1

MA TRN KIM TRA LN 4

I/ HIDROCACBON THM (8 cu) Bit: (2 cu) Hiu: (4 cu) Vn dng: (2 cu)
Cu 1: Chn pht biu sai:
A. Stiren l cht lng khng mu, nh hn nc v khng tan trong nc, cn c tn l vinylbenzen.
B. Stiren khng tham gia phn ng th vi Br
2
khan (Fe bt , t
o
).
C. Stiren va c tnh cht ging anken va c tnh cht ging benzen.
D. Stiren lm mt mu dung dch KMnO
4
mi iu kin
Cu 2: S ng phn hirocacbon thm ca C
9
H
12
l:
A. 6 B. 7 C. 8 D. 9
Cu 3: iu kin thch hp benzen tc dng c vi cc cht trong nhm no sau y
A. Brom khan, kh Clo, dung dch KMnO
4
, hidro.
B. Brom khan, kh Clo, hn hp HNO
3
c v H
2
SO
4
c, hidro.
C. Hn hp HNO
3
c, H
2
SO
4
c, KMnO
4
, hidro.
D. Dung dch brom, hn hp HNO
3
c, H
2
SO
4
c, hidro
Cu 4: ng dng no sau y khng phi ca benzen?
A. Dng lm dung mi B. Tng hp cc monome trong sn xut polime lm cht do, cao su, t, si
C. Lm du bi trn
D. iu ch nitrobenzen, anilin, phenol dng tng hp phm nhum, dc phm, thuc tr dch hi,.
Cu 5: Cho cc cht thm sau: (1)C
6
H
5
OH ,(2) C
6
H
5
CH
3
, (3) C
6
H
5
COOH , (4) C
6
H
5
NH
2
, (5) C
6
H
5
NO
2
,
(6) C
6
H
5
OCH
3
. Cc cht c nh hng th ortho (o-) v para (p-) l:
A. 1,2,3,5. B. 1,2,4,6. C. 1,3,5,6. D. 3,4,5,6.
Cu 6: Cho dy bin ha sau: 3C
2
H
2

C C
0
600 ,
X
2
, Br Fe
Y .
Cht Y trong dy bin ha l :
A.Benzen B. Toluen C.Brom benzen D. Benzylbromua
Cu 7: Khi vng benzen c sn mt nhm ankyl th nhm th k tip s u tin vo v tr:
A. meta. B. ortho v para. C. meta v para. D. ortho v meta.
Cu 8 : t chy hon ton 27,6 gam toluen sau dn ton b sn phm chy vo bnh ng dung dch
Ca(OH)
2
d thu c m gam kt ta. Ga tr ca m l:
A. 30 B. 210 C.21 D. 300

II/ANCOL (10 cu) Bit: (4 cu) Hiu: (3 cu) Vn dng: (3 cu)
Cu 9: Cng thc ca ancol no, n chc, bc I l:
A. C
n
H
2n+2
O (n 1) B. C
n
H
2n+1
OH (n 1)
C. C
n
H
2n+1
CH
2
OH (n 0) D. RCH
2
OH (R l gc hidrocacbon)
Cu 10: Cho cc ancol sau: (1) ancol etylic (2) ancol isopropylic (3) ancol tert-butylic
(4) ancol benzylic (5) pentan- 3 ol. Bc ca cc ancol trn ln lt l:
A. Bc I: (1), (4); bc II: (2), (5); bc III: (3) B. Bc I: (1); bc II: (2); bc III: (3), (4), (5)
C. Bc I: (1), (4); bc II: (2); bc III: (3), (5) D. Bc I: (1); bc II: (2), (4); (5); bc III: (3)
Cu 11: Dy gm cc cht tc dng c vi ancol metylic l: (iu kin phn ng c )
A. Na
2
O; HCl bc khi;H
2
SO
4
c; K, O
2
B. CuO; HCl long, lnh; Na, KOH, dd Br
2
C. CuO; Cu(OH)
2
; HBr bc khi, HNO
3
c, K D. CuO, HNO
3 c
, H
2
SO
4
c, K, C
2
H
5
OH
Cu 12: Chn cm t ng nht in vo ch (.......) sau:
Nhit si ca ancol cao hn hn nhit si ca ankan tng ng v gia cc phn t ancol tn ti........
A. Lin kt cng ha tr. B. Lin kt hiro. C. Lin kt phi tr. D. Lin kt ion.
Cu 13: tch phenol ra khi hn hp phenol, benzen v ancol benzylic th ha cht cn dng l:
A. Dung dch Br
2
, CO
2
B. Dung dch NaOH v HCl
C. Dung dch NaCl, HCl D. Na v CO
2
Cu 14: S ng phn ancol X c cng thc phn t C
5
H
12
O b oxi ha bi CuO, t
o
to thnh andehid l:
A. 2 B. 3 C.4 D.5
Cu 15: Tn gi ca ancol: (CH
3
)
2
CHCH(OH)CH
3
l:
A. 3-metyl butan-2-ol B. 2-metyl butan-3-ol
C. 1,1-imetyl propan-2-ol D. 2-metyl butan-1-ol
2


