in phn dung dch CuSO4 th pH ca dung dch tng dn B. Khi in phn dung dch NaCl th pH ca dung dch gim dn C. Khi in phn hn hp dung dch CuSO4 + NaCl th pH ca dung dch khng i D. Khi in phn dung dch hn hp HCl + NaCl th pH ca dung dch tng dn Cu 6. in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn dung dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l 2+ A. anot xy ra s oxi ho: Cu Cu + 2e. B. catot xy ra s oxi ho: 2H2O + 2e 2OH + H2 + 2+ C. anot xy ra s kh: 2H2O O2 + 4H + 4e. D. catot xy ra s kh: Cu + 2e Cu. Cu 7. Khi in phn NaCl nng chy (in cc tr), ti catt xy ra + + A. s oxi ho ion Na . B. s oxi ho ion Cl . C. s kh ion Cl . D. s kh ion Na . Cu 8. in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp) n khi khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3 v Cu(NO3)2. B. KNO3, HNO3 v Cu(NO3)2. C. KNO3, KCl v KOH. D. KNO3 v KOH. Cu 9. Ho tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 1,680. B. 4,480. C. 3,920. D. 4,788. Cu 10. in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (kc) thot ra anot sau 9650 giy in phn l A. 1,344 lt. B. 2,240 lt. C. 1,792 lt. D. 2,912 lt. Cu 11. in phn 1 lt dung dch NaCl (d) vi in cc tr, mng ngn xp ti khi dung dch thu c c pH = 12 (coi lng Cl2 tan v tc dng vi nc khng ng k, th tch dung dch thay i khng ng k), th th tch kh thu c ant (kc) l: A. 0,112 lt B. 0,224 lt C. 0,336 lt D.1,12lt Cu 12. in phn 200ml dung dch hn hp gm HCl 0,1M v CuSO4 0,5M bng in cc tr. Khi katt c 3,2g Cu th th tch kh (kc) thot ra ant l A. 0,56 lt B. 0,84 lt C. 0,672 lt D. 0,448 lit Cu 13. in phn dung dch BaCl2 vi in cc tr, mng ngn xp, sau mt thi gian thy ant thot ra 0,56 lt (kc) mt cht kh. Hin tng xy ra catt l: A. c 3,425 gam Ba bm vo in cc B. gii phng 0,28 lt kh O2 (kc) C. gii phng 0,56 lt kh H2 (kc) D. gii phng 0,56 lt kh O2 (kc) Cu 14. in phn dung dch cha m gam hn hp 2 mui CuSO4 v NaCl vi cng dng in I = 4A cho n khi nc c 2 in cc cng b in phn th dng li. Khi anot c 448 ml kh thot ra (kc). Dung dch sau in phn ha tan va 1,6g CuO. Gi tr ca m l A. 5,97g B. 4,8g C. 4,95g D. 3,875g Cu 15. in phn dung dch hn hp cha 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr, mng ngn xp). Khi catot bt u si bt kh th dng in phn. Ti thi im ny khi lng catot tng: A. 0,0 gam B. 18,4 gam C. 12,8 gam D. 5,6 gam Cu 16. in phn dung dch mui nitrat ca kim loi R cha bit ha tr, thy catot tch ra 5,4 gam kim loi, anot thot ra 0,28 lt kh (kc). Kim loi R l: A. Fe (56) B. Cu (64) C. Ag (108) D. Pb (207) Cu 17. in phn dung dch NaCl n ht (c mng ngn, in cc tr), cng dng n 1,61A th ht 60 pht. Thm 0,04 mol H2SO4 vo dung dch sau in phn th thu c mui vi khi lng: A. 4,26 gam B. 7,20 gam C. 5,24 gam D. 6,39 gam Cu 18. Ha tan 1,17 gam NaCl vo nc ri em in phn c mng ngn, thu c 500 ml dung dch c pH = 12. Cho Na = 23; Cl = 35,5. Hiu sut in phn l: A. 15% B. 25% C. 35% D. 45% Cu 19. Tin hnh in phn (in cc tr, c mng ngn) mt dung dch cha m gam hn hp CuSO4 v NaCl cho n khi nc bt u b in phn c hai in cc th dng li. Lc anot thu c 6,72 lit kh (kc), dung dch sau in phn c th ha tan ti a 10,2 gam Al2O3. Gi tr ca m l: A. 67,10 hoc 89,55 B. 74,50 hoc 89,55 C. 67,10 hoc 70,50 D. 67,10 hoc 74,50 Cu 20. in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,1M. C. 0,2M. D. 0,05M. Cu 21. in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp). dung
Chu Anh Tun -
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2-
dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l (bit ion SO4 khng b in phn trong dung dch) A. b < 2a. B. 2b = a. C. b = 2a. D. b > 2a. Cu 22. in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l A. 4,05. B. 5,40. C. 1,35. D. 2,70. Cu 23. in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v 67,2 3 m ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l A. 108,0. B. 75,6. C. 67,5. D. 54,0. Cu 24. in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l A. 1,792 lt. B. 2,912 lt. C. 1,344 lt. D. 2,240 lt. Cu 25. in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l A. kh Cl2 v O2. B. kh Cl2 v H2. C. ch c kh Cl2. D. kh H2 v O2. Cu 26. in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt st vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l A. 1,50. B. 2,25. C. 3,25. D. 1,25. Cu 27. in phn mt dung dch mui MCln vi in cc tr. Khi catot thu c 16 gam kim loi M th anot thu c 5,6 lt kh (ktc). Kim loi M c th l. A. Ca B. Fe C. Cu D. Al Cu 28. in phn dung dch mui sunfat ca kim loi ha tr II thu oc 3,36 l kh (ktc) anot v 16,8 g kim loi catot. Xc nh cng thc ha hc ca mui sunfat trn. A. ZnSO4 B. FeSO4 C. NiSO4 D. CuSO4 Cu 29. Chia 8,84g hn hp 1 mui kim loi (I) clorua v BaCl2 thnh 2 phn bng nhau. Ho tan hon ton phn th nht vo nc ri cho tc dng vi dung dch AgNO3 th thu c 8,61g kt tA. em in phn nng chy phn th 2 th thu c V lt kh A bay ra anot, bit rng s mol mui kim loi (I) clorua gp 4 ln s mol BaCl2. Cho hiu sut phn ng 100%. Kim loi ho tr (I) l A.K B.Cs C.Li D.Na Cu 30. Trong 500ml dung dch A c cha 0,4925 g mt hn hp gm mui clorua v hiroxit ca kim loi kim. o pH ca dung dch l 12 v khi in phn 1/10 dung dch A cho n khi ht Cl2 th thu c 11,2 ml kh Cl2 2730C v 1 atm. Tn kim loi kim l A. Kali B. Liti C. Natri D. Xexi Cu 31. in phn dung dch mui sunfat ca kim loi M ho tr II. Khi anot thu c 0,448 lit kh (kc) th thy khi lng catot tng 2,368 gam. Cng thc ca mui l A. NiSO4 B.CaSO4 C. MgSO4 D. Kt qu khc Cu 32. in phn 200ml dung dch CuSO4 vi cc in cc tr bng dng in c I = 9,65A. Khi th tch cc kh thot ra c 2 in cc u bng 1,12 lt (kc) th ngng in phn. Kim loi sinh ra catot c khi lng bng A.6,4g B.3,2g C.9,6g D.kt qu khc Cu 33. Ho tan hn hp 2 mui CuCl2 v Cu(NO3)2 vo nc pha long thnh 200ml dung dchA. in phn dung dchA mt thi gian, anot thu c 0,448 lt hn hp kh B (kc) c t khi so vi H2 bng 25,75. Khi lng kim loi bm vo catot l A.1,82g B.1,92g C. 2,88g D.3g Cau 34. Cho 2 lt dung dch hn hp A gm CuCl2 0,1M v BaCl2 0,2M. in phn dung dchA c mng ngn in cc n khi thu c dung dch c pH=13 (coi nh th tch dung dch thay i khng ng k).Tng th tch kh thot ra anot (kc) l A.3,36 lt B.7,62 lt C.6,72 lt D.5,04 lt Cu 35. Cho 250 g dung dch CuSO4 8% (dung dchA). in phn dung dch A n khi nng CuSO4 trong dung dch thu c gim i v bng phn na so vi trc phn ng th dng li. Khi lng kim loi bm trn catot v th tch kh thot ra anot (kc) ln lt l A. 2,02 g v 0,357 lt B.6,12g v 1,071 lt C. 4,08 g v 0,714 lt D.5,07g v 0,814 lt Cu 36. Ho tan 50g tinh th CuSO4.5H2O vo 600 ml dung dch HCl 0,2M ta thu c dung dch A.Tin hnh in phn vi dng in c cng 1,34 A trong thi gian 4 gi, bit hiu sut in phn l 100%. Khi lng kim loi thu c catot v th tch kh thot ra anot (kc) ln lt l A.12,8g v 1,793 lt B.6,4g v 0,896 lt C.9,6g v 0,896 lt D.6,4g v 1,792 lt Cu 37. Cho 2 bnh in phn ging nhau c in cc tr. Bnh 1 ng 100 ml dung dch AgNO3 0,15M, bnh 2 ng 100ml dung dch mui sunfat ca kim loi M ha tr (II) ng sau Al trong dy in ha. Tin hnh in
Chu Anh Tun -
- 0935166002
phn 2 bnh vi cng dng in v thi gian nh nhau. Khi catot bnh 1 c 0,648 g kim loi bm vo th catot bnh 2 bt u c kh thot ra v khi lng ca kim loi bm vo l 0,192 gam. Kim loi M l A. Canxi B. ng C. St D. Magie Cu 38. in phn dung dch mui MCln vi in cc tr. Khi catot thu c 16g kim loi M th anot thu c 5,6 lt kh (kc). Kim loi M l A. Ca B. Cu C. Mg D. Na Cu 39. Ho tan 1,63g hn hp X gm Mg, Al2O3, CuO trong dung dch HCl va , thu c 0,672 lt H2 (kc) v dung dch A. Nu in phn dung dch A n khi khi lng catot khng i th dng li, thy anot c 0,112 lt kh thot ra (kc) v dung dch B. Phn trm khi lng ca mi cht trong hn hp X ln lt l A. 44,17%;24,54%;31,29% B. 44%;24%;32% C. 22,085%;49,08%;28,835% D. Kt qu khc Cu 40. in phn (vi in cc Pt) 200 ml dung dch Cu(NO3)2 n khi bt u c kh thot ra catot th dng li. yn dung dch cho n khi khi lng catot khng i, khi lng catot tng 3,2 g so vi lc cha in phn. Nng dung dch Cu(NO3)2 l A. 1M B. 2M C. 1,5M D. 0,25M Cu 41. in phn 120 gam dung dch A cha KOH 2,8% v KCl 2,98%(c mng ngn in cc) mt thi gian n khi nng KOH trong dung dch thu c bng 3,95% th dng li. Phn trm khi lng KCl b in phn l A. 30,20% B. 25,05% C. 50,05% D. 75,25% Cu 42. Cho 200 g dung dch hn hp gm AgNO3 4,25% v Cu(NO3)2 9,4% (dung dch A).in phn dung dch A n khi catot c 8,2 gam kim loi bm vo th dng li, thu c dung dch B. Nng phn trm ca cc cht trong dung dch B l A. Cu(NO3)2 5,545% v HNO3 4,542% B. Cu(NO3)2 2,622% v HNO3 2,270% C. Cu(NO3)2 8,317% v HNO3 6,813% D. Cu(NO3)2 7,29% v HNO3 4,552% Cu 43. in phn 500 ml dung dch cha hn hp HgCl2 0,2 M v CuCl2 0,4 M vi cc in cc than ch bng dng in 10A trong thi gian 1 gi. Nng mol ca cht cn li trong dung dch sau in phn l A. 0,1135M B. 0,454M C. 0,227M D. 0,55M Cu 44. Ho tan 6,32 g hn hp Ag2SO4 v CuSO4 vo nc c dung dch A.in phn dung dch A n khi catot bt u xut hin bt kh th dng li.Ly catot ra sch, lm kh, cn li thy khi lng tng 3,44 gam. Phn trm khi lng 2 mui trong hn hp u l A. 24,68% v 75,32% B. 49,37% v 50,63% C. 70,55% v 29,45% D. Kt qu khc Cu 45. Dung dch X cha hn hp KCl v NaCl. in phn c mng ngn in cc tr 200 g dung dch X n khi t khi ca kh cc dng bt u gim th dng li. trung ho dung dch sau in phn cn 200 ml dung dch H2SO4 0,5M. C cn dung dch sau khi trung ho th c 15,8 g mui khan. Khi lng mui KCl v NaCl ln lt l A. 3,77g v 2,925 g B. 11,31g v 8,775 g C. 7,45g v 5,85 g D. Kt qu khc Cu 46. in phn c mng ngn in cc tr 100 ml dung dch MgCl2 0,15 M vi cng dng din 0,1A trong thi gian 9650 giy (bit rng th tch dung dch khng thay i trong qu trnh in phn). Nng mol ca ion Mg2+trong dung dch sau in phn l A. 0,1M B. 0,15M C. 0,2M D. 0,3M Cu 47. in phn 200ml dung dch CuSO4 vi dng in c I = 1A. Kt thc in phn khi catot bt u c bt kh thot ra. trung ho dung dch sau khi kt thc in phn dng va 50ml dung dch NaOH 0,2M. Bit hiu sut in phn l 100%. Nng mol ca dung dch CuSO4 l A. 0,0375M B. 0,025M C. 0,05M D. 0,075M Cu 48. Ha tan hon ton 17,4 gam hn hp X gm 3 kim loi Al, Fe, Mg trong dung dch HCl thy thot ra 13,44 lt kh (kc). Khi cho 34,8 gam hn hp X tc dng vi dung dch CuSO4 d, lc ly ton b cht rn thu c sau phn ng tc dng vi dung dch HNO3 nng d th thu c V lt kh NO2 (kc). Th tch kh NO2 thu c l A. 26,88 lt B. 53,76 lt C. 13,44 lt D. 44,8 lt Cu 49. in phn dung dch c cha 37,6 g Cu(NO3)2 v 59,6 g KCl,c mng ngn,in cc tr. Sau 1 thi gian thy khi lng dung dch gim 34,3 gam so vi ban u, th tch dung dch l 0,8 lt. Nng mol ca cc cht trong dung dch sau khi in phn l A. KCl 0,25M; KNO3 0,5M; KOH 0,25M C. KCl 0,25M; KNO3 0,375M B. KCl 0,375M; KNO3 0,625M; KOH 0,25M D. KCl 0,375M; KOH 0,25M Cu 50. in phn 200g dung dch mui MSO4 4% n khi 2 cc cng c kh thot ra th dng li.Ly catot ra sch, lm kh cn li thy khi lng tng ln 3,2 gam. Cng thc mui l A. CaSO4 B. MgSO4 C. CdSO4 D.CuSO4.
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Chu Anh Tun -
- 0935166002
Chuyn 7:
BI TP NHIT HA
Cu 1. Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t chy l A. 64,68%. B. 74,69%. C. 95,00%. D. 25,31%. Khi nhit phn hon ton 100 gam mi cht sau: KClO (xc tc MnO ), KMnO Cu 2. 3 2 4, KNO3 v AgNO3 . Cht to ra lng O2 ln nht l A. KClO3. B. KNO3. C. AgNO3. D. KMnO4. Cu 3. Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton, thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. Phn trm khi lng ca FeS trong hn hp X l A. 42,31%. B. 26,83%. C. 59,46%. D. 19,64%. Cu 4. Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4, MnO2 v KCl. Ton b lng O2 tc dng ht vi cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16. Thnh phn % theo khi lng ca KMnO4 trong X l A. 62,76%. B. 72,06%. C. 74,92%. D. 27,94%. Cu 5. t chy hon ton 8,8gam FeS v 12 gam FeS2 thu c kh. Cho kh ny sc vo Vml dung dch NaOH 25%(d=1,28g/ml) c mui trung ha. Gi tr ti thiu ca V l A. 50ml. B. 75ml. C. 100ml. D. 120ml. Cu 6. t chy hon ton hn hp X gm 0,02 mol FeS2 v 0,01 mol FeS ri cho kh thu c hp th ht vo dung dch KMnO4 va , thu c V lt dung dch c pH = 2 (b qua s thu phn ca mui). Gi tr ca V l A. 8 B. 2. C. 6. D. 4. Cu 7. t chy hn hp lu hunh v cacbon (th tch khng ng k) trong bnh kn ng oxi d, sau a bnh v nhit ban u th p sut trong bnh so vi trc khi t s: A. tng B. gim C. khng i D. c th tng hoc gim ph thuc lng C, S Cu 8. Nung hn hp A gm CaCO3 v CaSO3 ti phn ng hon ton c cht rn B c khi lng bng 50,4% khi lng ca hn hp A. Cht rn A c % khi lng hai cht ln lt l: A. 40% v 60% B. 30% v 70% C. 25% v 75% D. 20% v 80% Cu 9. Sau khi ozon ha 100 ml kh oxi, a v trng thi ban u th p sut gim 5% so vi p sut ban u. Thnh phn % th tch ca ozon trong hn hp sau phn ng l: A. 15,3% B. 20,3% C. 10% D. 10,53% Cu 10. Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn ton b Y vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch tan mt phn v thot ra kh NO (sn phm kh duy nht). Bit cc phn ng xy ra hon ton. Phn trm khi lng ca X phn ng l A. 25%. B. 60%. C. 70%. D. 75%. Cu 11. Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 0,896. B. 0,448. C. 1,120. D. 0,224. Cu 12. Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,112. B. 0,448. C. 0,560. D. 0,224. Cu 13. Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ho tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l A. 28,57%. B. 57,15%. C. 18,42%. D. 14,28%. Cu 14. Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H2 (ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi cc phn ng kt thc th s mol NaOH phn ng l A. 0,08 mol. B. 0,06 mol. C. 0,16 mol. D. 0,14 mol. Cu 15. Nung hn hp gm 10,8 gam Al v 16,0 gam Fe2O3 (trong iu kin khng c khng kh), sau khi phn ng xy ra hon ton thu c cht rn Y. Khi lng kim loi trong Y l A. 22,4 gam. B. 16,6 gam. C. 5,6 gam. D. 11,2 gam. Cu 16. Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, Fe, ZnO, MgO. B. Cu, FeO, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, Fe, Zn, MgO. Cu 17. Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng hon
Chu Anh Tun -
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ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l A. 4,0 gam. B. 8,3 gam. C. 2,0 gam. D. 0,8 gam. Cu 18. Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ho tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy l A. CrO. B. Fe3O4. C. FeO. D. Cr2O3. Cu 19. kh hon ton 8,0 gam bt Fe2O3 bng bt Al ( nhit cao, trong iu kin khng c khng kh) th khi lng bt nhm cn dng l A. 8,10 gam. B. 1,35 gam. C. 2,70 gam. D. 5,40 gam. Khi cho 41,4 gam hn hp X gm Fe O , Cr O v Al O tc dng vi dung dch NaOH c (d), sau Cu 20. 2 3 2 3 2 3 phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l (Cho: hiu sut ca cc phn ng l 100%; O = 16; Al = 27; Cr = 52; Fe = 56) A. 66,67%. B. 20,33%. C. 50,67%. D. 36,71%. Cu 21. t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi tr ca V l A. 300. B. 150. C. 100. D. 200. Cu 22. Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc); - Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l A. 29,43. B. 22,75 C. 21,40. D. 29,40. Cu 23. Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2(d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l A. 36,7. B. 45,6. C. 48,3. D. 57,0. Cu 24. Trn 10,8 gam bt Al vi 34,8 gam bt Fe3O4 ri tin hnh phn ng nhit nhm trong iu kin khng c khng kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H2SO4 long (d), thu c 10,752 lt kh H2 (ktc). Hiu sut ca phn ng nhit nhm l A. 80%. B. 60%. C. 70%. D. 90%. Cu 25. Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 ( ktc). Gi tr ca V l A. 4,48. B. 7,84. C. 10,08. D. 3,36. Cu 26. Trn 0,54 gam bt Al vi Fe2O3 v CuO, ri tin hnh phn ng nhit nhm iu kin khng c khng kh, thu c hn hp cht rn A. Ha tan A trong dung dch HNO3 thu c 0,896 lt (kc) hn hp kh B gm NO2 v NO. T khi ca hn hp B so vi H2 l: A. 17 B. 19 C. 21 D. 23 Cu 27. Trn 6,48 g Al vi 16 g Fe O ri thc hin phn ng nhit nhm th thu c cht rn A, cho A tc dng
2 3
vi dd NaOH d th c 1,344 lt kh ktc. Hiu sut ca phn ng nhit nhm: A. 100% B. 75% C. 83,33% D. 80% Cu 28. kh hon ton 3,04 gam hn hp Y (gm FeO, Fe3O4, Fe2O3) th cn 0,05 mol H2. Mt khc ho tan hon ton 3,04 gam hn hp Y trong dung dch H2SO4 c th thu c th tch kh SO2 (sn phm kh duy nht) iu kin tiu chun l: A. 224ml. B. 448ml. C. 336ml. D. 112ml. Cu 29. kh hon ton 6,4 gam mt oxt kim loi cn 0,12 mol kh H2. Mt khc ly lng kim loi to thnh cho tan hon ton trong dung dch H2SO4 long th thu c 0,08 mol H2. Cng thc oxit kim loi l: A. CuO. B. Al2O3. C. Fe3O4. D. Fe2O3. Cu 30. Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l (Cho H = 1; C = 12; O = 16; Fe = 56) A. FeO; 75%. B. Fe3O4; 75%. C. Fe2O3; 75%. D. Fe2O3; 65%. Cu 31. Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gis cc phn ng xy ra hon ton. Phn khng tan Z gm A. MgO, Fe3O4, Cu. B. MgO, Fe, Cu. C. Mg, Fe, Cu. D. Mg, Al, Fe, Cu. Cu 32. Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng thu c 0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l A. Fe2O3 v 0,448. B. Fe3O4 v 0,224. C. Fe3O4 v 0,448. D. FeO v 0,224.
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Cu 33. Cho mt lung CO i qua ng s dng m gam Fe2O3 nung nng. Sau mt thi gian thu c 13,92 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3. Ho tan ht X bng HNO3 c nng c 5,824 lt NO2 (kc). Gi tr ca m l: A. 18,08 gam B. 16,0 gam C. 11,84 gam D. 9,76 gam Cu 34. kh hon ton 8,64 g hn hp Fe, FeO, Fe2O3 v Fe3O4 cn 0,5 mol CO. Mt khc ha tan hon ton hn hp trn bng dung dch HNO3 long d th thu c V lt NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 2,688 B. 2,389 C. 4,704 D. 3,316 Cu 35. Nung hn hp X ng s mol gm FeS2 v FeCO3 vo bnh kn cha khng kh vi lng gp i lng cn thit phn ng ht vi X. Sau khi nung a bnh v nhit ban u (khng kh cha O2, N2 vi t l th tch 1:4). p sut trong bnh trc v sau phn ng l p1, p2. Quan h gia chng l A. p1 = 2p2. B. p1 > p2. C. p2 > p1. D. p1 = p2. Cu 36. Thi mt lung kh CO qua hn hp Fe v Fe2O3 nung nng thu c kh B v cht rn D. Cho B qua nc vi trong d thy to ra 6 gam kt ta. Ho tan D bng H2SO4 c nng d thy to ra 0,18 mol kh SO2 v 24 gam mui. Phn trm s mol ca Fe v Fe2O3 trong hn hp ban u ln lt l. A. 45% ; 55% B. 80%; 20% C. 75% ; 25% D. 66,67% ; 33,33% Cu 37. Trn m gam bt Al vi Fe2O3 ri nung nng trong iu kin khng c khng kh mt thi gian th c hn hp rn X gm Fe2O3, Fe3O4, FeO, Fe, Al2O3 v Al d. Ha tan hon ton X trong dd HNO3 c, nng th c 6,72 lt kh NO (kc). Gi tr ca m l:
2
A. 2,7g B. 4,05g C. 8,1g D. 5,4g Cu 38. iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l A. 54,0 gam. B. 45,0 gam. C. 81,0 gam. D. 40,5 gam. Cu 39. Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 ( ktc). Gi tr ca V l (cho O = 16, Al = 27, Cr = 52) A. 7,84. B. 4,48. C. 10,08. D. 3,36. Cu 40. Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l: (Cho: hiu sut ca cc phn ng l 100%) A. 26,08%. B. 36,71%. C. 50,67%. D. 66,67%.
Chuyn 8:
BI TP HIRCACBON
Cu 1. Trong cng nghip, axeton c iu ch t A. cumen. B. xiclopropan. C. propan-2-ol. D. propan-1-ol. Cu 2.Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. anken. B. ankan. C. ankaien. D. ankin. Cu 3. Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2; CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l A. 2. B. 3. C. 4. D. 1. Cu 4. Cht no sau y c ng phn hnh hc? A. But-2-en. B. But-2-in. C. 2-clopropen. D. 1,2-icloetan. Cu 5. S lin kt (xich ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln lt l: A. 4; 3; 6. B. 3; 5; 9. C. 5; 3; 9. D. 4; 2; 6. Cu 6. Cht no sau y c ng phn hnh hc? A. CH3-CH=CH-CH=CH2. B. CH3-CH=C(CH3)2. C. CH2=CH-CH=CH2. D. CH2=CH-CH2-CH3. Cu 7. Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v xiclopentan.Trong cc cht trn, s cht phn ng c vi dung dch brom l A. 5. B. 6. C. 4. D. 3. Cu 8. Cht X tc dng vi benzen (xt, t) to thnh etylbenzen. Cht X l A. C2H6. B. C2H2. C. CH4. D. C2H4. Cu 9.Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt bt st) l A. p-bromtoluen v m-bromtoluen. B. o-bromtoluen v p-bromtoluen. C. o-bromtoluen v m-bromtoluen. D. benzyl bromua.
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+ Cl2 (1:1)
+ NaOH + HCl , Fe Y Z. Cu 10. Cho s : C6H6 (benzen) X to , p
Hai cht hu c Y, Z ln lt l: A. C6H4(OH)2, C6H4Cl2. B. C6H6(OH)6, C6H6Cl6. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. Cu 11. Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. propen v but-2-en . B. eten v but-1-en . C. 2-metylpropen v but-1-en . D. eten v but-2-en . Cu 12. Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l A. 4. B. 5. C. 3. D. 2. Cu 13.S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 3. B. 4. C. 2. D. 5. Cu 14. Cho cc phn ng: to C2H4 + Br2 HBr + C2H5OH
askt (1:1mol) C2H4 + HBr C2H6 + Br2 S phn ng to ra C2H5Br l A. 4. B. 2. C. 3. D. 1. Cu 15. Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. etilen. B. stiren. C. xiclopropan. D. xiclohexan. Cu 16. Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A. 3-etylpent-2-en. B. 3-etylpent-3-en. C. 2-etylpent-2-en. D. 3-etylpent-1-en. Cu 17. Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 1. B. 4. C. 2. D. 3.
+ Br2 ,as + KOH / C2 H 5OH 2 4 X Y Z (trong X, Y, Z l Cu 18. Cho dy chuyn ho sau: Benzen 1:1 xt ,t o to
+C H
sn phm chnh). Tn gi ca Y, Z ln lt l A. 1-brom-2-phenyletan v stiren. B. 1-brom-1-phenyletan v stiren. C. 2-brom-1-phenylbenzen v stiren. D. benzylbromua v toluen. Cu 19. Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau. (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh. (g) Hp cht C9H14BrCl c vng benzen trong phn t. S pht biu ng l A. 5. B. 3. C. 4. D. 2. Cu 20. Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A. 24. B. 31. C. 34. D. 27. Cu 21. Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l (Cho H = 1; C = 12; Cl = 35,5) A. 3-metylpentan. B. 2,3-imetylbutan. C. butan. D. 2-metylpropan. Cu 22. Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l A. 7,3. B. 6,6. C. 5,85. D. 3,39. Cu 23. t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l (Cho H = 1; C = 12; O = 16) A. 56,0 lt. B. 78,4 lt. C. 84,0 lt. D. 70,0 lt. Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4lm xc tc) thu c hn Cu 24. hp Z gm hai ancol X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k) A. C4H9OH v C5H11OH. B. C2H5OH v C3H7OH. C. C2H5OH v C4H9OH. D. C3H7OH v C4H9OH. Cu 25. t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l
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A. 25,8. B. 22,2. C. 12,9. D. 11,1. Cu 26. t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 75% v 25%. B. 20% v 80%. C. 35% v 65%. D. 50% v 50%. Cu 27. t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. 2,2-imetylpropan. C. etan. D. 2-Metylpropan. Cu 28. kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l A. 2,688. B. 2,240. C. 4,480. D. 1,344. Cu 29. Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 8,0. B. 16,0. C. 3,2. D. 32,0. Cu 30. Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 40%. B. 50%. C. 20%. D. 25%. Cu 31. Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau o khi phn ng vi H2 (d, xc tc Ni, t ), cho cng mt sn phm l: A. 2-metylpropen, cis-but-2-en v xiclobutan. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. xiclobutan, cis-but-2-en v but-1-en. o Cu 32. Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, t ), thu c hn hp Y ch c hai hirocacbon. Cng thc phn t ca X l A. C3H4. B. C2H2. C. C4H6. D. C5H8. Cu 33. t chy hon ton 6,72 lt (ktc) hn hp gm hai hirocacbon X v Y (MY > MX), thu c 11,2 lt kh CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l A. C2H6. B. C2H2. C. CH4. D. C2H4. Cu 34. Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A. 10. B. 20. C. 30. D. 40. Cu 35. Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 ltdung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A. C2H2 v C3H8. B. C3H4 v C4H8. C. C2H2 v C4H8. D. C2H2 v C4H6. Cu 36. Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A. C4H8. B. C3H4. C. C3H6. D. C3H8. Cu 37. Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C4H8. B. C3H4. C. C2H4. D. C3H6. Cc ng phn ng vi cng thc phn t C H O (u l dn xut ca benzen) c tnh cht: tch nc thu Cu 38. 8 10 c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 1. B. 3. C. 4. D. 2. Cu 39. C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. nc brom. B. giy qu tm. C. dung dch phenolphtalein. D. dung dch NaOH. Cu 40.Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l (cho H = 1, C = 12, N = 14, O = 16) A. 60%. B. 70%. C. 80%. D. 50%. Cu 41. Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 2,2-imetylpropan. B. 3,3-imetylhecxan. C. isopentan. D. 2,2,3-trimetylpentan. Cu 42. Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C5H12. B. C4H10. C. C6H14. D. C3H8.
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Cu 43. t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H6. B. CH4. C. C3H8. D. C2H4. Cu 44. Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. anken. B. ankan. C. ankin. D. ankaien. Cu 45. Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C2H4. B. CH4 v C3H6. C. CH4 v C3H4. D. C2H6 v C3H6. Cu 46. Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 5. B. 4. C. 2. D. 6. Cu 47. Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. B. C2H6 v C2H4. C. CH4 v C4H8. D. CH4 v C3H6. Cu 48. t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CH2=C=CH2, CH2=C=C=CH2. B. CHC-CH3, CH2=C=C=CH2. C. CH2=C=CH2, CH2=CH-CCH. D. CHC-CH3, CH2=CH-CCH. Cu 49. Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8.Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 26,88 lt. B. 22,4 lt. C. 44,8 lt. D. 33,6 lt. Cu 50. Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,24 mol. B. 0,48 mol. C. 0,60 mol. D. 0,36 mol.
Chuyn 9:
BI TP DN XUT HALOGEN ANCOL - PHENOL
Cu 1. Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y); HOCH2CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Z, T. B. X, Y, R, T. C. Z, R, T. D. X, Y, Z, T. Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v Cu 2. vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. HOC6H4CH2OH. B. CH3C6H3(OH)2. C. CH3OC6H4OH. D. C6H5CH(OH)2. Cu 3. Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 4. B. 2. C. 1. D. 3. o Cu 4. Khi un nng hn hp ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4c, 140 C) th s ete thu c ti a l A. 2. B. 4. C. 1. D. 3. Cu 5. Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l A. CH3-CH2-CHOH-CH3. B. CH3-CH2-CH2-OH. C. CH3-CHOH-CH3. D. CH3-CO-CH3. Cu 6. Dy gm cc cht u tc dng vi ancol etylic l: o A. NaOH, K, MgO, HCOOH (xc tc). B. Ca, CuO (t ), C6H5OH (phenol), HOCH2CH2OH. o o o C. HBr (t ), Na, CuO (t ), CH3COOH (xc tc). D. Na2CO3, CuO(t ),CH3COOH(xc tc), (CH3CO)2O. Cu 7. Kh nng phn ng th nguyn t clo bng nhm -OH ca cc cht c xp theo chiu tng dn t tri sang phi l: A. anlyl clorua, phenyl clorua, propyl clorua. B. anlyl clorua, propyl clorua, phenyl clorua. C. phenyl clorua, anlyl clorua, propyl clorua. D. phenyl clorua, propyl clorua, anlyl clorua.
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Cu 8. Pht biu ng l: A. Thu phn benzyl clorua thu c phenol. B. Phenol phn ng c vi dung dch NaHCO3. C. Phenol phn ng c vi nc brom. D. Vinyl axetat t/d vi dd NaOH to ancol etylic. Cu 9. Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu c X. Tn gi ca X l A. propanal. B. metyl phenyl xeton. C. imetyl xeton. D. metyl vinyl xeton. Cu 10. un si hn hp gm propyl bromua, kali hiroxit v etanol thu c sn phm hu c l A. propan-2-ol. B. propen. C. propin. D. propan. Cu 11. S ancol ng phn cu to ca nhau c cng thc phn t C5H12O, tc dng vi CuO un nng sinh ra xeton l A. 3. B. 2. C. 4. D. 5. Cu 12. S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l A. 4. B. 6. C. 5. D. 7. Cu 13. Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. CH3OCH2CH2CH3. B. (CH3)3COH. C. CH3CH(CH3)CH2OH. D. CH3CH(OH)CH2CH3. Cu 14. Dy gm cc cht u phn ng vi phenol l: A. nc brom, anhirit axetic, dung dch NaOH. B. dung dch NaCl, dung dch NaOH, kim loi Na. C. nc brom, anehit axetic, dung dch NaOH. D. nc brom, axit axetic, dung dch NaOH. Cu 15. S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 3. B. 2. C. 4. D. 1. Cu 16. Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l A. 2-metylbut-2-en. B. 2-metylbut-3-en. C. 3-metylbut-2-en. D. 3-metylbut-1-en. Cu 17. nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. nc Br2. C. Na kim loi. D. H2 (Ni, nung nng). o o + HCl ( du ) + Br (1:1 mol ), Fe , t + NaOH ( du ), t , p 2 Cu 18. Cho s chuyn ho sau: Toluen Z X Y Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol.
to Cu 19. Cho dy chuyn ho sau: Phenol Phenyl axetat Y (hp cht thm) Hai cht X, Y trong s trn ln lt l: A. anhirit axetic, natri phenolat. B. anhirit axetic, phenol. C. axit axetic, natri phenolat. D. axit axetic, phenol. Cu 20. Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C2H5OH v C4H9OH. B. C2H4(OH)2 v C3H6(OH)2. C. C2H4(OH)2 v C4H8(OH)2. D. C3H5(OH)3 v C4H7(OH)3. Cu 21. Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. axit acrylic. C. metyl axetat. D. phenol. Cu 22. Cho cc hp cht sau: (a) HOCH2-CH2OH. (b) HOCH2-CH2-CH2OH. (c) HOCH2-CH(OH)-CH2OH. (d) CH3-CH(OH)-CH2OH. (e) CH3-CH2OH. (f) CH3-O-CH2CH3. Cc cht u tc dng c vi Na, Cu(OH)2 l: A. (c), (d), (f). B. (c), (d), (e). C. (a), (c), (d). D. (a), (b), (c).
+X + NaOHdu
X (anken) Y Z. Cu 23. Cho s chuyn ho: Butan-2-ol Trong X, Y, Z l sn phm chnh. Cng thc ca Z l A. (CH3)2CH-CH2-MgBr. B. (CH3)3C-MgBr. C. CH3-CH(MgBr)-CH2-CH3. D. CH3-CH2-CH2 -CH2-MgBr. Cu 24. Trong s cc pht biu sau v phenol (C6H5OH): (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (2), (3), (4). B. (1), (2), (3). C. (1), (3), (4). D. (1), (2), (4).
H 2 SO4 ,t o
+ HBr
+ Mg , etekhan
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+ dd Br2 + NaOH CuO,t o O 2 , xt

