Chuyn LTH 2014 AXIT CACBOXYLIC

AXIT CACBOXYLIC
TRONG CC THI H C
L THUYT TRNG T
Cu 1: Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic
(Z) v imetyl ete ()! "#y $%m cc cht c &'p x(p theo chi)u t*n$ +,n
nhi-t . &/i l
A. , X, Y, Z! B. , Z, Y, X! C. Z, , Y, X! D. Y, , X, Z!
Cu 2: "#y $%m cc cht c x(p theo chi)u nhi-t . &/i t*n$ +,n t0 tri
&an$ ph1i l
A. C2
3
C24, C
5
2
6
42, C
5
2
7
, C2
3
C442!
B. C2
3
C442, C
5
2
7
, C2
3
C24, C
5
2
6
42!
C. C
5
2
7
, C
5
2
6
42, C2
3
C24, C2
3
C442!
D. C
5
2
7
, C2
3
C24, C
5
2
6
42, C2
3
C442!
Cu 3: "#y $%m cc cht c &'p x(p theo chi)u t*n$ +,n nhi-t . &/i t0
tri &an$ ph1i l
A. C2
3
C442, 2C442, C
5
2
6
42, C2
3
C24!
B. 2C442, C2
3
C442, C
5
2
6
42, C2
3
C24!
C. C2
3
C442, C
5
2
6
42, 2C442, C2
3
C24!
D. C2
3
C24, C
5
2
6
42, 2C442, C2
3
C442!
Cu 4: 8xit no tron$ &9 cc axit &au c: t;nh axit m<nh nht=
A. C2
5
>?C2
5
?C442! B. C2
3
?C>
5
?C442!
C. C2
3
C2>?C442! D. C2
3
?CCl
5
?C442!
Cu 5: Cho cc cht 2Cl (X)@ C
5
2
6
42 (Y)@ C2
3
C442 (Z)@ C
7
2
6
42
(phenol) ()! "#y $%m cc cht c &'p x(p theo t;nh axit t*n$ +,n (t0 tri
&an$ ph1i) l
A. (X), (Z), (), (Y)! B. (Y), (), (Z), (X)!
C. (Y), (), (X), (Z)! D. (), (Y), (X), (Z)!
Cu 6: "#y $%m cc cht x(p theo chi)u lAc axit t*n$ +,n t0 tri &an$ ph1i
l
A. 2C442, C2
3
C442, C2
3
C2
5
C442!
B. C2
3
C442, 2C442, (C2
3
)
5
C2C442!
C. C
7
2
6
42, C2
3
C442, C2
3
C2
5
42!
D. C2
3
C442, C2
5
ClC442, C2Cl
5
C442!
Cu 7: Bhi cho a mol m.t hp cht hCu cD X (chEa C, 2, 4) ph1n En$
hon ton vFi Ga hoHc vFi Ga2C4
3
thI )u &inh ra a mol Jh;! Cht X l
A. ancol o-hiroxiKenLylic! B. axit aipic!
G!" B#CH H$U H#NH T%&n' 1
Chuyn LTH 2014 AXIT CACBOXYLIC
C. axit 3?hiroxipropanoic! D. etylen $licol!
Cu 8: 2Mn hp $%m N,O mol m.t axit cacKoxylic Dn chEc v N,O mol
mu9i cPa axit : vFi Jim lo<i Ji)m c: tQn$ Jh9i ln$ l O6,R $am! Sn cPa
axit trSn l
A. axit Kutanoic! B. axit propanoic! C. axit metanoic! D. axit etanoic!
Cu 9: 2ai hp cht hCu cD X, Y c: cTn$ c/n$ thEc phUn tV C
3
2
7
4
5
! C1 X
v Y )u tc +Wn$ vFi Ga@ X tc +Wn$ c vFi Ga2C4
3
cXn Y c: Jh1 n*n$
tham $ia ph1n En$ trn$ K<c! C/n$ thEc cu t<o cPa X v Y l,n lt l
A. C
5
2
6
C442 v C2
3
C2(42)C24!
