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Tk
BAI TP PHENOL
CTTQ CnH2n-7(OH)
I. ng ng - ng phn - danh php
Bi 1. Hp cht thm X c CTPT l C7H8O
a, S n ph!n c"a hp cht thm X l#
$. % B. & C. ' (. )
*, S n ph!n c"a X c ph+n ,n -.i /a l#
$. % B. & C. ' (. )
c, S n ph!n c"a X -0a ph+n ,n -.i /a -0a ph+n ,n -.i
/aOH l#
$. & B. 1 C. % (. '
Bi %. Hp cht thm X c CTPT l C8H11O
a, S n ph!n 2h3n t4c 56n -.i /a - /aOH l#
$. ' B. ) C. 7 (. 7
*, S n ph!n X th8a m9n : :a; l#
X < /aOH 2h3n ph+n ,n

(1) (2)
1
Y Y
p=lim>
$. 1 B. % C. & (. '
Bi &. Hp cht h?; c X c c3n th,c C7H7O%. Bi@t X t4c
56n -.i AOH th>= tB lC : m=l 1#%, DEF : n ph!n c;
tG= c"a X l#
$. 1 B. % C. & (. '
Bi '. Ch= ph>n=l HXI, pJcK>L=l HCH&JC7H'JOHI HMI, K; *>nLFlic
HNI. COp cht n= :a; !F l n Pn c"a nha; Q
$. X - M B. X - N C. M - N (. X,M - N
Bi ). TRn c"a hp cht CH& l#

Cl
OH
$. %Jcl=J'm>tFl ph>n=l B. 1Jm>tFlJ&Jcl=
ph>n=l '
C. 'Jm>tFlJ%Jcl= ph>n=l (. 1Jcl=J&Jm>tFl
ph>n=lJ'
II. Tnh cht vt l
Bi 1 . C!; n= :a; !F 2h3n Sn Q
$. Ph>n=l cTn c liRn 2@t hi5K= liRn ph!n tU
B. Ph>n=l c liRn 2@t hi5K= -.i n.c
C. /hiCt V :3i c"a ph>n=l thp hn nhiCt V :3i c"a
>tFl*>L>n
(. Ph>n=l Wt tan tK=n n.c lGnh
Bi %. Th, tX tYn 5Zn V ta tK=n n.c c"a 59F n= :a; !F
Sn Q
$. *>L>n [ ph>n=l [ >tan=l B. *>nL>n [
>tan=l [ ph>n=l
C. ph>n=l [*>nL>n [ >tan=l (. >tan=l [ *>nL>n [
ph>n=l
Bi &. Cht n= :a; !F c liRn 2@t hi5K= nVi ph!n tU Q
$. =JnitK=ph>n=l B. mJnitK=ph>n=l C. pJnitK=ph>n=l
(. C+ $ - B
Bi '. X\t liRn 2@t hi5K= c tK=n c4c n ph!n c"a ]JC7H'J
OH
1.
O O
H
]

%.
O ^ H
. . .
]
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O J H
. . .
. . .
]
&.
. . .
] O ^ H
. . .
] O ^ H
. . .
_iRn 2@t n= c *i`; 5ian Sn Q
$. 1 B. % C. % - & (. 1, % -
&
Bi ). Ch= c4c cht# *>nL>n, =JnitK= ph>n=l, pJnitK= ph>n=l.
/hiCt V :3i c"a c4c cht tYn 5Zn th>= th, tX n= :a; !F Q
$. *>nL>n [ =Jn=tK= ph>n=l [ pJnitK= ph>n=l B.
*>nL>n [ pJnitK=ph>n=l [ =JnitK= ph>n=l
C. pJnitK=ph>n=l [ =JnitK= ph>n=l [ *>nL>n (. =JnitK=
ph>n=l [ *nL>n [ pJnitK=ph>n=l
III. Tnh cht ha hc
A. S chuyn ha - PTHH
Bi 1. Ch= 59F ch;F`n ha :a;#
T=l;>n
0
2
/ / Br Fe NaOH t p HCl
B C D .DEF ( l#
$. B>nLFl cl=K;a B. mJb>tFl
ph>n=l
C. =Jb>tFl ph>n=l - pJm>tFl ph>n=l (. =J
cl=t=l;>n - pJcl=t=l;>n
Bi %. Cht h?; c M c CTCT# C8H11O. M ph+n ,n -.i C;O, t
=
tG= :+n phcm c 2h+ nYn ph+n ,n tK4n n - th8a m9n :
#
(1) (2)
1
Y Y
p=li:tiK>n. DEF CTCT c"a M l# CH%JOH
$. C7H)JCH%CH%OH B. H&CJCHJOH C. (.
C7H)JOJCH%JCH&
CH&
Bi &. Hp cht h?; c X c id; ch@ t0 >tFl*>nL>n th>= :
#
! 2 4 2 " 4
0
2 4 2 4
/
# " 2 "