CH 3OH ,t o , xt
Z T E Cu 25. Cho s chuyn ho: C3H6 X Y Bit E l este a chc. Tn gi ca Y l A. propan-2-ol. B. propan-1,2-iol. C. glixerol. D. propan-1,3-iol. Cu 26. Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l A. metyl isopropyl xeton. B. 2-metylbutan-3-on. C. 3-metylbutan-2-ol. D. 3-metylbutan-2-on. Cu 27. Pht biu no sau y ng? A. Khi un C2H5Br vi dung dch KOH ch thu c etilen. B. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi. o C. un ancol etylic 140 C (xc tc H2SO4 c) thu c imetyl ete. D. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng. Cu 28. Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4metylphenol; (6) -naphtol. Cc cht thuc loi phenol l: A. (1), (3), (5), (6). B. (1), (4), (5), (6). C. (1), (2), (4), (5). D. (1), (2), (4), (6).
H ,t to +H + Cu 29. Cho s phn ng: Stiren X Y Z. Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l: A. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH. B. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH. C. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br. D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3. Cu 30. C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 (xc o tc Ni, t )? A. 2. B. 4. C. 3. D. 5. Cu 31. Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 5. B. 4. C. 3. D. 6. Cu 32. Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l: A. phenol, natri hiroxit, natri phenolat. B. natri phenolat, axit clohiric, phenol. C. anilin, axit clohiric, phenylamoni clorua. D. phenylamoni clorua, axit clohiric, anilin. Cu 33. C bao nhiu ancol bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? (Cho H = 1; C = 12; O = 16) A. 4. B. 2. C. 5. D. 3. Cu 34. t chy hon ton mt ancol X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O. B. C3H8O2. C. C3H4O. D. C3H8O3. Cu 35. Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O = 16) A. 3. B. 2. C. 4. D. 5. Cu 36. t chy hon ton hn hp M gm hai ancol X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l: A. C2H6O, CH4O. B. C2H6O2, C3H8O2. C. C3H6O, C4H8O. D. C2H6O, C3H8O. Cu 37. t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 vi t l s mol tng ng l 3:2. Cng thc phn t ca X l A. C2H6O2. B. C2H6O. C. C4H10O2. D. C3H8O2. Cu 38. Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 5,75 gam. B. 2,30 gam. C. 1,15 gam. D. 4,60 gam. o Cu 39. Cho 10 ml dung dch ancol etylic 46 phn ng ht vi kim loi Na (d), thu c V lt kh H2 (ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l A. 3,360. B. 0,896. C. 4,256. D. 2,128. Cu 40. Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m l A. 14,0. B. 7,0. C. 10,5. D. 21,0. Cu 41. t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng ng thu c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh trn vi H2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l
+ H 2O + o + CuO + Br2
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A. 6,45 gam. B. 7,40 gam. C. 5,46 gam. D. 4,20 gam. Cu 42. Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = 23) A. CH3OH v C2H5OH. B. C3H7OH v C4H9OH. C. C3H5OH v C4H7OH. D. C2H5OH v C3H7OH. Cu 43. Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l (cho H = 1, C =12, O = 16) A. 0,64. B. 0,46. C. 0,32. D. 0,92. Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO thu c nh hn 35,2 gam. Bit rng, Cu 44. 2 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho C =12, O = 16) A. C6H4(OH)2. B. HOCH2C6H4COOH. C. C2H5C6H4OH. D. HOC6H4CH2OH. Cu 45. X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l (cho C = 12, O = 16) A. C3H5(OH)3. B. C3H7OH. C. C2H4(OH)2. D. C3H6(OH)2. Cu 46. Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l A. 3. B. 1. C. 4. D. 2. Cu 47. un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi o H2SO4c 140 C. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l A. C2H5OH v C3H7OH. B. C3H7OH v C4H9OH. C. C3H5OH v C4H7OH. D. CH3OH v C2H5OH. Cu 48. un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O. Cu 49. t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc).Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 4,9 v propan-1,2-iol. B. 9,8 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. Cu 50. un nng hn hp hai ancol n chc, mch h vi H2SO4c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH3OH. B. C2H5OH v CH2=CH-CH2-OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CH-CH2-OH. Cu 51. Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l: A. m = 2a - V/11,2. B. m = a - V/5,6. C. m = a + V/5,6. D. m = 2a -V/22,4. Cu 52. Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 4. C. 6. D. 5. Cu 53. Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOCH3. B. HO-CH2-C6H4-OH. C. HO-C6H4-COOH. D. CH3-C6H3(OH)2. Cu 54. t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c 3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l A. 7,42. B. 4,72. C. 5,72. D. 5,42. Cu 55. Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l A. 18,24. B. 27,36. C. 22,80. D. 34,20. Cu 56. Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,45. B. 0,60. C. 0,36. D. 0,54. Cu 57. t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4c th tng khi lng ete ti a thu c l A. 7,40 gam. B. 5,60 gam. C. 7,85 gam. D. 6,50 gam. Cu 58. t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi tr ca V l
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A. 15,68. B. 14,56. C. 4,48. D. 11,20. Cu 59. Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong, thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l A. 486. B. 324. C. 405. D. 297. Cu 60. Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 7. B. 3. C. 9. D. 10. Cu 61. Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh hai phn bng nhau: - t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O. o - un nng phn 2 vi H2SO4 c 140 C to thnh 1,25 gam hn hp ba ete. Ho hi hon ton hn hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut). Hiu sut phn ng to ete ca X, Y ln lt l A. 30% v 30%. B. 20% v 40%. C. 40% v 20%. D. 25% v 35%.
Chuyn 10:
ANHIT - XTON
Cu 1. Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2-OH (4). o Nhng cht phn ng hon ton vi lng d H2 (Ni, t ) cng to ra mt sn phm l: A. (2), (3), (4). B. (1), (2), (4). C. (1), (3), (4). D. (1), (2), (3). Cu 2. Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d AgNO3 trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 21,6 gam. D. 64,8 gam. Cu 3. Anehit no mch h X c cng thc n gin nht C2H3O. Cng thc phn t ca X l A. C4H6O2. B. C6H9O3. C. C2H3O. D. C8H12O4. Cu 4. iu kin thch hp: cht X phn ng vi cht Y to ra anehit axetic; cht X phn ng vi cht Z to ra ancol etylic. Cc cht X, Y, Z ln lt l: A. C2H2, H2O, H2. B. C2H2, O2, H2O. C. C2H4, H2O, CO. D. C2H4, O2, H2O. Cu 5. ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi tc dng vi kh H2 (xc tc Ni, o t ) sinh ra ancol? A. 4. B. 3. C. 1. D.2. Cu 6. Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO l A. 2. B. 4. C. 1. D. 3. Cu 7. S ng phn xeton ng vi cng thc phn t C5H10O l A. 5. B. 4. C. 3. D. 6. Cu 8. Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. B. CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. C. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. D. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. Cu 9. Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: A. HCOOC2H3, C2H2, CH3COOH. B. C2H5OH, C2H2, CH3COOC2H5. C. CH3COOH, C2H2, C2H4. D. C2H5OH, C2H4, C2H2. Cu 10. Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH. Phn ng ny chng t C6H5-CHO A. ch th hin tnh oxi ho. B. va th hin tnh oxi ho, va th hin tnh kh. C. khng th hin tnh kh v tnh oxi ho. D. ch th hin tnh kh. Cu 11. Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho mn s
H 2 SO4 , dac Ni ,t chuyn ho sau: X Y Este c mi chui chn.Tn ca X l: A. 2,2-imetylpropanal. B. 2-metylbutanal. C. 3-metylbutanal. D. pentanal. Cu 12. Pht biu no sau y v anehit v xeton l sai? A. Axeton khng phn ng c vi nc brom. B. Axetanehit phn ng c vi nc brom. C. Anehit fomic tc dng vi H2O to thnh sn phm khng bn.
+ H2 o + CH 3COOH
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D. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn. Cu 13. X, Y, Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O. X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l: A. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3. B. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH. C. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH. D. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO. Cu 14. Cho cc pht biu sau: (a) Anehit va c tnh oxi ho va c tnh kh. (b) Phenol tham gia phn ng th brom kh hn benzen. (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt. (d) Dung dch axit axetic tc dng c vi Cu(OH)2. (e) Dung dch phenol trong nc lm qu tm ho . (g) Trong cng nghip, axeton c sn xut t cumen. S pht biu ng l A. 2. B. 4. C. 5. D. 3. Cu 15. Cho s phn ng:
2 + HCN X2. (1) CH3CHO X1 + H + ,t o
+H O
Mg + CO2 HCl Y1 (2) C2H5Br Y2 + Y3 . ete Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l A. axit 2-hiroxipropanoic v axit propanoic. B. axit axetic v axit propanoic. C. axit 3-hiroxipropanoic v ancol propylic. D. axit axetic v ancol propylic. Cu 16. Cho s phn ng: xt ,t o xt ,t o (1) X + O2 axit cacboxylic Y1. (2) X + H2 ancol Y2.
(3) Y1 + Y2 t Y3 + H2O. Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l A. anehit axetic. B. anehit metacrylic. C. anehit acrylic. D. anehit propionic. Cu 17. Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l (Cho H = 1; C = 12; O = 16; Ag = 108) A. CH2=CH-CHO. B. OHC-CHO. C. CH3CHO. D. HCHO. Cu 18. t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc dng vi lng d hoc AgNO3 trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X phn ng. Cng thc ca X l A. CH3CHO. B. C2H5CHO. C. HCHO. D. (CHO)2. Cu 19. Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 32,44%. B. CH3CHO v 67,16%. C. HCHO v 50,56%. D. CH3CHO v 49,44%. Cu 20. Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. HCHO v C2H5CHO. B. C2H3CHO v C3H5CHO. C. HCHO v CH3CHO. D. CH3CHO v C2H5CHO. Cu 21. Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2 gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 43,2. B. 21,6. C. 16,2. D. 10,8. Cu 22. Hn hp G gm hai anehit X v Y, trong MX < MY < 1,6MX. t chy hn hp G thu c CO2 v H2O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung dch AgNO3 trong NH3 thu c 0,25 mol Ag. Tng s cc nguyn t trong mt phn t Y l A. 6. B. 9. C. 10. D. 7. Cu 23. Cho 0,1 mol anehit X tc dng vi lng d AgNO3 trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108) A. CH3CH(OH)CHO. B. CH3CHO. C. HCHO. D. OHC-CHO. Cu 24. Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. HCHO. B. CH2= CHCHO. C. CH3CH2CHO. D. CH3CHO. Cu 25. t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. khng no c hai ni i, n chc. B. no, hai chc. C. khng no c mt ni i, n chc. D. no, n chc.
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Cu 26. Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l (cho H = 1, C = 12, O = 16) A. C2H3CHO. B. C2H5CHO. C. CH3CHO. D. HCHO. Cu 27. Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 9,2. B. 7,8. C. 8,8. D. 7,4. Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag O (hoc AgNO3) trong dung Cu 28. 2 dch NH3un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. C2H5CHO. C. HCHO. D. C4H9CHO. Cu 29. un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. no, hai chc. B. no, n chc. C. khng no (cha mt ni i C=C), hai chc. D. khng no (cha mt ni i C=C), n chc. Cu 30. Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 65,5%. B. 80,0%. C. 76,6%. D. 70,4%. Cu 31. Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c 54 o gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t ) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n+1CHO (n 0). B. CnH2n-1CHO (n 2). C. CnH2n-3CHO (n 2). D. CnH2n(CHO)2 (n 0). Cu 32. Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2( ktc). Phn trm theo th tch ca H2 trong X l A. 35,00%. B. 53,85%. C. 46,15%. D. 65,00%. Cu 33. t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. C. HO-CH2-CH2-CH2-CHO. D. HO-CH2-CH=CH-CHO. Cu 34. t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. CH2=CH-CH2-OH. B. O=CH-CH=O. C. C2H5CHO. D. CH3COCH3. Cu 35. Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HO-CH2-CHO v HO-CH2-CH2-CHO. B. HO-CH(CH3)-CHO v HOOC-CH2-CHO. C. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO. D. HCOOCH3 v HCOOCH2-CH3. Cu 36. Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 24,8. B. 10,5. C. 8,8. D. 17,8. Cu 37. Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 13,5. B. 15,3. C. 8,5. D. 8,1. Cu 38. Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l A. 10,2. B. 9,5. C. 10,9. D. 14,3. Cu 39. Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol l: A. C2H5OH, C2H5CH2OH. B. CH3OH, C2H5OH. C. C2H5OH, C3H7CH2OH. D. CH3OH, C2H5CH2OH. Cu 40. Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l A. CH4. B. C3H6. C. C2H2. D. C2H4. Cu 41. Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l
Chu Anh Tun -
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A. 16,3%. B. 48,9%. C. 65,2%. D. 83,7%. Cu 42. t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l A. anehit khng no, mch h, hai chc. B. anehit axetic. C. anehit no, mch h, hai chc. D. anehit fomic. Cu 43. hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H2(ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l A. CH2=C(CH3)-CHO v OHC-CHO. B. H-CHO v OHC-CH2-CHO. C. CH2=CH-CHO v OHC-CH2-CHO. D. OHC-CH2-CHO v OHC-CHO. Cu 44. Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l A. 20%. B. 50%. C. 30%. D. 40%. Cu 45. Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca Z l A. anehit propionic. B. anehit butiric. C. anehit axetic. D. anehit acrylic. Cu 46. X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H2 (ktc). Gi tr ln nht ca V l A. 5,6. B. 13,44. C. 11,2. D. 22,4.
Chuyn 11:
BI TP AXIT CACBOXYLIC
Cu 1. Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 3. B. 2. C. 4. D. 1. Cu 2. Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CH2OH v CH3CHO. B. CH3CHO v CH3CH2OH. C. CH3CH2OH v CH2=CH2. D. CH3CH(OH)COOH v CH3CHO. Cu 3. Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l: A. C2H5OH, CH3COOH. B. C2H4, CH3COOH. C. CH3COOH, CH3OH. D. CH3COOH, C2H5OH. Cu 4. Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l: A. (Y), (T), (X), (Z). B. (T), (Y), (X), (Z). C. (X), (Z), (T), (Y). D. (Y), (T), (Z), (X). Cu 5. Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3OH, C2H5OH, CH3CHO. B. CH3CHO, C2H5OH, C2H5COOCH3. C. C2H4(OH)2, CH3OH, CH3CHO. D. CH3CHO, C6H12O6 (glucoz), CH3OH. Cu 6. Qu trnh no sau y khng to ra anehit axetic? o o A. CH2=CH2 + H2O (t , xc tc HgSO4). B. CH2=CH2 + O2 (t , xc tc). o o C. CH3COOCH=CH2 + dung dch NaOH (t ). D. CH3CH2OH + CuO (t ). Cu 7. Hai cht X v Y c cng cng thc phn t C2H4O2. Cht X phn ng c vi kim loi Na v tham gia phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO3. Cng thc ca X, Y ln lt l: A. CH3COOH, HOCH2CHO. B. HOCH2CHO, CH3COOH. C. HCOOCH3, CH3COOH. D. HCOOCH3, HOCH2CHO.
+ KCN 3 X Y. Cu 8. Cho s chuyn ha: CH3CH2Cl Trong s trn, X v Y ln lt l A. CH3CH2NH2 v CH3CH2COOH. B. CH3CH2CN v CH3CH2OH. C. CH3CH2CN v CH3CH2COOH. D. CH3CH2CN v CH3CH2CHO.
+ H O + ,t o
Y T CH3COOH Cu 9. Cho s phn ng: CH4 (X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng). Cht T trong s trn l A. C2H5OH. B. CH3COONa. C. CH3OH. D. CH3CHO. Cu 10. Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l: A. C6H5OH, CH3COOH, CH3CH2OH. B. HCOOH, CH3COOH, CH3CH2COOH.
+ X , xt ,t o
+ Z , xt ,t o
+ M , xt ,t o
Chu Anh Tun -
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C. CH3COOH, CH2ClCOOH, CHCl2COOH. D. CH3COOH, HCOOH, (CH3)2CHCOOH. Cu 11. Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. axit fomic, vinylaxetilen, propin. B. anehit axetic, butin-1, etilen. C. anehit axetic, axetilen, butin-2. D. anehit fomic, axetilen, etilen. Cu 12. Pht biu khng ng l: A. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. B. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. C. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. Cu 13. Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l A. Z, T, Y, X. B. T, Z, Y, X. C. T, X, Y, Z. D. Y, T, X, Z. Cu 14. Cho s chuyn ho sau: C3H4O2 + NaOH X + Y X + H2SO4 long Z + T Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l: A. CH3CHO, HCOOH. B. HCHO, CH3CHO. C. HCHO, HCOOH. D. HCOONa, CH3CHO. Cu 15. Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3COOH, HCOOH, C2H5OH, CH3CHO. B. CH3CHO, C2H5OH, HCOOH, CH3COOH. C. HCOOH, CH3COOH, C2H5OH, CH3CHO. D. CH3COOH, C2H5OH, HCOOH, CH3CHO. Cu 16. Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol. B. axit aipic. C. ancol o-hiroxibenzylic.D. axit 3-hiroxipropanoic. o Cu 17. Dy gm cc cht u tc dng vi H2 (xc tc Ni, t ), to ra sn phm c kh nng phn ng vi Na l: A. CH3OC2H5, CH3CHO, C2H3COOH. B. C2H3CHO, CH3COOC2H3, C6H5COOH. C. C2H3CH2OH, CH3COCH3, C2H3COOH. D. C2H3CH2OH, CH3CHO, CH3COOH. Cu 18. Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; O = 16; Ca = 40) A. CH2=CH-COOH. B. CH3-CH2-COOH. C. CH3COOH. D. HCC-COOH. Cu 19. Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v CH3CH(OH)CHO. B. C2H5COOH v HCOOC2H5. C. HCOOC2H5 v HOCH2CH2CHO. D. HCOOC2H5 v HOCH2COCH3. Cu 20. Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng th thu c 21,6 gam Ag. Tn gi ca X l A. axit metacrylic. B. axit etanoic. C. axit acrylic. D. axit propanoic. Cu 21. Axit cacboxylic X c cng thc n gin nht l C3H5O2. Khi cho 100 ml dung dch axit X nng 0,1M phn ng ht vi dung dch NaHCO3 (d), thu c V ml kh CO2 (ktc). Gi tr ca V l A. 224. B. 112. C. 448. D. 336. Cu 22. Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c 31,1 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l A. C3H4O2 v C4H6O2. B. C2H4O2 v C3H6O2. C. C3H6O2 v C4H8O2. D. C2H4O2 v C3H4O2. Cu 23. Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H2SO4 c), un nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l A. 50,00%. B. 31,25%. C. 62,50%. D. 40,00%. Cu 24. t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH3, CH3OH thu c 2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l A. CH3COOH. B. C3H5COOH. C. C2H3COOH. D. C2H5COOH. Cu 25. Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX < MY < 82). C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO3 sinh ra kh CO2. T khi hi ca Y so vi X c gi tr l A. 1,61. B. 1,57. C. 1,91. D. 1,47. Cu 26. t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. CH3-COOH. B. HOOC-CH2-CH2-COOH.
Chu Anh Tun -
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C. HOOC-COOH. D. C2H5-COOH. Cu 27. Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l (cho H = 1, C = 12, O = 16) A. 8,10. B. 16,20. C. 6,48. D. 10,12. Cu 48. trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l (cho H = 1, C = 12, O = 16, Na = 23) A. HCOOH. B. C2H5COOH. C. CH3COOH. D. C3H7COOH. Cu 28. t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 6,72. B. 11,2. C. 4,48. D. 8,96. Cu 29. Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 8,64 gam. B. 6,84 gam. C. 6,80 gam. D. 4,90 gam. Cu 30. Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C3H4O3. B. C9H12O9. C. C6H8O6. D. C12H16O12. Cu 31. Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. CH3COOH. B. C3H7COOH. C. C2H5COOH. D. HCOOH. Cu 32. Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: A. HCOOH, HOOC-COOH. B. HCOOH, HOOC-CH2-COOH. C. HCOOH, CH3COOH. D. HCOOH, C2H5COOH. Cu 33. Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l A. 2,88 gam. B. 0,56 gam. C. 0,72 gam. D. 1,44 gam. Cu 34. Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc).t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-COOH v 42,86%. B. HOOC-CH2-COOH v 70,87%. C. HOOC-COOH v 60,00%. D. HOOC-CH2-COOH v 54,88%. Cu 35. Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l A. CH3COOH v C2H5COOH. B. HCOOH v CH3COOH. C. C3H7COOH v C4H9COOH. D. C2H5COOH v C3H7COOH. Cu 36. Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l A. axit etanoic. B. axit butanoic. C. axit metanoic. D. axit propanoic. Cu 37. Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l A. HCOOH v C3H7OH. B. CH3COOH v CH3OH. C. CH3COOH v C2H5OH.D. HCOOH v CH3OH. Cu 38. Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l A. C2H5COOH v 56,10%. B. C3H5COOH v 54,88%. C. HCOOH v 45,12%. D. C2H3COOH v 43,90%. Cu 39. t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h gia cc gi tr x, y v V l A. V = 28 55 ( x + 30 y ) . B. V = 28 95 ( x 62 y ) . C. V = 28 95 ( x + 62 y ) . D. V = 28 55 ( x 30 y ) . Cu 40. t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi z =y- x). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l A. axit acrylic. B. axit fomic. C. axit aipic. D. axit oxalic.
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Cu 41. Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong cng iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2 (ktc). Cng thc cu to ca X, Y ln lt l A. CH3-COOH v HOOC-CH2 -COOH. B. H-COOH v HOOC-COOH. C. CH3-CH2-COOH v HOOC-COOH. D. CH3-COOH v HOOC-CH2-CH2-COOH. Cu 42. Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,8. B. 0,3. C. 0,2. D. 0,6. Cu 43. Trung ho 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l A. 3,36 lt. B. 1,12 lt. C. 2,24 lt. D. 4,48 lt. Cu 44. Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu cho a mol X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l A. 25,41%. B. 74,59%. C. 46,67%. D. 40,00%.
Chuyn 12:
BI TP ESTE - LIPIT
Cu 1. Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 4. B. 5. C. 3. D. 6. Cu 2. Pht biu no sau y sai? A. Nhit si ca este thp hn hn so vi ancol c cng phn t khi. B. S nguyn t hiro trong phn t este n v a chc lun l mt s chn. C. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol. D. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn. Cu 3. S hp cht l ng phn cu to, c cng cng thc phn t C4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 4. B. 2. C. 1. D. 3. Cu 4. Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm gm 2 mui v ancol etylic. Cht X l A. CH3COOCH2CH3. B. CH3COOCH(Cl)CH3. C. CH3COOCH2CH2Cl. D. ClCH2COOC2H5. Cu 5. Cng thc ca triolein l A. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5. B. (CH3[CH2]14COO)3C3H5. C. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5. D. (CH3[CH2]16COO)3C3H5. Cu 6. Mnh khng ng l: A. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. B. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. C. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. D. CH3CH2COOCH=CH2 c th trng hp to polime. Cu 7. Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca 13te l A. CH3COO-CH=CH2. B. HCOO-C(CH3)=CH2. C. CH2=CH-COO-CH3. D. HCOO-CH=CH-CH3. Cu 8. Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 4. B. 5. C. 6. D. 3. Cu 9. Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 4. B. 5. C. 3. D. 2. Cu 10. Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. etyl axetat. B. ru etylic. C. ru metylic. D. axit fomic. Cu 11. Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l A. 4. B. 5. C. 2. D. 3. Cu 12. Pht biu ng l: A. Khi thy phn cht bo lun thu c C2H4(OH)2.
Chu Anh Tun -
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B. Phn ng gia axit v ru khi c H2SO4c l phn ng mt chiu. C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ru (ancol). D. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. Cu 13. Pht biu khng ng l: A. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. B. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). + C. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N -CH2-COO . D. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. Cu 14. S ng phn este ng vi cng thc phn t C4H8O2 l A. 5. B. 2. C. 4. D. 6.
+ H 3O + KCN X to Cu 15. Cho s chuyn ha: CH3CH2Cl Y.
+
Cng thc cu to ca X, Y ln lt l: A. CH3CH2CN, CH3CH2COOH. C. CH3CH2CN, CH3CH2CHO.

