1. Cu to nguyn t - Bng h thng tun hon..............................................................................

2
2. Phn ng oxi ha kh................................................................................................................ 5
3. Nhm Halogen v hp cht halogen............................................................................................. 12
4. Oxi lu hunh v hp cht......................................................................................................... 14
5. Tc phn ng ha hc.............................................................................................................. 17
6. S in li axit baz mui..................................................................................................... 19
7. Nit Pht pho v hp cht......................................................................................................... 26
8. Cacbon Silic v hp cht........................................................................................................... 33
9. i cng v kim loi.................................................................................................................. 37
10. Kim loi kim v hp cht.......................................................................................................... 49
11. Kim loi kim th v hp cht.................................................................................................... 51
12. Nhm (Al) v hp cht............................................................................................................... 54
13. St v mt s kim loi quan trng.............................................................................................. 59

~1~

CU TO NGUYN T - BNG TUN HON CC NGUYN T HA HC

Cu 1 (H - KB 2011) Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l
A. [Ar]3d9 v [Ar]3d3.

B. [Ar]3d9 v [Ar]3d14s2.

C. [Ar]3d74s2 v [Ar]3d14s2 .

D. [Ar]3d74s2 v [Ar]3d3.
37

Cu 2 (H - KB 2011) Trong t nhin Clo c hai ng v bn: 17 Cl chim 24,23% tng s nguyn t,
35
37
Cl . Thnh phn % theo khi lng ca 17
Cl trong HClO4 l
cn li l 17
A. 8,43%.

B. 8,79%.

C. 8,92%.

D. 8,56%.
63

65

Cu 3 (H - C KA 2007) Trong t nhin, nguyn t ng c hai ng v l 29 Cu v 29 Cu . Nguyn

63
Cu l
t khi trung bnh ca ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v 29
A. 27%.

B. 50%.

C. 54%.

D. 73%.

Cu 4. Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca

mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt
l (bit s hiu nguyn t ca nguyn t : Na = 11; Al = 13; P = 15; Cl = 17; Fe = 26)
A. Al v Cl

B. Al v P

C. Na v Cl

D. Fe v Cl
+

Cu 5 (H - KA 2012) Nguyn t R to c cation R . Cu hnh electron phn lp ngoi cng ca R +

( trng thi c bn) l 2p6. Tng s ht mang in trong nguyn t R l
A. 10

B. 11

C. 22

D. 23

Cu 6 (H - KA 2012) X v Y l hai nguyn t thuc cng mt chu k, hai nhm A lin tip. S proton
ca nguyn t Y nhiu hn s proton ca nguyn t X. Tng s ht proton trong nguyn t X v Y l 33.
Nhn xt no sau y v X, Y l ng?
A. n cht X l cht kh iu kin thng.
B. m in ca X ln hn m in ca Y.
C. Lp ngoi cng ca nguyn t Y ( trng thi c bn) c 5 electron.
D. Phn lp ngoi cng ca nguyn t X ( trng thi c bn) c 4 electron
Cu 7 (H - KA 2007) Dy gm cc ion X+, Y- v nguyn t Z u c cu hnh electron 1s22s22p6 l:
A. K+, Cl-, Ar.

B. Li+, F-, Ne.

C. Na+, F-, Ne.

D. Na+, Cl-, Ar.

Cu 8 (H - KB 2010) Mt ion M3+ c tng s ht proton, ntron, electron l 79, trong s ht mang
in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l
A. [Ar]3d54s1.

B. [Ar]3d64s2.

C. [Ar]3d64s1.

D. [Ar]3d34s2.

Cu 9 (H - KA 2010) Nhn nh no sau y ng khi ni v 3 nguyn t:

26
13

X ,

55
26

Y ,

26
12

Z?

A. X v Z c cng s khi.

B. X, Z l 2 ng v ca cng mt nguyn t ho hc.

C. X, Y thuc cng mt nguyn t ho hc.

D. X v Y c cng s ntron.

Cu 10 (C- KA 2008) Nguyn t ca nguyn t X c cu hnh electron

1s22s22p63s23p64s1, nguyn t ca nguyn t Y c cu hnh electron 1s 22s22p5. Lin kt ho hc gia nguyn
t X v nguyn t Y thuc loi lin kt
A. kim loi.

B. cng ho tr.

C. ion.

D. cho nhn

Cu 11 (C- KA 2008) Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S

ht mang in ca mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t
X v Y ln lt l (bit s hiu nguyn t ca nguyn t: Na = 11; Al = 13; P = 15; Cl = 17; Fe = 26)
A. Fe v Cl.

B. Na v Cl.

C. Al v Cl.

D. Al v P.

Cu 12 (C- KA 2009) Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c

s khi l 35. S hiu nguyn t ca nguyn t X l

~2~

A. 18.

B. 23.

C. 17.

D. 15.

Cu 13 (C- KA 2009) Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn
t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X
v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l
A. kim loi v kim loi.

B. phi kim v kim loi.

C. kim loi v kh him.

D. kh him v kim loi

Cu 14 (C- KA 2007) Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in

ca cc nguyn t tng dn theo th t
A. M < X < Y < R.

B. R < M < X < Y.

C. Y < M < X < R.

D. M < X < R < Y

Cu 15 (H - KA 2007) Anion X- v cation Y2+ u c cu hnh electron lp ngoi cng l 3s 23p6. V tr

ca cc nguyn t trong bng tun hon cc nguyn t ha hc l:
A. X c s th t 17, chu k 4, nhm VIIA ; Y c s th t 20, chu k 4, nhm IIA
B. X c s th t 17, chu k 3, nhm VIIA ; Y c s th t 20, chu k 4, nhm IIA
C. X c s th t 18, chu k 3, nhm VIIA ; Y c s th t 20, chu k 3, nhm IIA
D. X c s th t 18, chu k 3, nhm VIA ; Y c s th t 20, chu k 4, nhm IIA
Cu 16: Nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52. Trong ht nhn nguyn t
X c s ht khng mang in nhiu hn s ht mang in l 1. V tr (chu k, nhm) ca X trong bng tun
hon cc nguyn t ha hc l
A. Chu k 3, nhm VA.

B. Chu k 3, nhm VIIA.

C. Chu k 2, nhm VA.

D. Chu k 2, nhm VIIA

Cu 17 (H - KA 2009) Cho Cu hnh electron ca ion X2+ l 1s22s22p63s23p63d6. Trong bng tun hon
cc nguyn t ho hc, nguyn t X thuc
A. chu k 4, nhm VIIIB.

B. chu k 4, nhm VIIIA.

C. chu k 3, nhm VIB.

D. chu k 4, nhm IIA.

Cu 18 Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA, nguyn t Y nhm VA.
Cng thc ca hp cht to thnh t 2 nguyn t trn c dng l
A. X2Y3.

B. X2Y5.

C. X3Y2.

D. X5Y2.

Cu 19 ( H - KA 2010) Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th

A. bn knh nguyn t tng, m in gim.

B. bn knh nguyn t v m in u tng.

C. bn knh nguyn t gim, m in tng.

D. bn knh nguyn t v m in u gim

Cu 20 (H - KB 2008) Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l:
A. N, P, O, F.

B. P, N, F, O.

C. N, P, F, O.

D. P, N, O, F.

Cu 21 (H - KA 2008) Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng
dn t tri sang phi l
A. F, O, Li, Na.

B. F, Na, O, Li.

C. F, Li, O, Na.

D. Li, Na, O, F.

Cu 22 (H - KA 2009) Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns 2np4. Trong

hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X
trong oxit cao nht l
A. 27,27%.

B. 40,00%.

C. 60,00%.

D. 50,00%.

Cu 23 (H - KA 2007) Cho dy cc cht: N2, H2, NH3, NaCl, HCl, H2O. S cht trong dy m phn t ch
cha lin kt cng ha tr khng cc l
A. 2.

B. 4.

C. 3.

D. 5.

Cu 2 4 (H - KA 2008 ) Nguyn t ca nguyn t X c cu hnh electron 1s22s22p63s23p64s1 ,

nguyn t ca nguyn t Y c cu hnh electron 1s22s22p5. Lin kt ho hc gia nguyn t X v nguyn
t Y thuc loi lin kt
A. cho nhn

B. ion

C. cng ho tr

~3~

D. kim loi

Cu 25 (H - KA 2008) Hp cht trong phn t c lin kt ion l

A. NH4Cl.

B. NH3.

C. HCl.

D. H2O.

Cu 26 (H - KA 2011) Cc cht m phn t khng phn cc l:

A. HBr, CO2, CH4.

B. Cl2, CO2, C2H2.

C. NH3, Br2, C2H4.

D. HCl, C2H2, Br2.

Cu 27 (H - KB 2007) Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng
s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha
duy nht. Cng thc XY l
A. AlN.

B. MgO.

C. LiF.

D. NaF.

Cu 28 (H - KB 2009) Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm
VIII), theo chiu tng ca in tch ht nhn nguyn t th
A. tnh phi kim gim dn, bn knh nguyn t tng dn.
C. m in gim dn, tnh phi kim tng dn.
dn.

B. tnh kim loi tng dn, m in tng dn.

D. tnh kim loi tng dn, bn knh nguyn t gim

Cu 29 (H - KB 2009) Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm

cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l:
A. N, Si, Mg, K.

B. K, Mg, Si, N.

C. K, Mg, N, Si.

D. Mg, K, Si, N.

Cu 30 (H - KB 2012) Nguyn t Y l phi kim thuc chu k 3, c cng thc oxit cao nht l YO 3.
Nguyn tt Y to vi kim loi M hp cht c cng thc MY, trong M chim 63,64% v khi lng. Kim
loi M l
A. Zn

B. Cu

C. Mg

Cu 31 (H - KB 2012) Pht biu no sau y l sai?

A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng.
B. Cc nhm A bao gm cc nguyn t s v nguyn t p.
C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim.
D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c

~4~

D. Fe

PHN NG OXI HA KH
Cu 1: kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi
A. Ba.

B. K.

C. Fe.

D. Na.

Cu 2: SO2 lun th hin tnh kh trong cc phn ng vi

A. O2, nc Br2, dung dch KMnO4.

B. dung dch KOH, CaO, nc Br2.

C. dung dch NaOH, O2, dung dch KMnO4.

D. H2S, O2, nc Br2.

Cu 3: kh ion Fe3+ trong dung dch thnh ion Fe2+c th dng mt lng d
A. kim loi Cu.

B. kim loi Ba.

C. kim loi Ag.

D. kim loi Mg.

Cu 4: Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al 2O3, MgO, Fe3O4, CuO thu c

cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng
xy ra hon ton. Phn khng tan Z gm
A. Mg, Fe, Cu.

B. MgO, Fe3O4, Cu.

C. MgO, Fe, Cu.

D. Mg, Al, Fe, Cu.

Cu 5 : Th t mt s cp oxi ho - kh trong dy in ho nh sau:

Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+.
Cp cht khng phn ng vi nhau l
A. Fe v dung dch FeCl3.
B. Fe v dung dch CuCl2.
C. dung dch FeCl2 v dung dch CuCl2.
D. Cu v dung dch FeCl3.
Cu 6: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng
xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn
trm th tch ca kh CO2 trong hn hp kh sau phn ng l
A. Fe3O4; 75%.

B. FeO; 75%.

C. Fe2O3; 75%.

D. Fe2O3; 65%.

Cu 7: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4

c, nng n khi cc phn ng xy
ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l
A. MgSO4.

C. MgSO4, Fe2(SO4)3 v FeSO4.

B. MgSO4 v Fe2(SO4)3.

D. MgSO4 v FeSO4.

Cu 8: SO2 lun th hin tnh kh trong cc phn ng vi

A. H2S, O2, nc Br2.
B. dung dch KOH, CaO, nc Br2.
C. dung dch NaOH, O2, dung dch KMnO4.
D. O2, nc Br2, dung dch KMnO4.
Cu 9: Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al 2O3, MgO, Fe3O4, CuO thu c
cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng
xy ra hon ton. Phn khng tan Z gm
A. Mg, Fe, Cu.

B. MgO, Fe, Cu.

C. MgO, Fe3O4, Cu.

D. Mg, Al, Fe, Cu.

Cu 10: Trng hp khng xy ra phn ng ha hc l

t
A > 3O2 + 2 H 2 S
2 H 2 O + 2 SO2

B > O3 + 2 KI + H 2 O
2 KOH + I 2 + O2
C > FeCl2 + H 2 S
FeS + 2 HCl

~5~

D > Cl2 + 2 NaOH

NaCl + NaClO + H 2 O
Cu 11: Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy b oxi ha
khi tc dng vi dung dch HNO3c, nng l
A. 3.

B. 5

C. 4

D. 6.

Cu 12: Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu.

Trong phn ng trn xy ra
A. s kh Fe2+ v s oxi ha Cu.

B. s kh Fe2+ v s kh Cu2+.

C. s oxi ha Fe v s oxi ha Cu.

D. s oxi ha Fe v s kh Cu2+.

Cu 13: Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy
nht, ktc). Kh X l
A. N2O.

B. NO2.

C. N2.

D. NO.

Cu 14: Cp cht khng xy ra phn ng ho hc l

A. Cu + dung dch FeCl3.
B. Fe + dung dch FeCl3.
C. Fe + dung dch HCl.
D. Cu + dung dch FeCl2.
Cu 15: Cho bit phn ng oxi ho - kh xy ra trong pin in ho Fe Cu l:
Fe + Cu2+ Fe2+ + Cu ; E0(Fe2+/Fe) = 0,44 V, E0(Cu2+/Cu) = + 0,34 V.
Sut in ng chun ca pin in ho Fe - Cu l
A. 1,66 V.

B. 0,10 V.

C. 0,78 V.

D. 0,92 V.

Cu 16: Cho cc phn ng:

Ca(OH)2 + Cl2 CaOCl2 + H2O

2H2S + SO2 3S + 2H2O

2NO2 + 2NaOH NaNO3 + NaNO2 + H2O

4KClO3 KCl + 3KClO4

O3 O2 + O
S phn ng oxi ho kh l
A. 2.

B. 3.

C. 5.

D. 4.

Cu 17: Cho bit cc phn ng xy ra sau:

2FeBr2 + Br2 2FeBr3
2NaBr + Cl2 2NaCl + Br2
Pht biu ng l:
A. Tnh oxi ha ca Cl2 mnh hn ca Fe3+.
-

B. Tnh oxi ha ca Br2 mnh hn ca Cl2.

2+

D. Tnh kh ca Cl- mnh hn ca Br-.

C. Tnh kh ca Br mnh hn ca Fe .

Cu 18: Cho dy cc cht v ion: Cl2, F2, SO2, Na +, Ca2+, Fe2+, Al3+, Mn2+, S2-, Cl-. S cht v ion trong dy
u c tnh oxi ho v tnh kh l
A. 5.

B. 6.

C. 4.

D. 3.

Cu 19: Cho cc phn ng sau:

H2S + O2 (d) Kh X + H2O
NH3 + O2 Kh Y + H2O
NH4HCO3 + HCl long Kh Z + NH4Cl + H2O
Cc kh X, Y, Z thu c ln lt l:
A. SO2, NO, CO2.

B. SO3, N2, CO2.

C. SO2, N2, NH3.

D. SO3, NO, NH3.

Cu 20: Cho cc phn ng:

~6~

(1) O3 + dung dch KI

(2) F2 + H2O
(3) MnO2 + HCl c
(4) Cl2 + dung dch H2S
Cc phn ng to ra n cht l:
A. (1), (2), (4).

B. (2), (3), (4).

C. (1), (2), (3).

D. (1), (3), (4).

Cu 21: Trong cc cht: FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ho v
tnh kh l
A. 2.

B. 3.

C. 5.

D. 4.

Cu 22: Th t mt s cp oxi ho - kh trong dy in ho nh sau: Mg 2+/Mg; Fe2+/Fe; Cu2+/Cu;Fe3+/Fe2+;

Ag+/Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l:
A. Fe, Cu, Ag+.

B. Mg, Fe2+, Ag.

C. Mg, Cu, Cu2+.

D. Mg, Fe, Cu.

Cu 23: Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c dung
dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh.
Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra.
Phn trm khi lng ca Al trong hn hp ban u l
A. 19,53%.

B. 15,25%.

C. 10,52%.

D. 12,80%.

Cu 24: Nguyn t S ng vai tr va l cht kh, va l cht oxi ho trong phn ng no sau y?
A. S + 2Na Na2S
B. S + 3F2 SF6
C. 4S + 6NaOH(c) 2Na2S + Na2S2O3 + 3H2O.
D. S + 6HNO3 (c) H2SO4 + 6NO2 + 2H2O.
Cu 25: Cho phn ng:
Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O.
Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l
A. 31.

B. 47.

C. 27

D. 23.

Cu 26: Cho bit th t t tri sang phi ca cc cp oxi ho - kh trong dy in ho (dy th in cc

chun) nh sau: Zn2+/Zn; Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Cc kim loi v ion u phn ng c vi ion
Fe2+ trong dung dch l:
A. Ag, Cu2+.

B. Ag, Fe3+.

C. Zn, Ag+.

D. Zn, Cu2+.

Cu 27: Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn
ng xy ra hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht ca N ). Gi
tr ca a l
A. 5,6.

B. 8,4.

C. 11,2.

D. 11,0.

Cu 28: Cho 3,16 gam KMnO4 tc dng vi dung dch HCl c (d), sau khi phn ng xy ra hon ton th s
mol HCl b oxi ha l
A. 0,10.

B. 0,05.

C. 0,02.

D. 0,16.

Cu 29: Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng tc dng vi dung dch
HNO3c, ngui l:
A. Cu, Fe, Al.

B. Fe, Al, Cr.

C. Cu, Pb, Ag.

D. Fe, Mg, Al.

Cu 30: Cho cc cht: KBr, S, SiO2, P, Na3PO4, FeO, Cu v Fe2O3. Trong cc cht trn, s cht c
th b oxi ha bi dung dch axit H2SO4c, nng l

~7~

A. 4.

B. 5.

C. 7.

D. 6.

Cu 31: nhn ra ion NO3 trong dung dch Ba(NO3)2, ngi ta un nng nh dung dch vi
A. kim loi Cu.

B. dung dch H2SO4 long.

C. kim loi Cu v dung dch Na2SO4.

D. kim loi Cu v dung dch H2SO4 long.

Cu 32: Cho phn ng:

6FeSO4 + K2Cr2O7 + 7H2SO4 3Fe2(SO4)3 + Cr2(SO4)3 + K2SO4 + 7H2O
Trong phn ng trn, cht oxi ha v cht kh ln lt l
A. K2Cr2O7v FeSO4.

B. K2Cr2O7v H2SO4.

C. H2SO4v FeSO4.

D. FeSO4v K2Cr2O7.

Cu 33 Cho cc phn ng sau:

a) FeO + HNO3 (c, nng)

b) FeS + H2SO4 (c, nng)

c) Al2O3 + HNO3 (c, nng)

d) Cu + dung dch FeCl3

e) CH3CHO + H2
f) glucoz + AgNO3 (hoc Ag2O) trong dung dch NH3
g) C2H4 + Br2

h) glixerol (glixerin) + Cu(OH)2

Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l:

A. a, b, d, e, f, h.

B. a, b, d, e, f, g.

C. a, b, c, d, e, h.

D. a, b, c, d, e, g.

Cu 34: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3,
FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l
A. 8.

B. 5.

C. 7.

D. 6.

Cu 35: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu vi
dung dch HNO3c, nng l
A. 10.

B. 11.

C. 8.

D. 9.

Cu 36: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn
ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l (cho Fe = 56)
A. 80.

B. 40.

C. 20.

D. 60.

Cu 37: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2SO4c, nng (gi thit SO2 l sn phm kh duy
nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56)
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.
B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
D. 0,12 mol FeSO4.
Cu 38: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong
dung dch HNO3 (d), thot ra 0,56 lt ( ktc) NO (l sn phm kh duy nht). Gi tr ca m l
A. 2,52.

B. 2,22.

C. 2,62

D. 2,32.

Cu 39: Cho cc phn ng xy ra sau y:

(1) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag
(2) Mn + 2HCl MnCl2 + H2
Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l
A. Mn2+, H+, Fe3+, Ag+.

B. Ag+, Fe3+, H+, Mn2+.

C. Ag+, Mn2+, H+, Fe3+.

D. Mn2+, H+, Ag+, Fe3+.

Cu 40: Thc hin hai th nghim:

1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO.

~8~

2) Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2
lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V 1 v V2 l (cho
Cu = 64)
A. V2 = V1.

B. V2 = 2V1.

C. V2 = 2,5V1.

D. V2 = 1,5V1.

Cu 41: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), thot ra 0,112 lt ( ktc)
kh SO2 (l sn phm kh duy nht). Cng thc ca hp cht st l
A. FeS.

B. FeS2.

C. FeO

D. FeCO3.

Cu 42: Cho cc phn ng sau:

4HCl + MnO2 MnCl2 + Cl2 + 2H2O.
2HCl + Fe FeCl2 + H2.
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O.
6HCl + 2Al 2AlCl3 + 3H2.
16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O.
S phn ng trong HCl th hin tnh oxi ha l
A. 2.

B. 1.

C. 4.

D. 3.

Cu 43: Cho 11,36 gam hn hp gm Fe, FeO, Fe 2O3 v Fe3O4 phn ng ht vi dung dch HNO 3 long (d),
thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m
gam mui khan. Gi tr ca m l
A. 38,72.

B. 35,50.

C. 49,09.

D. 34,36.

Cu 44: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung
dch HCl c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4.

B. MnO2.

C. CaOCl2.

D. K2Cr2O7.

Cu 45: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO 3 long, thu c 940,8 ml kh NxOy (sn
phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l
A. NO v Mg.

B. NO2 v Al.

C. N2O v Al.

D. N2O v Fe.

Cu 46: Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O
Sau khi cn bng phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca
HNO3 l
A. 13x - 9y.

B. 46x - 18y

C. 45x - 18y.

D. 23x - 9y.

Cu 47: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng
hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A. 0,8 gam.

B. 8,3 gam.

C. 2,0 gam.

D. 4,0 gam.

Cu 48: Cho 6,72 gam Fe vo 400 ml dung dch HNO 3 1M, n khi phn ng xy ra hon ton, thu c kh
NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l
A. 1,92.

B. 3,20

C. 0,64.

D. 3,84.

Cu 49: Cho dy cc cht v ion: Zn, S, FeO, SO 2, N2, HCl, Cu2+, Cl-. S cht v ion c c tnh oxi ha v
tnh kh l
A. 7.

B. 5.

C. 4.

D. 6.

Cu 50: Cho cc phn ng sau:

(a) 4HCl + PbO2 PbCl2 + Cl2 + 2H2O.
(b) HCl + NH4HCO3 NH4Cl + CO2 + H2O.
(c) 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O.
(d) 2HCl + Zn ZnCl2 + H2.
S phn ng trong HCl th hin tnh kh l
A. 2.

B. 3.

C. 1.

D. 4.

~9~

Cu 51: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v H2SO4 0,25M. Sau khi cc
phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca m v V ln lt l
A. 10,8 v 4,48.
B. 10,8 v 2,24.
C. 17,8 v 2,24.
D. 17,8 v 4,48.
Cu 52: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X
v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan.
Gi tr ca m l
A. 52,2.

B. 54,0.

C. 58,0.

D. 48,4.

Cu 53: Thc hin cc th nghim sau:

(I) Sc kh SO2 vo dung dch KMnO4.
(II) Sc kh SO2 vo dung dch H2S.
(III) Sc hn hp kh NO2 v O2 vo nc.
(IV) Cho MnO2 vo dung dch HCl c, nng.
(V) Cho Fe2O3 vo dung dch H2SO4 c, nng.
(VI) Cho SiO2 vo dung dch HF.
S th nghim c phn ng oxi ho - kh xy ra l
A. 6.

B. 5.

C. 4.

D. 3.

Cu 54: Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O
S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr
ca k l
A. 3/14.

B. 4/7.

C. 1/7.

D. 3/7.

Cu 55: Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2-OH

Phn ng ny chng t C6H5-CHO
A. va th hin tnh oxi ho, va th hin tnh kh.
B. khng th hin tnh kh v tnh oxi ho.
C. ch th hin tnh oxi ho.
D. ch th hin tnh kh.
Cu 56: Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M.
Ho tan ht a gam M bng dung dch H 2SO4c nng (d), thu c 20,16 lt kh SO 2 (sn phm kh duy
nht, ktc). Oxit MxOy l
A. FeO.

B. CrO.

C. Cr2O3.

D. Fe3O4.

Cu 57: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch

HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc)
gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr
ca m l
A. 40,5.

B. 50,4.

C. 33,6

D. 44,8.
2+

Cu 58: Cho dy cc cht v ion: Fe, Cl2, SO2, NO2, C, Al, Mg , Na+, Fe2+, Fe3+. S cht v ion va c tnh
oxi ho, va c tnh kh l
A. 6.

B. 4.

C. 5.

Cu 59: Cho cc phn ng sau:

Fe + 2Fe(NO3)3 3Fe(NO3)2
AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag

~ 10 ~

D. 8.

Dy sp xp theo th t tng dn tnh oxi ho ca cc ion kim loi l:

A. Ag+, Fe3+, Fe2+.

B. Ag+, Fe2+, Fe3+.

C. Fe2+, Fe3+, Ag+.

D. Fe2+, Ag+, Fe3+.

Cu 60: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dungdch gm

H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO(sn phm kh
duy nht ca N+5). Trn a mol NO trn vi 0,1 mol O 2thu c hn hp kh Y. Cho ton b Y tc dng vi
H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l
A. 4.

B. 1.

C. 2.

D. 3.

Cu 61: Cho cc phn ng:

(a) Sn + HCl (long)

(b) FeS + H2SO4 (long)

(c) MnO2 + HCl (c)

(d) Cu + H2SO4 (c)

(e) Al + H2SO4 (long)

(g) FeSO4 + KMnO4 + H2SO4

S phn ng m H+ ca axit ng vai tr cht oxi ho l

A. 3.

B. 5.

C. 2.

~ 11 ~

D. 6.

NHM HALOGEN V HP CHT HALOGEN

Cu 1: (H B 2008) Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l
A. N, P, F, O.

B. N, P, O, F.

C. P, N, O, F.

D. P, N, F, O.

Cu 2: Cho 31,84g hn hp NaX v NaY (X, Y l 2 nguyn t halogen 2 chu k lin tip) vo dung dch
AgNO3 d th thu c 57,34g kt ta. Cng thc ca 2 mui l
A. NaBr v NaI.

B. NaF v NaCl.

C. NaCl v NaBr.

D. Khng xc nh c.

Cu 3: (H A 2007) Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na 2CO3 ng thi
khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c
xut hin kt ta. Biu thc lin h gia V vi a, b l
A. V = 22,4(a + b).

B. V = 11,2(a - b).

C. V = 11,2(a + b).

D. V = 22,4(a - b).

C. 4.

D. 2.

Cu 4: (H B 2009) Cho cc phn ng sau

PbCl2 + Cl2 + 2H2O.

HCl + NH4HCO3 NH4Cl + CO2 + H2O.
2HCl + 2HNO3 2NO2 + Cl2 + 2H2O.
2HCl + Zn ZnCl2 + H2.
4HCl + PbO2

S phn ng trong HCl th hin tnh kh l

A. 3.

B. 1.

Cu 5: (H A 2008) Cho cc phn ng sau

4HCl + MnO2

MnCl2 + Cl2 + 2H2O.

FeCl2 + H2.
14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O.
6HCl + 2Al 2AlCl3 + 3H2.
16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O.
2HCl + Fe

S phn ng trong HCl th hin tnh oxi ha l

A. 4.

B. 2.

C. 3.

D. 1.

Cu 6: (H B 2008) Cho dy cc cht v ion: Cl2, F2, SO2, Na+, Ca2+, Fe2+, Al3+, Mn2+, S2-, Cl-. S cht v
ion trong dy u c tnh oxi ho v tnh kh l
A. 3.

B. 4.

C. 5.

D. 6.

Cu 7: (H A 2009) Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi

lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l
A. KMnO4.

B. CaOCl2.

C. K2Cr2O7.

D. MnO2.

Cu 8: Cho m gam n cht halogen X2 tc dng vi Mg d thu c 19g mui. Cng m gam X 2 cho tc
dng vi Al d thu c 17,8g mui. X l
A. Flo.

B. Clo.

C. Iot.

D. Brom.

Cu 9: (H B 2009) Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai
nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch
AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l
A. 52,8%.

B. 58,2%.

C. 47,2%.

D. 41,8%.

Cu 10: (C A 2009) Trong cc cht: FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c
tnh oxi ho v tnh kh l

~ 12 ~

A. 3.

B. 2.

C. 5.

D. 4.

Cu 11: Phn ng gia hydro v cht no sau y thun nghch

A. Flo.

B. Clo.

C. Iot.

D. Brom

Cu 12: (H A 2007) Trong phng th nghim, ngi ta thng iu ch clo bng cch
A. in phn dung dch NaCl c mng ngn.
B. in phn nng chy NaCl.
C. cho F2 y Cl2 ra khi dung dch NaCl.
D. cho dung dch HCl c tc dng vi MnO2, un nng.
Cu 13: (H B 2007) Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100oC. Sau khi phn
ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l (cho Cl = 35,5; K = 39)
A. 0,48M.

B. 0,24M.

C. 0,4M.

D. 0,2M.

Cu 14: (H B 2009) Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng
l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X,
sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l
A. 28,7.

B. 68,2.

C. 57,4.

D. 10,8.

Cu 16: c im no di y khng phi l c im chung ca cc nguyn t halogen (F, Cl, Br, I

A. C s oxi ho -1 trong mi hp cht
B. To ra hp cht lin kt cng ho tr co cc vi hidro
C. Nguyn t ch co kh nng thu thm 1 e
D. Lp electron ngoi cng ca nguyn t c 7 electron
Cu 17: (H B 2007) Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA (phn
nhm chnh nhm II) tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H 2 ( ktc). Hai kim loi
l (cho Be = 9, Mg = 24, Ca = 40, Sr = 87, Ba = 137)
A. Ca v Sr.

B. Sr v Ba.

C. Mg v Ca.

D. Be v Mg.

Cu 18: (H A 2008) oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH,
lng ti thiu Cl2 v KOH tng ng l
A. 0,03 mol v 0,08 mol.

B. 0,03 mol v 0,04 mol.

C. 0,015 mol v 0,08 mol.

D. 0,015 mol v 0,04 mol.

Cu19: (C A 2009) Cht dng lm kh kh Cl2 m l

A. dung dch H2SO4 m c .

B. Na2SO3 khan.

C. dung dch NaOH c.

D. CaO .

Cu 20: (H A 2009) Dy gm cc cht u tc dng c vi dung dch HCl long l

A. Mg(HCO3)2, HCOONa, CuO.

B. AgNO3, (NH4)2CO3, CuS.

C. KNO3, CaCO3, Fe(OH)3.

D. FeS, BaSO4, KOH.

Cu 21: (H A - 2010) Trong phn ng K2Cr2O7 + HCl -> KCl + CrCl3 + Cl2 + H2O
S phn t ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l:
A. 4/7

B. 1/7

C. 3/14

D. 3/7

Cu 22: (HA - 2010) Nh t t tng git n ht 30ml dd HCl 1M vo 100ml dd cha Na2CO3 0,2M v
NaHCO3 0,2M sau phn ng thu c s mol CO2 l:
A. 0,030

B. 0,010

C. 0,020

D. 0,015

Cu 23: (HB - 2010) H hp X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dd HCl d, sau
phn ng thu c dd cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO d cho hh kh
thu c sau phn ng li t t qua dd Ba(OH)2 d th thu c m agm kt ta. Gi tr ca m l:
A. 73,875

B. 78,875

C. 76,755

~ 13 ~

D. 147,75

OXI LU HUNH V HP CHT CA CHNG

THI TUYN SINH CAO NG NM 2007
Cu 1: Khi ha tan hiroxit kim loi M(OH) 2 bng mt lng va dd H 2SO4 20% thu c ddmui trung ho c
nng 27,21%. Kim loi M l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Cu = 64; Zn = 65)
A. Cu.

B. Zn.

C. Fe.

D. Mg.

Cu 2: SO2 lun th hin tnh kh trong cc phn ng vi

A. H2S, O2, nc Br2.

B. dung dch NaOH, O2, dung dch KMnO4.

C. dung dch KOH, CaO, nc Br2.

D. O2, nc Br2, dung dch KMnO4.

Cu 3: Ha tan hon ton 3,22 gam hh X gm Fe, Mg v Zn bng mt lng va dd H2SO4 long, thu c 1,344
lt hiro ( ktc) v dd cha m gam mui. Gi tr ca m l:
A. 9,52.

B. 10,27.

C. 8,98.

D. 7,25.

THI TUYN SINH CAO NG NM 2008

Cu 1: Trng hp khng xy ra phn ng ha hc l
t
A. 3O2 + 2H2S
2H2O + 2SO2. B. FeCl2 + H2S FeS + 2HCl.
o

C. O3 + 2KI + H2O 2KOH + I2 + O2.

D. Cl2 + 2NaOH NaCl + NaClO + H2O.

Cu 2: X l kim loi thuc PNC nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X v Zn tc dng vi
lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung
dch H2SO4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l
A. Ba.

B. Ca.

C. Sr.

D. Mg.

Cu 3: Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c
hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan
G. t chy hon ton X v G cn va V lt kh O2 ( ktc). Gi tr ca V l
A. 2,80.

B. 3,36.

C. 3,08.

D. 4,48.

Cu 4: Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H2SO4 0,28M thu c
dung dch X v 8,736 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l
A. 38,93 gam.

B. 103,85 gam. C. 25,95 gam.

D. 77,86 gam.

THI TUYN SINH CAO NG NM 2009

Cu 1: phn bit CO2 v SO2 ch cn dng thuc th l

A. nc brom.

B. CaO.

C. dung dch Ba(OH)2.

D. dung dch NaOH.

Cu 2: Cht kh X tan trong nc to ra mt dd lm chuyn mu qu tm thnh v c th c dng lm

cht ty mu. Kh X l
A. NH3.
B. CO2.
C. SO2.
D. O3.
THI TUYN SINH I HC, CAO NG NM 2007, Khi A
Cu 1: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th
l
A. Fe.
B. CuO.
C. Al.
D. Cu.
Cu 2: Ho tan 5,6 gam Fe bng dd H2SO4 long (d), thu c dd X. dd X phn ng va vi V ml dd KMnO4
0,5M. Gi tr ca V l (cho Fe = 56)
A. 80.
B. 40.
C. 20.
D. 60.
Cu 3: Cho m gam hh Mg, Al vo 250 ml dd X cha hh axit HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 (
ktc) v dd Y (coi th tch dd khng i). dd Y c pH l
A. 1. B. 6. C. 7. D. 2.
Cu 4: Ho tan hon ton 2,81 gam hh gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng,
hh mui sunfat khan thu c khi c cn dd c khi lng l (cho H = 1, O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65)
A. 6,81 gam.
B. 4,81 gam.
C. 3,81 gam.
D. 5,81 gam.
THI TUYN SINH I HC, CAO NG NM 2008, khi A
Cu 1: Trong phng th nghim, ngi ta iu ch oxi bng cch
A. in phn nc.