HNO H SO C H OH KMnO
H SO H SO t
C H C H A B X
+

. DEF CTCT c"a X l#
$. =J/O%JC7H'JCOOC%H) B. mJ/O%J
C7H'JCOOC%H)
C. ph+n ,nJ/O%JC7H'JCOOC%H) (. C+ $
- C
Bi '. Ch= c4c ph+n ,n :a;#
H$I < HBI HCI < H(I e HCI < HfI /hXa ph>n=l g=manRhit
HfI < O% HHI e HhI HiI < HAI
HiI H_I e H_I < Cl% HbI < HBI
HbI < H/I HCI < H(I e /a < H]I H/I < HAI
DEF $, h, b c th` l#
$. C%H)O/a, C%H7, C%H)Cl B. C7H)OH,
C&H8, C&H7Cl
C. C7H)O/a, CH', C7H)Cl (. j4p 4n
2h4c
Bi ). Ch= : :a;# OH
CH' X1 X% X& X' DEF X%, X&, X' lZn lt l#
$. C7H7, C7H)BK, C7H)O/a B. C%H%, C7H7,
C7H)BK
C. CH&OH, HCHO, C7H7 (. C7H7,
C7H)BK, C7H)BK%
Bi 7. Ph+n ,n n= :a; !F 2h3n Sn Q
$. OH
OH
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< &BK% H55I BK BK < &HBK
BK
OH OH
B. < %BK% H55I BK BK < %HBK
CH& CH&
C. OH
OH
< %BK% H55I BK BK < %HBK
CH&
CH&
(. OH OH
CH& < %BK% H55I BK CH& < %HBK
BK
Bi 7. Ch= : *i@n ha#
C7H7 X C7H)OH M C7H)OH . DEF X, M lZn lt l#
$. C7H)Cl, C7H)/O% B. C7H)/H%, C7H)O/a
C. C7H)Cl

, C7H)O/a

(. C7H)COOH, C7H)BK
Bi 8. Ph>n=l 2h3n ph+n ,n -.i cht n= :a; !F Q
$. /a - 55 /aOH B. /.c BK% C. 55 /aCl (. Hkn hp
H/O& - H%SO' Oc
Bi l. Ph>n=l c th` ph+n ,n -.i cht n= :a; !F Q)
$. 55 /aOH, /a B. 55 BK%, 55 H/O& C. 55
C%H)COOH, 55 H%SO' (. $, B Sn
Bi 11. _F 11,7) ph>n=l ch= ph+n ,n h@t -.i n.c *K=m 5,
hiC; :;t ph+n ,n 7'm. Ahi ln 2@t t"a tKnn th; c *on
*a= nhiR; HtK=n c4c i4 tKp :a;I#
$. %7,'8 B. 7',7) C. '1,&7) (. C+ $, B, C d; :ai
Bi 11. Ch= 18,8 am ph>n=l t4c 56n -.i ') am 5;n 5pch
H/O& 7&m HH%SO' Oc lm qSc t4c - ;n nne hiC; :;t
111mI. H8i 2hi ln aqit picKic H%,',7JtKinitK= ph>n=lI th; c l
*a= nhiR; HtK=n c4c i4 tKp :a;I#
$. )1 B. &',&) C. &) (. '),8)
Bi 1%. jt ch4F h=n t=n hkn hp HXI m % ph>n=l HMI - HNI
n Pn 2@ ti@p nha; th; c 8&,7 CO% - 18 H%O.
Trn : m=l c"a HMI - HNI th; c *on *a= nhiR; HtK=n c4c
i4 tKp :a;I#
$. 1,& m=l B. 1,%) m=l C. 1,% m=l (. 1,1) m=l
Bi 1&. TK;n hsa h@t l,' am ph>n=l *on D ml 5;n 5pch
/aOH 1b HlF 5 11m := -.i ln cZn 5tnI. H8i D c i4 tKp *a=
nhiR; H tK=n c4c : :a;I#
$. 81ml B. l1ml C. 111ml (.
11)ml
Bi 1'. _Zn lt c4c cht C%H)Cl, C%H)OH, C7H)OH -= 5;n
5pch /aOH n nn. H8i mF cht c ph+n ,n Q
$. Ah3n cht n= B. bVt cht C. Hai cht
(. C+ *a cht
Bi 1). Th;c thU 5;F nht c th` 5tn ` ph!n *iCt *a cht
l8n# ph>n=l, :tiK>n - K; *>nLFlic l#
$. /a B. 55 /aOH C. 55 BK% (. u;v
tWm
Bi 17. j` ph!n *iCt ph>n=l - K; *>nLFlic c th` 5tn th;c
thU n= Q
$. 55 BK% B. /a C. 55 /aOH (. C+ $
- C
Bi 17. Ph>n=l ph+n ,n c -.i 59F cht n= :a; !F#
$. CH&COOH, /a%CO&, /aOH, /a, 55 BK%, H/O& B.
HCHO, /a%CO&, 55 BK%, /aOH. /a
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C. HCHO, H/O&, 55 BK%, /aOH, /a (. C+ $, B,
C
Bi 18. Ch= 1),) hkn hp % ph>n=l $ - B liRn ti@p nha; tK=n
59F n Pn c"a ph>n=l t4c 56n -0a " -.i 1,) lWt 5;n
5pch /aOH 1,&b. C3n th,c ph!n tU c"a % ph>n=l - m 2hi
ln c"a hkn hp l#
$. C7H7OH H7l,78mI - C8HlOH

