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CNG HA X HI CH NGHA VIT NAM

c lp T do Hnh phc

THI TUYN SINH CAO HC NM 2009


TRNG I HC S PHM H NI
Mn thi: C s l thuyt Ho hc
(thi gian 180 pht khng k thi gian giao )
Cu I:
1. Hy pht biu ni dung nguyn l phn i xng v p dng nguyn l tm
hm song m t trng thi c bn ca Li+ (c trnh by chi tit).
2. Cho nguyn t ho hc c Z = 26, hy trnh by:
a) Chi tit v kt qu cu hnh electron ca nguyn t (c dung lng t).
b) Tnh cht ho hc in hnh dng n cht ca nguyn t.
c) Vi ht c s oxi ho no (ion no) bn nht ca nguyn t ?
d) Tm s hng c bn ca nguyn t v ion va xt im c)
3 a) p dng h thc En = 13, 6

Z2
(theo eV), hy tnh cc tr nng lng E1, E2, E3
n2

theo kJ.mol -1 cho N +6.


b) C qui lut no lin h cc tr s En vi n (n l s lng t chnh)? Qui lut
phn nh quan h no v cu to nguyn t?
Cu II.
1. Thc nghim cho bit: CO 2- c hnh tam gic u, 3 nh l 3 O; cc lien kt
C O cng di; in tch h c gii tro u trn cc O. Hy vit cng
thc cu to Lewis v p dng m hnh VSEPR gii thch kt qu thc
nghim .
2. p dng ng thi thuyt lin kt ho tr (thuyt VB) v thuyt obitan phn t
(thuyt MO) hy gii thch s hnh thnh lin kt Ho hc (c v y )
trong: a) N2; b) CH4 (hnh t din u, tm l C, 4 nh l 4H).
3. p dng m hnh ht chuyn ng t do trong hp th hnh ch nht mt
chiu. hy tnh:
a) Nng lng cc electron pi (e- )ca phn t hexatrien, C6H10, mch h theo
kJ/mol;
b) di sng (theo nano met, nm) ca vach ph hp th tng ng s chuyn
di mt electron t HOMO ln LUMO trong phn t ny.
Bit: me = 9,11.10 31 kg; c = 3.108 m.s -1; h = 6,626.10 34J.s; d = 0, 140nm.
Cu III

S phn hu metan CH4 (kh) C(rn, graphit) + 2H2 (kh) c cc s liu sau y ti 250C:
0
Nhit ca phn ng, H pu = 74,85kJ / mol : Bin thin entropi ca phn ng,
0
S pu
= 80, 67 J / K .mol .
1. Hy tnh hng s cn bng Kp 298K.
0
2. Tnh hng s cn bng 500C vi gi thit nhit ca phn ng, H pu khng
ph thuc nhit . Hy nhn xt v chiu ca phn ng ti nhit ny.
3. Tnh phn ly ca CH4 2 p sut 0,01 bar v 1 bar ( cng 250C).
4.
Hy gii thch s thay i ca phn ly theo p sut v theo c nhit . S
thay i ny c ph hp vi nguynl chuyn dch cn bng Le Chatelier
khng?
Cu IV
Phn ng izome ho xyclopropan thnh propen c thc hin 5000C. Trong mt
th nghim, s chuyn ho ca xyclopropan c kho st cc p sut ban u
khc nhau v kt qu c ghi trong bng sau:
P0 (Torr)
200
200
400
400 600
600
Thi gian (giy 100
200
100
200 100
200
P(Torr)
186
173
373
347 559
P0 l p sut ban u v P l p sut ti thi im t ca xyclopropan)
1. Hy xc nh bc v hng s tc phn ng.
2. Xc nh thid gian na phn ng (t1/2)

520

Cu V
Cho 2 in cc Ni2+ (0,1M)/Ni v Ag+(0,1M)/Ag cng cc th kh tiu chun ln
lt l -0,25V v 0,799V.
1. Hy thit lp s pin hnh thnh t hai in cc cho. Vit cc phn ng
xy ra trn cng trn tng in cc v phn ng tng qut xy ra trong pin.
2. Tnh sc in ng E 250C ca pin theo iu kin cho. Khi h t ti
trng thi cn bng, sc in ng ca E bng bao nhiu?
3. Tnh hng s cn bng ca phn ng tng qut.
---------------------------------------------------------------------Ghi ch: Ngi coi thi khng gii thch g thm.

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