Cu 16: Cho 1,84 gam glixerol phn ng vi Na d thu c bao nhiu mililit kh H
2
(ktc)?
A.672. B. 336 C. 224 D. 448
Cu 17: Cho 9,2 gam ancol X no, n chc, mch h phn ng vi Na d thu c 2,24 lit kh H
2
(kc).
Cng thc phn t ca X l:
A. CH
3
OH B. C
3
H
7
OH C. C
2
H
5
OH D. C
4
H
9
OH
Cu 18: t chy mt lng ancol X no, n chc thu c 4,48 lt kh CO
2
( ktc) v 5,4 gam H
2
O. Cng thc phn t
ca ancol X l:
A. CH
3
OH B. C
2
H
5
OH C. C
3
H
7
OH D. C
4
H
9
OH
IV/ PHENOL ( 4 cu) Bit: (2 cu) Hiu: (1 cu) Vn dng: (1 cu)
Cu 19: Hy chn cc pht biu ng v phenol:
1/ Phenol c tnh axit nhng yu hn axit cacbonic
2/ Phenol khng lm i mu qu tm thnh , nhng lm i mu phenolphtalein sang hng.
3/ Nguyn t H trong nhm OH ca phenol linh ng hn nguyn t H trong nhm OH ca etanol
4/ Phenol tan rt tt trong nc (k c lnh) l do to lin kt hidro vi nc.
A. 1,2,3 B. 1,2,4 C. 1,2 D. 1,3
Cu 20: C bao nhiu cht cha vng benzen c cng cng thc phn t C
7
H
8
O tc dng vi Na v dung dch
NaOH?
A. 2. B. 3. C. 4. D. 1.
Cu 21: Cho cc pht biu sau:
(1) Do nh hng ca nhm OH nn mt electron vng benzen tp trung nhiu v tr o v p
(2) ancol benzylic v phenol l ancol thm, tc dng c vi Na
(3) etilen glicol tc dng vi Cu(OH)
2
(4) phenol c tnh axit lm qu tm ho
(5) phenol v ancol u tc dng vi Na v NaOH do nhm OH ging nhau
Cc pht biu ng l:
A. (1), (2), (3), (4), (5) B. (1), (3), (4) C. (1), (2), (3), (5) D. (1), (3)
Cu 22: Cn bao nhiu gam phenol phn ng va vi 400 ml dung dch brom 1,5 M ?
A. 19,4 B. 18,8 C. 18,4 D. 18,6
TNG HP ( 10 cu) Bit: (2 cu) Hiu: ( 3 cu) Vn dng: (3 cu)
Cu 23 : Hy chn cu pht biu sai:
A. Phenol l cht rn kt tinh d b oxi ho trong khng kh thnh mu hng nht
B. Phenol c tnh axit yu nhng mnh hn H
2
CO
3

C. Khc vi benzen, phenol phn ng vi dung dch Br
2
nhit thng to kt ta trng.
D. Nhm OH v gc phenyl trong phn t phenol c nh hng qua li ln nhau.
Cu 24: Cho 4 ancol : C
2
H
5
OH (1); C
2
H
4
(OH)
2
(2); C
3
H
5
(OH)
3
(3) v HOCH
2
CH
2
CH
2
OH (4). Ancol
khng ha tan c Cu(OH)
2
l:
A. 1 v 2 B. 2 v 4 C. 1 v 4 D. 1 v 3