B. nhit phn Cu(NO3)2.

~ 14 ~

C. nhit phn KClO3 c xc tc MnO2. D. chng ct phn on khng kh lng.

Cu 2: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung dch Fe(NO3)3.
Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag)
A. Fe, Cu.

B. Cu, Fe.

C. Ag, Mg.

D. Mg, Ag.

THI TUYN SINH I HC, CAO NG NM 2009, khi A

Cu 1: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c
2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A. 101,68 gam. B. 88,20 gam.

C. 101,48 gam. D. 97,80 gam.

Cu 2: Trng hp no sau y khng xy ra phn ng ho hc?

A. Sc kh Cl2 vo dung dch FeCl2.
C. Sc kh H2S vo dung dch FeCl2.

B. Sc kh H2S vo dung dch CuCl2.

D. Cho Fe vo dung dch H2SO4 long, ngui.

Cu 3: Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit)
nng 0,95m gam. Phn trm khi lng PbS b t chy l
A. 95,00%.

B. 25,31%.

C. 74,69%.

D. 64,68%.

THI TUYN SINH I HC, CAO NG NM 2007, Khi B

Cu 1: Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s
A. nhn 13 electron.

B. nhn 12 electron.

C. nhng 13 electron.

D. nhng 12 electron.

Cu 2: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau
khi phn ng xy ra hon ton, thu c (cho Fe = 56)
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.

B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.

C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.

D. 0,12 mol FeSO4.

Cu 3: C th phn bit 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l
A. giy qu tm.

B. Zn.

C. Al.

D. BaCO3.

Cu 4: Cho 0,01 mol mt hp cht ca st tc dng ht vi H2SO4 c nng (d), thot ra 0,112 lt ( ktc) kh SO2 (l
sn phm kh duy nht). Cng thc ca hp cht st l
A. FeS.

B. FeS2.

C. FeO

D. FeCO3.

THI TUYN SINH I HC, CAO NG NM 2008, khi B

Cu 1: Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d). Sau khi cc phn
ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp kh. Bit p sut
kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc phn ng, lu hunh mc oxi
ho +4, th tch cc cht rn l khng ng k)
A. a = 0,5b.

B. a = b.

C. a = 4b.

D. a = 2b.

Cu 2: Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng rc ln thu ngn ri
gom li l
A. vi sng.
B. ct.
C. mui n.
D. lu hunh.
THI TUYN SINH I HC, CAO NG NM 2009, khi B

Cu 1: Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra
hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y
trong khng kh n khi lng khng i, thu c cht rn Z l
A. hn hp gm BaSO4 v FeO.

B. hn hp gm Al2O3 v Fe2O3.

C. hn hp gm BaSO4 v Fe2O3.

D. Fe2O3.

Cu 2: Trn 100 ml dd hh gm H2SO4 0,05M v HCl 0,1M vi 100 ml dd hh gm NaOH 0,2M v Ba(OH)2
0,1M, thu c dd X. dd X c pH l
A. 13,0.
B. 1,2.
C. 1,0.
D. 12,8.
Cu 3: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3.
Cht to ra lng O2 ln nht l
A. KClO3.
B. KMnO4. C. KNO3.
D. AgNO3.
Cu 4: C cc th nghim sau:
(I) Nhng thanh st vo dung dch H2SO4 long, ngui.
(III) Sc kh CO2 vo nc Gia-ven.
S th nghim xy ra phn ng ho hc l

(II) Sc kh SO2 vo nc brom.

(IV) Nhng l nhm vo dung dch H2SO4 c, ngui.

A. 2.

~ 15 ~

B. 1.

C. 3.

D. 4.

Cu 5: Ha tan hon ton 20,88 gam mt oxit st bng dd H2SO4 c, nng thu c dd X v 3,248 lt kh
SO2 (sn phm kh duy nht, ktc). C cn dd X, thu c m gam mui sunfat khan. Gi tr ca m l
A. 52,2.

B. 54,0.

C. 58,0.

D. 48,4.

Cu 6: ng dng no sau y khng phi ca ozon?

A. Ty trng tinh bt, du n.

B. Cha su rng.

C. iu ch oxi trong phng th nghim.

D. St trng nc sinh hot.

~ 16 ~

TC PHN NG HA HC
Cu 1: Cho phng trnh ho hc ca phn ng tng hp amoniac
t , xt

N 2 ( k ) + 3H 2 ( k )
2 NH 3 (k )

Khi tng nng ca hiro ln 2 ln, tc phn ng thun

A. tng ln 8 ln.

B. tng ln 6 ln.

C. tng ln 2 ln.

D. gim i 2 ln.

Cu 2: Cho cc cn bng ho hc:

N2(k) + 3H2(k)

2NH3(k)

H2(k) + I2(k) 2HI (k)

(2)

2SO2 (k) + O2 (k)

2NO2 (k)

(1)

2SO3 (k)

N2O4 (k)

(3)
(4)

Khi thay i p sut nhng cn bng ha hc b chuyn dch l:

A. (1), (2), (3).

B. (2), (3), (4).

C. (1), (3), (4).

D. (1), (2), (4).

Cu 3: Cho cc cn bng sau:

(1) 2SO2(k) + O2(k) xt,to 2SO3(k)
(2) N2(k) + 3H2(k)xt,to 2NH3(k)
(3) CO2 (k) + H2 (k) to CO (k) + H2O (k)
(4) 2HI (k) to H2 (k) + I2(k)
Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l
A. (1) v (2).

B. (1) v (3).

C. (3) v (4).

D. (2) v (4).

Cu 4: Cho cn bng (trong bnh kn) sau:

CO (k) + H2O (k) CO2 (k) + H2 (k)

H < 0

Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H 2; (4) tng p sut
chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l:
A. (1), (4), (5).

B. (1), (2), (3).

C. (2), (3), (4).

D. (1), (2), (4).

Cu 5: Cho cn bng ho hc: PCl5 (k) PCl3 (k) + Cl2 (k); >0.
Cn bng chuyn dch theo chiu thun khi
A. thm Cl2 vo h phn ng.

C. tng nhit ca h phn ng.

B. thm PCl3 vo h phn ng.

D. tng p sut ca h phn ng.

Cu 6: Cho cn bng ha hc:

N2(k) + 3H2(k) 2NH3(k) H < 0

Cn bng trn chuyn dch theo chiu thun khi

A. tng nhit ca h phn ng.

C. tng p sut ca h phn ng.

B. gim p sut ca h phn ng.

D. thm cht xc tc vo h phn ng.

Cu 7: Cho cn bng ho hc: 2SO2(k) + O2(k) 2SO3(k); phn ng thun l phn ng to nhit. Pht biu
ng l:
A. Cn bng chuyn dch theo chiu thun khi tng nhit .
B. Cn bng chuyn dch theo chiu nghch khi gim nng O2.
C. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng.

~ 17 ~

D. Cn bng chuyn dch theo chiu nghch khi gim nng SO3.
Cu 8: Cho cn bng sau trong bnh kn: 2NO2(k)
(mu nu )

N2O4(k).
(khng mu)

Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c

A. H < 0, phn ng ta nhit.
B. H > 0, phn ng ta nhit.
D. H < 0, phn ng thu nhit.
C. H > 0, phn ng thu nhit.
Cu 9: Cho cn bng: 2SO2(k) + O2(k) 2SO3(k). Khi tng nhit th t khi ca hn hp kh
so vi H2 gim i. Pht biu ng khi ni v cn bng ny l:
A. Phn ng thun thu nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
B. Phn ng nghch to nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
C. Phn ng nghch thu nhit, cn bng dch chuyn theo chiu thun khi tng nhit .
D. Phn ng thun to nhit, cn bng dch chuyn theo chiu nghch khi tng nhit .
Cu 10: Xt cn bng: N2O4(k) 2NO2(k) 25oC. Khi chuyn dch sang mt trng thi cn bng
mi nu nng ca N2O4tng ln 9 ln th nng ca NO2
A. tng 9 ln

B. tng 3 ln.

C. tng 4,5 ln.

D. gim 3 ln.

Cu 11: Cho cc cn bng sau:

(I) 2HI (k) H2(k) + I2(k);
(II) CaCO3 (r) CaO (r) + CO2 (k);
(III) FeO (r) + CO (k) Fe (r) + CO2 (k);
(IV) 2SO2(k) + O2(k) 2SO3(k).
Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l
A. 1.

B. 2.

C. 3.

D. 4.

Cu 12: Cho cn bng ho hc: H2(k) + I2(k) 2HI (k); H > 0.

Cn bng khng b chuyn dch khi
A. gim nng HI.

C. tng nhit ca h.

B. gim p sut chung ca h.

D. tng nng H2.

Cu 13: Cho cn bng ho hc sau: 2SO2 (k) + O2 (k) 2SO3 (k); H < 0.
Cho cc bin php: (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4)
dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng
bin php no lm cn bng trn chuyn dch theo chiu thun?
A. (1), (2), (4), (5).

B. (2), (3), (4), (6).

C. (1), (2), (4).

D. (2), (3), (5).

~ 18 ~

S IN LI AXIT BAZ MUI

Cu 1: Tin hnh cc th nghim sau:
(1) Sc kh H2S vo dung dch FeSO4;

(2) Sc kh H2S vo dung dch CuSO4;

(3) Sc kh CO2 (d) vo dung dch Na2SiO3;

(4) Sc kh CO2 (d) vo dung dch Ca(OH)2;

(5) Nh t t dung dch NH3 n d vo dung dch Al2(SO4)3;

(6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3.
Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l
A.5.

B. 6.

C. 3.

D. 4.

Cu 2: Cho a lt dung dch KOH c pH = 12,0 vo 8,00 lt dung dch HCl c pH = 3,0 thu c dd Y c pH =11,0. Gi tr
ca a l
A.1,60.

B. 0,80.

C. 1,78.

D. 0,12.

Cu 3: C 4 ng nghim c nh s theo th t 1, 2, 3, 4. Mi ng nghim cha mt trong cc dung dch AgNO3,

ZnCl2, HI, Na2CO3. Bit rng: - Dung dch trong ng nghim 2 v 3 tc dng c vi nhau sinh ra cht kh; - Dung dch
trong ng nghim 2 v 4 khng phn ng c vi nhau. Dung dch trong cc ng nghim 1, 2, 3, 4 ln lt l:
A. ZnCl2, HI, Na2CO3, AgNO3.

B. ZnCl2, Na2CO3, HI, AgNO3.

C. AgNO3, HI, Na2CO3, ZnCl2.

D. AgNO3, Na2CO3, HI, ZnCl2.

Cu 4: Cho cc dung dch long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn hp gm HCl v NaNO3. Nhng
dung dch phn ng c vi kim loi Cu l:
A.(1), (3), (5).

B. (1), (2), (3).

C. (1), (3), (4).

D. (1), (4), (5).

C. K+, Ba2+, OH, Cl.

D. Na+, K+, OH,

Cu 5: Dy gm cc ion cng tn ti trong mt dung dch l:

A. Al3+, PO43, Cl, Ba2+.
HCO3

B. Ca2+, Cl, Na+, CO32.

Cu 6: Ho tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dung dch X v cht rn Y. Sc kh CO2
n d vo dung dch X, sau khi cc phn ng xy ra hon ton thu c kt ta l
A.Fe(OH)3.

B. K2CO3.

C. Al(OH)3.

D. BaCO3.

Cu 7: Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100 ml dung dch
X cn dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong oleum trn l
A.32,65%.

B. 35,95%.

C. 37,86%.

D. 23,97%.

Cu 8: Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H2SO4 (d), thu c dung dch cha 7,5 gam
mui sunfat trung ho. Cng thc ca mui hirocacbonat l
A.NaHCO3.

B. Ca(HCO3)2.

C. Ba(HCO3)2.

D. Mg(HCO3)2.

Cu 9: Nh t t dung dch NaOH n d vo dung dch X. Sau khi cc phn ng xy ra hon ton ch thu c dung
dch trong sut. Cht tan trong dung dch X l
A.AlCl3.

B. CuSO4.

C. Ca(HCO3)2.

D. Fe(NO3)3.

Cu 10: Thuc th dng phn bit dung dch NH4NO3 vi dung dch (NH4)2SO4 l
A. ng(II) oxit v dung dch NaOH.

B. ng(II) oxit v dung dch HCl.

C. dung dch NaOH v dung dch HCl.

D. kim loi Cu v dung dch HCl.

Cu 11: Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04
mol H2SO4 thu c m gam kt ta. Gi tr ca m l
A.2,568.

B. 1,560.

C. 4,128.

D. 5,064.

C. dung dch Ba(OH)2.

D. dung dch NaOH.

Cu 12: phn bit CO2 v SO2 ch cn dng thuc th l

A. nc brom.

B. CaO.

~ 19 ~

Cu 13: Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht
tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l
A.8,3 v 7,2.

B. 11,3 v 7,8.

C. 13,3 v 3,9.

D. 8,2 v 7,8.

Cu 14: Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn ng thu
c m gam kt ta. Gi tr ca m l
A.19,7.

B. 39,4.

C. 17,1.

D. 15,5.

Cu 15: Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l:
A. NaHCO3, MgO, Ca(HCO3)2.

B. NaHCO3, ZnO, Mg(OH)2.

C. NaHCO3, Ca(HCO3)2, Al2O3.

D. Mg(OH)2, Al2O3, Ca(HCO3)2.

Cu 16: Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt dung dch l:

A. Al3+,NH4+,Br-,OH-

B.Mg2+,K+,SO42-,PO43-.

C. H+,Fe3+,NO3-,SO42-

D.Ag+,Na+,NO3-,Cl-

Cu 17: Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu c dung dch Y v kh Z.
Nh t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T. Axit X l
A.H2SO4 c.

B. HNO3.

C. H3PO4.

D. H2SO4 long.

Cu 18: Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi lng d
dung dch Ba(OH)2 to thnh kt ta l
A.5.

B. 4.

C. 1.

D. 3.

Cu 19: Dung dch X cha cc ion: Fe3+, SO42-, NH4+, Cl-. Chia dung dch X thnh hai phn bng nhau: - Phn mt tc
dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; - Phn hai tc dng vi
lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung dch X l
(qu trnh c cn ch c nc bay hi)
A.3,73 gam.

B. 7,04 gam.

C. 7,46 gam.

D. 3,52 gam.

Cu 20: Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca cc dung dch
c sp xp theo chiu tng t tri sang phi l:
A.(3), (2), (4), (1).

B. (4), (1), (2), (3).

C. (1), (2), (3), (4).

D. (2), (3), (4), (1).

Cu 21: Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong dy to thnh kt ta khi
phn ng vi dung dch BaCl2 l
A.4.

B. 6.

C. 3.

D. 2.

Cu 22: t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra
hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi
tr ca V l
A.150.

B. 100.

C. 200.

D. 300.

Cu 23: Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dy c tnh cht lng
tnh l
A.5.

B. 2.

C. 3.

D. 4.

Cu 24: Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7
l
A. Na2CO3, C6H5ONa, CH3COONa.

B. Na2CO3, NH4Cl, KCl.

C. KCl, C6H5ONa, CH3COONa.

D. NH4Cl, CH3COONa, NaHSO4.

Cu 25: Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t
dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca
m l
A.1,59.

B. 1,17.

C. 1,71.

D. 1,95.

Cu 26: Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO42. Tng khi lng cc mui tan c
trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l (Cho O = 16; S = 32; Cl = 35,5; K = 39; Cu = 64)
A.0,03 v 0,02.

B. 0,05 v 0,01.

C. 0,01 v 0,03.

Cu 27: Cc hp cht trong dy cht no di y u c tnh lng tnh?

~ 20 ~

D. 0,02 v 0,05.

A. Cr(OH)3, Fe(OH)2, Mg(OH)2.

B. Cr(OH)3, Zn(OH)2, Pb(OH)2.

C. Cr(OH)3, Zn(OH)2, Mg(OH)2.

D. Cr(OH)3, Pb(OH)2, Mg(OH)2.

Cu 28: Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau. - Cho phn 1 vo dung dch KOH (d) thu c
0,784 lt kh H2 (ktc). - Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim
loi Y. Ho tan hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc). Khi lng (tnh theo gam) ca K,
Al, Fe trong mi phn hn hp X ln lt l:
A. 0,39; 0,54; 1,40.

B. 0,78; 1,08; 0,56.

C. 0,39; 0,54; 0,56.

D. 0,78; 0,54; 1,12.

Cu 29: Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l
A. 3.

B. 4.

C. 2.

D. 1.

Cu 30: Tin hnh cc th nghim sau: (1) Cho dung dch NaOH vo dung dch Ca(HCO3)2. (2) Cho dung dch HCl ti
d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (3) Sc kh H2S vo dung dch FeCl2. (4) Sc kh NH3 ti d vo dung
dch AlCl3. (5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (6) Sc kh etilen vo dung dch
KMnO4. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 6.

B. 3.

C. 5.

D. 4.

Cu 31: Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch Y v phn khng
tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta
A. Fe(OH)3.

B. Fe(OH)2 v Cu(OH)2.

C. Fe(OH)2, Cu(OH)2 v Zn(OH)2.

D. Fe(OH)3 v Zn(OH)2.

Cu 32: Dung dch X gm CH3COOH 1M v HCl 0,001M. Gi tr pH ca dung dch X l (Ka = 1,75.10-5)
A. 1,77.

B. 2,33.

C. 2,43.

D. 2,55.

Cu 33: Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch KOH 2M vo X th
thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c 2a gam kt ta. Gi tr ca m
l
A.17,71.

B. 16,10.

C. 32,20.

D. 24,15.

Cu 34: Cho dung dch X gm: 0,007 mol Na+; 0,003 mol Ca2+; 0,006 mol Cl; 0,006 mol HCO3 v 0,001 mol NO3.
loi b ht Ca2+ trong X cn mt lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l
A.0,180.

B. 0,120.

C. 0,444.

D. 0,222.

Cu 35: Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tc dng c vi dung dch NaOH
long nhit thng l
A.4.

B. 5.

C. 3.

D. 6.

Cu 36: Dung dch X c cha: 0,07 mol Na+; 0,02 mol SO42-v x molOH- . Dung dch Y c cha ClO4-,NO3-v y mol
H+; tng s mol ClO4-,NO3- l 0,04. Trn X v Y c 100 ml dung dch Z. Dung dch Z c pH (b qua s in li ca
H2O) l
A.1.

B. 12.

C. 13.

D. 2.

Cu 37: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3 0,2M v NaHCO3
0,2M, sau phn ng thu c s mol CO2 l
A.0,020.

B. 0,030.

C. 0,015.

D. 0,010.

Cu 38: Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam
kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l
A.20,125.

B. 22,540.

C. 12,375.

D. 17,710.

Cu 39: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2 v
CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l
A.3.

B. 2.

C. 1.

D. 4.

Cu 40: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung
dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l
A. 4,48.

B. 3,36.

C. 2,24.

~ 21 ~

D. 1,12.

Cu 41: C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3.
Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l
A.4.

B. 2.

C. 5.

D. 3.

Cu 42: T hai mui X v Y thc hin cc phn ng sau:

X +X1
ng l

to

CO2 ; X1+H2O X2 : X2+Y X +Y1 +H2O ; X2+ 2Y X +Y2 +2H2O Hai mui X, Y tng

A.CaCO3, NaHSO4.
NaHCO3.

B. BaCO3, Na2CO3.

C. CaCO3, NaHCO3.

D. MgCO3,

Cu 43: Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi phn ng
hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l
A.0,45.

B. 0,35.

C. 0,25.

D. 0,05.

Cu 44: Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi
dung dch HCl, dung dch NaOH l
A.4.

B. 5.

C. 7.

D. 6.

Cu 45: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v
dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A.0,55.

B. 0,60.

C. 0,40.

D. 0,45.

Cu 46: Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y
c pH l
A.4.

B. 3.

C. 2.

D. 1.

Cu 47: Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy ra hon

ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l
A. 10,8.

B. 5,4.

C. 7,8.

D. 43,2.

Cu 48: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon
ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1 tc dng vi dung dch H2SO4 long (d), sinh
ra 3,08 lt kh H2 ( ktc); - Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l
A.22,75

B. 21,40.

C. 29,40.

D. 29,43.

Cu 49: Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra l
A. c kt ta keo trng, sau kt ta tan.

B. ch c kt ta keo trng.

C. c kt ta keo trng v c kh bay ln.

D. khng c kt ta, c kh bay ln.

Cu 50: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u, thu c V lt kh
( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V
vi a, b l:
A.V = 22,4(a - b).

B. V = 11,2(a - b).

C. V = 11,2(a + b).

D. V = 22,4(a + b).

Cu 51: Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l
A.a : b = 1 : 4.

B. a : b < 1 : 4.

C. a : b = 1 : 5.

D. a : b > 1 : 4.

Cu 52: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th l
A.Fe.

B. CuO.

C. Al.

D. Cu.

Cu 53: Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht
lng tnh l
A.3.

B. 5.

C. 2.

D. 4.

Cu 54: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c
5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l
A.1.

B. 6.

C. 7.

D. 2.

Cu 55: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung
dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l

~ 22 ~

A.4.

B. 1.

C. 3.

D. 2.

Cu 56: Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dd
NaOH (c, nng) l
A.4.

B. 6.

C. 3.

D. 5.

Cu 57: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4

0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N+5).
Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch
c pH = z. Gi tr ca z l
A.2.

B. 4.

C. 3.

D. 1.

Cu 58: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M,
sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl 2 (d)
th thu c 33,552 gam kt ta. T l x : y l
A.3 : 4.

B. 3 : 2.

C. 4 : 3.

D. 7 : 4.

Cu 59: Cho dy cc oxit sau: SO2, NO2, NO, SO3, CrO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi
H2O iu kin thng l
A.7.

B. 5.

C. 6.

D. 8.

Cu 60: Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu cht trong
dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH?
A.3.

B. 5.

C. 4.

D. 2.

Cu 61: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung
dch
A.Pb(NO3)2.

B. NaHS.

C. AgNO3.

D. NaOH.

Cu 62: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4,
Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l
A.4.

B. 7.

C. 5.

D. 6.

Cu 63: Pht biu no sau y khng ng?

A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht.
B. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh.
C. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng.
D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng.
Cu 64: Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu c dung dch Y
v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt ta. Gi tr ca
x l
A.1,2.

B. 0,8.
2+

C. 0,9.
+

D. 1,0.

Cu 65: Dung dch X cha cc ion: Ca , Na , HCO3 v Cl , trong s mol ca ion Cl l 0,1. Cho 1/2 dung dch X
phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch
Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi
tr ca m l
A.9,21.

B. 9,26.

C. 8,79.

D. 7,47.

Cu 66: Hn hp bt X gm Cu, Zn. t chy hon ton m gam X trong oxi (d), thu c 40,3 gam hn hp gm CuO
v ZnO. Mt khc, nu cho 0,25 mol X phn ng vi mt lng d dung dch KOH long nng, th thu c 3,36 lt kh
H2 (ktc). Phn trm khi lng ca Cu trong X l
A.19,81%.

B. 29,72%.

C. 39,63%.

Cu 67: Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng?
A. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4.
B. in li ca axit fomic s gim khi thm dung dch HCl.
C. Khi pha long dung dch trn th in li ca axit fomic tng.

~ 23 ~

D. 59,44%.

D. in li ca axit fomic trong dung dch trn l 14,29%.

Cu 68: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH
0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l
A. 13,0.

B. 1,2.

C. 1,0.

D. 12,8.

Cu 69: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon
ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh
H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6.

B. 48,3.

C. 36,7.

D. 57,0.

(3) Na2SO4 + BaCl2

(4) H2SO4 + BaSO3

Cu 70: Cho cc phn ng ha hc sau:

(1) (NH4)2SO4 + BaCl2

(2) CuSO4 + Ba(NO3)2

(5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 Cc phn ng u c cng mt phng trnh ion rt gn
l:
A. (1), (2), (3), (6).

B. (1), (3), (5), (6).

C. (2), (3), (4), (6).

D. (3), (4), (5), (6).

Cu 71: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25oC, Ka ca CH3COOH
l 1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25oC l
A. 1,00.

B. 4,24.

C. 2,88.

D. 4,76.

Cu 72: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh
NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra
hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l
A.21,95% v 2,25.

B. 78,05% v 2,25.

C. 21,95% v 0,78.

D. 78,05% v 0,78.

Cu 73: Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c
200 ml dung dch c pH = 12. Gi tr ca a l (bit trong mi dung dch [H+][OH-] = 10-14)
A. 0,15.

B. 0,30.

C. 0,03.

D. 0,12.

Cu 74: Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng
c vi dung dch Ba(HCO3)2 l:
A. HNO3, NaCl, Na2SO4.

B. HNO3, Ca(OH)2, KHSO4, Na2SO4.

C. NaCl, Na2SO4, Ca(OH)2.

D. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2.

Cu 75: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6
gam. Gi tr ln nht ca V l (cho H = 1, O = 16, Al = 27)
A. 1,2.

B. 1,8.

C. 2,4.

D. 2.

Cu 76: Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nucng cho m gam X
vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l (bit cc th
tch kh o trong cng iu kin,
A. 39,87%.

B. 77,31%.

C. 49,87%.

D. 29,87%.

Cu 77: Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo
H2O (d), un nng, dung dch thu c cha
A. NaCl, NaOH, BaCl2.

B. NaCl, NaOH.

C. NaCl, NaHCO3, NH4Cl, BaCl2.

D. NaCl

Cu 78: C th phn bit 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l
A. giy qu tm.

B. Zn.

C. Al.

D. BaCO3.

Cu 79: Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v
HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l
A. 7.

B. 2.

C. 1.

D. 6.

Cu 80: Cho dy cc oxit: NO2, Cr2O3, SO2, CrO3, CO2, P2O5, Cl2O7, SiO2, CuO. C bao nhiu oxit trong dy tc
dng c vi dung dch NaOH long?
A. 6.

B. 7.

C. 8.

Cu 81: Cho cc phn ng sau:

~ 24 ~

D. 5.

(a) FeS + 2HCl FeCl2 + H2S

(b) Na2S + 2HCl 2NaCl + H2S
(c) 2AlCl3 + 3Na2S + 6H2O 2Al(OH)3 + 3H2S + 6NaCl
(d) KHSO4 + KHS K2SO4 + H2S
(e) BaS + H2SO4 (long) BaSO4 + H2S
S phn ng c phng trnh ion rt gn S2- + 2H+ H2S l
A. 4.

B. 3.

C. 2.

D. 1.

Cu 82: Mt dung dch gm: 0,01 mol Na+; 0,02 mol Ca2+; 0,02 mol HCO3- v a mol ion X (b qua s in li ca
nc). Ion X v gi tr ca a l
A. NO3- v 0,03

B. Cl- v 0,01

C. CO32- v 0,03

D. OH- v 0,03

Cu 83: Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu tm ha xanh. Trn ln hai dung dch
trn thu c kt ta. Hai cht X v Y tng ng l
A. KNO3 v Na2CO3.

B. Ba(NO3)2 v Na2CO3.

C. Na2SO4 v BaCl2.

D. Ba(NO3)2 v K2SO4.

Cu 84: Bit 250C, hng s phn li baz ca NH3 l 1,74.10-5, b qua s phn li ca nc. Gi tr pH ca dung dch
NH3 0,1M 250oC l
A. 11,12

B. 4,76

C. 13,00

~ 25 ~

D. 9,24

NIT PHT PHO V HP CHT CA CHNG

Cu 1: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt ( ktc) hn hp kh X
(gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l
A. 2,24.

B. 4,48.

C. 5,60.

D. 3,36.

Cu 2: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c
1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr
ca m l
A.38,72.

B. 35,50.

C. 49,09.

D. 34,36.

Cu 3: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm
kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l
A.1,92.

B. 3,20.

C. 0,64.

D. 3,84.

Cu 4: Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c cht rn X (gi s phn ng xy
ra hon ton). Phn trm khi lng ca Cu trong X l
A.85,88%.

B. 14,12%.

C. 87,63%.

D. 12,37%.

Cu 5: un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc
phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO2 (khng c
sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l
A.50,4.

B. 40,5.

C. 44,8.

D. 33,6.

Cu 6: Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn ng xy ra hon ton
(sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi lng mui khan thu c l
A. 19,76 gam.

B. 22,56 gam.

C. 20,16 gam.

D. 19,20 gam.

Cu 7: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn ng xy
ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc
phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l
A. 0,224 lt v 3,750 gam.
gam.

B. 0,112 lt v 3,750 gam.

C. 0,224 lt v 3,865 gam.

D. 0,112 lt v 3,865

Cu 8: Hn hp kh X gm N2 v H2 c t khi so vi He bng 1,8. un nng X mt thi gian trong bnh kn (c bt Fe lm

xc tc), thu c hn hp kh Y c t khi so vi He bng 2. Hiu sut ca phn ng tng hp NH3 l
A.25%.

B. 50%.

C. 36%.

D. 40%.

Cu 9: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh NxOy (sn phm kh
duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l
A.NO v Mg.

B. NO2 v Al.

C. N2O v Al.

D. N2O v Fe.

Cu 10: Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O Sau khi cn bng phng trnh ho hc
trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l
A.13x - 9y.

B. 46x - 18y.

C. 45x - 18y.

D. 23x - 9y.

Cu 11: Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v
hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH bng
A.4.

B. 2.

C. 1.

D. 3.

Cu 12: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn
hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam
cht rn khan. Gi tr ca m l
A.38,34.

B. 34,08.

C. 106,38.

D. 97,98.

Cu 13: Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3
0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung
dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l

~ 26 ~

A.360.

B. 240.

C. 400.

D. 120.

Cu 14: Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l 0,3M v 0,7M.
Sau khi phn ng tng hp NH3 t trng thi cn bng t oC, H2 chim 50% th tch hn hp thu c. Hng s cn
bng KC t oC ca phn ng c gi tr l
A.2,500.

B. 3,125.

C. 0,609.

D. 0,500.

Cu 15: Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn
ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A.0,746.

B. 0,448.

C. 1,792.

D. 0,672.

Cu 16: Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch
cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l
A.0,04.

B. 0,075.

C. 0,12.

D. 0,06.

Cu 17: thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi ta ho tan X bi dung
dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%)
A. c mol bt Al vo Y.

B. c mol bt Cu vo Y.

C. 2c mol bt Al vo Y.

D. 2c mol bt Cu vo Y.

Cu 18: Ho tan hon ton 13,00 gam Zn trong dung dch HNO3 long, d thu c dung dch X v 0,448 lt kh N2 (ktc).
Khi lng mui trong dung dch X l A.18,90 gam.
B. 37,80 gam.
C. 28,35 gam.
D.
39,80 gam.
Cu 19: Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2 (ktc) v
dung dch X. Nh t t dung dch NH3 n d vo dung dch X thu c kt ta, lc ht lng kt ta, nung n khi
lng khng i thu c 2,04 gam cht rn. Gi tr ca V l
A.0,448.

B. 0,224.

C. 1,344.

D. 0,672.

Cu 20: Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d dung dch HNO3. Sau khi cc phn
ng xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam
mui khan. Kh X l
A.N2O.

B. NO2.

C. N2.

D. NO.

Cu 21: Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn ng xy ra
hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht ca ). Gi tr ca a l N
A.5,6.

B. 11,2.

C. 8,4.

D. 11,0.

Cu 22: Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc phn ng xy ra hon
ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d dung dch HCl th thu c 0,336 lt kh
( ktc). Gi tr ca m1 v m2 ln lt l
A.8,10 v 5,43.

B. 1,08 v 5,43.

C. 0,54 v 5,16.

D. 1,08 v 5,16.

Cu 23: Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c dung dch X v 3,136
lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18
gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm khi lng ca Al trong
hn hp ban u l
A.19,53%.

B. 12,80%.

C. 10,52%.

D. 15,25%.

Cu 24: Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu c dung dch Y v kh Z. Nh
t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T. Axit X l
A.H2SO4 c.

B. HNO3.

C. H3PO4.

D. H2SO4 long.

Cu 25: Nhit phn hon ton 34,65 gam hn hp gm KNO3 v Cu(NO3)2, thu c hn hp kh X (t khi ca X so vi
kh hiro bng 18,8). Khi lng Cu(NO3)2 trong hn hp ban u l
A.8,60 gam.

B. 20,50 gam.

C. 11,28 gam.

D. 9,40 gam.

Cu 26: Chia m gam Al thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh
H2; - Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn phm kh duy nht). Quan h
gia x v y l
A.x = 2y.

B. y = 2x.

C. x = 4y.

~ 27 ~

D. x = y.

Cu 27: Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy nht, ktc).
Kh X l
A.N2O.

B. NO2.

C. N2.

D. NO.

Cu 28: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M
v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N+5). Trn a
mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH
= z. Gi tr ca z l
A.2.

B. 4.

C. 3.

D. 1.

Cu 29: Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc
dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ho tan ton b Y bng dung dch HNO3 (long, d)
c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l A.57,15%.
B. 14,28%.
C. 28,57%.
D. 18,42%.
Cu 30: Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn
hp Y. Ho tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S
mol HNO3 phn ng l
A.0,12.

B. 0,14.

C. 0,16.

D. 0,18.

Cu 31: Pht biu no sau y khng ng?

A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht.
B. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh.
C. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng.
D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng.
Cu 32: Mt loi phn supephotphat kp c cha 69,62% mui canxi ihirophotphat, cn li gm cc cht khng cha
photpho. dinh dng ca loi phn ln ny l
A.48,52%.
Cu 33: Cho s chuyn ho:

B. 42,25%.
P2O5

+KOH

C. 39,76%.
X

H3PO4

Y +KOH

D. 45,75%.
Cc cht X, Y, Z ln lt l:

A. K3PO4, K2HPO4, KH2PO4. B. KH2PO4, K2HPO4, K3PO4.

K2HPO4.
D. KH2PO4, K3PO4, K2HPO4.

C. K3PO4, KH2PO4,

Cu 34: Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn ng xy ra
hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l
A.6,72.

B. 8,96.

C. 4,48.

D. 10,08.

Cu 35: Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u. Sau khi
cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam
kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.

B. 137,1.

C. 97,5.

D. 108,9.

Cu 36: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng
xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m
v V ln lt l
A. 10,8 v 4,48.

B. 10,8 v 2,24.

C. 17,8 v 2,24.

D. 17,8 v 4,48.

Cu 37: Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO4 0,5M, thu c dung dch X. C cn dung dch X,
thu c hn hp gm cc cht l
A. KH2PO4 v K3PO4.

B. KH2PO4 v K2HPO4.

C. KH2PO4 v H3PO4.

D. K3PO4 v KOH.

Cu 38: Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (sn phm kh
duy nht) to thnh ln lt l
A. 0,03 v 0,02.

B. 0,06 v 0,01.

C. 0,03 v 0,01.

D. 0,06 v 0,02.

Cu 39: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2
(sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon
ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l
A.21,95% v 2,25.

B. 78,05% v 2,25.

C. 21,95% v 0,78.

~ 28 ~

D. 78,05% v 0,78.

Cu 40: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh
NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l
A. 8,88 gam.

B. 13,92 gam.

C. 6,52 gam.

D. 13,32 gam.

Cu 41: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc).
Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh
NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 11,5.

