Phm Cng Tun T in thoi: 0938.934.492 Facebook: www.facebook.com/tuantu.itus Trng H Khoa hc T nhin TP.

P.HCM - Kha hc Luyn thi i hc mn Ha Hc B GIO DC V O TO THI TH ( thi gm c 06 trang)

THI TUYN SINH I HC NM 2014

Mn: HA HC; Khi A,B Thi gian lm bi : 90 pht, khng k thi gian pht

H v tn th sinh: . S bo danh: ... Cho khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Li = 7; Na = 23; K = 39; P = 31; Mg = 24; Ca = 40; Ba = 137; Al = 27; Cr = 52; Fe = 56; Ni = 59; Cu = 64; Br = 80; I = 127; Sn = 119; Ag = 108. I. PHN CHUNG DNH CHO TT C CC TH SINH (t cu 1 n cu 40) Cu 1: Cho 21,4 gam mt mui clorua tc dng vi dung dch AgNO3 d thu c 57,4 g kt ta. Mt khc cho 10,7 gam mui clorua trn tc dng vi 500ml dung dch KOH 1M, n phn ng hon ton, c cn dung dch thu c m gam cht rn khan.Tnh m A. 31,7 g B. 23,7 g C. 38,7g D. 28,7g Cu 2: Cho bt Fe vo dung dch NaNO3 v HCl n phn ng hon thu c dd A, hn hp kh X gm NO v H2 v c cht rn khng tan. Trong dd A cha cc mui: A. FeCl3 ; NaCl B. Fe(NO3)3 ; FeCl3 ; NaNO3 ; NaCl C. FeCl2 ; Fe(NO3)2 ; NaCl ; NaNO3. D. FeCl2, ; NaCl Cu 3: Ho tan m gam hn hp gm Cu v Fe3O4 trong dung dch HCl d, sau phn ng cn li 8,32 gam cht rn khng tan v dung dch X. C cn dung dch X thu c 61,92 gam cht rn khan. Gi tr ca m l: A. 103,67. B. 43,84. C. 70,24. D. 55,44. Cu 4: Cho V(lt) kh CO2 hp th hon ton bi 200 ml dd Ba(OH)2 0,5M v NaOH 1,0M. Tnh V kt ta thu c l cc i? A. 2,24 lt V 8,96 lt B. 2,24 lt V 5,6 lt C. 2,24 lt V 4,48 lt D. 2,24 lt V 6,72 lt Cu 5: Cho cc cp dung dch phn ng vi nhau: (1) Na2CO3 + H2SO4 (2) K2CO3 + FeCl3 (3) Na2CO3 + CaCl2 (4) NaHCO3 + Ba(OH)2 (5) (NH4)2SO4 + Ba(OH)2 (6) Na2S + FeCl2 . S cp cht phn ng c to kt ta l: A. 5 B. 3 C. 2 D. 4 Cu 6: Cho dy cc cht: metylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, phenylclorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 5 B. 4 C. 6 D. 3 Cu 7: Dung dch A cha 0,02 mol Fe(NO3)3 v 0,3 mol HCl c kh nng ho tan c Cu vi khi lng ti
a l:

A. 6,4g. B. 0,576g. C. 5,76g. D. 0,64g. Cu 8: Tch nc hon ton t hn hp gm 2 ancol A, B ta c hn hp X gm cc olefin. Nu t chy hon ton th thu c 0,66g CO2. Nu khi t chy hon ton X th t ng khi lng CO2 v H2O thu c l A. 0,39g B. 0,903g C. 0,93g D. 0,94g Cu 9: t chy hon ton 9,16 gam hn hp X gm 1 este v 1 axit hu c ,cn v a 0,45 mol O2, v thu c s mol CO2 bng s mol H2O.Tnh th tch dung dch NaOH 1M phn ng v a ht 9,16 gam hn hp X. A. 80 ml B. 100 ml C. 120ml D. 150ml

