Trng THPT chuyn Nguyn Quang Diu THI TH I HC M 101

MN HO HC
thi gian lm bi: 90 pht
P N ! H"#N$ D%N $I&I
I' PH(N CH)N$ CH* T+T C& TH, -INH (44 cu, t cu 1 n cu 40):
C.u 1' Hn hp kh X gm p!p"n# "tan# b$ta%&#'%(i"n# b$t%&%in )* t+ kh,i -! ./i O
0
l &#12 3,t )h45 h!n
t!n 0#01 m!l hn hp X i h6p th7 t!n b8 -9n ph:m )h45 .! b;nh <$ng <=)h >a?OH@
0
?<A@ th; kh,i lAng
b;nh tBng thCm m gam2 Di4 t= )Ea m l:
F2 1#0 >2 &'#&2 C2&0#G H2 I#'
$i/i
3Jt )Kng thL) )h$ng )Ea )4) )h6t l C
M
H
N
&0MON P&#12 '0
M P
'#1
Qh,i lAng <$ng <=)h >a?OH@
0
tBng bRng mCO
0
OmH
0
O P 0#012'#12GG O 0#012'2&SP 1001 ga2
C.u 3: HTa tan h!n t!n G#NG gam hn hp X U <Vng b8t gm W# X"W . X"W
0
t!ng <$ng <=)h HNO
'
(J)
n*ng <A

th$ (A) 0#1I m!l NO
0
?l -9n ph:m khY <$5 nh6t@

. <$ng <=)h F2 Ch! <$ng <=)h F t4) <7ng ./i
<$ng <=)h >a?OH@
0
<A# lZ) . n$ng k[t tEa ([n kh,i lAng khKng (\i# (A) m gam hn hp ]n ^2 Di4 t= )Ea
m l
4' 0'#SI12 5' 00#NI12 C' &1#&G12 H2 &I#1G1
$i/i
X": a W: b
1NaO'0b P G#NG aP0#0G
'aONb P 0#1I bP0#0I1
m P 0'' 2 0#0I1 O 0#00 2 &N0 P 300678
C.u 9: Nh_ t` t` )h! ([n <A <$ng <=)h QOH .! <$ng <=)h Fl
0
? WO
G
@
'
2 Hian tAng M95 a l
F2 )* k[t tEa k"! t]ng# -a$ (* k[t tEa tan2 >2 )h+ )* k[t tEa k"! t]ng2
C2 )* k[t tEa k"! t]ng . )* kh ba5 lCn2 H2 khKng )* k[t tEa# )* kh ba5 lCn2
C.u 1: b!ng phTng th nghiam# (c (id$ )h[ m8t lAng nh_ kh X tinh khi[t# ngAi ta ($n n*ng <$ng <=)h
am!ni nitat be! h!2 Qh X l
F2 NO2 >2 NO
0
2 C2 N
0
O2 H2 N
0
2
$i/i
NH
G
NO
'

0 t
N
0
O

O 0H
0
O
C.u 8 : C6$ h;nh "l")t!n )Ea i!n C$
O
. C
0O
lfn lAt l :
F2 gFh'<
&0
. gFh'<
G
2 >2 gFh'<
S
G-
0
. gFh'<
0
G-
0
2
C2 gFh'<
&0
. gFh'<
0
G-
0
2 H2 gFh'<
S
G-
0
. gFh'<
G
2
C.u 6: Manh (d ;h<ng (ng l:
F2 CH
'
CH
0
CH
0
COOCHPCH
0
)ing <e5 (ng (jng ./i CH
0
PCHCOOCH
0
CH
'
2
>2 CH
'
CH
0
COOCHPCH
0
t4) <7ng ./i <$ng <=)h NaOH th$ (A) an("hit . m$,i2
C2 CH
'
CH
0
COOCHPCH
0
t4) <7ng (A) ./i <$ng <=)h >
0
2
H2 CH
'
CH
0
COOCHPCH
0
)* thc ting hp tV! p!lim"2
C.u 7: He5 )4) i!n M[p th"! )hid$ gi9m <fn tnh !Mi h!4 l
F2 Fg
O
#C$
0O
#Mg
0O
# X"
'O
#X"
0O
2 > Mg
0O
# X"
'O
# C$
0O
# Fg
O
# X"
0O
2
C2 Fg
O
# X"
'O
# C$
0O
# X"
0O
# Mg
0O
2 H2 X"
'O
# Fg
O
# C$
0O
# Mg
0O
# X"
0O
2
C.u =: Fni!n X

. )ati!n k
+ 0
(d$ )* )6$ h;nh "l")t!n gi,ng ./i )6$ h;nh "l")t!n )Ea ag!n ? F@2 l= t
)Ea )4) ng$5Cn t, t!ng b9ng t$fn h!n )4) ng$5Cn t, h*a hZ) l:
F2 X )* -, thL tm &I# )h$ kn G# nh*m looF ?pNC loo@q k )* -, thL tm 00# )h$ kn G# nh*m ooF ?pNC oo@2
>2 X )* -, thL tm &S# )h$ kn '# nh*m loF ?pNC lo@q k )* -, thL tm 00# )h$ kn G# nh*m ooF ?pNC oo@2
C2 X )* -, thL tm &I# )h$ kn '# nh*m looF ?pNC loo@q k )* -, thL tm 00# )h$kn G# nh*m ooF ?pNC oo@2
H2 X )* -, thL tm &S# )h$ kn '# nh*m looF ?pNC loo@q k )* -, thL tm 00# )h$kn '# nh*m ooF ?pNC oo@2
&
C.u >: Qhi (,t )h45 h!n t!n m8t amin (rn )hL) X# th$ (A) &N#S lt kh CO
0
# 0#S lt kh N
0
?)4) thc t)h
kh (! U (kt)@ . 00#01 gam H
0
O2 CKng thL) phsn tY )Ea X l
F2 C
'
H
I
N2 >2 C
0
H
I
N2 C2 C
'
H
9
N2 H2 C
G
H
9
N2
$i/i
C
M
H
5
N O O
0
t MCO
0
O 0#15H
0
O O 0#1N
0