B. 10,5.

C. 12,3.

D. 15,6.

Cu 42: Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht:
A. K3PO4, K2HPO4.

B. K2HPO4, KH2PO4.

C. K3PO4, KOH.

D. H3PO4, KH2PO4.

Cu 43: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15
mol Cu l (bit phn ng to cht kh duy nht l NO) A. 1,0 lt.
B. 0,6 lt. C. 0,8 lt.
D. 1,2 lt.
Cu 44: Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3
(d), thot ra 0,56 lt ( ktc) NO (l sn phm kh duy nht). Gi tr ca m l
A. 2,52.

B. 2,22.

C. 2,62.

D. 2,32.

Cu 45: Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2)
Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn
phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l
A.V2 = V1.

B. V2 = 2V1.

C. V2 = 2,5V1.

D. V2 = 1,5V1.

Cu 46: Trong cc th nghim sau:

(1) Cho SiO2 tc dng vi axit HF. (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng.
(4) Cho CaOCl2 tc dng vi dung dch HCl c. (5) Cho Si n cht tc dng vi dung dch NaOH. (6) Cho kh O3 tc
dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. S th nghim to ra n cht l
A.7.

B. 6.

C. 5.

D. 4.

Cu 47: Khi so snh NH3 vi NH4 , pht biu khng ng l:

A. Phn t NH3 v ion NH4+ u cha lin kt cng ha tr.

B. Trong NH3 v NH4+, nit u c s oxi ha 3.

C. NH3 c tnh baz, NH4+ c tnh axit.

D. Trong NH3 v NH4+, nit u c cng ha tr 3.

Cu 48: Thc hin cc th nghim sau:

(1) t dy st trong kh clo. (2) t nng hn hp bt Fe v S (trong iu kin khng c oxi). (3) Cho FeO vo dung dch
HNO3 (long, d). (4) Cho Fe vo dung dch Fe2(SO4)3. (5) Cho Fe vo dung dch H2SO4 (long, d). C bao nhiu
th nghim to ra mui st(II)?
A. 2.

B. 1.

C. 4.

D. 3.

Cu 49: Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe2O3 + CO (k), (3) Au + O2 (k), (4) Cu + Cu(NO3)2
(r), (5) Cu + KNO3 (r), (6) Al + NaCl (r). Cc trng hp xy ra phn ng oxi ho kim loi l:
A.(1), (3), (6).

B. (2), (5), (6).

C. (2), (3), (4).

D. (1), (4), (5).

Cu 50: Xt cn bng: N2O4 (k) 2NO2 (k) 25oC. Khi chuyn dch sang mt trng thi cn bng mi nu nng ca
N2O4 tng ln 9 ln th nng ca NO2 A.tng 9 ln.
B. tng 3 ln.
C. tng 4,5 ln. D.
gim 3 ln.
Cu 51: Pht biu no sau y l ng?
A. Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3-) v ion amoni (NH4+).
hp cc mui (NH4)2HPO4 v KNO3.
C. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK.
thc l (NH4)2CO3.

B. Amophot l hn
D. Phn ur c cng

Cu 52: Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu
ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l
A.amophot.

B. ure.

C. natri nitrat.

~ 29 ~

D. amoni nitrat.

(1) Cu(NO3)2

Cu 53: Cho cc phn ng sau: (4)

u to kh N2 l:
A.(2), (4), (6).

NH3 + Cl2

to
to

;(2) NH4NO2

to

;(5) NH4Cl

B. (3), (5), (6).

;(3) NH3 + O2

8500c,Pt

;(6) NH3 + CuO

C. (1), (3), (4).

to

Cc phn ng

D. (1), (2), (5).

Cu 54: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni nitrit
bo ho. Kh X l
A.NO.

B. NO2.

C. N2O.

D. N2.

Cu 55: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln
lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l
A.8.

B. 5.

C. 7.

D. 6.

Cu 56: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th l
A.Fe.

B. CuO.

C. Al.

D. Cu.

Cu 57: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu vi dung dch HNO3
c, nng l
A.10.

B. 11.

C. 8.

D. 9.

Cu 58: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung
dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l
A.4.

B. 1.

C. 3.

D. 2.

Cu 59: Dy gm cc kim loi u tc dng c vi dung dch HCl nhng khng tc dng vi dung dch HNO3 c,
ngui l:
A.Cu, Fe, Al.

B. Fe, Al, Cr.

C. Cu, Pb, Ag.

D. Fe, Mg, Al.

Cu 60: Tin hnh cc th nghim sau: (1) Sc kh H2S vo dung dch FeSO4; (2) Sc kh H2S vo dung dch CuSO4; (3)
Sc kh CO2 (d) vo dung dch Na2SiO3; (4) Sc kh CO2 (d) vo dung dch Ca(OH)2; (5) Nh t t dung dch NH3
n d vo dung dch Al2(SO4)3; (6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3. Sau khi cc phn
ng xy ra hon ton, s th nghim thu c kt ta l
A.5.

B. 6.

C. 3.

D. 4.

Cu 61: nhn ra ion NO3 trong dung dch Ba(NO3)2, ngi ta un nng nh dung dch vi
A. kim loi Cu.
dung dch H2SO4 long.

B. dung dch H2SO4 long.

C. kim loi Cu v dung dch Na2SO4. D. kim loi Cu v

Cu 62: Cho cc dung dch long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn hp gm HCl v NaNO3. Nhng
dung dch phn ng c vi kim loi Cu l:
A.(1), (3), (5).

B. (1), (2), (3).

C. (1), (3), (4).

D. (1), (4), (5).

Cu 68: Cht rn X phn ng vi dung dch HCl c dung dch Y. Cho t t dung dch NH3 n d vo dung dch Y, ban
u xut hin kt ta xanh, sau kt ta tan, thu c dung dch mu xanh thm. Cht X l
A.FeO.

B. Cu.

C. CuO.

D. Fe.

Cu 64: Thuc th dng phn bit dung dch NH4NO3 vi dung dch (NH4)2SO4 l
A. ng(II) oxit v dung dch NaOH.

B. ng(II) oxit v dung dch HCl.

C. dung dch NaOH v dung dch HCl.

D. kim loi Cu v dung dch HCl.

Cu 65: Sn phm ca phn ng nhit phn hon ton AgNO3 l:

A.Ag2O, NO, O2.

B. Ag2O, NO2, O2.

C. Ag, NO, O2.

D. Ag, NO2, O2.

C. (NH4)3PO4 v KNO3.

D. (NH4)2HPO4 v

Cu 66: Phn bn nitrophotka (NPK) l hn hp ca

A. (NH4)2HPO4 v KNO3.
NaNO3

B. NH4H2PO4 v KNO3.

Cu 67: Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy b oxi ha khi tc dng vi
dung dch HNO3 c, nng l
A.3.

B. 5.

C. 4

~ 30 ~

D. 6.

Cu 68: Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO3)2, dung dch HNO3 (c, ngui). Kim loi M l
A.Al.

B. Zn.

C. Fe.

D. Ag.

C. NaNO3.

D. K2CO3

Cu 69: Phn bn no sau y lm tng chua ca t?

A. KCl.

B. NH4NO3.

Cu 70: Phn ng nhit phn khng ng l

A. 2KNO3
C. NH4Cl

to
to

2KNO2 + O2.

B. NH4NO2

NH3 + HCl.

D. NaHCO3

to
to

N2 + 2H2O.
NaOH + CO2.

Cu 71: Thnh phn chnh ca qung photphorit l

A. Ca3(PO4)2.

B. NH4H2PO4.

C. Ca(H2PO4)2.

Cu 72: Cho cn bng ho hc: N2 (k) + 3H2 (k)

hc khng b chuyn dch khi
A. thay i p sut ca h.

D. CaHPO4.

2NH3 (k); phn ng thun l phn ng to nhit. Cn bng ho

B. thay i nng N2.

C. thay i nhit .

D. thm cht xc tc Fe.

Cu 73: Cho cc phn ng sau:

H2S + O2 (d)
H2O

to

Kh X + H2O ;NH3 + O2

to ,Pt

Kh Y + H2O ;NH4HCO3 + HCl long Kh Z + NH4Cl +

Cc kh X, Y, Z thu c ln lt l:
A. SO3, NO, NH3.

B. SO2, N2, NH3.

C. SO2, NO, CO2.

D. SO3, N2, CO2

Cu 74: Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l
A. 1.

B. 3.

C. 2.

D. 4.

Cu 75: Khi cho Cu tc dng vi dung dch cha H2SO4 long v NaNO3, vai tr ca NaNO3 trong phn ng l
A. cht xc tc.

B. cht oxi ho.

C. mi trng.

D. cht kh.

Cu 76: Mt loi phn kali c thnh phn chnh l KCl (cn li l cc tp cht khng cha kali) c sn xut t
qung xinvinit c dinh dng 55%. Phn trm khi lng ca KCl trong loi phn kali l
A. 95,51%.

B. 87,18%.

C. 65,75%.

D. 88,52%.

Cu 77: Thnh phn chnh ca phn bn phc hp amophot l

A. NH4H2PO4 v (NH4)2HPO4.

B. NH4NO3 v Ca(H2PO4)2.

C. NH4H2PO4 v Ca(H2PO4)2.

D. Ca3(PO4)2 v (NH4)2HPO4.

Cu 78: Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh th KNO3 to thnh kh
Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to thnh kh Z. Cc kh X, Y v Z ln lt l
A. Cl2, O2 v H2S

B. H2, O2 v Cl2.

C. SO2, O2 v Cl2.

D. H2, NO2 v Cl2.

Cu 79: Cho 1,42 gam P2O5 tc dng hon ton vi 50 ml dung dch KOH 1M, thu c dung dch X. C cn
dung dch X thu c cht rn khan gm
A. H3PO4 v KH2PO4.

B. K3PO4 v KOH.

Cu 80: Cho phn ng: N2 (k) + 3H2 (k)

bng chuyn dch theo chiu thun l

C. KH2PO4 v K2HPO4.

D. K2HPO4 v K3PO4.

2NH3 (k); H = 92 kJ. Hai bin php u lm cn

A. gim nhit v gim p sut.

B. tng nhit v tng p sut.

C. gim nhit v tng p sut.

D. tng nhit v gim p sut.

Cu 81: Cho 18,4 gam hn hp X gm Cu2S, CuS, FeS2 v FeS tc dng ht vi HNO3 (c nng d) thu
c V lt kh ch c NO2 ( ktc, sn phm kh duy nht) v dung dch Y. Cho ton b Y vo mt lng d
dung dch BaCl2, thu c 46,6 gam kt ta, cn khi cho ton b Y tc dng vi dung dch NH3 d thu c
10,7 gam kt ta. Gi tr ca V l
A. 38,08.

B. 11,2.

C. 24,64.

~ 31 ~

D. 16,8.

Cu 82: t 5,6 gam Fe trong khng kh, thu c hn hp cht rn X. Cho ton b X tc dng vi dung dch
HNO3 long (d), thu c kh NO (sn phm kh duy nht) v dung dch cha m gam mui. Gi tr ca m l
A. 18,0.

B. 22,4.

C. 15,6.

D. 24,2.

Cu 83: Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500 ml dung dch HNO3 1M.
Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O (ktc) duy nht v dung dch X cha m gam mui.
Gi tr ca m l
A. 34,10

B. 31,32

C. 34,32

D. 33,70

Cu 84: Ho tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn phm thu c gm dung
dch X v mt cht kh thot ra. Dung dch X c th ha tan ti a m gam Cu. Bit trong cc
qu trnh trn, sn phm kh duy nht ca N+5 u l NO. Gi tr ca m l
A. 12,8.

B. 6,4.

C. 9,6.

D. 3,2.

Cu 85: Ho tan Au bng nc cng toan th sn phm kh l NO; ho tan Ag trong dung dch HNO3 c
th sn phm kh l NO2. s mol NO2 bng s mol NO th t l s mol Ag v Au tng ng l
A. 1 : 2.

B. 3 : 1.

C. 1 : 1.

D. 1 : 3.

Cu 86: Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung dch HNO3 1,5M, thu
c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc) gm NO v N2O. T khi ca X so vi H2 l
16,4. Gi tr ca m l
A. 98,20.

B. 97,20.

C. 98,75.

D. 91,00.

Cu 87: Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c dung dch ch
cha mt cht tan v kim loi d. Cht tan l
A. Cu(NO3)2.

B. HNO3.

C. Fe(NO3)2.

~ 32 ~

D. Fe(NO3)3.

CACBON SILIC V HP CHT CA CHNG

Cu 1 (Khi A 2011): Trong cc th nghim sau: (1) Cho SiO 2 tc dng vi axit HF. (2) Cho kh SO 2 tc dng vi kh
H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl 2 tc dng vi dung dch HCl c. (5) Cho Si n cht
tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung
dch NaNO2 un nng.
S th nghim to ra n cht l
A. 7.

B. 6.

C. 5.

D. 4.

Cu 2 (Khi A 2011): Nhm nhng cht kh (hoc hi) no di y u gy hiu ng nh knh khi nng ca chng
trong kh quyn vt qu tiu chun cho php?
A. CH4 v H2O.

B. CO2 v CH4.

C. N2 v CO.

D. CO2 v O2.

Cu 3 (Khi A 2010): Pht biu khng ng l:

A. Tt c cc nguyn t halogen u c cc s oxi ho: -1, +1, +3, +5 v +7 trong cc hp cht.
B. Trong cng nghip, photpho c sn xut bng cch nung hn hp qung photphorit, ct v than cc 1200 oC
trong l in.
C. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon.
D. Hiro sunfua b oxi ho bi nc clo nhit thng.
Cu 4 (Khi A 2008): T hai mui X v Y thc hin cc phn ng sau: X
X2+Y X+ Y1 +H2O ;
A.CaCO3, NaHSO4.

X2+ 2Y X+ Y2+2H2O
B. BaCO3, Na2CO3.

to

X1 +CO2 ;

X1 +H2O X2 ;

.Hai mui X, Y tng ng l

C. CaCO3, NaHCO3.

D. MgCO3, NaHCO3.

Cu 5 (C 2011): Tin hnh cc th nghim sau: (1) Sc kh H2S vo dung dch FeSO4; (2) Sc kh H2S vo dung
dch CuSO4; (3) Sc kh CO2 (d) vo dung dch Na2SiO3; (4) Sc kh CO2 (d) vo dung dch Ca(OH)2; (5) Nh t
t dung dch NH3 n d vo dung dch Al2(SO4)3; (6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3.
Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l
A.5.

B. 6.

C. 3.

D. 4

Cu 6 (C 2010): Ho tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dung dch X v cht rn Y.
Sc kh CO2 n d vo dung dch X, sau khi cc phn ng xy ra hon ton thu c kt ta l
A.Fe(OH)3.

B. K2CO3.

C. Al(OH)3.

D. BaCO3

Cu 7 (C 2009): phn bit CO2 v SO2 ch cn dng thuc th l

A. nc brom.

B. CaO.

C. dung dch Ba(OH)2.

D. dung dch NaOH.

Cu 8 (C 2009): Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l:
A. NaHCO3, MgO, Ca(HCO3)2.
B. NaHCO3, ZnO, Mg(OH)2. C. NaHCO3, Ca(HCO3)2,
Al2O3.
D. Mg(OH)2, Al2O3, Ca(HCO3)2.
Cu 9 (C 2009): Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k)
CO2 (k) + H2 (k) H < 0 Trong cc
yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H 2; (4) tng p sut chung ca h; (5) dng
cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l:
A.(1), (4), (5).

B. (1), (2), (3).

C. (2), (3), (4).

D. (1), (2), (4).

Cu 10 (C 2007): Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu
c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng xy ra
hon ton. Phn khng tan Z gm
A.MgO, Fe, Cu.

B. Mg, Fe, Cu.

C. MgO, Fe3O4, Cu.

D. Mg, Al, Fe, Cu.

Cu 11 (C 2007): Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l

A. NaOH v NaClO.

B. Na2CO3 v NaClO

.C. NaClO3 v Na2CO3.

~ 33 ~

D. NaOH v Na2CO3.

Cu 12 (Khi B 2012): Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl 2, Ca(NO3)2, NaOH, Na2CO3,
KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l
A.4.

B. 7.

C. 5.

D. 6.

Cu 13 (Khi B 2010): Pht biu no sau y khng ng?

A. Dung dch m c ca Na2SiO3 v K2SiO3 c gi l thy tinh lng.
B. m chy magie c th c dp tt bng ct kh.
C. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon.
D. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho.
Cu 14 (Khi A 2011): Hp th hon ton 0,672 lt kh CO2 (ktc) vo 1 lt dung dch gm NaOH 0,025M v Ca(OH) 2
0,0125M, thu c x gam kt ta. Gi tr ca x l
A.2,00.

B. 1,00.

C. 1,25.

D. 0,75.

Cu 15 (Khi A 2010): Cho m gam NaOH vo 2 lt dung dch NaHCO 3 nng a mol/l, thu c 2 lt dung dch X.
Ly 1 lt dung dch X tc dng vi dung dch BaCl 2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1 lt dung dch X
vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m tng
ng l
A.0,08 v 4,8.

B. 0,04 v 4,8.

C. 0,14 v 2,4.

D. 0,07 v 3,2.

Cu 16 (Khi A 2010): Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na 2CO3
0,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l
A.0,020.

B. 0,030.

C. 0,015.

D. 0,010.

Cu 17 (Khi A 2009): Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M
v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l
A.1,182.

B. 3,940.

C. 1,970.

D. 2,364.

Cu 18 (Khi A 2009): Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn
ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A.0,8 gam.

B. 8,3 gam.

C. 2,0 gam.

D. 4,0 gam.

Cu 19 (Khi A 2009): Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh
CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
A.m = 2a V/22,4.

B. m = 2a V/11,2.

C. m = a + V/5,6.

D. m = a V/5,6.

Cu 20 (Khi A 2009): Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n
ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l
A.4,48.

B. 3,36.

C. 2,24.

D. 1,12.

Cu 21 (Khi A 2008): Cho V lt hn hp kh ( ktc) gm CO v H 2 phn ng vi mt lng d hn hp rn gm

CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V
l
A.0,448.

B. 0,112.

C. 0,224.

D. 0,560.

Cu 22 (Khi A 2008): Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol
hn hp kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A.0,55.

B. 0,60.

C. 0,40.

D. 0,45.

Cu 23 (Khi A 2008): Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M
v Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l
A.19,70.

B. 17,73.

C. 9,85.

D. 11,82.

Cu 24 (Khi A 2007): Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u,
thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu
thc lin h gia V vi a, b l:
A.V = 22,4(a - b).

B. V = 11,2(a - b).

C. V = 11,2(a + b).

D. V = 22,4(a + b).

Cu 25 (Khi A 2007): Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH) 2 nng a mol/l,
thu c 15,76 gam kt ta. Gi tr ca a l A.0,032.
B. 0,048.
C. 0,06. D. 0,04.

~ 34 ~

Cu 26 (C 2010): Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M, thu c dung dch
X. Coi th tch dung dch khng thay i, nng mol ca cht tan trong dung dch X l
A.0,6M.

B. 0,2M.

C. 0,1M.

D. 0,4M..

Cu 27 (C 2010): Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H 2SO4 (d), thu c dung dch
cha 7,5 gam mui sunfat trung ho. Cng thc ca mui hirocacbonat l
A.NaHCO3.

B. Ca(HCO3)2.

C. Ba(HCO3)2.

D. Mg(HCO3)2.

Cu 28 (C 2009): Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y
ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln
lt l
A.8,3 v 7,2.

B. 11,3 v 7,8.

C. 13,3 v 3,9.

D. 8,2 v 7,8.

Cu 29 (C 2009): Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn
ng thu c m gam kt ta. Gi tr ca m l
A.19,7.

B. 39,4.

C. 17,1.

D. 15,5.

Cu 30 (C 2009): Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng thu
c 0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l
A.Fe3O4 v 0,224.

B. Fe3O4 v 0,448.

C. FeO v 0,224.

D. Fe2O3 v 0,448.

Cu 31 (C 2008): Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe 2O3 (

nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch
Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l: A.1,120.
B. 0,896. C. 0,448.
D. 0,224.
Cu 32 (Khi B 2011): Hp th hon ton 2,24 lt CO 2 (ktc) vo 100 ml dung dch gm K 2CO3 0,2M v KOH x
mol/lt, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl 2 (d),
thu c 11,82 gam kt ta. Gi tr ca x l
A.1,6.

B. 1,2.

C. 1,0.

D. 1,4.

Cu 33 (Khi B 2011): Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO 2 v
H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ho tan ton b Y bng dung
dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l
A.57,15%.

B. 14,28%.

C. 28,57%.

D. 18,42%.

Cu 34 (Khi B 2011): Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10 lt. Nung nng bnh
mt thi gian 830oC h t n trng thi cn bng: CO (k) + H2O (k) CO2 (k) + H2 (k) (hng s cn bng KC =
1). Nng cn bng ca CO, H2O ln lt l
A. 0,08M v 0,18M.

B. 0,018M v 0,008M.

C. 0,012M v 0,024M.
2+

B. 9,26.

D. 0,008M v 0,018M.

Cu 35 (Khi B 2010): Dung dch X cha cc ion: Ca , Na , HCO3 v Cl , trong s mol ca ion Cl l 0,1. Cho
1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi
dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht
rn khan. Gi tr ca m l
A.9,21.

C. 8,79.

D. 7,47.

Cu 36 (Khi B 2009): Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi
phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y,
cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l
A. 45,6.

B. 48,3.

C. 36,7.

D. 57,0.

Cu 37 (Khi B 2008): Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh CO 2
( ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l
A. 40%.

B. 50%.

C. 84%.

D. 92%

Cu 38 (Khi B 2007): Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v
kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng
l
A. 5,8 gam.

B. 6,5 gam.

C. 4,2 gam.

~ 35 ~

D. 6,3 gam.

Cu 39 (Khi A 2012): Cho cc phn ng sau :

(a) H2S + SO2

lmol 1:2
(b) Na2S2O3 + dung dch H2SO4 (long) (c) SiO2 + Mg t

(d)Al2O3+ dd NaOH

(e) Ag + O3

(g) SiO2 + dung dch HF

S phn ng to ra n cht l
A. 4.

B. 5.

C. 6.

D. 3.

Cu 40 (Khi A 2012):Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch Ba(HCO 3)2 thu
c kt ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n khi khng cn kh thot ra th
ht 560 ml. Bit ton b Y phn ng va vi 200 ml dung dch NaOH 1M. Khi lng kt ta X l
A. 3,94 gam.

B. 7,88 gam.

C. 11,28 gam.

D. 9,85 gam.

Cu 41 (Khi A 2012): Cho cc pht biu sau

(a) Kh CO2 gy ra hin tng hiu ng nh knh
(b) Kh SO2 gy ra hin tng ma axit.
(c) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon
(d) Moocphin v cocain l cc cht ma ty
S pht biu ng l
A. 2.

B. 4.

C. 3.

D. 1.

Cu 42 (Khi B 2012):Cho cc th nghim sau:

(a) t kh H2S trong O2 d;(b) Nhit phn KClO3 (xc tc MnO2); (c) Dn kh F2 vo
nc nng; (d) t P trong O2 d;(e) Kh NH3 chy trong O2;(g) Dn kh CO2 vo dung
dch Na2SiO3.S th nghim to ra cht kh l
A. 5.

B. 4.

C. 2.

D. 3.

Cu 43 (Khi B 2012): Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi
gian thu
c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH)2 d, thu c 29,55 gam
kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca V l
A. 2,24.

B. 4,48.

C. 6,72.

D. 3,36.

Cu 44 (C 2012): Hp th hon ton 0,336 lt kh CO2 (ktc) vo 200 ml dung dch gm NaOH 0,1M v
KOH 0,1M thu c dung dch X. C cn ton b dung dch X thu c bao nhiu gam cht rn khan?
A. 2,44 gam

B. 2,22 gam

C. 2,31 gam

D. 2,58 gam.

Cu 45 (C 2012): Dung dch E gm x mol Ca2+, y mol Ba2+, z mol HCO 3 . Cho t t dung dch
Ca(OH)2 nng a mol/l vo dung dch E n khi thu c lng kt ta ln nht th va ht V lt dung
dch Ca(OH)2. Biu thc lin h gia cc gi tr V, a, x, y l

A. V =

x+ y
a

B. V =

x + 2y
a

C. V = 2a( x + y )

~ 36 ~

D. V = a(2 x + y )

I CNG V KIM LOI

Tc vt l, ha hc, dy th in cc chun
Cu 1. (Cu 7 i Hc KA 2007) Dy cc ion xp theo chiu gim dn tnh oxi ha l (bit trong dy
in ha, cp Fe3+/Fe2+ ng trc cp Ag+/Ag):
A. Ag+, Fe3+, Cu2+, Fe2+. B. Ag+, Cu2+, Fe3+, Fe2+.
C. Fe3+, Ag+, Cu2+, Fe2+. D. Fe3+, Cu2+, Ag+, Fe2+.
Cu 2. (Cu 26 i Hc KB 2007) Cho cc phn ng xy ra sau y:
(1)

AgNO3 + Fe(NO3)2
Fe(NO3)3 + Ag

(2)

Mn + 2HCl
MnCl2 + H2

Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l

A. Ag + , Mn2+, H+, Fe 3 + .B. Mn2+, H+, Ag + , Fe 3+ .
C. Ag + , Fe 3+ , H+, Mn2+. D. Mn2+, H+, Fe 3+ , Ag + .
Cu 3. (Cu 51 Cao ng 2007) Cho cc ion kim loi: Zn2+, Sn2+, Ni2+, Fe2+, Pb2+. Th t tnh oxi ha
gim dn l
A. Pb2+ > Sn2+ > Fe2+ > Ni2+ > Zn2+.

B. Sn2+ > Ni2+ > Zn2+ > Pb2+ > Fe2+ .

C. Zn2+ > Sn2+ > Ni2+ > Fe2+ > Pb2+.

D. Pb2+ > Sn2+ > Ni2+ > Fe2+ > Zn2+.

Cu 4. (Cu 35 Cao ng 2008) Cho p ha hc: Fe + CuSO4

FeSO4 + Cu.
Trong phn ng trn xy ra
A. s kh Fe 2 + v s oxi ha Cu.

B. s kh Fe 2+ v s kh Cu2+.

C. s oxi ha Fe v s oxi ha Cu.

D. s oxi ha Fe v s kh Cu2+.

Cu 5. (Cu 52 Cao ng 2008) Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc
phn ng ha hc sau:
X + 2YCl3 XCl2 + 2YCl2;
Y + XCl2 YCl2 + X.
Pht biu ng l:
A. Ion Y2+ c tnh oxi ha mnh hn ion X2+.
B. Kim loi X kh c ion Y2+.
C. Kim loi X c tnh kh mnh hn kim loi Y.
D. Ion Y3+ c tnh oxi ha mnh hn ion X2+.
Cu 6. (Cao ng2007) Th t mt s cp oxi ha kh trong dy in ha nh sau:
Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+. Cp cht khng phn ng vi nhau l
A. Fe v dung dch CuCl2.

B. Fe v dung dch FeCl3.

C. dung dch FeCl2 v dung dch CuCl2.

D. Cu v dung dch FeCl3.

Cu 7. (Cu 47 Cao ng 2008) Cp cht khng xy ra phn ng ho hc l

A. Cu + dung dch FeCl3.

B. Fe + dung dch HCl.

C. Fe + dung dch FeCl3.

D. Cu + dung dch FeCl2.

3+

Cu 8. (Cu 4 Cao ng 2007) kh ion Fe trong dung dch thnh ion Fe2+ c th dng mt lng d
A. kim loi Mg.

B. kim loi Cu.

C. kim loi Ba.

~ 37 ~

D. kim loi Ag.

Cu 9. (Cu 49 i Hc KA 2007) Mnh khng ng l

A. Fe kh c Cu2+ trong dung dch.
B. Fe3+ c tnh oxi ha mnh hn Cu2+.
C. Fe2+ oxi ha c Cu.
D. tnh oxi ha ca cc ion tng theo th t Fe2+, H+, Cu2+, Ag+.
Cu 10. (Cu 23 Cao ng 2007) kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi
A. Fe.

B. Na.

C. K.

D. Ba.

Cu 11. (Cu 36 i Hc KA 2008) X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim
loi tc dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ha:
Fe3+/Fe2+ ng trc Ag+/Ag)
A. Fe, Cu.

B. Cu, Fe.

C. Ag, Mg.

D. Mg, Ag.

Cu 12. (Cu 58 Cao ng 2009) Th t mt s cp oxi ha kh trong dy in ha nh sau: Mg2+/Mg;

Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l:
B. Mg,Cu, Cu2+.

A. Mg, Fe, Cu.

C. Fe, Cu, Ag+

D. Mg, Fe2+, Ag.

Cu 13. (Cu 9 Cao ng 2009) Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl,
va tc dng c vi dung dch AgNO3?
A. Zn, Cu, Mg

B. Al, Fe, CuO

C. Fe, Ni, Sn

D. Hg, Na, Ca

Cu 14. (Cu 29 Cao ng 2008) Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO3)2,
dung dch HNO3 (c, ngui). Kim loi M l
A. Al.

B. Ag.

C. Fe.

D. Zn.

Cu 15. (Cu 8 Cao ng 2010) Cho bit th t t trai sang phai cua cac cp oxi hoa kh trong day in
hoa nh sau: Zn2+/Zn ; Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+; Ag+/Ag. Cac kim loai va ion u p c vi ion Fe2+
trong dung dich la
A. Zn, Cu2+

B. Ag, Fe3+

C. Ag, Cu2+

D. Zn, Ag+

Cu 16. (Cu 50 Cao ng 2010) Kim loi M c th c iu ch bng cch kh ion ca n trong oxit
bi kh H2 nhit cao. Mt khc, kim loi M kh c ion H+ trong dung dch axit long thnh H2. Kim
loi M l
A. Al

B. Mg

C. Fe

D. Cu

Cu 17. (Cu 44 i Hc KA 2010) Cc cht va tc dng c vi dung dch HCl va tc dng c

vi dung dch AgNO3 l:
A. CuO, Al, Mg.

B. Zn, Cu, Fe.

C. MgO, Na, Ba.

D. Zn, Ni, Sn.

Cu 18. (Cu 36 Cao ng 2011) Dy gm cc kim loi u tc dng c vi dung dch HCl nhng
khng tc dng vi dung dch HNO3 c, ngui l:
A. Fe, Al, Cr

B. Cu, Fe, Al

C. Fe, Mg, Al

D. Cu, Pb, Ag

Cu 19. (Cu 44 Cao ng 2011) Dy gm cc ion u oxi ha c kloi Fe l

A. Cr2+, Au3+, Fe3+.

B. Fe3+, Cu2+, Ag+.

C. Zn2+, Cu2+, Ag+.

D. Cr2+, Cu2+, Ag+.

Cu 20. (Cu 57 i Hc KA 2011) Cho cc phn ng sau:

Fe + 2Fe(NO3)3
3Fe(NO3)2
AgNO3 + Fe(NO3)2
Fe(NO3)3 + Ag
Cu 21. Dy sp xp theo th t tng dn tnh oxi ha cc ion kim loi l:
A. Ag+, Fe2+, Fe3+

B. Fe2+, Fe3+, Ag+

C. Fe2+, Ag+, Fe3+

D. Ag+, Fe3+, Fe2+

Cu 22. (DHA2012): Cho cc cp oxi ha kh c sp xp theo chiu tng dn tnh oxi ha ca dng oxi
ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l ng?
A. Cu2+ oxi ha c Fe2+ thnh Fe3+.

B. Fe3+ oxi ha c Cu thnh Cu2+.

C. Cu kh c Fe3+ thnh Fe.

D. Fe2+ oxi ha c Cu thnh Cu2+.

~ 38 ~

Cu 23. (DHA2012): Cho hn hp gm Fe v Mg vo dung dch AgNO 3, khi cc phn ng xy ra hon ton
thu c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui trong X l:
A. Mg(NO3)2 v Fe(NO3)2

B. Fe(NO3)2 v AgNO3

C. Fe(NO3)3 v Mg(NO3)2

D. AgNO3 v Mg(NO3)2

Cu 24. (DHB2012): Pht biu no sau y l sai?

A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng.
B. Cc nhm A bao gm cc nguyn t s v nguyn t p.
C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim
D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c.
Cu 25. (CD2012): Dung dch long (d) no sau y tc dng c vi kim loi st to thnh mui st(III)?
A. HNO3.

B. H2SO4.

C. FeCl3.

D. HCl.

Cu 26. (CD2012): Cho dy cc ion : Fe2+, Ni2+, Cu2+, Sn2+. Trong cng iu kin, ion c tnh oxi ha mnh
nht trong dy l
A. Fe2+

B. Sn2+

C. Cu2+

D. Ni2+

Cu 27. (CD2012): Dung dch long (d) no sau y tc dng c vi kim loi st to thnh mui st(III)?
A. HNO3.

B. H2SO4.

C. FeCl3.

D. HCl.

Cu 28. (CD2012): Cho dy cc ion : Fe2+, Ni2+, Cu2+, Sn2+. Trong cng iu kin, ion c tnh oxi ha mnh
nht trong dy l
A. Fe2+

B. Sn2+

C. Cu2+

D. Ni2+

Cu 29. (DHA2013): Cho bt Fe vo dung dch gm AgNO3 v Cu(NO3)2. Sau khi cc phn ng xy ra hon
ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X v hai kim loi
trong Y ln lt l:
A. Cu(NO3)2; Fe(NO3)2 v Cu; Fe

B. Cu(NO3)2; Fe(NO3)2 v Ag; Cu

C. Fe(NO3)2; Fe(NO3)3 v Cu; Ag

D. Cu(NO3)2; AgNO3 v Cu; Ag.

Cu 30. (DHA2013): Kim loi st tc dng vi dung dch no sau y to ra mui st(II)?
A. CuSO4.

B. HNO3 c, nng, d.

C. MgSO4.

D. H2SO4 c, nng, d.

Cu 31. (DHA2013): Cho cc cp oxi ha kh c sp xp theo th t tng dn tnh oxi ha ca cc ion

kim loi: Al3+/Al; Fe2+/Fe, Sn2+/Sn; Cu2+/Cu. Tin hnh cc th nghim sau:
(a) Cho st vo dung dch ng(II) sunfat.
(b) Cho ng vo dung dch nhm sunfat.
(c) Cho thic vo dung dch ng(II) sunfat.
(d) Cho thic vo dung dch st(II) sunfat.
Trong cc th nghim trn, nhng th nghim c xy ra phn ng l:
A. (b) v (c)

B. (a) v (c)

C. (a) v (b)

D. (b) v (d)

cAl(NO3)3 + dNO + eH2O.T l a : b l

Cu 32. (DHA2013): Cho phng trnh phn ng aAl +bHNO3
A. 1 : 3

B. 2 : 3

C. 2 : 5

D. 1 : 4.

Cu 33. (DHB2013): Cho phn ng: FeO + HNO3 Fe(NO3)3 + NO + H2O.

Trong phng trnh ca phn ng trn, khi h s ca FeO l 3 th h s ca HNO3 l
A. 6.

