Professional Documents
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APPENDIX
Drawings List
Item : Document Title : Documen No. : Doc. size No of Pages Rev.
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Content
Firm’s history 3
Preface 3
1. Design features 4
2. Function 6
3. Tests 7
4. Type list 8
5. Technical data 20
6. Special designs 21
7. Ordering data 23
2
Firm’s history Preface
Since its foundation the company has been The Buchholz relay was developed in 1921 by Max
passed through an eventful history with regard Buchholz, Oberrat at the Prussian Electric supply
to ownership, affiliation and connected with this company - PLC in Kassel. Since that time it has been an
changes of firm names. important protection and monitoring device for liquid-
cooled transformers and choke coils. It is known for its
easy operation, high reliability, maintenance-free
operation and extremely long life.
1863 Foundation of the company
The Buchholz relay is built in the cooling cycle of the
as sugar factory
appliances to be protected and responds in the event of
troubles like gas accumulation, loss as well as high flow
1943 Establishment of SIEMENS
of the insulation liquid. For transformers with hermetical
Magdeburg
closure by means of a membrane (rubber sack) in the
expansion tank Buchholz relays can be used also as
1948 VEB1 Elektromotorenwerk
indicating device (“Air Cell Failure Relay”) of this
Barleben; VEM
membrane.
(state-owned firm)
The company has had for more than 50 years experience
1951 VEB1 Starkstromanlagenbau in producing Buchholz relays and other protection
Magdeburg devices for liquid-cooled appliances. It ranks among the
(state-owned firm) most distinguished manufacturers of this kind of
equipment. Experiences collected and profound know-
1951 Start of manufacturing how are the sound basis for a high product quality.
Buchholz relays at site References from reputed transformer manufacturers and
in Barleben further users are proof of the high level of the products.
The company is ISO 9001/2000 certified.
1970 VEB1 Elektrotechnik und
Gerätebau Magdeburg; The staff of highly qualified engineers and experienced
EGEM skilled workers do their best to guarantee top quality
(state-owned firm) high-precision products.
1
VEB = nationally owned firm
3
Elektromotoren und
Gerätebau Barleben GmbH
1. Design features
Casing
(Figures 1A and 1B)
The casing is a weather-resistant
casting of light alloy and is provided
with a paint coat. It is supplied either
with screwed or flanged ends (1).
The variants of casings are shown
under para. 4, further are possible on
request.
The casing has sightglasses (2) for
inspection of function of the switching
systems. The sightglasses with scale 2
divisions permit reading of collected
3
gas volume.
1
The relays can be equipped with lids
(3, may be folded up) before the Figure 1A: casing with
sightglasses. flange connection
Figure 1B: casing with
thread connection
Cover (Figure 2)
8
The cover is a weather-resistant casting
of light alloy and is provided with a paint
7 coat. Terminal box (1), test valve (2) and
5 test key, covered by a cap nut (3) as well
as a plate for operation of the test key (4)
are arranged above the cover. The
terminal box has an earthing contact (5)
9 and at most eight electrical connectors
9
(6). By the number of these connectors
6 the design of the switching systems
concerning kind and quantity of the
1 magnet contact tubes is determined.
The aluminium cap (7) seals the terminal
box. If the cap is opened the contact
setting (8) can be seen. The cable may
3 be optionally brought in through one of
2 both cable glands (9).
4
4
Switchgear (Figures 3A and 3B)
Switchgear of a single-float
Buchholz relay:
float (1)
permanent magnet(s) (2)
one or more magnet contact tube(s) (3)
frame (4)
mechanical testing device (5)
damper (6)
1
5 The damper is hold by permanent magnets.
2
6 3
4
Figure 3A: Switchgear of a single-float
Buchholz relay
Switchgear of a double-float
Buchholz relay:
4 1a
2a
5
Elektromotoren und
Gerätebau Barleben GmbH
2. Function
In the following the operation of a Buchholz relay is explained using the example of a double-float
Buchholz relay. The relay is built in the connecting pipe between the transformer tank and the
conservator. During normal operation it is filled completely with insulating liquid. Due to buoyancy the
floats are at their top position. If a fault occurs inside the transformer, the Buchholz relay responds as
follows:
The upper and lower switching system form a functional unit in the single-float Buchholz relay. In case
of a fault, the single-float Buchholz relay normally isolates the transformer immediately from the mains
system.