0#I1 &#&01 0#&01
M P ' 5 P9
C.u 10: Ch! <e5 )4) )h6t: ph"n5l aM"tat# .in5laM"tat# anl5l aM"tat# "t5la)5lat# m"t5laM"tat# "t5l u!mat#
tipanmitin2 W, )h6t t!ng <e5 khi thE5 phsn t!ng <$ng <=)h NaOH ?<A@# ($n n*ng -inh a an)!l l:
F2 G >2 ' C2 1 H2 N
C.u 11' H6p th7 h!n t!n G#GS lt CO
0
?(kt)@ .! &00 ml <$ng <=)h gm Q
0
CO
'
0#GM . QOH M m!lvlt #
-a$ khi )4) ph9n Lng M95 a h!n t!n th$ (A) <$ng <=)h k2 Ch! t!n b8 k t4) <7ng ./i <$ng <=)h
>a?NO
'
@
0
?<A@# th$ (A) 0'#NG gam k[t tEa2 Di4 t= )Ea M l:
F2 0#0 > 2 0#S C2 0#G H2 &#G
$i/i
nCO
0
P 0#0 m!l
n>aCO
'
P 0#&0
nCO
'
0%
P 0#0G Pw W, m!l CO
'
0%
<! CO
0
-inh a l P 0#&0 x 0#0G P 0#0S m!l
CO
0
O 0OH

t CO
'
0
0#0S y 0#&N y 0#0S
CO
0
O OH

t HCO
'

? 0#0%0#0S@t0#&0t 0#&0
t\ng m!l OH

P 0#0S m!l
M P 0#0Sv0#& P 0#S
C.u 13: 3,t )h45 h!n t!n 0#00 gam m8t "-t" X ? tV! nCn t` m8t aMit )a)b!M5li) (rn )hL) . m8t an)!l
(rn )hL)@ th$ (A) 0#GG gam CO
0
. 0#&S gam H
0
O2 W, "-t" (ng phsn )Ea X l:
F2 0 >2 1 C2 N H2G
$i/i
nCO
0
P 0#0& q nH
0
O P 0#0& t "-t" n!# (rn
t C
n
H
0n
O
0
t nCO
0
0#0&vn %%%%%0#0&
t M P 0#00nv0#0& P 00n
z &Gn O '0 P 00n t n P G t "-t" C
G
H
S
O
0
)* G (ng phsn "-t"2
C.u 19: Ch! G00 gam m8t l!Vi )h6t b{! )* )h+ -, aMit bRng I t4) <7ng .`a (E ./i m8t lAng NaOH# th$
(A) G&1#& gam hn hp m$,i khan2 Qh,i lAng NaOH (e tham gia ph9n Lng l:
F2 '& gam >2 N0 gam C2 N0 gam H2 '&#G1 gam
$i/i
DZi -, m!l NaOH l a
)h+ -, aMit l I nCn -, m!l NaOH <ing t$ng hTa aMit ?-, m!l QOH@l: G00 M IM &0
%'
v1N P 0#01m!l
-, m!l H
0
O tV! a: 0#01 m!l
-, m!l NaOH pL ti"-t": a x 0#01 -, m!l gliM"!l th$ (A): ?a%0#01@v'
3|>bQ|: m?)h6t b{!@ O m NaOH P m m$,i O mgliM"!l O m H
0
O
G00 O G0a P G&1#& O 90 ?a%0#01@v' O &S M 0#01 aP &#11 m NaOH P 63 ga2
0
C.u 11: H}n '#'N lt hn hp kh X gm hai hi(!)a)b!n .! b;nh (mng <$ng <=)h b!m ?<A@2 Wa$ khi ph9n
Lng M95 a h!n t!n# )* S gam b!m (e ph9n Lng . )Tn lVi 0#0G lt kh2 N[$ (,t )h45 h!n t!n '#'N lt X
th; -inh a 1#N lt kh CO
0
2 CKng thL) phsn tY )Ea hai hi(!)a)b!n l ?bi[t )4) thc t)h
kh (d$ (! U (kt)@
F2 CH
G
. C
0
H
G
2 >2 CH
G
. C
'
H
G
2 C2 CH
G
. C
'
H
N
2 H2 C
0
H
N
. C
'
H
N
2
$i/i
Qh )Tn lVi l ankan C
n
H
0nO0
: 0#& m!l
C
M
H
5
)Tn lVi: 0#01 m!l q n >
0
P 0#01 Pw C
M
H
5
l ank"n: C
m
H
0m
0#&n O 0#01m P 0#01 0n O m P 1 Pw n P& q m P '
C.u 18: Ch! )4) ph9n Lng -a$:
a@ X"O O HNO
'
?(J)# n*ng@ t
b@ X"W O H
0
WO
G
?(J)# n*ng@ t
)@ Fl
0
O
'
O HNO
'
?(J)# n*ng@ t
<@ C$ O <$ng <=)h X"Cl
'
t
"@ CH
'
CHO O H
0

