s gio dc-o to thi bnh

trng THPT nguyn du

thi TH I HOC KhI A; B NM HC 2012- 2013- LN TH 2

mn: ho hc
Ngy thi: 14/4/2013
Thi gian lm bi 90 pht khng k thi gian giao
M :132

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cu 1: Cho 4,62 gam hn hp X gm phenol v mt ancol no n chc A phn ng vi Na thu c 672 ml H 2 (kc) .
Mt khc cng 4,62 gam hn hp trn tc dng vi 150 ml dung dch KOH 0,2M. CTPT ca A l :
A. C2H5OH
B. C4H9OH
C. CH3OH
D. C3H7OH
Cu 2: Nung nng m gam hn hp X gm Al v Fe 2O3 ti phn ng hon ton, thu c cht rn Y. Nghin nh, trn
u v chia Y lm 2 phn:
- Phn 1: Cho tc dng vi dung dch NaOH n d thu c 0,336 lt H 2 (ktc) v cht rn Z. Ha tan cht rn Z
trong dung dch HCl d thu c 2,016 lt kh H2 (ktc)
- Phn 2: Cho tc dng vi dung dch HCl d thu c 7,056 lt kh H 2 (ktc). Gi tr ca m l :
A. 21,24 gam.
B. 39,6 gam.
C. 29,7 gam.
D. 13,38 gam.

Cu 3: t chy hon ton m gam hn hp gm anehit fomic, axit axetic, glucoz, glixerol thu c 21,84 lt CO 2
(ktc) v 20,25 gam nc. Thnh phn phn trm khi lng ca glixerol trong hn hp ban u l:
A. 46,7%
B. 23,4%
C. 18,4%
D. 43,8%

Cu 4: Cu hnh electron lp ngoi cng ca ion X 2+ l 3s23p63d9. V tr ca X trong bng tun hon cc nguyn t ho
hc l

A. Chu k 3, nhm IA.

B. Chu k 4, nhm IB.
C. Chu k 3, nhm VIIIA.
D. Chu k 4, nhm VIIIB.
Cu 5: Trung ho m gam dung dch axit cacboxylic n chc nng 8,64% bng m gam dung dch NaOH th thu c
dung dch cha mui nng 5,64%. Vy cng thc ca axit l:
A. CH3COOH
B. C2H3COOH
C. C3H5COOH

D. HCOOH

Cu 6: iu no sau y khng ng?

A. T visco, t axetat l t tng hp.
B. Nilon-6,6 v t capron l t poliamit.
C. Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn bin dng
khi thi tc dng.
D. T tm, bng, len, xenluloz l polime thin nhin

Cu 7: Cho 14,3 gam hn hp X gm Mg, Zn v Al ha tan ht trong V lt dung dch HNO 3 1M va thu c 9,856
lt NO2 (ktc) v dung dch Z cha 81,9 gam mui. Th tch HNO 3 cn dng l
A. 1,28 lt.
B. 1,44 lt.
C. 1,58 lt.

D. 1,51 lt.

Cu 8: Cho 500ml dung dch hn hp gm NaOH 0,2M v Ba(OH) 2 0,1M vo cc cha 200 ml dung dch AlCl 3 a (M),
khuy u, sau phn ng thu c 3,12 gam kt ta. Vy gi tr ca a l:
A. 0,2M
B. 0,25M
C. 0,3M

D. 0,4M

Cu 9: Cho 10g fomon tc dng vi lng d dung dch AgNO 3/NH3 thy xut hin 54g kt ta. Nng % ca dung
dch ny l:
A. 37,0%.

B. 37,5%

C. 39,5%.

D. 75%

Cu 10: Cho cc cht: O2; O3; O2/H2S; dung dch KCN; dung dch HCl; dung dch HNO 3 long. C bao nhiu cht phn
ng c vi Ag?
A. 4

B. 3

C. 6

D. 5

Cu 11: Cht no cha lin kt cho nhn? ( theo quy tc bt t)

A. CO
B. N2
C. HClO
D. CO2
Cu 12: Cho s sau: X + Y Na2SO4 + CO2 + H2O. Hy cho bit c bao nhiu cp X, Y tho mn?
A. 2
B. 1
C. 4
D. 3
Cu 13: Ha tan 18,72 gam hn hp X gm NaHCO 3, KHCO3, MgCO3 bng dung dch HCl d, thu c 4,48 lt kh
CO2 ( ktc). Khi lng KCl to thnh trong dung dch sau phn ng l
A. 8,94.
B. 7,92.
C. 5,96.

