Phn tch dung dch m hp kim ng thit

Phn tch dung dch m hp kim ng thic pirophotphat

Xc nh hm lng ng

Ht 5 mL mu
Erlen 250 mL 50 mL nc ct
5 git ch th PAN
Chun bng EDTA 0.1M ti khi dung dch c mu xanh l
0.1 0.0635 1000
( / ) 1.27
5
EDTA
EDTA
xV x x
Cu g L V
Xc nh hm lng thic
Ht 5 mL mu
Erlen 250 mL 50 mL nc ct
10 mL m 5
30 mL urotropin 10%
6 git Xylenol Cam
Chun bng Zn
2+
0.05M ti khi dung dch xut hin mu xanh cam
25 mL EDTA 0.05M
un si, ngui
2
2
4
0.05 (25 ) 0.1187 1000
( / ) 1.187 (25 )
5
Zn
Zn
x V x x
Sn g L x V

Xc nh hm lng tng gc pirophotphat
Ht 1 mL mu
Erlen 250 mL 50 mL nc ct
20 mL Zn(CH
3
COO)
2
5%
( trung ho theo MO)
Chun bng NaOH 0.1N ti khi dung dch c mu vng
2 git MO
Thm H2SO4 n
dung dch mu vng
Dung dch m ng thic xianua
Phn tch ng
Ht 2 mL mu vo erlen 250 mL
un nng ti khi c khi trng
50 mL nc ct
5 git ch th PAN
Chun bng EDTA 0.2M ti khi dung dch c mu xanh l
25 mL EDTA 0.05M
100 mL nc ct + NH3 ti dung
dch mu xanh dng
0.2 0.0635 1000
( / ) 6.35
2
0.2 0.0895 1000
( / ) 8.95
2
EDTA
EDTA
EDTA
EDTA
xV x x
Cu g L V
xV x x
CuCN g L V


Ht 2 mL mu
Erlen 250 mL 50 mL nc ct
Chun bng AgNO
3
0.1N ti khi dung dch c
kt ta mu vng
2 mL KI 10%
3
3
O
O
0.1 x0.049x1000
( / ) 4.9
2
AgN
AgN
xV
NaCN g L V
Ly dung dch va
xc nh HCl
nh mc 250mL. Lc
ly dch lc
20 mL BaCl
2
10%
Ht 50 mL dung dch lc
0.2 x0.04x1000 250
( / ) . 20
2 50
HCl
HCl
xV
NaOH g L V
2 git PP
Chun bng HCl 0.2N ti dung dich khng mu