+ H , du ( Ni ,t o )
B. CH3CH2NH2, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4.

o
+ NaOHdu ,t + HCl 2 X Y Z. Cu 16. Cho s chuyn ho: Triolein Tn ca Z l A. axit linoleic. B. axit oleic. C. axit panmitic. D. axit stearic. Cu 17. Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l A. 3. B. 1. C. 2. D. 4.
X Cu 18. Cho s chuyn ho sau: C2H2 Y t , xt , p Cao su buna-N. Cc cht X, Y, Z ln lt l: A. vinylaxetilen; buta-1,3-ien; stiren. B. axetanehit; ancol etylic; buta-1,3-ien. C. vinylaxetilen; buta-1,3-ien; acrilonitrin. D. benzen; xiclohexan; amoniac. Cu 19. Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-COOC3H7. B.CH3OCO-CH2-CH2-COOC2H5 C. CH3OCO-CH2-COOC2 H5. D. C2H5OCO-COOCH3. Cu 20. Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phn ng c vi dung dch NaOH nhng khng c phn ng trng bc l A. 9. B. 8. C. 5. D. 4. Cu 21. Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 5. B. 2. C. 3. D. 4. Cu 22. Pht biu no sau y ng? A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ho hc, ch cn dng thuc th l nc brom. B. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t OH trong nhm COOH ca axit v H trong nhm OH ca ancol. C. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. D. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. Cu 23. Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. Dung dch NaOH (un nng). B. Cu(OH)2 ( iu kin thng). C. H2O (xc tc H2SO4 long, un nng). D. H2 (xc tc Ni, un nng). Cu 24. Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH3. B. CH3COOCH=CH-CH3.C. HCOOCH=CH2. D. CH3COOCH=CH2. Cu 25. Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O =16) A. 4. B. 3. C. 5. D. 2. Cu 26. trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l (Cho H = 1; O = 16; K = 39) A. 6,0. B. 5,5. C. 7,2. D. 4,8. Cu 27. un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16)
xt ,t o
+ H 2 ,t Pd , PdCO3
+Z o
Chu Anh Tun -
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A. 62,5%. B. 75%. C. 50%. D. 55%. Cu 28. Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l (Cho H = 1; C = 12; O =16; Na = 23) A. etyl propionat. B. isopropyl axetat. C. etyl axetat. D. metyl propionat. Cu 29. S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng c vi dung dch NaOH l A. 6. B. 4. C. 3. D. 5. Este n chc X c t khi hi so vi CH l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH Cu 30. 4 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH3-CH2-COO-CH=CH2. B. CH3 -COO-CH=CH-CH3. C. CH2=CH-COO-CH2-CH3. D. CH2=CH-CH2-COO-CH3. Cu 31. Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh phn ng: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l A. 58 vC. B. 82 vC. C. 44 vC. D. 118 vC. Cu 32. un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l A. 8,8 gam. B. 4,4 gam. C. 5,2 gam. D. 6,0 gam. Cu 33. Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l: A. H-COO-CH3, CH3-COOH. B. CH3-COOH, CH3-COO-CH3. C. CH3-COOH, H-COO-CH3. D. (CH3)2CH-OH, H-COO-CH3. Cu 34. Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ru (ancol). Cho ton b lng ru thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X gm A. hai este. B. mt este v mt ru. C. mt axit v mt este. D. mt axit v mt ru. Cu 35. X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 200 ml. B. 150 ml. C. 400 ml. D. 300 ml. Cu 36. Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CHCH2COOCH3. B. CH2=CHCOOC2H5. C. CH3COOCH=CHCH3. D. C2H5COOCH=CH2. Cu 37. Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l A. mt este v mt axit. B. hai este. C. mt este v mt ancol. D. hai axit. Cu 38. trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dung dch cha a gam NaOH. Gi tr ca a l A. 0,200. B. 0,075. C. 0,150. D. 0,280. Cu 39. Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l A. HCOOCH3 v 6,7. B. CH3COOCH3 v 6,7. C. HCOOC2H5 v 9,5. D. (HCOO)2C2H4v 6,6. Cu 40. Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l A. CH3COOCH=CH2. B. C2H5COOCH3. C. CH3COOC2H5. D. CH2=CHCOOCH3. Cu 41. phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (MX < MY) cn va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO2 (ktc) v 5,4 gam H2O. Cng thc ca Y l A. CH3COOC2H5. B. CH2=CHCOOCH3. C. CH3COOCH3. D. C2H5COOC2H5. Cu 42. x phng ho hon ton 52,8 gam hn hp hai este no, n chc, mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. C2H5COOC2H5v C3H7COOCH3. B. C2H5COOCH3 v CH3COOC2H5. C. CH3COOC2H5 v HCOOC3H7. D. HCOOC4H9 v CH3COOC3H7.
Chu Anh Tun -
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Cu 43. Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH)2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l A. 53,33%. B. 43,24%. C. 37,21%. D. 36,36%. Cu 44. Hp cht hu c X c cng thc phn t l C4H8O3. X c kh nng tham gia phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thy phn ca X trong mi trng kim c kh nng ho tan Cu(OH)2 to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l A. CH3COOCH2CH2OH. B. HCOOCH2CH(OH)CH3. HCOOCH CH CH OH. C. D. CH3CH(OH)CH(OH)CHO. 2 2 2 Cu 45. Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 2,925. B. 2,412. C. 0,342. D. 0,456. Cu 46. Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l (cho H = 1, C = 12, O = 16) A. C17H31COOH v C17H33COOH. B. C17H33COOH v C15H31COOH. C. C17H33COOH v C17H35COOH. D. C15H31COOH v C17H35COOH. Cu 47. X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23) A. 3,28 gam. B. 10,4 gam. C. 8,56 gam. D. 8,2 gam. Cu 48. Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C = 12, N = 14, O = 16) A. C2H5COOCH3 v HCOOCH(CH3)2. B. HCOOCH2CH2CH3 v CH3COOC2H5. C. HCOOC2H5 v CH3COOCH3. D. C2H3COOC2H5 v C2H5COOC2H3. Cu 49. Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol o cn cho phn ng chy) 139,9 C, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l A. C4H8O2. B. C2H4O2. C. C3H6O2. D. CH2O2. Cu 50. X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1,C =12, O = 16, Na = 23) A. HCOOCH(CH3)2. B. C2H5COOCH3. C. CH3COOC2H5. D. HCOOCH2CH2CH3. Cu 51. Este X c cc c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. o B. un Z vi dung dch H2SO4c 170 C thu c anken. C. Cht Y tan v hn trong nc. D. Cht X thuc loi este no, n chc. Cu 52. Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3COO-(CH2)2-COOC2H5. B. CH3OOC-CH2-COO-C3H7. C. CH3OOC-(CH2)2-COOC2H5. D. CH3COO-(CH2)2-OOCC2H5. Cu 53. Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl axetat. B. n-propyl axetat. C. etyl axetat. D. metyl fomiat. Cu 54. X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 17,80 gam. B. 18,24 gam. C. 18,38 gam. D. 16,68 gam. Cu 55. Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. HCOOCH=CHCH2CH3. B. CH3COOC(CH3)=CH2. C. HCOOC(CH3)=CHCH3. D. HCOOCH2CH=CHCH3. Cu 56. Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A. 2. B. 5. C. 4. D. 3.
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Cu 57. X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. HCOOCH3 v HCOOC2H5. B. CH3COOC2H5 v CH3COOC3H7. C. C2H5COOCH3 v C2H5COOC2H5. D. CH3COOCH3 v CH3COOC2H5. Cu 58. X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3bng dung dch NaOH, o thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140 C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 18,00. B. 16,20. C. 4,05. D. 8,10. Cu 59. X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. HCOONa, CHC-COONa v CH3-CH2-COONa. C. CH3-COONa, HCOONa v CH3-CH=CH-COONa. D. CH2=CH-COONa, HCOONa v CHC-COONa. Cu 60. Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOC2H5. B. HCOOH v HCOOC3H7. C. C2H5COOH v C2H5COOCH3. D. CH3COOH v CH3COOC2H5. Cu 61. Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 29,75. B. 27,75. C. 26,25. D. 24,25. Cu 62. Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C2H4O2 v C5H10O2. B. C2H4O2 v C3H6O2. C. C3H4O2 v C4H6O2. D. C3H6O2 v C4H8O2. Cu 63. Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2(cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. HOOC-CHO. B. HCOOC2H5. C. CH3COOCH3. D. O=CH-CH2-CH2OH. Cu 64. t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin).Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 6,66. B. 8,88. C. 10,56. D. 7,20. Cu 65. Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. HCOOH v CH3COOH. B. CH3COOH v C2H5COOH. C. HCOOH v C2H5COOH. D. C2H5COOH v C3H7COOH. Cu 66. Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,005. B. 0,010. C. 0,020. D. 0,015. Cu 67. Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l A. metyl axetat. B. metyl propionat. C. etyl axetat. D. vinyl axetat. Cu 68. Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (oCH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,24. B. 0,96. C. 0,72. D. 0,48. Cu 69. t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l A. 4. B. 6. C. 5. D. 2. Cu 70. t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Tng 7,92 gam. B. Tng 2,70 gam. C. Gim 7,74 gam. D. Gim 7,38 gam. Cu 71. Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 15,5. B. 17,5. C. 14,5. D. 16,5.
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Cu 72. Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l A. 31 gam. B. 30 gam. C. 32,36 gam. D. 31,45 gam. Cu 73.Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l A. 27,92%. B. 72,08%. C. 75%. D. 25%. Cu 74. Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l A. 2. B. 5. C. 4. D. 6.
Chuyn 13:
BI TP CACBONHIRAT
Cu 1.Cacbohirat nht thit phi cha nhm chc ca A. ancol. B. amin. C. xeton. D. anehit. Cu 2.Cp cht no sau y khng phi l ng phn ca nhau? A. 2-metylpropan-1-ol v butan-2-ol. B. Saccaroz v xenluloz. C. Ancol etylic v imetyl ete. D. Glucoz v fructoz. Cu 3.Cu to mch h ca phn t glucoz khc cu to mch h ca phn t fructoz l: A. phn t glucoz c mt nhm anehit B. phn t glucoz c 4 nhm OH C. phn t glucoz c cu to mch nhnh D. phn t glucoz c nhm xeton Cu 4.Cht no sau y khng cho kt ta trng bc khi tc dng vi dung dch AgNO3/NH3 ? A. mantozo B. fructozo C. vinyl axetat D. axetilen Cu 5.Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan Cu(OH)2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l A. mantoz. B. saccaroz. C. xenluloz. D. glucoz. Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 Cu 6. l A. 3. B. 2. C. 4. D. 1. Cu 7.Cho cc cht: saccaroz, glucoz, fructoz, etyl fomat, axit fomic v anehit axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH)2 iu kin thng l A. 5. B. 4. C. 2. D. 3. Cu 8.Cho cc chuyn ho sau: t o , xt Ni ,t o X + H2O Y + H2 Y Sobitol
t , xt Y + 2AgNO3 + 3NH3 + H2O Amoni gluconat + 2Ag + 2NH4NO3 o diepluc , as t , xt Y Z + H2O X + G E+Z X, Y v Z ln lt l: A. tinh bt, glucoz v kh cacbonic. B. tinh bt, glucoz v ancol etylic. C. xenluloz, fructoz v kh cacbonic. D. xenluloz, glucoz v kh cacbon oxit. Cu 9.Cho cc dung dch ring bit sau : Glucoz, tinh bt, glixerin , phenol , andehit axetic , benzen.Thuc th dng nhn bit dung dch l ? B. Na, Qu tm , AgNO3/NH3 A. Na, Qu tm , Cu(OH)2 C. Na, Qu tm , nc brom D. Cu(OH)2, dung dch T2 , nc brom Cu 10.Cho cc ho cht: Cu(OH)2 (1) ; dung dch AgNO3/NH3 (2) ; H2/Ni, to (3) ; H2SO4 long, nng (4). Mantoz c th tc dng vi cc ho cht: A. (1) v (2) B. (2) v (3) C. (3) v (4) D. (1),(2) v (4) Cu 11.Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit. (c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam. (d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l A. 6. B. 5. C. 4. D. 3. Cu 12.Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz.
o
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(b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau. (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3. (d) Trong dung dch, glucoz v fructoz u ho tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (e) Trong dung dch, fructoz tn ti ch yu dng mch h. (g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ). S pht biu ng l A. 3. B. 5. C. 2. D. 4. Cu 13.Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 3. B. 4. C. 6. D. 5. Cu 14.Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S cht trong dy tham gia phn ng trng gng l A. 2. B. 3. C. 4. D. 5. Cu 15.Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (1), (3), (4) v (6). B. (2), (3), (4) v (5). C. (3), (4), (5) v (6). D. (1), (2), (3) v (4). Cu 16.C mt s nhn xt v cacbohirat nh sau: (1) Saccaroz, tinh bt v xenluloz u c th b thu phn. (2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng tham gia phn ng trng bc. (3) Tinh bt v xenluloz l ng phn cu to ca nhau. (4) Phn t xenluloz c cu to bi nhiu gc -glucoz. (5) Thu phn tinh bt trong mi trng axit sinh ra fructoz. Trong cc nhn xt trn, s nhn xt ng l A. 3. B. 4. C. 2. D. 5. Cu 17.c im khc nhau gia glucoz v fructoz l : A.S nhm chc -OH B.T l nguyn t cc nguyn t C.Thnh phn nguyn t D.V tr nhm cacbonyl Cu 18.Dy gm cc dung dch u tham gia phn ng trng bc l: A. Glucoz, glixerol, mantoz, axit fomic. B. Glucoz, fructoz, mantoz, saccaroz. C. Fructoz, mantoz, glixerol, anehit axetic. D. Glucoz, mantoz, axit fomic, anehit axetic. Cu 19. chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. Cu(OH)2 trong NaOH, un nng. B. kim loi Na. C. Cu(OH)2 nhit thng. D. AgNO3 trong dung dch NH3, un nng. Cu 20.Dng nhng ha cht no sau y c th nhn bit c bn cht lng khng mu l glixerol, ancol etylic, dung dch glucoz v anilin ? A. Na v dung dch AgNO3 / NH3 B. Dung dch AgNO3 / NH3 v Cu(OH)2 C. Dung dch Br2 v Cu(OH)2 D. Na v dung dch Br2 Cu 21.ng khng c tnh kh l ng: B. glucoz C. fructoz D. saccaroz A. mantoz Cu 22.Fructoz khng phn ng vi cht no sau y ? A. dd Br2 B. H2/Ni, t0C C. Cu(OH)2/NaOH D. dd AgNO3 / NH3 Cu 23.Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. saccaroz. B. mantoz. C. xenluloz. D. tinh bt. Cu 24.Mt phn t saccaroz c A. hai gc -glucoz. B. mt gc -glucoz v mt gc -fructoz. C. mt gc -glucoz v mt gc -fructoz. D. mt gc -glucoz v mt gc -fructoz. Cu 25.Nhm cc cht u tham gia phn ng trng bc v phn ng kh Cu(OH)2 thnh Cu2O l A. glucoz v saccaroz. B. glucoz v mantoz. C. glucoz v xenluloz. D. saccaroz v mantoz. Cu 26.Pht biu khng ng l + o A. Sn phm thy phn xenluloz (xc tc H , t ) c th tham gia phn ng trng gng. B. Dung dch fructoz ho tan c Cu(OH)2. + o C. Thy phn (xc tc H , t ) saccaroz cng nh mantoz u cho cng mt monosaccarit. D. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O. Cu 27.Pht biu no sau y khng ng? A. dng mch h, glucoz c 5 nhm OH k nhau. B. Glucoz tn ti dng mch h v dng mch vng. C. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH. D. Glucoz tc dng c vi nc brom. Cu 28.Pht biu no sau y l ng?
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A. Amilopectin c cu trc mch phn nhnh. B. Glucoz b kh bi dung dch AgNO3 trong NH3. C. Xenluloz c cu trc mch phn nhnh. D. Saccaroz lm mt mu nc brom. Cu 29.Thuc th ti thiu c th dng nhn bit hexan, glixerin v dung dch glucoz l: A. Na B. ddAgNO3/NH3 C. Dung dch HCl D. Cu(OH)2. Cu 30.Thu phn hon ton tinh bt trong dung dch axit v c long, thu c cht hu c X. Cho X phn ng o vi kh H2 (xc tc Ni, t ), thu c cht hu c Y. Cc cht X, Y ln lt l: A. glucoz, sobitol. B. glucoz, etanol. C. glucoz, saccaroz. D. glucoz, fructoz. Cu 31.Tinh bt v xenluloz khc nhau ch : A. V thnh phn nguyn t B. tan trong nc C. c trng ca phn ng thy phn D. V cu trc mch phn t Cu 32.Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng A. ho tan Cu(OH)2. B. trng gng. C. thy phn. D. trng ngng. Cu 33.Tnh cht c trng ca saccaroz l: 1. tham gia phn ng hiro ho . 2. cht rn kt tinh, khng mu. 3. khi thu phn to ra glucoz v fructoz. 4. tham gia phn ng trng gng. 5. phn ng vi ng(II) hiroxit. Nhng tnh cht no ng? A. 3,4,5. B. 1,2,3,5. C. 1,2,3,4. D. 2,3,5. Cu 34.Trong cng nghip sn xut gng soi v rut phch ngi ta s dng: A. dung dch sacaroz tc dng vi dung dch AgNO3 trong NH3 B. axetilen tc dng vi dung dch AgNO3 trong NH3. C. andehit fomic tc dng vi dung dch AgNO3 trong NH3 D. dung dch glucoz tc dng vi dung dch AgNO3 trong NH3. Cu 35.T glucozo bng mt phng trnh phn ng trc tip c th iu ch c : A. CH3-CH(OH)-COOH B. C3H7OH C. HCOOH D. CH3COOH Cu 36.Cho 360 gam glucoz ln men thnh ancol etylic (gi s ch c phn ng to thnh ancoletylic). Cho tt c kh CO2 hp th vo dung dch NaOH th thu c 212 gam Na2CO3 v 84 gam NaHCO3. Hiu sut ca phn ng ln men ancol l: A. 50% B. 62,5% C. 75% D. 80% Cu 37.Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 (hoc Ag2O) trong dung dch NH3thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch glucoz dng l (Cho H = 1; C = 12; O = 16; Ag = 108) A. 0,20M. B. 0,02M. C. 0,01M. D. 0,10M. Cu 38.Cho m gam hn hp gm glucoz v fructoz tc dng vi lng d AgNO3/ NH3 to ra 6,48 g Ag. Cng m gam hn hp ny tc dng ht vi 1,20g Br2 trong dung dch. Phn trm s mol ca glucoz trong hn hp l A. 25% B. 50% C. 12,5% D. 40% Cu 39.Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l (cho H = 1, C = 12, O = 16, Ca = 40) A. 550. B. 650. C. 750. D. 810. Cu 40.Ha tan m gam hn hp saccaroz v mantoz vo nc thu c dung dch X. Chia X thnh hai phn bng nhau. Phn th nht tc dng vi lng d dung dch AgNO3 trong NH3, thu c 10,8 gam kt ta. Phn th hai un hi lu trong mi trng axit (HCl long) thu c dung dch Y. Dung dch Y phn ng va ht vi 40 gam Br2 trong dung dch. Gi thit cc phn ng u xy ra hon ton. Khi lng m bng: A. 68,4 gam B. 273,6 gam C. 205,2 gam D. 136,8 gam Cu 41. Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 4,5 kg. B. 5,4 kg. C. 5,0 kg. D. 6,0 kg. Cu 42.Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to thnh ancol etylic l A. 54%. B. 60%. C. 40%. D. 80%. Cu 43.Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l A. 58. B. 48. C. 60. D. 30. Cu 44.Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l A. 30,0. B. 15,0. C. 20,0. D. 13,5. Cu 45.Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 2,25 gam. B. 1,80 gam. C. 1,44 gam. D. 1,82 gam. Cu 46.Ngi ta iu ch C2H5OH t xenluloz vi hiu sut ca cc qu trnh l 60% th khi lng C2H5OH thu
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c t 32,4 gam xenluloz l (H = 1, C = 12, O = 16) A. 30,67 gam B. 18,4 gam C. 12,04 gam D. 11,04 gam Cu 47.Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg xenluloz trinitrat (hiu sut 80%) l A. 42,86 lt. B. 42,34 lt. C. 53,57 lt. D. 34,29 lt. Cu 48.Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %) A. 49 lt. B. 81 lt. C. 55 lt. D. 70 lt. Th tch dung dch HNO 96% (D=1,52 g/ml) cn dng tc dng vi lng d xenluloz to 297 gam Cu 49. 3 xenluloz trinitrat l: A. 43,17 ml B. 150 ml C. 143,90 ml D. 129,52 ml Cu 50.Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c dung dch X. Cho ton b dung dch X phn ng ht vi lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 21,60. B. 2,16. C. 4,32. D. 43,20. Cu 51.Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A. 0,06 mol. B. 0,095 mol. C. 0,090 mol. D. 0,12 mol. Cu 52.Tnh khi lng mt loi go c t l tinh bt l 80% cn dng khi ln men (hiu sut ln men l 50%) thu c 460 ml ancol 50o (khi lng ring ca etylic 0,80g/ml). A. 430 g B. 520g. C. 760g D. 810g Cu 53.Trong 1 kg go cha 81% tinh bt c bao nhiu mt xch? A. 4.1021. B. 3.1023. C. 3.1024. D. 3.1021. Cu 54.T 1 tn khoai c cha 20% tinh bt, sn xut c 100 lt ancol etylic nguyn cht c d = 0,8 g/ml. Hiu sut ca qu trnh sn xut l A. 70,4% B. 78,2% C. 100% D. Khng xc nh c Cu 55.T 100kg go cha 81% tinh bt c th iu ch c bao nhiu lt ancol nguyn cht (d=0,8g/ml). Bit hiu sut ca c qu trnh l 75%. A. 57,5 lt B. 41,421 lt C. 42,24 lt D. 43,125 lt Cu 56.T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh theo xenluloz l 90%). Gi tr ca m l A. 26,73. B. 33,00. C. 29,70. D. 25,46. Cu 57.T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 20%. B. 10%. C. 80%. D. 90%. Cu 58.Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 1,10 tn. B. 2,97 tn. C. 3,67 tn. D. 2,20 tn. Cu 59. Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l (cho H = 1, C =12, N = 14, O = 16) A. 42 kg. B. 21 kg. C. 30 kg. D. 10 kg. Cu 60.T nguyn liu g cha 50% xenluloz, ngi ta iu ch c ancol etylic vi hiu sut 81%. Tnh khi lng g cn thit iu ch c 1000 lt cn 92 (bit ancol nguyn cht c D = 0,8g/ml). A. 3115kg. B. 3200kg. C. 3810kg. D. 4000kg. Cu 61.Xenluloz trinitrat l cht d chy v n mnh, c iu ch t xenluloz v axit nitric. Th tch axit nitric 99,67% c d = 1,52g/ml cn sn xut 59,4 kg xenluloz trinitrat nu hiu sut t 90% l ( C = 12, N = 14, O = 16, H = 1) : A. 27,72 lt B. 32,52 lt C. 26,52 lt D. 11,2 lt Cu 62.T mt loi bt g cha 60% xenluloz c dng lm nguyn liu sn xut ancol etylic. Nu dng 1 tn bt g trn c th iu ch c bao nhiu lt ancol 700. bit hiu sut ca qu trnh iu ch l 70%, khi lng ring ca ancol nguyn cht l 0,8 g/ml. A. 450 lt B. 420 lt C. 426 lt D. 456 lt Cu 63.T x tn mn ca cha 5O% xenluloz sn xut c O,5 tn ancol etylic ( bit hiu sut c qu trnh l t 7O% ) gi tr ca x l ?( C=12, H= 1, O =16) A.1 ,6O7 tn B.1 tn C.3,214 tn D.2,516 tn