B. 10.

C. 8.

D. 4.

Cu 34. (DHB2013) : Cho phng trnh ha hc ca phn ng : 2Cr + 3Sn2+

2Cr3+ + 3Sn
Nhn xt no sau y v phn ng trn l ng?
A. Cr3+ l cht kh, Sn2+ l cht oxi ha

~ 39 ~

B. Sn2+ l cht kh, Cr3+ l cht oxi ha

C. Cr l cht oxi ha, Sn2+ l cht kh
D. Cr l cht kh, Sn2+ l cht oxi ha
n mn in ha, pin in
Cu 35. (Cu 7 Cao ng 2007) Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb;
Fe v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim lai trong Fe
b ph hy trc l
A. 4.

B. 1.

C. 2.

D. 3.

Cu 36. (Cu 4 i Hc KA 2009) Cho cc hp kim sau: CuFe (I); ZnFe (II); FeC (III); SnFe (IV).
Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l:
A. I, II v III.

B. I, II v IV.

C. I, III v IV.

D. II, III v IV.

2+

Cu 37. (Cu 50 i Hc KA 2008) Bit rng ion Pb trong dung dch oxi ha c Sn. Khi nhng hai
thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th
A. c Pb v Sn u b n mn in ha
B. c Pb v Sn u khng b n mn in ha
C. ch c Pb b n mn in ha
D. ch c Sn b n mn in ha
Cu 38. (Cu 31 i Hc KB 2007) C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c
ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l
A. 0.

B. 1.

C. 2.

D. 3.

Cu 39. (Cu 50 i Hc KB 2008) Tin hnh bn th nghim sau:

- Th nghim 1: Nhng thanh Fe vo dung dch FeCl3;
- Th nghim 2: Nhng thanh Fe vo dung dch CuSO4;
- Th nghim 3: Nhng thanh Cu vo dung dch FeCl3;
- Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n
mn in ho l
A. 1.

B. 2

C. 4

D. 3

Cu 40. (Cu 51 i Hc KB 2007) Trong pin in ha ZnCu, qu trnh kh trong pin l

A. Cu

Cu2+ + 2e.

C. Zn2 + 2e

Zn.

B. Zn

Zn2+ + 2e.

D. Cu2+ + 2e

Cu.

Cu 41. (Cu 52 i Hc KA 2008) Mt pin in ha c in cc Zn nhng trong dung dch ZnSO4 v

in cc Cu nhng trong dung dch CuSO4. Sau mt thi gian pin phng in th khi lng
A. c hai in cc Zn v Cu u tng
B. in cc Zn gim cn khi lng in cc Cu tng.
C. in cc Zn tng cn khi lng in cc Cu gim.
D. c hai in cc Zn v Cu u gim
Cu 42. (Cu 30 i Hc KB 2010) Co 4 dd ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhung vao mi dd
mt thanh Ni. S trng hp xut hin n mon in hoa la
A. 1

B. 4

C. 3

D. 2

Cu 43. (CDA2013) : Pht biu no di y khng ng?

A. Nguyn tc chung iu ch kim loi l kh ion kim loi thnh nguyn t kim loi.
B. Bn cht ca n mn kim loi l qu trnh oxi ha - kh.

~ 40 ~

C. Tnh cht ha hc c trng ca kim loi l tnh kh.

D. n mn ha hc pht sinh dng in.
Cu 44. (CD2012): Tin hnh cc th nghim sau:
(a) Cho l Fe vo dung dch gm CuSO4 v H2SO4 long;
(b) t dy Fe trong bnh ng kh O2;
(c) Cho l Cu vo dung dch gm Fe(NO3) v HNO3;
(d) Cho l Zn vo dung dch HCl;
S th nghim c xy ra n mn in ha l
A. 3

B. 2

C. 1

D. 4

in phn, iu ch, tinh ch

Cu 41. (Cu 8 Cao ng2009) Nguyn tc chung c dng iu ch kim loi l
A. cho hp cht cha ion kim loi tc dng vi cht kh.
B. kh ion kim loi trong hp cht thnh nguyn t kim loi.
C. oxi ho ion kim loi trong hp cht thnh nguyn t kim loi
D. cho hp cht cha ion kim loi tc dng vi cht oxi ho.
Cu 42. (Cu 46 i Hc KA 2007) Dy gm cc kim loi c iu ch trong cng nghip bng phng
php in phn hp cht nng chy ca chng l
A. Na, Cu, Al.

B. Fe, Ca, Al.

C. Na, Ca, Zn.

D. Na, Ca, Al.

Cu 43. (Cu 48 Cao ng 2008) Hai kim loi c th c iu ch bng phng php in phn dung
dch l
A. Na v Fe.

B. Mg v Zn.

C. Cu v Ag.

D. Al v Mg.

Cu 44. (Cu 39 i Hc KA 2009) Dy cc kim loi u c th c iu ch bng phng php in

phn dung dch mui ca chng l:
A. Ba, Ag, Au.

B. Fe, Cu, Ag.

C. Al, Fe, Cr.

D. Mg, Zn, Cu.

Cu 45. (Cu 5 i Hc KA 2008) Khi in phn NaCl nng chy (in cc tr), ti catt xy ra
A. s kh ion Cl-.

B. s oxi ha ion Cl-.

C. s oxi ha ion Na+.

D. s kh ion Na+.

Cu 46. (Cu 32 i Hc KB 2009) in phn nng chy Al2O3 vi anot than ch (hiu sut in phn
100%) thu c m kg Al catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24
lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l
A. 54,0

B. 75,6

C. 67,5

D. 108,0

Cu 47. (Cu 32 i Hc KB 2007) in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc
tr, c mng ngn). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a
v b l
A. b > 2a.

B. b = 2a.

C. b < 2a.

D. 2b = a.

Cu 48. (Cu 27 i Hc KA 2007) in phn dung dch CuCl2 vi in cc tr sau mt thi gian thu
c 0,32 gam Cu catot v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung
dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch
khng thay i). Nng ban u ca dung dch NaOH l
A. 0,15M.

B. 0,1M.

C. 0,05M.

D. 0,2M.

Cu 49. (Cu 29 i Hc KB 2009) in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2
0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy.
Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05

B. 2,70

C. 1,35

D. 5,40

Cu 50. (Cu 56 Cao ng 2010) in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn
dung dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l

~ 41 ~

A. catot xy ra s oxi ha: 2H2O +2e 2OH +H2

B. anot xy ra s kh: 2H2O O2 + 4H+ +4e
C. anot xy ra s oxi ha: Cu Cu2+ +2e
D. catot xy ra s kh: Cu2+ + 2e Cu
Cu 51. (Cu 36 i Hc KA 2010) Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng
n mn in ha xy ra khi nhng hp kim Zn Cu vo dung dch HCl c c im l:
A. Phn ng xy ra lun km theo s pht sinh dng in.
B. u sinh ra Cu cc m.
C. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi.
D. Phn ng cc dng u l s oxi ha Cl-.
Cu 52. (Cu 50 i Hc KA 2010) in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c
cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm
thu c anot l
A. kh Cl2 v O2.

B. kh H2 v O2.

C. ch c kh Cl2.

D. kh Cl2 v H2.

Cu 53. (Cu 52 i Hc KA 2010) in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12
mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l
A. 2,240 lt.

B. 2,912 lt.

C. 1,792 lt.

D. 1,344 lt.

Cu 54. (Cu37 Cao ng 2011) in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi
catot thu c 3,2 gam kim loi th th tch kh (ktc) thu c anot l:
A. 3,36 lt

B. 1,12 lt

C. 0,56 lt

D. 2,24 lt

Cu 55. (Cu 3 i Hc KA 2011) Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in
phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy
nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c
hai in cc l 0,1245 mol. Gi tr ca y l
A. 4,480.

B. 3,920.

C. 1,680.

D. 4,788.

Cu 56. (Cu 14 i Hc KA 2011) in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2
(in cc tr, mng ngn xp) n kh khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit
lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l
A. KNO3 v KOH.

B. KNO3, KCl v KOH.

C. KNO3 v Cu(NO3)2. D. KNO3, HNO3 v Cu(NO3)2.

Cu 57. (Cu 43 i Hc KA 2011) Khi in phn dung dch NaCl (cc m bng st, cc dng bng
than ch, c mng ngn xp) th:
A. cc dng xy ra qtrinh oxi ha ion Na+ v cc m xy ra qu trnh kh ion Cl-.
B. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ha Cl-.
C. cc m xy ra qu trnh oxi ha H2O v cc dng x ra qu trnh kh ion Cl-.
D. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qtrnh oxi ha ion Cl-.
Cu 58 (DHA2012): Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui
(vi in cc tr) l:
A. Ni, Cu, Ag.

B. Li, Ag, Sn.

C. Ca, Zn, Cu.

D. Al, Fe, Cr.

Cu 59 (CD2012): Kim loi no sau y iu ch c bng phng php thy luyn?

A. Ca.

B. K.

C. Mg.

D. Cu.

Cu 60 (CDA2013) : Sn phm thu c khi in phn dung dch KCl (in cc tr, mng ngn xp) l
A. KOH, O2 v HCl

B. KOH, H2 v Cl 2

C. K v Cl 2

D. K, H2 v Cl 2

Cu 61 (CDA2013): in phn dung dch gm NaCl v HCl ( in cc tr, mng ngn xp). Trong qu trnh
in phn , so vi dung dch ban u , gi tr pH ca dung dch thu c

~ 42 ~

A. khng thay i

B. tng ln

C. gim xung

D. tng ln sau gim xung

Cu 62 (DHA2013): Tin hnh in phn dung dch cha m gam hn hp CuSO 4 v NaCl (hiu sut 100%,
in cc tr, mng ngn xp), n khi nc bt u b in phn c hai in cc th ngng in phn, thu
c dung dch X v 6,72 lt kh (ktc) anot. Dung dch X ha tan ti a 20,4 gam Al2O3. Gi tr ca m l
A. 25,6.

B. 23,5

C. 51,1.

D. 50,4.

Kl tc dng axit HCl, H2SO4 long

Cu 63. (Cu 27 Cao ng 2007) Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt
lng va dung dch H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch cha m gam mui. Gi tr
ca m l
A. 9,52.

B. 10,27.

C. 8,98.

D. 7,25.

Cu 64. (Cu 19 i Hc KA 2009) Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va

dung dch H2SO4 10% thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A. 101,48 gam.

B. 101,68 gam.

C. 97,80 gam.

D. 88,20 gam.

Cu 65. (Cu 44 Cao ng 2008) Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung
dch hn hp HCl 1M v H 2 SO 4 0,28M thu c dung dch X v 8,736 lt kh H2 (ktc). C cn dung dch
X thu c lng mui khan l
A. 38,93 gam.

B. 77,86 gam.

C. 103,85 gam.

D. 25,95 gam.

Cu 66. (Cu 54 Cao ng 2008) Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d
dung dch H2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 (
ktc).C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l
A. 48,8.

B. 42,6.

C. 47,1.

D. 45,5.

Cu 67. (Cu 40 i Hc KA 2007) Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp
axit HCl 1M v dung dch H2SO4 0,5M, thu c 5,32 lt H2 (ktc) v dung dch Y (coi th tch dung dch
khng i). Dung dch Y c pH l
A. 7.

B. 1.

C. 2.

D. 6.

Cu 68. (Cu 17 i Hc KB 2007) Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc
nhm IIA tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l
A. Be v Mg.

B. Mg v Ca.

C. Sr v Ba.

D. Ca v Sr.

Cu 69. (Cu 26 i Hc KB 2008) Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi
kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric
(c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m
l
A. 11,5.

B. 10,5

C. 12,3

D. 15,6

Cu 70. (Cu 34 Cao ng 2008) X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho
1,7 gam hn hp gm kim loi X v Zn tc dng vi lng d dung dch HCl, sinh ra 0,672 lt kh H2 (
ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung dch H 2 SO 4 long, th th tch kh hiro
sinh ra cha n 1,12 lt ( ktc). Kim loi X l
A. Sr.

B. Mg.

C. Ba.

D. Ca.

Cu 71. (Cu 42 Cao ng 2007) Ha tan hon ton hn hp X gm Fe v Mg bng mt lng va

dung dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn
trm ca MgCl2 trong dung dch Y l
A. 24,24%

B. 11,79%

C. 28,21%

D. 15,76%

Cu 72. (Cu 32 i Hc KA 2010) Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi
kim th Y tc dng ht vi lng d dung dch HCl long, thu c ,56 lt kh (ktc). Kim loi X, Y l
A. natri v magie.

B. liti v beri.

C. kali v canxi.

~ 43 ~

D. kali v bari.

Cu 73. (DHA2012): Ha tan hon ton 2,43 gam hn hp gm Mg v Zn vo mt lng va dung dch
H2SO4 long, sau phn ng thu c 1,12 lt H2 (ktc) v dung dch X. Khi lng mui trong dung dch X l
A. 5,83 gam.

B. 7,33 gam.

C. 4,83 gam.

D. 7,23 gam.

Cu 74. (CD2012): Ha tan hon ton 1,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th
Y (Mx < My) trong dung dch HCl d, thu c 1,12 lt kh H2 (ktc). Kim loi X l
A. K.

B. Na.

C. Rb.

D. Li.

Cu 75. (CD2012): Ha tan hon ton 2,7 gam hn hp X gm Fe, Cr, Al bng dung dch HCl d, thu c
1,568 lt kh H2 (ktc). Mt khc, cho 2,7 gam X phn ng hon ton vi kh Cl 2 d, thu c 9,09 gam mui.
Khi lng Al trong 2,7 gam X l bao nhiu?
A. 0,54 gam

B. 0,81 gam

C. 0,27gam

D. 1,08 gam

Cu 76. (CD2012): Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 : 1). Cho X

tc dng vi H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc dng vi dung dch H 2SO4 long
(d) thu c 0,25V lt kh. Bit cc kh o cng iu kin, cc phn ng u xy ra hon ton. T l s mol
ca Fe v Al trong X tng ng l
A. 1 : 2.

B. 5 : 8.

C. 5 : 16.

D. 16 : 5.

Cu 77. (CDA2013) : Ha tan hon ton 20,6 gam hn hp gm Na2CO3 v CaCO3 bng dung dch HCl d,
thu c V lt kh CO2 (ktc) v dung dch cha 22,8 gam hn hp mui. Gi tr ca V l
A. 1,79

B. 4,48

C. 2,24

D. 5,60

Kl tc dng HNO3, H2SO4 c

Cu 78. (Cu 38 i Hc KB 2007) Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi
phn ng hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l
A. Fe(NO3)3.

B. Fe(NO3)2.

C. HNO3.

D. Cu(NO3)2.

Cu 79. (Cu 48 Cao ng 2007) Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n
khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung
dch Y l
A. MgSO4 v FeSO4.

B. MgSO4.

C. MgSO4 v Fe2(SO4)3. D. MgSO4 , Fe2(SO4)3. v FeSO4.

Cu 80. (Cu 46 i Hc KB 2008) Th tch dung dch HNO3 1M (long) t nht cn dng ho tan
hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 1,0 lt.

B. 0,6 lit

C. 0,8 lit

D. 1,2 lit

Cu 81. (Cu 43 Cao ng 2008) Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24
lt kh X (sn phm kh duy nht, ktc). Kh X l
A. N2O.

B. NO2.

C. N2.

D. NO.

Cu 82. (Cu 19 i Hc KA 2007) Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit
HNO3, thu c V lt ( ktc) hn hp kh X (gm NO v NO2) v dunh dch Y (ch cha hai mui v axit
d). T khi ca X i vi H2 bng 19. Gi tr V l
A. 3,36.

B. 2,24.

C. 4,48.

D. 5,60.

Cu 83. (Cu 25 Cao ng 2009) Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch
HNO3 long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt
kh ho nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng,
khng c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l
A. 12,80%

B. 15,25%

C. 10,52%

D. 19,53%

Cu 84. (Cu 10 i Hc KB 2007) Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2 SO 4 c, nng
(gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c
A. 0,12 mol FeSO4.

B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4.

C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.

D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.

~ 44 ~

Cu 85. (Cu 23 i Hc KA 2009) Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long,
thu c 940,8 ml kh NxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim
loi M l
A. NO v Mg.

B. N2O v Al

C. N2O v Fe.

D. NO2 v Al.

Cu 86. (Cu 20 i Hc KB 2010) Ha tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng
dung dch H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v
dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l
A. 39,34%.

B. 65,57%.

C. 26,23%.

D. 13,11%.

Cu 87. (Cu 26 i Hc KA 2010) Cho x mol Fe tan hoan toan trong dung dich cha y mol H2SO4 (ti l
x : y = 2 : 5), thu c mt san phm kh duy nht va dung dich chi cha mi sunfat. S mol electron do
lng Fe trn nhng khi bi hoa tan la
A. 3x

B. y

C. 2x

D. 2y

Cu 88. (Cu 7 i Hc KB 2010) Kh hon ton m gam oxit MxOy cn va 17,92 lt kh CO (ktc),
thu c a gam kim loi M. Ha tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh
SO2 (sn phm kh duy nht, ktc). Oxit MxOy l
A. Cr2O3.

B. FeO.

C. Fe3O4.

D. CrO.

Cu 89. (Cu 2 i Hc KB 2010) Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi,
sau mt thi gian thu c 2,71 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO3 (d), thu c
0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l
A. 0,12

.B. 0,14.

C. 0,16.

D. 0,18.

Cu 90. (Cu 11 i Hc KA 2011) un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 :

3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v
5,6 lt hn hp kh (ktc) gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn
ng l 44,1 gam. Gi tr ca m l
A. 44,8.

B. 40,5.

C. 33,6.

D. 50,4.

Cu 91. (DHB2012): Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung dch HNO 3
1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc) gm NO v N 2O. T khi ca X
so vi H2 l 16,4. Gi tr ca m l
A. 98,20

B. 97,20

C. 98,75

D. 91,00

Cu 92. (CD2012): Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500 ml dung dch
HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N 2O (ktc) duy nht v dung dch X cha m
gam mui. Gi tr ca m l
A. 34,10

B. 31,32

C. 34,32

D. 33,70

Cu 93. (DHA2013): Ha tan hon ton m gam Al bng dung dch HNO3 long, thu c 5,376 lt (ktc) hn
hp kh X gm N2, N2O v dd cha 8m gam mui. T khi ca X so vi H2 bng 18. Gi tr ca m l
A. 17,28

B. 19,44

C. 18,90

D. 21,60 .

Cu 94. (CDA2013) : Cho m gam Al phn ng hon ton vi dung dch HNO3 long (d), thu c 4,48 lt
kh NO (ktc, sn phm kh duy nht) . Gi tr ca m l
A. 4,05

B. 8,10

C. 2,70

D. 5,40

Kl tc dng dung dch mui

Cu 95. (Cu 39 Cao ng 2008) Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3.
Sau khi cc phn ng xy ra hon ton, thu c hn hp rn gm ba kim loi l:
A. Al, Cu, Ag.

B. Fe, Cu, Ag.

C. Al, Fe, Ag.

D. Al, Fe, Cu.

Cu 96. (Cu 25 i Hc KA 2009) Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn

ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X
l

~ 45 ~

A. Fe(NO3)2 v AgNO3. B. AgNO3 v Zn(NO3)2.

C. Zn(NO3)2 v Fe(NO3)2.

D. Fe(NO3)3 v Zn(NO3)2.

Cu 97. (Cu 44 i Hc KA 2008) Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung
dch AgNO3 1M. Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th
t trong dy th in ha : Fe3+/Fe2+ ng trc Ag+/Ag)
A. 59,4

B. 64,8

C. 32,4

D. 54,0

Cu 98. (Cu 21 Cao ng 2009) Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3
0,3M. Sau khi cc phn ng xy ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi
lng d dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l
A. 8,10 v 5,43

B. 1,08 v 5,16

C. 0,54 v 5,16

D. 1,08 v 5,43

Cu 99. (Cu 34 i Hc KB 2008) Tin hnh hai th nghim sau:

- Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr
ca V1 so vi V2 l
A. V1 = V2.

B. V1 = 10V2.

C. V1 = 5V2.

D. V1 = 2V2.

Cu 100. (Cu 56 i Hc KB 2008) Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi
lng cht rn sau khi cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn
phn dung dch sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l
A. 13,1 gam.

B. 17,0 gam.

C. 19,5 gam.

D. 14,1 gam.

Cu 101. (Cu 45 i Hc KA 2009) Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2
mol Cu2+ v 1 mol Ag+ n khi cc phn ng xy ra hon ton, thu c mt dung dch cha 3 ion kim loi.
Trong cc gi tr sau y, gi tr no ca x tha mn trng hp trn?
A. 1,5

B. 1,8

C. 2,0

D. 1,2

Cu 102. (Cu 47 i Hc KB 2007) Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4.

Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo
khi lng ca Zn trong hn hp bt ban u l
A. 90,27%.

B. 85,30%.

C. 82,20%.

D. 12,67%.

Cu 103. (Cu 42 i Hc KB 2009) Nhng mt thanh st nng 100 gram vo 100 ml dung dch hn hp
gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c
101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 2,16 gam

B. 0,84 gam

C. 1,72 gam

D. 1,40 gam

Cu 104. (Cu 42 Cao ng 2009) Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi
lng 50 gam vo 200 ml dung dch AgNO3 1M cho n khi phn ng xy ra hon ton,. Lc dung dch, em
c cn thu c 18,8 gam mui khan. Kim loi M l
A. Mg

B. Zn

C. Cu

D. Fe

Cu 105. (Cu 32 Cao ng 2010) Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch
CuSO4 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi.
Phn trm v khi lng ca Fe trong hn hp ban u l
A. 56,37%

B. 37,58%

C. 64,42%

D. 43,62%

Cu 106. (Cu 2 i Hc KA 2010) Cho 19,3 gam hn hp bt Zn va Cu co ti l mol tng ng la 1 : 2

vao dung dich cha 0,2 mol Fe2(SO4)3. Sau khi cac phan ng xay ra hoan toan, thu c m gam kim loai. Gia
tri cua m la
A. 6,40

B. 16,53

C. 12,00

D. 12,80

Cu 107. (Cu 21 i Hc KB 2010) in phn (vi in cc tr) 200 ml dung dich CuSO4 nng x
mol/l, sau mt thi gian thu c dung dich Y vn con mau xanh, co khi lng giam 8g so vi dung dich ban
u. Cho 16,8g bt Fe vao Y, sau khi cac phan ng xay ra hoan toan, thu c 12,4g kim loai. Gia tri cua x la
A. 2,25

B. 1,5

C. 1,25

~ 46 ~

D. 3,25

Cu 108 (DHA2012): Cho 2,8 gam bt st vo 200 ml dung dch gm AgNO3 0,1M v Cu(NO3)2 0,5M; khi
cc phn ng xy ra hon ton thu c m gam cht rn X. Gi tr ca m l
A. 4,72.

B. 4,08.

C. 4,48.

D. 3,20

Cu 109 (DHB2012): Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO 3 0,12M. Sau khi cc
phn ng xy ra hon ton, thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn hp ban
u l
A. 0,168 gam

B. 0,123 gam

C. 0,177 gam

D. 0,150 gam

Cu 110 (CD2012): Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn
thu c dung dch X v 1,68 lt kh Cl 2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi
12,6 gam Fe. Gi tr ca V l
A. 0,60.

B. 0,15.

C. 0,45.

D. 0,80.

Cu 111 (DHA2013): Cho 1,37 gam Ba vo 1 lt dung dch CuSO4 0,01 M. Sau khi cc phn ng xy ra hon
ton, khi lng kt ta thu c l
A. 3,31 gam

B. 2,33 gam

C. 1,71 gam

D. 0,98 gam.

Kl tc dng vi phi kim

Cu 112. (Cu 45 i Hc KA 2007) Ha tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong
500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c
khi lng l
A. 4,81 gam.

B. 5,81 gam.

C. 3,81 gam.

D. 6,81 gam.

Cu 113. (Cu 7 i Hc KA 2008) Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt
tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl
2M va phn ng ht vi Y l:
A. 57 ml.

B. 50 ml.

C. 75 ml.

D. 90 ml.

Cu 114. (Cu 60 Cao ng 2009) Nung nng 16,8 gam hn hp Au, Ag, Cu, Fe, Zn vi mt lng d
kh CO2, n khi cc phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M
va phn ng vi cht rn X l
A. 600 ml.

B. 200 ml.

C. 800 ml.

D. 400 ml.

Cu 115. (Cu 4 i Hc KA 2008) ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3
(trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l:
A. 0,23.

B. 0,18.

C. 0,08.

D. 0,16.

Cu 116. (Cu 12 i Hc KB 2008) Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung
dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2
v m gam FeCl3. Gi tr ca m l
A. 9,75.

B. 8,75

C. 7,8

D. 6,5

Cu 117. (Cu 29 i Hc KA 2008) Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht
vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X.
C cn dung dch X thu c m gam mui khan. Gi tr ca m l
A. 38,72.

B. 35,50.

C. 49,09.

D. 34,36

Cu 118. (Cu 31 Cao ng 2009) t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i
trong hp cht) trong hn hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh
phn ng l 5,6 lt ( ktc). Kim loi M l
A. Be

B. Cu

C. Ca

D. Mg

Cu 119. (Cu 38 Cao ng 2008) Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong
iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii
phng hnhp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2
( ktc). Gi tr ca V l
A. 4,48.

B. 3,08.

C. 3,36.

~ 47 ~

D. 2,80.

Cu 120. (Cu 7 Cao ng 2011) t chy hon ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu
c 30,2 gam hn hp oxit. Th tch kh oxi (ktc) tham gia phn ng l:
A. 17,92 lt

B. 4,48 lt

C. 11,20 lt

D. 8,96 lt

Cu 121. (DHB2012): t chy hn hp gm 1,92 gam Mg v 4,48 gam Fe vi hn hp kh X gm Clo v

Oxi, sau phn ng ch thu c hn hp Y gm cc oxit v mui clorua (khng cn kh d) ha tan Y bng
mt lng va 120 ml dung dch HCl 2M, thu c dung dch Z. Cho AgNO 3 d vo dung dch Z, thu
c 56,69 gam kt ta. Phn trm th tch ca Clo trong hn hp X l
A. 51,72%

B. 76,70%

C. 53,85%

D. 56,36%

Cu 122. (CDA2013): Cho 7,84 lt hn hp kh X (ktc) gm Cl 2 v O2 phn ng va vi 11,1 gam hn

hp Y gm Mg v Al, thu c 30,1 gam hn hp Z. Phn trm khi lng ca Al trong Y l
A. 75,68%

B. 24,32%

C. 51,35%

D. 48,65%

Cu 123. Cho 50 ml dung dch HNO3 1M vo 100 ml dung dch KOH nng x mol/l, sau phn ng thu
c dung dch ch cha mt cht tan duy nht. Gi tr ca x l
A. 0,5

B. 0,8

C. 1,0

D. 0,3

Phn ng nhit luyn

Cu 124. (Cu 41 i Hc KA 2007) Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO,
MgO nung nhit cao. Sau phn ng hn hp rn cn li l
A. Cu, Fe, Zn, Mg.

B. Cu, Fe, ZnO, MgO.

C. Cu, FeO, ZnO, MgO.

D. Cu, Fe, Zn, MgO.

Cu 125. (Cu 13 Cao ng 2007) Cho kh CO (d) i vo ng s nung nng ng hn hp X gm

Al2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn
khng tan Z. Gi s cc phn ng xy ra hon ton. Phn khng tan Z gm
A. MgO, Fe, Cu.

B. Mg, Fe, Cu.

C. MgO, Fe3O4, Cu.

D. Mg, Al, Fe, Cu.

Cu 126. (Cu 17 Cao ng 2008) Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn

hp rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton
b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l
A. 0,224.

B. 0,896.

C. 0,448.

D. 1,120.

Cu 127. (Cu 22 i Hc KA 2008) Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt

lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn
hp rn gim 0,32 gam. Gi tr ca V l
A. 0,448.

B. 0,112.

C. 0,224.

D. 0,560.

Cu 128. (Cu 12 i Hc KA 2009) Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3
nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u
l
A. 0,8 gam.

B. 8,3 gam.

C. 2,0 gam.

D. 4,0 gam.

Cu 129. (Cu 46 Cao ng 2007) Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8
gam mt oxit st n khi phn ng xy ra hon ton . Kh thu c sau phn ng c t khi so vi hiro bng
20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l
A. FeO; 75%.

B. Fe2O3; 75%

C. Fe2O3; 65%

D. Fe3O4; 75%.

Cu 130. (Cu 46 i Hc KB 2010) Hn hp X gm CuO va Fe2O3. Hoa tan hoan toan 44 gam X bng
dd HCl (d), sau phan ng thu c dd cha 85,25 gam mui. Mt khac, nu kh hoan toan 22 gam X bng
CO (d), cho hn hp khi thu c sau phan ng li t t qua dd Ba(OH)2 (d) thi thu c m gam kt tua.
Gia tri cua m la
A. 76,755

B. 73,875

C. 147,750

~ 48 ~

D. 78,875

KIM LOI KIM V HP CHT

Cu 1: Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch
HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l
A.4,48.

B. 3,36.

C. 2,24.

D. 1,12.

Cu 2: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u, thu c V lt kh (
ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a,
b l:
A.V = 22,4(a - b).

B. V = 11,2(a - b).

C. V = 11,2(a + b).

D. V = 22,4(a + b).

Cu 3: Ho tan hon ton 6,645 gam hn hp mui clorua ca hai kim loi kim thuc hai chu k k tip nhau vo nc
c dung dch X. Cho ton b dung dch X tc dng hon ton vi dung dch AgNO3 (d), thu c 18,655 gam kt ta.
Hai kim loi kim trn l
A.Rb v Cs.

B. Na v K.

C. Li v Na.

D. K v Rb.

Cu 4: Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O. Tng h s ca cc cht (l
nhng s nguyn, ti gin) trong phng trnh phn ng l
A. 23.

B. 27.

C. 47.

D. 31.

Cu 5: Dy gm cc kim loi c cu to mng tinh th lp phng tm khi l:

A.Be, Mg, Ca.

B. Li, Na, K.

C. Na, K, Mg.

D. Li, Na, Ca.

Cu 6: Nh t t dung dch NaOH n d vo dung dch X. Sau khi cc phn ng xy ra hon ton ch thu c dung dch
trong sut. Cht tan trong dung dch X l
A.AlCl3.

B. CuSO4.

C. Ca(HCO3)2.

D. Fe(NO3)3.

Cu 7: Thuc th dng phn bit 3 dung dch ring bit: NaCl, NaHSO4, HCl l
A.NH4Cl.

B. (NH4)2CO3.

C. BaCO3.

D. BaCl2.

Cu 8: Nhit phn hon ton 34,65 gam hn hp gm KNO3 v Cu(NO3)2, thu c hn hp kh X (t khi ca X so vi
kh hiro bng 18,8). Khi lng Cu(NO3)2 trong hn hp ban u l
A.8,60 gam.

B. 20,50 gam.

C. 11,28 gam.

D. 9,40 gam.

Cu 9: Trong cng nghip, natri hiroxit c sn xut bng phng php

A. in phn dung dch NaCl, khng c mng ngn in cc.
B. in phn dung dch NaNO3, khng c mng ngn in cc.
C. in phn dung dch NaCl, c mng ngn in cc.
D. in phn NaCl nng chy.
Cu 10: Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2 ( ktc). Th tch dung
dch axit H2SO4 2M cn dng trung ho dung dch X l
A. 150ml.

B. 75ml.

C. 60ml.

D. 30ml.

Cu 11: Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l

A. NaOH v NaClO.

B. Na2CO3 v NaClO.

C. NaClO3 v Na2CO3.

D. NaOH v Na2CO3.

Cu 12: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l:

A.Na, K, Ca.

B. Na, K, Ba.
2+

C. Li, Na, Mg.

D. Mg, Ca, Ba.

Cu 13: Dung dch X cha cc ion: Ca , Na , HCO3 v Cl , trong s mol ca ion Cl l 0,1. Cho 1/2 dung dch X phn
ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2
(d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m
l
A.9,21.

B. 9,26.

C. 8,79.

~ 49 ~

D. 7,47

Cu 14: Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml dung dch cha mt
cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l
A. Na.

B. Ca.

C. Ba.

D. K.

Cu 15: Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung dch HCl (d),
sinh ra 0,448 lt kh ( ktc). Kim loi M l
A. Na.

B. K.

C. Rb.

D. Li.

Cu 15: Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O
(d), un nng, dung dch thu c cha
A. NaCl, NaOH, BaCl2.

B. NaCl, NaOH.

C. NaCl, NaHCO3, NH4Cl, BaCl2.

D. NaCl.

Cu 17: Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v HCl
0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l
A. 7.

B. 2.

C. 1.

D. 6.

Cu 18: Pht biu no sau y l sai?

A. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht.
B. Tt c cc tinh th phn t u kh nng chy v kh bay hi.
C. Tinh th nc , tinh th iot u thuc loi tinh th phn t.
D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lk CHT
Cu 19: Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 : 1). Cho X tc dng vi
H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc dng vi dung dch H2SO4 long (d) thu c
0,25V lt kh. Bit cc kh o cng iu kin, cc phn ng u xy ra hon ton. T l s mol ca Fe v Al
trong X tng ng l
A. 1 : 2.

B. 5 : 8.

C. 5 : 16.

D. 16 : 5.

Cu 20: Ha tan hon ton 1,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y (Mx < My)
trong dung dch HCl d, thu c 1,12 lt kh H2 (ktc). Kim loi X l
A. K.

B. Na.

C. Rb.

D. Li.

Cu 21: Pht biu no sau y l ng?

A.Trong hp cht, tt c cc kim loi kim u c s oxi ha +1.
B.Trong nhm 1A, tnh kh ca cc kim loi gim dn t Li n Cs
C.Tt c cc hiroxit ca kim loi nhm IIA u d tan trong nc
D.Tt c cc kim loi nhm IIA u c mng tinh th lp phng tm khi
Cu 22: Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu c dung dch X
trong sut. Thm t t dung dch HCl 1M vo X, khi ht 100 ml th bt u xut hin kt ta; khi ht
300 ml hoc 700 ml th u thu c a gam kt ta. Gi tr ca a v m ln lt l
A. 15,6 v 27,7.

B. 23,4 v 35,9.

C. 23,4 v 56,3.

D. 15,6 v 55,4.

Cu 23: Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch Ba(HCO3)2 thu c kt
ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n khi khng cn kh thot ra th ht
560 ml. Bit ton b Y phn ng va vi 200 ml dung dch NaOH 1M. Khi lng kt ta X l
A. 3,94 gam.

B. 7,88 gam.

C. 11,28 gam.

~ 50 ~

D. 9,85 gam.

KIM LOI KIM TH V HP CHT

Cu 1: Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l:
A. HCl, NaOH, Na2CO3.
Na2CO3.

B. NaOH, Na3PO4, Na2CO3.

C. KCl, Ca(OH)2, Na2CO3.

D. HCl, Ca(OH)2,

Cu 2: Hp cht no ca canxi c dng c tng, b bt khi gy xng?