D. 7,02
Trang 1/5 - M thi 132

Cu 14: Trong s cc hp cht thm c cng thc phn t C 7H8O2, c bao nhiu cht tc dng vi NaOH trong dung
dch theo t l mol 1 : 2 nhit thng?
A. 8 cht
B. 7 cht

C. 5 cht

D. 6 cht

Cu 15: in phn 100ml dung dch Y gm KCl 0,1M v Cu(NO3)2 0,2M vi cng dng in 5A trong 579 giy,
in cc tr, mng ngn xp. Gi s nc bay hi khng ng k. gim khi lng ca dung dch sau khi in phn
l:
A. 1,59 gam.
B. 1,475 gam.
C. 1,67 gam.
D. 1,155 gam.

Cu 16: Cho 10,26 gam hn hp gm saccaroz v mantoz ho tan vo nc thu c dung dch X. Thu phn X
trong mi trng axit d (hiu sut mi cht u bng 80%) thu c dung dch Y. Trung ho Y bng NaOH sau thc
hin phn ng trng gng vi dung dch AgNO 3/NH3 d, sau phn ng thu c 10,8 g Ag. % khi lng ca mantoz
trong hn hp ban u l:
A. 33,33%
B. 66,67%
C. 60%
D. 40%

Cu 17: trung ha 15,9 gam hn hp A (gm mt axit cacboxylic n chc v mt axit cacboxylic hai chc) cn V
ml dung dch NaOH 0,5M. C cn dung dch sau phn ng thu c 23,6 gam cht rn khan. Ga tr ca V l:
A. 350
B. 175
C. 700
D. 400

Cu 18: Cho 32,25 gam mt mui c cng thc phn t l CH 7O4NS tc dng ht vi 750 ml dung dch NaOH 1M un
nng thy thot ra cht kh lm xanh qu tm m v thu c dung dch X ch cha cc cht v c. C cn dung dch X
thu c bao nhiu gam cht rn khan?
A. 50,0
B. 45,5
C. 35,5
D. 30,0

Cu 19: Cho 15,17 gam hn hp X gm Mg; Al; Zn v Sn tc dng vi dung dch H 2SO4 long d, sau phn ng thu
c 8,512 lt kh H2 (kc). Mt khc cng lng hn hp X trn cho tc dng vi dung dch HNO 3 c nng d, sau
phn ng thu c 18,368 lit kh NO2(kc) l sn phm kh duy nht. % khi lng ca Sn trong hn hp ban u l:
A. 23,53%
B. 78,44%
C. 54,23%
D. 47,07%

Cu 20: Hidrat hoa 7,8 gam axetilen co xuc tac HgSO 4 800C, hiu sut phan ng nay la H %. Cho toan b hn hp thu
c sau phan ng vao dung dich AgNO3 d trong NH3 thi thu c 66,96 gam kt tua. Gia tri H la:
A. 7%
B. 70%
C. 93%
D. 10,3%
Cu 21: Cho s bin ha: CH4 XY CH3COOH.
tha mn vi s bin ha trn th Y l
A. C2H5OH.
B. CH3CHO hoc CH3CH2Cl.
C. CH3CHO.
D. C2H4 hoc C2H5OH.