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Chuyn 14:
BI TP AMIN - AMINOAXIT
Cu 1. Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau: A. lng trng trng, glucoz, fructoz, glixerol. B. glucoz, lng trng trng, glixerol, ancol etylic. C. glucoz, mantoz, glixerol, anehit axetic. D. saccaroz, glixerol, anehit axetic, ancol etylic. Cu 2. Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 5. B. 2. C. 4. D. 3. Cu 3. Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. amoni acrylat. B. axit -aminopropionic. C. axit -aminopropionic. D. metyl aminoaxetat. o Cu 4. Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (t ) o v vi dung dch HCl (t ). S phn ng xy ra l A. 5. B. 3. C. 6. D. 4. Cu 5. Cht X c cng thc phn t C4H9O2N. Bit: X + NaOH Y + CH4O Y + HCl (d) Z + NaCl. Cng thc cu to ca X v Z ln lt l A. H2NCH2COOC2H5 v ClH3NCH2COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. C. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. D. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. Cu 6. S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 4. B. 3. C. 5. D. 2. Cu 7. Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 3. B. 1. C. 2. D. 4. Cu 8. Dung dch no sau y lm qu tm chuyn mu xanh? A. Glyxin. B. Phenylamoni clorua. C. Anilin. D. Etylamin. Cu 9. S amin thm bc mt ng vi cng thc phn t C7H9N l A. 2. B. 3. C. 4. D. 5. Cu 10. ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH, va phn ng c vi dung dch HCl? A. 2. B. 1. C. 4. D. 3. Cu 11. Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 3. B. 5. C. 2. D. 4. Cu 12. Hai cht no sau y u tc dng c vi dung dch NaOH long? A. ClH3NCH2COOC2H5 v H2NCH2COOC2H5. B. CH3NH3Cl v H2NCH2COONa. C. CH3NH3Cl v CH3NH2. D. CH3NH2 v H2NCH2COOH. Cu 13. Pht biu no sau y ng? A. Amino axit l hp cht c tnh lng tnh. B. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho hp cht mu tm. C. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit. D. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit. Cu 14. Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. Y, Z, T. C. X, Y, Z. D. X, Y, T. Cu 15. Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun cha chc hiroxyl. B. protit lun l cht hu c no. C. protit lun cha nit. D. protit c khi lng phn t ln hn. Cu 16. Cho s phn ng:
+ CuO 3 + HNO3 X Z. NH3 Y 1:1 to Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: A. C2H5OH, HCHO. B. CH3OH, HCOOH. C. C2H5OH, CH3CHO. D. CH3OH, HCHO. + CH I
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Cu 17. C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH -CH -CH(NH )-COOH, ClH3N-CH -COOH, HOOC-CH -CH -CH(NH2)-COOH, H2N-CH -COONa. S lng cc dung dch c pH < 7 l A. 4. B. 5. C. 3. D. 2. Cu 18. Cht phn ng vi dung dch FeCl3 cho kt ta l A. CH3OH. B. CH3COOCH3. C. CH3COOH. D. CH3NH2. Cu 19. un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: + + A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N -CH2-COOHCl , H3N -CH2-CH2-COOHCl . + + C. H2N-CH2-COOH, H2N-CH(CH3)-COOH. D. H3N -CH2-COOHCl , H3N -CH(CH3)-COOHCl . Cu 20. Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaCl. B. dung dch HCl. C. Cu(OH)2 trong mi trng kim. D. dung dch NaOH. Cu 21. Pht biu no sau y l ng? A. Benzen lm mt mu nc brom nhit thng. B. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. C. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. D. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. Cu 22. S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3. B. 4 C. 2. D. 1. Cu 23. Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v CH3NH2. B. CH3OH v NH3. C. C2H5OH v N2. D. CH3NH2 v NH3. Cu 24. Pht biu ng l: A. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit. B. Axit nucleic l polieste ca axit photphoric v glucoz. C. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz. D. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m. Cu 25. C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 3. B. 9. C. 4. D. 6. Cu 26. Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. axit 2-aminopropionic v amoni acrylat. B. axit 2-aminopropionic v axit 3-aminopropionic. C. vinylamoni fomat v amoni acrylat. D. amoni acrylat v axit 2-aminopropionic. Cu 27. Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-AlaVal nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Ala-Val-Val-Phe. B. Gly-Phe-Gly-Ala-Val. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly. Cu 28. Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch lysin. B. Dung dch valin. C. Dung dch alanin. D. Dung dch glyxin. Cu 29. Khi ni v peptit v protein, pht biu no sau y l sai? A. Thy phn hon ton protein n gin thu c cc -amino axit. B. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. C. Tt c cc protein u tan trong nc to thnh dung dch keo. D. Protein c phn ng mu biure vi Cu(OH)2. Cu 30. S ng phn amino axit c cng thc phn t C3H7O2N l A. 3. B. 2. C. 1. D. 4. Cu 31. Ancol v amin no sau y cng bc? A. (C6H5)2NH v C6H5CH2OH. B. (CH3)3COH v (CH3)3CNH2. C. C6H5NHCH3 v C6H5CH(OH)CH3. D. (CH3)2CHOH v (CH3)2CHNH2. Cu 32. Pht biu khng ng l: A. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu. B. ipeptit glyxylalanin (mch h) c 2 lin kt peptit.
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C. Etylamin tc dng vi axit nitr nhit thng to ra etanol. D. Metylamin tan trong nc cho dung dch c mi trng baz. Cu 33. trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C2H7N. B. C3H5N. C. CH5N. D. C3H7N Cu 34. Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; N = 14; O =16; Na = 23) A. CH2=CHCOONH4. B. H2NCH2COO-CH3. C. H2NCOO-CH2CH3. D. H2NC2H4COOH. Cu 35. Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NC2H4COOH. C. H2NCH2COOH. D. H2NC4H8COOH. Cu 36. Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 2. C. 3. D. 4. Cu 37. Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH3CH2CH3. B. HCOONH2(CH3)2. C. CH3COONH3CH3. D. CH3CH2COONH4. Cu 38.Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. C3H7NH2 v C4H9NH2. B. CH3NH2 v C2H5NH2. C. C2H5NH2 v C3H7NH2. D. CH3NH2 v (CH3)3N. Cu 39. Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v khi lng. Cho X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c xeton Z. Pht biu no sau y ng? A. Tn thay th ca Y l propan-2-ol. B. Phn t X c mch cacbon khng phn nhnh. Trong phn t X c mt lin kt . C. D. Tch nc Y ch thu c mt anken duy nht. Cu 40. Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l A. valin. B. phenylalanin. C. glyxin. D. alanin. Cu 41. Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 8,9 gam. B. 14,3 gam. C. 15,7 gam. D. 16,5 gam. Cu 42. t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. H2N-CH2-COO-CH3. B. H2N-CH2-COO-C3H7. C. H2N-CH2-CH2-COOH. D. H2N-CH2-COO-C2H5. Cu 43. Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) A. C3H7N. B. C4H9N. C. C2H7N. D. C3H9N. Cu 44. -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) A. CH3CH2CH(NH2)COOH. B. CH3CH(NH2)COOH. C. H2NCH2CH2COOH. D. H2NCH2COOH. + Cu 45. Mui C6H5N2 Cl (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong + o dung dch HCl nhit thp (0-5 C). iu ch c 14,05 gam C6H5N2 Cl (vi hiu sut 100%), lng C6H5NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,3 mol. B. 0,1 mol v 0,1 mol. C. 0,1 mol v 0,4 mol. D. 0,1 mol v 0,2 mol.
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Cu 46. Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2COOCH3. B. HCOOH3NCH=CH2. C. CH2=CHCOONH4. D. H2NCH2CH2COOH. Cu 47. Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 45. B. 46. C. 68. D. 85. Cu 48. Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C4H8O4N2. B. C5H11O2N. C. C5H9O4N. D. C4H10O2N2. Cu 49. Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 8,2. C. 9,6. D. 9,4. Cu 50. Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 8. B. 7. C. 5. D. 4.
+ H 2 SO4 , dac to Cu 51. Ngi ta iu ch anilin bng s sau: Benzen Nitro benzen Anilin. Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 111,6 gam. B. 186,0 gam. C. 93,0 gam. D. 55,8 gam. Cu 52. Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H6COOH. C. (H2N)2C3H5COOH. D. H2NC3H5(COOH)2. Cu 53.t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH3-CH2-NH-CH3. B. CH2=CH-CH2-NH2. C. CH2=CH-NH-CH3. D. CH3-CH2-CH2-NH2. Cu 54.Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,55. B. 0,70. C. 0,65. D. 0,50. Cu 55. Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,5. B. 7 v 1,5. C. 8 v 1,0. D. 7 v 1,0. Cu 56. t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,1. B. 0,3. C. 0,2. D. 0,4. Cu 57. ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 30. B. 45. C. 120. D. 60. Cu 58. Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. CH3CH2CH2NH2. B. H2N-(CH2)4-NH2. C. H2NCH2CH2NH2. D. H2NCH2CH2CH2NH2. Cu 59. Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 165,6. B. 123,8. C. 112,2. D. 171,0. Cu 60. Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 2. B. 1. C. 4. D. 3. + HNO3 , dac Fe+HCl
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Cu 61. Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 111,74. B. 66,44. C. 81,54. D. 90,6. Cu 62. Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/10 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l A. 16,30 gam. B. 8,15 gam. C. 7,09 gam. D. 7,82 gam. Cu 63. Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 4,45. B. 3,56. C. 2,67. D. 5,34.
Chuyn 15:
BI TP POLIME
Cu 1. Cc cht u khng b thu phn trong dung dch H2SO4 long nng l: A. nilon-6,6; poli(etylen-terephtalat); polistiren. B. t capron; nilon-6,6; polietilen. C. poli(vinyl axetat); polietilen; cao su buna. D. polietilen; cao su buna; polistiren. Cu 2. Cc loi t c ngun gc xenluloz A. Si bng, t tm, t nilon 6,6 B. T tm, len, t visco C. Si bng, t visco, t capron D. T axetat, si bng, t visco Cu 3. Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp l A. 4. B. 5. C. 2. D. 3. Cu 4. Cho cc polime: (1) polietilen, (2) poli(metyl metacrylat), (3) polibutaien, (4) polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch axit v dung dch kim l: A. (2), (3), (6). B. (1), (2), (5). C. (2), (5), (6). D. (1), (4), (5). Cu 5. Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 3. B. 1. C. 4. D. 2. Cu 6. Cho polime [- CO - (CH2)4 - CO - NH - (CH2)6 - NH - ] l poliamit, t poliamit ny ngi ta sn xut ra t poliamit no sau y: A. t nilon B. t capron C. t enang D. t visco Cu 7. Cho s phn ng: + HCN CH CH X; t / hop X polimeY; dongtrunghop X + CH2=CH-CH=CH2 polime Z. Y v Z ln lt dng ch to vt liu polime no sau y? A. T capron v cao su buna. B. T nilon-6,6 v cao su cloropren. C. T olon v cao su buna-N. D. T nitron v cao su buna-S. Cu 8. Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. buta-1,3-ien; cumen; etilen; trans-but-2-en. B. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. C. stiren; clobenzen; isopren; but-1-en. D. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. Cu 9. Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=CH-CH=CH2, CH3-CH=CH2. B. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, lu hunh. D. CH2=CH-CH=CH2, C6H5CH=CH2. Cu 10. tng hp polime, ngi ta khng th dng A. Phn ng trng ngng. B. Phn ng trng hp. C. Phn ng ng trng hp. D. Phn ng x phng ha. Cu 11. Hp cht u v cc hp cht trung gian trong qu trnh iu ch ra cao su buna (1) l: etilen (2), metan (3), ancol etylic (4), ivinyl (5), axetilen (6). Hy sp xp cc cht theo ng th t xy ra trong qu trnh iu ch. A. 3-6-2-4-5-1 B. 6-4-2-5-3-1 C. 2-6-3-4-5-1 D. 4-6-3-2-5-1 Cu 12.Khi un nng phenol vi fomanehit ly d to ra polime c cu to mng khng gian, loi polime ny l thnh phn chnh ca: A. nha PVC B. nha PE C. nha bakelit D. thu tinh hu c
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Cu 13. Nhn nh no sau y ng ? A. Khng tn ti este HCOOCH=CH2 v ancol CH2=CH-OH khng tn ti B. C2H5Cl l dn xut halogen ch khng phi este C. Khng th to este phenyl axetat t phn ng trc tip gia phenol v axit axetic D. thu c polivinyl ancol ch cn thc hin phn ng trng hp vinyl ancol. Cu 14. Nilon-6,6 l mt loi A. t poliamit. B. t visco. C. poli este. D. t axetat. Cu 15. Pht biu ng l: A. Cao su thin nhin l sn phm trng hp ca isopren. B. Tnh baz ca anilin mnh hn ca amoniac. C. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp. D. Tnh axit ca phenol yu hn ca ru (ancol). Cu 16. Pht biu no sau y khng ng? A. iu ch x phng bng phn ng gia cht bo vi NaOH un nng. B. iu ch cao su buna-S bng phn ng un nng Buta - 1,3 - ien vi lu hunh. C. T tm, bng, len l polime thin nhin. D. Du thc vt lm nht mu dung dch brom. Cu 17. Pht biu no sau y l ng? A. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. B. Trng hp stiren thu c poli(phenol-fomanehit). C. T visco l t tng hp. D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. Cu 18. Phenol khng phi l nguyn liu iu ch A. nha bakelit B. axit picric C. 2,4-D v 2,4,5-T D. thy tinh hu c Cu 19. Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l A. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. B. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. C. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. D. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. Cu 20. Polime c cu trc mng khng gian (mng li) l A. PVC. B. PE. C. nha bakelit. D. amilopectin. Cu 21. Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. C6H5CH=CH2. B. CH3COOCH=CH2. C. CH2 =CHCOOCH3. D. CH2=C(CH3)COOCH3. Cu 22.Polime no sau y c tn gi T nitron hay Olon c dng dt may o m? A. Polimetacrylat B. Poli vinyl clorua C. Poli acrilonitrin D. Poli Phenolfomanehit Cu 23.Polime no sau y c tng hp bng phn ng trng ngng? A. poli(metyl metacrylat). B. polistiren. C. poli(etylen terephtalat). D. poliacrilonitrin. Cu 24.Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A. CH2=CH-COO-C2H5. B. CH2=CH-COO-CH3. C. CH3COO-CH=CH2. D. C2H5COO-CH=CH2. Cu 25. Sn phm chnh ca phn ng trng hp butaien-1,3 l A. (CH2-CH(CH=CH2)n B. -(CH2-CH=CH-CH2)nC.-(CH2-CH-CH-CH2-)nD. phng n khc Cu 26. Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng ngng axit -aminocaproic. B. Trng ngng hexametyleniamin vi axit aipic. C. Trng hp vinyl xianua. D. Trng hp metyl metacrylat. Cu 27. Tin hnh trng hp Buta-1,3-ien c th thu c ti a bao nhiu polime? A. 1 B. 2 C. 3 D. 4 Cu 28. T nilon - 6,6 c iu ch bng phn ng trng ngng A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. C. H2N-(CH2)5-COOH. D. HOOC-(CH2)4-COOH v HO-(CH2)2-OH. Cu 29. Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylen- terephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca phn ng trng ngng l: A. (1), (3), (6). B. (1), (2), (3). C. (1), (3), (5). D. (3), (4), (5). Cu 30. Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to? A. T visco v t axetat. B. T visco v t nilon-6,6. C. T tm v t enang. D. T nilon-6,6 v t capron. Cu 31. Trong s cc polime tng hp sau y: nha PVC (1), caosu isopren (2), nha bakelit (3), thu tinh hu
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c (4), t nilon 6,6 (5). Cc polime l sn phm trng ngng gm: A. (1) v (5). B. (1) v (2) C. (3) v (4) D. (3) v (5). Cu 32. Trong thc t, phenol c dng sn xut A. nha rezit, cht dit c 2,4-D v thuc n TNT. B. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. C. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. D. nha rezol, nha rezit v thuc tr su 666. Cu 33. Cao su thin nhin c lu ha cha 1,71% lu hunh. Hi c khong bao nhiu mt xch isopren c mt cu ni isunfua S-S-? A. 52 B. 25 C. 46 D. 54 Cu 34. Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 328. B. 382. C. 479. D. 453. Cu 35. Cho PVC phn ng vi clo to thnh t clorin. Trung bnh c 3 mt xch PVC phn ng vi 1 phn t clo. % khi lng ca clo trong t clorin thu c l B. 66,7% C. 73,2% D. 56,81% A. 63,96% Cu 36. Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5) A. 3. B. 6. C. 4. D. 5. Cu 37. Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn 3 V m kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 224,0. B. 448,0. C. 358,4. D. 286,7. Cu 38. Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 113 v 152. B. 113 v 114. C. 121 v 152. D. 121 v 114. Cu 39. Khi cho phenol tc dng vi HCHO, ngoi nha phenol-fomandehit ngi ta cn thu c sn phm ph X c CTPT C8H10O3. X khng tc dng vi dung dch Na2CO3 nhng phn ng c vi dung dch NaOH. Khi cho 0,1 mol X tc dng vi Na gii phng ra lng H2 bng lng H2 sinh ra khi in phn hon ton dung dch cha 17,55g NaCl. CTCT thu gn ca X l A. (HO)2C6H2CH3(CH2OH) B. (HO)2C6H3CH2CHO C. (HO)2C6H5COCH3 D. HOC6H3(CH2OH)2 Cu 40. Khi clo ho PVC thu c mt loi t clorin cha 66,6%Clo theo khi lng. S mt xch trung bnh ca PVC tc dng vi mt phn t clo l: A. 1,5. B. 3. C. 2.D. 2,5. Cu 41. Mt loi cao su lu ho cha 3% lu hunh (v khi lng) . Hi trung bnh c bao nhiu mt xch Isopren c mt cu ni isunfua -S-S-, gi thit rng S thay th cho H nhm metylen trong mch cao su? A . 62 B . 30 C . 46 D . 64 Cu 42. Ngi ta sn xut cao su Buna t g theo s sau:
glucz ancol etylic Butaien-1,3 Cao su Buna. G Tnh lng g cn thit sn xut c 1 tn cao su, gi s trong g cha 50% xenluloz? A. 35,714 tn B. 18,365 tn C. 8,9285 tn D. 17,857 tn Cu 43. Th tch kh metan (kc) cn iu ch 1 tn PVC, nu hiu sut ton b qu trnh iu ch l 20%: B. 2897 lt C. 3000 lt D. 3584 m3 A. 3143 dm3 Cu 44. T glucoz iu ch cao su buna theo s sau y: glucoz ancol etylic buta-1,3-ien cao su buna. Hiu sut ca qu trnh iu ch l 75%, mun thu c 32,4kg cao su th khi lng glucoz cn dng l: A. 72kg. B. 192kg. C. 144kg D. 288kg.
35%
80%
60%
100%
Chuyn 16:
A. dd HNO3 B. dd HCl.
NHN BIT
C. CO2 v nc. D. BaCl2.
Cu 1: Dng ha cht no sau y nhn 4 dd:NaAlO2, AgNO3, Na2S, NaNO3? Cu 2: Ch dng duy nht mt dd no sau y tch ring ly Al ra khi hh Al, MgO, CuO,FeO v Fe3O4 m khi lng Al khng thay i? A. NaOH. B. H2SO4c, ngui.
C. H2SO4 long.
D. HNO3 long.
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Cu 3: Dng thuc th no sau y nhn ra 3 gi bt ring bit: Al, Fe, Al2O3 A. H SO long.
2 4
B. dd HCl.
C. HNO long.
3
D. dd KOH. D. NH3. D. H2O.
Cu 4: C 5 dd ring bit: FeCl3, FeCl2, AlCl3, NH4NO3, NaCl. Dng thuc th no sau y nhn 5 dd trn? A. NaOH. B. HCl. C. BaCl2. Cu 5: C 3 cht bt: Al, Al O , Cr.Nhn 3 cht trn ch dng 1 thuc th:
2 3
A. dd NaOH.
B. dd HCl.
C. dd FeCl2.
2
Cu 6: C th dng 1 thuc th nhn bit 3 dd: natri sunfat, kali sunfit, nhm sunfat? A. dd HCl. B. dd BaCl . C. dd NaOH. D. qu tm. Cu 7: Dng 2 ha cht no sau y nhn 4 dd: HCl, HNO3, KCl, KNO3? A. qu tm, dd AgNO3. C. dd Ba(OH) , dd AgNO .
2 3
B. qu tm, dd Ba(OH)2. D. dd phenolphtalein, dd AgNO .