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Phm Cng Tun T in thoi: 0938.934.492 Facebook: www.facebook.com/tuantu.itus Trng H Khoa hc T nhin TP.HCM - Kha hc Luyn thi i hc mn Ha Hc Cu 10: kh ion Fe3+ trong dung dch thnh ion Fe2+ c th dng mt lng d A. kim loi Ag. B. kim loi Ba. C. kim loi Mg. D. kim loi Cu. Cu 11: Phn ng c phng tr nh ion rt gn: HCO3- + OH- CO32- + H2O l A. 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O. B. 2NaHCO3 + 2KOH Na2CO3 + K2CO3 + 2H2O C. NaHCO3 + HCl NaCl + CO2 + H2O. D. Ca(HCO3) + 2NaOH CaCO3 + Na2CO3 + 2H2O. Cu 12: Cho cc cht sau: C2H5OH, C6H5OH, dung dch C6H5NH3Cl, dung dch NaOH, axit CH3COOH. Cho t ng cp cht tc dng vi nhau c xc tc thch hp, s cp cht c phn ng xy ra l: A. 5 B. 6 C. 4 D. 3 Cu 13: X phng ha hon ton 1 kg cht bo c ch s axit bng 2,8 ngi ta cn dng 350 ml KOH 1M. Khi lng glixerol thu c l A. 16,1 gam. B. 9,2 gam. C. 32,2 gam. D. 18,4 gam. Cu 14: Cho cc cht: NaHCO3, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht v a phn ng c vi dung dch HCl v a phn ng c vi dung dch NaOH l A. 7. B. 5. C. 6. D. 4. Cu 15: Khi in phn 500ml dung dch gm NaCl 0,2M v CuSO4 0,05M vi in cc tr khi kt thc in phn thu c dd X . Pht biu no sau y ng : A. Dung dch X ho tan c Al2O3. B. Kh thu c anot ca b nh in phn l : Cl2, H2. C. catt xy ra s oxi ho Cu2+. D. Dung dch X ho tan c kim loi Fe Cu 16: Cho cc nhn xt sau: 1. Na2CO3 c th lm mm mi nc cng. 2. Dung dch Ca(OH)2 c th lm mm nc cng tm thi nhng khng th lm mm nc cng vnh cu 3. Nc cng lm gim tc dng ca x phng do to kt ta. 4. Phn ng CaCO3 + CO2 + H2O Ca(HCO3)2 l phn ng gii thch s xm thc ca nc t nhin vo ni vi. S nhn xt ng l: A. 3. B. 4 C. 2. D. 1. Cu 17: Cho 1,2 lt hn hp gm hiro v clo vo b nh thu tinh bng thch anh y kn v chiu sng bng nh sng khuch tn. Sau mt thi gian ng ng chiu sng, thu c mt hn hp kh cha 30% hiroclorua v th tch v lng clo gim xung cn 20% so vi lng clo ban u. Thnh phn phn trm v th tch ca hiro trong hn hp ban u l A. 30,75%. B. 81,25%. C. 88,25%. D. 66,25%. Cu 18: Cho cc cht : axit oxalic, axit amino axetic, imetylamin, anilin, phenol, glixerol v amoniac. S cht trong cc cht cho lm i mu qu tim l A. 2 B. 5 C. 4 D. 3 Cu 19: Hp cht no sau y thuc loi ipeptit A. H2N-CH2CO-NH-CH(CH3)-COOH B. H2N-CH2-CH2-CO-NH-CH2-CH2-COOH C. H2N-CH2-NH-CH2COOH D. H2N-CH2-CH2-CO-NH-CH2-COOH Cu 20: t chy hon ton m gam hn hp gm hai este X1, X2 l ng phn ca nhau cn dng 19,6 gam O2, thu c 11,76 lit CO2 (ktc) v 9,45 gam H2O. Mt khc, nu cho m gam hn hp trn tc dng ht vi 200ml dung dch NaOH 1M ri c cn dung dch sau phn ng th cn li 13,95 gam cht rn khan. T l mol ca X1, X2 l A. 3:1. B. 2:3. C. 4:3. D. 1:2.