Cu 22: Cho dung dch AgNO3 tc dng vi dung dch cha cht tan X th c kt ta mu vng. Lc kt ta v cho
kt ta vo dung dch HNO3 th kt ta tan. X l cht no di y ?
A. K2SO4
B. H3PO4.
C. KCl

D. K3PO4

Cu 23: Nhn xt no sau y khng ng:

A. Au tan trong dung dch KCN; dung dch nc cng toan.
B. Bo qun P trng bng cch ngm trong nc.
C. in phn dung dch NaCl th catt xy ra qu trnh oxi ho H 2O
D. Nh t t dung dch H2SO4 long vo dung dch K2CrO4, thy dung dch chuyn t mu vng sang mu da cam.
Cu 24: Ha tan m(g) Fe3O4 trong 500 ml dung dch HCl 1,4M, thu c dung dch X. Sc mt lng Oxi d vo dung
dch X, thu c dung dch Y. Dung dch Y lm mt mu 100ml dung dch Br 2 0,1M. Gi tr ca m l:
A. 13,92 g.
B. 27,84 g.
C. 18,56 g.
D. 20,3 g
Tin
hnh
cc
th
nghim
sau:
Cu 25:
(a) Cho dung dch Ba(OH)2 vo dung dch NaHCO3.
(b) Cho dung dch Al2(SO4)3 ti d vo dung dch Na[Al(OH)4].
(c) Sc kh H2S ti d vo dung dch FeCl3.
(d) Sc kh H2S vo dung dch KMnO4/H2SO4 long
(e) Sc kh CO2 vo dung dch Na2SiO3.
(g) Sc kh H2S vo dung dch ZnCl2.
(h) Cho dung dch BaCl2 + dung dch Na2CrO7.
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 6
B. 4
C. 3
D. 5

Cu 26: Cho 1,94 gam hn hp A gm hai kim loi Cu, Zn c trn theo t l mol 1:2 vo 0,5 lt dung dch AgNO 3
0,1M. sau phn ng hon ton thu c m gam cht rn. Gi tr ca m l:
A. 6,04
B. 5,56
C. 5,88

D. 5,72
Trang 2/5 - M thi 132

Cu 27: t chy hon ton 17 gam hn hp X gm 1 ancol n chc v 1 este no, n chc, mch h thu c 12,32
lt CO2 (ktc) v 14,4 gam H 2O. Mt khc, nu un 17 gam hn hp X vi 150 ml dung dch KOH 0,8M, ri c cn dung
dch sau phn ng th khi lng cht rn khan thu c l:
A. 10,08 gam.
B. 11,76 gam.
C. 8,16 gam.
D. 9,96 gam.

Cu 28: Trong qu trnh hot ng ca pin in ho Zn Cu th:

A. nng ca ion Cu2+ trong dung dch tng.

B. khi lng ca in cc Zn tng.

C. khi lng ca in cc Cu gim.

D. nng ca ion Zn2+ trong dung dch tng.
Cu 29: Oxi ho 11,5 gam etanol thu c 16,1 gam hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho
ton b X tc dng vi Na (d), thu c 3,92 lt H2 (ktc). Vy % etanol b oxi ho l
A. 85%
B. 70%
C. 75%
D. 80%

Cu 30: Trn 100 ml dung dch gm Ba(OH) 2 0,1M v NaOH 0,1M vi 400 ml dung dch gm H 2SO4 0,0375M v HCl
0,0125M, thu c dung dch X. Gi tr pH ca dung dch X l:
A. 2.
B. 6.
C. 1.

D. 7.

Cu 31: Phn ng khng xy ra iu kin thng:

A. Li + N2 Li3N.
B. Hg + S HgS.
C. 2NO + O2 2NO2.
D. H2 + O2 H2O.
Cu 32: X phng ha han ton 16,4 gam hn hp hai este n chc cn 250 ml dung dch NaOH 1M. Sau phn ng,
c cn dung dch thu c hn hp hai ancol ng ng k tip v mt mui duy nht. Thnh phn phn trm v khi
lng ca hai este trong hn hp l:
A. 60% v 40%
B. 54,878% v 45,122% C. 67,683% v 32,317% D. 51,064% v 48,936%

Cu 33: Dy cc ion no sau y cng tn ti trong mt dung dch:

A. NH4+, K+, CO32-, OH-.
B. Ag+, Fe2+, NO3-, Na+.
2+
+
2C. Fe , H , NO3 , SO4 .
D. Ag+, Ba2+, F-, NO3-.
Cu 34: Polime no c cu trc mch phn nhnh ?
A. PVC
B. poli isopren
C. Amilopectin
D. PE
Cu 35: Cho 13,2 gam hn hp gm FeCO3 v FeS2 tc dng vi dung dch H2SO4 c nng d, sau phn ng thu c
hn hp kh X, dX/H2 = 28. % khi lng ca FeCO3 trong hn hp ban u l:
A. 88,28%
B. 11,72%
C. 12,12%

