Bi 1: Vit phng trnh phn ng hon thnh s sau:

FeCl
2
FeSO

Fe!"O
#
$
2
Fe!O%$
2
Fe &' &' '& & Fe
2
O
#
FeCl
#
Fe
2
!SO

$
#
Fe!"O
#
$
#
Fe!O%$
#

Hng dn gii
Fe ( 2%Cl FeCl
2
( %
2
FeCl
2
( )g
2
SO

FeSO

( 2)gCl&
FeSO

( *a!"O
#
$
2
Fe!"O
#
$
2
( *aSO

&
Fe!"O
#
$
2
( 2+O% Fe!O%$
2
( 2+"O
#

t,
Fe!O%$
2
( O
2
Fe
2
O
#
( %
2
O
2Fe ( #Cl
2
2FeCl
#
2FeCl
#
( #)g
2
SO

Fe
2
!SO

$
#
( -)gCl&
Fe
2
!SO

$
#
( #*a!"O
#
$
2
2Fe!"O
#
$
#
( #*aSO

&
Fe!"O
#
$
#
( #+O% Fe!O%$
#
( #+"O
#


t,
2Fe!O%$
#
Fe
2
O
#
( %
2
O
2FeCl
2

!l./ nh0t$
( Cl
2
2FeCl
#!1ng n2u$
2FeCl
#
( Fe #FeCl
2
34FeSO

( 2+5nO

( 6%
2
SO

7Fe
2
!SO

$
#
( +
2
SO

( 25nSO

( 6%
2
O
Fe
2
!SO

$
#
( Fe #FeSO

Fe!"O
#
$
2
( O
2
( %"O
#
Fe!"O
#
$
#
( 2%
2
O
2Fe!"O
#
$
#
( Cu 2Fe!"O
#
$
2
( Cu!"O
#
$
2
Fe!O%$
2!tr8ng 9anh$
( O
2
( 2%
2
O Fe!O%$
#!n2u :$

Bi 2: %on thnh /;/ phn ng sau:
Fe
2
!SO

$
#
( < Fe!"O
#
$
#
( <
)lCl
#
( < )l
2
!SO

$
#
( <
)l
2
O
#
( +%SO

< ( < ( <

+%CO
#
( Ca!O%$
2
< ( < ( <
"aCl ( < "aO% ( <
Ca!%CO
#
$
2
( < CaCO
#
& ( <
Hng dn gii
Fe
2
!SO

$
#
( #*a!"O
#
$
2
2Fe!"O
#
$
#
( #*aSO

&
2)lCl
#
( #)g
2
SO

)l
2
!SO

$
#
( - )gCl&
)l
2
O
#
( -+%SO

)l
2
!SO

$
#
( #+
2
SO

( #%
2
O
+%CO
#
( Ca!O%$
2
CaCO
#
& ( +O% ( %
2
O
=i>n ph2n /? 1;/h ng@n:
2"aCl ( 2%
2
O 2"aO% ( %
2
' ( Cl
2
'
Ca!%CO
#
$
2
(+
2
CO
#
CaCO
#
& ( 2+%CO
#

Bi 3: Vit /;/ AB phn ng /hC ra:
D /;/h iEu /h )l!O%$
#
D - /;/h iEu /h FeCl
2
F
Hng dn gii
D /;/h iEu /h )l!O%$
#
:
( +iG lo0i ( %
2
O
( O9it HiG lo0i ( %
2
O
( =i>n ph2n Iung IJ/h GuKi /lorua !/? 1;/h ng@n$
( 5uKi ( HiEG
( BhLM ph2n GuKi
( 5uKi ( a9it
3
)lCl
#
( #"aO% )l!O%$
#
( #"aO%
2)lCl
#
( - %
2
O 2)l!O%$
#
( #%
2
' ( #Cl
2
'
)l

C
#
( 32%
2
O )l!O%$
#
( #C%

"a)lO
2
( %Cl ( %
2
O )l!O%$
#
( "aCl
D - /;/h iEu /h FeCl
2
:
Fe ( 2%Cl FeCl
2
( %
2
'
Fe ( CuCl
2
FeCl
2
( Cu
FeO ( 2%Cl FeCl
2
( %
2
O
Fe!O%$
2
( 2%Cl FeCl
2
( 2%
2
O
FeS ( 2%Cl FeCl
2
( %
2
S'
FeCO
#
( 2%Cl FeCl
2
( CO
2
' ( %
2
O
2FeCl
#
( Fe #FeCl
2
Fe*r
2
( Cl
2
FeCl
2
( *r
2
Bi 4: C? 6 Iung IJ/h /ha: "a"O
#
F 5g!"O
#
$
2
F Fe!"O
#
$
2
F Cu!"O
#
$
2
F "a
2
SO

F 5gSO

F FeSO

F
CuSO

N %OM nPu /;/ thuK/ thQ 1 trnh RM phng ;n ph2n Ri>t 6 Iung IJ/h n?i trPnN
Hng dn gii
BhuK/ thQ S ph2n Ri>t l: II *aCl
2
F II "aO%N C;/h lG nh sau:
D Cho II *aCl
2
1o 6 Iung IJ/h sT thUM V Iung IJ/h /? Ht tLa l: "a
2
SO