3
Cu 8: loi b tp cht Fe, Cu c trong mu Ag, ngi ta ngm mu bc ny vo dd d dd(m khng lm tng lng Ag); A. H SO c, ngui. B. FeCl . C. AgNO . D. HNO .
2 4 3 3 3
Cu 9: Dng 1 thuc th phn bit 4 cht rn: NaOH, Al, Mg, Al2O3 l: A. dd HCl. B. nc. C. dd H2SO4. Cu 10: C th dng H SO c lm kh cc cht:
2 4
D. dd HNO3 c.
A. NH3, O2, N2, CH4, H2. C. SO2, NO2, CO2, CH4, H2.
4 3 4 2 4 2 4
B. CaO, CO2, CH4, H2. D. Na2O, Cl2, O2, CO2, H2. C. NaOH. C. qu tm. C. Ca(OH)2. D. Ba(OH)2. D. HCl. D. vi sng.
Cu 11: nhn 4 dd: NH NO , (NH ) SO , K SO , KOH, ch cn dng dd: A. qu tm. A. NaOH. A. ng sunfat khan. B. AgNO3. B. H SO .
2 4
Cu 12: C th dng thuc th no sau y nhn bit 4 dd ring bit: NH4Cl, NaCl, BaCl2, Na2CO3? Cu 13: lm kh kh H2S c th dng: B. P2O5. Cu 14: C cc dd : glucoz, glyxerol, etanol, etylfomat. C th dng thuc th no sau y nhn c c 4 dd trn? A. Cu(OH)2 B. dd NaOH C. dd AgNO3/NH3 D. dd HCl Cu 15: C 3 dd: saccaroz, glucoz, h tinh bt.Dng thuc th no sau y nhn 3 dd trn? A. I2 B. dd AgNO3:NH3 C. Cu(OH)2 D. dd Br2 Cu 16: Ch dng nc brom khng th phn bit c 2 cht no sau y? A. Anilin v xiclohexylamin. B. dd anilin v dd amoniac. C. Anilin v benzen. D. Anilin v phenol. Cu 17: Thuc th n gin nhn 3 dd kali clorua, km sunfat, kali sunfit l: A. dd HCl. B. dd BaCl2. C. qu tm. D. dd H2SO4. Cu 18: loi c H2SO4 ra khi hn hp vi HNO3, ta dng: A. dd Ca(NO3)2 va . B. dd AgNO3 va .
4 4 3
C. dd CaSO4 va .
4
D. dd Ba(OH)2 va .
4 2 4
Cu 19: Ch dng nc c th phn bit c cc cht trong dy: A. Na, Ba, NH Cl, NH NO . B. Na, Ba, NH Cl, (NH ) SO . C. Na, K, NH4NO3, (NH4)2SO4. D. Na, K, NH4Cl, (NH4)2SO4. Cu 20: Ch c giy mu m, la, v giy tm dd mui X. Ngi ta phn bit 4 l kh ring bit:O2, N2, H2S v Cl2 do c hin tng: kh(1) lm tn la chy bng ln, kh (2) lm mu ca giy mu b nht, kh (3) lm giy tm dd X c mu en.Kt lun sai l: A. Kh (1) l O2, X l mui CuSO4. B. Kh (1) l O2, kh (2) l Cl2. C. X l mui CuSO , kh (3) l Cl .
4 2
D. X l mui Pb(NO ) , kh (2) l Cl .