D. 87,88%

Cu 36: Cho dy cc cht: o-Crezol, isopren, glucoz, fructoz, mantoz, saccaroz, alanin, propanal, kh sunfur,
metylxiclopropan, xiclobutan v kh clo. S cht trong dy c kh nng lm mt mu dung dch nc brom nhit
thng l
A. 10.
B. 9.
C. 7.
D. 8.

Cu 37: Hn hp X gm hidro cacbon A th kh trong iu kin thng v oxi c trn theo t l th tch tng ng
l 2: 9. t chy hon ton hn hp X nhit cao thu c n hp kh Y gm CO 2, hi nc v oxi d, dY/H2 = 17.
S lin kt trong A l:
A. 3
B. 5
C. 6
D. 4

Cu 38: Hy sp xp cc axit sau : axit axetic (1); axit acrylic (2); phenol (3) , axit oxalic (4), axit cacbonic (5) theo trnh
t tng dn tnh axit?
A. (2) < (3) < (1) < (4) <(5)
C. (3) <(5)<(4) < (1) < (2)
Cu 39: Cho s phn ng
+ Cl 2 ( a . s )

B. (3) <(5)< (1) < (2) < (4)

D. (1) < (2) < (3) < (4) < (5)
+ CH 3COOH

+ NaOH du ,t
A

X .Tn gi ca X l:
C6H5 CH3
B
xt
A. phenl metyl ete
B. Benzyl axetat
C. metyl benzoat
D. phenyl axetat
Cu 40: C bao nhiu cp xy ra phn ng: ( triolein + I2); ( axit glutamic + C2H5OH/HCl); ( C2H5NH2 + C6H5NH3Cl);
(CH3COOH + C6H5ONa); (CH3OH + CO); ( axeton + dung dch nc Br2); ( benzen + Cl2 a/s)?
A. 4
B. 5
C. 6
D. 7
0

Cu 41: Cho 500 ml dung dch (NaOH 0,1M; KOH 0,2M) tc dng vi 200 ml dung dch H 3PO4 0,6M, sau phn ng c
cn dung dch thu c m gam cht rn khan. Gi tr ca m l:
A. 16,66 g
B. 16,78g
C. 17,56g

D. 17,2g

Cu 42: Cho cc dung dch sau cng nng mol/l : NH2CH2COOH (1), CH3COOH (2), CH3CH2NH2 (3), NH3 (4). Th
t pH tng dn l :
Trang 3/5 - M thi 132

A. (1), (2), (4), (3)

B. (1), (2), (3), (4)
Cu 43: Trong cc th nghim sau:

C. (2), (1), (4), (3)

D. (2), (1), (3), (4)

(a) O3 + dung dch KI.

(b) Ag2S + O2.
(c) NaClO + dung dch HCl c.
(d) Si + dung dch NaOH
(e) Cho kh NH3 tc dng vi kh Cl2.
(g) Cho dung dch H2O2 tc dng vi dung dch cha KMnO4 v H2SO4 (long).
(h) Nhit phn AgBr.
(i) Cho NaI tc dng vi dung dch axit H2SO4 c, nng.
S th nghim to ra n cht l
A. 8
B. 6
C. 7
D. 5

Cu 44: 200C tc ca mt phn ng l 1,3 mol/lit pht. Khi tng thm 10 0C th tc phn ng tng gp i. Vy
500C th tc phn ng trn l
A. 5,2 mol/lit pht
B. 20,8 mol/lit pht

C. 41,6 mol/lit pht

D. 10,4 mol/lit pht

Cu 45: Thuc th cn dng phn bit cc dung dch ring bit mt nhn : glucoz, glixerol, alanylglyxylvalin,
anehit axetic, ancol etylic l
A. AgNO3/dung dch NH3.
C. nc brom.