t Ni#
u@ gl$)!~r O FgNO
'
?h!J) Fg
0
O@ t!ng <$ng <=)h NH
'
t
g@ C
0
H
G
O >
0
t
h@ gliM"!l ?gliM"in@ O C$?OH@
0
t
k@ X"
0
O
'
O HNO
' (J)# n*ng
t
He5 gm )4) ph9n Lng (d$ th$8) l!Vi ph9n Lng !Mi h*a % khY l:
F2 a# b# <# "# u# k2 >2 a# b# <# "# u# g 2 C2 a# b# )# <# k# h2 H2 a# b# )# <# "# g2
C.u 16: Qhi n$ng hn hp )4) )h6t X"?OH@
0#
X"?NO
'
@
0
# X"?OH@
'
. X"CO
'
t!ng khKng kh ([n kh,i lAng
khKng (\i# th$ (A) m8t )h6t ]n l
F2 X"
'
O
G
2 >2 X"O2 C2 X"2 H2 X"
0
O
'
2
C.u 17: M8t hi(!)a)b!n X )* )Kng thL) phsn tY C
1
H
&0
# khi ("m t4) <7ng ./i )l! th"! t+ la m!l &:& ? (E
(id$ kian @ tV! a G -9n ph:m th[ )hLa & ng$5Cn tY )l! t!ng phsn tY2 tCn )Ea X l
F2i-!p"ntan2 >2 n"!p"ntan2 C2 p"ntan2 H2 0#0%(im"t5lp!pan2
C.u 1=: Ch! &'#0 gam m8t an("hit X (rn )hL)# mV)h hU ph9n Lng ./i lAng <A FgNO
'
?h!J) Fg
0
O@
t!ng <$ng <=)h NH
'
# ($n n*ng2 |Ang Fg -inh a )h! ph9n Lng h[t ./i aMit HNO
'
l!eng# th!4t a G#GS lt
kh NO ?-9n ph:m khY <$5 nh6t# (! U 0 atm# 0I'
0
C @2 CKng thL) )6$ tV! th$ gZn )Ea X l
F2 CH
'
CHO2 >2 HCHO2 2 CH
'
CH
0
CHO2 H2 CH
0
P CH%CHO2
$i/i
? N[$ l HCHO: HCHO t GFg 'Fg O GHNO
'
t 'FgNO
'
O NO O 0H
0
O
0#GG t &#IN &#IN t 0#1SI
3d )h! nNO P 0#0 Pw l!Vi
%CHO: CHO t 0Fg 'Fg O GHNO
'
t 'FgNO
'
O NO O H
0
O
0#' t 0#N 0#N y 0#0
M
CHO
P &'#0v0#' P GG Pw CH
'
CHO
C.u 1>: HTa tan h!n t!n 0G gam hn hp X"# C$ ?t+ la m!l &:&@ bRng aMit HNO
'
# th$ (A) l lt ?U (kt)@
hn hp kh X ?gm NO . NO
0
@ . <$ng <=)h k ?)h+ )hLa hai m$,i . aMit <A@2 b+ kh,i )Ea X (,i ./i O
0
bRng &#&SI12 Di4 t= )Ea l l
F2 &&#02 >2 S#9N2 C2 1#N02 H2 N#I02
$i/i
'
1Na O NGa P 0G a P 0#0
" nhAng P 0#02'O0#020 P &
M hh kh P &#&SI1 2 '0 P 'S 4p <7ng $i t]) (Ang )h{! Pw nNO : nNO
0
P &:&
nNO P nNO
0
P M P2 'M O M P & P2w M P 0#01 l P ? 0#01 O 0#01@ 200#G P 1103
C.u 30: Hi(at h*a 0 ank"n )h+ tV! thnh 0 an)!l ?A$@2 Hai ank"n (* l
F2 0%m"t5lp!p"n . b$t%&%"n ?h!J) b$t"n%&@2 >2 p!p"n . b$t%0%"n ?h!J) b$t"n%0@2
C2 "t"n . b$t%0%"n ?h!J) b$t"n%0@2 H2 "t"n . b$t%&%"n ?h!J) b$t"n%&@2
C.u 31: Ch! <e5 )4) )h6t . i!n: Cl
0
# X
0
# WO
0
# C# Na
O
# N
0
# Ca
0O
# X"
0O
# Fl
'O
# Mn
0O
# W
0
# HCl# Cl
%
2 W, )h6t
. i!n t!ng <e5 (d$ )* tnh !Mi h!4 . tnh khY l
F2 S2 >2 I 2 C2 N2 H2 12
C.u 33: Ch! t`ng )h6t: X"Cl
0
# X"# X"O# X"?OH@
0
# X"?OH@
'
# X"
'
O
G
# X"
0
O
'
# X"?NO
'
@
0
# X"?NO
'
@
'
# X"WO
G
#
X"
0
?WO
G
@
'
# X"CO
'
lfn lAt ph9n Lng ./i HNO
'
(J)# n*ng2 W, ph9n Lng th$8) l!Vi ph9n Lng !Mi h!4 % khY l
F2 92 >2 I2 C2 S 2 H2 N2
C.u 39: Ch! 0#0 m!l an("hit X t4) <7ng ./i lAng <A FgNO
'
?h!J) Fg
0
O@ t!ng <$ng <=)h NH
'
# ($n n*ng
th$ (A) SN#G gam Fg2 Hi(! h!4 X th$ (A) k# bi[t 0#0 m!l k ph9n Lng .`a (E ./i &1#N gam kali2 CKng
thL) )6$ tV! th$ gZn )Ea X l ?)h! Q P 0'# Fg P &0S@
F2 HCHO2 >2 CH
'
CHO2 C2 OHC%CHO 2 H2 CH
'
CH?OH@CHO2
$i/i
0#0 m!l k ph9n Lng .`a (E ./i 0#G m!l kali Pw k )* 0 nh*m OH ? l!Vi F# >@
-, m!l an<"h5t P 0#0q nFg P 0#S Pw ChZn C
C.u 31: H6p th7 h!n t!n &#'GG lt kh CO
0
?(kt)@ .! 0 lt <$ng <=)h gm NaOH 0#001M . Ca?OH@
0
0#0&01M# th$ (A) M gam k[t tEa2 Di4 t= )Ea M l
F2 0#12 >2 &#I12 C2 0#002 H2 &#012
Gii
nCO
0
P 0#0N
nNaOH P 0#01 q nCa?OH@
0
P 0#001 t nOH
%
P 0#&
CO
0
O OH
%
t HCO
'
%
0#0N%%%%%0#0N%%%%%%0#0N
t nOH
%
?<A@ P 0#& x 0#0N P 0#0G
HCO
'
%
O OH
%
t CO
'
0%
O H
0
O2
0#0N 0#0G%%%%0#0G
Ca
0O
O CO
'
0%
t CaCO
'

