Gio vin Nguyn Thu H

BI TP CHNG II
Cu 1: Cho pin: (Pt) H2 (p=1atm) | HCl (0,15M) | Hg2Cl2 ,Hg
o
25oC, j Hg
= 0,2681 V. Tnh S ca pin.
Cl / Hg ,Cl
-

Cu 2: 298K sc in ng chun ca pin (Pt)| Ce4+, Ce3+||Fe3+, Fe2+|(Pt) l 0,84 V. Tnh hng s cn
bng ca phn ng: Ce4+ + Fe2+ Ce3+ + Fe3+
Cu 3: Vit s pin m khi hot ng c cc phn ng tng ng sau:
a) Zn + Cu2+ Cu + Zn2+
b) Ag+ + Cl- AgCl
c) Zn + Cl2 ZnCl2
d) HgO(rn) + H2 Hg + O2
e) Ce4+ + Fe2+ Ce3+ + Fe3+
f) Zn + H2S ZnS + H2
Cu 4: Tnh S ca cc pin:
Ag | AgNO3 0,01 M || AgNO3 0,1 M | Ag.
Ag, AgCl | NaCl 0,1 M || NaCl 0,01 M | Ag.
Cu 5: S ca pin gm mt in cc calomen bo ha v in cc hiro nhng vo dung dch nghin
cu 25OC c gi tr bng 0,562 V. Bit th ca in cc calomen bo ha 25OC l 0,2415 V. Xc nh
pH ca dung dch nghin cu.
Cu 6: S ca pin (Pt) H2 (1atm) | H+, Cl- (0,01 M) | AgCl, Ag 25oC l 0,4615 V. Th in cc chun
ca in cc AgCl/Ag l 0,2225 V. Tnh pH ca dung dch nghin cu.
Cu 7: 25oC, th chun ca in cc Ag+/Ag l 0,7991 V, ca in cc AgCl/Ag l 0,224 V. Tnh tch
s tan ca AgCl
Cu 8: (Pt) H2 (1 atm) | CH3COOH 0,01 M, CH3COONa 0,01 M, NaCl 0,01 M| AgCl,Ag
Pin c sc in ng l 0,6220 V 298K. Bit th in cc chun ca AgCl/Ag l 0,2225 V. Vit cc
phng trnh phn ng in cc v tnh hng s phn ly ca CH3COOH.
Cu 9: Cho phn ng ho hc xy ra trong pin: Ag(NH3)2+ D Ag+ + 2 NH3
Hy vit s pin v xc nh hng s khng bn ca phc Ag(NH3)2+ .
Bit o(Ag+/Ag) = 0,7991 V; o(Ag(NH3)2+/Ag) = 0,373 V.
Cu 10: Vit phng trnh phn ng ca cc pin sau v tnh S iu kin chun:
Pt | Fe2+, H+,Fe3+ || HCl , Cl2 (Pt)
Pt | Fe2+, H+,Fe3+ || H+, MnO4-, Mn2+ | Pt
Cho bit cc gi tr o: Fe3+/Fe2+ 0,771V;
Cl2/2Cl- 1,359V; MnO4-,H+/Mn2+ 1,507V
Cu 11: Lp pin lm vic theo phn ng:
Sn + Pb2+ = Sn2+ + Pb
Tnh hng s cn bng Ka ca phn ng trn 250C, bit th chun ca cc in cc
j0298(Sn2+/Sn) = -0,14 V, j0298(Pb2+/Pb) = -0,1265 V.
Cu 12: Thit lp pin t cc in cc sau v tnh sc in ng:
Ag,AgBr|Br- (a=0,34)
jo = 0,0713V
Fe3+ (a=0,1), Fe2+ (a=0,02)|Pt jo = 0,771V
Cu 13: Cho pin (Pt) H2(P = 1atm)|HCl (a= 0,075)|Cl2 (P = 2 atm) (Pt)
a, Vit cc phn ng in cc. Xc nh du ca cc in cc.
b, Tnh sc in ng E ca pin trn. Bit : jClo / Cl = 1,358 (V)
-

Cu 14: Lp s pin to thnh t in cc Zn/ddZnSO4 l cc m v in cc calomen

(Hg/Hg2Cl2/ddKCl) l cc dng. Vit phng trnh phn ng xy ra ti mi in cc v phn ng trong
pin.
Sc in ng ca pin thay i nh th no khi nng Zn2+ tng?
Cu 15: Cho pin 250C:
(-) Cu|CuSO4 (a= 0,05) || HCl(a= 0,01)/Cl2(1atm)/Pt (+)
Bit
j oCl / Cl - =1,358 V
j oCu 2+ / Cu = 0,337 V
2

Bi tp chng II

Gio vin Nguyn Thu H

a) Vit phng trnh ca phn ng in cc v phn ng trong pin.

b) Tnh s E0, E ca pin; DG0, DG ca phn ng trong pin.
Cu 16: Tnh sc in ng 25oC ca pin
Zn|ZnSO4 0,01m || KClbo ha|Hg2Cl2, Hg
Bit: th chun ca in cc km l -0,763V, h s hot ion trung bnh ca ZnSO4 nng cho
bng 0,387, th chun ca in cc calomen bo ha l 0,242 V.
Cu 17: Vit phn ng xy ra trong pin
(-) (Pt)|H2(1atm)|ddHCl(a=0,15)|Hg2Cl2(r)|Hg (+)
v tnh sc in ng E ca pin bit th chun ca in cc calomel ti nng trn l 0,2681 V.

Bi tp chng II