TRNG THPT CHUYN

NGUYN HU
THI TH I HC LN III- NM 2014
M! H"# $%&
Thi gian lm bi: 90 pht;(60 cu trc nghim)
M' () *$+ 1,2
Cho khi l!"ng ngu#$n t% c&a c'c ngu#$n t: (: ); C: )*; +: ),; -: )6; +a: *.;/g: *,;0l: *1;
2: .*; Cl: .343; 5: .9; Ca:,0; Cr:3*; /n: 33; 67: 36; +i: 39; Cu: 6,; 8n: 63;9r: :0; 9a: ).1;
0g: )0:; 2n: ))9;
I. Phn chung cho tt c cc th sinh( 40 cu, t cu {<1>} n cu {<40>}
C-. 1! Cho hn hp X gm ancol benzylic, metanol, propenol v etilen glicol tc dng ht vi Na th
!"c #,$%% l&t '
(
)* !+tc,- ./t +hc, !0t chy hon ton m gam X th !"c 1,2%3 l&t +h& C4
(
)* !+tc, v
5,53 gam '
(
4- 6i tr7 c8a m l
/0 1,(3- 10 5,1%- C0 5,93- 20 %,3(-
C-. 2! Chia 2,#1 mol hn hp X gm hai an!ehit !:n ch;c < v hai ch;c = ) .
<
> .
=
, thnh hai ph?n
b@ng nha- 'i!ro hAa ph?n # c?n vBa !Cng $,53% l&t '
(
) !+tc,- Cho ph?n ( tc dng vi mDt l"ng d"
dng d7ch <gN4
$
E N'
$
th !"c (5,F( g <g v 3,5( g hn hp hai m0i amoni c8a hai aGit hH c:- Cc
phIn ;ng GIy ra hon ton- Jhnh ph?n K +h0i l"ng c8a < trong hn hp X lL
/0 %F,#(K 10 52,33K C0 $%,2FK 20 15,F#K
C-. ,! Mn nAng #2,9# gam hn hp X gm propyl clora v phenyl clora vi dng d7ch Na4' loNng,
vBa !8 v !n nAng, Oa !A thPm tip dng d7ch <gN4
$
!n d" vo hn hp Oa phIn ;ng th !"c 3,1#
gam +t t8a, cc phIn ;ng GIy ra hon ton- Qh0i l"ng phenyl clora cA trong hn hp X l
/0 (,9# gam- 10 %,2 gam- C0 %,9# gam 20 1,2 gam-
C-. 4! 'p chRt hH c: X cA cSng th;c phTn tU C
F
'
#1
4
%
- Qhi th8y phTn trong mSi tr"Vng +iWm th !"c
mDt m0i m tB m0i ny !iW ch trXc tip !"c aGit dYng OIn GRt t: nilonZ1,1- [0 cSng th;c cR t\o
thoI mNn l
/0 %- 10 (- C0 $- 20 #-
C-. 3! Jrong cc pht bi] Oa L
)#, Jheo chiW t^ng d?n !i_n t&ch h\t nhTn, cc +im lo\i +iWm th` )tB =e !n =a, cA nhi_t !D nAng chIy
giIm d?n-
)(, Qim lo\i .g cA +i] m\ng tinh th] lap ph":ng tTm di_n-
)$, Cc +im lo\i Na, =a, =e !W tc dng vi n"c * nhi_t !D th"Vng-
)%, Qim lo\i .g tc dng vi h:i n"c * nhi_t !D cao-
)5, Jrong cSng nghi_p, +im lo\i <l !"c !iW ch b@ng ph":ng php !i_n phTn <l
(
4
$
nAng chIy-
)1, Qim lo\i <l tan !"c trong dng d7ch 'N4
$
!/c, ngDi-
45 6$7* 8+9. (:; <=
/0 , 10 4 C0 30 20 2
C-. >! Jh8y phTn hon ton m
#
gam eOte X m\ch h* b@ng dng d7ch Na4' d", th !"c m
(
gam ancol b
)+hSng cA +hI n^ng phIn ;ng vi C)4',
(
, v #5 gam hn hp m0i c8a hai aGit cacboGylic !:n ch;c-
M0t chy hon ton m
(
gam b b@ng oGi d", th !"c 2,$ mol C4
(
v 2,% mol '
(
4- 6i tr7 c8a m
#
l