0#001 0#0G 0#001

t m k[t tEa P 0#0012&00 P 308 ga2'
C.u 38: Hian tAng M95 a khi nh_ .i giZt <$ng <=)h H
0
WO
G
.! <$ng <=)h Na
0
CO
G
l:
F2 H$ng <=)h )h$5cn t` m$ .ng -a$ khKng m$
>2 H$ng <=)h )h$5cn t` m$ <a )am -ang m$ .ng2
C2 H$ng <=)h )h$5cn t` m$ .ng -ang m$ <a )am2
H2 H$ng <=)h )h$5cn t` khKng m$ -ang m$ <a )am
C.u 36: Hp )h6t h$ )r F )* Cbpb C
I
H
S
O ? phsn tY )* .Tng b"n~"n@2 F )* M (ng phsn )6$ tV!# t!ng -,
(* )* 5 (ng phsn )6$ tV! t4) <7ng ./i nati nhAng khKng t4) <7ng ./i <$ng <=)h NaOH2 Di4 t= M . 5 lfn
lAt l
F2 1 . '2 >2 G . & 2
C2 G . '2 H21 . &2
$i/i
G
CH
'
C
N
H
G
OH ? .= t !# m# p@ : ' CbCb
C
N
H
1
CH
0
OH
C
N
H
1
OCH
'
C.u 37: 3ian phsn <$ng <=)h C$Cl0 ./i (ian )m) tr# -a$ m8t thi gian th$ (A) 0#NG gam C$ U )atKt .
m8t lAng kh X U anKt2 H6p th7 h!n t!n lAng kh X tCn .! G00 ml <$ng <=)h QOH ?U nhiat (8 thAng@2
Wa$ ph9n Lng# nng (8 QOH )Tn lVi l 0#&1M ?gi9 thi[t thc t)h <$ng <=)h khKng tha5 (\i@2 Nng (8 ban (f$
)Ea <$ng <=)h QOH l ?)h! C$ P NG@
F2 0#&1M2 >2 0#0M 2 C2 0#&M2 H2 0#01M2
$i/i
nC$ P nCl
0
P 0#0& 2 DZi M l -, m!l QOH ban (f$
0QOH Cl
0
t QCl O QClO O H
0
O
M 0#0&
0#00 0#0&
M%0#00

M % 0#00 P 0#&120#G P 0#0N Pw M P 0#0S gQOHh P 0#0Sv0#G P 003M
C.u 3=: W9n ph:m h$ )r )Ea ph9n Lng n! -a$ (s5 ;h<ng <ing (c )h[ tV! tr t\ng hp
F2 bing hp .in5l Mian$a2 >2 bing ngAng aMit %amin!)ap!i)2
C2 bing hp m"t5l m"ta)5lat' H2 bing ngAng h"Mam"t5l"n(iamin ./i aMit a(ipi)2
C.u 3>: ph4t bic$ ;h<ng (ng l:
F2 FMit aM"ti) ph9n Lng ./i <$ng <=)h QOH# l65 <$ng <=)h m$,i .`a tV! a )h! t4) <7ng ./i kh CO0
lVi th$ (A) aMit aM"ti)2
>2 ph"n!l ph9n Lng ./i <$ng <=)h QOH# l65 m$,i .`a tV! a )h! t4) <7ng ./i <$ng <=)h HCl lVi th$
(A) ph"n!l2
C2 Fnilin ph9n Lng ./i <$ng <=)h HCl# l65 m$,i .`a tV! a )h! t4) <7ng ./i <$ng <=)h QOH lVi th$
(A) anilin2
H2 H$ng <=)h kali ph"n!lat ph9n Lng ./i kh CO0# l65 k[t tEa .`a tV! a )h! t4) <7ng ./i <$ng <=)h
QOH lVi th$ (A) kali ph"n!lat2
C.u 90: b\ng ha -, ?)4) -, ng$5Cn# t,i gi9n@ )Ea t6t )9 )4) )h6t t!ng phArng t;nh ph9n Lng gia X" ./i
<$ng <=)h HNO
'
(J)# n*ng ? -9n ph:m khY <a5 nh6t l N
0
@l
F2 II 2 >2 1S2 C2 NN2 H2 GS2
$i/i
&0X" O 'NHNO
'
t &0X"?NO
'
@
'
O 'N
0
O &S H
0
O
C.u 91: %amin!aMit X )hLa m8t nh*m %NH02 Ch! '0#9 gam X t4) <7ng ./i aMit HCl ?<A@# th$ (A) G&#S1
gam m$,i khan2 CKng thL) )6$ tV! th$ gZn )Ea X l
F2 H
0
NCH
0
COOH2 >2 H
0
NCH
0
CH
0
COOH2
C2 CH
'
CH
0
CH?NH
0
@COOH2 H2 CH
'
CH?NH
0
@COOH2
$i/i
nHCl P
' # 0
1 # 'N
9 # '0 S1 # G&
=