A. Thch cao nung (CaSO4.H2O).

B. vi (CaCO3).

C. Vi sng (CaO).

D. Thch cao sng (CaSO4.2H2O).

3

Cu 3: Khi lng ring ca canxi kim loi l 1,55 g/cm . Gi thit rng, trong tinh th canxi cc nguyn t l nhng hnh
cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi tnh theo l thuyt l
A.0,185 nm.

B. 0,196 nm.

C. 0,155 nm.

D. 0,168 nm.

Cu 4: Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y tc dng ht vi lng d dung dch
HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l
A.kali v bari.

B. liti v beri.

C. natri v magie.

D. kali v canxi.

Cu 5: Pht biu no sau y ng?

A. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit nng chy gim dn.
B. Kim loi xesi c dng ch to t bo quang in.
C. Kim loi magie c kiu mng tinh th lp phng tm din.
D. Cc kim loi: natri, bari, beri u tc dng vi nc nhit thng.
Cu 6: Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc).
Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung dch X bi dung dch Y, tng khi lng
cc mui c to ra l
A.13,70 gam.

B. 12,78 gam.

C. 18,46 gam.

D. 14,62 gam.

Cu 7: Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt dung dch X. Ly 1 lt dung dch X
tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt tA. Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d)
ri un nng, sau khi kt thc cc phn ng thu c 7,0 gam kt tA. Gi tr ca a, m tng ng l
A.0,08 v 4,8.

B. 0,04 v 4,8.
+

C. 0,14 v 2,4.

B. 0,120.

D. 0,07 v 3,2.

Cu 8: Cho dung dch X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl ; 0,006 mol HCO3 v 0,001 mol NO3.
loi b ht Ca2+ trong X cn mt lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l
A.0,180.

2+

C. 0,444.

D. 0,222.

Cu 9: Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung dch cha Na2CO3 0,2M v NaHCO3 0,2M,
sau phn ng thu c s mol CO2 l
A.0,020.

B. 0,030.

C. 0,015.

D. 0,010.

Cu 10: Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2 0,12M,
thu c m gam kt tA. Gi tr ca m l
A.1,182.

B. 3,940.

C. 1,970.

D. 2,364.

Cu 11: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2 v
CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l
A.3.

B. 2.

C. 1.

D. 4.

Cu 12: Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c,
cht to ra lng kh Cl2 nhiu nht l
A.KMnO4.

B. MnO2.

C. CaOCl2.

Cu 13: Dy gm cc cht u tc dng c vi dung dch HCl long l:

~ 51 ~

D. K2Cr2O7.

A. KNO3, CaCO3, Fe(OH)3.

HCOONa, CuO.

B. FeS, BaSO4, KOH.

C. AgNO3, (NH4)2CO3, CuS.

D. Mg(HCO3)2,

Cu 27: Hp th hon ton 4,48 lt kh CO2 ( ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH)2 0,2M,
sinh ra m gam kt tA. Gi tr ca m l
A.19,70.

B. 17,73.

C. 9,85.

D. 11,82.

Cu 14: Dy gm cc kim loi u c cu to mng tinh th lp phng tm khi l:

A.Na, K, Ca, BA.

B. Na, K, Ca, Be.

C. Li, Na, K, Mg.

D. Li, Na, K, Rb.

Cu 15: Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d dung dch HNO3. Sau khi cc phn
ng xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam
mui khan. Kh X l
A.N2O.

B. NO2.

C. N2.

D. NO.

Cu 16: Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M, thu c dung dch X. Coi th tch
dung dch khng thay i, nng mol ca cht tan trong dung dch X l
A.0,6M.

B. 0,2M.

C. 0,1M.

D. 0,4M.

Cu 17: Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H2SO4 (d), thu c dung dch cha 7,5 gam
mui sunfat trung ho. Cng thc ca mui hirocacbonat l
A.NaHCO3.

B. Ca(HCO3)2.

Cu 18: Cho s chuyn ho sau:

A. HCl, HNO3, Na2CO3.
MgCO3.

CaO +X

C. Ba(HCO3)2.

CaCl2 +Y Ca(NO3)2

B. Cl2, HNO3, CO2.

+Z CaCO3

D. Mg(HCO3)2.

Cng thc ca X, Y, Z ln lt l:

C. HCl, AgNO3, (NH4)2CO3.

D. Cl2, AgNO3,

Cu 32: t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp kh Cl2 v O2. Sau
phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l
A.Mg.

B. CA.

C. Be.

D. Cu.

C. Na2CO3 v Ca(OH)2.

D. NaCl v Ca(OH)2.

Cu 19: Hai cht c dng lm mm nc cng vnh cu l

A. Na2CO3 v HCl.

B. Na2CO3 v Na3PO4.

Cu 20: X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X v Zn tc
dng vi lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d
dung dch H2SO4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l
A.BA.

B. CA.

C. Sr.

D. Mg.

Cu 21: Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy nht, ktc).
Kh X l
A.N2O.

B. NO2.

C. N2.

D. NO.

Cu 22: Hai kim loi c th c iu ch bng phng php in phn dung dch l
A.Al v Mg.

B. Na v Fe.

C. Cu v Ag.

D. Mg v Zn.

Cu 23: Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l:

A. Bt Mg, dung dch BaCl2, dung dch HNO3.

B. Kh Cl2, dung dch Na2CO3, dung dch HCl.

C. Bt Mg, dung dch NaNO3, dung dch HCl.

D. Kh Cl2, dung dch Na2S, dung dch HNO3.

Cu 24: Hp th hon ton 2,24 lt CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x mol/lt, sau khi cc phn
ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl2 (d), thu c 11,82 gam kt
tA. Gi tr ca x l
A.1,6.

B. 1,2.

C. 1,0.

D. 1,4.

Cu 25: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4,
Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l
A.4.

B. 7.

C. 5.

D. 6.

Cu 26: Ha tan hon ton 2,45 gam hn hp X gm hai kim loi kim th vo 200 ml dung dch HCl 1,25M, thu c
dung dch Y cha cc cht tan c nng mol bng nhau. Hai kim loi trong X l

~ 52 ~

A.Mg v CA.

B. Be v Mg.
2+

C. Mg v Sr.
2+

D. Be v CA.

2-

Cu 27: Mt mu nc cng cha cc ion: Ca , Mg , HCO3 , Cl , SO4 . Cht c dng lm mm mu nc cng

trn l
A. Na2CO3.

B. HCl.

C. H2SO4.

D. NaHCO3.

Cu 28: Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh
NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l
A. 8,88 gam.

B. 13,92 gam.

C. 6,52 gam.

D. 13,32 gam.

C. Ca(H2PO4)2.

D. CaHPO4.

Cu 29: Thnh phn chnh ca qung photphorit l

A. Ca3(PO4)2.

B. NH4H2PO4.

Cu 30: Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh CO2 ( ktc). Thnh
phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l
A. 40%.

B. 50%.

C. 84%.

D. 92%.

Cu 31: Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c
vi dung dch Ba(HCO3)2 l:
A. HNO3, NaCl, Na2SO4.
B. HNO3, Ca(OH)2, KHSO4, Na2SO4.
Ca(OH)2.
D. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2.

C. NaCl, Na2SO4,

Cu 32: Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v kh X. Lng kh
X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l (cho H = 1, C =
12, O = 16, Na = 23)
A. 5,8 gam.

B. 6,5 gam.

C. 4,2 gam.
o

Cu 33: T hai mui X v Y thc hin cc phn ng sau:

t
X
X2 +Y

X1 + CO2
X + Y1 + H2O

D. 6,3 gam.
X1 + H2O
X2 + 2Y

X2
X + Y2 + 2H2O

Hai mui X, Y tng ng l

A.CaCO3, NaHSO4.

B. BaCO3, Na2CO3.

C. CaCO3, NaHCO3.

D. MgCO3, NaHCO3.

Cu 34: Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam
kt tA. Gi tr ca a l (cho C = 12, O = 16, Ba = 137)
A.0,032.

B. 0,048.

C. 0,06.

D. 0,04.

Cu 35: ho tan hon ton 6,4 gam hn hp gm kim loi R (ch c ha tr II) v oxit ca n cn va 400 ml dung
dch HCl 1M. Kim loi R l
A.BA.

B. Be.

C. Mg.
+

D. Ca.

Cu 36: Mt cc nc c cha cc ion: Na (0,02 mol), Mg (0,02 mol), Ca (0,04 mol), Cl (0,02 mol), HCO3 (0,10 mol)
v SO42 (0,01 mol). un si cc nc trn cho n khi cc phn ng xy ra hon ton th nc cn li trong cc
A. l nc mm.
thi.

2+

B. c tnh cng vnh cu.

2+

C. c tnh cng ton phn.

D. c tnh cng tm

Cu 37: Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi lng d dung
dch Ba(OH)2 to thnh kt ta l
A.5.

B. 4.

C. 1.

D. 3.

Cu 38: Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong dy to thnh kt ta khi phn
ng vi dung dch BaCl2 l
A.4.

B. 6.

C. 3.

~ 53 ~

D. 2.

NHM V HP CHT CA NHM

Cu 1: Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau.
- Cho phn 1 vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc).
- Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim loi Y. Ho tan hon ton Y
vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc). Khi lng (tnh theo gam) ca K, Al, Fe trong mi phn hn hp
X ln lt l:
A.0,39; 0,54; 1,40.

B. 0,78; 1,08; 0,56.

C. 0,39; 0,54; 0,56.

D. 0,78; 0,54; 1,12.

Cu 2: Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l
A.3.

B. 4.

C. 2.

D. 1.

Cu 3: Phn chua c dng trong ngnh cng nghip thuc da, cng nghip giy, cht cm mu trong ngnh nhum vi,
cht lm trong nC. Cng thc ho hc ca phn chua l
A. Na2SO4.Al2(SO4)3.24H2O. B. K2SO4.Al2(SO4)3.24H2O.
Li2SO4.Al2(SO4)3.24H2O.

C. (NH4)2SO4.Al2(SO4)3.24H2O.

D.

Cu 4 : Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn ng xy
ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot rA. Thm tip vo bnh 0,425 gam NaNO3, khi cc
phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l
A. 0,224 lt v 3,750 gam.
gam.

B. 0,112 lt v 3,750 gam.

C. 0,224 lt v 3,865 gam.

D. 0,112 lt v 3,865

Cu 5: Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml kh NxOy (sn phm kh
duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l
A.NO v Mg.

B. NO2 v Al.

C. N2O v Al.

D. N2O v Fe.

Cu 6: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng hon ton, thu
c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A.0,8 gam.

B. 8,3 gam.

C. 2,0 gam.

D. 4,0 gam.

Cu 7: Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c 2,24 lt kh
H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A.101,68 gam.

B. 88,20 gam.

C. 101,48 gam.

D. 97,80 gam.

Cu 8: Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn
hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam
cht rn khan. Gi tr ca m l
A.38,34.

B. 34,08.

C. 106,38.

D. 97,98.

Cu 9: Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H2 ( ktc). Th
tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l
A.2,80 lt.

B. 1,68 lt.

C. 4,48 lt.

D. 3,92 lt.

Cu 10: Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi phn ng hon
ton, thu c 7,8 gam kt tA. Gi tr ln nht ca V thu c lng kt ta trn l
A.0,45.

B. 0,35.

C. 0,25.

D. 0,05.

Cu 11: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v
dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A.0,55.

B. 0,60.

C. 0,40.

D. 0,45.

Cu 12: Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy ra hon

ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l
A. 10,8.

B. 5,4.

C. 7,8.

~ 54 ~

D. 43,2.

Cu 13: Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc phn ng xy ra
hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag)
A.59,4.

B. 64,8.

C. 32,4.

D. 54,0.

Cu 14: Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon
ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: - Phn 1 tc dng vi dung dch H2SO4 long (d), sinh
ra 3,08 lt kh H2 ( ktc); - Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l
A.22,75

B. 21,40.

C. 29,40.

D. 29,43.

Cu 15: Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra l
A. c kt ta keo trng, sau kt ta tan.

B. ch c kt ta keo trng.

C. c kt ta keo trng v c kh bay ln.

D. khng c kt ta, c kh bay ln.

Cu 16: Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l
A.a : b = 1 : 4.

B. a : b < 1 : 4.

C. a : b = 1 : 5.

D. a : b > 1 : 4.

Cu 17: Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht
lng tnh l
A.3.

B. 5.

C. 2.

D. 4.

Cu 18: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c
5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l
A.1.

B. 6.

C. 7.

D. 2.

Cu 19: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy ca
chng, l:
A.Na, Ca, Al.

B. Na, Ca, Zn.

C. Na, Cu, Al.

D. Fe, Ca, Al.

Cu 20: thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi ta ho tan X bi dung
dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%)
A. c mol bt Al vo Y.
Y.

B. c mol bt Cu vo Y.

C. 2c mol bt Al vo Y.

D. 2c mol bt Cu vo

Cu 21: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung
dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l
A.4.

B. 1.

C. 3.

D. 2.

Cu 22: Tin hnh cc th nghim sau: (1) Sc kh H2S vo dung dch FeSO4; (2) Sc kh H2S vo dung dch CuSO4;
(3) Sc kh CO2 (d) vo dung dch Na2SiO3; (4) Sc kh CO2 (d) vo dung dch Ca(OH)2; (5) Nh t t dung dch
NH3 n d vo dung dch Al2(SO4)3;
(6) Nh t t dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3. Sau khi cc phn ng xy ra hon ton, s th nghim
thu c kt ta l
A.5.

B. 6.

C. 3.

D. 4.

Cu 23: Nung hn hp gm 10,8 gam Al v 16,0 gam Fe2O3 (trong iu kin khng c khng kh), sau khi phn ng xy ra
hon ton thu c cht rn Y. Khi lng kim loi trong Y l
A.16,6 gam.

B. 11,2 gam.

C. 5,6 gam.

D. 22,4 gam.

Cu 24: t chy hon ton 17,4 gam hn hp Mg v Al trong kh oxi (d) thu c 30,2 gam hn hp oxit. Th tch kh
oxi (ktc) tham gia phn ng l
A.4,48 lt.

B. 8,96 lt.

C. 17,92 lt.

D. 11,20 lt.

Cu 25: Cho hn hp X gm Cu, Ag, Fe, Al tc dng vi oxi d khi un nng c cht rn Y. Cho Y vo dung dch HCl
d, khuy k, sau ly dung dch thu c cho tc dng vi dung dch NaOH long, d. Lc ly kt ta to thnh em
nung trong khng kh n khi lng khng i thu c cht rn Z. Bit cc phn ng xy ra hon ton. Thnh phn ca
Z gm:
A.Fe2O3, CuO.
Ag2O.

B. Fe2O3, CuO, Ag.

C. Fe2O3, Al2O3.

~ 55 ~

D. Fe2O3, CuO,

Cu 26: Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2 (ktc) v
dung dch X. Nh t t dung dch NH3 n d vo dung dch X thu c kt ta, lc ht lng kt ta, nung n khi
lng khng i thu c 2,04 gam cht rn. Gi tr ca V l
A.0,448.

B. 0,224.

C. 1,344.

D. 0,672.

Cu 27: Ho tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dung dch X v cht rn Y. Sc kh CO2
n d vo dung dch X, sau khi cc phn ng xy ra hon ton thu c kt ta l
A.Fe(OH)3.

B. K2CO3.

C. Al(OH)3.

D. BaCO3.

Cu 28: Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht tan
duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt tA. Gi tr ca m v a ln lt l
A.8,3 v 7,2.

B. 11,3 v 7,8.

C. 13,3 v 3,9.

D. 8,2 v 7,8.

Cu 29: Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c dung dch X v 3,136
lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18
gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot rA. Phn trm khi lng ca Al trong
hn hp ban u l
A.19,53%.

B. 12,80%.

C. 10,52%.

D. 15,25%.

Cu 29: Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l:
A. NaHCO3, MgO, Ca(HCO3)2. B. NaHCO3, ZnO, Mg(OH)2. C. NaHCO3, Ca(HCO3)2, Al2O3. D. Mg(OH)2,
Al2O3, Ca(HCO3)2.
Cu 30: Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X. Cho ton b X tc
dng vi 200 ml dung dch Ba(OH)2 1M, sau phn ng thu c m gam kt tA. Gi tr ca m l
A.7,8.

B. 46,6.

C. 54,4.

D. 62,2.

Cu 31: Ch dng dung dch KOH phn bit c cc cht ring bit trong nhm no sau y?
A.Mg, Al2O3, Al.

B. Mg, K, NA.

C. Zn, Al2O3, Al.

D. Fe, Al2O3, Mg.

Cu 32: Chia m gam Al thnh hai phn bng nhau: - Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh
H2; - Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn phm kh duy nht). Quan h
gia x v y l
A.x = 2y.

B. y = 2x.

C. x = 4y.

D. x = y.

Cu 33: Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra hon ton, thu
c hn hp rn gm ba kim loi l:
A.Fe, Cu, Ag.

B. Al, Cu, Ag.

C. Al, Fe, Cu.

D. Al, Fe, Ag.

Cu 34: Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H2SO4 0,28M thu c
dung dch X v 8,736 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l
A.38,93 gam.

B. 103,85 gam.

C. 25,95 gam.

D. 77,86 gam.

Cu 35: t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra
hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi
tr ca V l
A.150.

B. 100.

C. 200.

D. 300.

Cu 36: Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dy c tnh cht lng tnh
l
A.5.

B. 2.

C. 3.

D. 4.

Cu 37: Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long nng (trong iu kin
khng c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc). C cn dung dch X (trong iu kin khng c
khng kh) c m gam mui khan. Gi tr ca m l
A.42,6.

B. 45,5.

C. 48,8.

D. 47,1.

Cu 38: Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu c cht rn Y.
Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng xy ra hon ton. Phn
khng tan Z gm
A.MgO, Fe, Cu.

B. Mg, Fe, Cu.

C. MgO, Fe3O4, Cu.

~ 56 ~

D. Mg, Al, Fe, Cu.

Cu 39: Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t
dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca
m l (Cho H = 1; O = 16; Na = 23; Al = 27; S = 32; K = 39; Ba = 137)
A.1,59.

B. 1,17.

C. 1,71.

D. 1,95.

Cu 40: Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng
thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam
Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l (Cho: hiu sut ca cc phn ng l 100%; O =
16; Al = 27; Cr = 52; Fe = 56)
A.50,67%.

B. 20,33%.

C. 66,67%.

D. 36,71%.

Cu 41: Cc hp cht trong dy cht no di y u c tnh lng tnh?

A. Cr(OH)3, Fe(OH)2, Mg(OH)2.
Mg(OH)2. D. Cr(OH)3, Pb(OH)2, Mg(OH)2.

B. Cr(OH)3, Zn(OH)2, Pb(OH)2.C. Cr(OH)3, Zn(OH)2,

Cu 42: Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3 (trong iu kin khng c O2), sau khi
phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn
ng xy ra hon ton, thu c 2,016 lt H2 (ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c,
nng), sau khi cc phn ng kt thc th s mol NaOH phn ng l
A.0,14 mol.

B. 0,08 mol.

C. 0,16 mol.

D. 0,06 mol.

Cu 43: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau
khi cc phn ng kt thc thu c 8,424 gam kt tA. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th
thu c 33,552 gam kt tA. T l x : y l
A.3 : 4.

B. 3 : 2.

C. 4 : 3.

D. 7 : 4.

Cu 44: Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn
hp Y. Ho tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S
mol HNO3 phn ng l
A.0,12.

B. 0,14.

C. 0,16.

D. 0,18.

Cu 45: Pht biu no sa uy khng ng khi so snh tnh cht ha hc ca nhm v crom?
A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui.
mnh hn crom.

B. Nhm c tnh kh

C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol. D. Nhm v crom u bn trong khng kh
v trong nC.
Cu 46: Pht biu no sau y khng ng?
A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht.
B. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh.
C. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng.
D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng.
Cu 47: Trn 10,8 gam bt Al vi 34,8 gam bt Fe3O4 ri tin hnh phn ng nhit nhm trong iu kin khng c khng
kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H2SO4 long (d), thu c 10,752 lt kh H2 (ktc).
Hiu sut ca phn ng nhit nhm l
A.80%.

B. 90%.

C. 70%.

D. 60%.

Cu 48: Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu c dung dch Y v
4,68 gam kt tA. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt tA. Gi tr ca
x l
A.1,2.

B. 0,8.

C. 0,9.

D. 1,0.

Cu 49: Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra hon ton, thu
c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi
lng khng i, thu c cht rn Z l
A. hn hp gm BaSO4 v FeO.
gm BaSO4 v Fe2O3.
D. Fe2O3.

B. hn hp gm Al2O3 v Fe2O3.

~ 57 ~

C. hn hp

Cu 50: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v 67,2 m3 (
ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong
(d) thu c 2 gam kt tA. Gi tr ca m l
A. 108,0.

B. 75,6.

C. 54,0.

D. 67,5.

Cu 51: Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon
ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh
H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt tA. Gi tr ca m l
A. 45,6.

B. 48,3.

C. 36,7.

D. 57,0.

Cu 52: Th nghim no sau y c kt ta sau phn ng?

A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3.

B. Cho dung dch NH3 n d vo dung dch AlCl3

C. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).

vo dung dch Ca(OH)2.

D. Thi CO2 n d

Cu 53: Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2
(sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon
ton thu c m gam kt tA. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l
A.21,95% v 2,25.

B. 78,05% v 2,25.

C. 21,95% v 0,78.

D. 78,05% v 0,78.

Cu 54: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc).
Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh
NO2 (sn phm kh duy nht, ktc). Gi tr ca m l
A. 11,5.

B. 10,5.

C. 12,3.

D. 15,6.

Cu 55: Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch
A. NaOH (d).

B. HCl (d).

C. AgNO3 (d).

D. NH3(d).

Cu 56: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam.
Gi tr ln nht ca V l (cho H = 1, O = 16, Al = 27)
A. 1,2.

B. 1,8.

C. 2,4.

D. 2.

Cu 57: Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng cho m gam X vo
dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l (bit cc th tch
kh o trong cng iu kin, cho Na = 23, Al = 27)
A. 39,87%. B. 77,31%. C. 49,87%. D. 29,87%.
Cu 58: thu c Al2O3 t hn hp Al2O3 v Fe2O3, ngi ta ln lt:
A. dng kh H2 nhit cao, dung dch NaOH (d).

B. dng kh CO nhit cao, dung dch HCl (d).

C. dng dung dch NaOH (d), dung dch HCl (d), ri nung nng.
NaOH (d), kh CO2 (d), ri nung nng.

D. dng dung dch

Cu 59: Nung hn hp bt gm Al v Fe2O3 (trong iu kin khng c oxi), thu c hn hp cht rn X. Chia
X thnh 2 phn bng nhau:Cho phn 1 vo dung dch HCl (d) thu c 7,84 lt kh H2 (ktc);Cho phn 2 vo
dung dch NaOH (d) thu c 3,36 lt kh H2 (ktc). Bit rng cc phn ng u xy ra hon ton. Phn trm
khi lng ca Fe trong X l
A. 42,32%.

B. 46,47%.

C. 66,39%.

D. 33,61%.

Cu 60: Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn ng nhit nhm X (khng c khng
kh) n khi phn ng xy ra hon ton thu c hn hp gm
A. Al, Fe, Fe3O4 v Al2O3.

B. Al2O3, Fe v Fe3O4.

C. Al2O3 v Fe.

D. Al, Fe v Al2O3.

Cu 61: Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M. Sau khi cc phn ng xy ra hon ton,
thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn hp ban u l
A. 0,168 gam.

B. 0,123 gam.

C. 0,177 gam.

D. 0,150 gam.

Cu 62: t 16,2 gam hn hp X gm Al v Fe trong kh Cl2 thu c hn hp cht rn Y. Cho Y vo nc d, thu c

dung dch Z v 2,4 gam kim loi. Dung dch Z tc dng c vi ti a 0,21 mol KMnO4 trong dung dch H2SO4 (khng
to ra SO2). Phn trm khi lng ca Fe trong hn hp X l
A. 72,91%.

B. 64,00%.

C. 66,67%.

~ 58 ~

D. 37,33%.

ST V MT S KIM LOI QUAN TRNG

THI I HC 2007- KHI A
Cu 1. Cho tng cht : Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3,
FeCO3, ln lt phn ng vi HNO3 c nng. S phn ng thuc loi phn ng oxiha kh l.
A. 8

B. 6

C. 5

D. 7

Cu 2. Mnh khng ng l
A. Fe3+ c tnh oxiha mnh hn Cu2+
B. Fe Kh c Cu2+ trong dung dch.
C. Fe2+ oxiha c Cu2+
D. tnh oxiha tng th t : Fe2+, H+, Cu2+, Ag+
Cu 3. Khi nung hn hp cc cht Fe(NO 3)2, Fe(OH)3 v FeCO3 trong khng kh n khi lng khng i
th thu c mt cht rn
A. Fe2O3

B. FeO C. Fe3O4

D.Fe

Cu 4. Ho tan 5,6 gam Fe bng dd H2SO4 long d thu c dung dch X, dung dch X phn ng va vi
V ml dd KMnO4 0,5M. gi tr V l
A. 40

B. 60

C. 20

D.80

Cu 5. Ho tan hon ton 2,81 gam hh Fe 2O3, MgO, ZnO trong 500ml axit H2SO4 0,1M ( va ). Sau phn
ng, hh mui sunfat khan thu c khi c cn dung dch c khi lng l
A. 6,81 gam

B. 4,81 gam

C. 3,81 gam

D. 5,81 gam

6. Tng h s ( cc nguyn t ti gin) ca tt c cc cht trong p Cu vi HNO3 c nng l

A. 11

B. 10

C. 8

D. 9

Cu 7. Ho tan hon ton 12 gam hn hp Fe, Cu ( t l mol 1:1) bng axit HNO 3 c V lt ( ktc) hh kh X
(gm NO v NO2 ) v dd Y ( ch cha hai mui v axit d) . T khi hi ca X i vi H 2 bng Cu 19. Gi
tr ca V l
A. 3,36

B. 2,24

C. 5,60

D.4,48

Cu 8. Ho tan hon ton hh gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 v c dd X ( ch cha hai
mui sunfat) v kh duy nht NO. Gi tr ca A l
A. 0,06

B. 0,04

C. 0,075

D. 0,12

THI I HC 2007- KHI B

Cu 1. Cho hh Fe, Cu phn ng vi dd HNO 3 long. Sau khi phn ng hon ton, thu c dd ch cha mt
cht tan v kim loi d. Cht tan l
A. Cu(NO3)2

B. HNO3

C. Fe(NO3)2

D. Fe(NO3)3

Cu 2. Nung m gam bt st trong oxi thu c 3 gam hh rn X. Ho tan ht hh X trong dd HNO 3 d thot ra
0,56 lt kh NO ktc( NO l sn phm kh duy nht). Gi tr m l
A. 2,52

B. 2,22

C. 2,62

D. 2,32

Cu 3. Cho 6,72 gam Fe vo dd cha 0,3 mol H 2SO4 c nng ( gi thit SO2 l sn phm kh duy nht). Sau
phn ng xy ra hon ton , thu C.
A. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4

B. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d

C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4

D. 0,12 mol FeSO4

Cu 4.Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 l
A. nhn 13 e

B. nhn 12 e

C. nhng 13 e

D. nhng 12 e

Cu 5. Cho 0,01 mol mt hp cht ca Fe tc dng ht vi H2SO4 c nng d thot ra 0,112 lt kh SO2 l sn
phm kh duy nht. Cng thc ca hp cht st l

~ 59 ~

A. FeS

B. FeS2

C. FeO

D. FeCO3

Cu 6. in phn dd cha a mol CuSO4 v b mol NaCl ( vi in cc tr, c mng ngn xp). dd sau in
phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l ( bit ion SO 42- khng b in phn
trong dd)
A. b > 2a

B. b = 2a

C. b < 2a

D. 2b = a

Cu 7. Cho Cu tc dng vi dd cha H2SO4 long v NaNO3, vai tr ca NaNO3 trong phn ng l
A. cht xc tc

B. cht oxiha

C. mi trng

D. cht kh

Cu 8. Thc hin hai th nghim :

1) Cho 3,84 gam Cu phn ng vi 80ml dd HNO3 1M thot ra V1 lt NO
2) Cho 3,84 gam Cu phn ng vi 80ml dd cha HNO3 1M v H2SO40.5M thot ra V2 lt NO
Bit NO lsn phm kh duy nht, cc th tch kh o trong cng iu kin. Quan h gia V1 v V2 l
A. V2 = V1

B. V2 = 2V1

C. V2 = 2,5V1

D. V2 = 1,5V1

THI I HC 2008 - KHI A

Cu 1. oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c KOH, lng ti thiu Cl2 v
KOH tng ng l
A. 0,015 mol v 0,04 mol.

B. 0,015 mol v 0,08 mol.

C. 0,03 mol v 0,08 mol.

D. 0,03 mol v 0,04 mol.

Cu 2. Trong cc loi qung st, qung c hm lng st cao nht l

A. hematit nu.

B. manhetit.

C. xierit.

D. hematit .

Cu 3. Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc
phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l
A. 59,4.

B. 64,8.

C. 32,4.

D. 54,0.

4. Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng
xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau:
- Phn 1 tc dng vi dung dch H2SO4 long (d), sinh ra 3,08 lt kh H2 ( ktc);
- Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 ( ktc). Gi tr ca m l
A. 22,75

B. 21,40.

C. 29,40.

D. 29,43.

Cu 5. Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v

Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr
ca V l
A. 0,448.

B. 0,112.

C. 0,224.

D. 0,560.

Cu 6. Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi
thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn
ng ht vi Y l
A. 57 ml.

B. 50 ml.

C. 75 ml.

D. 90 ml.

Cu 7. ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO
bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l
A. 0,23.

B. 0,18.

C. 0,08.

D. 0,16.

Cu 8. Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long
(d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dd X thu c m
gam mui khan. Gi tr ca m l
A. 38,72.

B. 35,50.

C. 49,09.

D. 34,36.

Cu 9. Cho Cu v dung dch H2SO4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra
kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai
thot ra. Cht X l

~ 60 ~

A. amophot.

B. ure.

C. natri nitrat.

D. amoni nitrat.

Cu 10. Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M.
Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V
l
A. 0,746.

B. 0,448.

C. 1,792.

D. 0,672.

THI I HC-CAO NG 2008 - KHI B

Cu 1. Cho cc dung dch : HCl , NaOH c , NH3 , KCl . S dung dch phn ng c vi Cu(OH)2 l
A. 1

B. 3

C. 2

D. 4

Cu 2. Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng
xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l :
A. 9,75

B. 8,75

C. 7,80

D. 6,50

Cu 3. Tin hnh hai th nghim sau :

- Th nghim 1 : Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M;
- Th nghim 2 : Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M.
cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca V1 so
vi V2 l
A. V1 = V2

B. V1 = 10V2

C. V1 = 5V2

D. V1 = 2V2

Cu 4. Nung mt hn hp rn gm a mol FeCO 3 v b mol FeS2 trong bnh kn cha khng kh (d). khi cc
p xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe 2O3 v hn hp kh. Bit
p sut kh trong bnh trc v sau p bng nhau, mi lin h gia a v b l (bit sau cc phn ng S mc
oxi ho +4, th tch cc cht rn l khng ng k).
A. a = 0,5b

B. a = b

C. a = 4b

D. a = 2b

Cu 5.Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch
A. NaOH (d) B. HCl (d)

C. AgNO3 (d)

D. NH3 (d)

Cu 6. Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15
mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO)
A. 1,0 lt

B. 0,6 lt

C. 0,8 lt

D. 1,2 lt

Cu 7. Cho m gam hh X gm Al, Cu vo dd HCl (d), sau khi kt thc p sinh ra 3,36 lt kh (ktc). Nu cho
m gam hh X trn vo mt lng d HNO 3 (c, ngui), sau khi kt thc p sinh ra 6,72 lt kh NO 2 (sn phm
kh duy nht, ktc). Gi tr ca m l
A. 11,5

B. 10,5

C. 12,3

D. 15,6

Cu 8. Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam
cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH
bng
A. 2.

B. 3.

C. 4.

D. 1.

Cu 9.Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy
ra hon ton, thu c hn hp rn gm ba kim loi l:
A. Fe, Cu, Ag.

B. Al, Cu, Ag.

C. Al, Fe, Cu.

D. Al, Fe, Ag.

Cu 10. t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh) n

khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch
NaOH 1M sinh ra 3,36 lt H2 ( ktc). Gi tr ca V l
A. 150.

B. 100.

C. 200.

D. 300.

Cu 11. Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4
long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc).
C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l
A. 42,6.

B. 45,5.

C. 48,8.

~ 61 ~

D. 47,1.

Cu 12. Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dy
c tnh cht lng tnh l
A. 5.

B. 2.

C. 3.

D. 4.

Cu 13. Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh),
thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn
hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (
ktc). Gi tr ca V l
A. 2,80.

B. 3,36.

C. 3,08.

D. 4,48.

THI I HC-CAO NG 2009 :

Cu 1. Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu c
dung dch Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn mt thu c
m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu c m 2 gam mui
khan. Bit m2 - m1 = 0,71. Th tch dung dch HCl dng l
A. 160 ml

B. 80 ml

C. 240 ml

D. 320 ml

Cu 2.Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl 3; 0,016 mol Al2(SO4)3 v
0,04 mol H2SO4 thu c m gam kt tA. Gi tr ca m l
A. 4,128

B. 2,568

C. 1,560

D. 5,064

Cu 3. Ch dng dng dch KOH phn bit c cc cht ring bit trong nhm no sau y ?
A. Zn, Al2O3, Al

B. Mg, K, Na

C. Mg, Al2O3, Al

D. Fe, Al2O3, Mg

Cu 4. Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36
gam cht rn. Gi tr ca m l
A. 5,04

B. 4,32

C. 2,88

D. 2,16

Cu 5. Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung

dch AgNO3 ?
A. Zn, Cu, Mg

B. Al, Fe, CuO

C. Fe, Ni, Sn

D. Hg, Na, Ca

Cu 6. Cho m1 gam Al vo 100 ml dung dch gm Cu(NO 3)2 0,3M v AgNO3 0,3M. Sau khi cc phn ng xy
ra hon ton th thu c m 2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d dung dch HCl th thu
c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l
A. 8,10 v 5,43

B. 1,08 v 5,16

C. 0,54 v 5,16

D. 1,08 v 5,43

Cu 7. Trong cc cht : FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ho v
tnh kh l
A. 5

B. 4

C. 2

D. 3

Cu 8. Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng thu c

0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l
A. FeO v 0,224

B. Fe2O3 v 0,448

C. Fe3O4 v 0,448

D. Fe3O4 v 0,224

Cu 9. Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200 ml dung
dch AgNO3 1M cho n khi phn ng xy ra hon ton,. Lc dung dch, em c cn thu c 18,8 gam mui
khan. Kim loi M l
A. Mg

B. Zn

C. Cu

D. Fe

Cu 10. iu ch c 78 gam Cr t Cr 2O3 (d) bng phng php nhit nhm vi hiu sut ca phn ng
l 90% th khi lng bt nhm cn dng ti thiu l
A. 81,0 gam

B. 40,5 gam

C. 45,0 gam

D. 54 gam

Cu 11. Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO 3 2M, thu c m gam kt
tA. Gi tr ca m l
A. 34,44

B. 47,4

C. 12,96

D. 30,18

Cu 11. Th t mt s cp oxi ha kh trong dy in ha nh sau: Mg 2+/Mg; Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+;

Ag+/Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l:

~ 62 ~

A. Mg, Fe, Cu.

B. Mg,Cu, Cu2+.

C. Fe, Cu, Ag+

. D. Mg, Fe2+, Ag.