/0 ##,1- 10 #1,(- C0 #2,1- 20 #%,1-
C-. ?! 'p chRt X cA vcng benzen v cA cSng th;c phTn tU l C
G
'
y
4
(
- =it trong X cA t`ng O0 liPn +t d
l (2- 4Gi hAa X trong !iW +i_n th&ch hp th !"c chRt b cA cSng th;c phTn tU l C
G
'
yZ%
4
(
- 'Ny cho bit
X cA bao nhiP cSng th;c cR t\oe
/0 ( 10 5 C0 $ 20 %
C-. @! Cho chRt X vo dd Na4' !n nAng th !"c +h& b f cho chRt rgn X vo dng d7ch 'Cl Oa !A cho
C vo thRy C tan ra v cA +h& +hSng m bay lPn hAa nT trong +hSng +h&- Nhi_t phTn X trong !iW +i_n
th&ch hp th !"c mDt oGit phi +im- hay X l chRt no Oa !Ty e
/0 N'
%
N4
$
0 10 N'
%
N4
(
- C0 )N'
%
,
(
[- 20 )N'
%
,
(
[4
%
-
C-. A! Cho m gam hp chRt hH c: X cA cSng th;c phTn tU l C
$
'
1
4
(
tc dng hon ton vi (22 ml dng
d7ch Q4' 2,9. th !"c dng d7ch b- CS c\n b th !"c #(,33 gam chRt rgn +han- CSng th;c cR t\o
c8a X v gi tr7 c8a m l
/0 C
(
'
5
C44' v 3,33 gam- 10 C
(
'
5
C44' v 1,11 gam-
Jrang #E1 Z .N !W thi #$(
C0 C'
$
C44C'
$
v 1,11 gam- 20 'C44C'
(
C'
$
v 3,33 gam-
C-. 10! Cho m gam ie vo dng d7ch ch;a !ng thVi '
(
[4
%
v 'N4
$
th !"c dng d7ch X v %,%3 l&t
N4)dy nhRt,- JhPm tip '
(
[4
%
vo X thj l\i th !"c thPm #,9F( l&t +h& N4 dy nhRt nHa v dng d7ch
b- kng d7ch b ho tan vBa ht 3,$( gam C +hSng cA +h& bay ra )cc +h& !o * !+tc,- Qh0i l"ng c8a ie
!N cho vo l
/0 #1,(% g- 10 ##,( g- C0 #1,3 g- 20 F,1 g-
C-. 11! Mn nAng hn hp X gm 2,# mol aGetonf 2,23 mol propenalf 2,21 mol iOopren v 2,$( mol hi!ro
cA Ni lm GCc tc th hn hp +h& v h:i b- Jl +h0i c8a b Oo vi +hSng +h& l $95E(2$- 'i_ ORt hi!ro !N
tham gia phIn ;ng cDng l
/0 F$,95K 10 39,5K C0 32K 20 95,1K
C-. 12! Cho ((,9( gam hn hp gm ie, ie4, ie
(
4
$
v ie
$
4
%
phIn ;ng ht vi dng d7ch 'N4
$
loNng d"
th !"c h l&t +h& N4)dy nhRt * !+tc, v dng d7ch X- CS c\n dng d7ch X th !"c 99,%% gam m0i
+han- 6i tr7 c8a h l
/0 (,133 l&t- 10 (,(% l&t- C0 %,%3 l&t- 20 5,1 l&t-
C-. 1,! Cho #9,#5 gam hn hp X gm Na v =a vo n"c th !"c dng d7ch b v $,F( l&t '
(
)!+tc,-
Cho +h& C4
(
vo dng d7ch b- J&nh th] t&ch C4
(
)!+tc, c?n cho vo dng d7ch X !] +t t8a th !"c l ln
nhRt e
/0 (,(% l&t m h m %,%3 l&t 10 (,(% l&t m h m 5,1 l&t
C0 h n (,(% l&t ho/c h n 5,1 l&t 20 $,$1 l&t m h m 5,1 l&t
C-. 14! Nng nAng hn hp gm #5,3 gam Q.n4
%
v (%,5 gam QCl4
$
mDt thVi gian th !"c $1,$ gam
hn hp b gm 1 chRt- Cho b tc dng vi dng d7ch 'Cl !/c d" !n nAng l"ng +h& clo Oinh ra cho hRp
th vo $22 ml dng d7ch Na4' 5. !n nAng th !"c dng d7ch o- CS c\n o !"c chRt rgn +han cc