M
X
P
&0'
' # 0
9 # '0
=
Pw O G1O &N P &0' @A B @ 13 Pw C
C.u 93: H! tan &&#0 gam X" bRng <$ng <=)h H
0
WO
G
l!eng ?<A@# th$ (A) <$ng <=)h X2 H$ng <=)h X ph9n
Lng .`a (E ./i M gam <$ng <=)h QMnO
G
'&#N2 Di4 t= )Ea M l
F2 G02 >2 00 2 C2 &02 H2 '02
$i/i
1
X"
0O
t X"
'O
O &" Mn
OI
O 1" t Mn
0#0 0#0 0#0G 0#0 m
<<
P
00
N # '&
&00 2 &1S 2 0G # 0
=
C.u 99: Ch! m gam tinh b8t lCn m"n thnh an)!l ?A$@ "t5li) ./i hia$ -$6t 902 b!n b8 lAng CO
0
-inh
a (A) h6p th7 h!n t!n .! <$ng <=)h Ca?OH@
0
# th$ (A) 1N0 gam k[t tEa . <$ng <=)h X2 3$n k <$ng
<=)h X th$ thCm (A) 010 gam k[t tEa2 Di4 t= )Ea m l
F2 1N02 >2 10G2 C2 91G 2 H2 I102
$i/i
nCaCO
'
P 1#N Pw nCO
0
P 1#N m!l
nCaCO
'
P 0#1 Pw nCa?HCO
'
@
0
P 0#1 Pw nCO
0
P 1 m!l
b\ng m!l CO
0
P 1#N O 1 P &0#N
?C
N
H
&0
O
1
@
n
t C
N
H
&0
O
N
t 0CO
0

1#' 1#' &0#N
M P 1#'2 &N02&00v90 P >81
C.u 91: Ch! <e5 )4) )h6t: Ca?HCO
'
@
0
# NH
G
Cl# ?NH
G
@
0
CO
'
# ^nWO
G
# Fl?OH@
'
# ^n?OH@
0
2 C?OH@
'
# CCl
0
#
NaCl# Wn?OH@
0
# pb?OH@
0
# QHCO
'
# QHW2 W, )h6t t!ng <e5 )* tnh )h6t lAng tnh l
F2 I2 >2 &02 C2 S2 H2 9 2
C.u 98' X phTng h*a &I#N gam m"t5lp!pi!nat bRng S0 g <$ng <=)h NaOH G2 Wa$ khi ph9n Lng M95 a
h!n t!n# )K )Vn <$ng <=)h th$ (A) )h6t ]n khan )* kh,i lAng l
F2 S#1N gam2 >2 '#0S gam2 C2 I#NS gam 2 H2 &9#0 gam2
$i/i
W, m!l "-t" P 0#0
W, m!l NaOH P 0#0S
Ch6t ]n l C
0
H
1
COONa P 0#0S 2 9N P 706=
C.u 96: Hn hp X gm aMit HCOOH . aMit CH
'
COOH ?t+ la m!l &:&@2 |65 &0#N gam hn hp X t4) <7ng
./i &&#1 gam C
0
H
1
OH ?)* M) t4) H
0
WO
G
(J)@ th$ (A) m gam hn hp "-t" ?hia$ -$6t )Ea )4) ph9n Lng
"-t" h!4 (d$ bRng S0@2 Di4 t= )Ea m l ?)h! H P &# C P &0# O P &N@
F2 &0#&02 >2 N#GS2 C2 S#&02 H2 &0#9N 2
$i/i
M
hh P
1'
0
N0 GN
=
+

COOH P 1' Pw P S
b\ng -, m!l aMit P &0#N v1' P 0#0
W, m!l an)!l P &&#1vGN P 0#01 Pw an)!l <A
-, m!l "-t" P 0#0 Pw m "-t" P 0#0 ? S O GG O 09@ 2S0v&00 P 130>6
? COOC
0
H
1
@
C.u 97: 3,t )h45 h!n t!n M m!l aMit h$ )r X (A) 0M m!l CO
0
2 MJt kh4)# (c t$ng hTa M m!l X )fn .`a
(E 0M m!l QOH2 CKng thL) )6$ tV! th$ gZn )Ea k l
F2 HOOC%CH
0
xCH
0
%COOH2 >2 C
0
H
1
%COOH2
C2 CH
'
%COOH2 H2 HOOC%COOH2
C.u 9=: bhE5 phsn h[t m gam t"tap"ptit Fla%Fla%Fla%Fla ?mV)h hU@ th$ (A) hn hp gm 1N#9N gam Fla#
NG gam Fla%Fla . 11#GG gam Fla%Fla%Fla2 Di4 t= )Ea m l
F2 &N'#0S2 >2 &&&#IG2 C2 S&#1G2 H2 NN#GG2
Gii
nFla P
=
S9
9N # 1N
0#NG q nFla%Fla P
=
&S 0 2 S9
NG
0#G q nFla%Fla%Fla P
=
'N ' 2 S9
GG # 11
0#0G
t nFla%Fla%Fla%Fla P ?0#NG O 0#G20 O 0#0G2' @v G P 0#1G
m P ?S92G x &S2'@20#1G P 16900= ga2'
N
C.u 9>: Ch! b,n <$ng <=)h )* )ing nng (8 m!l : ?&@ H
0
NCH
0
COOH# ?0@ CH
'
COOH# ?'@ CH
'
CH
0
NH
0
#
?G@ HCOOH2 He5 M[p th"! thL tm pH tBng <fn l:
F2 ?'@# ?&@# ?G@# ?0@ >2 ?&@# ?0@# ?G@#?'@ C2 ?G@# ?0@ # ?'@ # ?&@ H2 ?G@ ?0@# ?&@# ?'@
C.u 10: Ch! m gam hn hp X"# Fl .! G00 ml <$ng <=)h X )hLa hn hp aMit HCl &M . aMit H
0
WO
G
0#1M# th$ (A) S#9&10 lt H
0
?U (kt)@ . <$ng <=)h k ?)!i thc t)h <$ng <=)h khKng (\i@2 H$ng <=)h k )* pH
l
F2 &2 >2 N2 C2 I2 H2 0 2
Gii
nH
0
P 0#'9S Pw nH P 0#I9N
nH
O
P 0#S
Pw H
O
<A P 0#00G m!l Pw gH
O
h P 0#00Gv0#G P 0#0& Pw pH P 0
II' PH(N BICN$: D 10 c.u E
Th sinh ch c lm mt trn! h"i #h$n (%h$n & h'c %h$n ()
4' ThFG chHng IrJnh ChuKn ( 10 cu, t cu 41 n cu )0):
C.u 11: Ch! l$ng kh H
0
?<A@ $a hn hp )4) !Mit Fl
0
O
'
# C$O# X"
0
O
'
# ^nO# MgO n$ng U nhiat (8 )a!2
Wa$ ph9n Lng hn hp ]n )Tn lVi l:
F2 C$# X"# ^n# Fl
0
O
'
#

