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Bi tp ha l chng cn bng pha v dung dich

Cu 1: Khi lng ring ca phenol dng rn v dng lng ln lt l 1,072 v 1,056 g/ml; nhit nng chy ca phenol l 24,93 cal/g; nhit kt tinh 1 atm l 41 oC. Xc nh nhit nng chy ca phenol 500 atm. Cu 2: p sut hi bo ha ca axit xyanhi ric HCN ph thuc vo nhit theo phng trnh lgP (mmHg) = 7,04- 1237/T Xc nh nhit si v nhit ha hi ca HCN iu kin thng. Cu 3: Mt cht hu c A c p sut hi bo ha cc nhit 323 v 348K ln lt l 227 v 630 mmHg. a) Xc nh nhit si v nhit ha hi ca A. b) Tnh khi lng phn t ca A bit nhit ha hi ring ca A l 117 cal/g. Cu 4: Trn ni cao p sut 660 mmHg, nc s si nhit no, bit nhit ho hi ca nc bng 9,72 kcal/(mol.K). Cu 5: Khi un nng lu hunh rombic chuyn thnh lu hunh n t km theo bin thin th tch ring l V = 0,0138 ml/g; 1atm s chuyn i th hnh gia hai dng lu hunh rn trn xy ra 95,5 0C cn 10 atm s chuyn pha xy ra 95,8 0C. Tnh nhit chuyn pha. Cu 6: Nhit nng chy chun ( 1 atm) ca Bi l 271 0C. iu kin t trng ca Bi rn v Bi lng ln lt l 9,673 v 10 g/cm 3 . Mt khc khi p sut tng ln 1 atm th nhit nng chy gim i 0,00354 K. Tnh nhit nng chy ca Bi. Cu 7: Xem dung dch ca CCl 4 v SnCl4 l dung dch l tng. Tnh thnh phn mol ca dung dch si 100oC di p sut 760 mmHg v thnh phn mol ca bong bng hi u tin, bit rng 100 oC p sut hi bo ho ca CCl4 v SnCl4 ln lt l 1450 v 500 mmHg. (S: 0,274 v 0,522) Cu 8: Mt dung dch l tng ca A v B cha 25% mol A. 25 oC, pha hi cn bng ca n cha 50% mol A. Nhit ha hi ca A v B ln lt l 5 v 7 kcal/mol. Tnh t o s p sut hi bo ho ca A v B khi nguyn cht (P o /Po ) 25oC A v B 100 C. (S: 3 v 1,52) Cu 9: 80oC, p sut hi bo ho ca cc cht nguyn cht A v B ln lt l 100 v 600 mmHg a) Hy v th p sut thnh phn pha lng (P-x) ca dung dch l tng A-B. b) Cho dung dch cha 40% mol B vo mt bnh kn c th tch sao cho 80 oC c 1/3 s mol ca dung dch b ho hi. Tnh thnh phn mol ca pha lng v pha hi cn bng. (S: xB = 0,261 v yB = 0,679) Cu 10: Mt dung dch cha 0,5 mol propanol v 0,5 mol etanol c chng cho n khi nhit si ca dung dch l 90 oC. p sut hi ca phn ngng t thu c l 1066 mmHg (cng o 90 oC). Xem dung dch l l tng v bit rng 90 oC p sut hi bo ha ca propanol v etanol ln lt l 574 v 1190 mmHg. Hy tnh: a) Thnh phn mol ca dung dch cn li trong bnh chng b) Thnh phn mol ca phn (hi) ngng t c) S mol etanol ho hi. (S: a) xE = 0,3; b) xE = 0,8; c) 0,32 mol) Cu 11: Hn hp khng tan ln H2O v CCl4 si 64oC, p sut hi ca CCl 4 nhit l 560 mm Hg.

Bi tp ha l chng cn bng pha v dung dich


Xc nh lng hi nc ti thiu cn thit chng li cun c 1 kg CCl 4 p sut kh quyn l 760 mm Hg. Cu 12: Nc v cacbontetraclorua CCl4 l hai cht lng khng tan ln. 25oC dung dch cha I2 trong nc c nng 0,0612 g/l nm cn bng vi dung dch cha I2 trong CCl4 c nng 5,202 g/l. Lc u 10 ml dung dch I2/CCl4 nng 3,2 g/l vi 150 ml nc ct n cn bng. Tnh nng ca I2 trong CCl4 v trong nc lc cn bng. Cu 13: Nhit si ca h hon ton khng tan ln naphtalen - nc 733 mmHg l 98oC, p sut hi nc bo ho nhit l 707 mmHg. Tnh phn khi lng ca naphtalen trong phn chng ct. Cu 14: C 0,06 g iod cha trong 2 lt dung dch nc. Tnh lng iod cn li trong sau khi chit bng 50 ml tetraclorua cacbon CCl4 theo 2 cch: a) Chit 1 ln bng 50 ml CCl4 b) Chit 2 ln, mi ln dng 25 ml CCl4 C I 2 / CCl 4 80 . Bit h s phn b K C I 2 / H 2O Cu 15: H 2 cht lng phenol v nc c bng nhit chuyn trng thi (t trong sang c) thnh phn khi lng nh sau: %phenol 10 20 30 35 40 45 50 55 60 70 t (oC) 42 52 60 67 66 65 63 60 50 28 o a) Ly 10 g phenol v 20 g nc cho vo ng nghim v gi 60 C. Xc nh s pha, thnh phn v khi lng mi pha trong h trng thi cn bng. b) Nu thm vo h (a) 20 g nc, gi nguyn nhit th quan st thy hin tng g? Cu 16: Dung dch gm 0,5g ure (H2NCONH2) v 25 g nc ct c nhit bt u kt tinh l -0,62 oC. Thm 0,5g ng vo dung dch trn th nhit bt u kt tinh s l -0,82oC. a) Hy xc nh hng s nghim lnh ca nc. b) Tnh nhit nng chy ca nc. c) Xc nh khi lng phn t ca loi ng thm vo. Cu 17: Ho tan 0,645 g naphtalen C 10H8 trong 43,25 g dioxan C 4H8O2 th dung dch c tng im si l 0,364 oC. Ho tan 0,748 g cht A vo 45,75 g dioxan th tng im si l 0,255oC. Bit rng dioxan c nhit si l 100,8oC. a) Hy xc nh nhit ho hi ca dioxan. b) Tnh hng s nghim si ca dioxan. c) Xc nh phn t khi ca cht A. (S: 7800 cal/mol; 3,12 ; M = 210). Cu 18: 20oC p sut hi bo ha ca nc l 17,54 mmHg, mt dung dch ure c p sut hi l 17,22 mmHg. Xc nh p sut thm thu ca dung dch trn 40oC, bit khi lng ring ca dung dch l 1,01 g/ml.

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