phIn ;ng GIy ra hon ton- Qh0i l"ng chRt rgn +han th !"c l
/0 #( g 10 F#,3 g C0 ### g 20 9F,3 g
C-. 13! Jrong cc th0c thU OaL )#, dng d7ch '
(
[4
%
loNng, )(, C4
(
v '
(
4, )$, dng d7ch =aCl
(
, )%,
dng d7ch 'Cl- Jh0c thU cA th] dYng phTn bi_t !"c cc chRt rgn riPng bi_t gmL CaC4
$
, =a[4
%
, Q
(
C4
$
, Q
(
[4
%
l
/0 )#, v )(, 10 )(, v )%, C0 )#,, )(,, )%, 20 )#,, )(,, )$,
C-. 1>! hi GCc tc men th&ch hp chRt hH" c: < b7 thp phTn hon ton cho hai aminoaGit thiPn nhiPn X
v b vi tp l_ O0 mol c8a cc chRt trong phIn ;ng nh" OaL# mol < q ( mol '
(
4

( mol X q # mol b-
Jhp phTn hon ton (2,$ gam < th !"c m
#
gam X v m
(
gam b- M0t chy hon ton m
(
gam b c?n 3,%
l&t 4
(
* !+c th !"c #$,( gam C4
(
, 1,$ gam '
(
4 v #,($ l&t N
(
* (9
2
C, # atm- b cA CJrJ trYng vi
CJM6- Xc !7nh X,b v gi tr7 m
#
, m
(
e
/0 N'
(
ZC'
(
ZC44')#5,5g,,, C'
$
ZC')N'
(
,ZC44'f 3,F)g,-
10 N'
(
ZC'
(
ZC'
(
ZC44')#5g, , C'
$
ZC')N'
(
,ZC44'f 3,F)g,-
C0 N'
(
ZC'
(
ZC44')#5g,, C'
$
ZC')N'
(
,ZC44', 3,F)g,-
20 N'
(
ZC'
(
ZC44' )#5g,, C'
(
)N'
(
,ZC'
(
ZC44'f 3,F5)g,-
C-. 1?! 4Gi ho # ancol !:n ch;c b@ng 4
(
cA m/t chRt GCc tc th !"c hn hp X- Chia X thnh ba ph?n
b@ng nha- rh?n # tc dng ht vi Na th !"c 3,F1 l&t '
(
)!+tc, v hn hp b, lm +hS b th !"c %3,3
gam chRt rgn +han- rh?n ( tc dng vi Na'C4
$
d" thj th !"c %,%3 l&t +h& C4
(
)!+tc,- rh?n ba, tc dng
vi <gN4
$
E N'
$
d" th !"c (#,1 g b\c- CJCJ c8a ancol !N dYng lL
/0 C
(
'
$
C'
(
4' 10 C
(
'
5
4' C0 C
(
'
5
C'
(
4' 20 C'
$
4'
C-. 1@! Cho a gam rhStphotriclora )rCl
$
, vo n"c !"c dng d7ch X- M] trng hca ht dng d7ch X c?n
dYng 522 ml dng d7ch Na4' 2,$ .- J&nh ae
/0 $,%$95 g 10 5,#51 g C0 (,$95 g 20 %,#(5 g
C-. 1A! Cho 2,2# mol mDt eOte X phIn ;ng vBa ht vi #22 ml dng d7ch Na4' 2,(., OIn phsm t\o ra
chl gm mDt m0i v mDt ancol !W cA O0 mol b@ng O0 mol eOte, !W cA cR t\o m\ch cacbon +hSng phTn
nhnh- ./t +hc G phcng ho hon ton mDt l"ng eOte X b@ng dng d7ch Q4' vBa !8, thj vBa ht (22
ml Q4' 2,#5. v th !"c $,$$ gam m0i- X lL
/0 ttylenglycol oGalat- 10 Mimetyl a!ipat- C0 Mietyl oGalat 20 ttylenglicol a!ipat-
C-. 20! JhXc hi_n phIn ;ng nhi_t nhSm vi F,11 gam hn hp X gm ie
G
4
y
v nhSm, th !"c hn hp
rgn b- Cho b tc dng vi dng d7ch Na4' d" th !"c 2,19( l&t +h& )!+tc,, dng d7ch k v chRt +hSng
Jrang (E1 Z .N !W thi #$(
tan o- [c C4
(
!n d" vo dng d7ch k luc +t t8a v nng !n +h0i l"ng +hSng !`i !"c 5,# gam chRt