B. C
5
2
6
C442 v 2C44C
5
2
6
!
C. 2C44C
5
2
6
v 24C2
5
C2
5
C24!
D. 2C44C
5
2
6
v 24C2
5
C4C2
3
!
Cu 1: 2ai cht X v Y c: cTn$ c/n$ thEc phUn tV C
5
2
Y
4
5
! Cht X ph1n
En$ c vFi Jim lo<i Ga v tham $ia ph1n En$ trn$ K<c! Cht Y ph1n En$
c vFi Jim lo<i Ga v ho tan c CaC4
3
! C/n$ thEc cPa X, Y l,n lt
l
A. 24C2
5
C24, C2
3
C442! B. 2C44C2
3
, 24C2
5
C24!
C. C2
3
C442, 24C2
5
C24! D. 2C44C2
3
, C2
3
C442!
Cu 11: 8xit cacKoxylic X c: c/n$ thEc Dn $i1n nht l C
3
2
6
4
5
! Bhi cho
ONN ml +un$ +Zch axit X n%n$ . N,O[ ph1n En$ h(t vFi +un$ +Zch
Ga2C4
3
(+), thu c \ ml Jh; C4
5
(Jtc)! ]i trZ cPa \ l
A. OO5! B. 55Y! C. YYR! D. 337!
Cu 12: 2ai cht hCu cD X, Y c: thnh ph,n phUn tV $%m C, 2, 4
([
X
^[
Y
^R5)! C1 X v Y )u c: Jh1 n*n$ tham $ia ph1n En$ trn$ K<c v
)u ph1n En$ c vFi +un$ +Zch B2C4
3
&inh ra Jh; C4
5
! _ Jh9i hDi cPa
Y &o vFi X c: $i trZ l
A. O,Y`! B. O,7O! C. O,6`! D. O,aO!
Cu 13: 8xit cacKoxylic no, m<ch hb X c: c/n$ thEc thAc n$hi-m
(C
3
2
Y
4
3
)
n
, vcy c/n$ thEc phUn tV cPa X l
A. C
7
2
R
4
7
! B. C
a
2
O5
4
a
! C. C
3
2
Y
4
3
! D. C
O5
2
O7
4
O5
!
Cu 14: C: Kao nhiSu cht c: thd ph1n En$ vFi axit eomic tron$ &9 cc cht
&au: B42, G2
3
, Ca4, [$, Cu, Ga
5
C4
3
, Ga
5
f4
Y
, C2
3
42, C
7
2
6
42,
8$G4
3
gG2
3
=
A. R! B. a! C. `! D. 7!
Cu 15: Cho cc cht: C2
3
C2
5
42, C
5
2
7
, C2
3
42, C2
3
C24, C
7
2
O5
4
7
,
C
Y
2
ON
, C
5
2
6
Cl! f9 cht c: thd i)u ch( trAc ti(p ra axit axetic (Khn$ O ph1n
En$) l
G!" B#CH H$U H#NH T%&n' 2
Chuyn LTH 2014 AXIT CACBOXYLIC
A. 5! B. 3! C. Y! D. 6!
Cu 16: "#y $%m cc cht c: thd i)u ch( trAc ti(p (Khn$ m.t ph1n En$)
t<o ra axit axetic l
A. C
5
2
Y
(42)
5
, C2
3
42, C2
3
C24!
B. C2
3
C24, C
5
2
6
42, C
5
2
6
C44C2
3
!
C. C2
3
42, C
5
2
6
42, C2
3
C24!
D. C2
3
C24, C
7
2
O5
4
7
($lucoLD), C2
3
42!