Cu 13.Nung nng 16,8 gam hn hp Au, Ag, Cu, Fe, Zn vi mt lng d kh O 2, n khi cc phn ng xy
ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn ng vi cht rn X l
A. 600 ml.

B. 200 ml.

C. 800 ml.

D. 400 ml.

Cu 14.Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H 2SO4 0,5M
v Na NO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy
nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu
ca V l
A. 240.

B. 120.

C. 360.

D. 400.

Cu 15. Trng hp no sau y khng xy ra phn ng ha hc?

A. Cho Fe vo dung dch H2SO4 long, ngui.

B. Sc kh Cl2 vo dung dch FeCl2.

C. Sc kh H2S vo dung dch CuCl2.

D. Sc kh H2S vo dung dch FeCl2.

Cu 16. Cho cc hp kim sau: Cu-Fe (I); Zn Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht
in li th cc hp kim m trong Fe u b n mn trc l:
A. I, II v III.

B. I, II v IV.

C. I, III v IV.

D. II, III v IV.

Cu 17. Ha tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110ml dung dch KOH 2M vo X, thu
c a gam kt tA. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt tA.
Gi tr ca m l
A. 20,125.

B. 12,375.

C. 22,540.

D. 17,710.

Cu 18. Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn ng
hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l
A. 0,8 gam.

B. 8,3 gam.

C. 2,0 gam.

D. 4,0 gam.

Cu 19. Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H 2SO4 10% thu c
2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l
A. 101,48 gam.

B. 101,68 gam.

C. 97,80 gam.

D. 88,20 gam.

Cu 20. Cho hn hp gm Fe v Zn vo dung dch AgNO 3 n khi cc phn ng xy ra hon ton, thu c
dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l
A. Fe(NO3)2 v AgNO3.

B. AgNO3 v Zn(NO3)2.

C. Zn(NO3)2 v Fe(NO3)2.

D. Fe(NO3)3 v Zn(NO3)2.

Cu 21. Cho 6,72 gam Fe vo 400ml dung dch HNO 3 1M, n khi phn ng xy ra hon ton, thu c kh
NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ha tan ti a m gam Cu. Gi tr ca m l
A. 1,92.

B. 0,64.

C. 3,84.

D. 3,20.
2+

Cu 22. Cho dy cc cht v ion: Zn, S, FeO, SO2, N2, HCl, Cu , Cl . S cht v ion c c tnh oxi ha v tnh
kh l
A. 4.

B. 6.

C. 5.

D. 7.

Cu 23. Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam
cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH
bng
A. 2.

B. 3.

C. 4.

D. 1.

Cu 24. C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl2, Cr(NO3)3, K2CO3,
Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim
c kt ta l
A. 5.

B. 2.

C. 4.

D. 3

Cu 25. Ha tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt H2(
ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l
A. 3,92 lt.

B. 1,68 lt

C. 2,80 lt

~ 63 ~

D. 4,48 lt

Cu 26. Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi cc
phn ng xy ra hon ton, thu c mt dung dch cha 3 ion kim loi. Trong cc gi tr sau y, gi tr no
ca x tha mn trng hp trn?
A. 1,5

B. 1,8

C. 2,0

D. 1,2

Cu 27. Cho sut in ng chun ca cc pin in ha: Zn-Cu l 1,1 V; Cu-Ag l 0,46 V. Bit th in cc
0
0
0
chun E Ag + / Ag = +0,8V . Th din cc chun EZn2+ / Zn v ECu 2+ / Cu c gi tr ln lt l
A. +1,56 V v +0,64 V

B. 1,46 V v 0,34 V

C. 0,76 V v + 0,34 V

D. 1,56 V v +0,64 V

Cu 28. Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit)
nng 0,95 m gam. Phn trm khi lng PbS b t chy l
A. 74,69 %

B. 95,00 %

C. 25,31 %

D. 64,68 %

Cu 29. Trng hp xy ra phn ng l

A. Cu + Pb(NO3)2 (long)

B. Cu + HCl (long)

C. Cu + HCl (long) + O2

D. Cu + H2SO4 (long)

Cu 30. Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO 3)2 0,2M v H2SO4 0,25M. Sau khi cc
phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht,
ktc). Gi tr ca m v V ln lt l
A. 17,8 v 4,48.

B. 17,8 v 2,24.

C. 10,8 v 4,48.

D. 10,8 v 2,24.

Cu 31. Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy
u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung
dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l
A. 151,5.

B. 97,5.

C. 137,1.

D. 108,9.

Cu 32. Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh hn s mol mui tng ng.
t mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu vng. Hai mui X, Y ln lt l:
A. KMnO4, NaNO3.

B. Cu(NO3)2, NaNO3.

C. CaCO3, NaNO3.

D. NaNO3, KNO3.

Cu 33. Ha tan hon ton 20,88 gam mt oxit st bng dung dch H 2SO4 c, nng thu c dung dch X v
3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan.
Gi tr ca m l
A. 52,2.

B. 48,4.

C. 54,0.

D. 58,0.

Cu 34. Ha tan m gam hn hp gm Al, Fe vo dung dch H 2SO4 long (d). Sau khi cc phn ng xy ra
hon ton, thu c dung dch X. Cho dung dch Ba(OH) 2 (d) vo dung dch X, thu c kt ta Y. Nung Y
trong khng kh n khi lng khng i, thu c cht rn Z l
A. hn hp gm Al2O3 v Fe2O3.

B. hn hp gm BaSO4 v FeO.

C. hn hp gm BaSO4 v Fe2O3.

D. Fe2O3.

Cu 35. Cho 2,24 gam bt st vo 200 ml dung dch cha hn hp gm AgNO 3 0,1M v Cu(NO3)2 0,5M. Sau
khi cc phn ng xy ra hon ton, thu c dung dch X v m gam cht rn Y. Gi tr ca m l
A. 2,80.

B. 4,08.

C. 2,16.

D. 0,64.

Cu 36. Th nghim no sau y c kt ta sau phn ng?

A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3.
B. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
C. Thi CO2 n d vo dung dch Ca(OH)2.
D. Cho dung dch NH3 n d vo dung dch AlCl3.
Cu 37. Nung nng m gam hn hp gm Al v Fe 3O4 trong iu kin khng c khng kh. Sau khi phn ng
xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y,
cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt tA. Gi tr ca
m l

~ 64 ~

A. 48,3

B. 57,0

C. 45,6

D. 36,7

Cu 38. in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl 2 0,1M v NaCl 0,5M (in cc
tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in
phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l
A. 4,05

B. 2,70

C. 1,35

D. 5,40

Cu 39. Nhng mt thanh st nng 100 gram vo 100 ml dung dch hn hp gm Cu(NO 3)2 0,2M v AgNO3
0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi
to thnh u bm ht vo thanh st). Khi lng st phn ng l
A. 2,16 gam

B. 0,84 gam

C. 1,72 gam

D. 1,40 gam

Cu 40. Cho s chuyn ho gia cc hp cht ca crom :

+ (Cl2 + KOH)
+ H 2SO 4
+ (FeSO 4 + H 2SO 4 )
+ KOH
Cr(OH)3
X
Y
Z
T

Cc cht X, Y, Z, T theo th t l:
A. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3

B. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3

C. KCrO2; K2Cr2O7; K2CrO4; CrSO4

D. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3

Cu 41. Ho tan hon ton 24,4 gam hn hp gm FeCl 2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt
lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra
hon ton sinh ra m gam cht rn. Gi tr ca m l
A. 68,2

B. 28,7

C. 10,8

D. 57,4

0
0
0
Cu 42. Cho cc th in cc chun : E Al3+ /Al = 1, 66V; E Zn 2+ /Zn = 0, 76V ; E Pb2+ / Pb = 0,13V ;

= +0,34V . Trong cc pin sau y, pin no c sut in ng chun ln nht?

E0

Cu 2 + /Cu

A. Pin Zn - Pb

B. Pin Pb - Cu

C. Pin Al - Zn

D. Pin Zn - Cu

Cu 43. Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO
(sn phm kh duy nht) to thnh ln lt l
A. 0,03 v 0,01

B. 0,06 v 0,02

C. 0,03 v 0,02

D. 0,06 v 0,01

Cu 44. Ho tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO 3 c, nng thu c 1,344
lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH 3 (d) vo dung dch Y, sau khi
phn ng xy ra hon ton thu c m gam kt tA. Phn trm v khi lng ca Cu trong hn hp X v gi
tr ca m ln lt l
A. 21,95% v 0,78

B. 78,05% v 0,78

C. 78,05% v 2,25

D. 21,95% v 2,25

THI I HC CAO NG 2010:

Cu 1. Cho 1,56 gam hn hp gm Al va Al2O3 phan ng ht vi dung dich HCl (d), thu c V lit khi H 2
(ktc) va dung dich X. Nho t t dung dich NH3 n d vao dung dich X thu c kt tua, loc ht lng kt
tua, nung n khi lng khng i thu c 2,04 gam cht rn. Gia tri cua V la
A. 0,672

B. 0,224

C. 0,448

D. 1,344

Cu 2. Cho cac dung dich loang: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn hp gm HCl va NaNO3.
Nhng dung dich phan ng c vi kim loai Cu la
A. (1), (2), (3)

B. (1), (3), (5)

C. (1), (4), (5)

D. (1), (3), (4)

Cu 3. Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn ng
xy ra hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht) Ga tr ca a l
A. 8,4

B. 5,6

C. 11,2

D. 11,0

Cu 4. Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO 4 0,5M. Sau khi cc phn ng
xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi. Phn trm v khi lng ca Fe trong
hn hp ban u l
A. 56,37%

B. 37,58%

C. 64,42%

Cu 5. Pht biu no sau y khng ng?

~ 65 ~

D. 43,62%

A. Crom(VI) oxit l oxit baz

B. Ancol etylic bc chy khi tip xc vi CrO3
C. Khi phn ng vi dung dch HCl, kim loi Cr b oxi ho thnh ion Cr2+
D. Crom(III) oxit v crom(II) hiroxit u l cht c tnh lng tnh
Cu 6. Kim loi M c th c iu ch bng cch kh ion ca n trong oxit bi kh H 2 nhit cao. Mt
khc, kim loi M kh c ion H+ trong dung dch axit long thnh H2. Kim loi M l
A. Al

B. Mg

C. Fe

D. Cu

Cu 7. Cho m gam bt crom phn ng hon ton vi dung dch HCl (d) thu c V lt kh H 2 (ktc). Mt
khc cng m gam bt crom trn phn ng hon ton vi kh O2 (d) thu c 15,2 gam oxit duy nht. Gi tr
ca V l
A. 2,24

B. 4,48

C. 3,36

D. 6,72

Cu 8. Cho 19,3 gam hn hp bt Zn va Cu co ti l mol tng ng la 1 : 2 vao dung dich cha 0,2 mol
Fe2(SO4)3. Sau khi cac phan ng xay ra hoan toan, thu c m gam kim loai. Gia tri cua m la
A. 6,40

B. 16,53

C. 12,00

D. 12,80

Cu 9. Nung nong tng cp cht trong binh kin: (1) Fe + S (r), (2) Fe 2O3 + CO (k), (3) Au + O2 (k), (4) Cu +
Cu(NO3)2 (r), (5) Cu + KNO3 (r) , (6) Al + NaCl (r). Cac trng hp xay ra phan ng oxi hoa kim loai la :
A. (1), (3), (6)

B. (2), (3), (4)

C. (1), (4), (5)

D. (2), (5), (6)

Cu 10. Cho x mol Fe tan hoan toan trong dung dich cha y mol H 2SO4 (ti l x : y = 2 : 5), thu c mt san
phm kh duy nht va dung dich chi cha mi sunfat. S mol electron do lng Fe trn nhng khi bi hoa tan
la
A. 3x

B. y

C. 2x

D. 2y

Cu 11. Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O
S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l
A. 4/7.

B. 1/7.

C. 3/14.

D. 3/7.

Cu 11. in phn (in cc tr) dung dch X cha 0,2 mol CuSO 4 v 0,12 mol NaCl bng dng in c
cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l
A. 2,240 lt.

B. 2,912 lt.

C. 1,792 lt.

D. 1,344 lt.

Cu 13. Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng
d dung dch HCl long, nng thu c dung dch Y v kh H 2. C cn dung dch Y thu c 8,98 gam mui
khan. Nu cho m gam hn hp X tc dng hon ton vi O 2 (d) to hn hp 3 oxit th th tch kh O 2
(ktc) phn ng l
A. 2,016 lt.

B. 0,672 lt.

C. 1,344 lt.

D. 1,008 lt.

Cu 14. Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c
2,71 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO 3 (d), thu c 0,672 lt kh NO (sn phm
kh duy nht, ktc). S mol HNO3 phn ng l
A. 0,12.

B. 0,14.

C. 0,16.

D. 0,18.

Cu 15. Kh hon ton m gam oxit M xOy cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ha
tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO 2 (sn phm kh duy nht,
ktc). Oxit MxOy l
A. Cr2O3.

B. FeO.

C. Fe3O4.

D. CrO.

3+

Cu 16. Mt ion M c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht
khng mang in l 19. Cu hnh electron ca nguyn t M l
A. [Ar]3d54s1.

B. [Ar]3d64s2.

C. [Ar]3d64s1.

D. [Ar]3d34s2.

Cu 17. Ha tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d).
Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp
mui sunfat. Phn trm khi lng ca Cu trong X l
A. 39,34%.

B. 65,57%.

C. 26,23%.

~ 66 ~

D. 13,11%.

Cu 18. in phn (vi in cc tr) 200 ml dung dich CuSO 4 nng x mol/l, sau mt thi gian thu c
dung dich Y vn con mau xanh, co khi lng giam 8g so vi dung dich ban u. Cho 16,8g bt Fe vao Y, sau
khi cac phan ng xay ra hoan toan, thu c 12,4g kim loai. Gia tri cua x la
A. 2,25

B. 1,5

C. 1,25

D. 3,25

Cu 19. Trn 10,8g bt Al vi 34,8g bt Fe3O4 ri tin hanh phan ng nhit nhm trong iu kin khng co
khng khi. Hoa tan hoan toan hn hp rn sau phan ng bng dung dich H 2SO4 loang (d) thu c 10,752 lit
khi H2 (ktc). Hiu sut cua phan ng nhit nhm la
A. 80%

B. 90%

C. 70%

D. 60%

Cu 20. t chay hoan toan m gam FeS 2 bng mt lng O2 va u, thu c khi X. Hp thu ht X vao 1 lit
dung dich cha Ba(OH)2 0,15M va KOH 0,1M, thu c dung dich Y va 21,7 gam kt tuA. Cho Y vao dung
dich NaOH, thy xut hin thm kt tuA. Gia tri cua m la
A. 23,2

B. 12,6

C. 18,0

D. 24,0

Cu 21. Hn hp X gm CuO va Fe 2O3. Hoa tan hoan toan 44 gam X bng dung dich HCl (d), sau phan ng
thu c dung dich cha 85,25 gam mui. Mt khac, nu kh hoan toan 22 gam X bng CO (d), cho hn
hp khi thu c sau phan ng li t t qua dung dich Ba(OH) 2 (d) thi thu c m gam kt tu A. Gia tri cua
m la
A. 76,755

B. 73,875

C. 147,750

D. 78,875

Cu 22. Hn hp bt X gm Cu, Zn. t chay hoan toan m gam X trong oxi (d), thu c 40,3 gam hn hp
gm CuO va ZnO. Mt khac, nu cho 0,25 mol X phan ng vi mt lng d dung dich KOH loang nong, thi
thu c 3,36 lit khi H2 (ktc). Phn trm khi lng cua Cu trong X la
A. 19,81%

B. 29,72%

C. 39,63%

D. 59,44%

Cu 23. Cho 0,3 mol bt Cu va 0,6 mol Fe(NO3)2 vao dung dich cha 0,9 mol H2SO4 (loang). Sau khi cac
phan ng xay ra hoan toan, thu c V lit khi NO (san phm kh duy nht, ktc). Gia tri cua V la
A. 6,72

B. 8,96

C. 4,48

D. 10,08

Cu 24. Phat biu nao sau y khng ung ?

A. Trong mi trng kim, mui Cr(III) co tinh kh va bi cac cht oxi hoa manh chuyn thanh mui Cr(VI).
B. Do Pb2+/Pb ng trc 2H+/H2 trong day in hoa nn Pb d dang phan ng vi dung dich HCl loang
ngui, giai phong khi H2.
C. CuO nung nong khi tac dung vi NH3 hoc CO, u thu c Cu
D. Ag khng phan ng vi dung dich H2SO4 loang nhng phan ng vi dung dich H2SO4 c nong.
Cu 25. Cho s chuyn ha:
Fe3O4 + dung dch HI (d) X + Y + H2O
Bit X v Y l sn phm cui cng ca qu trnh chuyn ha. Cc cht X v Y l
A. Fe v I2.

B. FeI3 v FeI2.

C. FeI2 v I2.

~ 67 ~

D. FeI3 v I2.

1. Hidrocacbon no khng no thm..............................................................................................69

2. Ancol Phenol............................................................................................................................. 74
3. Anhit Xeton...........................................................................................................................79
4. Axit Cacboxylic............................................................................................................................ 82
5. Este Lipit................................................................................................................................... 87
6. Cacbohidrat.................................................................................................................................. 93
7. Amin............................................................................................................................................. 97
8. Aminoaxit..................................................................................................................................... 100
9. Polime v vt liu polime.............................................................................................................104

~ 68 ~

HIROCACBON NO KHNG NO THM

Cu 1: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch
Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnhtng thm 6,7 gam.
Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12)
A. C2H2 v C4H6.

B. C2H2 v C4H8.

C. C3H4 v C4H8.

D. C2H2 v C3H8.

Cu 2: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi
lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu
c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40)
A. 20.

B. 40.

C. 30.

D. 10.

Cu 3: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng
clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5)
A. C3H6.

B. C3H4.

C. C2H4.

D. C4H8

Cu 4: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l

A. 2-metylpropen v but-1-en (hoc buten-1).

B. propen v but-2-en (hoc buten-2).

C. eten v but-2-en (hoc buten-2).

D. eten v but-1-en (hoc buten-1).

Cu 5: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp

trn thu
c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng
19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16)
A. C3H8.

B. C3H6.

C. C4H8.

D. C3H4.

Cu 6: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3
cht lng trn l
A. dung dch phenolphtalein.

B. dung dch NaOH.

C. nc brom.

D. giy qu tm

Cu 7: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l
75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80)
A. 3,3-imetylhecxan.

B. isopentan.

C. 2,2-imetylpropan.

D. 2,2,3-trimetylpentan.

Cu 8: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol
X, tng khi lng ca CO2 v H2O thu c l
A. 20,40 gam.

B. 18,96 gam.

C. 16,80 gam.

D. 18,60 gam.

Cu 9: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l

A. 4.

B. 3.

C. 2.

D. 5.

Cu 10: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c
hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn
hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l
A. 1,20 gam.

B. 1,04 gam.

C. 1,64 gam.

D. 1,32 gam

Cu 11: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o
cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l
A. C5H12.

B. C3H8.

C. C4H10.

D. C6H14.

Cu 12: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3,

CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l
A. 3.

B. 2.

C. 1.

D. 4.

Cu 13: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l

~ 69 ~

A. 2.

B. 4.

C. 3.

D. 5.

Cu 14: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong
mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi
cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l
A. 3.

B. 2.

C. 5.

D. 4.

Cu 15: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn
ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th
sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. C2H6 v C3H6.

B. CH4 v C3H6.

C. CH4 v C2H4.

D. CH4 v C3H4.

Cu 16: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng hn t

ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankan.

B. ankin.

C. ankaien.

D. anken.

Cu 17: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi

H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l
A. C2H4.

B. C2H6.

C. C3H8.

D. CH4.

Cu 18: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l

A. xiclohexan.

B. xiclopropan.

C. stiren.

D. etilen.

Cu 19: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c

khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.

B. 0,2 mol C2H4 v 0,1 mol C2H2.

C. 0,1 mol C3H6 v 0,2 mol C3H4.

D. 0,2 mol C3H6 v 0,1 mol C3H4

Cu 20: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th
khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng
d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l
A. 20%.

B. 50%.

C. 25%.

D. 40%.

Cu 21: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi
ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp
kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l
A. CH3-CH=CH-CH3.

B. CH2=CH2.

C. CH2=C(CH3)2.

D. CH2=CH-CH2-CH3.

Cu 22: Dy gm cc cht u c kh nng tham gia phn ng trng hp l:

A. stiren; clobenzen; isopren; but-1-en.
B. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua.
C. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen.
D. buta-1,3-ien; cumen; etilen; trans-but-2-en.
Cu 23: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y
(cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn
gi ca X l
A. but-2-en.

B. xiclopropan.

C. propilen.

D. but-1-en.

Cu 24: un nng hn hp kh X gm 0,02 mol C 2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu
c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh
tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l
A. 0,328.

B. 0,205.

C. 0,620.

D. 0,58

Cu 25: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l

A. 2-etylpent-2-en.

B. 3-etylpent-2-en.

en

~ 70 ~

C. 3-etylpent-3-en.

D. 3-etylpent-1-

Cu 26: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch
Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung
dch Ba(OH)2 ban u. Cng thc phn t ca X l
A. C3H8.

B. C3H6.

C. C3H4.

D. C2H6.

Cu 27: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng 11,25. t chy hon

ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l
A.

CH4 v C4H8.

B. C2H6 v C2H4.

C. CH4 v C2H4.

D. CH4 v C3H6.

Cu 28: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung

nng, thu c hn hp Y gm C 2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh
brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H 2 l 8. Th tch O2 (ktc) cn
t chy hon ton hn hp Y l
A. 33,6 lt.

B. 22,4 lt.

C. 26,88 lt.

D. 44,8 lt.

Cu 29: Cho 13,8 gam cht hu c X c cng thc phn t C 7H8 tc dng vi mt lng d dung dch AgNO3
trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn?
A. 5.

B. 6.

C. 4.

D. 2.

Cu 30: t chy hon ton hn hp X gm C 2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09
mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO 3 trong
NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l:
A. CHC-CH3, CH2=CH-CCH.

B. CHC-CH3, CH2=C=C=CH2.

C. CH2=C=CH2, CH2=CH-CCH.

D. CH2=C=CH2, CH2=C=C=CH2.

Cu 31: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to
v ng phn hnh hc) thu c l
A. 2.

B. 4.

C. 1.

D. 3.

Cu 32: Cho dy chuyn ho sau:

Benzen + ( C2H4, xt, to ) > X + ( Br 2 as t l 1:1 )
(trong X, Y, Z l sn phm chnh).

>

Y ( KOH/ C 2H5OH xt, to )

>

Tn gi ca Y, Z ln lt l
A. 1-brom-1-phenyletan v stiren.

B. 1-brom-2-phenyletan v stiren.

C. 2-brom-1-phenylbenzen v stiren.

D. benzylbromua v toluen.

Cu 33: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5 -COOK + K2CO3 + MnO2 + KOH + H2O.
Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l
A. 24.

B. 34.

C. 27.

D. 31

Cu 34: Cho cc pht biu sau:

(a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO 2 bng s mol H2O th X l
anken.
(b) Trong thnh phn hp cht hu c nht thit phi c cacbon.
(c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr.
(d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau.
(e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh.
(g) Hp cht C9H14BrCl c vng benzen trong phn t.
S pht biu ng l
A. 3.

B. 2.

C. 5.

D. 4.

Cu 35: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H 2 l 17. t chy hon

ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH) 2 (d) th khi lng
bnh tng thm m gam. Gi tr ca m l

~ 71 ~

A. 6,6.

B. 5,85.

C. 7,3.

D. 3,39.

Cu 36: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C 4H10, C4H8, C4H6 v H2. T khi
ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l
A. 0,48 mol.

B. 0,24 mol.

C. 0,36 mol.

D. 0,60 mol.

Cu 37: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l

A. 8.

B. 7.

C. 9.

D. 5.

Cu 38: Hirat ha 5,2 gam axetilen vi xc tc HgSO 4 trong mi trng axit, un nng. Cho ton b cc
cht hu c sau phn ng vo mt lng d dung dch AgNO 3 trong NH3 thu c 44,16 gam kt ta. Hiu
sut phn ng hirat ha axetilen l
A. 80%.

B. 70%.

C. 92%.

D. 60%.

Cu 39: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca
X l
A. 6.

B. 5.

C. 7.

D. 4.

Cu 40: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn
phm chy hp th ht vo bnh ng dung dch Ba(OH) 2. Sau cc phn ng thu c 39,4 gam kt ta v
khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l
A. C3H4

B. CH4.

C. C2H4.

D. C4H10

Cu 41: t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn va 10,5

lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch
hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc
mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l
A. 46,43%

B. 31,58%.

C. 10,88%.

D. 7,89%

Cu 42: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp

Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l
A. 70%.

B. 60%.

C. 50%.

D. 80%.

Cu 43: Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt
mu dung dch brom l
A. 2.

B. 3.

C. 4.

D. 5.

Cu 44: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt
thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch brom d, sau khi
phn ng xy ra hon ton, khi lng brom tham gia phn ng l
A. 24 gam.

B. 16 gam.

C. 0 gam.

D. 8 gam.

Cu 45: t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin
nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l
A. hai ankaien.

B. mt anken v mt ankin.

C. hai anken.

D. mt ankan v mt ankin.

Cu 46: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l
A. 3-metylbutan-2-ol.

B. 3-metylbutan-1-ol

C. 2-metylbutan-2-ol.

D. 2-metylbutan-3-ol.

Cu 47: Trong mt bnh kn cha 0,35 mol C2H2; 0,65 mol H2 v mt t bt Ni. Nung nng bnh mt thi
gian, thu c hn hp kh X c t khi so vi H 2 bng 8. Sc X vo lng d dung dch AgNO 3 trong NH3
n phn ng hon ton, thu c hn hp kh Y v 24 gam kt ta. Hn hp kh Y phn ng va vi bao
nhiu mol Br2 trong dung dch?
A. 0,10 mol.

B. 0,20 mol.

C. 0,25 mol.

Cu 48: iu kin thch hp xy ra cc phn ng sau:

(a) 2C + Ca CaC2

(b) C + 2H2 CH4

(c) C + CO2 2CO

(d) 3C + 4Al Al4C3

Trong cc phn ng trn, tnh kh ca cacbon th hin phn ng

~ 72 ~

D. 0,15 mol

A. (c)

B. (b)

C. (a)

D. (d)

Cu 49: Khi c chiu sng, hirocacbon no sau y tham gia phn ng th vi clo theo t l mol 1 : 1, thu
c ba dn xut monoclo l ng phn cu to ca nhau?
A. isopentan.

B. pentan.

C. neopentan.

D. butan.

Cu 50: Tn thay th (theo IUPAC) ca (CH3)3C-CH2-CH(CH3)2 l

A. 2,2,4-trimetylpentan

B. 2,2,4,4-tetrametylbutan

C. 2,4,4,4-tetrametylbutan

D. 2,4,4-trimetylpentan

Cu 51: Hn hp X gm H2, C2H4 v C3H6 c t khi so vi H2 l 9,25. Cho 22,4 lt X (ktc) vo bnh kn c
sn mt t bt Ni. un nng bnh mt thi gian, thu c hn hp kh Y c t khi so vi H 2 bng 10. Tng s
mol H2 phn ng l
A. 0,070 mol

B. 0,015 mol

C. 0,075 mol

D. 0,050 mol

Cu 52: Hn hp X gm hiro, propen, axit acrylic, ancol anlylic (C 3H5OH). t chy hon ton 0,75 mol X,
thu c 30,24 lt kh CO2 (ktc). un nng X vi bt Ni mt thi gian, thu c hn hp Y. T khi hi ca
Y so vi X bng 1,25. Cho 0,1 mol Y phn ng va vi V lt dung dch Br2 0,1M. Gi tr ca V l
A. 0,6.

B. 0,5.

C. 0,3.

D. 0,4.

Cu 53: Cho 3,36 lt kh hirocacbon X (ktc) phn ng hon ton vi lng d dung dch AgNO 3 trong NH3,
thu c 36 gam kt ta. Cng thc phn t ca X l
A. C4H4.

B. C2H2.

C. C4H6.

D. C3H4.

Cu 54: Trong cc cht: stiren, axit acrylic, axit axetic, vinylaxetilen v butan, s cht c kh nng tham gia
phn ng cng hiro (xc tc Ni, un nng) l
A. 3.

B. 5.

C. 2.

D. 4.

Cu 55: Cho s phn ng: C2H2 X CH3COOH.

Trong s trn mi mi tn l mt phn ng, X l cht no sau y?
A. CH3COONa.

B. C2H5OH.

C. HCOOCH3.

D. CH3CHO

Cu 56 : Hirocacbon no sau y khi phn ng vi dung dch brom thu c 1,2-ibrombutan?

A. But-1-en

B. Butan

C. But-1-in

D. Buta-1,3-ien

Cu 57: un si dung dch gm cht X v KOH c trong C2H5OH , thu c etilen. Cng thc ca X l
A. CH3CH2Cl

B. CH3COOH

C. CH3CHCl2

D. CH3COOCH = CH2

Cu 58: Hn hp kh X gm C2H6, C3H6 v C4H6. T khi ca X so vi H2 bng 24. t chy hon ton 0,96
gam X trong oxi d ri cho ton b sn phm chy vo 1 lt dung dch Ba(OH)2 0,05M. Sau khi cc phn ng
xy ra hon ton, thu c m gam kt ta . Gi tr ca m l
A. 9,85.

B. 5,91.

C. 13,79.

D. 7,88.

Cu 59: Trng hp m tn etilen thu c 1 tn polietilen (PE) vi hiu sut phn ng bng 80%. Gi tr ca m
l
A. 1,80.

B. 2,00.

C. 0,80.

D. 1,25.

Cu 60: S ng phn cu to, mch h ng vi cng thc phn t C4H6 l

A. 2.

B. 5.

C. 4.

D. 3.

Cu 61: Cho 27,2 gam ankin X tc dng vi 15,68 lt kh H2 (ktc) c xc tc thch hp, thu c hn hp Y
(khng cha H2). Bit Y phn ng ti a vi dung dch cha 16 gam Br2. Cng thc phn t ca X l
A. C4H6.

B. C3H4.

C. C2H2.

D. C5H8.

Cu 62: Cht no di y khi phn ng vi HCl thu c sn phm chnh l 2-clobutan?

A. But-1-en.

B. Buta-1,3-ien.

~ 73 ~

C. But-2-in.

D. But-1-in.

ANCOL - PHENOL
Cu 1: Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi
9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = 23)
A. C3H5OH v C4H7OH.

B. C2H5OH v C3H7OH.

C. C3H7OH v C4 H9OH.

D. CH3OH v C2H5OH

Cu 2: Cho s
+ Cl 2 (1:1)
+ NaOH, du
+ HCl
C6 H 6
X
Y
Z Hai cht hu c Y, Z ln lt l:
Fe, t o
t o cao,P cao

A. C6H6(OH)6, C6H6Cl6.

B. C6H4(OH)2, C6H4Cl2.

C. C6H5OH, C6H5Cl.

D. C6H5ONa, C6H5OH.

Cu 3: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca
nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l
A. (CH3)3COH.

B. CH3OCH2CH2CH3.

C. CH3CH(OH)CH2CH3.

D. CH3CH(CH3)CH2OH.

Cu 4: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit
rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l (cho C =12, O = 16)
A. HOCH2C6H4COOH.

B. C6H4(OH)2.

C. HOC6H4CH2OH.

D. C2H5C6H4OH.

Cu 5: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng
hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l
15,5. Gi tr ca m l (cho H = 1, C =12, O = 16)
A. 0,64.

B. 0,46.

C. 0,32.

D. 0,92

Cu 6: S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi

dung dch NaOH l
A. 3.

B. 1.

C. 4.

D. 2..

Cu 7: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi
nc v 6,6 gam CO2. Cng thc ca X l (cho C = 12, O = 16)
A. C3H7OH.

B. C3H6(OH)2.

C. C3H5(OH)3.

D. C2H4(OH)2.

Cu 8: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch
nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn
ng vi cng thc phn t C8H10O, tho mn tnh cht trn l
A. 2.

B. 4.

C. 1.

D. 3.

Cu 9: Dy gm cc cht u phn ng vi phenol l:

A. nc brom, anehit axetic, dung dch NaOH.
B. dung dch NaCl, dung dch NaOH, kim loi Na.
C. nc brom, axit axetic, dung dch NaOH.
D. nc brom, anhirit axetic, dung dch NaOH
Cu 10: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc
dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l
13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh
ra 64,8 gam Ag. Gi tr ca m l
A. 9,2.

B. 7,8.

C. 7,4.

D. 8,8.

Cu 11: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu: tng khi lng ca
cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l
A. 2.

B. 3.

C. 4.

~ 74 ~

D. 1.

Cu 12: Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l
A. 2-metylbuten-3 (hay 2-metylbut-3-en).

B. 2-metylbuten-2 (hay 2-metylbut-2-en).

C. 3-metylbuten-2 (hay 3-metylbut-2-en).

D. 3-metylbuten-1 (hay 3-metylbut-1-en).

Cu 13: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi

H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc.
Cng thc phn t ca hai ru trn l
A. CH3OH v C2H5OH

B. C3H7OH v C4H9OH.

C. C3H5OH v C4H7OH.

D. C2H5OH v C3H7OH.

Cu 14: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol
vi
A. Na kim loi.

B. H2 (Ni, nung nng).

C. dung dch NaOH.

D. nc Br2.

Cu 15: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X
(gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung
dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 70,4%.

B. 65,5%.

C. 76,6%.

D. 80,0%.

Cu 16: Cho s chuyn ho sau:

0

+ Br2 (1:1mol),Fe,t
+ NaOH (d ),t ,p
+ HCl(d)
Toluen
X
Y
Z

Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm

A. o-bromtoluen v p-bromtoluen.

B. benzyl bromua v o-bromtoluen.

C. m-metylphenol v o-metylphenol.

D. o-metylphenol v p-metylphenol.

Cu 17: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp
sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l
A. C4H8O.

B. CH4O.

C. C2H6O.

D. C3H8O

Cu 18: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn
hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
A. C3H5(OH)3 v C4H7(OH)3.

B. C2H5OH v C4H9OH.

C. C2H4(OH)2 v C4H8(OH)2.

D. C2H4(OH)2 v C3H6(OH)2.

Cu 19: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht

X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm
ng vi cng thc phn t ca X l
A. 3.

B. 6.

C. 4.

D. 5.

Cu 20: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 (
ktc) v a gam H2O. Biu thc lin h gia m, a v V l:
A. m = 2a V/22,4.

B. m = 2a V/11,2.

C. m = a + V/5,6.

D. m = a V/5,6

Cu 21: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng
vi dung dch NaHCO3. Tn gi ca X l
A. anilin.