MgO2 >2 C$# X"# Fl# ^nO# MgO2
C2 C$# X"# ^n# Fl#Mg2 H2 C$# X"O# Fl# ^nO# MgO2
C.u 13: 3c )hLng minh t!ng phsn tY )Ea gl$)!~r )* nhid$ nh*m hi(!M5l# ngAi ta )h! <$ng <=)h gl$)!~r
ph9n Lng ./i
F2 kim l!Vi Na2
>2 FgNO
'
?h!J) Fg
0
O@ t!ng <$ng <=)h NH
'
# ($n n*ng2
C2 C$?OH@
0
t!ng NaOH# ($n n*ng2
H2 C$?OH@
0
U nhiat (8 thAng2
C.u 19: bhm) hian )4) th nghiam ./i hn hp gm Fg . C$ ?hn hp X@:
?a@ Ch! X .! b;nh )hLa m8t lAng <A kh O
'
?U (id$ kian thAng@
?b@ Ch! X .! m8t lAng <A <$ng <=)h HNO
'
?(J)@
?)@ Ch! X .! m8t lAng <A <$ng <=)h HCl ?khKng )* mJt O
0
@
?<@ Ch! X .! m8t lAng <A <$ng <=)h X"Cl
'
bh nghiam m C$ b= !Mi h*a )Tn Fg khKng b= !Mi h*a l:
F2 ?a@ >2 ?b@ C2 ?<@ H2 ?)@
C.u 11: Qhi t4)h nA/) t` m8t )h6t X )* )Kng thL) phsn tY C
G
H
&0
O tV! thnh ba ank"n l (ng phsn )Ea
nha$ ?tnh )9 (ng phsn h;nh hZ)@2 CKng thL) )6$ tV! th$ gZn )Ea X l
F2 ?CH
'
@
'
COH2 >2 CH
'
OCH
0
CH
0
CH
'
2
C2 CH
'
CH?OH@CH
0
CH
'
2 H2 CH
'
CH?CH
'
@CH
0
OH2
C.u 18: H! tan h!n t!n 1#N0 gam hn hp gm X"
0
O
'
# MgO# ^nO t!ng 100 ml aMit H
0
WO
G
0#0M ?.`a
(E@2 Wa$ ph9n Lng# hn hp m$,i -$nuat khan th$ (A) khi )K )Vn <$ng <=)h )* kh,i lAng l
F2 N#S& gam2 >2 9#N0 gam2 C2 I#N0 gam2 H2 &'#N0 gam 2
Gii
m P 1#N0 O 0#120#02 9N x 0#120#02 &N P 19063
I
C.u 16: He5 gm )4) kim l!Vi (A) (id$ )h[ t!ng )Kng nghiap bRng phArng ph4p (ian phsn hp )h6t
n*ng )h95 )Ea )hng# l:
F2 Q # Ca# Fl2 >2 Q# Ca# ^n2 C2 Q# C$# Fl2 H2 X"# Ca# Fl2
C.u 17: He5 gm )4) )h6t (d$ t4) <7ng ./i FgNO
'
?h!J) Fg
0
O@ t!ng <$ng <=)h NH
'
# l:
F2 an("hit aM"ti)# b$t%&%in# b$t%0%in%# "til"n2 >2 an("hit aM"ti)# aM"til"n# p!p"n# b$t%&%in2
C2 aMit u!mi)# b$t%&%in# .in5laM"til"n# p!pin2 H2 an("hit u!mi)# p!pin# aM"til"n# "til"n2
C.u 1=: Hn hp X gm C
0
H
0
. H
0
)* )ing -, m!l2 |65 m8t lAng hh X )h! $a )h6t M) t4) n$ng n*ng#
th$ (A) hh k gm C
0
H
G
# C
0
H
N
# C
0
H
0
. H
0
2 W7) k .! << b!m ?<A@ th; kh,i lAng b;nh b!m tBng 0&#N
gam . th!4t a S#9N lt hh kh ?(kt)@ )* t+ kh,i -! ./i H
0
l S2 bhc t)h O
0
?(kt)@ )fn (c (,t )h45 h!n t!n
hn hp k l
F2 00#G lt2 >2 NI#0 lt2 C2 0N#SS lt2 H2 ''#N lt'
$i/i
nC
0
H
0
P nH
0
P a
mX P mk P 0&#N O 0#G2&N P 0Sgam
t 0Sa P 0S t a P 0Sv0S P &
? b9! t!n ng$5Cn t, C . H@ t 3,t )h45 k )ng nhA (,t )h45 X t nO
0
P & 20 O & P '
l O
0
P ' 200#G P 6703 LMI'
C.u 1>: bi[n hnh )4) th nghiam -a$:
?&@ Ch! <$ng <=)h NaOH .! <$ng <=)h Ca?HCO
'
@
0
2
?0@ Ch! <$ng <=)h NH
'
([n <A .! <$ng <=)h C$Cl
0