Cu 25 : Dy cht no sau y u lm mt mu dung dch brom?
A. Axetilen, etilen, stiren, phenol B. Axetilen, toluen , stiren, phenol
C. Etanol, etan , stiren, phenol D. Toluen, benzen, etanol
Cu 26: Thuc th phn bit glixerol, etanol v phenol l:
A. Na, dung dch brom B. Dung dch brom, Cu(OH)
2
C. Cu(OH)
2
, qu tm D. Dung dch brom, qu tm
Cu 27: un nng hn hp 4 ancol no, n chc, mch h vi H
2
SO
4
c nhit thch hp th c th thu c ti a
bao nhiu ete?
A. 8 B. 10 C. 4 D. 2
Cu 28: Mt ancol no, n chc c t khi hi so vi oxi bng 1,875. Cng thc ca ancol l:
A. C
4
H
9
OH B. C
3
H
7
OH C. C
5
H
11
OH. D. C
2
H
5
OH
Cu 29 : Cho 18,6 gam hn hp A gm etanol v phenol tc dng vi Na d thu c 3,36 lt kh H
2
( kc).
Phn trm khi lng ca etanol v phenol trong hn hp ln lt l:
A.49,46% v 50,54% B. 38,68% v 61,32%
C. 40,53% v 59,47% D. 60,24% v 39,76%
Cu 30: un nng m gam hn hp hai ancol n chc tc dng vi H
2
SO
4
c 140
o
C thu c 21,6 gam
H
2
O v 72 gam hn hp 3 ete c s mol bng nhau v bng x mol .Ga tr ca m v x ln lt l:

A. 93,6 v 0,4 B. 50,4 v 1,2 C. 93,6 v 1,2 D. 50,4 v 0,3
3

MA TRN RA KIM TRA 1 TIT - Ha hc 11 CB
I/ HIDROCACBON THM (7 cu) Bit: (2 cu) Hiu: (2 cu) Vn dng: (1 cu) Bi tp ( 2 cu)
Cu 1: Cng thc chung ca dy ng ng ankylbenzen l:
A.C
n
H
2n-6
( n 6) B. C
n
H
2n-3
( n 6). C. C
n
H
2n-6
( n 1). D. C
n
H
2n+6
( n 1)
Cu 2: Hin tng g xy ra khi un nng toluen vi dung dch KMnO
4
?
A. Dung dch KMnO
4
b mt mu. B. Xut hin kt ta trng
C. Si bt kh D. Dung dch KMnO
4
khng b mt mu.
Cu 3: Thuc th no di y c dng phn bit cc cht lng: benzen, toluen, vinylbenzen (stiren)?
A. Dung dch KMnO
4
long lnh. B. Dung dch KMnO
4
un nng
C. Dung dch Brom. D. Dung dch NaOHCu 4: Nguyn liu no dng iu
ch 2,4,6- trinitrotoluen ( thuc n TNT)?
A. C
6
H
6
v HNO
3
m c B. C
7
H
8
v HNO
3
m c
C. C
7
H
8
v HNO
3
m c, H
2
SO
4
m c D. C
6
H
6
v HNO
3
m c, H
2
SO
4
m c
Cu 5: Ankylbenzen X c phn trm nguyn t cacbon l 92,30%. Cng thc phn t ca X l:
A. C
6
H
6
B. C
7
H
8
C. C
8
H
10
D. C
9
H
12
Cu 6: S ng phn hidrocacbon thm ca C
8
H
10
l?
A. 3 B. 4 C. 5 D. 6
Cu 7: t chy ht m gam 2 ng ng ca benzen A, B thu c 8,1 gam H
2
O v 15,456 lt kh CO
2
. Cng
thc phn t ca A, B v m ln lt l:
A. C
6
H
6
, C
7
H
8
, 12,6 gam. B. C
7
H
8
, C
8
H
10
, 10,8 gam.
C. C
8
H
10
, C
9
H
12
, 9,18 gam. B. C
8
H
10
, C
8
H
8
, 10,8 gam
III/ANCOL (8 cu) Bit: (3 cu) Hiu: (3 cu) Vn dng: (3 cu)
Cu 8: Phng php sinh ha iu ch ancol etylic l:
A. ln men glucoz B. hidrat ha anken
C. thy phn dn xut halogen D. Axetilen hp nc
Cu 9A: Oxi ha ancol X bng CuO, t
o