3 2 2
Cu 21: Cho 5dd: FeCl3, FeCl2, AgNO3 , NH3 , hn hp NaNO3 v KHSO4. S dd ha tan c Cu kim loi l: A. 5 B. 2 C. 3 D. 4 Cu 22: t chy st trong clo d c cht X, nung st vi lu hunh thu c cht y. xc nh thnh phn phn t v ha tr ca cc ng.t trong X, Y c th dng ha cht no sau y? A. dd H2SO4 , dd BaCl2. B. dd HNO3, dd Ba(OH)2.
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C. dd H2SO4 v dd AgNO3 .
D. dd HCl, NaOH, oxy. D. dd AgNO3:NH3
Cu 23: phn bit 3 dd: glucoz, caccaroz, andehytaxetic c th dng: A. Cu(OH)2 B. Na C. dd Br2
Cu 24: Nhn bit 4 dd(khong 0,1 M)Na2SO4, Na2CO3, BaCl2, LiNO3 ch cn dng: A. axit sunfuric. B. qu tm. C. phenolphtalein. D. bari hydroxyt. Cu 25: Thuc th nhn cc dd: NH4NO3, NaNO3, Al(NO3)3, Mg(NO3)2,Fe(NO3)2,Fe(NO3)3, Cu(NO3)2 l: A. NaCl. B. NaOH.
2 3 2 2 2
C. Na2CO3.
D. NaAlO2.
3
Cu 26: C cc bnh kh: N NH , Cl , CO , O khng nhn. xc nh bnh NH Cn dng:(1)giy qu m, (2)bng tm nc, (3)bng tm dd HCl c, (4)Cu(OH)2, (5)AgCl. Cch lm ng l: A. (1), (2), (3), (5). B. (1), (2), (3). C. (1), (3), (4). Cu 27: Ch dng Na CO c th nhn c tng dd trong dy no sau y?
2 3
D. (1),(3).
A. KNO3, MgCl2, BaCl2. C. NaCl, MgCl2, Fe(NO3)3. Cu 28: lm kh kh amoniac ngi ta dng: A. P2O5. B. axit sunfuric khan. A. giy qu tm m. A. qu tm. A. qu tm. B. dd HCl. B. Na2CO3.
3 3
B. CaCl2, Fe(NO3)2, MgSO4. D. Ca(NO3)2, MgCl2, Al(NO3)3. C. ng sunfat khan. C. dd BaCl .