B. phenol.

C. axit acrylic.

D. metyl axetat

Cu 22: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly

7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O.
Hai ancol l
A. C2H5OH v CH2=CH-CH2-OH.

B. C2H5OH v CH3OH.

C. CH3OH v C3H7OH.

D. CH3OH v CH2=CH-CH2-OH.

Cu 23: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc,
nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca
m v tn gi ca X tng ng l
A. 9,8 v propan-1,2-iol.

B. 4,9 v propan-1,2-iol.

~ 75 ~

C. 4,9 v propan-1,3-iol.

D. 4,9 v glixerol.

Cu 24: Cho cc hp cht sau:

(a) HOCH2-CH2OH. (b) HOCH2-CH2-CH2OH.
(c) HOCH2-CH(OH)-CH2OH. (d) CH3-CH(OH)-CH2OH.
(e) CH3-CH2OH. (f) CH3-O-CH2CH3.
Cc cht u tc dng c vi Na, Cu(OH)2 l:
A. (a), (c), (d).

B. (c), (d), (f).

C. (a), (b), (c).

D. (c), (d), (e).

Cu 25: Cho s chuyn ho:

H 2SO 4 c
+ HBr
+ Mg, etekhan
Butan - 2 - ol
X(anken)
Y
Z
to

Trong X, Y, Z l sn phm chnh. Cng thc ca Z l

A. (CH3)2CH-CH2-MgBr.

B. CH3-CH(MgBr)-CH2-CH3.

C. (CH3)3C-MgBr.

D. CH3-CH2-CH2 -CH2-MgBr

Cu 26: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon
ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm
hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca
m l
A. 13,5.

B. 8,1.

C. 8,5.

D. 15,3

Cu 27: Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO. Cho ton
b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol
l:
A. C2H5OH, C3H7CH2OH.

B. CH3OH, C2H5OH.

C. C2H5OH, C2H5CH2OH.

D. CH3OH, C2H5CH2OH.

Cu 28: t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c 3,808 lt
kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l
A. 5,42.

B. 7,42.

C. 5,72.

D. 4,72.

Cu 29: Trong s cc pht biu sau v phenol (C6H5OH):

(1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl.
(2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm.
(3) Phenol dng sn xut keo dn, cht dit nm mc.
(4) Phenol tham gia phn ng th brom v th nitro d hn benzen.
Cc pht biu ng l:
A. (1), (3), (4).

B. (1), (2), (3).

C. (2), (3), (4).

D. (1), (2), (4).

Cu 30: Cho s chuyn ho:

0

dung dich Br2

O2 , xt
NaOH
CH 3OH ,t , xt
CuO ,t
X
Y

T
Z
E (Este a chc).
C3H6

Tn gi ca Y l
A. propan-2-ol.

B. glixerol.

C. propan-1,3-iol.

D. propan-1,2-iol.

Cu 31: Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol
th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l
A. CH3-CH2-CH2-OH.

B. CH3-CH(OH)-CH3.

C. CH3-CH2-CH2-CH2-OH.

D. CH3-CH2-CH(OH)-CH3

Cu 32: t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm
-OH) cn va V lt kh O 2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi tr
ca V l

~ 76 ~

A. 11,20.

B. 14,56.

C. 4,48.

D. 15,68.

Cu 33: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23.

Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn
hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng
d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l
A. 16,3%.

B. 65,2%.

C. 48,9%.

D. 83,7%.

Cu 34: Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy
ra hon ton, thu c x mol hn hp kh gm: CO2 , CO, N2 v H2. Gi tr ca x l
A. 0,45.

B. 0,60.

C. 0,36.

D. 0,54

Cu 35: Pht biu no sau y ng?

A. Khi un C2H5Br vi dung dch KOH ch thu c etilen.
B. un ancol etylic 14o0C (xc tc H2SO4 c) thu c imetyl ete.
C. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng.
D. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi
Cu 36: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H 2
(xc tc Ni, to )?
A. 2.

B. 5.

C. 4.

D. 3.

Cu 37: Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4metylphenol; (6) -naphtol. Cc cht thuc loi phenol l:
A. (1), (3), (5), (6).

B. (1), (4), (5), (6).

C. (1), (2), (4), (5).

D. (1), (2), (4), (6).

Cu 38: t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c
8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H 2SO4 c th tng khi lng
ete ti a thu c l
A. 6,50 gam.

B. 7,85 gam.

C. 7,40 gam.

D. 5,60 gam.

+ H 2O
+ Br2
+ CuO
X
Y
Z
Cau 39: Cho s phn ng: Stiren
H + ,t 0
t0
H+

Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l:

A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br.
B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH.
C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH
D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3.
Cu 40: Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong
X, t l khi lng cc nguyn t l m C: mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu
c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha
mn cc tnh cht trn?
A. 3.

B. 9.

C. 7.

D. 10.

Cu 41: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic,
natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l
A. 3.

B. 4.

C. 6.

D. 5.

Cu 42: Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k

tip thnh hai phn bng nhau:
- t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O.
- un nng phn 2 vi H2SO4 c 140oC to thnh 1,25 gam hn hp ba ete. Ho hi hon ton hn hp ba
ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut).
Hiu sut phn ng to ete ca X, Y ln lt l
A. 20% v 40%.

B. 40% v 20%.

C. 25% v 35%.

~ 77 ~

D. 30% v 30%.

Cu 43: Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H 2SO4 c thu c anken Y.
Phn t khi ca Y l
A. 56.

B. 70.

C. 28.

D. 42.

Cu 44: Cho cc pht biu sau v phenol (C6H5OH):

(a) Phenol tan nhiu trong nc lnh.
(b) Phenol c tnh axt nhng dung dch phenol trong nc khng lm i mu qu tm.
(c) Phenol c dng sn xut phm nhum, cht dit nm mc.
(d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen.
(e) Cho nc brom vo dung dch phenol thy xut hin kt ta.
S pht biu ng l
A. 5.

B. 2.

C. 3.

D. 4

Cu 45: Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5, p-HO-C6H4-COOH, pHCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin sau?
(a) Ch tc dng vi NaOH theo t l mol 1 : 1.
(b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng.
A. 3.

B. 4.

C. 1.

D. 2.

Cu 46: t chy hon ton mt lng ancol X to ra 0,4 mol CO 2 v 0,5 mol H2O. X tc dng vi Cu(OH)2
to ra dung dch mu xanh lam. Oxi ha X bng CuO to hp cht hu c a cht Y. Nhn xt no sau y
ng vi X?
A. X lm mt mu nc brom.
B. Trong X c hai nhm OH lin kt vi hai nguyn t cacbon bc hai.
C. Trong X c ba nhm CH3.
D. Hirat ha but-2-en thu c X.
Cu 47: Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic, mt anehit,
ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc dng ht vi Na
d, thu c 0,504 lt kh H2 (ktc). Phn hai cho phn ng trng bc hon ton thu c 9,72 gam Ag. Phn
trm khi lng ancol b oxi ho l
A. 31,25%.

B. 62,50%.

C. 40,00%.

D. 50,00%.

Cu 48: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu
c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H2 (ktc).
Gi tr ca V l
A. 6,72.

B. 11,20.

C. 5,60.

D. 3,36.

Cu 49: t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml kh O2, thu

c 160 ml hn hp Y gm kh v hi. Dn Y qua dung dch H2SO4 c (d), cn li 80 ml kh Z. Bit cc
th tch kh v hi o cng iu kin. Cng thc phn t ca X l
A. C4H10O.

B. C4H8O2.

C. C4H8O.

D. C3H8O

Cu 50: C bao nhiu cht cha vng benzen c cng cng thc phn t C7H8O?
A. 3.

B. 6.

C. 4.

D. 5.

Cu 51: t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt kh CO2 (ktc) v 15,3
gam H2O. Mt khc, cho m gam X tc dng vi Na (d), thu c 4,48 lt kh H2 (ktc). Gi tr
ca m l
A. 12,9.

B. 15,3.

C. 16,9.

~ 78 ~

D. 12,3.

ANHIT- XETON
Cu 1 (H A/07): Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc
Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24
lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16)
A. CH3CHO.

B. HCHO.

C. CH3CH2CHO.

D. CH2 = CHCHO

Cu 2 (H A/07): Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch
NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6
gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108)
A. HCHO.

B. CH3CHO.

C. OHC-CHO.

D. CH3CH(OH)CHO

Cu 3 (H B/07): Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong
dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l
A. HCHO.

B. CH3CHO.

C. CH2=CH-CHO.

D. OHC-CHO.

Cu 4 (H B/07): Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l

A. CH3CH2OH v CH2=CH2.

B. CH3CH2OH v CH3CHO.

C. CH3CHO v CH3CH2OH.

D. CH3CH(OH)COOH v CH3CHO.

Cu 5 (H A/08): un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy

ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit
, p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z
phn ng. Cht X l anehit
A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc.
C. no, n chc.

D. khng no (cha mt ni i C=C), n chc.

Cu 6 (H A/08): Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng
ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi
so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch
NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l
A. 7,8.

B. 8,8.

C. 7,4.

D. 9,2.

Cu 7 (H A/08): Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc
AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch
HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l
A. C3H7CHO.

B. HCHO.

C. C4H9CHO.

D. C2H5CHO.

Cu 8 (H B/08) : Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn
phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc
AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 76,6%.

B. 80,0%.

C. 65,5%.

D. 70,4%.

Cu 9 (C 08): Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc
AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l
A. 21,6 gam.

B. 10,8 gam.

C. 43,2 gam.

D. 64,8 gam.

Cu 10 (C 08): t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc
dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X
phn ng. Cng thc ca X l
A. HCHO.

B. (CHO)2.

C. CH3CHO.

D. C2H5CHO.

Cu 11(C 08): Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3.

~ 79 ~

S cht trong dy tham gia phn ng trng gng l

A. 6.

B. 4.

C. 5.

D. 3.

Cu 12(C 08): Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht
l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l
A. CH3-CHOH-CH3.

B. CH3-CH2-CH2-OH.

C. CH3-CH2-CHOH-CH3.

D. CH3-CO-CH3.

Cu 13 (H A/09): Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi

phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7
gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l
A. 46,15%.

B. 35,00%.

C. 53,85%.

D. 65,00%.

Cu 14 (H A/09): Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong
o
NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t ) th 0,125 mol X phn
ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l
A. CnH2n(CHO)2 (n 0).

B. CnH2n+1CHO (n 0).

C. CnH2n-1CHO (n 2).

D. CnH2n-3CHO (n 2).

Cu 15 (C A/09): Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong
dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag.
Hai anehit trong X l
A. HCHO v C2H5CHO.

B. HCHO v CH3CHO.

C. C2H3CHO v C3H5CHO.

D. CH3CHO v C2H5CHO.

Cu 16 (C A/09): Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k

tip nhau trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M
l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln
lt l
A. HCHO v 50,56%.

B. CH3CHO v 67,16%.

C. CH3CHO v 49,44%.

D. HCHO v 32,44%.

Cu 17 (H B/09): Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip
nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng
m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 17,8.

B. 24,8.

C. 10,5.

D. 8,8.

Cu 18 (H B/09): Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi
ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn
phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi
tr ca m l
A. 15,3.

B. 13,5.

C. 8,1.

D. 8,5.

Cu 19 (H A/10): Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO.
Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76 gam Ag.
Hai ancol l:
A. CH3OH, C2H5CH2OH.
C. C2H5OH, C3H7CH2OH.

B. CH3OH, C2H5OH.
D. C2H5OH, C2H5CH2OH.

Cu 20 (H A/10): Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch
AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c.
Gi tr ca m l
A. 9,5.

B. 10,9.

C. 14,3.

D. 10,2.

Cu 21 (C B/10): Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu c
X. Tn gi ca X l

~ 80 ~

A. metyl phenyl xeton.

B. metyl vinyl xeton.

C. imetyl xeton.

D. propanal.

Cu 22 (H B/10): Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s

mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2
gam H2O. Hirocacbon Y l
A. CH4.

B. C2H2.

C. C3H6.

D. C2H4.

Cu 23 (H A/11): t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong
cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong
NH3 th thu c 0,04 mol Ag. X l
A. anehit no, mch h, hai chc.

B. anehit khng no, mch h, hai chc.

C. anehit axetic.

D. anehit fomic.

Cu 24 (H A/11): Pht biu no sau y v anehit v xeton l sai?

A. Axetanehit phn ng c vi nc brom.
B. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn.
C. Axeton khng phn ng c vi nc brom.
D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn.
Cu 25 (H B/11): hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam,
cn1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO3
trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l
A. CH2=C(CH3)-CHO v OHC-CHO.

B. OHC-CH2-CHO v OHC-CHO.

C. H-CHO v OHC-CH2-CHO.

D. CH2=CH-CHO v OHC-CH2-CHO.

Cu 26 (H B/11): Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z).

Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc,
thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c
0,784 lt CO2 (ktc). Tn ca Z l
A. anehit acrylic.

B. anehit butiric.

C. anehit propionic.

D. anehit axetic.

Cu 27 (H B/11): X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u

c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y
c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt
H2 (ktc). Gi tr ln nht ca V l
A. 22,4.

B. 13,44.

C. 5,6.

D. 11,2.

Cu 28 (H A/12): Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un nng. Cho
ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO3 trong NH3 thu c 44,16 gam
kt ta. Hiu sut phn ng hirat ha axetilen l
A. 60%.

B. 80%.

C. 92%.

D. 70%.

Cu 29 (H B/12): Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic,

mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc
dng ht vi Na d, thu c 0,504 lt kh H2 (ktc). Phn hai cho phn ng trng bc hon ton thu c
9,72 gam Ag. Phn trm khi lng ancol b oxi ho l
A. 50,00%.

B. 62,50%.

C. 31,25%.

~ 81 ~

D. 40,00%.

AXIT CACBOXYLIC
Cu 1: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam
mui ca axit hu c. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; O = 16; Ca = 40)
A. CH2=CH-COOH.

B. CH3COOH.

C. HCC-COOH.

D. CH3-CH2-COOH.

Cu 2: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti
trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16)
A. 55%.

B. 50%.

C. 62,5%.

D. 75%.

Cu 3: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc

dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l
A. 2.

B. 5.

C. 4.

D. 3.

Cu 4: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu
c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l
A. 8,96.

B. 11,2.

C. 6,72.

D. 4,48.

Cu 5: Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl ete (T). Dy gm
cc cht c sp xp theo chiu tng dn nhit si l
A. T, Z, Y, X.

B. Z, T, Y, X.

C. T, X, Y, Z.

D. Y, T, X, Z.

Cu 6: trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch
NaOH 2,24%. Cng thc ca Y l (cho H = 1, C = 12, O = 16, Na = 23)
A. CH3COOH.

B. HCOOH.

C. C2H5COOH.

D. C3H7COOH.

Cu 7: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3)
trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l
A. 43,2 gam.

B. 10,8 gam.

C. 64,8 gam.

D. 21,6 gam.

Cu 8: Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH
1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng
th thu c 21,6 gam Ag. Tn gi ca X l
A. axit acrylic.

B. axit propanoic.

C. axit etanoic.

D. axit metacrylic.

Cu 9: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A.

CH3CHO, C2H5OH, C2H5COOCH3.
B. CH3CHO, C6H12O6 (glucoz), CH3OH. C.
CH3OH, C2H5OH, CH3CHO.
D. C2H4(OH)2, CH3OH, CH3CHO.
Cu 10: Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht
c sp xp theo tnh axit tng dn (t tri sang phi) l:
A. (T), (Y), (X), (Z).

B. (X), (Z), (T), (Y).

C. (Y), (T), (Z), (X).

D. (Y), (T), (X), (Z).

Cu 11: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na; X
tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X
v Y ln lt l
A. C2H5COOH v HCOOC2H5.

B. HCOOC2H5 v HOCH2COCH3.

C. HCOOC2H5 v HOCH2CH2CHO.

D. C2H5COOH v CH3CH(OH)CHO.

Cu 12: t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH3, CH3OH thu
c
2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X phn ng va vi 30 ml dung
dch NaOH 1M, thu c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l

~ 82 ~

A. C3H5COOH.

B. CH3COOH.

C. C2H3COOH.

D. C2H5COOH.

Cu 13: Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton
vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c
31,1 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l
A. C2H4O2 v C3H4O2.

B. C2H4O2 v C3H6O2.

C. C3H4O2 v C4H6O2.

D. C3H6O2 v C4H8O2.

Cu 14: Hai cht X v Y c cng cng thc phn t C2H4O2. Cht X phn ng c vi kim loi Na v
tham gia phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO3. Cng
thc ca X, Y ln lt l:
A. CH3COOH, HOCH2CHO.

B. HCOOCH3, HOCH2CHO.

C. HCOOCH3, CH3COOH.

D. HOCH2CHO, CH3COOH.

Cu 15: Axit cacboxylic X c cng thc n gin nht l C3H5O2. Khi cho 100 ml dung dch axit X nng
0,1M phn ng ht vi dung dch NaHCO3 (d), thu c V ml kh CO2 (ktc). Gi tr ca V l
A. 448.

B. 224.

C. 112.

D. 336.

Cu 16: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng
vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng
este ho u bng 80%). Gi tr ca m l (cho H = 1, C = 12, O = 16)
A. 10,12.

B. 6,48.

C. 8,10.

D. 16,20.

Cu 17: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y
cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l
A. HOOC-CH2-CH2-COOH.

B. C2H5-COOH.

C. CH3-COOH.

D. HOOC-COOH.

Cu 18: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng
ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li)
A. y = 100x.

B. y = 2x.

C. y = x - 2.

D. y = x + 2.

Cu 19: Cho s chuyn ho sau:

C3H4O2 + NaOH X + Y
X + H2SO4 long Z + T
Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l:
A. HCHO, CH3CHO.

B. HCHO, HCOOH.

C. CH3CHO, HCOOH.

D. HCOONa, CH3CHO.

Cu 20: Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch
NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l
A. 8,64 gam.

B. 6,84 gam.

C. 4,90 gam.

D. 6,80 gam.

Cu 21: Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t
ca X l
A. C6H8O6.

B. C3H4O3.

C. C12H16O12.

D. C9H12O9.

Cu 22: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH
0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn
t ca X l
A. C2H5COOH.

B. CH3COOH.

C. HCOOH.

D. C3H7COOH.

Cu 43: Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn
hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH
1M. Hai axit l:

~ 83 ~

A. HCOOH, HOOC-COOH.

B. HCOOH, HOOC-CH2-COOH.

C. HCOOH, C2H5COOH.

D. HCOOH, CH3COOH.

Cu 24: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l:

A. CH3COOH, C2H5OH, HCOOH, CH3CHO. B. CH3CHO, C2H5OH, HCOOH, CH3COOH.
C. CH3COOH, HCOOH, C2H5OH, CH3CHO. D. HCOOH, CH3COOH, C2H5OH, CH3CHO.
Cu 25: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia
X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy
hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z
trong hn hp X ln lt l
A. HOOC-CH2-COOH v 70,87%.

B. HOOC-CH2-COOH v 54,88%.

C. HOOC-COOH v 60,00%.

D. HOOC-COOH v 42,86%.

Cu 26: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn

ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va
40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l
A. 0,56 gam.

B. 1,44 gam.

C. 0,72 gam.

D. 2,88 gam.

o
Cu 27: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 C, Ka
-5
o
ca CH3COOH l 1,75.10 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 C l
A. 1,00.

B. 4,24.

C. 2,88.

D. 4,76.

Cu 28: Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi
kim c tng khi lng l 15,8 gam. Tn ca axit trn l
A. axit propanoic.

B. axit etanoic.

C. axit metanoic.

D. axit butanoic.

Cu 29: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy
ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c H2SO4
c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi
thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l
A. C3H7COOH v C4H9COOH.

B. CH3COOH v C2H5COOH.

C. C2H5COOH v C3H7COOH.

D. HCOOH v CH3COOH.

Cu 30: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml

dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc)
v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l
A. 0,015.

B. 0,010.

C. 0,020.

D. 0,005.

Cu 31: Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu

kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng
ngng. Cc cht X v Y ln lt l
A. vinylamoni fomat v amoni acrylat.
B. amoni acrylat v axit 2-aminopropionic.
C. axit 2-aminopropionic v amoni acrylat.
D. axit 2-aminopropionic v axit 3-aminopropionic.
Cu 32: Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam.
Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu
cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v
phn trm khi lng ca X trong Z l
A. C3H5COOH v 54,88%.

B. C2H3COOH v 43,90%.

C. C2H5COOH v 56,10%.

D. HCOOH v 45,12%.

~ 84 ~

o
Cu 33: Dy gm cc cht u tc dng vi H2 (xc tc Ni, t ), to ra sn phm c kh nng phn
ng vi Na l:
A. C2H3CH2OH, CH3COCH3, C2H3COOH. B. C2H3CHO, CH3COOC2H3, C6H5COOH.
C. C2H3CH2OH, CH3CHO, CH3COOH.

D. CH3OC2H5, CH3CHO, C2H3COOH.

Cu 44: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este

Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra
16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l
A. HCOOH v CH3OH.

B. CH3COOH v CH3OH.

C. HCOOH v C3H7OH.

D. CH3COOH v C2H5OH.

Cu 35: Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng?
A. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4.
B. in li ca axit fomic s gim khi thm dung dch HCl.
C. Khi pha long dung dch trn th in li ca axit fomic tng.
D. in li ca axit fomic trong dung dch trn l 14,29%.
Cu 34: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi
NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt
kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l
A. 0,2.

B. 0,3.

C. 0,6.

D. 0,8.

Cu 37: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic,
ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v
dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no?
A. Gim 7,38 gam.

B. Tng 2,70 gam.

C. Tng 7,92 gam.

D. Gim 7,74 gam.

Cu 40: Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit
axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi
43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l
A. 0,72.

B. 0,24.

C. 0,48.

D. 0,96.

Cu 44: Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln

hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong cng iu kin nhit
, p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2 (ktc). Cng thc
cu to ca X, Y ln lt l
A. H-COOH v HOOC-COOH.

B. CH3-COOH v HOOC-CH2-CH2-COOH.

C. CH3-CH2-COOH v HOOC-COOH.

D. CH3 -COOH v HOOC-CH2 -COOH.

Cu 44: Ho hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln

hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o trong cng iu kin nhit
, p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2 (ktc). Cng thc
cu to ca X, Y ln lt l
A. H-COOH v HOOC-COOH.

B. CH3-COOH v HOOC-CH2-CH2-COOH.

C. CH3-CH2-COOH v HOOC-COOH.

D. CH3 -COOH v HOOC-CH2 -COOH.

2011
Cu 45: Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau
khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc
ca X l
A. CH3COOCH=CH2. B. CH3COOC2H5. C. C2H5COOCH3.

D. CH2=CHCOOCH3

Cu 46: Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l:

~ 85 ~

A. HCOOH, CH3COOH, CH3CH2COOH.

B. CH3COOH, CH2ClCOOH, CHCl2COOH.

C. CH3COOH, HCOOH, (CH3)2CHCOOH.

D. C6H5OH, CH3COOH, CH3CH2OH.

2012
Cu 47: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht
vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt O2
(ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l
A. 1,62.

B. 1,44.

C. 3,60.

D. 1,80.

Cu 48: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt
ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO2 v
0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam
este. Gi tr ca m l
A. 8,16.

B. 4,08.

C. 2,04.

D. 6,12.

Cu 49: Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt axit no, a chc Y (c
mch cacbon h, khng phn nhnh) thu c mt th tch hi bng th tch ca 2,8 gam N2 (o trong
cng iu kin nhit , p sut). t chy hon ton 8,64 gam hn hp hai axit trn thu c 11,44 gam
CO2. Phn trm khi lng ca X trong hn hp ban u l
A. 72,22%.

B. 27,78%.

C. 35,25%.

D. 65,15%.

Cu 50: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c
dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m
gam mui. Gi tr ca m l
A. 44,65.

B. 50,65.

C. 22,35.

D. 33,50.

Cu 51: Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol X cn 0,24 mol O2, thu
c CO2 v 0,2 mol H2O. Cng thc hai axit l
A. HCOOH v C2H5COOH.

B. CH2=CHCOOH v CH2=C(CH3)COOH.

C. CH3COOH v C2H5COOH.

D. CH3COOH v CH2=CHCOOH.

Cu 52: Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t
C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l
A. 3.

B. 2.

C. 4.

~ 86 ~

D. 1.

ESTE - LIPIT
Cu 1: Mnh khng ng l:
A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3.
B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui.
C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2.
D. CH3CH2COOCH=CH2 c th trng hp to polime.
Cu 2: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai
loi axit bo l (cho H = 1, C = 12, O = 16)
A. C15H31COOH v C17H35COOH.

B. C17H33COOH v C15H31COOH.

C. C17H31COOH v C17H33COOH.

D. C17H33COOH v C17H35COOH

Cu 3: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon
ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23)
A. 8,56 gam.

B. 3,28 gam.

C. 10,4 gam.

D. 8,2 gam.

Cu 4: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit.
Cng thc cu to thu gn ca este l
A. CH2=CH-COO-CH3.

B. HCOO-C(CH3)=CH2.

C. HCOO-CH=CH-CH3.

D. CH3COO-CH=CH2

Cu 5: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi:
Na, NaOH, NaHCO3. S phn ng xy ra l
A. 2.

B. 3.

C. 5.

D. 4.

Cu 6: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung

dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1, C =12, O = 16, Na
= 23)
A. HCOOCH2CH2CH3.

B. HCOOCH(CH3)2.

C. C2H5COOCH3.

D. CH3COOC2H5

Cu 7: Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng
bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C =
12, N = 14, O = 16)
A. C2H5COOCH3 v HCOOCH(CH3)2.

B. HCOOC2H5 v CH3COOCH3.

C. C2H3COOC2H5 v C2H5COOC2H3.

D. HCOOCH2CH2CH3 v CH3COOC2H5

Cu 8: Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol
(ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l
A. 6.

B. 4.

C. 5.

D. 3.

Cu 9: Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y.
T X c th iu ch trc tip ra Y. Vy cht X l
A. ru metylic.

B. etyl axetat.

C. axit fomic.

D. ru etylic.

Cu 10: Este X c cc c im sau:

- t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;
- Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t
cacbon bng mt na s nguyn t cacbon trong X).
Pht biu khng ng l:
A. Cht X thuc loi este no, n chc.
B. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O.

~ 87 ~

C. Cht Y tan v hn trong nc.

D. un Z vi dung dch H2SO4 c 170oC thu c anken.
Cu 11: S ng phn este ng vi cng thc phn t C4H8O2 l
A. 6.

B. 5.

C. 2.

D. 4.

Cu 12: Pht biu ng l:

A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch.
B. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu.
C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ru (ancol).
D. Khi thy phn cht bo lun thu c C2H4(OH)2.
Cu 13: Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2,
CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l
A. 4.

B. 2.

C. 3.

D. 5.

Cu 14: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn
ng. Tn gi ca este l
A. etyl axetat.

B. metyl axetat.

C. metyl fomiat.

D. n-propyl axetat.

Cu 15: Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi
100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn
ca X l
A. CH3COO(CH2)2OOCC2H5.
C. CH3OOCCH2COOC3H7.

B. CH3OOC(CH2)2COOC2H5.
D. CH3COO(CH2)2COOC2H5.

Cu 16: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn
ng thu c khi lng x phng l
A. 17,80 gam.

B. 18,24 gam.

C. 16,68 gam.

D. 18,38 gam.

Cu 17: X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui
ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este
l
A. CH3COOCH3 v CH3COOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.

B. C2H5COOCH3 v C2H5COOC2H5.
D. HCOOCH3 v HCOOC2H5

Cu 18: X phng ha hon ton 66,6 gam hn hp hai este HCOOC 2H5 v CH3COOCH3 bng dung dch
NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H 2SO4 c 140 oC, sau khi phn ng
xy ra hon ton thu c m gam nc. Gi tr ca m l
A. 4,05.

B. 8,10.

C. 18,00.

D. 16,20.

Cu 19: X phng ho mt hp cht c cng thc phn t C 10H14O6 trong dung dch NaOH (d), thu c
glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l:
A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
B. HCOONa, CHC-COONa v CH3-CH2-COONa.
C. CH2=CH-COONa, HCOONa v CHC-COONa.
D. CH3-COONa, HCOONa v CH3-CH=CH-COONa.
Cu 20: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit
C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO 3 trong NH3 to ra kt
ta l
A. 3.

B. 4.

C. 5.

D. 2.

Cu 21: Cht hu c X c cng thc phn t C 5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH,
thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l
A. HCOOC(CH3)=CHCH3.
C. HCOOCH2CH=CHCH3.

B. CH3COOC(CH3)=CH2.
D. HCOOCH=CHCH2CH3

~ 88 ~

Cu 22: Cho cc hp cht hu c:

(1) ankan; (2) ancol no, n chc, mch h;
(3) xicloankan; (4) ete no, n chc, mch h;
(5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h;
(7) ankin; (8) anehit no, n chc, mch h;
(9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc.
Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l:
A. (2), (3), (5), (7), (9).

B. (1), (3), (5), (6), (8).

C. (3), (4), (6), (7), (10).

D. (3), (5), (6), (8), (9).

Cu 23: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va
3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt
mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C3H6O2 v C4H8O2.

B. C2H4O2 v C5H10O2.

C. C2H4O2 v C3H6O2.

D. C3H4O2 v C4H6O2.

Cu 24: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong
NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O 2 (cng iu kin v nhit v p
sut). Khi t chy hon ton 1 gam X th th tch kh CO 2 thu c vt qu 0,7 lt ( ktc). Cng thc cu
to ca X l
A. HCOOC2H5.

B. OCH-CH2-CH2OH.

C. CH3COOCH3.

D. HOOC-CHO.

Cu 25: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH
0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn,
sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) th khi lng bnh tng 6,82 gam.
Cng thc ca hai hp cht hu c trong X l
A. CH3COOH v CH3COOC2H5

B. C2H5COOH v C2H5COOCH3.

C. HCOOH v HCOOC3H7.

D. HCOOH v HCOOC2H5.

Cu 26: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so
vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu
c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 26,25.

B. 27,75.

C. 24,25.

D. 29,75

Cu 27: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c
mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l
A. C2H5COOH v C3H7COOH.

B. HCOOH v C2H5COOH.

C. HCOOH v CH3COOH.

D. CH3COOH v C2H5COOH

Cu 28: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l

A. 4.

B. 1.

C. 2.

D. 3.

Cu 29: Cho s chuyn ho:

0

+ HCl
+ H 2 du ( Ni ,t )
+ NaOH du ,t
Z. Tn ca Z l
X
Y
Triolein

A. axit stearic.

B. axit panmitic.

C. axit oleic.

D. axit linoleic

Cu 30: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th
tch kh CO2 bng 6/7 th tch kh O 2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc
dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht
rn khan. Gi tr ca m l
A. 8,88.

B. 10,56.

C. 6,66.

D. 7,20.

Cu 31: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C 5H10O2, phn ng c
vi dung dch NaOH nhng khng c phn ng trng bc l

~ 89 ~

A. 4.

B. 5.

C. 8.

D. 9.

Cu 32: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (M X < MY). Bng mt phn
ng c th chuyn ho X thnh Y. Cht Z khng th l
A. metyl propionat.

B. metyl axetat.

C. etyl axetat.

D. vinyl axetat.

Cu 33: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh
nng lm mt mu nc brom l
A. 3.

B. 5.

C. 4.

D. 6.

Cu 34: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc
c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l
A. C2H5OCO-COO CH3.

B. CH3OCO- CH2- CH2-COO C2H5.

C. CH3OCO- CH2-COO C2H5.

D. CH3OCO-COO C3H7

Cu 35: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z

c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam
mui v 8,05 gam ancol. Cng thc ca X v Y l
A. CH3COOH v C2H5OH.

B. CH3COOH v CH3OH.

C. HCOOH v C3H7OH.

D. HCOOH v CH3OH.

Cu 36: Hp cht hu c mch h X c cng thc phn t C 5H10O. Cht X khng phn ng vi Na, tho mn
s chuyn ho sau:
+ H2
+ CH 3COOH
X
Y

H 2 SOa
Ni , t 0
4, c

Este c mi mui chn. Tn ca X l

A. 2,2-imetylpropanal.

B. 3-metylbutanal.

C. pentanal.

D. 2-metylbutanal.

Cu 37: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s
nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th
lng NaOH phn ng l 10 gam. Gi tr ca m l
A. 14,5.

B. 17,5.

C. 15,5.

D. 16,5.

Cu 38: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri
hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung
dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no?
A. Gim 7,74 gam.

B. Gim 7,38 gam.

C. Tng 2,70 gam.

D. Tng 7,92 gam.

Cu 39: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n
chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l
A. 5.

B. 4.

C. 6.

D. 2.

Cu 40: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th
lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn
cu to ca X tho mn cc tnh cht trn l
A. 5.

B. 2.

C. 6.

D. 4.

Cu 41: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c
207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l
A. 32,36 gam.

B. 31,45 gam.

C. 30 gam.

D. 31 gam

Cu 42: Triolein khng tc dng vi cht (hoc dung dch) no sau y?

A. H2 (xc tc Ni, un nng).

B. Dung dch NaOH (un nng).

C. H2O (xc tc H2SO4 long, un nng).

D. Cu(OH)2 ( iu kin thng).

Cu 43: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy
khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l
A. 3.

B. 5.

C. 4.

Cu 44: Pht biu no sau y ng?

~ 90 ~

D. 2.

A. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t trong nhm OH ca axit
COOH v H trong nhm ca ancol -OH
B. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc
phm, m phm.
C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ho hc, ch cn dng
thuc th l nc brom.
D. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm
ca chui chn.
Cu 45: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c
2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l
A. 25%.

B. 72,08%.

C. 27,92%.

D. 75%.

Cu 46: Cho cc pht biu sau:

(a) Cht bo c gi chung l triglixerit hay triaxylglixerol.
(b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c.
(c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch.
(d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5.
S pht biu ng l
A. 3.

B. 2.

C. 4.

D. 1.

Cu 47: Kh este no, n chc, mch h X bng LiAlH 4, thu c ancol duy nht Y. t chy hon ton Y
thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng CO 2 v H2O
l
A. 24,8 gam.

B. 28,4 gam.

C. 16,8 gam.

D. 18,6 gam.

Cu 48: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c
23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M,
c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol
mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l
A. 3 : 5.

B. 3 : 2.

C. 2 : 3.

D. 4 : 3.

Cu 49: Thy phn este X mch h c cng thc phn t C4H6 O2, sn phm thu c c kh nng
trng bc. S este X tha mn tnh cht trn l
A. 6.

B. 4.

C. 5.

D. 3.

Cu 50: S trieste khi thy phn u thu c sn phm gm glixerol, axit CH3COOH v axit
C2H5COOH l
A. 2.

B. 6.

C. 4.

D. 9.

Cu 51: Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH,
to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l
A. HCOOC6H4C2H5.