thu c andehid n chc. X l:
A. Ancol n chc bc 1 B. Ancol n chc bc 2
C. Ancol n chc bc 3 D. Ancol n chc bc 1 v bc 2.
Cu 9B: Khi t chy ancol A mch h thu c
O H
n
2
=
2
CO
n . Kt lun ng v ancol A l:
A. ancol no, n chc B. ancol khng no C. ancol khng no, n chc D. ancol a chc
Cu 10: Dy cht no di y u tc dng c vi metanol ?
A. Na, HBr, C
2
H
5
OH B. Na, Br
2
, C
3
H
7
OH
C. NaOH, HBr, C
2
H
5
OH D. NaOH, HBr, Cu(OH)
2
Cu 11: phn bit 2 l dung dch cha glixerol v propan-1-ol b mt nhn, ngi ta dng :
A. Cu(OH)
2
B. Dung dch AgNO
3
/ NH
3
C. Na kim loi D. Nc brom
Cu 12: S ng phn ancol X c cng thc phn t C
4
H
10
O b oxi ha bi CuO, t
o
to thnh andehid l:
A. 2 B. 3 C.4 D.5
Cu 13: Tn gi ca ancol: (CH
3
)
2
CHCH
2
CH
2
CH(OH)CH
3
l:
A. 5-metyl hexan-2-ol B. 2-metyl hexan-5-ol
C. 1,1-imetyl pentan-2-ol D. 2-metyl hexan-1-ol
Cu 14: Cho 1,38 gam glixerol phn ng vi Na d thu c bao nhiu mililit kh H
2
(kc)?
A. 504. B. 336 C. 224 D. 448
Cu 15: Cho 6,4 gam ancol X no, n chc, mch h phn ng vi Na d thu c 2,24 lit kh H
2
(kc). Cng
thc phn t ca X l:
A. CH
3
OH B. C
3
H
7
OH C. C
2
H
5
OH D. C
4
H
9
OH
Cu 16: : t chy hon ton m gam hn hp X gm 3 ancol (n chc, thuc cng dy ng ng), thu c
4,48lt CO
2
(ktc) v 5,85 gam H
2
O. Mt khc, nu un nng m gam X vi H
2
SO
4
c th tng khi lng ete
ti a thu c l:
A. 7,85 gam B. 7,425 gam C. 2,80 gam D. 3,925 gam
IV/ PHENOL ( 4 cu) Bit: (2 cu) Hiu: (1 cu) Vn dng: (1 cu)
Cu 17: Nh nc brom vo dung dch phenol hin tng quan st c l:
A. Nc brom mt mu, xut hin kt ta trng B. Nc brom mt mu, xut hin kt ta vng
C. Nc brom chuyn sang mu xanh D. Nc brom khng b mt mu
Cu 18: Chn cu ng nht?
4

A. Phenol tan trong dung dch NaOH ch l s ha tan bnh thng.
B. Phenol l ancol thm .
C. Phenol tc dng vi NaOH , Na , dung dch brom, HNO
3
c
D. C
6
H
5
CH
2
OH l ng ng ca phenol.
Cu 19: Phn ng no di y chng minh phenol c tnh axit yu hn axit cacbonic:
A. 2C
6
H
5
OH + 2Na 2C
6
H
5
ONa + H
2
B. C
6
H
5
OH + NaOH C
6
H
5
ONa + H
2
O
C. C
6
H
5
ONa + CO
2
+ H
2
O C
6
H
5
OH + NaHCO
3
D.