F 5gSO

F FeSO

F
CuSO

!nh?G )$ /Wn Iung IJ/h HhXng /? hi>n tYng g l: "a"O

#
F 5g!"O
#
$
2F
Fe!"O
#
$
2
F Cu!"O
#
$
2
!nh?G *$N
D Brong GZi nh?G )F * Eu I[ng II "aO% S thQ:
"h\n ra "a
2
SO

1 "a"O
#
HhXng /? hi>n tYng g
"h\n ra CuSO

1 Cu!"O
#
$
2
t0o Ht tLa Gu 9anh:
CuSO

( 2"aO% Cu!O%$
2
& ( "a
2
SO

]anh
"h\n ra 5gSO

1 5g!"O
#
$
2
t0o Ht tLa Gu tr8ng:
5g!"O
#
$
2
( 2"aO% 5g!O%$
2
& ( 2"a"O
#
Br8ng
"h\n ra FeSO

1 Fe!"O
#
$
2
t0o Ht tLa Gu tr8ng hi 9anhF sau ? G^t l_/ Ht tLa sT /huMSn
thnh Gu n2u :
FeSO

( 2"aO% Fe!O%$
2
& ( "a
2
SO

Fe!O%$
2
( O
2
( 2%
2
O Fe!O%$
#
& n2u :
"h\n Rit /hC R`ng thuK/ thQ aui Jnh
=2M l I0ng Ri t\p E Ri O /ho sbn G^t lo0i thuK/ thQ nhUt Jnh 1 MPu /cu /hC I[ng thuK/
thQ nM S nh\n Rit G^t lo0t /;/ /hUt G E Ri MPu O /hoN
Bi 5: %Wa tan hZn hYp ] gG 33F2 gaG HiG lo0i 5 1 -dF- gaG o9it 5
9
O
M
/La HiG lo0i ? trong 2
let Iung IJ/h %ClF thu Y/ Iung IJ/h ) 1 F6 let Hhe %
2
!Ht/$N "u /fng hWa tan hZn hYp ] ?
trong 2 let Iung IJ/h %"O
#
th thu Y/ Iung J/h * 1 -Fg2 let Hhe "O !Ht/$N
aN BG HiG lo0i 5N
RN BG /Xng th/ o9it /La HiG lo0i ?N
Hng dn gii
aN Ba /? ABAh sau: 5 ( n%Cl 5Cl
n
( ni2%
2

aGol nai2 Gol
5
9
O
M
( 2M%Cl 95Cl
2M
( M%
2
O
SK Gol %
2
j 4F2 Gol jk nai2 j 4F2 jk na j 4F jk a j 4Fin !1li a l sK Gol /La HiG lo0i 5 /cn tG$N
Ba /? 4FinN 5 j 33F2 jk 5 j 26n
*i>n lu\n S tG 5
n 3 2 #
5 26 !lo0i$ 7- !nh\n$ 6 !lo0i$
Vli 5 j 7- th:a GOnF 1\M HiG lo0i /cn tG l Fe m n
Fe
j 4F2 Gol
2
RN noi /Xng th/ o9it 5
9
O
M
l Fe
9
O
M

Ba /? sK Gol /La Hhe "O l: n
"O
j 4F# !Gol$
Fe ( %"O
#
Fe!"O
#
$
#
( "O ( 2%
2
O !3$
4F2Gol 4F2Gol
SK Gol "O V phn ng !2$ l: n
"O
j 4F# p 4F2 j 4F3 !Gol$
#Fe
9
O
M
( !329D2M$%"O
#
#9Fe!"O
#
$
#
( !#9D2M$"O ( !-9DM$%
2
O !2$
#Gol !#9D2M$Gol
-dF-
4F3Gol
7-9 ( 3-M
Ba /? : -dF-i!7-9(3-M$ j !#9D2M$i4F3 jk -9 j 6M jk 9 j # m M j
V\M /Xng th/ o9it Fe
9
O
M
/cn tG l Fe
#
O

Bi 6: +hQ hon ton F4- gaG 3 o9it HiG lo0i R`ng CO V nhi>t ^ /ao thnh HiG lo0iN qrn ton R^
Hhe sinh ra 1o Rnh sng II Ca!O%$
2
IF thUM t0o thnh g gaG Ht tLaN "u lUM lYng HiG lo0i t0o
thnh !G gaG$ hWa tan ht 1o II %Cl I th thu Y/ 3F3g- let %
2
!Ht/$N BG /Xng th/ /La o9it
HiG lo0i 1 HhKi lYng /La HiG lo0iN
Hng dn gii
Bheo E Ri ta /? s sau :
+hQ

