Trang 1/5 - M thi 122

KHA LUYN N THI H

Nm hc 2013 - 2014
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LUYN THI I HC - NGY 16/03/2014
MN: HA HC LP 12 KHI A, B
Thi gian lm bi: 90 pht;
M thi 122
H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit s khi ca cc nguyn t:
H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg = 24; Al = 27; Si = 28; P = 31; S = 32; Cl = 35,5; K = 39;
Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137
(Th sinh khng c s dng BNG TUN HON CC NGUYN T HA HC)
Cu 1: Cho CO phn ng vi CuO mt thi gian to hn hp kh A v hn hp rn B . Cho A phn ng
vi mt dung dch cha 0,025mol Ca(OH)
2
to 2(g) kt ta . Ly cht rn B phn ng vi dung dch
HNO
3
c, nng d to V(lt) kh (ktc) mu nu . Gi tr ca V l:
A. 1,344 lt hoc 0,672 lt B. 1,120 lt hoc 0,672 lt
C. 1,344 lt hoc 0,896 lt. D. 1,120 lt hoc 0,896 lt
Cu 2: Cho phn ng sau Fe
3
O
4
+ HNO
3
Fe(NO
3
)
3
+ NO
2
+ NO + H
2
O
Nu t l s mol gia NO v NO
2
l 1 : 2 th h s cn bng ca HNO
3
trong phng trnh ho hc l
A. 30 B. 48 C. 38 D. 66
Cu 3: Cho cn bng sau: 3A
(k)
2B
(k)
+ D
(r)
. Khi tng nhit ca phn ng, t khi hi ca hn hp
kh so vi H
2
tng ln. Khng nh no sau y ng?
A. Phn ng thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng nghch.
B. Phn ng thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng thun.
C. Phn ng thun l thu nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng thun.
D. Phn ng thun l to nhit; khi tng nhit , cn bng chuyn dch theo chiu phn ng nghch.
Cu 4: Cho cng thc cht A l C
3
H
5
Br
3
. Khi A tc dng vi dung dch NaOH d to ra mt hp cht tp
chc ca ancol bc 1 v anehit. Cng thc cu to ca A l
A. CH
3
-CHBr-CHBr
2
. B. CH
2
Br-CH
2
-CHBr
2
.
C. CH
2
Br-CHBr-CH
2
Br. D. CH
3
-CBr
2
-CH
2
Br.
Cu 5: Trn u 6,102 gam hn hp Al, Fe
3
O
4
v CuO (cc cht c cng s mol) ri tin hnh phn ng
nhit nhm thu c hn hp X. Cho X tc dng vi dung dch HNO
3
d c V ml ( ktc) hn hp kh
NO
2
v NO theo t l mol tng ng l 1:1. Gi tr ca V l
A. 806,4 B. 604,8 C. 403,2 D. 645,12
Cu 6: Hp cht thm X, c cng thc phn t C
8
H
8
O
2
va c kh nng tc dng vi Na, va c kh
nng tc dng vi NaOH v lm qu tm chuyn mu hng. S ng phn cu to ca X l
A. 4. B. 5. C. 6. D. 3.
Cu 7: Phn ng no sau y sai?
A. 3Na[Al(OH)
4
] + AlCl
3
4Al(OH)
3
+ 3NaCl
B. 3Na
2
CO
3
+ 2FeCl
3
+ 3H
2
O 2Fe(OH)
3
+ 6NaCl + 3CO
2
C. Ag
2
S + 10HNO
3
2AgNO
3
+ H
2
SO
4
+ 8NO
2
+ 4H
2
O
D. C
2
H
5
ONa + H
2
O C
2
H
5
OH + NaOH
Cu 8: Hy la chn cc ho cht cn thit trong phng th nghim iu ch kh sunfur?
A. Na
2
SO
3
v dung dch H
2
SO
4
c B. CaSO
3
v dung dch H
2
SO
4
c
C. CaSO
4
v dung dch H
2
SO
4
long D. CaSO
4
v dung dch H
2
SO
4
c
Cu 9: Cacbon phn ng vi tt c cc cht trong dy no sau y ?