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Phm Cng Tun T in thoi: 0938.934.492 Facebook: www.facebook.com/tuantu.itus Trng H Khoa hc T nhin TP.HCM - Kha hc Luyn thi i hc mn Ha Hc Cu 21: Cho cc pht biu sau: (a) Anehit v a c tnh oxi ha v a c tnh kh (b) Phenol khng tham gia phn ng th (c) Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen. (d) Dung dch lng trng trng tc dng c vi Cu(OH)2 cho dung dch phc c mu xanh tm (e) Trong cng nghip, axeton v phenol c sn xut t cumen S pht biu ng l: A. 4 . B. 5. C. 3. D. 2. Cu 22: Cu no sau y l khng ng A. Cht xc tc khng nh hng n trng thi cn bng ho hc ca phn ng thun nghch B. Phn ng thun nghch khi t trng thi cn bng khng chu nh hng ca nhit C. Khi phn ng thun nghch trang thi cn bng th phn ng thun v nghch u khng d ng li D. Phn ng thun nghch trng thi cn bng , khi lng cc cht hai v ca phng tr nh ho hc l khng i. Cu 23: t chy hon ton 25,3 gam hn hp X gm RCOOH, C2H3COOH, v (COOH)2 thu c m gam H2O v 15,68 lt CO2 (ktc). Mt khc, 25,3 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2.Gi tr ca m l A. 10,8 gam B. 9 gam C. 7,2 gam D. 8,1gam Cu 24: Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit. (c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam m. (d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. S pht biu ng l A. 5 B. 3 C. 4 D. 6 Cu 25: C bao nhiu ng phn l hp cht thm, n chc c cng thc phn t C8H8O2 tc dng vi dd NaOH nhng khng tc dng vi kim loi Na? A. 5. B. 6. C. 4. D. 7. Cu 26: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, dd NaOH, CaCO3. S phn ng xy ra l: A. 5 B. 4 C. 2 D. 3 Cu 27: Hn hp X gm Ankan A v H2 c t khi hi ca X so vi H2 l 29. Nung nng X cracking hon ton A thu c hh c t khi hi so vi H2 l 145/9 . Xc nh cng thc phn t ca A: A. C3H8 B. C6H14 C. C4H10 D. C5H12 Cu 28: C 4 mu kim loi Na, Al, Ca, Fe. Ch dng nc lm thuc th th s kim loi c th phn bit c ti a l A. 4 B. 2 C. 1 D. 3 Cu 29: Dy no sau y ch gm cc polime thuc loi cht do? A. PVC, poli stiren, PE, PVA. B. Polibutadien, nioln -6,6, PVA, xenluloz. C. PE, polibutadien, PVC, PVA. D. PVC, polibutadien, nilon-6, nha bakelit. Cu 30: t chy hon ton 12,88 gam hn hp gm 1 axit no, n chc, mch h v 1 ancol no, n chc, mch h c 0,54 mol CO2 v 0,64 mol H2O. Thc hin phn ng este ha hon ton lng hn hp trn th thu c m (g) este. Gi tr ca m l A. 10,20 g B. 8,82 g C. 12,30 g D. 11,08 g Cu 31: t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hh kh Cl2
v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hh kh phn ng l 5,6 lt ( ktc). Kim loi M l

