DNG 1 :

PHNG PHP BO TON KHI LNG 1

Cu 1 :Ho tan hon ton 2,81 gam hn hp gm Fe2O3 , MgO , ZnO trong 500 ml dung dch axit H2SO4 long 0,1 M va . Sau phn ng , hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l ? S : 6,81 gam Cu 2 :Ho tan hon ton 3,22 gam hn hp X gm Fe , Mg , Zn bng mt lng va dung dch H2SO4 long , thu c 1,344 lt kh H2 ktc v dung dch cha m gam mui . Ga tr ca m l ? Cu 3 :Nung 13,44 gam hn hp 2 mui cacbonat ca 2 kim loi ho tr 2 . Thu c 6,8 gam cht rn v kh X . Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M , khi lng mui khan thu c sau phn ng l ? Cu 4 :Khi cho 4 gam hn hp kim loi gm Cu , Zn , Al vo dung dch H2SO4 c nng d thu c 4,48 lt kh SO2 iu khin tiu chun . Khi lng mui clorua thu c khi cho 4 gam hn hp trn tc dng vi kh Clo . Cu 5 :Ho tan hon ton 10 gam hn hp hai mui XCO3 , Y2(CO3)2 bng dung dch HCl . Ta thu c dung dch Z v 0,672 lt kh bay ra ktc . C cn dung dch Z th thu c m gma mui khan . Tnh m . S : 10.33 Cu 6 : Thi mt lung kh CO d i qua ng s ng m gam hn hp gm CuO , Fe2O3 ,FeO , Al2O3 . Nung nng c hn hp rn c khi lng 16 gam dn hon ton kh thu c vo dung dch nc vi trong d thy c 15 gam kt ta trng . Tnh m ? Cu 7 : Cho 14,5 gam hn hp Mg , Zn , Fe tc dng ht vi dung dch H2SO4 long thy thot ra 6,72 lt kh H2 ktc . C cn dung dch sau phn ng thu c m gam mui khan . Ga tr ca m l . s ; 43,3 Cu 8 : Dn mt lung kh kh CO d qua ng nghim ng m gam hn hp X gm Fe2O3 v CuO nung nng thu c cht rn Y . Kh ra khi ng c dn vo bnh dung dch Ca(OH)2 d thu uc 40 gam kt ta . Ho tan cht rn Y trong dung dch HCl d thy c 4,48 lt kh H2 bay ra ktc . Tnh m ? S : 24 gam Cu 9 :Ho tan hon ton 23 gam hn hp mui cc bonat ca kim loi ho tr I , v mt mui ca kim loi ho tr II bng dung dch HCl d thy thot ra 4,48 lt kh CO2 ktc . C cn dung dch sau phn ng th khi lng mui khan thu c l . Cu 10 : Cho 7,28 gam kim loi M tc dng hon ton vi dung dch HCl , sau phn ng thu c thu c 2,912 lt kh H2 27,3 C ; M l kim loi no ? Cu11 :Kh hon ton hn hp X gm FeO v Fe2O3 bng H2 nhit cao , kt thc th nghim thu c 9 gam H2O v 22,4 gam cht rn . % S mol ca FeO trong hn hp X l : Cu 12 :Cho mt lung kh CO i qua ng s ng m gam Fe2O3 nung nng . Sau mt thi gian thu c 13,92 gam hn hp X gm Fe , FeO , Fe3O4 v Fe2O3 . Ho tan ht X bng HNO3 c nng c 5,824 lt kh NO2 iu kin tiu chun . Tnh m

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Cu 13 :Thi mt lung kh CO i qua ng s ng m gam hn hp gm Fe3O4 v CuO nung nng thu c 2,32 gam hn hp cht rn . Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH)2 d thu c 5 gam kt ta . m c gi tr l : Cu 14 :Kh hon ton 17,6 gam hn hp X gm Fe , FeO , Fe2O3 cn 2,24 lt CO ktc . Khi lng st thu oc l ? Cu 15 :Ngm mt thanh kim loi M c khi lng 50 gam trong dung dch HCl . Sau phn ng thu c 3,36 lt kh H2 ktc v thy khi lng l kim loi gim 1,68 % so vi ban u . M l kim loi di y ? Cu 17 :Ho tan hon ton 10 gam hn hp X gm 2 mui khan FeSO4 v Fe2(SO4)3 vo nc . Dung dch thu c phn ng hon ton vi 1,58 gam KMnO4 trong mi trung axits H2SO4 d . Thnh % v khi lng ca FeSO4 trong X l . Cu 18 :in phn 250 ml dung dch CuSO4 vi in cc tr , khi catt bt u c bt kh th ngng in phn , thy khi lng ca tt tng 4,8 gam . Nng mol/lt ca CuSO4 ban u l . Cu 19 :Ha tan hon ton 12 gam hn hp X gm Fe , Cu bng dung dch HNO3 d , kt thc th nghim thu c 6,72 lt ktc . Hn hp B gm NO v NO2 c khi lng 12,2 gam gam . Khi lng mui nitrt sinh ra l ? Cu 20 :Nhit phn hon ton 9,4 gam mui Nitrat ca mt kim loi thu c 4 gam mt xt . Cng thc ca mui l g Cu 21 :Ho tan hn hp X gm 6,4 gam Cu v 5,6 gam Fe bng dung dch HNO3 1M . Sau phn ng thu c dung dch A v kh NO duy nht . Cho tip dung dch NaOH vo dung dch A thu c kt ta B v dung dch C . Lc kt ta , ra ri em kt ta B nung trong khng kh n khi lng khng i th khi lng cht rn thu c l . Cu 22 :Ho tan hon ton hn hp X gm 0,4 mol FeO v O,1 mol Fe2O3 vo dung dch HNO3 long d thu c dung dch A v kh NO duy nht . Dung dch A cho tc dng vi dung dch NaOH d thu c kt ta . Ly ton b lng kt ta nung trong khng kh n khi lng khng i thu c cht rn c khi lng l ? Cu 23 :Nung 6,58 gam Cu(NO3)2 trong bnh kn mt thi gian , thu c 4,76 gam cht rn v hn hp kh X . Ho tan hon ton X vo H2O c 300 ml dung dch Y . Dung dch Y c PH bng ? Cu24 :Cho kh CO i qua ng s cha 16 gam Fe2O3 un nng , sau phn ng thu c hn hp rn X gm Fe , FeO , Fe3O4 , Fe2O3 . Ho tan hon ton X bng H2SO4 c nng thu thu c dung dung dch Y . C trong dung Y lng mui khan thu c l ? Cu25 : kh hon ton CuO , FeO cn 4,48 lt kh H2 ktc . Nu cng kh hon ton hn hp bng CO th lng CO thu c khi cho qua dung dch nc vi trong d th khi lng kt ta sinh ra l bao nhiu ?

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DNG 2 : PHNG PHP BO TON KHI LNG 2

VD1 : Cho chui phn ng nh sau :
+ O2 + O2 + H2SO4 + Ba(NO3)2 + NaOH to H2

Fe Fe3O4 Fe2O3 Fe2(SO4)3 Fe(NO3)3 Fe(OH)3 Fe2O3 Fe3O4 Vit cc phng trnh phn ng xy ra . V tnh s mol ca cc nguyn t trong hp cht . a ra nhn xt VD2 :Cho hn hp gm 0,1 mol Fe ; 0,2 mol FeO , O,2 mol Fe2O3 v 0,1 mol Fe3O4 tc dng hon ton vi dung dch H2SO4 c nng . Vit cc phng trnh phn ng xy ra v tnh khi lng mui thu c . Cu 1:Cho 1,6 gam bt Fe2O3 tc dng vi axit d HCl .Khi lng mui trong dung dch sau phn ng l ? Cu 2 :Ho tan hon ton hn hp gm Fe , FeO , Fe2O3 , Fe3O4 trong dung dch HNO3 long nng d thu c 4,48 lt kh NO duy nht ktc v 96,8 gam mui Fe(NO3)3 phn ng . Tnh s mol HNO3 s : 1,4 mol Cu hi ph : Tnh m H2O to thnh , m xit ban u . Cu 3 :Hn hp X gm mt xit ca st c khi lng 2,6 gam . Cho kh CO d i qua X nung nng , kh i ra hp th vo dung dch nc vi trong d th thu c 10 gam kt ta . Tnh tng khi lng ca Fe c trong X l ? S : 1 gam . Cu 4 :Ho tan hon ton m gam Fe trong dung dch HCl thu c x gam mui clorua . Nu ho tan hon ton m gam Fe trong dung dch HNO3 long d th thu c y gam mui nitrat . Khi lng 2 mui chnh lch nhau 23 gam . Ga tr ca m l ? Cu 5 :Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 va thu c dung dch X ch cha hai mui sunfat v kh duy nht NO . Ga tr ca a l ? S : a = 0,06 mol Cu 6 :Cho kh CO i qua ng s cha 16 gam Fe2O3 un nng sau phn ng thu c hn hp rn X gm Fe , FeO , Fe3O4 , Fe2O3 . Ho tan hon ton X bng H2SO4 c nng thu c dung dch Y . C cn dung dch Y thu c lng mui khan l bao nhiu S : 40 Cu hi them : Nu cho bit kh SO2 thu uc l 0,3 mol , Tnh n H2SO4 , Cu 7 :Ho tan hon ton hn hp X gm 6,4 gam Cu v 5,6 gam Fe bng dung dch HNO3 1M sau phn ng thu c dung dch A v kh NO duy nht . Cho tip dung dch NaOH d vo dung dch A thu c kt ta B v dung dch C . Lc kt ta B ri em nung ngoi khng kh n khi lng khng i th khi lng cht rn thu c l ? S : 16 Cu 8 :Ho tan hon ton hn hp X gm 0,4 mol FeO v 0,1 mol Fe2O3 vo dung dch HNO3 long d , thu c dung dch A v kh NO duy nht . Dung dch A cho tc dng vi dung dch NaOH d thu c kt ta . Ly ton b kt ta nung trong khng kh n khi lng khng i thu c cht rn c khi lng l ? S : 48 gam Cu 9 :Ho tan hon ton a gam hn hp X gm Fe v Fe2O3 trong dung dch HCl thu
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c 2,24 lt kh H2 ktc v dung dichj B .Cho dung dch B tc dng vi dung dch NaOH d lc ly kt ta , nung trong khng kh n khi lng khng i thu c cht rn c khi lng bng 24 gam . Tnh a ? s : 21.6 gam .