rgn- Cc phIn ;ng GIy ra hon ton- CSng th;c c8a oGit Ogt l
/0 QhSng Gc !7nh !"c 10 ie
(
4
$
C0 ie
$
4
%
20 ie4
C-. 21! Qhi cr^c+inh d? mv ng"Vi ta th !"c hn hp ( hi!rocacbon X, b l !ng phTn c8a nha,
chCng cA phTn tU +h0i l 31- 'alogen ho mi !ng phTn chl cho $ dwn GRt monohalogen- X, b cA tPn
gui l
/0 heGanf (Zmetylpentan 10 (,$Z!imetylbtanf (,(Z !imetyl btan
C0 $Zmetyl pentanf (,$Z !imetyl btan 20 heGanf (,(Z!imetyl btan
C-. 22! 'ai hi!rocacbon X v b !W cA cSng th;c phTn tU C
1
'
1
v X cA m\ch cacbon +hSng nhnh- X
lm mRt m dng d7ch n"c brom v dng d7ch th0c t&m * !iW +i_n th"Vng- b +hSng tc dng vi (
dng d7ch trPn * !iW +i_n th"Vng nh"ng tc dng !"c vi '
(
d" t\o ra o cA cSng th;c phTn tU C
1
'
#(
- X
tc dng vi dng d7ch <gN4
$
trong N'
$
d" t\o ra C
1
'
%
<g
(
- X v b l
/0 =enzen v 'eGZ#,5Z!iin- 10 'eGZ#,5Z!iin v benzen-
C0 'eGZ#,%Z!iin v benzen- 20 'eGZ#,%Z!iin v tolen-
C-. 2,! Cho ie
$
4
%
vo dng d7ch 'Cl )vBa !8, th !"c dng d7ch X- 'Ny cho bit trong cc hAa chRt
OaL C, .g, <g, <gN4
$
, Na
(
C4
$
, NaN4
$
, Na4', N'
$
, Qx, '
(
[ cA bao nhiP hAa chRt tc dng !"c vi
dng d7ch X-
/0 9 10 F C0 3 20 1
C-. 24! JhXc hi_n cc th& nghi_m OaL
)#,- [c +h& C
(
'
(
vo dng d7ch Q.n4
%
- )(,- [c C4
(
d" vo dng d7ch Na<l4
(
)$,- Chi Ong vo hn hp +h& )C'
%
f Cl
(
,- )%,- [c +h& '
(
[ vo dng d7ch ieCl
$
-
)5,- [c +h& N'
$
vo dng d7ch <lCl
$
- )1,- [c +h& [4
(
vo dng d7ch '
(
[-
[0 th& nghi_m cA phIn ;ng oGi hoZ +hU GIy ra l
/0 #,(,%,5 10 (,%,5,1- C0 #,$,%,1- 20 #,(,$,%-
C-. 23! Jheo yy tgc bt tU trong phTn tU N'
%
Cl cA O0 +i] liPn +t +hc nha l
/0 %- 10 $- C0 5- 20 (-
C-. 2>! X, b, o l $ ngyPn t0 thDc cYng ch +z c8a bIng t?n hon- =it oGit c8a X +hi tan trong n"c
t\o thnh mDt dng d7ch lm hng yz t&m, b phIn ;ng vi n"c lm Ganh giRy yz t&m, ccn o phIn ;ng
!"c vi cI aGit +iWm- Jrat tX giIm d?n t&nh +hU c8a $ ngyPn t0 trPn lL
/0 X, o, b 10 b, o, X C0 X, b, o 20 o, b, o
C-. 2?! JB N'
(
)C'
(
,
1
N'
(
v mDt chRt hH c: X cA th] !iW ch t: NilonZ1,1- CJCJ c8a X lL
/0 '44C)C'
(
,
%
C44' 10 '44C)C'
(
,
5
C44'
C0 '44C)C'
(
,
1
C44' 20 C'4)C'
(
,
%
C'4
C-. 2@! Jrong bjnh +&n cA h_ cTn b@ng hAa huc OaL C4
(
)+, q '
(
)+,

C4 )+, q '
(
4 )+, f ' { 2-
X|t cc tc !Dng Oa !n h_ cTn b@ngL
)a, J^ng nhi_t !Df )b, JhPm mDt l"ng h:i n"cf
)c, giIm p ORt chng c8a h_f )d, dYng chRt GCc tcf
)e, thPm mDt l"ng C4
(
f
Jrong nhHng tc !Dng trPn, cA bao nhiP tc !Dng lm cTn b@ng chy]n d7ch theo chiW thane
