KIM TRA HC K II NM HC 2012 - 2013

MN: HA HC LP 11
Thi gian: 45 pht; (khng k thi gian pht ))
H v tn.Lp..

M 1335

(Th sinh khng c s dng Bng tun hon cc nguyn t ha hc)

(Cho H = 1; C = 12; N = 14; O = 16; Na = 23; Ca = 40; Ag = 108)
A. TRC NGHIM (5 im).
Cu 1: Cho s phn ng sau: CH4 X Y PVC. Trong , X v Y ln lt l:
A. C2H6, CH2=CHCl.
B. C3H4, CH3CH=CHCl.
C. C2H2, CH2=CHCl.
D. C2H4, CH2=CHCl.
Cu 2: S ng phn cu to ng vi cng thc phn t C5H12 l:
A. 3 ng phn.
B. 4 ng phn.
C. 5 ng phn.
D. 2 ng phn.
Cu 3: Cht khng lm i mu qu tm l:
A. NaOH.
B. C6H5OH.
C. CH3COOH.
D. CH3COONa.
Cu 4: Ch dng duy nht mt thuc th no di y c th phn bit c: benzen, stiren, toluen?
A. Oxi khng kh.
B. dd KMnO4.
C. dd Brom.
D. dd HCl.
Cu 5: Hp cht c cng thc cu to sau: CH3CH(CH3)CH2CH2OH, c tn gi l:
A. 2-metylbutan-4-ol.
B. 4-metylbutan-1-ol.
C. pentan-1-ol.
D. 3-metylbutan-1-ol.
Cu 6: Cho dy cc cht sau: buta-1,3-ien, propen, but-2-en, pent-2-en. S cht c ng phn hnh hc:
A. 4.
B. 1.
C. 2.
D. 3.
Cu 7: phn bit ba cht lng sau: Glixerol, etanol, phenol, thuc th cn dng l:
A. Cu(OH)2, Na.
B. Cu(OH)2, dd Br2.
C. Qu tm, Na.
D. Dd Br2, qu tm.
Cu 8: Dy no sau y gm cc cht u c kh nng phn ng vi dung dch AgNO 3/NH3?
A. CH3COCH3, HCCH.
B. HCHO, CH3COCH3.
C. CH3CHO, CH3-CCH.
D. CH3-CC-CH3, CH3CHO.
Cu 9: Cht no sau y khi cng HCl ch cho mt sn phm duy nht:
A. CH2=CH-CH2-CH3.
B. CH2=CH-CH3.
C. CH2=C(CH3)2.
D. CH3-CH=CH-CH3.
Cu 10: S ng phn ancol no, n chc, mch h c cng cng thc phn t C4H10O l:
A. 6.
B. 4.
C. 8.
D. 2.
Cu 11: t chy hon ton 896 ml hirocacbon A (ktc) thu c CO 2 v H2O. Hp th hon ton sn phm chy
bng nc vi trong d thy khi lng bnh ng dung dch Ca(OH) 2 tng 7,44 gam v trong bnh c 12 gam kt ta.
Cng thc phn t ca A l:
A. C3H6.
B. C4H8.
C. C3H8.
D. C4H10.
Cu 12: Ly mt lng Na kim loi phn ng va ht vi 16,3 gam hn hp X gm ba ancol no, n chc th thu
c V lt H2 (ktc) v 25,1 gam rn Y. Gi tr ca V l:
A. 4,48 lt.
B. 3,36 lt.
C. 3,92 lt.
D. 2,8 lt.
Cu 13: Hy chn cu pht biu ng v phenol:
1. Phenol tan trong dung dch NaOH to thnh natriphenolat.
2. Phenol tan v hn trong nc lnh.
3. Phenol c tnh axit nhng n l axit yu hn axit cacbonic.
4. Phenol phn ng c vi dung dch nc Br2 to kt ta trng.
A. 1, 2, 3.
B. 1, 2, 4.
C. 2, 3, 4.
D. 1, 3, 4.
Cu 14: Dy ng ng ca ancol no, n chc, mch h c cng thc chung l:
A. CnH2n-1OH (n 3).
B. CnH2n-7OH (n 6).
C. CnH2n+1OH (n 1).
D. CnH2n+2-x(OH)x (n x, x > 1).
Cu 15: un nng mt ancol no, n chc, mch h X vi H 2SO4 c nhit thch hp thu c cht hu c Y. T
khi hi ca Y so vi X bng 0,61. X c cng thc phn t l:
A. C3H7OH.
B. CH3OH.
C. C2H5OH.
D. C4H9OH.
B. T LUN (5 im).
Cu 1. (1,5 im). Hon thnh s phn ng sau.
C2H5Cl
(1) C2H4
(2) C2H5OH
(3) CH3CHO
(4) C2H5OH
(5) CH3COOH.