DNG 3 :

PHNG PHP BO TON ELECTRON

Cu 1:Ho tan hon ton 12 gam hn hp Fe , Cu t l mol 1:1 bng axit HNO3 , Thu uc V lt kh ktc hn hp kh X gm NO v NO2 v dung dch Y ch cha hai mui v axit d . T khi ca X i vi H2 bng 19 . Ga tr ca V l bao nhiu ? Cu 2 :Cho 0,01 mol hp cht ca st tc dng ht vi H2SO4 c nng d thot ra 0,112 lt kh SO2 iu kin tiu chun l sn phm kh duy nht . Cng thc ca hp cht Fe l g trong : FeO , FeCO3 , FeS , FeS2 Cu 3 :Cho 12 gam hn hp Fe V Cu tc dng ht vi dung dch H2SO4 c nng d . Sau khi phn ng xy ra hon ton thu c 5,6 lt kh SO2 ktc v dung dch X . Khi lng ca Fe trong 12 gam hn hp u l bao nhiu ? Cu 4 :Hn hp X gm Cu v Fe c t l khi lng tng ng l 7:3 . Ly m gam X cho phn ng xy ra hon ton vi dung dch cha 44,1 gam HNO3 sau phn ng cn li 0,75m gam cht rn v c 0,56 lt kh Y gm NO v NO2 ktc . Ga tr ca m l ? S : m = 50,4 gam Cu 5 :Trn 0,54 gam bt Al vi bt CuO v Fe2O3 ri tin hnh phn ng nhit nhm trong iu kin khng c khng kh Ho tan hn hp thu c vo dung dch HNO3 d th c hn hp kh NO v NO2 vi t l mol tng ng l 1:3 . Th tch 2 kh thu c l ?S : 0,896 lt Cu 6 : m gam phi bo st ngoi khng kh , sau mt thi gian bin thnh hn hp X c khi lng 12 gam gm Fe , FeO , Fe3O4 , Fe2O3 . Cho X tc dng hon ton vi dung dch HNO3 thy gii phng ra 2,24 lt kh NO duy nht . Ga tr ca m l ? S : 10.08 gam Cu 7 :Trn 0,81 gam bt Al vi bt Fe2O3 v CuO ri t nng tin hnh phn ng nhit nhm thu c hn hp X . Ho tan hon ton X trong dung dch HNO3 un nng thu c V lt kh NO iu kin tiu chun . Tnh V ?S : 0,672 lit Cu 8 :Ho tan hon ton 6,4 gam Cu trong dung dch HNO3 long d thu c hn hp kh X gm 0,04 mol NO v 0,01 mol NxOy . Cng thc ca NxOy l ? S : N2O Cu 9 :Cho V lt hn hp kh Cl2 , O2 ktc tc dng va ht vi 2,7 gam Al v 3,6 gam Mg thu c 22,1 gam sn phm . V c gi tr bng . A.3,36 B.4,48 C.5,6 D.6.72 Bi 11 :Hn hp X gm hai kim loi A ,B ng trc H trong dy hat ng ho hc v c ho tr khng i trong cc hp cht . Chia m gam X thnh hai phn bng nhau .
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Phn I : ho tan hon ton trong dung dch cha axit HCl v H2SO4 long to ra 3,36 lt kh . Phn II : tc dng hon ton vi dung dch HNO3 thu c V lt kh NO sn phm kh duy nht Bit cc th tch kh o ktc . Tnh V A.2,24 lit B.3,36 l C.4,48 l D.6,72 l Cu 12 :Trn 0,54 g bt nhm vi bt Fe2O3 v CuO ri tin hnh phn ng nhit nhm thu c hn hp A. Ho tan hon ton A trong dung dch HNO3 c hn hp kh gm NO v NO2 c t l s mol tng ng l 1 : 3. Th tch (ktc) kh NO v NO2 ln lt l: A. 0,224 lt v 0,672 lt B. 0,672 lt v 0,224 lt. C. 2,24 lt v 6,72 lt. D. 6,72 lt v 2,24 lt. Cu 13 :Cho hn hp gm FeO, CuO, Fe3O4 c s mol ba cht u bng nhau tc dng ht vi dung dch HNO3 thu c hn hp kh gm 0,09 mol NO2 v 0,05 mol NO. S mol ca mi cht l: A. 0,12 mol. B. 0,24 mol. C. 0,21 mol. D. 0,36 mol. Cu 14 : Cho a gam Al tc dng ht vi dung dch HNO3 long th thu c 0,896 lt hn hp kh X, gm N2O v NO ktc, t khi ca X so vi hiro bng 18,5. Tm gi tr ca a? A. 1,98 gam. B. 1,89 gam. C. 18,9 gam. D. 19,8 gam Cu 15 :Cho tan hon ton 3,76 gam hn hp X dng bt gm S , FeS , FeS2 trong dung dch HNO3 thu c 0,448 mol NO2 v dung dch D . Cho dung dch D tc dng vi dung dch Ba(OH)2 d lc v nung kt ta n khi lng khng i thu c m gam hn hpc rn . Tnh gi tr ca m . A.11,65 g B.12,815 g C.13,98 g D.15,145 g

DNG 4 :

PHNG PHP GII TON ION

Phng trnh ion : iu kin c Phn ng gia cc ion : Mt trong 3 iu kin sau . + L phn ng ca Axt v Baz + Sn phm sau phn ng c kt ta . + Sn phm sau phn ng c kh V d : H+ + OH- H2O ( Phn ng AXT BAZ TRUNG HO ) 2+ CO3 + H CO2 + H2O ( Phn ng A B TRUNG HO ) + HCO3 + H CO2 + H2O ( Phn ng AXT BAZ TRUNG HO ) HCO3- + OH- CO32- + H2O ( Phn ng AXT BAZ TRUNG HO ) CO32- + Ba2+ BaCO3 ( To kt ta )
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 NH4+ + OH- NH3 + H2O ( To kh ) Cc dng ton nn gii theo phng php ion : + Nhiu axit + Kim loi + Nhiu baz + Nhm , Al3+ , H+ + Nhiu mui HCO3- + OH+ Cu + HNO3 + H2SO4 . Bi tp : Phn I : Vit cc phng trnh phn ng di dng ion trong cc trng hp sau : 1.Trn dung dch gm NaOH , Ba(OH)2 , KOH vi dung dch gm HCl , HNO3 . 2.Trn dung dch gm NaOH , Ba(OH)2 , KOH vi dung dch gm HCl , H2SO4 3.Ho tan hn hp kim loi gm Na , Ba vo dung dch gm NaCl , Na2SO4 4.Ho tan hn hp kim loi gm Na, Ba vo dung dch gm HCl , H2SO4 5.Ho tan hn hp kim loi gm Na , Ba vo dung dch cha (NH4)NO3 6.Ho tan hn hp kim loi gm K , Ca vo dung dch cha (NH4)2CO3 7.Ho tan hn hp K , Ca vo dung dch hn hp cha NH4HCO3 8.Ho tan K , Na, Al vo nc 9.Ho tan hn hp gm Al , Fe vo dung dch hn hp gm HCl , H2SO4 . 10.Trn NaOH , KOH vi NaHCO3 v Ca(HCO3)2 11.Trn dung dch gm Na2CO3 , K2CO3 vi dung dch cha CaCl2 , MgCl2 , Ba(NO3)2 Phn II : Bi tp Cu 1 :Trn 200 ml dung dch hn hp NaOH 1M , Ba(OH)2 0,5M vo 300 ml dung dch hn hp HCl 0,5M , H2SO4 1M Tnh nng ca cc ion cn li sau phn ng v Khi lng kt ta to thnh . Cu 2 :Trn 200 ml dung dch NaHSO4 0,2M v Ba(HSO4)2 0,15M vi V lit dung dch hn hp NaOH 1M v Ba(OH)2 1M thu c dung dch c PH = 7 . Tnh V v khi lng kt ta to thnh . Cu 3 :Thm m gam K vo 300 ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X . Cho t t 200 ml dung dch Al2(SO4)3 0,1M thu c kt ta Y . thu uc lng kt ta Y ln nht th gi tr ca m l A.1,17 B.1,71 C.1,95 D.1,59 Cu 4 :Trn dung dch Ba2+ ; OH- : 0,06 v Na+ 0,02 mol vi dung dch cha HCO3- 0,04 mol ; (CO3)2- 0,04 mol v Na+.Khi lng (g)kt ta thu c sau phn ng l ? Cu 5 :Cho m gam hn hp Mg , Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M thu c 5,32 lt kh H2 ktc v dung dch Y . Tnh PH ca dung dch Y ( Coi dung dch c th tch nh ban u ) . s : PH = 1 Cu 6 :Cho hn hp X cha Na2O , NH4Cl , NaHCO3 v BaCl2 c s mol mi cht u bng nhau . Cho hn hp X vo H2O d un nng dung dch thu c cha . A.NaCl B.NaCl , NaOH C.NaCl , NaOH , BaCl2 D.NaCl , NaHCO3 , NH4Cl , BaCl2 Cu 7 :Trn 100 ml dung dch gm Ba(OH)2 0,1M v NaOH 0,1M vi 400 ml dung dch gm H2SO4 0,0375M v HCl 0,0125M thu c dung dch X . Tnh PH ca dung dch X .
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Cu 8 :Cho dung dch cha a mol Ca(HCO3)2 vo dung dch cha a mol Ca(HSO4)2. Hin tng quan st c l ? A. Si bt kh B. vn c C. Si bt kh v vn c D. Vn c, sau trong sut tr li. Cu 10 :Trn V1 ml dung dch gm NaOH 0,1M , v Ba(OH)2 0,2 M vi V2 ml gm H2SO4 0,1 M v HCl 0,2 . M thu oc dung dch X c gi tr PH = 13 . Tnh t s V1 : V2 A.4/5 B.5/4 C.3/4 D.4/3 Cu 11 :Ho tan hon ton hn hp X gm Fe , Mg bng mt lng va dung dch HCl 20% , thu c dung dch Y . Nng ca FeCl2 trong dung dch Y l 15,76 % . Nng % ca MgCl2 trong dung dch Y l ? A.11,79% B.24,24% C.28,21% D.15,76% Cu 12.Mt dung dch cha a mol NaHCO3 v b mol Na2CO3. Khi thm (a+b) mol CaCl2 hoc (a+b) mol Ca(OH)2 vo dung dch th lng kt ta thu c trong hai trng hp c bng nhau khng ?
A. Lng kt ta trong hai trng hp c bng nhau. B. Lng kt ta trong trng hp 2 gp i vi trng hp 1. C. Trng hp 1 c b mol kt ta, trng hp 2 c (a+b) mol kt ta. D. Trng ,hp 1 c a mol kt ta, trng hp 2 c (a+b) mol kt ta.