/0 % 10 $ C0 # 20 (-
C-. 2A! M0t chy hon ton hn hp X hai amin no !:n ch;c m\ch h* !ng !}ng + tip th !"c C4
(
v
'
(
4 cA tl l_
(
(
9
#$
C-
( -
;
;
=
- N cho (%,F g hn hp X tc dng vi 'Cl d" !"c bao nhiP gam m0i +hane
/0 $F,5 g 10 %$,#5 g C0 %1,3 g 20 5(,(95 g
C-. ,0! reptit X !"c cR t\o b*i mDt amino aGit trong phTn tU chl ch;a # nhAm ZC44' v # nhAm
ZN'
(
- Jh8y phTn hon ton 2,# mol X trong dng d7ch Na4' )!"c lRy d" (2K Oo vi l"ng phIn ;ng,,
cS c\n dng d7ch Oa phIn ;ng th !"c chRt rgn cA +h0i l"ng nhiW h:n X l 95 g- [0 liPn +t peptit
trong phTn tU X l
/0 #5- 10 #9- C0 #1- 20 #%-
C-. ,1! rhIn ;ng giHa ( chRt no Oa !Ty cA ph":ng trjnh ion th gun lL
(
( -( ( -
+
+
Jrang $E1 Z .N !W thi #$(
/0
(
( 2 5-( +
10 'N4
$
qCa)4',
(
C0
$
C( C--( +a-( +
20
( % (
) , ( 2- /g -( +
C-. ,2! Cho cc pht bi] OaL
)a, 'i!ro hAa hon ton glcoz: t\o ra aGit glconic-
)b, ~ !iW +i_n th"Vng, glcoz: v Oaccaroz: !W l nhHng chRt rgn, d tan trong n"c-
)c, Xenlloz: trinitrat l ngyPn li_ !] OIn GRt t: nhTn t\o v ch t\o th0c OCng +hSng +hAi-
)d, <milopectin trong tinh bDt chl cA cc liPn +t Z#,%Zglicozit-
)e, [acaroz: b7 hAa !en trong '
(
[4
%
!/c-
), Jrong cSng nghi_p d"c phsm, Oaccaroz: !"c dYng !] pha ch th0c-
Jrong cc pht bi] trPn, O0 pht bi] !Cng l
/0 $- 10 %- C0 (- 20 5-
C-. ,,! Cho viPn on vo dng d7ch '
(
[4
%
, Oa !A thPm vi giut C[4
%
vo- hiPn on b7 ^n mcn theo
+i]L
/0 CI ^n mcn hAa huc lwn ^n mcn !i_n hAa 10 n mcn !i_n hAa
C0 n mcn vat l& 20 n mcn hAa huc
C-. ,4! M0t chy $,( gam mDt eOte t !:n ch;c, m\ch h* !"c $,53% l&t C4
(
)!+tc, v (,$2% gam '
(
4-
N cho #5 gam t tc dng vi (22 ml dng d7ch Na4' #., cS c\n dng d7ch Oa phIn ;ng th !"c
#%,$ gam chRt rgn +han- hay cSng th;c c8a ancol t\o nPn eOte trPn cA th] l
/0 C'
(
nC'Z4' 10 C'
$
4' C0 C'
$
C'
(
4' 20 C'
(
nC'ZC'
(
4'
C-. ,3! 'ca tan hon ton (% gam hn hp X gm .4, .)4',
(
v .C4
$
). l +im lo\i cA hAa tr7
+hSng !`i, trong #22 gam dng d7ch '
(
[4
%
$F,(K th !"c #,#( l&t +h& )!+tc, v dng d7ch b chl ch;a
mDt chRt tan dy nhRt cA nng !D $F,%#K- Qim lo\i . l
/0 C- 10 .g- C0 Ca- 20 on-
C-. ,>! Cho dng d7ch Q
(
[ l?n l"t vo cc dng d7ch riPng bi_t OaL ieCl
(
, CCl
(
, rb)N4
$
,
(
, onCl
(
,
ieCl
$
, .nCl
(
- [0 +t t8a +hac nha tao ra trong cac thi nghiPm trPn lL
/0 % 10 9 C0 5 20 1
C-. ,?! Cho dng d7ch )riPng bi_t, cc chRt OaL aGetonf aGit acrylicf aGit aGeticf vinyl aGetat, Oaccaroz:,