(T )* +#NG TO,N -UAN TRNG
+.n' 1" /H0N 1NG *T CH,Y
Cu 17: i9t chy hon ton N,O mol m.t axit cacKoxylic Dn chEc, c,n v0a
P \ l;t 4
5
(b Jtc), thu c N,3 mol C4
5
v N,5 mol 2
5
4! ]i trZ cPa \ l
A. R,a7! B. 7,`5! C. Y,YR! D. OO,5!
Cu 18: i9t chy hon ton x mol axit cacKoxylic j, thu c y mol
C4
5
v L mol 2
5
4 (vFi L k y ? x)! Cho x mol j tc +Wn$ vFi Ga2C4
3
(+)
thu c y mol C4
5
! Sn cPa j l
A. axit oxalic! B. axit eomic! C. axit aipic! D. axit acrylic!
Cu 19: i9t chy hon ton x $am hMn hp $%m hai axit cacKoxylic hai
chEc, m<ch hb v )u c: m.t liSn J(t /i CkC tron$ phUn tV, thu c \ l;t
Jh; C4
5
(Jtc) v y mol 2
5
4! lidu thEc liSn h- $iCa cc $i trZ x, y v \ l
A. \ k
5R
( 3N )
66
x y
! B. \ k
5R
( 75 )
a6
x y
!
C. \ k
5R
( 3N )
66
x y +
! D. \ k
5R
( 75 )
a6
x y +
!
Cu 2: 2o hDi O6,65 $am hMn hp $%m m.t axit no Dn chEc X v m.t
axit no a chEc Y (&9 mol X lFn hDn &9 mol Y), thu c m.t thd t;ch hDi
Khn$ thd t;ch cPa 6,7 $am G
5
(o tron$ cTn$ i)u Ji-n nhi-t ., p &ut)!
G(u 9t chy ton K. hMn hp hai axit trSn thI thu c ON,`65 l;t C4
5
(Jtc)! C/n$ thEc cu t<o cPa X, Y l,n lt l
A. C2
3
?C442 v 244C? C2
5
?C442!
B. 2?C442 v 244C?C442!
C. C2
3
?C442 v 244C? C2
5
C2
5
?C442!
D. C2
3
C2
5
?C442 v 244C?C442!
Cu 21: 2Mn hp X $%m axit eomic, axit acrylic, axit oxalic v axit axetic!
Cho m $am X ph1n En$ h(t vFi +un$ +Zch Ga2C4
3
thu c O,3YY l;t C4
5
(Jtc)! i9t chy hon ton m $am X c,n 5,NO7 l;t 4
5
(Jtc), thu c Y,RY
$am C4
5
v a $am 2
5
4! ]i trZ cPa a l
A. O,75! B. O,RN! C. 3,7N! D. O,YY!
G!" B#CH H$U H#NH T%&n' 2
Chuyn LTH 2014 AXIT CACBOXYLIC
Cu 22: 2:a hDi R,7Y $am hMn hp $%m m.t axit no, Dn chEc, m<ch hb X
v m.t axit no, a chEc Y (c: m<ch cacKon hb, Jh/n$ phUn nhnh) thu
c m.t thd t;ch hDi Khn$ thd t;ch cPa 5,R $am G
5
(o tron$ cTn$ i)u Ji-n
nhi-t ., p &ut)! i9t chy hon ton R,7Y $am hMn hp hai axit trSn thu
c OO,YY $am C4
5
! mh,n tr*m Jh9i ln$ cPa X tron$ hMn hp Kan ,u l
A. `5,55n! B. 76,O6n! C. 5`,`Rn! D. 36,56n!
Cu 23: 2Mn hp X $%m hai axit cacKoxylic Dn chEc! i9t chy hon ton
N,O mol X c,n N,5Y mol 4
5
, thu c C4
5
v N,5 mol 2
5
4! C/n$ thEc hai
axit l
A. C2
3
C442 v C
5
2
6
C442!
B. C2
5
kC2C442 v C2
5
kC(C2
3
)C442!
C. 2C442 v C
5
2
6
C442!