Cu 13 :in phn dung dch NaCl vi in cc tr mng ngn xp thu c dung dich c phn ng va vi Ca(HCO3)2 to ra 1 gam kt ta . Kh Cl2 thu c dn qua bnh ng KOH 1M 100 C . Tnh V KOH dng . A.100 ml B.20 ml C.10 ml D.40 ml Cu 14 :Thc hin hai th nghim sau : 1.Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt kh NO . 2.Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5M thot ra V2 lt kh NO So snh V1 v V2 Cu 15 :Cho 0,2 mol Na vo 100 ml dung dch cha CuSO4 0,1M v H2SO4 2M . Hin tng quan st c l . A.C kh bay ln B.C kh bay ln v c kt ta xanh C.C kt ta D.C kh bay ln v c kt ta mu xanh sau kt ta li tan . Cu 16 :Dung dch X c cc ion Mg2+ , Ba2+ , Ca2+ V 0,1 mol Cl- , 0,2 mol NO3- . Thm dn V lt dung dch K2CO3 1M vo dung dch X n khi c lng kt ta ln nht . Ga tr ca V l ?

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DNG 5 :

Al3+ + DUNG DCH KIM

L thuyt : AlCl3 + NaOH Al2(SO4)3 + KOH Al(NO3)3 + KOH AlCl3 + Ca(OH)2 Al2(SO4)3 + Ba(OH)2 Phng trnh ion : Al3+ + OH- Al(OH)3 Al + OH- AlO2AlO2- + H+ + H2O Al(OH)3 V d 1 : Cho t t 100 ml dung dch NaOH 5M vo 200 ml dung dch Al(NO3)3 1M Tnh nng mol ca cc ion sau phn ng .

Luyn tp :
Cu 1 : Thm m gam K vo 300 ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X . Cho t t 200 ml dung dch Al2(SO4)3 0,1M thu c kt ta Y . thu uc lng kt ta Y ln nht th gi tr ca m l . A.1,17 B.1,71 C.1,95 D.1,59 Cu 2 :Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,1M . Lung kt ta thu c l 15,6 gam . Tnh gi tr ln nht ca V ? Cu 3 :Th tch dung dch NaOH 2M l bao nhiu khi cho tc dng vi 200 ml dung dch X ( HCl 1M AlCl3 0,5M ) th thu uc kt ta ln nht ? s : 250 ml Cu 4 :Cho V lt dung dch hn hp 2 mui MgCl2 1M v AlCl3 1M tc dng vi 1 lt NaOH 0,5M th thu c kt ta ln nht . Tnh V. S : V = 100 m l . Cu 5 : Cho V lt dung dch hn hp 2 mui MgCl2 1M v AlCl3 1M tc dng vi 1.1 lt NaOH 0,5M thu c 9.7 gam kt ta . Tnh V ln nht . S : 100 ml . Cu 6: Cho V lt dung dch NaOH 0,2M vo dung dch cha 0,15 mol AlCl3 thu c 9,86 gam kt ta . Tnh V . Cu 7 : Cho 1 lt dung dch HCl vo dung dch cha 0,2 mol NaAlO2 lc ,nung kt ta n khi lng khng i c 7,65 gam cht rn . Tnh nng ca dung dch . Cu 8 : Hn hp X gm Na v Al. Cho m gam X vo lng d nc th thot ra 1 lt kh .Nu cng cho m gam X vo dung dch d th c 1,75 lt kh .Tnh thnh phn phn trm khi lng ca cc cht trong hn hp X (bit cc kh o iu kin tiu chun ). Cu 9 : Chia m gam hn hp A gm Ba , Al thnh 2 phn bng nhau: -Phn 1: Tan trong nc d thu c 1,344 lt kh H2 (ktc) v dung dch B. -Phn 2: Tan trong dung dch Ba(OH)2 d c 10,416 lt kh H2(ktc) a/ Tnh khi lng kim loi trong hn hp ban u . b/ Cho 50ml dung dch HCl vo B .Sau phn ng thu c 7,8 gam kt ta .Tnh nng mol ca dung dch HCl .
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Cu 10:Thm 240 ml dung dch NaOH vo cc ng 100 ml dung dch AlCl3 nng a mol , khuy u ti phn ng hon ton thy trong cc c 0,08 mol kt ta . Thm vo cc 100 ml dung dch NaOH 1M khuy u thy phn ng xy ra hon ton thu oc 0,06 mol kt ta . Tnh nng a A.2M B.1,5M C.1M D.1,5M Cu 11: Trong 1 cc ng 200 ml dd AlCl3 2M. Rt vo cc V ml dd NaOH nng a mol/l, ta thu c mt kt ta, em sy kh v nung n khi lng khng i th c 5,1g cht rn a) Nu V = 200 ml th a c gi tr no sau y: A. 2M B. 1,5M hay 3M C. 1M hay 1,5M D. 1,5M hay 7,5M b) Nu a = 2 mol/l th gi tr ca V l: A. 150 ml B. 650 ml C. 150 ml hay 650 ml D. 150 ml hay 750 ml Cu 12 : Hn hp X gm cc kim loi Al , Fe , Ba . Chia X thnh 3 phn bng nhau : Phn I tc dng vi nc d , thu c 0,896 lt kh H2 Phn II tc dng vi 500 ml dung dch NaOH 1M d thu c 1,568 lt kh H2 Phn III tc dng vi HCl d thu uc 2,24 lt kh H2 1.Tnh phn trm khi lng cc kim loi trong hn hp X 2. Sau phn ng phn II , lc c dung dch Y , Tnh th tch dung dch HCl 1M cn thm vo dung dch Y : A.Thu c lng kt ta nhiu nht . B.Thu c 1,56 g kt ta

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DNG 6 :

BI TON IN PHN

Cu 1:in phn 100ml dung dch cha AgNO3 0.1M v Cu(NO3)2 0.1M vi cng dng in I l 1.93A.Tnh thi gian in phn (vi hiu xut l 100%). 1) kt ta ht Ag (t1) 2) kt ta ht Ag v Cu (t2) a)t1 = 500s, t2 = 1000s b) t1 = 1000s, t2 = 1500s c)t1 = 500s, t2 = 1200s d) t1 = 500s, t2 = 1500s Cu 2:in phn 100ml dung dch CuSO4 0.2M vi cng I = 9.65 A.Tnh khi lng Cu bm bn catot khi thi gian in phn t1 = 200s v t2 = 500s(vi hiu sut l 100%). a) 0.32g ; 0.64g b) 0.64g ; 1.28g c) 0.64g ; 1.32g d) 0.32g ; 1.28g Cu 3:in phn 100ml dung dch CuSO4 0.1M cho n khi va bt u si bt bn catot th ngng in phn. Tnh pH dung dch ngay khi y vi hiu sut l 100%.Th tch dung dch c xem nh khng i. Ly lg2 = 0.30. a) pH = 0.1 b) pH = 0.7 c) pH = 2.0 d) pH = 1.3 Cu 4:in phn 100ml dung dch cha NaCl vi in cc tr ,c mng ngn, cng dng in I l 1.93A. Tnh thi gian in phn c dung dch pH = 12, th tch dung dch c xim nh khng thay i,hiu sut in phn l 100%. a) 100s b) 50s c) 150s d) 200s Cu 5:in phn 100 ml dung dch CuSO4 002M v AgNO3 0.1M vi cng dng in I = 3.86A.Tnh thi gian in phn c mt khi lng kim loi bm bn catot l 1.72g.Cho Cu =64. Ag = 108. a) 250s b) 1000s c) 500s d) 750s Cu 6:in phn 100ml dung dch CuCl2 0.08M. Cho dung dch thu c sau khi in phn tc dng vi dung dch AgNO3 d th thu c 0.861g kt ta. Tnh khi lng Cu bm bn catot v th tch thu c bn anot. Cho Cu = 64. a) 0.16g Cu ; 0.056 l Cl2 b) 0.64g Cu ; 0.112 l Cl2 c) 0.32g Cu ; 0.112 l Cl2 d) 0.64g Cu ; 0.224 l Cl2 Cu 7:in phn 100ml dung dch CuSO4 0.1M vi cng I = 9065A.Tnh th tch kh thu c bn catot v bn anot lc t1 = 200s v t2 = 300s. a) catot:0;112ml; anot:112;168ml c) catot:0;112ml; anot:56;112ml b) catot:112;168ml; anot:56;84ml d) catot:56;112ml; anot:28;56ml Cu 8:in phn 100ml dung dch AgNO3 0.2M. Tnh cng I bit rng phi in phn trong thi gian 1000s th bt u si bt bn catot v tnh pH ca dung dch ngay khi y. Th tch dung dch c xem nh khng thay i trong qu trnh in phn. Ly lg2 = 0.30. a) I = 1.93A,pH = 1.0 b) I = 2.86A,pH = 2.0 c) I = 1.93A,pH = 1.3 d) I = 2.86A,pH = 1.7 Cu 9:in phn 200ml dung dch CuSO4 0.1M v MgSO4 cho n khi bt u si bt bn catot th ngng in phn. Tinh khi lng kim loi bm bn catot v th tch(ktc)
Page | 10

thot ra bn anot.Cho Cu = 64, Mg = 24. a) 1.28g; 2.24 lt b) 0.64; 1.12lt c) 1.28g; 1.12 lt d) 0.64; 2.24 lt 3 Cu 10 : Khi in phn 1 dm dd NaCl (d = 1,2). Trong qu trnh in phn ch thu c 1 cht kh in cc. Sau qu trnh in phn kt thc, ly dd cn li trong bnh in phn c cn cho ht hi nc thu c 125g cn kh. em cn kh nhit phn khi lng gim i 8g Hiu sut qu trnh in phn l: A. 46,8 B. 20,3 C. 56,8 D. 20,3 E. Kt qu khc Cu 11 : in phn 100 ml hn hp dung dch gm FeCl3 1M , FeCl2 2M , CuCl2 1M v HCl 2M vi in cc tr c mng ngn xp cng dng in l 5A trong 2 gi 40 pht 50 giy catot thu c A.5,6 g Fe B.2,8 g Fe C.6,4 g Cu D.4,6 g Cu Cu 12 : in phn hon ton dung dch hn hp gm a mol Cu(NO3)2 v b mol NaCl vi in cc tr , mng ngn xp . dung dch thu c sau khi in phn c kh nng phn ng vi Al2O3 th A. b = 2a B.b > 2a C.b < 2a D.b < 2a hoc b > 2a