B. Na.
D. Cu(OH)2/dung dch NaOH.

Cu 46: Cho cc cht benzen (X), toluen (Y),nitrobenzen (Z), phenol (T) phn ng vi brom th kh nng phn ng xy
ra d dn theo trnh t no sau y?
A. Z, X, Y, T.
B. T, Z, X, Y.

C. Z, T, X, Y.

D. Y, Z, T, X.

Cu 47: Dy cc cht u lm mt mu dung dch thuc tm l

A. Axeton, etilen, anehit axetic, cumen
B. Benzen, but-1-en, axit fomic, p-xilen
C. Etilen, axetilen, anehit fomic, toluen
D. Xiclopropan, but-1-in, m-xilen, axit acrylic
Cu 48: Hn hp G gm glyxin v axit glutamic. Cho 5,535 gam hn hp G vo 150 ml dung dch HCl 0,5M c dung
dch Z. Dung dch Z phn ng va vi 100 ml dung dch KOH 1,5M. Thnh phn phn trm theo khi lng ca
glyxin v axit glutamic trong hn hp G ln lt l:
A. 30,49% v 69,51% B. 60,17% v 39,83%
C. 40,65% v 59,35%
D. 20,33% v 79,67%

Cu 49: X l qung hematit cha 62% Fe 2O3. Y l qung manhetit cha 70% Fe 3O4. Trn a tn qung X vi b tn qung
Y thu c qung Z, m t 1 tn qung Z c th iu ch c 0,5 tn gang cha 4% cacbon. T l a/b l:
A. 0,785.
B. 0,585.
C. 0,825.
D. 0,595.

Cu 50: Cho cc cht Zn(OH)2; Al(OH)3; Ni(OH)2; Cr(OH)3; AgCl; AgBr; Cu(OH)2 . S cht tan c trong dung dch
NH3 l:
A. 2.

B. 4.

C. 3.

D. 5.

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Trang 4/5 - M thi 132

P N THI TH I HC LN 2- NM HC 2013
MN HA HC
cauhoi
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50

132
D
B
A
B
B
A
C
C
B
A
A
C
A
D
B
A
C
B
A
B
C
D
C
C
A
D
A
D
C
A
D
B
D
C
D
D
A
B
B
C
A
C
A
D
D
A
C
D
B
B

209
D
A
B
B
B
B
D
B
A
D
A
C
B
C
C
C
B
A
D
D
D
B
C
A
C
C
A
A
B
B
A
C
D
A
D
B
C
B
B
D
C
A
D
D
A
D
A
B
C
C

357
C
B
B
C
C
D
A
C
C
D
A
C
D
C
B
D
B
A
D
B
A
C
A
C
A
A
B
A
B
A
B
D
B
D
B
B
D
B
C
C
A
D
C
D
A
A
D
B
D
C

485
C
B
B
A
B
D
D
D
D
A
C
C
D
B
A
A
C
D
C
C
B
C
A
A
B
D
D
A
C
D
D
B
A
C
B
C
B
C
C
A
B
C
A
B
A
B
D
C
D
A

570
D
B
B
D
D
B
A
C
A
A
A
D
C
D
C
B
B
B
A
C
B
D
A
B
C
C
A
C
D
D
D
C
C
B
D
B
C
A
A
A
A
B
C
C
B
D
A
D
C
C

628
A
A
D
A
B
B
A
A
B
C
B
B
D
D
C
A
B
D
B
D
C
D
D
B
A
C
C
C
D
A
C
C
A
D
D
A
B
A
D
A
A
C
C
B
B
C
D
C
B
A

743
D
A
D
A
C
A
C
A
B
B
B
C
C
C
C
C
D
D
D
D
C
B
B
A
C
B
A
D
C
D
B
A
A
A
B
D
A
B
A
D
C
C
D
B
D
B
A
A
A
B

896
B
A
B
C
B
C
B
C
A
B
C
B
C
A
C
B
B
C
C
D
D
A
C
D
C
A
B
C
D
A
A
C
D
B
D
A
B
D
D
D
C
D
D
D
A
A
A
B
A
A

Trang 5/5 - M thi 132