H&1,&%mI B.
C7H)OH

H7l,78mI - C7H7OH

H&1,&%mI
C. C7H)OH

H&1,&%mI - C7H7OH

H7l,78mI (. A@t
w;+ 2h4c


ch;FRn d l;FCn thi Gi hxc Jtn J-JtJwJt
BAI TP PHENOL
CTTQ CnH2n-7(OH)
I. ng ng - ng phn - danh php
Bi 1. Hp cht thm X c CTPT l C7H8O
a, S n ph!n c"a hp cht thm X l#
$. % B. & C. ' (. )
*, S n ph!n c"a X c ph+n ,n -.i /a l#
$. % B. & C. ' (. )
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c, (H-C-K-!""#I S n ph!n c"a X ph+n ,n c -.i
/aOH l#
$. & B. 1 C. % (. '
Bi %. Hp cht thm X c CTPT l C8H11O
a, S n ph!n 2h3n t4c 56n -.i /a - /aOH l#
$. ' B. ) C. 7 (. 7
*, S n ph!n X th8a m9n : :a; l#
X < /aOH 2h3n ph+n ,n

(1) (2)
1
Y Y
p=lim>
$. 1 B. % C. & (. '
Bi &. Hp cht h?; c X c c3n th,c C7H7O%. Bi@t X t4c
56n -.i AOH th>= tB lC : m=l 1#%, DEF : n ph!n c;
tG= c"a X l#
$. 1 B. % C. & (. '
Bi '. Ch= ph>n=l HXI, pJcK>L=l HCH&JC7H'JOHI HMI, K; *>nLFlic
HNI. COp cht n= :a; !F l n Pn c"a nha; Q
$. X - M B. X - N C. M - N (. X,M - N
Bi ). TRn c"a hp cht CH& l#

Cl
OH
$. %Jcl=J'Jm>tFl ph>n=l B. 1Jm>tFlJ&Jcl=
ph>n=lJ '
C. 'Jm>tFlJ%Jcl= ph>n=l (. 1Jcl=J&Jm>tFl
ph>n=lJ'
II. Tnh cht vt l
Bi 7 . C!; n= :a; !F 2h3n Sn Q
$. Ph>n=l cTn c liRn 2@t hi5K= liRn ph!n tU
B. Ph>n=l c liRn 2@t hi5K= -.i n.c
C. /hiCt V :3i c"a ph>n=l thp hn nhiCt V :3i c"a
>tFl*>L>n
(. Ph>n=l Wt tan tK=n n.c lGnh
Bi 7. Th, tX tYn 5Zn V tan tK=n n.c c"a 59F n= :a; !F
Sn Q
$. *>L>n [ ph>n=l [ >tan=l B. *>nL>n [
>tan=l [ ph>n=l
C. ph>n=l [*>nL>n [ >tan=l (. >tan=l [ *>nL>n [
ph>n=l
Bi 8. Cht n= :a; !F c liRn 2@t hi5K= nVi ph!n tU Q
$. =JnitK=ph>n=l B. mJnitK=ph>n=l C. pJ
nitK=ph>n=l (. C+ $ - B
Bi l. Ch= c4c cht# *>nL>n, =JnitK= ph>n=l, pJnitK= ph>n=l.
/hiCt V :3i c"a c4c cht tYn 5Zn th>= th, tX n= :a; !F Q
$. *>nL>n [ =JnitK= ph>n=l [ pJnitK= ph>n=l B.
*>nL>n [ pJnitK=ph>n=l [ =JnitK= ph>n=l
C. pJnitK=ph>n=l [ =JnitK= ph>n=l [ *>nL>n (. =JnitK=
ph>n=l [ *nL>n [ pJnitK=ph>n=l
Bi11.(T$-!""#I PhRn=l l8n - K; >tFlic d; ph+n ,n c
-.i
$. 55 /aOH B.55 BK% C.55 /a%CO&
(. 2im l=Gi /a
III. Tnh cht ha hc
A. S chuyn ha - PTHH
Bi 11. Ch= 59F ch;F`n ha :a;#
T=l;>n
0
2
/ / Br Fe NaOH t p HCl
B C D .DEF ( l#
$. B>nLFl cl=K;a B. mJb>tFl
ph>n=l
C. =Jb>tFl ph>n=l - pJm>tFl ph>n=l (. =J
cl=t=l;>n - pJcl=t=l;>n
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Bi1 %. Cht h?; c M c CTCT# C8H11O. M ph+n ,n -.i C;O,
t
=
tG= :+n phcm c 2h+ nYn ph+n ,n tK4n n - th8a m9n
: #
(1) (2)
1
Y Y
p=li:tiK>n. DEF CTCT c"a M l# CH%JOH
$. C7H)JCH%CH%OH B. H&CJCHJOH C. (.
C7H)JOJCH%JCH&
CH&
Bi 1&. Hp cht h?; c X c id; ch@ t0 >tFl*>nL>n th>= :
#
! 2 4 2 " 4
0
2 4 2 4
/
# " 2 "