A. Fe
2
O
3
, Al
2
O
3
, CO
2
,HNO
3
B. CO, Al
2
O
3
, HNO
3
(c), H
2
SO
4
(c)
C. Fe
2
O
3
, CO
2
, H
2
, HNO
3
(c) D. CO, Al
2
O
3
, K
2
O, Ca
Cu 10: Cho 15 gam fomon 37,5% tc dng vi lng d AgNO
3
/NH
3
thy xut hin m gam kt ta .
Gi tr ca m l
A. 108,0. B. 81,0. C. 42,8 D. 40,5
Cu 11: Cht A c cng thc phn t C
11
H
20
O
4
. A tc dng vi NaOH to ra mui ca axit hu c B
mch thng v 2 ancol l etanol v propan-2-ol. Cng thc cu to ca A l
Trang 2/5 - M thi 122
A. C
2
H
5
OOC[CH
2
]
4
OOCCH
2
-CH
2
-CH
3
. B. C
2
H
5
OOC[CH
2
]
4
COOCH
2
-CH
2
-CH
3
.
C. C
2
H
5
OOC[CH
2
]
4
COOCH(CH
3
)
2
. D. C
2
H
5
OOC[CH
2
]
4
OOCCH(CH
3
)
2
.
Cu 12: Trng thi lai ha ca cc nguyn t cacbon trong cc phn t: CO
2
; C
2
H
6
; C
2
H
2
v C
2
H
4
ln
lt l
A. sp; sp
3
; sp; sp
2
. B. sp
2
; sp
3
; sp; sp
2
. C. sp; sp
2
; sp; sp
3
. D. sp; sp
3
; sp
2
; sp.
Cu 13: Pht biu no di y khng ng?
A. Nguyn t c cu thnh t cc ht c bn l proton, ntron v electron.
B. V nguyn t c cu thnh bi cc ht electron.
C. Ht nhn nguyn t c cu thnh t cc ht proton v ntron.
D. Vi mi nguyn t, khi lng nguyn t bng s khi.
Cu 14: Trong 1 kg go cha 81% tinh bt, c s mt xch C
6
H
10
O
5
- l
A. 12,044.10
24
. B. 6,020.10
24
. C. 16,20.10
24
. D. 3,012.10
24
.
Cu 15: Dng thuc th no sau y phn bit bn cht rn: NaCl, CaCO
3
, Na
2
CO
3
v BaSO
4
A. Nc B. Qu tm C. Nhit phn D. Nc v CO
2
Cu 16: Cho cc ion:HSO

4
, NO

3
, C
6
H
5
O
-
,
-
OCO-CH
2
-NH
+
3
, CH
3
NH
+
3
, Cu
2+
, Ba
2+
, Al(OH)

4
, HCO

3
.
Tng s ion c vai tr axit v tng s ion c vai tr lng tnh l
A. 3 v 2 B. 2 v 1 C. 1v 2 D. 2 v 2
Cu 17: Chia 4,58g hn hp gm ba kim loi Zn, Mg, Al thnh hai phn bng nhau:
- Phn 1 tan hon ton trong dung dch HCl gii phng 1,456l H
2
(ktc) v to ra m(g) hn hp mui
clorua .
- Phn 2 b oxi ha hon ton thu c m(g) hn hp ba oxit.
Gi tr ca m v m ln lt l:
A. 6,905 v 4,37 B. 6,905 v 3,33 C. 7,035 v 3,33 D. 7,035 v 4,37
Cu 18: chun mt dung dch Fe
2+
axit ho phi dng 50 ml dung dch K
2
Cr
2
O
7
0,02M.
chun cng lng dung dch Fe
2+
trn bng dung dch KMnO
4
th th tch dung dch KMnO
4
0,02M
cn dng l
A. 25 ml B. 60 ml C. 120 ml D. 30 ml
Cu 19: Hp cht A to bi ion M
2+
v ion X
2
2
. Tng s ht c bn to nn hp cht A l 241 trong ,
tng s ht mang in nhiu hn ht khng mang in l 47. Tng s ht mang in ca ion M
2+
nhiu
hn ca ion X
2
2
l 76 ht. V tr ca M trong bng tun hon l
A. 20, chu k 4, nhm IIA B. 12, chu k 3, nhm IIA
C. 56, chu k 6, nhm IIA D. 38, chu k 5, nhm IIA
Cu 20: Cho cc ion sau: Cl
-
; S
2-
; Ca
2+
; K
+
. Th t tng dn bn knh ca cc ion trn l
A. Ca
2+
; K
+
; S
2-
; Cl
-
B. Cl
-
; S
2-
; Ca
2+
; K
+
. C. S
2-
; Cl
-
; K
+
; Ca
2+
D. .Ca
2+
; K
+
; Cl
-
; S
2-
.
