ESTE-LIPIT-CACBOHIDRAT

(Trong thi i hc qua cc nm)

Cu 1 (A-2012): Cho cc pht biu sau:
(a) Cht bo c gi chung l triglixerit hay triaxylglixerol.
(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c.
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch.
(d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
S pht biu ng l
A. 3.
B. 2.
C. 4.
D. 1.
Cu 2 (A-2012): Cho s phn ng :
xuctac
(a) X + H2O
Y
(b) Y + AgNO3 + NH3 + H2O amoni gluconat + Ag + NH4NO3
xuctac
(c) Y
E+Z
anh sang
X+G
(d) Z + H2O
chat diepluc
X, Y, Z ln lt l:
A. Tinh bt, glucoz, etanol.
B. Tinh bt, glucoz, cacbon ioxit.
C. Xenluloz, saccaroz, cacbon ioxit.
D. Xenluloz, fructoz, cacbon ioxit
Cu 3 (A-2012): t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v
mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO 2 v 0,4 mol
H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca
m l
A. 4,08.
B. 6,12.
C. 8,16.
D. 2,04.
Cu 4 (A-2012): Kh este no, n chc, mch h X bng LiAlH 4, thu c ancol duy nht Y. t chy
hon ton Y thu c 0,2 mol CO 2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng
CO2 v H2O l
A. 24,8 gam
B. 28,4 gam
C. 16,8 gam
D. 18,6 gam
Cu 5 (B-2012): t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O 2,
thu c 23,52 lt kh CO 2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH
1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol
mui Z (My < Mz). Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 2 : 3
B. 4 : 3
C. 3 : 2
D. 3 : 5
Cu 6 (B-2012): Thy phn este X mch h c cng thc phn t C 4H6O2, sn phm thu c c kh nng
trng bc. S este X tha mn tnh cht trn l
A. 4
B. 3
C. 6
D. 5
Cu 7 (B-2012): Th nghim no sau y chng t trong phn t glucoz c 5 nhm hiroxyl?
A. Kh hon ton glucoz thnh hexan.
B. Cho glucoz tc dng vi Cu(OH)2.
C. Tin hnh phn ng to este ca glucoz vi anhirit axetic.
D. Thc hin phn ng trng bc.
Cu 8 (B-2012): S trieste khi thy phn u thu c sn phm gm glixerol, axit CH 3COOH v axit
C2H5COOH l
A. 9
B. 4
C. 6
D. 2
Cu 9 (B-2012): un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600 ml dung
dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z
gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H2 (ktc). C cn dung dch Y, nung
nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht kh. Gi
tr ca m l
A. 40,60
B. 22,60
C. 34,30
D. 34,51
Cu 10 (B-2012): Este X l hp cht thm c cng thc phn t l C 9H10O2. Cho X tc dng vi dung dch
NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l
A. CH3COOCH2C6H5
B. HCOOC6H4C2H5
C. C6H5COOC2H5
D. C2H5COOC6H5
Cu 11 (B-2011): Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S
cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l:

A. 4
B. 2
C. 5
D. 3
Cu 12 (B-2011): Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng
NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam
B. 32,36 gam
C. 30 gam
D. 31,45 gam
Cu 13 (B-2011): Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng
kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S
ng phn cu to ca X tha mn cc tnh cht trn l:
A. 4
B. 5
C. 6
D. 2
Cu 14 (B-2011): Triolein khng tc dng vi cht (hoc dung dch) no sau y?
A. H2O (xc tc H2SO4 long, un nng)
B. Cu(OH)2 ( iu kin thng)
C. Dung dch NaOH (un nng)
D. H2 (xc tc Ni, un nng)
Cu 15 (B-2011): Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X,
thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l:
A. 25%
B. 27,92%
C. 72,08%
D. 75%
Cu 16 (B-2011): Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c
dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt
lng d dung dch AgNO3 trong NH3 th lng Ag thu c l
A.0,090 mol
B. 0,095 mol
C. 0,12 mol
D. 0,06 mol
Cu 17 (B-2010): Hp cht hu c mch h X c cng thc phn t C 6H10O4. Thy phn X to ra hai ancol
n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l
A. CH3OCO-CH2-COOC2H5.
B. C2H5OCO-COOCH3.
C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5.
Cu 18 (B-2010): Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40
ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2 (ktc)
v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l
A. 0,015.
B. 0,010.
C. 0,020.
D. 0,005.
Cu 19 (B-2010): Cac dung dich phan ng c vi Cu(OH)2 nhit thng la
A. glixeron, axit axetic, glucoz
B. long trng trng, fructoz, axeton
C. anhit axetic, saccaroz, axit axetic
D. fructoz, axit acrylic, ancol etylic
Cu 20 (B-2010): Tng s hp cht hu c no, n chc, mach h, co cung cng thc phn t C 5H10O2,
phan ng c vi dung dich NaOH nhng khng co phan ng trang bac la
A. 4
B. 5
C. 8
D. 9
Cu 21 (B-2010): Cht X c cc c im sau: phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH) 2
nhit thng, phn t c lin kt glicozit, lam mt mau nc brom. Cht X la
A. xenluloz
B. mantoz
C. glucoz
D. Saccaroz
Cu 22 (A-2010): Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH
24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
A. HCOOH v C2H5COOH.
B. HCOOH v CH3COOH.
C. C2H5COOH v C3H7COOH.
D. CH3COOH v C2H5COOH
Cu 23 (A-2010): t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3),
thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin).
Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu
c 12,88 gam cht rn khan. Gi tr ca m l
A. 10,56.
B. 7,20.
C. 8,88.
D. 6,66.
Cu 24 (A-2010): T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu
sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung
ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 90%.
B. 10%.
C. 80%.
D. 20%.
Cu 25 (A-2009): Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dung
dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi
lng dung dch nc vi trong ban u. Gi tr ca m l
A. 13,5.
B. 30,0.
C. 15,0.
D. 20,0.
Cu 26 (A-2009): Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung
dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc
ca X l

A. CH3COOC(CH3)=CH2.
B. HCOOC(CH3)=CHCH3.
C. HCOOCH2CH=CHCH3
D. HCOOCH=CHCH2CH3.
Cu 27 (B-2009): Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung
dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn
hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) th khi lng bnh
tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l
A. HCOOH v HCOOC2H5
B. CH3COOH v CH3COOC2H5
C. C2H5COOH v C2H5COOCH3
D. HCOOH v HCOOC3H7
Cu 28 (B-2009): Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn
dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH,
thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C2H4O2 v C3H6O2
B. C3H4O2 v C4H6O2
C. C3H6O2 v C4H8O2
D. C2H4O2 v C5H10O2
Cu 29 (B-2009): Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch
AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O 2 (cng iu kin v
nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO 2 thu c vt qu 0,7 lt ( ktc).
Cng thc cu to ca X l
A. CH3COOCH3
B. O=CH-CH2-CH2OH
C. HOOC-CHO
D. HCOOC2H5