D. C2
3
C442 v C2
5
kC2C442!
Cu 24: li(t X l axit cacKoxylic Dn chEc, Y l ancol no, c1 hai cht )u
m<ch hb, c: cTn$ &9 n$uySn tV cacKon! i9t chy hon ton N,Y mol hMn
hp $%m X v Y (tron$ : &9 mol cPa X lFn hDn &9 mol cPa Y) c,n v0a P
3N,5Y l;t Jh; 4
5
, thu c 57,RR l;t Jh; C4
5
v Oa,R $am 2
5
4! li(t thd t;ch
cc Jh; o b i)u Ji-n tiSu chuon! Bh9i ln$ cPa Y tron$ N,Y mol hMn hp
trSn l
A. OO,Y $am! B. Oa,N $am! C. a,N $am! D. O`,` $am!
Cu 25: ron$ phUn tV axit cacKoxylic X c: &9 n$uySn tV cacKon Khn$ &9
nh:m chEc! i9t chy hon ton m.t ln$ X thu c &9 mol C4
5
Khn$ &9
mol 2
5
4! Sn $pi cPa X l
A. axit axetic! B. axit oxalic! C. axit eomic! D. axit malonic!
Cu 26: 8xit cacKoxylic X hai chEc (c: ph,n tr*m Jh9i ln$ cPa oxi nhq
hDn `Nn), Y v Z l hai ancol %n$ rn$ J( ti(p ([
Y
^ [
Z
)! i9t chy hon
ton N,5 mol hMn hp $%m X, Y, Z c,n v0a P R,a7 l;t Jh; 4
5
(Jtc), thu
c `,RY l;t Jh; C4
5
(Jtc) v R,O $am 2
5
4! mh,n tr*m Jh9i ln$ cPa Y
tron$ hMn hp trSn l
A. O6,an! B. 5a,an! C. 5a,7n! D. O5,7n!
Cu 27: 2Mn hp [ $%m 5 axit cacKoxylic )u no, m<ch hb 8, l (l hDn 8
m.t nh:m chEc)! 2:a hDi hon ton m $am [ thu c thd t;ch hDi Khn$
thd t;ch cPa ` $am nitD o cTn$ i)u Ji-n nhi-t ., p &ut! G(u cho m $am
[ tc +Wn$ vFi Ga + thu c Y,YR l;t 2
5
(Jtc)! Bhi 9t chy hon ton m
$am [ thu c 5R,7$ C4
5
! C/n$ thEc phUn tV cPa 8 v l l
A. C
5
2
Y
4
5
v C
3
2
Y
4
Y
! B. C2
5
4
5
v C
3
2
Y
4
Y
!
C. C
5
2
Y
4
5
v C
Y
2
7
4
Y
! D. C2
5
4
5
v C
Y
2
7
4
5
!
G!" B#CH H$U H#NH T%&n' 4
Chuyn LTH 2014 AXIT CACBOXYLIC
Cu 28: i9t chy ON,Y $am m.t axit cacKoxylic no, a chEc m<ch hb,
Jh/n$ phUn nhnh thu c N,3 mol C4
5
v N,5 mol 2
5
4! C/n$ thEc cu
t<o cPa axit l
A. 244C?(C2
5
)
3
?C442! B. 244C?C2
5
?C442!
C. 244C?C2
5
?C2
5
?C442! D. 244C?(C2
5
)
Y
?C442!