2
D. vi sng. D. dd Ca(OH) .
2
Cu 29: C cc bnh kh: N2 NH3, Cl2, CO2, O2 khng nhn. xc nh bnh NH3 v Cl2 ch cn dng: Cu 30: Phn bit 3 dd NaOH, HCl, H2SO4 ch dng: C. BaCO3.
3 3 2 2 4
D. Zn. D. dd BaCl2.
Cu 31: Thuc th phn bit 4 dd Al(NO ) , NaNO , Mg(NO ) , H SO l: B. dd NaOH. C. dd CH3COONa. Cu 32: nhn bit trong thnh phn khng kh c nhim tp cht hydro clorua, ta c th dn khng kh qua:(1)dd AgNO ,(2)dd NaOH, (3)nc ct c v git qu tm, (4)nc vi trong. Phng php ng l:
3
A. (1), (2), (3). B. (1),(3). C. (1). D. (1), (2), (3), (4). Cu 33: C cc dd AgNO3, ddH2SO4long,dd HNO3c, ngui, ddHCl. phn bit 2 kim loi:Al v Ag hoc Zn v Ag cn phi dng: A. 1 trong 4 dd. B. 2 trong 4 dd. C. 3 trong 4 dd. D. c 4 dd. Cu 34: thu c Ag tinh khit t hn hp bt Ag-Fe, ngi ta dng d dd: A. FeCl3. B. AgNO3. C. CuSO4. D. HNO3c, ngui, Cu 35: Phn bit 4 cht ring bit: axit fomic, axit axetic, etyl fomiat, metyl axetat. Dng thuc th ng nht: A. qu tm, dd Na2CO3 B. qu tm,dd NaOH C. qu tm,dd NaOH, Ag2 O/ddNH3 A. dd NaOH c, nng, CO2. C. dd NaOH long, dd HCl. Fe(NO3)3, Cu(NO3)2 l: A. NaOH. B. dd HCl. C. AgNO3. D. Ba(OH)2. Cu 38: C th dng NaOH ( th rn) lm kh cc cht kh A. NH3, SO2, CO, Cl2. B. N2, NO2, CO2, CH4, H2. C. N2. Cl2, O2, CO2, H2. D. NH3, O2, N2, CH4, H2. D. qu tm, Na B. dd NaOH c, nng, dd HCl. D.dd NaOH long, CO2. Cu 36: lm sch qung boxit c ln Fe2O3, SiO2 dng cho sn xut nhm, ngi ta dng:
Cu 37: Thuc th duy nht nhn cc dd: NH4NO3, (NH4)2SO4, NaNO3, Al(NO3)3, Mg(NO3)2, Fe(NO3)2,
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Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