Cu 13 :in phn 500 ml dung dch A FeSO4 v KCl vi in cc tr , gia cc in cc c mng ngn xp ngn cch . Sauk hi in phn xong anot thu c 4,48 lt kh B ktc . ca tt thu c kh C v bnh in phn thu c dung dch D . Dung dch D ha tan ti a 15,3 gam Al2O3 . 1.Tnh nng mol/l cc cht trong A 2.Tnh th tch kh C thot ra catot 3.Sau khi in phn khi lng dung dch A gim i bao nhiu gam ? Cu 14 : in phn 100 ml dung dch hn hp gm FeCl3 1M , FeCl2 2M , CuCl2 1M v HCl 2M vi in cc tr c mng ngn xp cng dng in l 5A , trong 2h40 pht 50 giy . ca tt thu c A.5,6 gam Fe B.6,4 gam Cu C.2,8 gam Fe D.4,6 gam Cu Cu 15 : in phn 200 ml dung dch hn hp gm HCl 0,1M v CuSO4 0,5M bng in cc tr . Khi catot c 3,2 gam Cu th th tch kh thot ra Anot l A.0,56 lt B.0,84 lt C.0,672 lt D.0,448 lt

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DNG 7 :

BI TP BIN LUN

L thuyt : A+B C+D+E Sau phn ng bin lun cc cht : + Chc c : C , D , E + C th : - A d - B d - C A v B d Nh vy sau phn ng c cc trng hp : + C , D , E to thnh V A d + C , D , E to thnh V B d + C , D ,E to thnh V A , B d Cc V d : Cu 1 :Nung nng CaCO3 thu c cht rn A c phn ng vi Axt to ra kh . Hi cht rn A c cht no . Cu 2 :Nung nng Cu(NO3)2 thu c cht rn A . Bit rng A ho tan oc mt phn trong nc .Hi A c phn ng vi cht no sau y ? Vit phn ng minh ho .HCl , NaOH , C2H5OH , CH3COOH , Mg(H)2 Cu 3 :Tin hnh phn ng nhit nhm Fe2O3 thu oc cht rn A . Bit rng A c phn ng vi HCl d to thnh kh Hi A bao gm nhng cht g ? Bit rng phn ng xy ra hon ton . Cu 4 :Nung nng Cu(NO3)2 thu c cht rn A . Bit rng A ho tan oc mt phn trong nc thu uc dung dch B v cht rn C . Cho dung dch B phn ng ln lt vi Fe , KOH , in phn dung dch .Cht rn C a vo bnh kn ri dn kh CO d thu oc cht rn D . Cho D phn ng vi dung dch AgNO3 , Fe2(SO4)3 , HCl , H2SO4 l , H2SO4 c , HNO3 . Vit tt c cc phn ng xy ra . Cu 5 :Tin hnh phn ng nhit nhm Fe2O3 thu oc cht rn A . Bit rng A c phn ng vi Ba(OH)2 d to thnh kh v dung dch B . Hi A , B bao gm nhng cht g ?( Bit rng phn ng nhit nhm xy ra hon ton ). Cu 6 :Dn kh CO2 vo dung dch NaOH . Dung dch thu oc c phn ng vi KOH . Hi dung dch A gm nhng cht no . Bit rng phn ng sy ra hon ton . Cu 7 :Dn kh CO2 vo dung dch NaOH . Dung dch thu oc c phn ng vi CO2 . Hi dung dch A gm nhng cht no . Bit rng phn ng sy ra hon ton . Cu 8 :Dn kh CO2 vo dung dch Ca(OH)2 . Dung dch thu oc c phn ng vi KOH . Hi dung dch A gm nhng cht no . Bit rng phn ng sy ra hon ton . Cu 9 :Dn kh CO2 vo dung dch Ca(OH)2 . Dung dch thu oc c phn ng vi CO2 . Hi dung dch A gm nhng cht no . Bit rng phn ng sy ra hon ton . Cu 10 :Trn ln dung dch A cha NaOH vi dung dch B cha AlCl3 phn ng xy ra hon ton Thu uc dung dch C .Bit rng C c phn ng vi CO2 to kt ta . Bin lun dung dch B . Cu 11 :Trn ln dung dch A cha NaOH vi dung dch B cha AlCl3 phn ng xy ra hon ton Thu uc dung dch C .Bit rng C c phn ng vi CO2 nhng khng to kt ta . Bin lun dung dch B . Cu 12 :t chy kim loi Al trong XI thu oc cht rn B .Cho B tc dng vi HCl d
Page | 12

thy c kh to thnh . Hi B . Cu 13 :Kh FeO bng CO thu c cht rn A c kh nng phn ng vi H2 . Hi A . Cu 14 :Tin hnh phn ng este ho C2H5OH vi CH3COOH . Sn phm thu c sau phn ng gm nhng cht g ?Bin lun . Cu 15 :Tin hnh phn ng xi ho ru CH3CH2H bng CuO . Hn hp hi thu oc sau phn ng c t khi so vi H2 l 22 . Hi hn hp hi sau phn ng gm nhng cht g .

Bi tp
Cu 1 :Nung nng m CaCO3 thu c 2,24 lt kh CO2 v cht rn A . Ho tan hon ton A bng HCl d thu oc 2,24 lt CO2 .Tnh khi lng m ? S : m = 20 gam Cu 2 :Nung nng mui 37.6 g Cu(NO3)2 thu uc 26.8 gam cht rn v hn hp kh A . Ho tan kh A vo 500 ml H2O thu oc dung dch B , Tnh PH ca dung dch B . S : PH = 0,7 Cu 3 : ( i hc khi A - 2006 ) Nung 6,58 gam Cu(NO3)2 trong bnh kn , sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X . Hp th hon ton hn hp X vo nc c 300 ml dung dch Y . Vit phng trnh ho hc ca cc phn ng xy ra v tnh PH ca dung dch Y . A.1 B.2 C.3 D.4 Cu 4 :Cho mt lung kh H2 i qua 0,8 gam CuO nung nng . Sau phn ng thy thu c 0,672 gam cht rn . Hiu sut phn ng kh CuO thnh Cu l . A.60 B.80 C.90 D.75 Cu 5 :( i hc khi A - 2007 )Cho 15,6 gam hn hp hai ancol n chc , k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na , thu c 24,5 gam cht rn . Hai ancol l . A.C3H5OH v C4H7OH B.C2H5OH v C3H7OH C.C3H7OH v C4H9OH D.CH3OH v C2H5OH Cu 6 :Dn V lt kh ktc hn hp X gm Axtilen v Hiro i qua ng s ng bt Niken nung nng , thu c kh Y . Dn Y vo lng d AgNO3 ( hoc Ag2O ) trong dung dch NH3 thu c 12 gam kt ta . Kh ra khi dung dch phn ng va vi 16 g Br2 v cn li kh Z . t chy hon ton kh Z thu c 2,24 lt kh CO2 ktc v 4,5 gam nc . Ga tr ca V bng . A.11,2 l B.13,44 l C.5,6 l D.8,96 l Cu 7 :Cho 9,86 gam hn hp gm Mg v Zn vo mt cc cha 430 ml dung dch H2SO4 1M . Sau khi phn ng hon ton thm tip vo cc 1,2 lt dung dch hn hp gm Ba(OH)2 0,05M v NaOH 0,7M , khuy u cho phn ng hon ton ri lc ly kt ta v nung n lng khng i th thu c 26,08 gam cht rn . Tnh khi lng mi kim loi trong hn hp u . S.Mg : 7,26 , Zn : 2,6 Cu 8 :xi ho 4 gam ru n chc Z bng O2 c mt xc tc thu c 5,6 gam hn hp X gm anhit , ru d v nc . Tn ca ru v hiu sut phn ng l . A.Mtanol , 75% B.Etanol , 75% C.Propanol-1 , 80% D.Metanol ,
Page | 13

80% Cu 9 :Cho 35,2 gam hn hp gm 2 este no n chc l ng phn ca nhau c t khi hi i vi H2 bng 44 tc dng vi 2 lt dung dch NaOH 0,4M , ri c cn dung dch va thu c , ta c 44,6 gam cht rn B. Cng thc cu to este l . B.C2H5COOCH3,CH3COOC2H5 A.HCOOC2H5,CH3COOCH3 C.HCOOC3H7,CH3COOC2H5 D.HCOOC3H7,CH3COOCH3 Cu 10 :Hp th hon ton 3,36 lt CO2 ktc vo 500 ml dung dch NaOH a M thu c dung dch c kh nng hp th ti a 2,24 lt CO2 ktc . Tnh gi tr ca a . A.0,4 B.0,5 C.0,6 D.0,8 Cu 11 :Dn 5,6 lt kh CO2 ktc vo bnh cha 200 ml dung dch NaOH nng a M , dung dch thu c c kh nng tc dng ti a 100 ml dung dch KOH 1M . Ga tr ca a l . A.0,75 B.1,5 C.2 D.2,5

DNG 8 :