HNO H SO C H OH KMnO
H SO H SO t
C H C H A B X
+

. DEF CTCT c"a X l#
$. =J/O%JC7H'JCOOC%H) B. mJ/O%J
C7H'JCOOC%H)
C. ph+n ,nJ/O%JC7H'JCOOC%H) (. C+ $
- C
Bi1'. Ch= c4c ph+n ,n :a;#
H$I < HBI HCI < H(I e HCI < HfI /hXa ph>n=l
g=manRhit
HfI < O% HHI e HhI HiI < HAI
HiI H_I e H_I < Cl% HbI < HBI
HbI < H/I HCI < H(I e /a < H]I H/I < HAI
DEF $, h, b c th` l#
$. C%H)O/a, C%H7, C%H)Cl B. C7H)OH,
C&H8, C&H7Cl
C. C7H)O/a, CH', C7H)Cl (. j4p 4n
2h4c
Bi 1). Ch= : :a;# OH
CH' X1 X% X& X' DEF X%, X&, X'
lZn lt l#
$. C7H7, C7H)BK, C7H)O/a B. C%H%, C7H7,
C7H)BK
C. CH&OH, HCHO, C7H7 (. C7H7,
C7H)BK, C7H)BK
Bi 17. Ch= : *i@n ha# C7H7 X C7H)OH M
C7H)OH . DEF X, M lZn lt l#
$. C7H)Cl, C7H)/O% B. C7H)/H%,
C7H)O/a
C. C7H)Cl

, C7H)O/a

(. C7H)COOH,
C7H)BK
Bi 17. Ph>n=l 2h3n ph+n ,n -.i cht n= :a; !F Q
$. /a - 55 /aOH B. /.c BK% C. 55 /aCl (. Hkn
hp H/O& - H%SO' Oc
Bi 18. Ph>n=l c th` ph+n ,n -.i cht n= :a; !F Q
$. 55 /aOH, /a B. 55 BK%, 55 H/O& C. 55
C%H)COOH, 55 H%SO' (. $, B Sn Bi 1l. Ch= lZn lt c4c
cht C%H)Cl, C%H)OH, C7H)OH -= 5;n 5pch /aOH ;n
nn. DEF mF cht c ph+n ,n Q
$. Ah3n cht n= B. 1 cht C. % cht (.
C+ & cht
Bi %1. Ph>n=l ph+n ,n c -.i 59F cht n= :a; !F#
$. CH&COOH, /a%CO&, /aOH, /a, 55 BK%, H/O& B.
HCHO, /a%CO&, 55 BK%, /aOH. /a
C. HCHO, H/O&, 55 BK%, /aOH, /a (. C+ $,
B,C
B. nhn bi- b!i p "# ph$n%&
Bi %1. j` ph!n *iCt ph>n=l - K; *>nLFlic c th` 5tn
th;c thU n= Q
$. 55 BK% B. /a C. 55 /aOH (.
C+ $ - C
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Bi %%. Th;c thU 5;F nht c th` 5tn ` ph!n *iCt *a
cht l8n# ph>n=l, :tiK>n - K; *>nLFlic l#
$. /a B. 55 /aOH C. 55 BK% (.
u;v tWm
Bi %&. j` ph!n *iCt ph>n=l - K; *>nLFlic c th` 5tn th;c
thU n= Q
$. 55 BK% B. /a C. 55 /aOH (.
C+ $ - C
Bi %'. _F 11,7) ph>n=l ch= ph+n ,n h@t -.i n.c *K=m 5,
hiC; :;t ph+n ,n 7'm. Ahi ln 2@t t"a tKnn th; c *on
*a= nhiR; HtK=n c4c i4 tKp :a;I#
$. %7,'8 B. 7',7) C. '1,&7)
(. C+ $, B, C d; :ai
Bi %). Ch= 18,8 am ph>n=l t4c 56n -.i ') am 5;n 5pch
H/O& 7&m HH%SO' Oc lm qSc t4c - ;n nne hiC; :;t
111mI. H8i 2hi ln aqit picKic H%,',7JtKinitK= ph>n=lI th; c l
*a= nhiR; HtK=n c4c i4 tKp :a;I#
$. )1 B. &',&) C. &) (. '),8)
Bi %7. jt ch4F h=n t=n hkn hp HXI m % ph>n=l HMI - HNI
n Pn 2@ ti@p nha; th; c 8&,7 CO% - 18 H%O.
Trn : m=l c"a HMI - HNI th; c *on *a= nhiR; HtK=n c4c
i4 tKp :a;I#
$. 1,& m=l B. 1,%) m=l C. 1,% m=l (. 1,1)
m=l
Bi %7. TK;n hsa h@t l,' am ph>n=l *on D ml 5;n 5pch
/aOH 1b HlF 5 11m := -.i ln cZn 5tnI. H8i D c i4 tKp *a=
nhiR; H tK=n c4c : :a;I#
$. 81ml B. l1ml C. 111ml (.
11)ml
Bi %8. Ch= 1),) hkn hp % ph>n=l $ - B liRn ti@p nha; tK=n
59F n Pn c"a ph>n=l t4c 56n -0a " -.i 1,) lWt 5;n
5pch /aOH 1,&b. C3n th,c ph!n tU c"a % ph>n=l - m 2hi
ln c"a hkn hp l#
$. C7H7OH H7l,78mI - C8HlOH