?'@ W7) kh H
0
W .! <$ng <=)h X"Cl
0
2
?G@ W7) kh NH
'
t/i <A .! <$ng <=)h FlCl
'
2
?1@ W7) kh CO
0
t/i <A .! <$ng <=)h NaFlO
0
?h!J) NagFl?OH@
G
h@2
?N@ W7) kh "til"n .! <$ng <=)h QMnO
G
2
?I@ W7) kh H
0
W .! <$ng <=)h C$Cl
0

?S@ W7) kh )l! .! <$ng <=)h NaOH
?9@ Ch! "tanal .! <$ng <=)h ba)nitat t!ng am!nia)
Wa$ khi )4) ph9n Lng k[t th)# )* ba! nhiC$ th nghiam th$ (A) k[t tEa
F2 I2 >2 G2 C2 12 H2 N2
Gii
O Ca?HCO
'
@
0
O NaOH t CaCO
'
O Na
0
CO
'
O H
0
O
O FlCl
'
O NH
'
O H
0
O t Fl?OH@
'
O NH
G
Cl
O NaFlO
0
O CO
0
O H
0
O t Fl?OH@
'
O NaHCO
'
O C
0
H
G O
QMnO
G
O H
0
O t C
0
H
G
?OH@
0
O MnO
0
O QOH2
?I@ W7) kh H
0
W .! <$ng <=)h C$Cl
0

?9@ Ch! "tanal .! <$ng <=)h ba)nitat t!ng am!nia)
C.u 80: 3,t )h45 h!n t!n m8t lAng )h6t h$ )r X th$ (A) N#I0 lt kh CO
0
# &#&0 lt kh N
0
?)4) kh (! U
(kt)@ . N#' gam H
0
O2 Qhi X t4) <7ng ./i <$ng <=)h QOH th$ (A) -9n ph:m )* m$,i H
0
N%CH
0
%COOQ2
CKng thL) )6$ tV! th$ gZn )Ea X l
F2 H
0
N%CH
0
%COO%C
'
H
I
2 >2 H
0
N%CH
0
%COO%CH
'
2
C2 H
0
N%CH
0
%CH
0
%COOH2 H2 H
0
N%CH
0
%COO%C
0
H
1
2
C
M
H
5
O
0
N O O
0
t MCO
0
O 0#15 H
0
O O 0#1 N
0