BI TON CO2

Cu 1:Cho 1,568 lt CO2 ktc li chm qua dung dch c ha tan 3,2 gam NaOH . Hyxc nh khi lng mui sinh ra ? Cu 2 :Cho 1,568 lt CO2 ktc li chm qua dung dch c ha tan 3,2 gam NaOH . Hy xc nh khi lng mui sinh ra ? Cu 3 :Cho 6 lt hn hp kh CO2 v N2 ktc i qua dung dch KOH to ra c 8,07 g hai mui . Hy xc nh thnh phn phn trm ca CO2 trong hn hp bn u Cu 4 :Cho 8 lt hn hp kh CO v CO2 trong CO2 chim 39,2 % i qua dung dch c cha 7,4 gam Ca(OH)2 . Hy xc nh s gam kt ta thu c sau phn ng ? Cu 5 :Cho m gam tinh bt ln men thnh ancol etylc vi hiu sut 81% .Ton b lng CO2 vo dung dch Ca(OH)2 thu c 550 gam kt ta v dung dch X un k dung dch X thu thm c 550 gam kt ta . Ga tr ca m l ? Cu 6 :Hp th hon ton 2,688 lt kh CO2 ktc vo 2,5 lt dung dch Ba(OH)2 nng a mol/l , thu c 15,76 gam kt ta .Ga tr ca a l ? Cu 7 :Cho 3,36 lt kh CO2 ktc vo 200 ml dung dch cha NaOH 1M v Ba(OH)2 0,5M . Khi lng kt ta thu c sau phn ng l ? Cu 8 :Dn 5,6 lt CO2 hp th hon ton vo 500 ml dung dch Ca(OH)2 nng a M th thu c 15 gam kt ta . Ga tr ca a l ? Cu 9 :Dn 112 ml CO2 ktc hp th han ton vo 200 ml dung dch Ca(OH)2 thu c 0,1 gam kt ta . Nng mol ca nc vi trong l ? Cu 10 :Dn 5,6 lt CO2 hp th hon ton vo 200 ml dung dch NaOH nng a M thu c dung dch c kh nng tc dng ti a 100 ml dung dch KOH 1M . Tnh a ?
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Cu 11. Cho ton 0,448 lt kh CO2 (ktc) hp th hon ton bi 200 ml dung dch Ba(OH)2 thu c 1,97 gam kt ta. Hy la chn nng mol/l ca dung dch Ba(OH)2. A. 0,05M B. 0,1M C. 0,15M D. p n khc. Cu 12. Cho 3,36lt kh CO2 (ktc) hp th bng 100 ml dung dch NaOH 1M v Ba(OH)2 1M th thu c bao bao nhiu gam kt ta. A. 19,7 gam B. 24,625 gam C. 14,775 gam D. c A, B u ng. Cu 13. Hn hp X gm 2 mui cacbonat ca 2 kim loi thuc 2 chu k lin tip ca phn nhm chnh nhm II. Ha tan ht 41,8 gam hn hp A trong dung dch HCl thu c kh B. Cho ton b kh B hp th vo 500 ml dung dch Ba(OH)2 1M. Lc b kt ta , ly dung dch nc lc tc dng vi lng d dung dch Na2SO4 th thu c 11,65 gam kt ta. Xc nh cng thc ca 2 mui. A. BeCO3 v MgCO3 B. MgCO3 v CaCO3 C. CaCO3 v SrCO3 D. c A, B u ng Cu 14. Dn kh CO i qua 20 gam CuO nung nng thu c cht rn X v kh CO2. Hp th hon ton kh CO2 sinh ra bng 300 ml dung dch Ba(OH)2 1M th thu c 39,4 gam kt ta. Cho cht rn X vo dung dch AgNO3 d thu c m gam kt ta. Tnh m. A. 43,2 gam B. 47,2 gam C. 86,4 gam D. c B v C

Cu 15 : Mt bnh cha 15 lt dd Ba(OH)2 0,01M. Sc vo dd V lt kh CO2 (ktc) ta thu c 19,7g kt ta trng th gi tr ca V l: A. 2,24 lt B. 4,4 lt C. 2,24 lt v 1,12 lt D. 4,4 lt v 2,24 lt Cu 16 : 2003 A Kh hon ton 4,06 gam mt xit kim loi bng CO nhit cao thnh kim loi . Dn ton b khi ssinh ra vo bnh ng dung dch Ca(OH)2 d , thy to thnh 7 gam kt ta . Nu ly lng kim loi sinh ra ha tan ht vo dung dch HCl d th thu c 1,176 lt kh H2 ktc . 1.Xc nh cng thc oxit kim loi 2.Cho 4,06 gam oxit kim loi trn tc dng hon ton vi 500 ml dung dch X v c kh SO2 bay ra . Hy xc nh nng mol/l ca mui trong dung dch X .

DNG 9 :

TRUNG HA IN

L thuyt : Mt dung dch tn ti cc ion : Aa+ ( m mol ) , Bb+( n mol ) v cc aninon Cc-(x mol ), Dd-(y mol) Ta c phng trnh trung ho in :

a .m + b.n x.c y.d = 0

Cc v d n gin : VD 1 : Dung dch tn ti cc ion sau : Al3+ : 0,5 mol ; Fe3+ : 0,5 mol ; NO3- : 0,5 mol ; SO42- : x mol Tnh x : VD 2 : Dung dch A c cha cc ion Ba2+ , Ca2+ , NO3- : 0,2 mol , Cl- : 0,2 mol . Tnh th tch ca MgSO4 2M va to kt ta ht vi cc ion c trong dung dch . S : V = 100 ml VD 3 : Dung dch A c cha cc ion : Ca2+ : 0.2 mol , Na+: 0.2 mol v cc anion Cl- : a
Page | 15

mol v NO3- b mol . Khi c cn thu c 36.55 gam . Tnh a , b S : a = 0.5 ; b = 0.1 Luyn tp : Cu 1 : Mt dung dch tn ti 3 ion : Al3+ ; Cu2+ ; SO42- tc dng va vi 800 ml dung dch Ba(OH)2 0,5M .Thu c kt ta , nung kt ta trong khng kh n khi lng khng i thu c 111,4 gam . Tnh khi lng mui ban u ? p s 50,2 gam Bi 2 : Mt dung dch cha cc ion Fe2+ , Cu2+ , Cl- , cho 1 lng 600 ml dung dch AgNO3 1M phn ng va vi dung dch trn . Thu c 82,55 gam cht rn . Tnh khi lng mui ban u . p s : m = 26,05 gam Cu 3 :Dung dch A cha cc ion Mg2+ , Ca2+ , HCO3- tc dng va vi 400 ml dung dch Ca(OH)2 1M . Sau phn ng ch thu c kt ta v H2O .Tnh khi lng mui ban u. p s m = 30,8 gam . Cu 4 : Dung dch Xc cha cc ion Ca2+ , Al3+, Cl- . lm kt ta ht ion Cl- trong 10 ml dung dch phi dng ht 70 ml AgNO3 1M .Khi c cn dung dch X thu c 35,55 gam mui khan . Tnh nng mol/l ca Ca2+ trong X Cu 5 : Trong 1 dung dch Y c cha cc ion Zn2+ , Fe3+ , (SO4)2- .Bit rng dng ht 350 ml dung dch NaOH 2M th lm kt ta ht ion dng trong 100 ml dd Y nu , thm tip 200 ml dd NaOH th mt cht kt ta va tan ht , cn li mt cht kt ta . Tnh nng ca Fe3+ trong dd Y ? Cu 6 : Dung dch Ba2+ ; OH- : 0,06 v Na+ 0,02 mol vi dung dch cha HCO3- 0,04 mol ; (CO3)2- 0,04 mol v Na+.Khi lng (g)kt ta thu c sau phn ng l ? Cu 7 : m gam hn hp Mg , Al vo 250 ml dung dch X cha hn hp 2 axit HCl 1M v Axit H2SO4 0,5M . Thu c 5,32 lt kh H2 ktc v dung dch Y , coi nh th tch khng di . Dung dch Y c PH l ? Cu 8 :Dung dch X gm c cc ion : Mg2+, Ba2+,Ca2+ v 0,1 mol Cl- , 0,2 mol NO3Thm dn V lt dung dch K2CO3 1M vo dung dch X n khi c lng kt ta ln nht . Ga tr ca V(ml) l ? Cu 9 : 12,9 gam hn hp gm Al v Mg phn ng vi 100 ml dung dch hn hp 2 axit HNO3 4M v H2SO4 7M m c thu c 0,1 mol mi cht kh SO2 ,NO , N2O . Tnh s mol kim loi Al trong hn hp ban u ? Cu 10 : Mt dung dch Y c cha cc ion Zn2+ , Fe3+ , (SO4)2- .Bit rng dng ht 350 ml dung dch NaOH 2M th lm kt ta ht ion dng trong 100 ml dd Y nu , thm tip 200 ml dd NaOH th mt cht kt ta va tan ht , cn li Cu 11 :dung dch Ba(OH)2 n d vo 50 ml dung dch A c cha cc ion NH4+ ,(SO4)2,NO3- . C 11,65 gam kt ta c to ra v un nng th c 4,48 lt kh thot ra Cu 12 : dung dch cha 0,02 mol Cu2+ , 0,03 mol K+ , x mol Cl- , y mol (SO4)2-Tng khi lng cc mui tan c trong dung dch l 5,345 gam . Ga tr ca x v y l : Cu 13 :m gam K vo 300 ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X .Cho t t dung dch X vo 200 ml dung dch Al2(SO4)3 0,1M thu c kt ta Y . thu c kt ta Y ln nht th gi tr ca m l ?
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Cu 14: Kt qu xc nh nng mol/lit ca cc ion trong 1 dd nh sau: Na+: 0,05; Ca2+: 0,01; NO3: 0,01; Cl-: 0,04; HCO3-: 0,025 Hi kt qu ng hay sai A. Sai B. ng C. Khng xc nh c do khng cho th tch dd D. Thiu iu kin tiu chun, khng xc nh c

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DNG 10 :

CU TO NGUYN T

Cu 1 : Cho hai nguyn t c cu hnh electron nguyn t l: + Nguyn t X : 1s22s22p63s2 + Nguyn t Y : 1s22s22p63s23p63d34s2 X v Y c thuc cng mt nhm nguyn t khng ? Gii thch Hai nguyn t ny cch nhau bao nhiu nguyn t ho hc? C cng chu k khng?. Cu 2 :Nguyn t X chu k 3,nhm VA ca bng tun hon. a) Vit cu hnh electron ca X. b)Vit cu hnh electron ca nguyn t nguyn t cng nhm thuc hai chu k k tip ( trn v di ) . Gii thch ti sao li vit c nh vy. Cu 3 : Cho nguyn t X c Z = 30 a)Vit cu hnh electron nguyn t X b)Vit cu hnh electron ca nguyn t nguyn t cng chu k,thuc hai nhm lin tip (trc v sau) vi nguyn t X v hy gii thch v sao li vit c nh vy. Cu 4 : Cho hai nguyn t X v Y hai lin tip nhau trong mt chu k ca bng HTTH v c tng s proton bng 27. Hy vit cu hnh electron nguyn t v xc nh v tr ca chng trong bng HTTH. Cu 5 : Cho hai nguyn t A,B ng k tip nhau trong bng HTTH v c tng s n v in tch ht nhn l 37. a)C th khng nh A,B thuc cng mt chu k khng? Xc nh ZA ,ZB . b)Xc nh v tr ca A, B trong bng TH .Cho bit A,B l kim loi ,phi kim,hay kh him? Cu 6 : Cho 1,2 gam mt kim loi thuc nhm IIA trong bng HTTH tc dng vi HCl thu c 0,672 lt kh (ktc).Tm kim loi ,vit cu hnh electron nguyn t,nu r v tr trong bng HTTH. Cu 7 : Cho 0,78 gam mt kim loi nhm IA tc dng vi HCl thu c 0,224 lt kh thot ra (ktc).nh tn kim loi . Cu 8 : Khi cho 5,4 gam mt kim loi M tc dng vi oxi khng kh thu c 10,2 gam 1 oxit M2O3. Tm tn kim loi M. Cu 9 : A l nguyn t chu k 3.Hp cht ca A vi cacbon cha 25 % cacbon v khi lng ,v khi lng phn t ca hp cht l 144 u.nh tn nguyn t A,cng thc phn t ca hp cht . Cu 10 : Mt nguyn t B to thnh 2 loi oxit c cng thc AOx v AOy ln lt cha 50% v 60% oxi v khi lng.Xc nh nguyn t B v cng thc phn t hai oxit. Cu 11 : Cho 8,8 gam hn hp 2 kim loi thuc hai chu k lin tip nhau v thuc nhm IIIA, tc dng vi HCl d th thu c 6,72 lt kh hiro (ktc). Da vo bng tun hon cho bit tn hai kim loi . Cu 12 : Hp cht A c cng thc MXx trong M chim 46,67% khi lng (M l kim loi, X l phi kim chu k 3). Trong ht nhn M c s ntron nhiu hn s proton 4 ht, cn X c s proton bng s ntron. Tng s ht proton ca A l 58. Xc nh M,X,A.