Ca!O%$2
CO CO
2
CaCO
#
&

O9it +t
g
Bheo s trPn jk n
CO
j n
CO2
j n
CaCO#
j u j 4F4g !Gol$
344
vp I.ng Jnh lu\t Ro ton HhKi lYng ta /?: G
o9it
( G
CO
j G
+t
( G
CO2

G
+t
j G
o9it
( G
CO
D G
CO2

j F4- ( !4F4gN 26$ p !4F4gN $ j 2Fd !gaG$
noi tPn HiG lo0i trPn l 5F h?a trJ l aF ta /?:
5 ( a%Cl 5Cl
a
( ai2 %
2
'
3F3g-
n
%2
j j 4F4727 !Gol$
22F
4F4727 4F347
n
5
j j !Gol$
ai2 a
2Fd
j k 5
5
j j 26a
4F347ia
*i>n lu\n:
a 3 2 #
5 26 !lo0i$ 7- !nh\n$ 6 !lo0i$

V\M nghi>G ph[ hYp l: a j 2 jk 5 j 7- !Fe$
4F347
n
Fe
j j 4F4727 !Gol$
2
+hKi lYng /La HiG lo0i s8t l : G
Fe
j 4F4727N 7- j 2Fd !gaG$
=wt /Xng th/ /La o9it s8t /cn tG l Fe
9
O
M
ta /? AB :
Fe
9
O
M
( CO 9Fe ( MCO
2

Ba /? tC l> sau :
#
n
Fe
9 4F4727 #
u j u j j u jk 9 j #F M j
n
CO2
M 4F4g
V\M /Xng th/ /La o9it /cn tG l Fe
#
O

N
Bi 7: Cho lung Hhe CO i aua Kng s sng 4F4 Gol hZn hYp ) gG FeO 1 Fe
2
O
#
Kt n?ngN Sau
Hhi Ht th_/ the nghi>G thu Y/ * gG /hUt nwng Fg6 gaGN +hi i ra Hh:i Kng s /ho hUp th.
1o Iung IJ/h *a!O%$
2
I thu Y/ dF-42 gaG Ht tLaN 5wt Hh;/ hWa tan /hUt r8n * R`ng II %Cl I
thUM tho;t ra 4F-2g2 let Hhe %
2
!Ht/$N
aN Benh x HhKi lYng o9it trong hZn hYp )
RN Benh x HhKi lYng /;/ /hUt trong *F Rit trong *
/? n
Fe#O
j 3i# y n
FeO
1 n
Fe2O#

%lng Irn: vp I.ng Ro ton HhKi lYng 1 Ro ton nguMPn tK
Hng dn gii
aN Ba /? 4F4 Gol hh ) !FeO 1 Fe
2
O
#
$ ( CO Fg6 hh * ( CO
2
CO
2
( *a!O%$
2
I *aCO
#
& ( %
2
O
4F4- Gol 4F4- Gol
n
CO2
j n
*aCO#
j 4F4- Gol 1 n
COp
j n
CO2
j 4F4- Gol
vp I.ng Jnh lu\t Ro ton HhKi lYngF ta /?:
G
)
( G
CO
j G
CO2
( G
*

jk G
)
j Fg6 ( 4F4-N p 4F4-N26 j 7F72 !gaG$
=wt nFeO j 9 GolF nFe
2
O
#
j M Gol trong hZn hYp *F ta /? :
9 ( M j 4F4 9 j 4F43 Gol
g29 ( 3-4M j 7F72 M j 4F4# Gol

4F43Ng2
jk xG
FeO
j 9 344x j 3#F4x
7F72
xG
Fe2O#
j 344 p 3#F4 j 6-Fd-x
RN Ba /? : n
%2
j 4F426 Gol
Fe ( 2%Cl FeCl
2
( %
2
'
Bheo phng trnh ta /? : n
Fe
j n
%2
j 4F426 Gol
theo /2u aF /? 4F43 Gol FeOF 4F4# Gol Fe
2
O
#
jk tzng sK Gol s8t Ran cu R`ng 4F4g GolN
%Zn hYp * gG: 4F426 Gol FeF a Gol FeOF R Gol Fe
2
O
#
F / Gol Fe
#
O

vp I.ng Jnh lu\t Ro ton nguMPn tK s8t ta /?:
a ( 2R ( #/ j 4F4g p 4F426 j 4F42 !3$
t0i /?: ai# ( Ri# p / j 4 !2$
g2a ( 3-4R ( 2#2/ j Fg6 p !4F426N 7-$ j #F23- !#$
B{ !3$F !2$ 1 !#$ ta /? h> AB: a ( 2R ( #/ j 4F42
ai# ( Ri# p / j 4
g2a ( 3-4R ( 2#2/ j #F23-
nii h> ta Y/ nghi>G : a j 4F432m R j -N34
D#
m / j -N34
D#

Ba /? phcn tr@G HhKi lYng /;/ /hUt trong * nh sau :
xG
FeO
j 36F3x m xG
Fe2O#
j 24x m xG
Fe#O
j 2dF3x
xG
Fe
j 344 p !36F3 ( 24 ( 2dF3$ j #2F6x