0#' 0#'1 0#01
M P '
5 P I
5' ThFG chHng IrJnh n.ng caG (10 cu, t cu )1 n cu *0):
S
C.u 81: 3,t )h45 h!n t!n a m!l aMit )a)b!M5li) # th$ (A) b m!l CO
0
. ) m!l H
0
O ?./i ) P b x a@2 Ch!
a m!l t4) <7ng ./i NaHCO
'
?<A@ th$ (A) b m!l CO
0
2 bCn )Ea l
F2 aMit a)5li)2 >2 aMit !Mali)' C2 aMit a(ipi)2 H2 aMit u!mi)2
Gii
W, C t$ng b;nh P nCO
0
vnaMit P bva
W, nh*m COOH P nCO
0
vnaMit P bva
t Ch6t )* -, C P -, nh*m )hL) ? l!Vi F# C@
FMit u!mi) )h45 )* nCO
0
P nH
0
O ?l!Vi H@ t )hZn >
C.u 83: ph4t bic$ ;h<ng (ng l:
F2 Hp )h6t C?oo@ )* tnh khY (J) tAng )Tn hp )h6t C?lo@ )* tnh !Mi h!4 mVnh2
>2 C4) hp )h6t C
0
O
'
# C?OH@
'
# ^nO# Fl?OH@
'
(d$ )* tnh )h6t lAng tnh2
C2 C4) hp )h6t CO# C?OH@
0
t4) <7ng (A) ./i <$ng <=)h HCl )Tn CO
'
t4) <7ng (A) ./i
<$ng <=)h QOH2
H2 bhCm <$ng <=)h kidm .! m$,i )!mat# m$,i n5 )h$5cn thnh m$,i (i)!mat2
C.u 89: 3c th$ l65 Fg tinh khi[t t` hn hp X ?gm a m!l Fl
0
O
'
# b m!l C$O# 0#&1 m!l Fg
0
O@# ngAi ta h!
tan X bUi <$ng <=)h )hLa ?Na O 0b O 0#'@ m!l HNO
'
(A) <$ng <=)h k# -a$ (* thCm ?gi9 thi[t hia$ -$6t )4)
ph9n Lng (d$ l &00@
F2 ~ m!l b8t Fl .! k2 >2 0#&1 m!l b8t C$ .! k2
C2 0~ m!l b8t Fl .! k2 H2 0~ m!l b8t C$ .! k2
Gii
Fl
0
O
'
O NHCl t 0FlCl
'
O 'H
0
O
a Na
C$O O 0HCl t C$Cl
0
O H
0
O
b 0b
Fg
0
O O 0HNO
'
t 0FgNO
'
O H
0
O
0#&1 0#' 0#'
C$ O 0FgNO
'
t C$?NO
'
@
0
O 0Fg
0#&1 0#'
C.u 81: Ch! )4) )h6t: HCN# H
0
# <$ng <=)h QMnO
G
# <$ng <=)h >
0
2 W, )h6t ph9n Lng (A) ./i
"t5lm"t5lM"t!n l
F2 02 >2 G2 C2 &2 H2 '2
C.u 88: C* G <$ng <=)h m$,i iCng biat: C$Cl
0
# NiCl
0
#MgCl
0
# ^nCl
0
# X"Cl
'
# FlCl
'
2 N[$ thCm <$ng <=)h
NH
'
?<A@ .! G <$ng <=)h tCn th; -, )h6t k[t tEa th$ (A) l
F2 12 >2 ' 2 C2 G2 H2 02
C.u 86: M8t "-t" )* )Kng thL) phsn tY l C
G
H
N
O
0
# khi th$ phsn t!ng mKi tAng aMit th$ (A) aM"t!n2
CKng thL) )6$ tV! th$ gZn )Ea "-t" (* l
F2 CH
0
PCH%COO%CH
'
2 >2 HCOO%C?CH
'
@PCH
0
2
C2 HCOO%CHPCH%CH
'
2 H2 HCOO%CHPCH
0
2
C.u 87: b!ng )* th nghiam -a$ :
?&@ Ch! WiO
0
t4) <7ng ./i aMit HX2
?0@ Ch! kh WO
0
t4) <7ng ./i kh H
0
W2
?'@ Ch! kh NH
'
t4) <7ng ./i C$O ($n n*ng2
?G@ Ch! CaOCl
0
t4) <7ng ./i <$ng <=)h HCl (J)2
?1@ Ch! Wi (rn )h6t t4) <7ng ./i <$ng <=)h NaOH2
?N@ Ch! kh O
'
t4) <7ng ./i Fg2
?I@ Ch! <$ng <=)h NH
G
Cl t4) <7ng ./i <$ng <=)h NaNO
0
($n n*ng2
?S@ Ch! X" .! <$ng <=)h HCl
W, th nghiam tV! a (rn )h6t l:
F2 G >2 I C2 N H2 1
9
Gii
O WiO
0
O HX t WiX
G
O H
0
O
O WO
0
O H
0
W t W O H
0
O
O NH
'
O C$O t C$ O N
0
O H
0
O
O CaOCl
0
O HCl t CaCl
0
O Cl
0
O H
0
O
O Wi O NaOH O H
0
O t Na
0
WiO
'
O H
0
O Fg O O
'
t Fg
0
O O O
0
O NH
G
Cl O NaNO
0
t NaCl O N
0
O H
0
O
O Ch! X" .! <$ng <=)h HCl
t C* I th nghiam tV! a (rn )h6t2
C.u 8=: Nh*m nhng )h6t kh ?h!J) hri@ n! <A/i (s5 (d$ gs5 hia$ Lng nh knh khi nng (8 )Ea )hng
t!ng kh $5dn .At $4 tiC$ )h$:n )h! ph{p
F2 O
0
. CO >2 CO
0
. O
'
C2 C
0
H
G
. H
0
O H2CO
0
. CH
G
Gii
CO
0
. CH
G
(d$ gs5 hia$ Lng nh knh2
C.u 8>: bhE5 phsn h!n t!n &00 gam hn hp hai (ip"tit th$ (A) &0I#0 gam hn hp X gm )4) amin!
aMit ?)4) amin! aMit )h+ )* m8t nh*m amin! . m8t nh*m )a)b!M5l t!ng phsn tY@2 N[$ )h! hn hp X t4)
<7ng ./i <$ng <=)h HCl ?<A@# )K )Vn ):n thn <$ng <=)h# th; lAng m$,i khan th$ (A) l :
F2 I#09 gam2 >2 I0#9 gam C2 S#&1 gam H2 &1N#G gam2
Gii
0(ip"tit O 0H
0
O t F
&
O F
0
O F
'
O F
G

m H
0
O P &0I#0 x &00 P I#0 t n H
0
O P I#0v&S P 0#G
W, m!l & amin! aMit l 0#0
b\ng m!l amin! aMit l 0#0 MG P 0#S
t n HCl P n amin!aMit P 0#S
t m m$,i P m amin!aMit O m HCl P &0I#0 O 0#S2'N#1 P 18601 ga2'
C.u 60: HTa tan hn hp b8t gm a gam C$ . G#NG gam X"
'
O
G
.! <$ng <=)h H
0
WO
G
?l!eng# 6t <A@ -a$ khi
)4) ph9n Lng k[t th) )h+ th$ (A) <$ng <=)h X2 H$ng <=)h X lm m6t m$ .`a (E 00 gam <$ng <=)h
QMnO
G
&1#S2 Di4 t= )Ea a l:
F2 0#1N >2 '#0 C2 0#NG H20#9N
Gii
n X"
'
O
G
P 0#00 q n QMnO
G
P 0#00
X"
'
O
G
O SH
O
t X"
0O
O 0X"
'O
O GH
0
O
0#00%%%%%%%%%%%%%%0#00%%%%%0#0G
C$ O 0X"
'O
t C$
0O
O 0X"
0O
M%%%%%%%%%%%%%%%%%%%%%%%%%%%%0M
t n X"
0O
P 0#00 O 0M
1X"
0O
O MnO
G
%
O SH
O
t 1X"
'O
O Mn
0O
O GH
0
O
0#&%%%%%%%0#00
t 0#00 O 0M P 0#& t M P 0#0G q l5 mC$ P 0#0G2NG P 0#1N gam2
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% Hb %%%%%%%%%%
&0