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Cu 13 : X v Y l 2 nguyn t u c hp cht kh vi H l XHa v YHa . Khi lng mol cht ny gp 2 ln khi lng mol cht kia. Khi lng phn t 2 oxit cao nht ca X v Y (X2Ob v Y2Ob) hn km nhau 34 u. a)X,Y l kim loi hay phi kim. b)Xc nh tn X,Y v cng thc phn t cc hp cht ca X,Y. Cu 14 : Tng s ht mang in trong ion AB32 bng 82. S ht mang in trong ht nhn ca nguyn t A nhiu hn s ht mang in trong ht nhn ca nguyn t B l 8. Xc nh s hiu nguyn t ca 2 nguyn t A,B. Vit cu hnh electron ca 2 nguyn t A,B. Xc nh v tr nguyn t A v B trong bng tun hon cc nguyn t ha hc. Cu 15 : X,Y l 2 halogen (thuc nhm VIIA) 2 chu k lin tip . Ha tan 16,15 gam hn hp NaX v NaY vo nc sau cho tc dng vi dung dch AgNO3 d thu c 33,15 gam kt ta. Xc nh tn ca X,Y v phn trm khi lng mi mui trong hn hp u. Cu 16 : Hp cht M to thnh t cation X+ v anion Y3. mi ion u do 5 nguyn t ca 2 nguyn t phi kim to nn.Bit tng s proton trong X+ l 11 v trong Y3 l 47. Hai nguyn t trong Y3 thuc 2 chu k lin tip c s th t cch nhau 7 n v. Hy xc nh cng thc ha hc ca M. Cu 17 : X,Y l 2 nguyn t cng 1 nhm A thuc 2 chu k k tip nhau trong bng tun hon. Tng s ht proton, electron v ntron trong Y l 55 trong s ht mang in nhiu hn s ht khng mang in l 1,75 ln. Hy xc nh s hiu nguyn t X,Y v s khi ca Y. Cu 18 : A,B,X l 3 nguyn t phi kim .Tng s ht proton, ntron,electron trong phn t AX2 l 52. S ht mang in ca AY2 nhiu hn s ht mang in ca AX2 l 28 ht. Phn t X2Y c tng s ht proton,electron v ntron l 28 trong s ht mang in bng 2,5 ln s ht khng mang in. a)Xc nh in tch ht nhn v s khi ca A,X,Y. b)Xc nh v tr ca A,B,X trong bng tun hon. Cu 19 : C hp cht MX3 trong : Tng s proton, ntron, elctron l 196. S ht mang in nhiu hn s ht khng mang in l 60. S khi ca M nh hn s khi ca X l 8. Tng s proton, ntron, elctron trong X nhiu hn trong ion M3+ l 16. Xc nh v tr ca M v X trong bng tun hon Cu 20 : X,Y,Z l 3 nguyn t phi kim ln lt nhm VA, VIA, VIIA. Oxit cao nht ca X c s ht mang in gp 2,5 ln s ht mang in ca oxit cao nht ca Y. S ht mang in ca oxit cao nht ca Z nhiu hn ln s ht mang in ca oxit cao nht ca Y l 28. S ht mang in ca 3 nguyn t X,Y,Z bng s ht mang in ca oxit cao nht ca Y. Xc nh s th t ca X,Y.

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DNG 11 :

BI TON KH N2 , NO2 , Cl2

KH NITO

Dng I : Hiu sut phn ng Cu 1: Mt hn hp A gm hai kh N2 v H2 theo t l mol 1 : 3 cho chng phn ng vi nhau to NH3 .Sau phn ng thu c hn hp kh B . T khi hi ca A i vi B l 0,6 .Tnh hiu sut phn ng tng hp NH3 . Cu 2: Cho mt bnh kn dung tch 112 lt trong cha N2 v H2 theo t l th tch 1:4 OoC v 200 at ( xc tc thch hp ) nung nng bnh mt thi gian sau a v nhit OoC thy p sut trong bnh gim 10% so vi p sut ban u . a) Tnh H % phn ng . b)Nu ly 12,5% lng NH3 to thnh iu ch c bao nhiu lt dung dch NH3 25% ( d= 0,907 g/ml Cu 3: un nng hn hp gm 200 gam NH4Cl v 200 gam CaO .T lng kh NH3 to ra iu ch c 224 ml dung dch NH3 30% ( d= 0,829 g/ml ) . Tnh H% phn ng un nng . Cu 4: Nn mt hn hp gm 4 lit N2 v 14 lit H2 trong bnh phn ng ( to >400 oC v xc tc thch hp ) .Sau phn ng thu c 16,4 lit hn hp kh ( cng k to v p ) . Tm H% . Cu 5 : T 112 lit N2 v 392 lit H2 to ra c 34 gam NH3 .Tnh H % phn ng ( V o ktc ) Cu 6 : Cn ly bao nhiu lit N2 v H2 to ra c 201,6 lit NH3 .Bit H% =18% ( V o ktc) . Cu 7: Lng NH3 tng hp c t 28 m3 hn hp N2 v H2 (ktc) c t l th tch l 1: 4 , em iu ch dung dch NH3 20% , d= 0,925 kg/l . Tnh th tch dung dch NH3 thu c bit H%=96% . Cu 8: Trong mt bnh kn cha 90mol N2 v 310 mol H2 , lc u c p sut bng p=200 atm . Nhit gi cho khng i n khi phn ng t n trng thi cn bng . Tnh p sut ca hn hp kh khi . Bit H%=20% . Cu 9: Hn hp kh N2 v H2 c t l th tch l 1:4 c nn ti p sut 252,56 atm v dn vo bnh phn ng c dung tch 20 lit, nhit trong bnh l 497 oC c gi khng i trong qu trnh phn ng . a)Tnh s mol N2 v H2 c lc u . b)Tnh s mol mi kh khi phn ng t ti trng thi cn bng bit H%=25% . c)Tnh p sut ca hn hp kh khi . Cu 10 : Mt hn hp kh gm N2 v H2 c t khi i vi H2 bng 3,6 .Sau khi un nng mt thi gian h t ti trng thi cn bng th t khi ca hn hp sau phn ng i vi H2. bng 4,5 a)Xc nh %V hn hp trc v sau phn ng . b) Tnh H% .
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DNG II : Xc nh thnh phn hn hp kh v p sut Cu 1 : Mt bnh kn dung tch 14 lit cha 14gam Nit Oo C . Tnh p . Cu 2: Trn 50 lit hn hp kh gm NO v N2 c t l s mol l 1:1 vi 50 lit khng kh .Tnh th tch kh NO2 to ra . (cc th tch kh o cng k ) Cu 3: Trn ln 60ml NH3 v 60ml O2 ri cho i qua ng ng cht xc tc Pt ( nhit cao). Hn hp kh i ra c lm ngui ,hi nc ngng t . Tnh %V mi kh trong hn hp cn li Cu 4: Thc hin phn ng vi 17,92 lit NH3 v 120 gam CuO . a)Tnh th tch N2 .(ktc) b)Tnh th tch dung dch H2SO4 ,n c nng 55% v d=1,427 g/ml lm tan ht cht rn thu c sau phn ng . Cu 5: Dung dch NH3 25% c d= 0,91 g/ml . a)Trong 100ml dung dch c ha tan bao nhiu lit NH3 (ktc) . b)Tnh th tch dung dch NH3 lm kt ta ht cation Al 3+ c trong 100ml dung dch Al2 (SO4 )3 1,115 M . Cu 6: Dn 8,96lit NH3 (ktc) cho tan vo 200ml dung dch H2 SO4 1,5M .Tnh nng cc mui c trong dung dch thu c . Cu 7: Ngi ta iu ch axit nitric t nguyn liu chnh l N2 . Ngi ta phi dng ht 168ml N2 (ktc) . Tnh khi lng dung dch HNO3 50,4% thu c. Cu 8 : Ngi ta iu ch axit nitric t nguyn liu chnh l N2 .Ngi ta phi dng ht 168 ml N2 (ktc ) vi H% = 80% . Tnh khi lng dung dch HNO3 50,4% thu dc . Cu 9: un nng 127 gam hn hp hai mui (NH4 )CO3 v NH4HCO3 hn hp phn hy ht thnh kh v hi nc . Lm ngui sn phm n 27 oC thu c 86,1 lit hn hp kh , di p sut 1 atm .Tnh t l s mol hai mui trong hn hp . Cu 10 : Hn hp kh N2 v H2 c t khi vi H2 bng 4,25 .Tnh %V mi kh trong hn hp . Cu 11 : A v B l hai oxit ca Nit c cng %N = 30,45% . Bit A c t khi so vi O2 bng 1,4375 . B to thnh t hai phn t A ha hp vi nhau . Xc nh CTPT ca A v B. Cu 12 : Mt bnh kn cha 4mol N2 v 16mol H2 c p sut l 400atm khi t trng thi cn bng th N2 tham gia phn ng l 25% . Cho nhit bnh gi khng i . a)Tnh s mol kh sau phn ng . b) Tnh p sut hn hp kh sau phn ng . KH CLO Cu 13 : Sc kh Clo vo dd NaBr v NaI n phn ng hon ton ta thu c 1,17g NaCl. S mol hn hp NaBr v NaI c trong dd ban u l: A. 0,1 mol B. 0,15 mol C. 1,5 mol D. 0,02 mol Cu 14 : Dn hon ton 0,112 lt kh Cl2 vo 200 ml dung dch NaOH nhit thng . Sau phn ng , nng NaOH cn li l 0,05 M gi thit th tch dung dch khng thay i . Nng ban u ca dung dch NaOH l ( Cho Cu = 64 )
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A.0,2 M B.0,15 M C.0,05 M D.0,1 M Cu 15 : Khi cho 10,5 gam NaI vo 50 ml dung dch Br2 0,5M , khi lng NaBr thu c l : A.10,5 g B.4,67 g C.5,15 g D.2,575 g Cu 16 : Ho tan hon ton 104,25 gam hn hp X gm NaCl , NaI vo nc c dung dch . Sc kh Cl2 d vo dung dch A Kt thc th nghim , c cn dung dch thu c 58,5 gam mui khan . Khi lng NaCl c trong hn hp X l : A.29,25 gam B.58,5 g C.17,55 g D.23,4 g Cu 17 : Dn hai lung kh Cl2 i qua 2 dung dch KOH , dung dch (I) long ngui , dung dch (II) m c , nng . Nu lng mui KCl sinh ra trong hai dung dch bng nhau th t l th tch kh Cl2 i qua 2 dung dch KOH (I) v (II ) l ? A.5/6 B.6/3 C.10/3 D.5/3 Cu 18 : Cho 13,44 lt kh Clo ktc i qua 2,5 lt dung dch KOH 100o C . Sau phn ng xy ra hon ton , thu c 37,25 gam KCl Dung dch KOH trn c nng l ( Cl = 35,5 , K = 39 ) . A.0,24 M B.0,2 M C.0,48 M D.0,4 M