Cu 21: Khi thu phn 0,01 mol este E to bi axit hu c n chc X v ancol Y th dng ng 1,68
gam KOH, cn khi thu phn 6,35 gam E th cn 3,0 gam NaOH v thu c 7,05 gam mui. Cng thc
phn t ca este l
A. C
14
H
18
O
6
. B. C
9
H
12
O
6
. C. C
12
H
20
O
6
. D. C
12
H
14
O
6
.
Cu 22: t chy hon ton 2,76 gam hn hp X gm C
x
H
y
COOH; C
x
H
y
COOCH
3
v CH
3
OH thu c
2,688 lt CO
2
( ktc) v 1,8 gam H
2
O. Mt khc, cho 2,76 gam hn hp X phn ng va vi 30 ml
dung dch NaOH 1M, thu c 0,96 gam CH
3
OH. Cng thc ca C
x
H
y
COOH l
A. C
2
H
3
COOH. B. CH
3
COOH. C. C
3
H
5
COOH. D. C
2
H
5
COOH.
Cu 23: S ng phn ng vi cng thc phn t C
3
H
5
Br bng
A. 2. B. 4. C. 3. D. 5.
Cu 24: Khi trn nhng th tch bng nhau ca dung dch A c pH = 13 v dung dch B c pH = 2 th thu
c dung dch c pH bng
A. 12,95 B. 12,65 C. 1,05 D. 1,35
Cu 25: Hn hp Z gm hai este X, Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong
dy ng ng (M
X
< M
Y
). t chy hon ton m gam Z cn dng 6,16 lt kh O
2
( ktc), thu c 5,6
lt kh CO
2
( ktc) v 4,5 gam H
2
O. Cng thc este X v gi tr m tng ng l
A. (HCOO)
2
C
2
H
4
v 6,6. B. HCOOC
2
H
5
v 9,5
Trang 3/5 - M thi 122
C. HCOOCH
3
v 6,7. D. CH
3
COOCH
3
v 6,7.
Cu 26: Cho 10,8 gam hn hp A gm Mg v Fe tc dng vi 500 ml dung dch AgNO
3
0,8M, sau khi
phn ng xy ra hon ton thu c dung dch B v 46 gam cht rn D . Thnh phn % khi lng ca
mt kim loi trong hn hp A l
A. 51,85% B. 22,32% C. 77,78% D. 25,93%
Cu 27: X l dung dch H
2
SO
4
0,02M, Y l dung dch NaOH 0,035M. Khi trn ln dung dch X vi dung
dch Y ta thu c dung dch Z c th tch bng tng th tch hai dung dch mang trn v c pH = 2. T l
th tch gia dung dch Y v dung dch X l
A. 2:1 B. 1:2 C. 3:2 D. 2:3
Cu 28: trung ho hn hp gm axit axetic, ancol propylic v p-crezol cn 150 ml dung dch NaOH
2M. Ho tan hon ton 28,8 gam hn hp trn trong hexan ri cho Na d vo th thu c 4,48 lt H
2
(
ktc). Lng p-crezol hn hp bng
A. 0,1 mol. B. 0,2 mol. C. 0,3 mol D. 0,4 mol
Cu 29: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch
A. Nu cho brom d vo dung dch A, sau phn ng hon ton, c cn thy khi lng mui khan thu
c gim 7,05 gam. Nu sc kh clo d vo dung dch A, phn ng hon ton, c cn dung dch thy
khi lng mui khan gim 22,625 gam. Thnh phn % khi lng ca mt cht trong hn hp X l
A. 47,8% B. 64,3% C. 35,9% D. 39,1%
Cu 30: Tinh th NaCl kt tinh theo kiu mng lp phng tm mt. S ion clo tip gip vi mi ion natri l
A. 4. B. 12. C. 8. D. 6.
Cu 31: t chy hon ton 200 ml hp cht hu c X (cha C, H, O) vi 1200 ml kh O
2
(ly d). Sau
phn ng th tch cn 1700 ml, sau khi i qua H
2
SO
4
c cn 900 ml v sau khi qua KOH cn 300 ml.