H&1,&%mI B.
C7H)OH

H7l,78mI - C7H7OH

H&1,&%mI
C. C7H)OH

H&1,&%mI - C7H7OH

H7l,78mI (. A@t
w;+ 2h4c
%&' tp a('n-an'l'n
CT Amin no n chc bc 1 CnH2+3N hay CnH2n+1NH2
Amin thm (cha 1 vng benzen) n chc bc 1 CnH2n!
"NH2#
Bi 1. a, C
'
H
11
/ c *a= nhiR; n ph!n Q
$.7 B.7 C.8 (. .l
*, C
'
H
11
/ c *a= nhiR; n ph!n *Ec h Q
$.& B. ' C.. ) (. 7
Bi %. $min n= 5.i !F c ' n c; tG= Q
$. C
%
H
7
/ B. C
&
H
l
/ C. C
'
H
11
/ (.
C
)
H
1&
/
Bi &. C
7
H
l
/ c *a= nhiR; n ph!n thm Q
$. 1 B. % C. & (. '
Bi '. $min n= 5.i !F l amin *Ec hh Q
$. CH
&
J CH
%
^ /H
%
B. CH
&
^ CH

^ CH
&
/H
%
C. CH& ^ /H ^ CH& (. CH& ^ / ^ CH% ^ CH&
CH&
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Bi ). C3n th,c n= :a; !F l c3n th,c ch;n c"a 59F
n Pn amin thm Hch,a 1 -sn *>nL>nI, n ch,c, *Ec
nht Q
$.CnH%nJ7/H% B. CnH%n<1/H%
C. C7H)/HCnH%n<1 (. CnH%nJ&/HCnH%nJ'
Bi 7. Ch= amin c c; tG=# CH&J CHHCH&I ^ /H%. TRn xi
Sn c"a amin l#
$. PK=pJ1JFlamin B. >tFlamin
C. jim>tFlamin (. PK=pJ%JFlamin
Bi 7. C3n th,c ph!n tU c"a i>tFl m>tFl amin l#
$. C)H1&/ B. C'H11/ C. C7H1)/
(. C)H11/
Bi 8. TRn xi c"a amin n= :a; !F 2h3n Sn Q
$. CH& ^ /H ^ CH& im>tFl amin B.
CH&CH%CH%/H% pK=panJ1Jamin
C. CH& ^ CH ^ /H% pK=pFl amin
CH& (. C7H)
^ /H% anilin
Bi l.COp anc=l - amin n= :a; !F c ctn *Ec#
$. HCH&I%CH ^ OH, HCH&I%CH ^ /H%
B. HCH&I&C ^ OH, HCH&I&C ^ /H%
C. C7H)/HCH&, C7H)CHHOHICH&
(. HC7H)I%/H, C7H)CH%OH
Bi 11. C!; n= 5.i !F 2h3n Sn Q
$. C4c amin d; c tWnh *aL
B. TWnh *aL c"a c4c amin d; mGnh hn /H&
C. $nilin c tWnh *aL F@; hn /H&
(. Tt c+ c4c amin n ch,c d; ch,a : ly n;FRn tU H
tK=n ph!n tU
Bi 11. TWnh *aL c"a cht n= :a; !F mGnh nht Q
$. C7H)/H% B. /H& C. CH&/H%
(. C&H7/H%
Bi 1%. Ch= H1I /H& ,H%Im>tFl amin , H&I anilin , H'I im>tFl
amin. TWnh *aL tYn 5Zn th>= th, tX l# $. H1I[H&I[H%I[H'I
B. H&I[H1I[H%I[H' C. H1I[H%I[H&I[H'I (. H&I[H1I[H'I[H%I
Bi 1&. Ch= c4c cht :a;#
1. C7H)/H% %. C%H)/H% &. HC%H)I%/H
'./aOH ). /H&
TKEt tX tYn 5Zn tWnh *aL c"a ) cht tKRn l#
$. H1I, H)I, H%I,H&I, H'I B. H1I,H%I,H)I,H&I,H'I C. H1I,H)I,H&I,
H%I,H'I (. H%I,H1I,H&I,H)I,H'I
Bi 1'. TWnh *aL c"a c4c cht tYn 5Zn th>= th, tX z 59F n=
:a;
$. /H&[ C7H)/H%[ CH&/HCH&[ CH&CH%/H%
B. /H&[ CH&CH%/H%[ CH&/HCH&[ C7H)/H%
C. C7H)/H%[ /H&[ CH&CH%/H%[ CH&/HCH&
(. C7H)/H%[ /H&[ CH&/HCH&[ CH&CH%/H%
Bi 1). Cht n= :a; !F c tWnh *aL mGnh nht Q