glcoz:, rctoz:, etyl omat, oZcrezol, aGit omic, btZ$ZenZ#,(Zdiol v an!ehit aGetic- [0 dng d7ch vBa
mRt m dng d7ch n"c brom, vBa phIn ;ng vi C)4',
(
ENa4' )trong !iW +i_n th&ch hp, lL
/0 9- 10 5- C0 %- 20 1-
C-. ,@! 'o tan hon ton 2,#5mol phn cha Q<l)[4
%
,
(
-#('
(
4 vo n"c, th !"c dng d7ch X- Cho
ton bD X tc dng vi (22 ml dng d7ch )=a)4',
(
#. q Na4' 2,95.,, Oa phIn ;ng hon ton th !"c
m gam +t t8a- 6i tr7 c8a m l
/0 52,5 g- 10 5%,%- C0 53,$- 20 %1,1-
C-. ,A! Cho hn hp gm 2,2# mol <l v 2,2( mol .g tc dng vi #22ml dng d7ch ch;a <gN4
$
v
C)N4
$
,
(
, Oa +hi phIn ;ng GIy ra hon ton th !"c m gam chRt rgn X gm $ +im lo\i, X tc dng hon
ton vi 'N4
$
!/c, d" th !"c h l&t N4
(
)* !+tc v dy nhRt ,- 6i tr7 c8a h l
/0 #,F2% l&t- 10 #,%51 l&t C0 #,513 l&t 20 #,($( l&t
C-. 40! Cho cc c/p chRt OaL
)#,- Qh& Cl
(
v +h& 4
(
- )1,- kng d7ch Q.n4
%
v +h& [4
(
-
)(,- Qh& '
(
[

v +h& [4
(
- )9,- 'g v [-
)$,- Qh& '
(
[ v dng d7ch rb)N4
$
,
(
- )3,- Qh& C4
(
v dng d7ch NaCl4-
)%,- Qh& Cl
(
v dng d7ch Na4'- )F,- C[ v dng d7ch 'Cl-
)5,- Qh& N'
$
v dng d7ch <lCl
$
- )#2,- kng d7ch <gN4
$
v dng d7ch ie)N4
$
,
(
-
[0 c/p chRt GIy ra phIn ;ng hAa huc * nhi_t !D th"Vng l
/0 3 10 9 C0 F 20 #2
II0 P$B C+D;E 10 &-.F T$G H+$ (IJ& &$% <=K 1 *CL; 2 6$B E 6$B I $LM& 6$B II F
P$B I! T$NL &$IO; *CP$ C$.Q E *R &-. ST41UV (W &-. ST30UVF
C-. 41! Mn # mol hn hp C
(
'
5
4' v C
%
'
F
4' )tp l_ mol t":ng ;ng l $L(, vi '
(
[4
%
!/c * #%2
o
C th
!"c m gam ete, bit hi_ ORt phIn ;ng c8a C
(
'
5
4' l 12K v c8a C
%
'
F
4' l %2K - 6i tr7 c8a m l
/0 #F,2% gam 10 5$,91 gam C0 (3,% gam 20 ($,9( gam
Jrang %E1 Z .N !W thi #$(
C-. 42! Cho O: ! OaL C
%
'
3
4
(
)X,
+a-( +
b
(
, , ,
( 1
o
- <t +a-( +a-( Ca- t
8 T C (
+ +
- X cA CJCJL
/0 C
(
'
5
C44C')C'
$
,
(
10 C'
$
C44C'
(
C'
$
C0 'C44C'
(
C'
(
C'
$
20 C'
$
C'
(
C'
(
C44'
C-. 4,! kNy gm cc +im lo\i !W tc dng !"c vi dng d7ch ieCl
$
lL
/0 ie, .g, C, <g, <l 10 <, C, <l, .g, on C0 ie, on, C, <l, .g 20 C, <g, <, .g, ie
C-. 44! Cho ph":ng trjnh ho hucL
ie[4
%
q Q.n4
%
q Q'[4
%
ie
(
)[4
%
,
$
q .n[4
%
q Q
(
[4
%
q '
(
4-
J`ng h_ O0 )O0 ngyPn t0, t0i giIn, c8a cc chRt phIn ;ng cA trong ph":ng trjnh lL
/0 %3 10 5% C0 5( 20 (3
C-. 43! Cho (F gam hn hp gm <l, C, <g tc dng vBa !8 vi F52 ml dng d7ch 'N4
$
nng !D a
molEl&t, th !"c dng d7ch ch;a F3,( gam m0i v 5,1 l&t hn hp X gm N4 v N
(
4 )* !+tc,- Jl +h0i c8a
X Oo vi hidro b@ng #1,%- 6i tr7 c8a a lL
/0 #,52 . 10 (,52 . C0 #,15 . 20 #,$5 .