Cu 29: 4xi ho hon ton m $am hMn hp X $%m hai anehit no, Dn
chEc, m<ch hb, J( ti(p nhau tron$ +#y %n$ rn$ thu c (m s R) $am hMn
hp Y $%m hai axit! iem 9t chy h(t hMn hp Y c,n v0a P 5a,O5 l;t 4
5
(b
Jtc)! ]i trZ m l
A. OR,Y`! B. 55,Y`! C. 5Y,R! D. 57,5!
+.n' 2" /H0N 1NG C3A NH4 CACBOXYL
Cu 3: run$ ho 6,YR $am hMn hp $%m axit axetic, phenol v axit
KenLoic, c,n +Tn$ 7NN ml +un$ +Zch Ga42 N,O[! C/ c<n +un$ +Zch &au
ph1n En$, thu c hMn hp cht r'n Jhan c: Jh9i ln$ l
A. Y,aN $am! B. 7,RY $am! C. R,7Y $am! D. 7,RN $am!
Cu 31: Cho 3,7 $am axit cacKoxylic no, Dn chEc X tc +Wn$ hon ton
vFi 6NN ml +un$ +Zch $%m B42 N,O5[ v Ga42 N,O5[! C/ c<n +un$ +Zch
thu c R,5R $am hMn hp cht r'n Jhan! C/n$ thEc phUn tV cPa X l
A. C2
3
C442! B. 2C442! C. C
3
2
`
C442! D. C
5
2
6
C442!
Cu 32: Cho hMn hp X $%m hai axit cacKoxylic no, m<ch Jh/n$ phUn nhnh!
i9t chy hon ton N,3 mol hMn hp X, thu c OO,5 l;t Jh; C4
5
(b Jtc)!
G(u trun$ hXa N,3 mol X thI c,n +Tn$ 6NN ml +un$ +Zch Ga42 O[! 2ai
axit : l
A. 2C442, 244C?C442! B. 2C442, 244C?C2
5
?C442!
C. 2C442, C
5
2
6
C442! D. 2C442, C2
3
C442!
Cu 33: 2Mn hp Z $%m hai axit cacKoxylic Dn chEc X v Y ([
X
t [
Y
) c:
tQn$ Jh9i ln$ l R,5 $am! Cho Z tc +Wn$ v0a P vFi +un$ +Zch Ga42,
thu c +un$ +Zch chEa OO,6 $am mu9i! [Ht Jhc, n(u cho Z tc +Wn$ vFi
m.t ln$ + +un$ +Zch 8$G4
3
tron$ G2
3
, thu c 5O,7 $am 8$! C/n$
thEc v ph,n tr*m Jh9i ln$ cPa X tron$ Z l
A. C
5
2
3
C442 v Y3,aNn! B. C
3
2
6
C442 v 6Y,RRn!
C. C
5
2
6
C442 v 67,ONn! D. 2C442 v Y6,O5n!