$. /H& B. C7H)/H% C. HCH&I%/H
(. HCH&I%CH/H%
Bi 17. TKEt tX tYn 5Zn tWnh *aL c"a 59F n= :a; !F
2h3n Sn Q
$. /H&[ C7H)/H% B. /H&[ CH&/H%[
CH&CH%/H%
C. CH&CH%/H%[ CH&/HCH& (. p ^
O%/C7H'/H%[ p ^ CH&C7H'/H%
Bi 17. /hEn q\t n= :a; !F 2h3n Sn Q
$. Ph>n=l l aqit csn anilin l *aL
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B. 55 ph>n=l lm w;v tWm ha 8, csn 55 anilin lm w;v tWm
ha qanh
C. Ph>n=l - $nilin d; 5a tham ia ph+n ,n th@ - d;
tG= 2@t t"a tKnn -.i 55 BK%
(. Ph>n=l - $nilin d; 2h tham ia ph+n ,n cVn - d;
tG= hp cht -sn n= 2hi cVn -.i hiK=
Bi 18. (;n 5pch cht n= 5.i !F 2h3n lm ri m; w;v
tWm
$. /H& B. CH&CH%/H% C. C7H)/H%
(. CH&CH%/HCH&
Bi 1l. (;n 5pch >tFlamin 2h3n t4c 56n -.i cht n= :a;
!F Q
$. 55 HCl B. ]>Cl& C. n.c BK% (.
C;HOHI%
Bi %1. Ch= : :a;#
CH' X C7H7 M C7H)/H% N C7H)/H%
a, X l cht n= :a; Q
$. CH&Cl B. C%H% C. C7H1% (. C7H)OH
*, M l cht n= :a; Q
$. C7H)CH& B. C7H)OH C. C7H)/O% (. C+ $,
B, C d; Sn
c, N l cht n= :a; Q
$. C7H)/H&Cl B. C7H)OH C. C7H)Cl (. C+ $, B, C
d; Sn
Bi %1. T{m c!; :ai tK=n c4c c!; :a; Q
$. >tFlamin 5a tan tK=n H%O 5= c liRn 2@t H -.i H%O#
H H
/ J H
. . .
O J H
. . .
/ J H
C%H) H C%H)
B. >tFlamin c 2h+ nYn tG= m;i -.i *aL mGnh
C. >tFlamin c 2h+ nYn tG= 2@t t"a -.i 55 ]>Cl&
(. >tFlamin c tWnh *aL 5= / csn cOp > cha liRn 2@t c 2h+
nYn nhEn H
<
Bi %%. Ch= 55 m>tFlamin ch= @n 5 lZn lt -= t0n n
nhiCm Xn c4c 55# $lCl&, ]>Cl&, NnH/O&I%, C;H/O&I%, HCl.
S cht 2@t t"a th; c l#
$. 1 B. % C. &
(. '
Bi %&. Ch= c4c 55 c4c cht :a; !F lZn lt t4c 56n -.i nha;
t0n 3i mVt# /H&, HCH&I%/H, HCl, C7H)/H&Cl, ]>Cl&. S ph+n
,n q+F Ka l#
$. 1 B. ) C. 7
(. 7
Bi %'. & lx mt nh9n ch,a KiRn K|# K; >tFlic, anilin, n.c. C th`
nhEn *i@t anilin *on#
$. H%O B. 55 /aOH C. BK% (.
C+ $, B , C d; Sn
Bi %). (tn n.c BK=m 2h3n ph!n *iCt c % cht tK=n cOp
n= :a; !F Q
$. 55 anilin - 55 /H& B. anilin -
qFcl=h>qFlaminHC7H11/H%I
C. 55 anilin - ph>n=l (. anilin -
*>nL>n
Bi %7.(H-C-K-!""#).C & cht l8n
*>nL>n,anilin,:tiK>n,Xn KiRn *iCt tK=n & lx mt nh9n.Th;c
thU ` ph!n *iCt & cht l8n tKRn l#
$. 55 ph>n=lphtal>in B.55 /aOH C. n.c BK%
(.iF w;{ tWm
Bi %7. Th;c thU tK=n 59F n= :a; !F 2h3n th` ph!n *iCt
c# ph>n=l, anilin - *>nL>n Q
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$. 55 BK% B. 55 HCl, 55 /aOH C. 55 HCl, 55 BK%(. 55
/aOH, 55 BK%