C-. 4>! Cho mDt O0 t&nh chRtL cA v7 ngut )#,f tan trong n"c )(,f tham gia phIn ;ng trng b\c )$,f hca tan
C)4',
(
* nhi_t !D th"Vng )%,f lm mRt m dng d7ch brom )5,f b7 th8y phTn trong dng d7ch aGit !n
nAng )1,f Cc t&nh chRt c8a rctoz: l
/0 )#,f )(,f )$,f )%,- 10 )#,f )$,f )5,f )1,- C0 )(,f )$,f)%,f )5,- 20 )#,f )(,f)%,f )1,-
C-. 4?! Cho ( cSng th;c phTn tU C
%
'
#2
4 v C
%
'
##
N, O0 !ng phTn ancol bac ( v amin bac ( l?n l"t l
/0 # v #- 10 # v $- C0 % v #- 20 % v 3-
C-. 4@! Cho % hp chRt th:m <, =, C, k cA nhi_t !D OSi t":ng ;ng nh" OaL 32f #$(,#f #3#,(f#3%,%
2
C-
CSng th;c <, =, C, k t":ng ;ng l L
/0 C
1
'
1
, C
1
'
5
N'
(
, C
1
'
5
4', C
1
'
5
Cl 10 C
1
'
1
, C
1
'
5
Cl, C
1
'
5
4', C
1
'
5
N'
(
C0 C
1
'
5
Cl, C
1
'
1
, C
1
'
5
N'
(
, C
1
'
5
4' 20 C
1
'
1
, C
1
'
5
Cl, C
1
'
5
N'
(
, C
1
'
5
4'
C-. 4A! Nng %% gam hn hp X gm C v C)N4
$
,
(
trong bjnh +&n cho !n +hi cc phIn ;ng GIy ra
hon ton th !"c chRt rgn b- ChRt rgn b phIn ;ng vBa !8 vi 122 ml dng d7ch '
(
[4
%
2,5 . v thRy b
tan ht- Qh0i l"ng C v C)N4
$
,
(
cA trong hn hp X l L
/0 #(,% g Cf $#,1 g C)N4
$
,
(
10 3,3 g Cf $5,( g C)N4
$
,
(
C0 1,% g Cf $9,1 g C)N4
$
,
(
20 F,1 g Cf $%,% g C)N4
$
,
(
C-. 30! M] nhan bit cc +h&L C4
(
, [4
(
, '
(
[, N
(
c?n dYng cc dng d7chL
/0 N"c brom v Ca)4',
(
10 Na4' v Ca)4',
(
C0 Q.n4
%
v Na4' 20 N"c brom v Na4'
P$B II! T$NL &$IO; *CP$ -; &#L
C-. 31! M] thXc hi_n O: ! chy]n ho OaL aGit aGetic

aGit cloaGetic

glyGin- C?n thPm cc chRt

phIn ;ng
/0 '
(
v N'
$
- 10 Cl
(
v N'
$
- C0 Cl
(
v amin- 20 'Cl v m0i amoni-
C-. 32! 'n hp X gm ( aGit cacboGylic !:n ch;c h:n +|m nha mDt ngyPn tU cacbon trong phTn tU-
M0t chy hon ton 2,# mol hn hp X c?n dYng 2,(% mol 4
(
th !"c 2,(% mol C4
(
v m gam n"c- Xa
chun cSng th;c c8a ( aGite
/0 aGit aGetic v aGit propionic 10 aGit aGetic v aGit acrylic
C0 aGit omic v aGit aGetic 20 aGit acrylic v aGit metacrylic
C-. 3,! Jrong # l&t dng d7ch C'
$