Cu 34: 2Mn hp X $%m axit axetic, axit eomic v axit oxalic! Bhi cho m
$am X tc +Wn$ vFi Ga2C4
3
(+) thI thu c O6,7R l;t Jh; C4
5
(Jtc)! [Ht
Jhc, 9t chy hon ton m $am X c,n R,a7 l;t Jh; 4
5
(Jtc), thu c 36,5
$am C4
5
v y mol 2
5
4! ]i trZ cPa y l
A. N,R! B. N,3! C. N,5! D. N,7!
G!" B#CH H$U H#NH T%&n' 5
Chuyn LTH 2014 AXIT CACBOXYLIC
Cu 35: run$ ho 3,RR $am hMn hp X $%m hai axit cacKoxylic no, Dn
chEc, m<ch hb Khn$ +un$ +Zch Ga42, c/ c<n ton K. +un$ +Zch &au ph1n
En$ thu c 6,5 $am mu9i Jhan! G(u 9t chy hon ton 3,RR $am X thI
thd t;ch oxi (Jtc) c,n +Tn$ l
A. O,O5 l;t! B. 3,37 l;t! C. Y,YR l;t! D. 5,5Y l;t!
Cu 36: 2Mn hp X $%m hai axit cacKoxylic no, m<ch hb Y v Z (phUn tV
Jh9i cPa Y nhq hDn cPa Z)! i9t chy hon ton a mol X, &au ph1n En$ thu
c a mol 2
5
4! [Ht Jhc, n(u cho a mol X tc +Wn$ vFi ln$ + +un$
+Zch Ga2C4
3
, thI thu c O,7a mol C4
5
! hnh ph,n n theo Jh9i ln$
cPa Y tron$ X l
A. Y7,7`n! B. `Y,6an! C. 56,YOn! D. YN,NNn!
Cu 37: 2Mn hp X chEa Ka axit cacKoxylic )u Dn chEc, m<ch hb, $%m
m.t axit no v hai axit Jh/n$ no )u c: m.t liSn J(t /i (CkC)! Cho m $am
X tc +Wn$ v0a P vFi O6N ml +un$ +Zch Ga42 5[, thu c 56,67 $am
hMn hp mu9i! i9t chy hon ton m $am X, hp thW ton K. &1n phom
chy Khn$ +un$ +Zch Ga42 +, Jh9i ln$ +un$ +Zch t*n$ thSm YN,NR $am!
Qn$ Jh9i ln$ cPa hai axit cacKoxylic Jh/n$ no tron$ m $am X l
A. O6,37 $am! B. a,a7 $am! C. O5,N7 $am! D. OR,a7 $am!
Cu 38: 2Mn hp X $%m hai axit cacKoxylic Dn chEc, m<ch hb, J( ti(p
nhau tron$ cTn$ +#y %n$ rn$! i9t chy hon ton Y,N5 $am X, thu c
5,3Y $am 2
5
4! [Ht Jhc ON,N6 $am X ph1n En$ v0a P vFi +un$ +Zch
Ga42, thu c O5,R $am mu9i! C/n$ thEc cPa hai axit l
A. C2
3
C442 v C
5
2
6
C442! B. C
5
2
6
C442 v C
3
2
`
C442!
C. C
3
2
6
C442 v C
Y
2
`
C442! D. C
5
2
3
C442 v C
3
2
6
C442!
Cu 39: Cho X v Y l hai axit cacKoxylic m<ch hb, c: cTn$ &9 n$uySn tV
cacKon, tron$ : X Dn chEc, Y hai chEc! Chia hMn hp $%m X v Y thnh
hai ph,n Khn$ nhau! mh,n m.t tc +Wn$ h(t vFi Ga, thu c Y,YR l;t Jh; 2
5
(Jtc)! i9t chy hon ton ph,n hai, thu c O3,YY l;t Jh; C4
5
(Jtc)!
mh,n tr*m Jh9i ln$ cPa Y tron$ hMn hp l
A. Y5,R7 n! B. 6`,OYn! C. R6,`On! D. 5R,6`n!
Cu 4: Cho O7,Y $am hMn hp X $%m 5 axit cacKoxylic l %n$ rn$ J(
ti(p nhau ph1n En$ hon ton vFi 5NN ml +un$ +Zch Ga42 O[ v B42
O[, thu c +un$ +Zch Y! C/ c<n +un$ +Zch Y, thu c 3O,O $am hMn
hp cht r'n Jhan! C/n$ thEc cPa 5 axit tron$ X l
A. C
5
2
Y
4
5
v C
3
2
Y
4
5
! B. C
5
2
Y
4
5
v C
3
2
7
4
5
!
C. C
3
2
Y
4
5
v C
Y
2
7
4
5
! D. C
3
2
7
4
5
v C
Y
2
R
4
5
!
G!" B#CH H$U H#NH T%&n' 6
Chuyn LTH 2014 AXIT CACBOXYLIC
Cu 41: 2Mn hp X $%m hai axit cacKoxylic Dn chEc, %n$ rn$ J( ti(p!
Cho 6,Y $am X ph1n En$ hon ton vFi +un$ +Zch Ga2C4
3
+, thu c
5,5Y l;t Jh; C4
5
(Jtc)! C/n$ thEc cPa hai axit tron$ X l
A. C
3
2
`
C442 v C
Y
2
a
C442! B. C
5
2
6
C442 v C
3
2
`
C442!