B. C2H5COOC6H5.

C. CH3COOCH2C6H5.

D. C6H5COOC2H5.

Cu 52: Hp cht X c thnh phn gm C, H, O, cha vng benzen. Cho 6,9 gam X vo 360 ml dung dch
NaOH 0,5M (d 20% so vi lng cn phn ng) n phn ng hon ton, thu c dung dch Y. C cn Y
thu c m gam cht rn khan. Mt khc, t chy hon ton 6,9 gam X cn va 7,84 lt O 2 (ktc), thu
c 15,4 gam CO2. Bit X c cng thc phn t trng vi cng thc n gin nht. Gi tr ca m l
A. 11,4.

B. 13,2.

C. 12,3.

D. 11,1.

Cu 53: Cho 0,1 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung dch NaOH d, un nng,
thu c m gam glixerol. Gi tr ca m l
A. 14,4.

B. 27,6

. C. 9,2.

D. 4,6.

Cu 54: Cht no sau y khi un nng vi dung dch NaOH thu c sn phm c anehit?
A. CH3COOCH=CHCH3.

B. CH2=CHCOOCH2CH3.

~ 91 ~

C. CH3COOCH2CH=CH2.

D. CH3COOC(CH3)=CH2.

Cu 55: Cho s cc phn

ng:
t
0

X +1500
NaOH
C (dung dch)
0

t0, CaO

Y + Z;

Q + H2;

Yt , +xt NaOH (rn)

T + P;

Q + H2O

Z.

Trong s trn, X v Z ln lt l
A. HCOOCH=CH2 v HCHO

B. CH3COOC2H5 v CH3CHO

C. CH3COOCH=CH2 v CH3CHO

D. CH3COOCH=CH2 v HCHO

Cu 56: Hai cht hu c X v Y, thnh phn nguyn t u gm C, H, O, c cng s nguyn t

cacbon (MX < MY). Khi t chy hon ton mi cht trong oxi d u thu c s mol H2O bng s
mol CO2. Cho 0,1 mol hn hp gm X v Y phn ng hon ton vi lng d dung dch AgNO3
trong NH3, thu c 28,08 gam Ag. Phn trm khi lng ca X trong hn hp ban u l
A. 39,66%.

B. 21,84%.

C. 78,16%.

D. 60,34%.

Cu 57: Thy phn hon ton m1 gam este X mch h bng dung dch NaOH d, thu c m2 gam
ancol Y (khng c kh nng phn ng vi Cu(OH)2) v 15 gam hn hp mui ca hai axit cacboxylic
n chc. t chy hon ton m2 gam Y bng oxi d, thu c 0,3 mol CO2 v 0,4 mol H2O. Gi tr
ca m1 l
A. 14,6.

B. 10,6.

C. 11,6.

D. 16,2.

Cu 58: Este no sau y khi phn ng vi dung dch NaOH d, un nng khng to ra hai mui?
A. CH3COO[CH2]2OOCCH2CH3.

B. C6H5COOC6H5 (phenyl benzoat).

C. CH3OOCCOOCH3.

D. CH3COOC6H5 (phenyl axetat

Cu 59: Hn hp X gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc, mch

h. t chy hon ton 21,7 gam X, thu c 20,16 lt kh CO2 (ktc) v 18,9 gam H2O. Thc hin
phn ng este ha X vi hiu sut 60%, thu c m gam este. Gi tr ca m l
A. 12,24.

B. 10,80.

C. 9,18.

D. 15,30.

Cu 60: Pht biu no sau y khng ng?

A. Cht bo l trieste ca etylen glicol vi cc axit bo.
B. Cc cht bo thng khng tan trong nc v nh hn nc.
C. Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni.
D. Cht bo b thy phn khi un nng trong dung dch kim.
Cu 61: Cacbohirat no sau y thuc loi isaccarit?
A. Saccaroz. B. Amiloz.

C. Xenluloz.

~ 92 ~

D. Glucoz.

CACBOHIDRAT
Cu 1 (TN THPT 2010): Cht no sau y khng tham gia phn ng thy phn?
A. Glucoz.

B. Saccaroz.

C. Protein.

D. Tinh bt.

Cu 2 (TN THPT 2010): Cht thuc loi cacbohirat l

A. poli(vinyl clorua).

B. protein.

C. glixerol.

D. xenluloz.

Cu 3 (TN THPT 2010): Cho m gam glucoz phn ng hon ton vi lng d dung dch AgNO 3 trong NH3
(un nng), thu c 21,6 gam Ag. Gi tr ca m l
A. 18,0.

B. 36,0.

C. 9,0.

D. 16,2.

Cu 4 (TN THPT 2010): Cho dy cc dung dch: glucoz, saccaroz, etanol, glixerol. S dung dch trong
dy phn ng c vi Cu(OH)2 nhit thng to thnh dung dch c mu xanh lam l
A. 1.

B. 4.

C. 3.

D. 2.

Cu 5 (TN THPT 2010): Tinh bt thuc loi

A. monosaccarit.

B. lipit.

C. isaccarit.

D. polisaccarit.

Cu 6 (TN THPT 2010): ng phn ca saccaroz l

A. glucoz.

B. mantoz.

C. xenluloz.

D. fructoz.

Cu 7 (CD-2009): Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l:

A. CH3CHO, C2H5OH, C2H5COOCH3.

B. CH3CHO, C6H12O6 (glucoz), CH3OH.

C. CH3OH, C2H5OH, CH3CHO.

D. C2H4(OH)2, CH3OH, CH3CHO.

Cu 8 (CD-2009): Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg
xenluloz trinitrat (hiu sut 80%) l
A. 42,34 lt.

B. 42,86 lt.

C. 34,29 lt.

D. 53,57 lt.

Cu 9 (CD-2009): Cho cc chuyn ho sau:

X + H2O

xt/ t

Y + H2 Sobitol
Ni / t 0

Y + 2AgNO3 + 3NH3 + H2O

Y

xt/ t

Amoni gluconat + 2Ag + 2NH4NO3

E+Z

luc
diep

X + G
Z + H2O as/ chat

X, Y v Z ln lt l:
A. xenluloz, fructoz v kh cacbonic.

B. tinh bt, glucoz v ancol etylic.

C. xenluloz, glucoz v kh cacbon oxit.

D. tinh bt, glucoz v kh cacbonic.

Cu 10 (CD-2009): Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO 2 sinh ra trong qu
trnh ny c hp th ht vo dung dch Ca(OH) 2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln
men l 75% th gi tr ca m l
A. 60.

B. 58.

C. 30.

D. 48.

Cu 11 (CD-2010): Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c dung dch X.
Cho ton b dung dch X phn ng ht vi lng d dung dch AgNO3 trong NH3, un nng, thu c m
gam Ag. Gi tr ca m l
A. 21,60.

B. 2,16.

C. 4,32.

D. 43,20.

Cu 12 (CD-2010): Thu phn hon ton tinh bt trong dung dch axit v c long, thu c cht hu c X.
Cho X phn ng vi kh H2 (xc tc Ni, to), thu c cht hu c Y. Cc cht X, Y ln lt l:
A. glucoz, sobitol. B. glucoz, saccaroz.

C. glucoz, etanol.

D. glucoz, fructoz.

Cu 13 (CD-2010): Cp cht no sau y khng phi l ng phn ca nhau?

~ 93 ~

A. Ancol etylic v imetyl ete.

B. Saccaroz v xenluloz.

C. Glucoz v fructoz.

D. 2-metylpropan-1-ol v butan-2-ol.

Cu 14 (CD-2011): Cho cc cht : saccaroz, glucoz , frutoz, etyl format , axit fomic v anehit axetic.
Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi
Cu(OH)2 iu kin thng l :
A. 3

B. 2

C. 4

D. 5

Cu 15 (CD-2011): Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu
trnh ln men to thnh ancol etylic l:
A. 60%

B. 40%

C. 80%

D. 54%

Cu 16 (CD-2011): C mt s nhn xt v cacbonhirat nh sau:

(1) Saccaroz, tinh bt v xenluloz u c th b thy phn
(2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng tham gia phn ng trng
bc.
(3) Tinh bt v xenluloz l ng phn cu to ca nhau
(4) Phn t xenluloz c cu to bi nhiu gc -glucoz
(5) Thy phn tinh bt trong mi trng axit sinh ra fructoz
Trong cc nhn xt trn, s nhn xt ng l
A. 2

B. 5

C. 4

D. 3

Cu 16 (DH A-2007): Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b
lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X.
un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l:
A. 750.

B. 650.

C. 810.

D. 550.

Cu 17 (DH A-2007): chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung
dch glucoz phn ng vi:
A. Cu(OH)2 trong NaOH, un nng.

B. Cu(OH)2 nhit thng.

C. kim loi Na.

D. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng.

Cu 18 (DH A-2007): Cho cc phn ng sau:

a) FeO + HNO3 (c, nng)

b) FeS + H2SO4 (c, nng)

c) Al2O3 + HNO3 (c, nng)

d) Cu + dung dch FeCl3

e) CH3CHO + H2

f) glucoz + AgNO3 (hoc Ag2O) trong dung dch NH3

Ni / t 0

g) C2H4 + Br2

h) glixerol (glixerin) + Cu(OH)2

Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l:

A. a, b, c, d, e, h.

B. a, b, c, d, e, g.

C. a, b, d, e, f, g.

D. a, b, d, e, f, h.

Cu 19 (DH B-2007): Pht biu khng ng l

A. Sn phm thy phn xenluloz (xc tc H+, t0) c th tham gia phn ng trng gng.
B. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O.
C. Dung dch fructoz ho tan c Cu(OH)2.
D. Thy phn (xc tc H+, t0) saccaroz cng nh mantoz u cho cng mt monosaccarit.
Cu 20 (DH B-2007): Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit
sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn
ng t 90%). Gi tr ca m l:
A. 30 kg.

B. 10 kg.

C. 21 kg.

D. 42 kg.

Cu 21 (DH A-2008): Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng
A. ho tan Cu(OH)2.

B. thy phn.

C. trng ngng.

Cu 22 (DH A-2008): Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l

~ 94 ~

D. trng gng.

A. xenluloz.

B. tinh bt.

C. saccaroz.

D. mantoz.

Cu 23 (DH A-2008): Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l
A. 2,25 gam.

B. 1,82 gam.

C. 1,44 gam.

D. 1,80 gam.

Cu 24 (DH B-2008): Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit
fomic. S cht tc dng c vi Cu(OH)2 l
A. 1.

B. 3.

C. 4.

D. 2.

Cu 25 (DH B-2008): Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru
(ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l
0,8 g/ml)
A. 5,4 kg.

B. 5,0 kg.

C. 6,0 kg.

D. 4,5 kg.

Cu 26 (DH B-2008): Cho dy cc cht: KAl(SO4)2.12H2O, C2H5OH, C12H22O11

CH3COOH, Ca(OH)2, CH3COONH4. S cht in li l
A. 3.

B. 4.

C. 5.

(saccaroz),

D. 2.

Cu 27 (DH B-2008): Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz).
S cht trong dy tham gia c phn ng trng gng l
A. 3.

B. 6.

C. 5.

D. 4.

Cu 28 (DH A-2009): Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo
dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi
khi lng dung dch nc vi trong ban u. Gi tr ca m l
A. 20,0.

B. 30,0.

C. 13,5.

D. 15,0.

Cu 29 (DH A-2009): Cacbohirat nht thit phi cha nhm chc ca

A. ancol.

B. xeton.

C. amin.

D. anehit.

Cu 30 (DH A-2009): Dy gm cc dung dch u tham gia phn ng trng bc l:

A. Glucoz, mantoz, axit fomic, anehit axetic. B. Fructoz, mantoz, glixerol, anehit axetic.
C. Glucoz, glixerol, mantoz, axit fomic.

D. Glucoz, fructoz, mantoz, saccaroz.

Cu 31 (DH B-2009): Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3);
phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn
trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l:
A. (3), (4), (5) v (6)

B. (1), (3), (4) v (6)

C. (2), (3), (4) v (5)

D. (1,), (2), (3) v (4)

Cu 32 (DH B-2009): Pht biu no sau y l ng ?

A. Glucoz b kh bi dung dch AgNO3 trong NH3

B. Xenluloz c cu trc mch phn nhnh

C. Amilopectin c cu trc mch phn nhnh

D. Saccaroz lm mt mu nc brom

Cu 33 (DH B-2009): Pht biu no sau y khng ng?

A. Glucoz tn ti dng mch h v dng mch vng
B. Glucoz tc dng c vi nc brom
C. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH
D. dng mch h, glucoz c 5 nhm OH k nhau.
Cu 34 (DH A-2010): Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz

B. mt gc -glucoz v mt gc -fructoz

C. mt gc -glucoz v mt gc -fructoz

D. hai gc -glucoz

Cu 35 (DH A-2010): T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic
(hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X.
trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l
A. 10%

B. 90%

C. 80%

~ 95 ~

D. 20%

Cu 36 (DH B-2010): Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan Cu(OH)2
nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l:
A. saccaroz .

B. mantoz.

C. xenluloz.

D. glucoz .

Cu 37 (DH A-2011): Xenluloz trinitrat c iu ch t phn ng gia axit nictric vi xenluloz (hiu
sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch
c l
A. 2,97 tn.

B. 3,67 tn.

C. 2,20 tn.

D. 1,10 tn.

Cu 38 (DH A-2011): Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b
qu trnh l 90%, Hp th ton b lng CO2, sinh ra khi ln men m gam tinh bt vo nc vi trong , thu
c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l
132 gam. Gi tr ca m l:
A. 405

B. 324

C. 486

D.297

Cu 39 (DH B-2011): Cho cc pht biu sau v cacbohirat:

(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit
(c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu xanh lam.
(d) Khi thy phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt
loi monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag.
(g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l:
A. 6

B. 3

C. 4

D. 5

Cu 40 (DH B-2011): Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu
c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt
lng d dung dch AgNO3 trong NH3 th lng Ag thu c l
A.0,090 mol

B. 0,095 mol

C. 0,12 mol

~ 96 ~

D. 0,06 mol

AMIN
Nm 2007 - Khi A
Cu 1: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh
o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16)
A. C3H7N.

B. C2H7N.

C. C3H9N.

D. C4H9N

Cu 2: Pht biu khng ng l:

A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2
li thu c axit axetic.
B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu
c phenol.
C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu
c anilin.
D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch
NaOH li thu c natri phenolat
Nm 2007 - Khi B
Cu 3: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l:
A. anilin, metyl amin, amoniac.

B. amoni clorua, metyl amin, natri hiroxit.

C. anilin, amoniac, natri hiroxit.

D. metyl amin, amoniac, natri axetat.

Y
Z
Cu 4: Cho s phn ng: NH 3 X
to
+ CH3 I
(1:1)

+ HONO

+ CuO

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l:

A. C2H5OH, CH3CHO.

B. C2H5OH, HCHO.

C. CH3OH, HCHO.

D. CH3OH, HCOOH.

Nm 2008 - Khi A
Cu 5: Pht biu ng l:
A. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp.
B. Tnh baz ca anilin mnh hn ca amoniac.
C. Cao su thin nhin l sn phm trng hp ca isopren.
D. Tnh axit ca phenol yu hn ca ru (ancol).
Nm 2008 - Khi B
Cu 6: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH
(phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l
A. 8.

B. 6.

C. 5.

D. 7.

Cu 7: Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi
NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu
sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l
A. 0,1 mol v 0,2 mol.

B. 0,1 mol v 0,1 mol.

C. 0,1 mol v 0,4 mol.

D. 0,1 mol v 0,3

mol.
Nm 2009 - Khi A
Cu 8: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng
phn cu to ca X l
A. 4.

B. 8.

C. 5.

~ 97 ~

D. 7

Cu 9: C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic,
benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl
th nhn bit c ti a bao nhiu ng nghim?
A. 5.

B. 6.

C. 3.

D. 4.

Cu 10: Pht biu no sau y l ng?

A. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam.
B. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.
C. Benzen lm mt mu nc brom nhit thng.
D. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni
Nm 2009 Khi B
+ HNO3 c
Fe + HCl
Nitrobenzen
Anilin
Cu 11: Ngi ta iu ch anilin bng s sau: Benzen
H 2SO4 c
to

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi
lng anilin thu c khi iu ch t 156 gam benzen l
A. 111,6 gam.

B. 55,8 gam.

C. 186,0 gam.

D. 93,0 gam

Nm 2010 - Khi A
Cu 12: Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l
A. C3H8.

B. C3H8O.

C. C3H9N.

D. C3H7Cl.

Cu 13: Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml
hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua
dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc
phn t ca hai hirocacbon l
A. CH4 v C2H6.

B. C2H6 v C3H8.

C. C3H6 v C4H8.

D. C2H4 v

C3H6.
Cu 14: t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh
cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit
nitr nhit thng, gii phng kh nit. Cht X l
A. CH3-CH2-CH2-NH2.

B. CH3-CH2-NH-CH3.

C. CH2=CH-NH-CH3.

D. CH2=CH-CH2-NH2.

Nm 2010 - Khi B
Cu 15: t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y
gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HC
A. 0,2.

B. 0,1.

C. 0,3.

D. 0,4.

Cu 16: Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl,
to ra 17,64 gam mui. Amin c cng thc l
A. H2NCH2CH2CH2CH2NH2.
C. H2NCH2CH2NH2

B.CH3CH2CH2NH2.
D. H2NCH2CH2CH2NH2.

Nm 2011 - Khi A
Cu 17: Thnh phn % khi lng ca nit trong hp cht hu c C XHYN l 23,73%. S ng phn amin bc
mt tha mn cc d kin trn l
A. 4.

B. 3.

C. 2.

D. 1.

Nm 2011 - Khi B
Cu 18: Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c
cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l:
A. anilin, axit clohiric, phenylamoni clorua.

B. phenol, natri hiroxit, natri phenolat.

C. natri phenolat, axit clohiric, phenol.

D. phenylamoni clorua, axit clohiric,

anilin.

~ 98 ~

Cu 19: Ancol v amin no sau y cng bc?

A. (CH3)2CHOH v (CH3)2CHNH2.

B. (C6H5)2NH v C6H5CH2OH.

C. C6H5NHCH3 v C6H5CH(OH)CH3.

D. (CH3)3COH v (CH3)3CNH2.

Nm 2012 - Khi A
Cu 20: Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH). S cht trong dy c kh
nng lm mt mu nc brom l
A. 4.

B. 3.

C. 5.

D. 2.

Cu 21: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (M X <

MY). t chy hon ton mt lng M cn dng 4,536 lt O 2 (ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc).
Cht Y l
A. etylmetylamin.

B. butylamin.

C. etylamin.

D. propylamin

Cu 22: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc
phenyl). Dy cc cht sp xp theo th t lc baz gim dn l :
A. (4), (1), (5), (2), (3).

B. (3), (1), (5), (2), (4).

C. (4), (2), (3), (1), (5).

D. (4), (2), (5), (1), (3).

Cu 23: S amin bc mt c cng cng thc phn t C3H9N l

A. 4.

B. 3.

C. 1.

D. 2.
+

H 3O
KCN
Y
Cu 24: Cho s chuyn ha : CH3Cl
X
t0

Cng thc cu to X, Y ln lt l:
A. CH3NH2, CH3COOH.

B. CH3NH2, CH3COONH4.

C. CH3CN, CH3COOH.

D. CH3CN, CH3CHO.

Nm 2012- Khi B
Cu 25: t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai hirocacbon ng ng k tip
bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b Y i qua dung dch
H2SO4 c (d), th tch kh cn li l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon
l
A. C3H6 v C4H8.

B. C3H8 v C4H10. C. C2H6 v C3H8.

~ 99 ~

D. C2H4 v C3H6

AMINOAXIT
Nm 2007 - Khi A
Cu 1: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95
gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5)
A. H2NCH2COOH.

B. H2NCH2CH2COOH.

C. CH3CH2CH(NH2)COOH.

D. CH3CH(NH2)COOH

Cu 2: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung
dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy
qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l
(cho H = 1, C = 12, N = 14, O = 16, Na = 23)
A. 16,5 gam.

B. 14,3 gam.

C. 8,9 gam.

D. 15,7 gam.

Cu 3: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o
ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa.
Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16)
A. H2N-CH2-COO-C3H7.

B. H2N-CH2-COO-CH3.

C. H2N-CH2-CH2-COOH.

D. H2N-CH2-COO-C2H5.

Nm 2007- Khi B
Cu 4: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca
aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi
dung dch HCl l
A. X, Y, Z, T.

B. X, Y, T.

C. X, Y, Z.

D. Y, Z, T.

Cu 5: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l

A. protit lun l cht hu c no.

B. protit lun cha chc hiroxyl.

C. protit c khi lng phn t ln hn.

D. protit lun cha nit.

Nm 2008 - Khi A
Cu 6: Pht biu khng ng l:
A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COO-.
B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl.
C. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin).
D. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt
Cu 7: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa.
S lng cc dung dch c pH < 7 l
A. 2.

B. 4.

C. 5.

D. 3.

Nm 2008 - Khi B
Cu 8: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht
hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l
A. 85.

B. 68.

C. 46.

D. 45.

Cu 9: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi
cc phn ng kt thc thu c sn phm l:
A. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-.
B. H2N-CH2-COOH, H2N-CH2-CH2-COOH.
C. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-.

~ 100 ~

D. H2N-CH2-COOH, H2N-CH(CH3)-COOH.
Cu 10: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch
NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu
to thu gn ca X l
A. H2NCH2COOCH3.

B. HCOOH3NCH=CH2.

C. H2NCH2CH2COOH.

D.CH2=CHCOONH4

Nm 2009 - Khi A
Cu 11: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol
amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc
phn t ca X l
A. C5H9O4N.

B. C4H10O2N2.

C. C5H11O2N.

D. C4H8O4N2

Cu 12: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l

A. dung dch NaOH.

B. dung dch NaCl.

C. Cu(OH)2 trong mi trng kim.

D. dung dch HCl.

Cu 13: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung
dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn
mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui
khan. Gi tr ca m l
A. 10,8.

B. 9,4.

C. 8,2.

D. 9,6

Nm 2009 - Khi B
Cu 14: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l
A. 1.

B. 2.

C. 3.

D. 4.

Cu 15: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch
NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T
ln lt l
A. CH3NH2 v NH3.

B. C2H5OH v N2.

C. CH3OH v CH3NH2.

D. CH3OH v NH3.

Cu 16: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam
mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l
A. H2NC3H5(COOH)2.
C. H2NC2H3(COOH)2.

B. (H2N)2C3H5COOH.
D. H2NC3H6COOH

Nm 2010 - Khi A
Cu 17: Pht biu ng l:
A. Axit nucleic l polieste ca axit photphoric v glucoz.
B. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit.
C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m.
D. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz.
Cu 18: C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit:
glyxin, alanin v phenylalanin?
A. 4.

B. 6.

C. 9.

D. 3.

Cu 19: Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung
dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l
A. 0,65.

B. 0,70.

C. 0,55.

D. 0,50.

Cu 20: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng
ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2.
Cc gi tr x, y tng ng l

~ 101 ~

A. 8 v 1,5.

B. 7 v 1,5.

C. 7 v 1,0 .

D. 8 v 1,0.

Nm 2010 - Khi B
Cu 21: Hai hp cht hu c X v Y c cng cng thc phn t l C 3H7NO2, u l cht rn iu kin
thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X
v Y ln lt l
A. vinylamoni fomat v amoni acrylat.
B. axit 2-aminopropionic v axit 3-aminopropionic.
C. axit 2-aminopropionic v amoni acrylat.
D. amoni acrylat v axit 2-aminopropionic.
Cu 22: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d),
thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung
dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l
A. 112,2.

B. 171,0.

C. 165,6.

D. 123,8.

Cu 23: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong

phn t cha mt nhm - NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi
lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc
vi trong d, to ra m gam kt ta. Gi tr ca m l
A. 45.

B. 60.

C. 120.

D. 30.

Cu 24: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol
valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit
Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l
A. Gly-Ala-Val-Phe-Gly.

B. Gly-Phe-Gly-Ala-Val.

C. Val-Phe-Gly-Ala-Gly.

D. Gly-Ala-Val-Val-Phe.

Nm 2011 - Khi A
Cu 25: S ng phn amino axit c cng thc phn t C3H7NO2 l
A. 3.

B. 4.

C. 1.

D. 2.

Cu 26: Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala,
32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l
A. 111,74.

B. 81,54.

C. 66,44.

D. 90,6.

Cu 27: Khi ni v peptit v protein, pht biu no sau y l sai?

A. Tt c cc protein u tan trong nc to thnh dung dch keo.
B. Protein c phn ng mu biure vi Cu(OH)2.
C. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit.
D. Thy phn hon ton protein n gin thu c cc -amino axit
Cu 28: Dung dch no sau y lm qu tm i thnh mu xanh?
A. Dung dch lysin.

B. Dung dch alanin.

C. Dung dch glyxin.

D. Dung dch

valin.
Cu 29: Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit
(cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 110 hn hp X tc
dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l
A. 7,82 gam.

B. 8,15 gam.

C. 16,30 gam.

D. 7,09 gam

Nm 2011 - Khi B
Cu 30: Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2.
Dy xp theo th t pH tng dn l:
A. (2), (1), (3).

B. (2), (3), (1).

C. (3), (1), (2).

Cu 31: Trong qu gc chn rt giu hm lng

~ 102 ~

D. (1), (2), (3).

A. -caroten

B. ete ca vitamin A.

C. este ca vitamin A.

D. vitamin A.

Cu 32: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi
lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol
sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b
Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l
A. 5,34.

B. 4,45.

C. 2,67.

D. 3,56

Cu 33: Pht biu khng ng l:

A. Metylamin tan trong nc cho dung dch c mi trng baz.
B. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu.
C. Etylamin tc dng vi axit nitr nhit thng to ra etanol.
D. ipeptit glyxylalanin (mch h) c 2 lin kt peptit.
Nm 2012 - Khi A
Cu 34: Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH 2 trong phn t), trong t l
mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t
chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo
nc vi trong d th khi lng kt ta thu c l
A. 20 gam.

B. 13 gam.

C. 10 gam.

D. 15 gam.

Cu 35: Pht biu no sau y l ng?

A. Mui phenylamoni clorua khng tan trong nc.
B. Tt c cc peptit u c phn ng mu biure.
C. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit.
D. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai.
Cu 36: Dung dch cht no sau y lm qu tm chuyn thnh mu hng?
A. axit -aminoglutaric.

B. axit ,-iaminocaproic.

C. axit -aminopropionic.

D. axit aminoaxetic.

Nm 2012 - Khi B
Cu 37: un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600
ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam
mui khan ca cc amino axit u c mt nhm COOH v mt nhm NH2 trong phn t. Gi tr ca m
l
A. 66,00.

B. 44,48.

C. 54,30.

D. 51,72.

Cu 38: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung
dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui.
Gi tr ca m l
A. 22,35.

B. 44,65.

C. 33,50.

~ 103 ~

D. 50,65

POLIME V VT LIU POLIME

A. Nm 2007
Cu 1: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng
vi k mt xch trong mch PVC. Gi tr ca k l
A. 3. B. 6.
C. 4. D. 5.
Cu 2: Cc ng phn ng vi cng thc phn t C 8H10O (u l dn xut ca benzen) c tnh cht:tch nc
thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi
cng thc phn t C8H10O, tho mn tnh cht trn l: A. 4.
B. 1.
C. 3.
D. 2.
Cu 3: Dy gm cc cht c dng tng hp cao su Buna-S l:
A. CH2=CH-CH=CH2, lu hunh.

B. CH2=C(CH3)-CH=CH2, C6H5CH=CH2.

C. CH2=CH-CH=CH2, C6H5CH=CH2.

D. CH2=CH-CH=CH2, CH3-CH=CH2.

B. Nm 2008
Cu 4: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176
vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l
A. 113 v 152. B. 113 v 114.

C. 121 v 152.

D. 121 v 114.

Cu 5: Pht biu ng l:
A. Cao su thin nhin l sn phm trng hp ca isopren.
B. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp.
C. Tnh axit ca phenol yu hn ca ru (ancol). D. Tnh baz ca anilin mnh hn ca amoniac.
Cu 6: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th
cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH 4 chim 80% th tch kh thin nhin v hiu sut
ca c qu trnh l 50%)
A. 286,7.

B. 358,4.

C. 224,0.

D. 448,0.

Cu7: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to
thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %)
A. 55 lt.

B. 81 lt.

C. 49 lt. D. 70 lt.

Cu 8: Polime c cu trc mng khng gian l: A. PVC. B. nha bakelit. C. PE. D. amilopectin.
Cu 9: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh
theo xenluloz l 90%). Gi tr ca m l
A. 33,00.

B. 25,46.

C. 26,73.

D . 29,70.

Cu 10: T nilon - 6,6 c iu ch bng phn ng trng ngng

A. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH.
C. H2N-(CH2)5-COOH.

D. HOOC-(CH2)2-CH(NH2)-COOH.

C. Nm 2009
Cu 11: Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dd nc vi
trong, thu c 10 gam kt ta. Khi lng dd sau phn ng gim 3,4 gam so vi khi lng dd nc vi
trong ban u. Gi tr ca m l:
A. 13,5

B. 30,0

C. 15,0

D. 20,0

Cu 12: Poli (metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l

A. CH3-COO-CH = CH2 v H2N-[CH2]5-COOH.

B. CH2 = C(CH3)-COOCH3 v H2N-[CH2]6-COOH.

C. CH2 = C(CH3)-COOCH3 v H2N-[CH2]5-COOH. D. CH2 = CH-COOCH3 v H2N-[CH2]6-COOH.

Cu 13: Dy gm cc cht u c kh nng tham gia phn ng trng hp l:
A. stiren; clobenzen; isopren; but-1-en.

B. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua.

C. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. D. buta-1,3-ien; cumen; etilen; trans-but-2-en.

~ 104 ~

Cu 14: Pht biu no sau y l ng?

A. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N.
B. T visco l t tng hp.
C. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng.
D. Trng hp stiren thu c poli(phenol-fomanehit).
Cu 15: Pht biu no sau y l ng?
A. Saccaroz lm mt mu nc brom.

B. Glucoz b kh bi dung dch AgNO3 trong

C. Xenluloz c cu trc mch phn nhnh.

D. Amilopectin c cu trc mch phn nhnh.

NH3.
Cu 16: Trong thc t, phenol c dng sn xut
A. nha PVC, nha novolac v cht dit c 2,4-D.
B. nha rezit, cht dit c 2,4-D v thuc n TNT.
C. PPF, cht dit c 2,4-D v axit picric.
D. nha rezol, nha rezit v thuc tr su 666.
Cu 17: Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg xenluloz
trinitrat (hiu sut 80%) l
A. 53,57 lt.

B. 34,29 lt.

C. 42,86 lt.

D. 42,34 lt.

Cu 18: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC
th s mt xch alanin c trong phn t X l
A. 328.
B. 479.
C. 453.
D. 382.
Cu 19: Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO 2 sinh ra trong qu trnh ny
c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l
75% th gi tr ca m l
A. 30.

B. 48.

C. 60

. D. 58.

D. Nm 2010
Cu 20: Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 21: Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylenterephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca phn ng trng ngng l:
A. (1), (3), (6).

B. (3), (4), (5).

C. (1), (2), (3).

D. (1), (3), (5).

Cu 22: Thu phn hon ton tinh bt trong dung dch axit v c long, thu c cht hu c X. Cho X phn
ng vi kh H2 (xc tc Ni, to), thu c cht hu c Y. Cc cht X, Y ln lt l:
A. glucoz, sobitol.

B. glucoz, saccaroz. C. glucoz, etanol.

D. glucoz, fructoz.

Cu 23: Polime no sau y c tng hp bng phn ng trng ngng?

A. poli(metyl metacrylat). B. poli(etylen terephtalat). C. polistiren.

D.poliacrilonitrin.

E. Nm 2011
Cu 24: Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp?
A. Trng hp vinyl xianua.

B. Trng ngng axit -aminocaproic.

C. Trng hp metyl metacrylat.

D. Trng ngng hexametyleniamin vi axit aipic.

Cu 25: Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60%
tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l
A. 2,97 tn.

B. 3,67 tn.

C. 1,10 tn.

D. 2,20 tn.

Cu 26: Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l
90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong, thu c 330 gam
kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi
tr ca m l A. 297.
B. 405.
C. 486.
D. 324.

~ 105 ~

Cu 27: Cho s phn ng:

CH CH + HCN X; X polime Y; X + CH2=CH-CH=CH2 polime Z. Y v Z ln lt dng ch
to vt liu polime no sau y?
A. T capron v cao su buna.

B. T nilon-6,6 v cao su cloropren.

C. T olon v cao su buna-N.

D. T nitron v cao su buna-S.

Cu 28: Cho cc pht biu sau v cacbohirat:

(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc.
(b) Tinh bt v xenluloz u l polisaccarit.
(c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam.
(d) Khi thu phn ht hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi
monosaccarit duy nht.
(e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag.
(g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol.
S pht biu ng l

A. 5.

B. 6.

C. 4.

D. 3.

Cu 29: Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc
loi t poliamit?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 30 Cho cc polime : (1) polietilen , (2) poli (metyl metacrylat), (3) polibutaien, (4) polistiren, (5)
poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch
axit v dung dch kim l: A. (2),(3),(6)
B. (2),(5),(6)
C. (1),(4),(5)
D. (1),(2),(5)
Cu 31 C mt s nhn xt v cacbonhirat nh sau:
(6) Saccaroz, tinh bt v xenluloz u c th b thy phn
(7) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH) 2 v c kh nng tham gia phn ng
trng bc
(8) Tinh bt v xenluloz l ng phn cu to ca nhau
(9) Phn t xenluloz c ccu to bi nhiu gc -glucoz
(10)

Thy phn tinh bt trong mi trng axit sinh ra fructoz

Trong cc nhn xt trn, s nhn xt ng l

A. 2

B. 5

C. 4

D. 3

F. Nm 2012
Cu 32. (C-2012) Pht biu no sau y l sai?
A. Lc baz ca anilin yu hn lc baz ca metylamin.
B. Cao su buna-N thuc loi cao su thin nhin.
C. Cht bo cn c gi l triglixerit hoc triaxylglixerol.
D. Poli(metyl metacrylat) c dng ch to thy tinh hu c.
Cu 33. (HA-2012) Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo ng t l mol):
(a) X + 2NaOH

t0

(c) nX3 + nX4

X1 + X2 + H2O
nilon-6,6 + 2nH2O

(b) X1 + H2SO4
(d) 2X2 + X3

X3 + Na2SO4
X5 + 2H2O

Phn t khi ca X5 l
A. 202.

B. 198.

C. 174.

D. 216.

Cu 34. (HB-2012) Cho cc cht: caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin (4), vinyl
axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l
A. (3), (4) v (5).

B. (1), (2) v (3).

C. (1), (3) v (5).

D. (1), (2) v (5).

Cu 35. (HB-2012) Cc polime thuc loi t nhn to l

A. t nilon-6,6 v t capron.

B. t visco v t xeluloz axetat.

~ 106 ~

C. t visco v t nilon-6,6.

D. t tm v t vinilon.

Cu 36. (HA-2012) Loi t no sau y c iu ch bng phn ng trng hp?

A. T nilon-6,6.

B. T visco.

C. T nitron. D. T xenluloz axetat.

~ 107 ~