C44' 2,2#. cA t`ng O0 phTn tU ch"a phTn li v ion lL 1,(1-#2
(#
=it
O0 <voga!roL 1,2(-#2
($
- MD !i_n li c8a C'
$
C44' b@ngL
/0 $K 10 #,$%K C0 %K 20 #K
C-. 34! Cho cc phIn ;ng OaL
)#, C)N4
$
,
(


2
t
)(, '
(
NC'
(
C44' q 'N4
(

)$, N'
$
q C4

2
t
)%, N'
%
N4
(


2
t
)5, C
1
'
5
N'
(
q 'N4
(


) ( HCl
2
5 2
)1, )N'
%
,
(
C4
$


2
t
[0 phIn ;ng th !"c N
(
l
/0 #, (, $- 10 (, $, %- C0 %, 5, 1- 20 $, %, 5-
Jrang 5E1 Z .N !W thi #$(
C-. 33! 'o tan mDt oGit +im lo\i .)cA ho tr7 xxx, trong mDt l"ng vBa !8 dng d7ch '
(
[4
%
(5K, Oa
phIn ;ng th !"c dng d7ch m0i cA nng !D (F,5#3#K- CSng th;c oGit !A l
/0 ie
(
4
$
- 10 Cr
(
4
$
- C0 <l
(
4
$
- 20 Ni
(
4
$
-
C-. 3>! M] phTn bi_t [4
(
v [4
$
)h:i, b@ng phIn ;ng trao !`i ta cA th] dYng chRt no Oa !Tye
/0 kd =aCl
(
10 dd =r
(
C0 kd =a)4',
(
20 kd Q.n4
%
C-. 3?! Cho cc chRt OaL C
(
'
5
4', C
1
'
5
4', C
1
'
5
N'
(
, dng d7ch C
1
'
5
4Na, dng d7ch Na4', dng d7ch
C'
$
C44', dng d7ch 'Cl- Cho tBng c/p chRt tc dng vi nha * !iW +i_n th&ch hp, O0 c/p chRt cA
phIn ;ng Gsy ra l
/0 #( 10 3 C0 #2 20 F
C-. 3@! rhenol )C
1
'
5
Z4', tc dng !"c vi nhHng chRt no trong cc chRt OaL )#, Na f )(, Na4' f )$,
'Cl f )%, Na'C4
$
f )5, dd =r
(
f )1,C'
$
C44'f )9, 'C'4f )3,)C'
$
C4,
(
4
/0 JRt cI cc chRt 10 )#,,)(,,)$,,)1, C0 )#,,)(,,)5,,)9,,)3, 20 )#,,)(,,)5,,)1,,)9,
C-. 3A! C$L $ (
2 2
E E
#, 5 f 2,#%
0u 0u 2n 2n
= ; = ;
+ +
= + =
- rhIn ;ng GIy ra +hi pin ho\t !Dng v ORt !i_n !Dng c8a
pin lL
/0
( $ 2
$ ( $ ( f #, 1%
pin
2n 0u 0u 2n = ;
+ +
+ + =
10
$ ( 2
$ ( ( $ f #, %1
pin
2n 0u 0u 2n = ;
+ +
+ + =
C0
$ ( 2
$ ( ( $ f #, 1%
pin
2n 0u 0u 2n = ;
+ +
+ + =
20
( $ 2
$ ( ( $ f #, $1
pin
2n 0u 0u 2n = ;
+ +
+ + =
C-. >0! Jrong cc chRt OaL dng d7ch Na4', C
(
'
5
4', et G^ng, dng d7ch C)N'
$
,
%
)4',
(
- [0 chRt ho
tan Genlloz: l
/0 # 10 ( C0 % 20 $
ZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZZ
ZZZZZZZZZZZ 'J ZZZZZZZZZZ
Jrang 1E1 Z .N !W thi #$(