.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................

.....................................................................................................................................................
.....................................................................................................................................................
Cu 2. (3,5 im). Ly 4,04 gam hn hp A gm hai ancol no, n chc, mch h, k tip nhau trong cng dy ng
ng tc dng vi Na kim loi d thu c 1,12 lt H2 (ktc).
a. Tm cng thc phn t ca hai ancol.
b. Tnh thnh phn phn trm v khi lng tng ancol trong hn hp A.
c. Oxi ha hon ton 4,04 gam hn hp ancol trn bng CuO, un nng sau , em ton b sn phm hu c cho tc
dng vi lng d dung dch AgNO3/NH3 th thu c a gam Ag. Tnh a.

.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
KIM TRA HC K II NM HC 2010 - 2011

HNG DN CHM THI CHNH THC

MN HO HC LP 11
Ngy thi: 07-05-2011
A. TRC NGHIM (5 im). 15 cu x 0,33 = 5 im
M 135.
Cu
1
2
3
4
5
6
7
8
C
A
B
B
D
C
B
C
M 208.
Cu
1
2
3
4
5
6
7
8
D
D
A
A
D
B
C
B
M 356.
Cu
1
2
3
4
5
6
7
8
C
C
A
B
B
C
D
D
M 483.
Cu
1
2
3
4
5
6
7
8
A
D
D
A
D
A
C
A

9
D

10
B

11
A

12
A

13
D

14
C

15
C

9
C

10
B

11
A

12
C

13
D

14
C

15
C

9
B

10
A

11
D

12
D

13
C

14
A

15
C

9
B

10
C

11
D

12
B

13
A

14
C

15
B

B. T LUN (5 im).
Cu 1 (1,5 im)

im

(1) C2H5Cl + KOH

(2) C2H4 + H2O
H

ancol
to

,t

(3) C2H5OH + CuO

C2H4 + KCl + H2O

C2H5OH
o

CH3CHO + Cu + H2O
o

(4) CH3CHO + H2
Ni,t

0,3 x 5

C2H5OH

(5) C2H5OH + O2 men giam

CH3COOH + H2O

Cu 2 (2,0 im)
a. t cng thc chung ca hai ancol l: CnH2n1OH ( n 1).
Ta c: nH2 = 1,12/22,4 = 0,05 mol
S : CnH2n1OH
Na

1
H
2 2

nhh x y 0,1

x 0,04mol
y 0,06mol

mhh 32x 46y 4,04

0,04.32
(%CH3OH)m
100 31,68% ; (%C2H5OH)m = 100-31,68 = 68,32%.
4,04
o

AgNO3 /NH3
c. S : CH3OH
4Ag
CuO,t HCHO
0,04

0,16
o
AgNO3 /NH3
CuO,t
C2H5OH
CH3CHO
2Ag


0,06

0,12
Vy: mAg = (0,16 + 0,12)108 = 30,24 g.
Hc sinh c th gii theo cch khc ng vn c im ti a.

MA TRN KHNG GHI CHUN

0,25
0,5

0,1

0,05
Ta c: M = 4,04/0,1 = 40,4 14n 18 40,4 n 1,6
V hai ancol ng ng k tip, chn: CH3OH: x mol ; C2H5OH: y mol.
(C th vit: CTPT ca hai ancol: CH4O v C2H6O).
b. Ta c hpt:

im

0,25
0,5

0,5
0,5
0,5
0,25
0,25

Ni dung kin
thc

Mc nhn thc
Thng hiu
TN
TL

Nhn bit
TN
TL
1

1
0.33

1. Hirocacbon no
2.
Hirocacbon 1
khng no

2
0.33

0.67

1
0.33

2
0.33

3.
Hirocacbon
thm

4.
Dn
xut 4
halogen ancol phenol
5. Anehit xeton 1
axit cacboxylic

0.67
1

0.33
1.34

0.33
2

0.33

1
0.67

7
2.5

1
0.33

4.84
1

1.0

6. Tng hp kin
thc
Tng

Tng

Vn dng
TN
TL

1
0.67

2
1.5

6
2.33

M 483
- Nhn bit: Cu: 1; 2; 5; 10; 11; 14; 15.
- Thng hiu: Cu: 4; 6; 9; 12; 13. (t lun: cu 1).
- Vn dng: Cu: 3; 7; 8.(t lun: cu 2a; 2b).
- Vn dng mc cao: (t lun: cu 3c).
- Tng hp kin thc: Cu 9; 12(t lun: Cu 1)

1.33
2.17

5
3.16

18
4.5

10