Bi %8. j` ph!n *iCt ph>n=l, anilin, *>nL>n, :itK>n n}i ta lZn
lt :U 56n c4c th;c thU z 59F n= :a; !FQ
$. u;v tWm, 55 BK% B. 55 /aOH, 55 BK% C. 55 BK%,
w;v tWm (. 55 HCl, w;v tWm
Bi %l. C th` ph!n *iCt ph>n=l - anilin *on cht n=
:a; Q
$. 55 BK% B. 55 HCl C. B>nL>n
(. H%O
Bi &1. C th` id; ch@ C%H)/H% t0 cht n= :a; !F Q
$. C%H)Cl B. C%H)/O% C. C%H)OH
(. C+ $, B, C, d; Sn
Bi &1. Ph+n ,n id; ch@ amin n= 5.i !F 2h3n hp lW Q
$. CH&h < /H& CH&/H% < Hh B. %C%H)h < /H&
HC%H)I%/H < %Hh
C. C7H)/O% < &H% C7H)/H% (. C7H)C/ < 'H
/ Fe HCl
C7H)CH%/H%
Bi &%. C th` t4ch KiRn *>nL>n - anilin *on 59F cht n=
n= Q
$. 55 /aOH, 55 BK% B. H%O, 55 HCl C. 55 HCl, 55
/aOH (. /aCl, 55 BK%
Bi &&. j` tinh ch@ anilin t0 hkn hp# ph>n=l, anilin, *>nL>n,
c4ch lm n= :a; l hp l~ Q
$. Hsa tan hkn hp tK=n 55 HCl 5, chi@t lF phn tan. ThRm
/aOH 5 - chi@t lF anilin tinh 2hi@t
B. Hsa tan hkn hp tK=n 55 BK% 5, lxc 2@t t"a, d hal=>n
ha th; c anilin
C. Hsa tan tK=n 55 /aOH 5, chi@t lF phZn tan - thri CO%
@n 5 -= th; c anilin tinh 2hi@t
(. (tn 55 /aOH ` t4ch ph>n=l, :a; 5tn BK% ` t4ch
anilin Ka 2h8i *>nL>n
Bi &'. j` l=Gi CH& ^ /H% Ka 2h8i hkn hp c ln c4c 2hW# C%H%,
C%H', C%H7, H% ta 5n hkn hp tKRn w;a 55 n= :a; Q
$. 55 H%SO' B. 55 C;H/O&I% C. 55 ]>Cl&
(. C+ $, B, C d; Sn
Bi &). X l amin n ch,c *Ec nht ch,a %&,7&m nit. CTPT
c"a X l#
$. C&H)/H% B. C'H7J/H% C. C&H7/H%
(. C)Hl/H%
Bi &7. $min n ch,c X ch,a 1l,718m nit th>= 2hi ln.
CTPT c"a X l#
$. C'H)/ B. C'H7/ C. C'Hl/ (. C'H11/
Bi &7. jt ch4F h=n t=n 1 amin n ch,c, *Ec 1 th; c
CO% - H%O th>= t lC m=l#
2 2
$
CO H O
n n
7#7. $min tRn xi
l { Q
$. pK=pFlamin B. ph>nFlamin
C .i:=pK=pFlamin (. pK=p>nFlamin
Bi &8. jt ch4F 1 59F n Pn c"a m>tFl amin th; c
2 2
$
CO H O
V V
%#&. Hth` tWch c4c 2hW = z ctn 2I. CTPT c"a
amin l#
$. C&Hl/ B. CH)/ C. C%H7/
(. C'H11/
Bi &l. jt ch4F h=n t=n 1 amin cha n=, n ch,c ch,a 1
liRn 2@t CC z mGch c4c*=n th; c CO% - H%O th>= tB lC
2 2
$
H O CO
n n
l#8. CTPT c"a amin l#
$. C&H7/ B. C'H8/ C. C'Hl/
(. C&H7/
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Bi '1. jt ch4F 1 amin n= n ch,c th; c CO% - H%O c tB
lC m=l
2 2
$
CO H O
V V
%#). $min c tRn l { Q
$. b>tFlamin B. jim>tFlamin C. TKim>tFlamin
(. i:=pK=pFlamin
Bi '1. jt ch4F h=n t=n 1 amin n ch,c n= c 1 liRn 2@t
3i z mGch C ta th; c CO% - H%O th>= tB lC m=l#
2 2
$
CO H O
V V