GIA S CHUYN HA CC LP 10-11-12-LTH KHU VC TP. H CH MINH

Phm Cng Tun T in thoi: 0938.934.492 Facebook: www.facebook.com/tuantu.itus Trng H Khoa hc T nhin TP.HCM - Kha hc Luyn thi i hc mn Ha Hc A. Cu. B. Mg. C. Be. D. Ca. Cu 32: Thc hin cc th nghim sau: 1) Sc kh Cl2 vo sa vi Ca(OH)2. 2) Sc kh SO2 vo dung dch H2S. 3) Cho MnO2 vo dung dch HCl c, nng. 4) Cho Fe2O3 vo dung dch H2SO4 c, nng. 5) Cho SiO2 vo dung dch HF. S th nghim c phn ng oxi ho - kh xy ra l A. 2 B. 3. C. 4. D. 5. Cu 33: Hn hp X gm ancol etylic v hai ankan l ng ng k tip. t chy hon ton 9,45 gam X thu c 13,05 gam nc v 13,44 lt CO2(ktc). Phn trm khi lng ca ancol etylic trong X l: A. 22,75% B. 52,92% C. 24,34% D. 38,09% Cu 34: Ho tan hon ton 18,5 gam hn hp X gm 3 oxit ca st bng dung dch H2SO4 long d sinh ra 44,5 gam mui sunfat. Nu cng cho 37 gam hn hp X trn phn ng vi lng d kh CO nhit cao. Sau phn ng, dn sn phm kh qua dung dch nc vi trong d th khi lng kt ta to thnh l m(g). Gi tr ca m l (cc phn ng xy ra hon ton) A. 90g. B. 120g. C. 65g. D. 75g. Cu 35: Hp cht c lin kt ion l A. NH3 B. CH3COOH. C. NH4NO3 D. HNO3 Cu 36: Nhng cht l th phm chnh gy ra cc hin tng: hiu ng nh knh; ma axit; thng tng ozon (l cc nguyn nhn ca s bin i kh hu ton cu) tng ng ln lt l: A. CO2 ; SO2 , NO2 ; CFC (freon: CF2Cl2 , CFCl3) B. CO2 ; SO2 , N2 ; CFC (freon: CF2Cl2 , CFCl3). C. N2 , CH4 ; CO2, H2S ; CFC (freon: CF2Cl2 , CFCl3). D. CFC (freon: CF2Cl2 , CFCl3) ; CO, CO2 ; SO2, H2S. Cu 37: Cho 8,3 gam hai kim loi kim k tip nhau tc dng vi 100 gam dung dch HCl 3,65% thu c dung dch X. Cho MgCl2 d vo dung dch X th thu c 4,35 gam kt ta. Hai kim loi l A. K v Rb B. Li v Na C. Na v K D. Rb v Cs Cu 38: Cho 11,8 gam hn hp Al v Cu tan hon ton trong dung dch HNO3 c nng (d) thu c 17,92 lt kh cht kh duy nht NO2 (ktc) v dung dch X ( NO2 l cht kh duy nht) . Cho dung dch X tc dng vi dd KOH d, sau phn ng hon ton, khi lng kt ta thu c l : A. 27,4 g B. 20,4 g C. 9,80 g D. 25,4 g Cu 39: Cho 13,8 gam hn hp gm but-1-in v anehit fomic vo lng d dung dch AgNO3/NH3 thy c 0,6 mol AgNO3 phn ng. Thnh phn % theo khi lng ca anehit fomic c trong hn hp l A. 65,22%. B. 32,60%. C. 26,40%. D. 21,74%. Cu 40: Thy phn m gam pentapeptit A c cng thc Gly-Gly-Gly-Gly-Gly thu c hn hp B gm 3 gam Gly; 0,792 gam Gly-Gly; 1,701 gam Gly-Gly-Gly; 0,738 gam Gly-Gly-Gly-Gly; v 0,303 gam Gly-Gly-Gly-Gly-Gly. Gi tr ca m l: A. 8,5450 gam B. 5,8345 gam C. 6,672 gam D. 5,8176 gam II. PHN RING: A. Theo chng trnh Chun (t cu 41 n cu 50) Cu 41: Cho hn hp K, Al, Fe, FeCO3, Fe3O4 tc dng vi dung dch NaOH d, lc ly kt ta ri chia lm 2 phn. - Phn 1: em tc dng vi dung dch HNO3 long d. - Phn 2: em tc dng vi dung dch HCl d. S phn ng oxi ha kh xy ra l A. 6 B. 8 C. 7 D. 5 GIA S CHUYN HA CC LP 10-11-12-LTH KHU VC TP. H CH MINH

Phm Cng Tun T in thoi: 0938.934.492 Facebook: www.facebook.com/tuantu.itus Trng H Khoa hc T nhin TP.HCM - Kha hc Luyn thi i hc mn Ha Hc Cu 42: Cho CO d i qua m gam hn hp gm Fe v Fe2O3 nhit cao sau phn ng ngi ta thu c 11,2 gam Fe. Nu cho m gam hn hp trn vo dung dch CuSO4 d, phn ng xong ngi tan nhn thy cht rn thu c c khi lng tng thm 0,8 gam. Gi tr ca m l A. 18 g. B. 24,2 g. C. 12,5 g. D. 13,6 g. Cu 43: C cc qui tr nh sn xut cc cht nh sau: 1500o C (1) 2CH4 C2H2 + 3H2
C 2 H4 ,H xt,t (2) C6H6 C6H5-C2H5 C6H5-CH=CH2
o +