6
3. Tests
To each Buchholz relay a works-number is given mentioned in the test certificate. Furthermore the
tests made with each Buchholz relay are documented in the test certificate.
- operating instructions
- test certificate.
DIN EN ISO 9001:2000 certificate
7
Elektromotoren und
Gerätebau Barleben GmbH
4. Type list
4.1. Single-float Buchholz relays with thread connection
Type code no. Mode of DN Flange Device weight Suited for
Works-design. connection of pipe dimensions dimensions (kg) transformer
DIN-design. (mm) (mm) (mm) ratings of
d1 d2 d3 d4 d5 f l h1 h2
01 Connection
(AG 25) thread 25 - - - - 16 185 170 62 3.1 < 1600 KVA
4.1.1. Type 01
170
250
300
350
3
cm
f
d1
l
G 11/ 2"
02
Flange
(AF 25/6) 4-holes 25 100 75 60 12 12 185 195 62 3.6 <1600 KVA
(-)
03
Flange
(AF 25/10) 4-holes 25 115 85 68 14 16 200 205 62 4.0 < 1600 KVA
(-)
25
Flange
(AF 25) 4-holes 25 100 75 -- 12 10 160 195 62 3.3 < 1600 KVA
(-)
250
300
350
cm3
f d1
l d4
d3
d2
8
4.3. Single-float Buchholz relays – possible switching system designs
As switching elements are used magnet contact tubes. There are normally-closed (NC), normally-
open (NO) or change-over (CO) versions.
For coding of the switching system version see point 7. ordering data, page 23.
The magnet contact tube version is coded by the last figure of the ordering number.
14 12 14 24 12 22 14 12 2 4
22 24 12 14 24 12 14 22 12 14
1
1 1 change-over Note:
(CO) --- Graphical symbol with
terminal marking The switching systems is shown in
its normal position, i.e. with the
2 4 Buchholz relay filled completely
with insulating liquid corresponding
to trouble-free operation of the
device to be monitored.
Terminal assignment
---
in terminal box
A plate showing the connection diagram and the terminal assignment is arranged inside the
cover of each Buchholz relay delivered by EMB.
9
Elektromotoren und
Gerätebau Barleben GmbH
Connection
04 thread
(BG 25) 25 - - - - 16 185 235 90 4.2 < 5000 KVA
(DG 25) 1
G 1 /2 “
Connection
21 thread
(BG 25 S) 25 - - - - 16 185 235 90 3.6 < 5000 KVA
(-) 1
G 1 /2 “
4.4.1. Type 04
170
250
300
350
cm 3
l d1
G11 /2"
4.4.2. Type 21
1 50
250
300
350
3
cm
d1
l
10
4.5. Double-float Buchholz relays with flange connection (round)
05
Flange
(BF 25/6) 4-holes 25 100 75 60 12 12 185 235 90 4.4 < 5000 KVA
(-)
06
(BF 25/10) Flange
(DR 25) 4-holes 25 115 85 68 14 18 200 235 90 4.8 <5000 KVA
23
Flange
(BF25/10S) 4-holes 25 115 85 68 14 18 200 235 90 4.4 < 5000 KVA
(-)
07
Flange > 5000 KVA
(BF 50/6) 4-holes 50 140 110 90 14 12 185 235 80 4.6
< 10000 KVA
(-)
08
Flange > 5000 KVA
(BF 50/10) 4-holes 50 165 125 102 18 16 195 250 80 5.9
< 10000 KVA
(DR 50)
09
Flange
(BF 80/10) 4-holes 80 200 160 138 18 15 195 265 80 6.2 > 10000 KVA
(-)
09-26.