8#11. CTPT c"a amin l#
$. C&H7/ B. C'Hl/ C. C'H8/ (. C&H7/
Bi '%. jt ch4F h=n t=n hkn hp % amin n= n ch,c, mGch
hz, *Ec 1 2@ ti@p nha; tK=n ctn 59F n Pn th; c CO%
- H%O th>= tB lC m=l
2 2
$
CO H O
V V
1#%. Hai amin c CTPT l#
$. CH&/H%, C%H)/H% B. C%H)/H%, C&H7/H%
C. C&H7/H%, C'Hl/H% (. C'Hl/H%, C)H11/H%
Bi '&. (H-C-K*-!""#) Ahi t ch4F h=n t=n 1 amin n=
n ch,c X th; c 8,' lWt 2hW CO%, 1,' lWt 2hW /% Hc4c th`
tWch = z 2tcI - 11,1%) H%O. CTPT c"a X l#
$. C&H7/ B. C%H7/ C. C&Hl/
(. C'Hl/
Bi ''. jt ch4F h=n t=n hkn hp % amin n= n ch,c n
Pn liRn ti@p c hkn hp :+n phcm 2hW c tB lC
2 2
$
CO H O
V V

8#17 H = z ctn 2I. CTPT c"a % amin l#
$. C%H)/H%, C&H7/H% B. C&H7/H%, C'Hl/H%
C. CH&/H%, C%H)/H% (. C'Hl/H%, C)H11/H%
Bi '). jt ch4F h=n t=n 7,% 1 amin n= n ch,c th{ ph+i
5tn h@t 11,18 lWt O% H2tcI. CTPT c"a amin l#
$. C%H)/H% B. CH&/H% C. C&H7/H%
(. C'Hl/H%
Bi '7. jt ch4F h=n t=n 1 amin thm *Ec nht X th; c
1,)78 lWt CO%, 1,%&% lWt hi H%O, 1,&&7 lWt /%. j` tK;n hsa
h@t 1,1) m=l X cZn %11ml 55 HCl 1,7)b. C4c 2hW = z 2tc.
CTPT c"a X l#
$. C7H)/H% B. HC7H)I%/H C. C%H)/H
(. C7H11/&
Bi '7. jt ch4F h=n t=n m 1 amin X *on 1 ln 2h3n
2hW -0a " th; c 17,7 CO%, 1%,7 H%O - 7l,'' lWt /%
H2tcI. i+ thi@t 2h3n 2hW ch m /% - O% tK=n =qi
chi@m %1m th` tWch 2h3n 2hW. X c CTPT l#
$. C%H)/H% B. C&H7/H% C. CH&/H% (.
C'Hl/H%
Bi '8. Ch= ln 5 anilin ph+n ,n h=n t=n -.i 55 ch,a 1,1)
m=l H%SO' l=9n. Ahi ln m;i th; c *on *a= nhiR; Q
$. 7,1 B. 1',% C. 1l,1 (.
%8,'
Bi 'l. bVt hkn hp X m % amin n= n ch,c l n Pn
2@ ti@p ph+n ,n -0a " -.i 1,1 lWt 55 H%SO' 1b ch= Ka 1 hkn
hp m % m;i c 2hi ln l %1,%. Ahi ln - CTPT mki
amin l#
$. ',) %H)/H%e ),l C&H7/H% B. ',) C&H7/H%e ),l
C%H)/H%
C. &,1 CH&/H%e ',) C%H)/H% (. ',) CH&/H%e &,1
C%H)/H%
Bi )1. TK;n hsa &,1 1 amin n ch,c X cZn 111 ml 55 HCl
1b. CTPT c"a X l#
$. C%H)/ B. CH)/ C. C&Hl/ (. C&H7/
Bi )1. Ch= &,1' hkn hp % amin n= n ch,c t4c 56n -0a
" -.i 55 HCl th; c ),l7 m;i. Bi@t tK=n hkn hp : m=l %
amin *on nha;. CT % amin l#
$. CH)/, C%H7/ B. C&Hl/, C%H7/ C. C&Hl/, C'H11/
(. A@t w;+ 2h4c
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Bi )%. Ch= l,8) hkn hp % amin, n ch,c *Ec 1 t4c 56n
-0a " -.i 55 HCl th; c 18,l7) m;i. Ahi ln HCl ph+i
5tn l#
$. l,)%1 B. l,1%) C. l,%1) (.
l,)1%
Bi )&. Ch= %1 hkn hp m & amin n ch,c n Pn
2@ ti@p t4c 56n -0a " -.i 55 HCl 1b, Ki c3 cGn 55 th{ th; J
c &1,78 hkn hp m;i.
a, Th` tWch 55 HCl 9 5tn l#
$. 111ml B. )1ml C. %11ml (. &%1ml
*, CTPT c"a & amin l# HBi@t ph!n tU 2hi c4c amin d; nh8
hn 81I
$. CH&/H%, C%H)/H%, C&H7/H% B. C%H&/H%, C&H)/H%,
C'H7/H%
C. C%H)/H%, C&H7/H%, C'Hl/H% (. C&H7/H%, C'Hl/H%,
C)H1%/H%
Bi )'. Ch= 1) hkn hp & amin n ch,c, *Ec 1 t4c 56n -0a
" -.i )1ml 55 HCl 1b. Ahi ln m;i th; c c i4 tKp l#
$. 17,8%) B. %1,18 C. %1,1%&
(. Ah3n q4c pnh c