C
6
H
5
OH + 3Br
2
C
6
H
3
OBr
3
+ 3HBr
Cu 20: Cn bao nhiu phenol tc dng va vi 300 ml dung dch brom 1M ?
A. 9,4 B. 9,2 C. 10,4 D. 8,6
TNG HP ( 10 cu) Bit: (2 cu) Hiu: ( 3 cu) Vn dng: ( 4 cu)
Cu 21 : : Cho cc cht sau: (1) H
2
O, (2) C
2
H
5
OH, (3) C
6
H
5
OH, (4) (CH
3
)
2
CHOH
Dy c sp xp theo chiu tng dn linh ng ca nguyn t H l:
A. (4) < (2) < (1) < (3) B. (4) < (2) < (3) < (1)
C. (1) < (2) < (4) < (3) D. (3) < (4) < (2) < (1)
Cu 22 : Dy cht no sau y u lm mt mu dung dch brom?
A. Axetilen, etilen, stiren, phenol B. Axetilen, etanol, stiren, phenol
C. Etanol, etan , stiren, phenol D. Toluen, benzen, etanol
Cu 23: Dng thuc th no phn bit 3 l dung dch b mt nhn cha : phenol, stiren, ancol benzylic?
A. Dung dch brom B. Na C. NaOH D. Qy tm
Cu 24: Cho HOC
6
H
4
CH
2
OH ln lt tc dng vi Na, dd NaOH, dd HBr, dd CuSO
4
, dd AgNO
3
/NH
3
. C
my phn ng xy ra?
A. 3 B.4 C.5 D. 2
Cu 25:So snh nhit si ca cc cht sau ancol etylic (1), etyl clorua (2), ietyl ete (3) v phenol (4) ta c:
A. (1 ) > (2) > (3) > (4) B. (4) > (3) > (2) > (1)
C. (4) > (1) > (3) > (2) D. (1) > (2) > (3) > (4)
Cu 26: Khi un ancol X vi H
2
SO
4
c, 170
o
C thu c anken Y c t khi so vi X l 0,6. Cng thc phn
t ca ancol X l:
A. C
2
H
6
O B. C
3
H
8
O C. C
4
H
10
O D. C
5
H
12
O
Cu 27: Trong day bien hoa sau: CH4
0
1500 C

A
0
2
, , H Ni t

B
2
, Cl as

C2H5Cl
0
, ddNaOH t

C
0
, CuO t

D
Cac chat A,B,C,D lan lt la:
A. C
2
H
2
, C
2
H
6
, C
2
H
5
OH, CH
3
CHO B. C
2
H
2
, C
2
H
4
, C
2
H
4
, HCHO
C. C
2
H
4
, C
2
H
6
, C
2
H
5
OH, CH
3
CHO D. C
2
H
2
, C
2
H
4
, C
2
H
5
OH, CH
3
CHO
Cu 27: Cho s sau:
(A)
1500
o
C
lm lnh nhanh
(B)
600
o
C
C
(C)
(D)
Br
bt Fe, t
o

Cc cht (A), (B), (C), (D) ln lt l:
A. CH
4
, C
2
H
4
, C
6
H
6
, Br
2
khan. B. CH
4
, C
2
H
2
, C
6
H
6
, HBr
C. C
2
H
2
, C
2
H
2
, C
6
H
6
, HBr
.
D. CH
4
, C
2
H
2
, C
6
H
6
, Br
2
khan.
Cu 28: Cho 18,6 gam hn hp A gm etanol v phenol tc dng vi Na d thu c 3,36 lt kh H
2
( kc).
Phn trm khi lng ca etanol v phenol trong hn hp ln lt l:
A.49,46% v 50,54% B. 38,68% v 61,32%
C. 40,53% v 59,47% D. 60,24% v 39,76%
Cu 29 : un nng m gam hn hp hai ancol n chc tc dng vi H
2
SO
4
c 140
o
C thu c 21,6 gam
H
2
O v 72 gam hn hp 3 ete c s mol bng nhau v bng x mol .Ga tr ca m v x ln lt l:

A. 93,6 v 0,4 B. 50,4 v 1,2 C. 93,6 v 1,2 D. 50,4 v 0,3
Cu 30: Hn hp G gm ru n chc no X v H
2
O.
Cho 21 gam G tc dng Na c 7,84 lt H
2
(ktc)
Cho 21 gam G t chy v cho sn phm chy hp th ht vo dd Ca(OH)
2
d. Khi lng kt ta to ra
trong bnh cha Ca(OH)
2
l:
A. 30g B. 45g C. 60g D. 75g