H2 O,men,t men,t (3) (C6H10O5)n C6H12O6 C2H5OH

o o

xt,t (4) CH3OH + CO CH3COOH

o

O2 ,xt,t (5) CH2=CH2 CH3-CHO

o

C bao nhiu qui tr nh sn xut trn l qui tr nh sn xut cc cht trong cng nghip A. 5. B. 2. C. 4 . D. 3. Cu 44: T dung dch CuCl2, c my cch trc tip iu ch kim loi Cu A. 1 B. 3 C. 0 D. 2 Cu 45: Thu phn 1 mol este X cn 3 mol NaOH .Hn hp sn phm thu c gm : glixerol, axit axetic v axit propionic. C bao nhiu CTCT tho mn vi X: A. 12. B. 6. C. 4. D. 2. Cu 46: un 1 mol hn hp C2H5OH v C4H9OH (t l mol tng ng l 3 : 2) vi H2SO4 c 140oC thu c m gam ete, bit hiu sut phn ng ca C2H5OH l 60% v ca C4H9OH l 40% . Gi tr ca m l A. 53,76 gam. B. 23,72 gam. C. 19,04 gam. D. 28,4 gam. Cu 47: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch . C cn cn thn dung dch thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng ? A. 0,28 B. 0,34 C. 0,36 D. 0,32 Cu 48: Cho cc cht: axetandehit, benzen, toluen, stiren, propilen, axetilen. S cht lm mt mu thuc tm nhit thng l: A. 5 B. 2 C. 3 D. 4 Cu 49: Hp cht hu c X mch h c cng thc CxHyO. Khi t chy hon ton a mol X thu c b mol CO2 v c mol H2O. Bit (b c) = a . Khi hidro ha hon ton 0,1 mol X th th tch H2 (ktc) cn l: A. 6,72 lit B. 4,48 lit C. 8,96 lit D. 2,24lit Cu 50: Pht biu no sau y khng ng? A. O3 c tnh oxi ha mnh hn O2. B. Mui AgI khng tan trong nc, mun AgF tan trong nc. C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. D. Cc nguyn t m nguyn t c 1,2,3,4 electron lp ngoi cng u l kim loi B. Theo chng trnh Nng cao (t cu 51 n cu 60) Cu 51: Cho cc cht: but-1-in, vinylaxetilen, etilen, anehit fomic, axit fomic, mantoz, etilen glicol. S cht kh c Ag+ trong [Ag(NH3)2]OH l: A. 6 cht B. 4 cht C. 5 cht D. 3 cht Cu 52: Hai cht hu c A, B c cng thc CH5NO2 v C2H7NO2. Hn hp X gm A v B cho tc dng vi NaOH d to ra 2,72 gam mt mui duy nht v bay ra mt hn hp kh c M = 27,5. Hn hp X c khi lng A. 1,47g B. 2,94g C. 3,32g D. 4,42g GIA S CHUYN HA CC LP 10-11-12-LTH KHU VC TP. H CH MINH

Phm Cng Tun T in thoi: 0938.934.492 Facebook: www.facebook.com/tuantu.itus Trng H Khoa hc T nhin TP.HCM - Kha hc Luyn thi i hc mn Ha Hc Cu 53: Cho 6,48 gam hn hp Al v Mg tc dng v a vi dung dch cha 0,87 mol HNO3 to ra sn phm kh X duy nht. Lm bay hi dung dch sau phn ng thu c m gam mui khan, m c th l A. 51,430g B. 47,355g C. 49,632g D. 56,592g Cu 54: t chy hon ton mt este mch h ch cha chc este c 2n E = n CO2 - n H2O . Mt khc thy phn E trong mi trng axit c hn hp ch gm axit cacboxylic X v ancol n chc . t chy hon ton c n CO2 = n H2O . Pht biu ng l: A. E phi l este n chc. B. Este E c 2 lin kt trong phn t. C. Axit cacboxylic X trng gng c. D. Este E c t nht 5C trong phn t. Cu 55: Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 4. B. 5. C. 7. D. 6. Cu 56: Nhng mt thanh magie vo dung dch c cha 0,4 mol Fe(NO3)3 v 0,025 mol Cu(NO3)2. Sau mt thi gian, ly thanh kim loi ra, ra sch, cn li thy khi lng tng 5,8 gam so vi thanh kim loi ban u. Khi lng magie phn ng l A. 3,48 gam. B. 12,6 gam. C. 10,44 gam. D. 12 gam. Cu 57: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l A. Gly, Val, Tyr, Ala B. Gly, Ala, Glu, Lys C. Gly, Ala, Glu, Tyr D. Gly, Val , Lys, Ala Cu 58: Hai kh no sau y c th cng tn ti trong cng mt b nh cha? A. O2 v Cl2. B. H2S v SO2. C. NH3 v HCl. D. HI v Cl2. Cu 59: Phn ng no sau y khng xy ra A. (NH4)2Cr2O7 Cr2O3 + N2 + H2O B. Zn(d) + Cr(NO3)3 Zn(NO3)2 + Cr(NO3)2 C. CrCl3 + Cl2 + NaOH Na2CrO2 + NaCl + H2O D. CrO3 + NH3 Cr2O3 + N2 + 3H2O. Cu 60: un si hn hp gm propyl bromua, kalihiroxit v etanol thu c sn phm hu c l A. Propin B. Propan-2-ol C. Propen D. Propan.
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GIA S CHUYN HA CC LP 10-11-12-LTH KHU VC TP. H CH MINH