Xc nh cng thc phn t ca X, bit cc kh c o cng iu kin.
A. C
4
H
8
O
2
. B. C
4
H
8
O. C. C
3
H
6
O
2
. D. C
3
H
8
O.
Cu 32: Nung hn hp gm 11,2g Fe; 6,4g Cu v 26g Zn vi mt lng d lu hunh n hon ton.
Sn phm ca phn ng tc dng vi dung dich HCl d thu c kh A . Tnh th tch dung dch CuSO
4
10% (d = 1,1g/ml) ti thiu cn dng hp th ht kh A?
A. 750,25lm B. 872,73ml C. 1018,18ml D. 525,25ml
Cu 33: Cho isopren phn ng vi Br
2
theo t l 1:1. S sn phn thuc loi dn xut ibrom thu c
(khng xt ng phn hnh hc) l
A. 3. B. 4. C. 2. D. 1.
Cu 34: C bao nhiu ng phn l dn xut ca benzen c cng thc phn t C
7
H
6
O
2
?
A. 4. B. 5. C. 2. D. 3.
Cu 35: Cho m gam Cu tc dng vi 100ml dung dch hn hp HNO
3
0,9M v H
2
SO
4
0,2M thu c
0,672 lt kh NO ktc l sn phm duy nht v dung dch X c pH = x. Gi tr ca m v x l
A. 2,88 v 1,5. B. 1,92 v 1,5. C. 1,92 v 1,0 D. 2,88 v 1,0
Cu 36: Pht biu no di y khng ng?
A. M ng vt ch yu cu thnh t cc este ca cc axit bo no, tn ti th rn.
B. Du thc vt ch yu cu thnh t cc este ca cc axit bo khng no, tn ti th lng.
C. Hiro ho du thc vt lng s to thnh cc m ng vt rn.
D. Cht bo nh hn nc v khng tan trong nc
Cu 37: Polime no di dy c cu to khng iu ho?
A.
-H
2
C - C - C - CH
2
- CH
2
- C - C- CH
2
-
CH
3
CH
3
Cl
Cl
CH
3
CH
3
Cl
Cl
B.
-H
2
C - C - CH
2
- C - CH
2
- C - CH
2
-C-
CH
3
H
CH
3
H
CH
3
H
CH
3
H
C.
-H
2
C - C = C - CH
2
- CH
2
- C = C- CH
2
-
Cl
H
Cl
H
D.
-H
2
C - C - CH
2
- C - C H
2
- C -
H H
OOCCH
3
H
OOCCH
3
OOCCH
3
Cu 38: C 6 ng nghim, mi ng nghim cha mt trong cc dung dch sau: glixerol; glucoz; lng
trng trng; axit fomic; natri hiroxit; axit axetic . phn bit 6 dung dch ny c th dng mt loi
thuc th l
Trang 4/5 - M thi 122
A. Qi tm. B. CuSO
4
. C. AgNO
3
/NH
3
. D. Br
2
.
Cu 39: t chy hon ton 0,336 lt kh ( ktc) mt ankaien lin hp X. Sn phm chy c hp th
hon ton vo 40 ml dung dch Ba(OH)
2
1,5M thu c 8,865 gam kt ta . Cng thc phn t ca X l
A. C
3
H
4
hoc C
5
H
8
B. C
4
H
6
. C. C
3
H
4
. D. C
5
H
8
.
