I HC HU

THI HT MN SAU I HC

TRNG I HC S PHM

Chuyn ngnh : HA V C

Mn thi: PHC CHT

Kha XVII (2008 - 2010)

Thi gian lm bi: 90 pht

s 1

Cu 1: (2,5 im)
1. Vit cng thc cu to ca Re3Cl9 v anion [Re2Cl8]22. Vit cng thc cu to v cho bit s hnh thnh lin kt trong cc phn t Mn2(CO)10; Fe(CO)5;
Co(CO)8; Ni(CO)4. Trong cc cng thc cu to ny, quy tc kh him ( quy tc s nguyn t hiu
dng (quy tc Sidgwick) c tun theo nh th no)?
Cu 2: (2,5 im)
Thc nghim cho thy c s hp th nh sng i vi nhng phc cht Ti(L)63+ nh sau:
L
H2O
Ur
FClBr-1
V (cm )
19 900
17 550
19 000
12 750
11 400
1. Hy sp xp dy ph ha hc i vi Ti3+ theo kt qu trn. So snh vi dy ha hc quang
ph thu nhn c t thuyt trng tinh th.
2. Bit rng phc Mn(H2O)63+ l phc spin cao, hy tnh moment t (theo l thuyt) ca phc
Mn(ur)63+.
3. Tnh moment t theo l thuyt ca phc Fe(H2O)63+.
4. C th c s chuyn di electron dd i vi phc Fe(H2O)63+ ny hay khng? Gii thch.
Cu 3: (2,5 im)
Hy gii thch:
1. Theo thuyt lin kt ha tr, i vi ion phc [Be(H2O)4]2+ c 4 phi t H2O cho 4 cp electron,
ngha l gp 8e vo ion trung tm Be2+ nhng ti sao in tch ca phc vn l +2?
2. Ti sao [Be(H2O)4]2+, [Al(H2O)6]3+ bn nhng [Be(H2O)6]2+, [Al(NH3)6]3+ li khng bn?
Cu 4: (2,5 im)
1. V cu hnh electron ca cc ion phc: [Co(NH3)6]2+; [Pt(NH3)6]2+; [CoF6]4- theo thuyt MO:
2. Hy so snh vi cch trnh by theo thuyt trng tinh th.