DNG 12 :

BI TON NHIT NHM

Cu 1 : t nng mt hn hp gm bt Al v Fe3O4 trong mi trng khng c khng kh , nhng cht cn li sau phn ng nu cho tc dng vi dung dch NaOH d s to ra 6,72 lt kh H2 ktc . Nu cho hn hp trn tc dng vi dung dch HCl th s thu c 26,88 lt kh H2 . Tnh s gam tng cht c trong hn hp ban u . Cu 2 : Tin hnh nhit nhm vi Fe2O3 trong iu kin khng c khng kh. Chia hh thu c thnh 2 phn sau khi trn u. Phn 2 hn phn 1 l 134 gam. Cho phn 1 tc dng vi NaOH thy c 16,8 lt kh H2 thot ra (kc). Ho tan phn 2 bng lng d HCl thy c 84lt H2 (kc). Cc phn ng xy ra hon ton. Xc nh khi lng ca Fe thu c v khi lng Al ban u. Cu 3 :Cho hn hp A c khi lng m gam gm bt Al v xt FexOy . Tin hnh phn ng nhit nhm hn hp A trong iu kin khng c khng kh , hn hp B . Nghin nh , trn u B ri chia thnh hai phn . Phn 1 c khi lng 14,49 gam c ha tan ht trong dung dch HNO3 un nng , c dung dch C v 3,696 lt kh NO duy nht ktc . Cho phn 2 tc dng vi lng d dung dch NaOH un nng thy gii phng 0,336 lt kh H2 ktc v cn li 2,52 gam cht rn . Cc phn ng u xy ra han ton . 1 Vit cc phng trnh phn ng xy ra 2. Xc nh cng th ca st .

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DNG 13 :

CC BI TP ST

Cu 1 :Cho 16,8 gam bt st vo 800 ml dung dch HNO3 0,5 M thu c kh NO duy nht . Tnh : Th tch kh thu c Tnh khi lng kim loi cn d . Khi lng mui thu c S : V = 2.24 lt , m kim loi d = 8.4 g , m Fe(NO3)2 = 27 g Cu 2 :Cho 16,8 gam bt st vo V lt dung dch HNO3 0,5 M thu c 8,4 gam kim loi d . Tnh th tch kh thu c . S : V = 2.24 l Cu 3 :Cho 16,8 gam bt Fe vo 400 ml dung dch HNO3 1M , thu c kh NO duy nht , lng mui thu c cho vo dung dch NaOH d thu c kt ta . Nung nng kt ta thu c m gam cht rn . Tnh m ? S : m FeO = 10.8 gam Cu 4 :Cho m gam Fe vo 400 ml dung dch HNO3 1M thu c V lt kh NO duy nht v 14 gam kim loi . Tnh m ? V ? S : m = 22.4 gam , V = 2,24 lt Cu 5 :Cho m gam Fe vo 800 ml dung dch HNO3 1M thu c V lt kh NO v dung dch A . Cho dung dch A tc dng vi dung dch NaOH d thu c kt ta B . em nung B trong khng kh thu c 18,8 gam cht rn . Tnh V ? m ? S : m = 14 gam , V = 2.24 lt Cu 6 :Cho 5,6 gam bt Fe tc dng vi 500 ml dung dch AgNO3 0,5 M . Tnh : khi lng mui thu c khi lng kim loi thu c S : m mui = 21.1 gam , m Ag = 27 gam Cu 7 : Cho m gam bt Fe tc dng vi 250 ml dung dch AgNO3 1M thu c dung dch A , cho ton vo dung dch A mt lng KOH d thu c kt ta , nung kt ta trong chn khng thu c 7,6 gam cht rn .Tnh m ? Cu 8 : 2002 A Cho 18,5 gam hn hp Z gm Fe , Fe3O4 tc dng vi 200 ml dung dch HNO3 long un nng v khuy u . Sau phn ng xy ra han ton thu c 2,24 lt kh NO duy nht ktc , dung dch Z1 v cn li 1,46 gam kim loi . 1.Vit phng trnh phn ng ha hc xy ra 2.Tnh nng mol/lit ca dung dch HNO3 3.Tnh khi lng mui trong dung dch Z1 Cu 9 : Kh 4,8 gam mt oxit ca kim loi trong dy in ha nhit cao cn 2,016 lt kh H2 ktc . Kim loi thu c em ha tan trong dung dch HCl thu c 1,344 lt kh H2 ktc . Hy xc nh cng thc ha hc ca oxit dng . Cu 10 : Mt dung dch c ha tan 1,58 gam KMnO4 tc dng vi dung dch hn hp c ha tan 9,12 gam FeSO4 v 9,8 gam H2SO4 . Hy tnh s gam cc cht c trong dung dch sau phn ng .
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Cu 11:Hn hp X gm Cu v Fe c t l khi lng tng ng l 7:3 . Ly m gam X cho phn ng xy ra hon ton vi dung dch cha 44,1 gam HNO3 sau phn ng cn li 0,75m gam cht rn v c 0,56 lt kh Y gm NO v NO2 ktc . Ga tr ca m l ? S : m = 50,4 gam

DNG 14 :

BI TP V HNO3 V MUI NITRAT

Cu 1: Nung nng hn hp 27,3 gam hn hp NaNO3 , Cu(NO3)2 . Hn hp kh thot ra c dn vo 89,2 ml nc th cn d 1,12 lt kh ktc khng b hp th . Tnh khi lng ca mi mui trong hn hp u Cu 2 : Cho bt Cu d vo V1 lt dung dch HNO3 4M v vo V2 lt dung dch HNO3 3M v H2SO4 1M . NO l kh duy nht thot ra . Xc nh mi quan h gia V1 v V2 bit rng kh thot ra hai th nghim l nh nhau . Cu 3 : Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO.Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l (cho Cu = 64) A. V2 = V1. B. V2 = 2V1. C. V2 = 2,5V1. D. V2 = 1,5V1. Cu 4 : Cho 200 ml gm HNO3 0,5M v H2SO4 0,25M tc dng vi Cu d c V lit NO (ktc) c cn dung dch sau phn ng c m gam mui khan . V v m c gi tr ln lt l : A.2,24; 12,7 B.1,12 ; 10,8 C.1,12 ; 12,4 D.1,12 ; 12,7 Cu 5 : Cho 0,96 gam Cu vo 100ml dung dch cha ng thi KNO3 0,08M v H2SO4 0,2M sinh ra V (lit ) mt cht kh c t khi so vi H2 l 15 v dung dch A . V c gi tr l : A. 0,1702 lit B. 0,3584 lit C. 0,448 lit D. 0,336 lit Cu 6 : em nung mt khi lng Cu(NO3)2 sau mt thi gian dng li , lm ngui ri em cn thy khi lng gim 0,54 gam . Vy khi lng mui Cu(NO3)2 b nhit phn l : A.0,5 gam B.0,49 gam C.9,4 gam D.0,94 gam

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CHUYN DCH CN BNG VN TC PHN NG

1.Cch tnh hiu ng nhit : Tnh theo lien kt E Q = Tng E sn phm Tng E ban u Tnh theo sinh nhit : Q = Tng Sn Sn phm Tng Sn ban u Sinh nhit ca n cht bng 0 2.Vn tc tc thi ca phn ng l Xt phn ng : mA+nBpC+qD Vn tc ca phn ng l : V = k . [A]m . [B]n Trong K l hng s tc phn ng , ch ph thuc vo nhit , [] l nng mol/l ca cc cht . A , B l cc cht kh hay dung dch 3.Vn tc trung bnh ca phn ng : v = -1/m . [A2 - A1] /[t2 t1] = 1/p . [C2-C1]/[t2-t1] 4.S ph thuc ca vn tc vo nhit phn ng . Vt2 = Vt1. (t2-t1)/10 . Trong l h s nhit ca phn ng . l s ln tng ca vn tc phn ng khi tng ln 10o C . 5.Phn ng thun nghch v cn bng ha hc Xt phn ng thun nghch : m A + n B p C + q D Vt = Kt . [A]m.[B]n Vn = Kn . [C]p.[D]q T ta c hng s cn bng ca phn ng : Kcb = Kt/Kn = [C]p.[D]q/ [A]m.[B]n Cu 1 : Phn ng gia hai cht kh A , B c biu din bng phng trnh sau A + B = 2C Tc phn ng l V = K . [A].[B] . Thc hin phn ng ny vi s khc nhau v nng ban u mi cht Trng hp 1 : Nng mi cht l 0,01 mol/l Trng hp 2 : Nng mi cht l 0,04 mol /l Trng hp 3 : Nng ca cht A l 0,04 mol/l ca cht B l 0,01 mol/l . Tnh tc ph ng ca mi trng hp . So snh Cu 2 : Tc phn ng ha hc c biu din theo phng trnh v = K . [A]x.[B]y . Giu nng B khng i , tng A ln hai ln th tc phn ng tng 2 ln Giu nng A khng i , tng B ln hai ln th tc phn ng tng 4 ln . hy tnh x , y Cu 3 : Cho phn ng ca cc cht kh sau : Ak + 2Bk Ck + Dk Hi tc phn ng tng hay gim bao nhiu ln i vi mi trng hp sau [A] = 2[A] v [B] = 2[B] [A] = [A] v [B] = 2[B] b.Nu nng ca A , B ban u khng i th tc phn ng (1) tng bao nhiu ln nu nhit tng ln 40 C . Bit rng c tng ln nhit thm 10 C th phn ng tng 2 ln . Cu 4 : Xt phn ng : m A + n B p C + q D TN1 : [A] = 0,5M , [B] = 0,5 M , v1 = 62,5 .10-4 mol/l.S
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TN2 : [A] = 0,5M , [B] = 0,8 M , v2 = 16 .10-3 mol/l.S TN3 : [A] = 0,8M , [B] = 0,8 M , v3 = 2,56 .10-2 mol/l.S a.Da vo cc gi tr trn hy xc nh m , n b.Tnh hng s tc phn ng . Cu 5 : Nng ban u ca SO2 v O2 trong h l SO2 + O2 = SO3 trng ng l 4 mol/l v 2 mol/l A.Tnh hng s cn bng ca phn ng bit rng khi t cn bng c 80% SO2 phn ng B. cn bng c 90% SO2 phn ng th lng oxi lc u ly vo l bao nhiu C.Nu tng p sut ln hai ln th cn bng chuyn dch theo chiu no .