C. C2
3
C442 v C
5
2
6
C442! D. 2C442 v C2
3
C442!
Cu 42: Cho Y,YY $am axit cacKoxylic, Dn chEc X tc +Wn$ hon ton vFi
6NN ml $%m: B42 N,O5[, Ga42 N,O5[! C/ c<n +un$ +Zch thu c a,O5
$am hMn hp cht r'n Jhan! C/n$ thEc phUn tV cPa X l
A. C2
3
C442! B. 2C442! C. C
3
2
`
C442! D. C
5
2
6
C442!
Cu 43: i9t chy hon ton 5a,O7 $am hMn hp X $%m uC442,
C
5
2
3
C442, v (C442)
5
thu c m $am 2
5
4 v 5O,a65 l;t C4
5
(Jtc)!
[Ht Jhc, 5a,O7 $am hMn hp X ph1n En$ hon ton vFi Ga2C4
3
+ thu
c OO,5 l;t (Jtc) Jh; C4
5
!]i trZ cPa m l
A. ON,R $am! B. a $am! C. R,O$am! D. O5,7 $am!
+.n' 2" (T )* /H0N 1NG 7H,C
Cu 44: i9t chy hon ton `,7 $am hMn hp $%m m.t axit cacKoxylic no,
Dn chEc, m<ch hb v m.t ancol Dn chEc (c: &9 n$uySn tV cacKon tron$
phUn tV Jhc nhau) thu c N,3 mol C4
5
v N,Y mol 2
5
4! hAc hi-n ph1n
En$ e&te h:a `,7 $am hMn hp trSn vFi hi-u &ut RNn thu c m $am e&te!
]i trZ cPa m l
A. Y,NR! B. 7,O5! C. R,O7! D. 5,NY!
Cu 45: 2Mn hp X $%m axit 2C442 v axit C2
3
C442 (t_ l- mol O:O)!
vy 6,3 $am hMn hp X tc +Wn$ vFi 6,`6 $am C
5
2
6
42 (c: xwc tc 2
5
f4
Y
Hc) thu c m $am hMn hp e&te (hi-u &ut cPa cc ph1n En$ e&te ho )u
Khn$ RNn)! ]i trZ cPa m l
A. ON,O5! B. 7,YR! C. R,ON! D. O7,5N!
Cu 46: Bhi thAc hi-n ph1n En$ e&te ho O mol C2
3
C442 v O mol
C
5
2
6
42, ln$ e&te lFn nht thu c l 5g3 mol! id <t hi-u &ut cAc <i
l aNn (t;nh theo axit) Jhi ti(n hnh e&te ho O mol C2
3
C442 c,n &9 mol
C
5
2
6
42 l (Ki(t cc ph1n En$ e&te ho thAc hi-n b cTn$ nhi-t .)
A. N,3Y5! B. 5,a56! C. 5,YO5! D. N,Y67!
Cu 47: Cho hMn hp X $%m ancol metylic v hai axit cacKoxylic (no, Dn
chEc, J( ti(p nhau tron$ +#y %n$ rn$) tc +Wn$ h(t vFi Ga, $i1i ph:n$ ra
7,`5 l;t Jh; 2
5
(Jtc)! G(u un n:n$ hMn hp X (c: 2
5
f4
Y
Hc lm xwc tc)
thI cc cht tron$ hMn hp ph1n En$ v0a P vFi nhau t<o thnh 56 $am hMn
hp e&te ($i1 thi(t ph1n En$ e&te ho <t hi-u &ut ONNn)! 2ai axit tron$
hMn hp X l
G!" B#CH H$U H#NH T%&n' 8
Chuyn LTH 2014 AXIT CACBOXYLIC
A. C
3
2
`
C442 v C
Y
2
a
C442! B. C
5
2
6
C442 v C
3
2
`
C442!