Lu hanh noi bo Thang 1 nam 2013

16 chuyn n thi i hc, cao ng 2012 - 2013

Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

CU TO NGUYN T, BNG TUN HON CC NGUYN T

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A. Na >Mg >Al >O >F >Na >Mg >Al

B. Mg >Al >Na >O >F >Mg >Al >Na

16 chuyn n thi i hc, cao ng 2012 - 2013

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PHN NG OXIHA-KH CN BNG, TC PHN NG

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(2)H2(k) + I2(k) 2HI (k) (4)2NO2 (k) N2O4 (k)

Khi thay i p sut nhng cn bng ha hc b chuyn dch l:

Chu Anh Tun -

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D. (1), (2), (3). D. nhit .

(2) N2(k) + 3H2(k) 2NH3(k)

D. thay i nng N2.

Chu Anh Tun -

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Chu Anh Tun -

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H2SO3 H+ +HSO3- (2);

[CO 2 ][ H 2 ] ) . S mol ca [CO ][H 2O ]

Chu Anh Tun -

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Chu Anh Tun -

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BI TP LIN QUAN N DUNG DCH AXIT HCl, HNO3, H2SO4

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Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

Chu Anh Tun -

Trng THPT s 1 Ngha Hnh

16 chuyn n thi i hc, cao ng 2012 - 2013

Chu Anh Tun -

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khi so vi hidro bng 22,85. X, Y ln lt l: A. CO2, N2O B. N2, CO2

IN LI pH CA DUNG DCH BI TP LIN QUAN N BAZ

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Chu Anh Tun 3+

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B. NaCl, NaHCO3, NH4Cl, BaCl2 D. NaCl