DNG 16 :

BI TON TNG GIM KHI LNG

Cu 1 : Cho 1,12 gam bt Fe v 0,24 gam bt Mg tc dng vi 250 ml dung dch CuSO4 khuy nh cho n khi mu xanh mt i . Nhn thy khi lng kim loi sau phn ng l 1,88 gam . Nng mol/l ca dung dch CuSO4 l bao nhiu . A.0,15M B.0,05M C.0,1M D.0,12M Cu 2 : Hai thanh kim loi ging nhau u cng ngun t R v ha tr II v c cng khi lng . Cho thanh th nht vo dung dch Cu(NO3)2 v thanh th hai vo dung dch Pb(NO3)2 . Sau mt thi gian khi s mol 2 mui bng nhau , ly 2 thanh kim loi ra khi dung dch thy khi lng thanh th nht gim 0,2% cn khi lng thanh th hai tng 28,4% . Nguyn t R l nguyn t no di y . Mg , Cu , Fe , Zn Cu 3 : Hai thanh kim loi cng cht c khi lng bng nhau . Mt c ngm trong dung dch CuCl2 , mt c ngm trong dung dch CdCl2 . Sau mt thi gian phn ng , ngi ta nhn thy khi lng l kim loi ngm trong dung dch CuCl2 tng 1,2 % v khi lng l kim loi kia tng 8,4% . Bit s mol CuCl2 v CdCl2 trong hai dung dch gim nh nhau v kim loi b oxi ha thnh ion kim loi c in tch +2 . Tm kim loi dng . Cu 4 : Ngm mt l Zn kim loi vo dung dch c cha 8,32 gam CdSO4 , sau khi phn ng dung dch khng cn Cd2+ th thy thanh kim loi tng 2,35% so vi ban u . Khi lng Zn ban u l . A.81g B.8 g C.13 g D.80 g

DNG 17 :

BI TON NNG PHN TRM

Cu 1 : Ha tan hon ton 10,2 gam oxit kim loi kim loi ha tr III cn 331,8 gam dung dch H2SO4 th va . Dung dch sau phn ng c nng 10% . Cng thc phn t ca oxit kim loi l . A.Fe2O3 B.Al2O3 C.Cr2O3 D.Mn2O3 Cu 2 : Ha tan mt kim loi M ha tr II vo dung dch HCl 14,6% c dung dch mui c nng 18,19% . Tm M
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Cu 3 : Ha tan va mt hidroxit ca kim loi M c ha tr II trong dung dch H2SO4 20% thu c dung dch mui c nng 27,21% . Tm M Cu 4 : Cho mt l ng c khi lng 10 gam vo 250 gam dung dch AgNO3 4% . Khi ly l ng ra th khi lng mui AgNO3 trong dung dch gim 17% . Khi lng l ng sau phn ng l bao nhiu Cu 5 : Ha tan 20 gam mui K2SO4 vo 150 gam nc c dung dch A , in phn dung dch A vi in cc tr cho n khi c dung dch c nng phn trm l 14,925% . Th tch kh sinh ra anot ( 20 C , 1 atm ) l bao nhiu . Cu 6 : Cho dung dch Axit axetic c nng x % tc dng va vi dung dch NaOH nng 10% th c dung dch mui c nng 10,25% . Tnh X A.29 B.62 C.30 D.65 Cu 7 :Ho tan hon ton hn hp X gm Fe , Mg bng mt lng va dung dch HCl 20% , thu c dung dch Y . Nng ca FeCl2 trong dung dch Y l 15,76 % . Nng % ca MgCl2 trong dung dch Y l ? A.11,79% B.24,24% C.28,21% D.15,76%

DNG 18 :

NHIU KIM LOI + NHIU MUI

Cu 1 :Cho 40 gam hn hp Mg v Fe vo 2.4 lit dung dch AgNO3 0.5 khi phn ng xong thu c 126.4 gam hn hp 2 kim loi . Vy Fe chim : A. 58.34% B.70 % C.79.2% D.Kt qu khc Cu 2 :Cho m gam hn hp Mg v Fe vo 0.8 lit dung dch AgNO3 0.5 M khi phn ng xong thu c 78.4 gam hn hp 3 kim loi . Ga tr ca m l : A. 40 B.41.66 C.72 D.Kt qu khc Cu 3 :Cho mt hn hp gm 0,03 mol Al v 0,05 mol Fe tc dng vi 100 ml dung dch cha AgNO3 v Cu(NO3)2, khuy k cho ti phn ng hon ton. Sau phn ng thu c dung dch A v 8,12 gam cht rn B gm 3 kim loi. Ha tan cht rn B bng dung dch HCl d thy bay ra 672 ml kh H2. Tnh nng mol ca AgNO3 v Cu(NO3)2 trong dung dch ban u ca chng. Bit cc phn ng xy ra hon ton. A.0,25M v 0,4M B. 0,35M v 0,5M C. 0,55M v 0,12M D. Kq khc

DNG 18 :

BI TON LIN QUAN N PH

Cu 1 : Cho hng s axit ca CH3COOH l 1,8.10-5 . PH ca dung dch CH3COOH 0,4M l . A.0,4 B.2,59 C.4 D.3,64 Cu 2 : Pha thm 40 cm3 nc vo 10 cm3 dung dch HCl c PH = 2 c mt dung dch mi c PH bng bao nhiu . A.2,5 B.2,7 C.5,2 D.3,5 Cu 3 : Cho 150 ml dung dch HCl 2M tc dng vi 50 ml dung dch NaOH 5,6M . Dung dch sau phn ng c PH bng bao nhiu . A.1,9 B.4,1 C.4,9 D.1
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Cu 4 : Trn 500 ml dung dch HCl 0,02M tc dng vi 500 ml dung dch NaOH 0,018M dung dch sau phn ng c PH l bao nhiu . Cu 5 : Cn thm bao nhiu ln th tch nc V2 so vi th tch ban u V1 pha long dung dch c PH = 3 thnh dung dch c PH = 4 . C.V1 = V2 D.V1 = 3V2 A.V2 = V1 B.V1 = 1/3 V2 Cu 6 : Trn 100 ml dung dch Ba(OH)2 0,5M vi 100 ml dung dch KOH 0,5M c dung dch A . Nng mol/l ca ion trong dung dch . A.0,65M B.0,55M C.0,75M D.0,85M Cu 7 : C dung dch H2SO4 vi PH = 1 . Khi rt t t 50 ml dung dch KOH 0,1M vo 50 ml dung dch trn . Nng mol./l ca dung dch thu c l A.0,005M B.0,003M C.0,25M D.0,025M Cu 8 :Trn V1 ml dung dch gm NaOH 0,1M , v Ba(OH)2 0,2 M vi V2 ml gm H2SO4 0,1 M v HCl 0,2 . M thu oc dung dch X c gi tr PH = 13 . Tnh t s V1 : V2 A.4/5 B.5/4 C.3/4 D.4/3 Bi 9 :Cho m gam hn hp Mg , Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M thu c 5,32 lt kh H2 ktc v dung dch Y . Tnh PH ca dung dch Y ( Coi dung dch c th tch nh ban u ) s : PH = 1 Bi 10 :Trn 100 ml dung dch gm Ba(OH)2 0,1M v NaOH 0,1M vi 400 ml dung dch gm H2SO4 0,0375 M v HCl 0,0125 M thu c dung dch X . Tnh PH ca dung dch X. Cu 11 : X l dung dch H2SO4 0,02 M . Y l dung dch NaOH 0,035 M . Khi trn ln dung dch X vi dung dch Y ta thu c dung dch Z c th tch bng tng th tch hai dung dch mang trn v c PH = 2 . Coi H2SO4 in li hon ton hai nc . Hy tnh t l th tch gia dung dch X v Y . Cu 12 : Thm t t 400 g dung dch H2SO4 49% vo nc v iu chnh lng nc c ng 2 lit dung dch A . Coi H2SO4 in hon ton c hai nc . 1.Tnh nng mol ca ion H+ trong dung dch A . 2.Tnh th tch dung dch NaOH 1,8M them vo 0,5 lit dung dch A thu c . A.dung dch c PH = 1 . B.Dung dch thu c c PH = 13 . Cu 13 : Trn 250 ml dung dch hn hp HCl 0,08 mol/l v H2SO4 0,01 mol /l vi 250 ml dung dch Ba(OH)2 c nng x mol /l thu c m gam kt ta v 500 ml dung dch c p H = 12 . Hy tnh m v x . Coi Ba(OH)2 in li hon ton c hai nc . Cu 14 :Trn 300 ml dung dch NaOH 0,1 mol/lit v Ba(OH)2 0,025 mol/l vi 200 ml dung dch H2SO4 nng x mol /lit Thu c m gam kt ta v 500 ml dung dch c PH = 2 . Hy tnh m v x . Coi H2SO4 in li hon ton c hai nc .

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