Cu 40: Khi trng ngng 7,5 gam axit amino axetic vi hiu sut 80%, ngoi amino axit cn d, thu
c m gam polime v 1,44 gam H
2
O. Gi tr ca m l
A. 5,56. B. 6,00. C. 4,25. D. 4,56.
Cu 41: Thm t t 300ml dung dch HCl 1M vo 200ml dung dch hn hp gm Na
2
CO
3
1M v
NaHCO
3
0,5M c dung dch A v gii phng V lt kh CO
2
ktc . Cho thm nc vi vo dung dch A
ti d thu c m gam kt ta trng. Gi tr ca m v V l
A. 15gam v 3,36lt B. 10gam v 3,36lt C. 10gam v 2,24lt D. 15gam v 2,24lt
Cu 42: So snh tnh baz ca cc cht sau: (a) C
6
H
5
NH
2
; (b) CH
3
-NH
2
; (c) CH
3
-C
6
H
4
-NH
2
; (d) O
2
N-
C
6
H
4
-NH
2
A. a> b > c > d B. a > b > d > c C. b > c > a > d D. b > c > d > a
Cu 43: ng vi cng thc phn t C
3
H
6
O c bao nhiu hp cht mch h bn khi tc dng vi H
2
(Ni,
t
0
) sinh ra ancol?
A. 4. B. 1. C. 2. D. 3.
Cu 44: Tn gi cho peptit
H
2
N-CH-CO-NH-CH
2
-CO-NH-CH-COOH
CH
3
CH
3
A. alanylglyxylalanyl. B. glixylalanylglyxin. C. glixylalanylglyxin. D. alanylglixylalanin.
Cu 45: Cho cc cht: tinh bt, benzen, cht bo, protein. S cht khi t chy ht trong khng kh to ra
hn hp chy gm CO
2
, H
2
O, N
2
l
A. 4. B. 5. C. 6. D. 3.
Cu 46: un nng 132,35 gam axit axetic vi 200 gam ancol isoamylic ((CH
3
)
2
CH-CH
2
CH
2
-OH) c
H
2
SO
4
lm xc tc thu c isoamyl axetat (du chui). Tnh lng du chui thu c, bit hiu sut
phn ng t 68%.
A. 97,5 gam. B. 195,0 gam. C. 292,5 gam. D. 159,0 gam
Cu 47: Trong s cc cht l propan, etyl clorua, axeton, v etyl axetat, th cht tan tt nht trong nc l
A. propan. B. etyl clorua C. etyl axetat D. axeton
Cu 48: Hn hp X gm CO v NO c t khi hi so vi H
2
l 14,5. V(l) hn hp X tc dng va vi
1,6g O
2
c hn hp Y. Cho Y sc vo 200 ml dung dch NaOH 2M c 200ml dung dch A . S cht
tan trong dung dch A v nng ca mt cht trong dung dch A l
A. 4 v 0,20M B. 4 v 0,25M C. 3 v 0,25M D. 3 v 0,20M
Cu 49: Nhng cu sau y, cu no sai ?
A. Cc nguyn t lin kt vi nhau thnh phn t chuyn sang trng thi c nng lng thp hn.
B. Phn t NH
4
NO
3
cha cc lin kt ion, lin kt cng ho tr.
C. Trong nhm A, cc nguyn t c xp theo chiu s hiu nguyn t tng dn.
D. Nguyn t ca cc nguyn t cng chu k c s electron bng nhau.
Cu 50: Hin tng ca th nghim no di y c m t khng ng?
A. Cho Br
2
vo dung dich phenol xut hin kt ta mu trng.
B. Cho qu tm vo dung dch phenol, qu chuyn mu .
C. Cho phenol vo dung dch NaOH, ban u phn lp, sau to dung dch ng nht.
D. Thi kh CO
2
qua dung dch natri phenolat xut hin vn c mu trng.
-----------------------------------------------
----------- HT ----------
Trang 5/5 - M thi 122
made cauhoi dapan
122 1C
122 2B
122 3C
122 4B
122 5A
122 6A
122 7C
122 8A
122 9C
122 10B
122 11C
122 12A
122 13D
122 14D
122 15D
122 16A
122 17B
122 18B
122 19C
122 20D
122 21D
122 22A
122 23D
122 24B
122 25C
122 26C
122 27D
122 28A
122 29A
122 30C
122 31D
122 32B
122 33A
122 34B
122 35D
122 36C
122 37A
122 38B
122 39A
122 40D
122 41C
122 42C
122 43D
122 44D
122 45A
122 46B
122 47D
122 48B
122 49D
122 50B