S Gio Dc & o To

TP. H CH MNH
Trng PTTH Chuyn L Hng Phong

K THI OLYMPIC TRUYN THNG 30/4
LN VIII - NM 2002
MN HA HC KHI
Thi gian lm bi: 180 pht
Ghi ch : Th sinh lm mi cu trn 1 hay nhiu t giy ring v ghi r cu s ...... trang 1 c!a mi t
giy lm "i

C!"
Nguyn t ca nguyn t A c b 4 s long t ca electron cui (electron cht cng) l:
n= 2; l = 1; m = - 1; ms = -
a/ Vit cu hnh electron, xc djnh vj tr ca A trong bng h thng tun hon?
b/ Vit cng thc cu to mt dng don cht ca A c cng thc phn t l A3. Vit cng thc cu to
dng don cht d v cho bit trng thi lai ha ca nguyn t trung tm.
c/ Mt dng don cht khc ca A c cng thc phn t l A2. Hy gii thch tnh thun t ca phn t
ny?
C!" 2
1. C cn bng sau: N2O4 (k) = 2NO2 (k)
a/ Cho 18,4 gam N2O4 vo bnh kn dung tch 5,904 lt 27C. Lc cn bng, p sut ca hn hop kh
trong bnh l 1 atm. Tnh p sut ring phn ca NO2 v N2O4 lc cn bng?
b/ Nu gim p sut ca h lc cn bng xung cn 0,5 atm th p sut ring phn ca NO2 v N2O4 lc
ny l bao nhiu? Kt qu c ph hop vi nguyn l Le Chtelier hay khng?
2. A l dung djch HCl 0,2 M; B l dung djch NaOH 0,2 M; C l dung djch CH3COOH 0,2 M (c hng s axit
Ka = 1,8 x 10
- 5
). Cc th nghim sau du thuc hin ti 25C.
a/ Tnh pH ca mi dung djch A, B, C.
b/ Tnh pH ca dung djch X l dung djch to thnh khi trn dung djch B vi dung djch C theo ti l th tch
1:1
c/ Tnh th tch dung djch B (theo mL) cn thm vo 20 mL dung djch A d thu doc dung djch c pH =
10.
C!" 3
1. Mui nguyn cht Y mu trng tan trong nc. Dung djch Y khng phn ng vi H2SO4 long, nhng
phn ng vi HCl cho kt ta trng tan trong dung djch NH3. Nu sau d axit ha dung djch to thnh
bng HNO3 li c kt ta trng xut hin tr li. Cho Cu vo dung djch Y, thm H2SO4 v dun nng th c
kh mu nu bay ra v xut hin kt ta den.
Hy cho bit tn ca Y v vit cc phn ng xy ra di dng phong trnh ion rt gon.
2. Mt hn hop gm Cu v Fe c ti l khi long 7:3. Ly m (gam) hn hop ny cho phn ng hon ton
vi dung djch HNO3 thy d c 44,1 gam HNO3 phn ng, thu doc 0,75m (gam) rn, dung djch B v 5,6
lt hn hop kh (diu kin tiu chun) gm NO v NO2. Hi c cn dung djch B thu doc bao nhiu gam
mui khan?
3. in phn 1 lt dung djch NaCl (D = 1,2 g/cm
3
) chi thu doc mt cht kh din cuc. C cn dung djch
sau din phn cn li 125 gam cht rn khan. Nhit phn cht rn ny thy khi long gim 8 gam. Tnh:
a/ Hiu sut ca qu trnh din phn?
b/ Nng d % v nng d mol/lt ca dung djch NaCl ban du?
c/ Khi long dung djch cn li sau din phn?
C!" 4
Vit cc phong trnh phn ng theo so d chuyn ha sau:
giai don chuyn B2 thnh B3, nu c rt t Br2, ngoi B3 ngi ta cn thu doc mt long nh ankan B4
khc. Hy xc djnh B4 v gii thch su to thnh B4?
C!" #
t chy hon ton mt hidrocacbon A thu doc CO2 v H2O theo ti l mol 9:4. Khi ha hoi 11,6 gam A th
th tch hoi chim 2,24 lt (quy v diu kin tiu chun). Mt khc A c th tc dng vi dung djch brom
theo ti l mol 1:2. A cng to kt ta khi tc dng vi dung djch AgNO3/NH3. Khi oxi ha A bng dung djch
KMnO4 trong H2SO4 to doc axit thom cha 26,23% oxi v khi long.
a/ Hy xc djnh cng thc cu to v goi tn A?
b/ B l mt dng dng k tip ca A c hot tnh quang hoc. Vit cng thc cu to v goi tn B?
(Cho: Cu = 64; Fe = 56; N = 14; O = 16; H =1; Na = 23; Cl = 35,5; C = 12)
H$T