C. 2C442 v C2
3
C442! D. C2
3
C442 v C
5
2
6
C442!
Cu 48: 2Mn hp [ $%m ancol no, Dn chEc X v axit cacKoxylic Dn chEc
Y, )u m<ch hb v c: cTn$ &9 n$uySn tV C, tQn$ &9 mol cPa hai cht l N,6
mol (&9 mol cPa Y lFn hDn &9 mol cPa X)! G(u 9t chy hon ton [ thI
thu c 33,7 l;t Jh; C4
5
(Jtc) v 56,5 $am 2
5
4! [Ht Jhc, n(u un n:n$
[ vFi 2
5
f4
Y
Hc d thAc hi-n ph1n En$ e&te ho (hi-u &ut l RNn) thI &9
$am e&te thu c l
A. OR,5Y! B. 3Y,5N! C. 55,RN! D. 5`,37!
Cu 49: Cho N,NY mol m.t hMn hp X $%m C2
5
kC2?C442, C2
3
C442
v C2
5
kC2?C24 ph1n En$ v0a P vFi +un$ +Zch chEa 7,Y $am Krom! [Ht
Jhc, d trun$ ho N,NY mol X c,n +Tn$ v0a P YN ml +un$ +Zch Ga42
N,`6 [! Bh9i ln$ cPa C2
5
kC2?C442 tron$ X l
A. N,`5 $am! B. O,YY $am! C. 5,RR $am! D. N,67 $am!
Cu 5: 2Mn hp X $%m m.t axit cacKoxylic no, Dn chEc, m<ch hb v
m.t ancol Dn chEc, m<ch hb! i9t chy hon ton 5O,` $am X, thu c
5N,O7 l;t Jh; C4
5
(Jtc) v OR,a $am 2
5
4! hAc hi-n ph1n En$ e&te h:a X
vFi hi-u &ut 7Nn, thu c m $am e&te! ]i trZ cPa m l
A. a,OR! B. O6,3N! C. O5,5Y! D. ON,RN!
Cu 51: 2Mn hp X $%m axit Y Dn chEc v axit Z hai chEc (Y, Z c: cTn$
&9 n$uySn tV cacKon)! Chia X thnh hai ph,n Khn$ nhau! Cho ph,n m.t tc
+Wn$ h(t vFi Ga, &inh ra Y,YR l;t Jh; 2
5
(b Jtc)! i9t chy hon ton ph,n
hai, &inh ra 57,Y $am C4
5
! C/n$ thEc cu t<o thu $pn v ph,n tr*m v) Jh9i
ln$ cPa Z tron$ hMn hp X l,n lt l
A. 244C?C442 v Y5,R7n! B. 244C?C442 v 7N,NNn!
C. 244C?C25?C442 v `N,R`n! D. 244C?C2
5
?C442 v 6Y,RRn!
Cu 52: Cho hMn hp $%m N,O mol 2C24 v N,O mol 2C442 tc +Wn$
vFi ln$ + 8$
5
4 (hoHc 8$G4
3
) tron$ +un$ +Zch G2
3
, un n:n$! fau Jhi
cc ph1n En$ x1y ra hon ton, Jh9i ln$ 8$ t<o thnh l
A. Y3,5 $am! B. ON,R $am! C. 7Y,R $am! D. 5O,7 $am!
Cu 53: run$ ho R,5 $am hMn hp $%m axit eomic v m.t axit Dn chEc
X c,n ONN ml +un$ +Zch Ga42 O,6[! G(u cho R,5 $am hMn hp trSn tc
+Wn$ vFi m.t ln$ + +un$ +Zch 8$G4
3
tron$ G2
3
, un n:n$ thI thu c
5O,7 $am 8$! Sn $pi cPa X l
A. axit acrylic! B. axit propanoic!
C. axit etanoic! D. axit metacrylic!
H!T
G!" B#CH H$U H#NH T%&n' 9