Flange 18
(BF80/10/8) 8-holes 80 200 160 138
M16
15 195 265 80 6.2 > 10000 KVA
(DR 80)
24
Flange
(BF 80/6) 4-holes 80 190 150 130 18 15 195 260 80 6.0 > 10000 KVA
(-)
11
Elektromotoren und
Gerätebau Barleben GmbH
4.5.2. Type 23
1 50
250
300
350
cm3
f d1
l d4
d3
d2
250
300
350 M 16
cm3
f
l d1
d4
d3
d2
12
4.6. Double-float Buchholz relays with flange connection (square)
Type code no. Mode of DN Flange Device weight Suited for
Works-design. connection of pipe dimensions dimensions (kg) transformer
DIN-design. (mm) (mm) (mm) ratings of
d1 b d3 d4 d5 f l h1 h2
10 Flange
(BF 80/Q) square
4-holes
80 125 132 - 18 20 200 235 80 5.0 > 10000 KVA
(DQ 80)
4.6.1. Type 10
63 Flange
(BC 80) square
4-holes
80 160 160 - 18 15 185 245 80 5.0 > 10000 KVA
(QJ-80)
Suited for connecting to Chinese butterfly valves (square flange). Further types on request.
4.7.1. Type 63
13
Elektromotoren und
Gerätebau Barleben GmbH
41 Flange
(NF 25) 4-holes 25 115 85 14 8 240 235 90 4.2 < 5000 KVA
43 Flange
(NF 80) 4-holes 80 200 160 18 11 240 265 80 5.5 > 10000 KVA
1 50
250
300
350
cm 3
f
d1
240
d3
d2
14
4.9. Double-float Buchholz relays with geometrical flange dimensions
according to British standard
Type code no. Mode of DN Flange dimensions Device dimensions weight Suited for
Works-design. connection of pipe (mm) (mm) (kg) transformer
(inch) (inch)
(mm) ratings of
d2 d3 d5 f l h1 h2 h3
(inch)
d1
Flange
51 - 72 M10 127 235 90 80
(BS 25)
square 25 - 2.83 M10
-
5 9.25 3.54 3.15
3.7 < 5000 KVA
4-holes
4.9.1. Type 51
15
Elektromotoren und
Gerätebau Barleben GmbH
As switching elements are used magnet contact tubes. There are normally-closed (NC), normally-
open (NO) or change-over (CO) versions.
For coding of the switching system version see point 7. ordering data, page 23.
The switching system version is coded by the last two figures of the ordering number.
13 13 13 13 13 13
14 14 14 14 14 14
23 23 11 23 33 11 21 23 11
12 24 34 12 22 24 12
24 24
23 13 13 11 11
14 12 12
24 14
11 21 31 13 21
23 33 43
22 24 32 34
24 34 44
12 14 14 22
16
...23 ...24 ...25 ...26 ...27 ...31
Alarm Alarm Alarm Alarm Alarm Alarm
1 NC 1 NC 1 NC 1 NC 1 NC 1 CO
11 11 11 21 11 21
12 12 12 22 12 22 24
22 24 32 34
14 24 22 32 14 22 12 14 14
21 21 21 21 21 13 23
22 24 22 24 22 24 22 24 22 24 14 24
12 34 44 32 42 14 12
12 14 34
14 13 34 33
17
Elektromotoren und
Gerätebau Barleben GmbH
13 23 13 23 13 23 13 23 23 33 11 13
14 24 14 24 14 24 14 24 24 34 12 14
34 44 12 22 34 12
12 12 14 24
12 14 12 14 12 14 22 24
12 14
21 23 33 21 31 23 21 11
24 34 22 32 24 22 12 14
22
18
Magnet contact tube version
Explanation of symbols: Upper switching system - Alarm
13
Alarm
1 NO
14
--- Graphical symbol with
terminal marking
11
Disconnection
1 NC
12
Terminal assignment
---
in terminal box
Note:
The switching systems are shown in their normal position, i.e. with the Buchholz relay filled
completely with insulating liquid corresponding to trouble-free operation of the device to be
monitored.
A plate showing the connection diagram and the terminal assignment is arranged
inside the cover of each Buchholz relay delivered by EMB.
19
Elektromotoren und
Gerätebau Barleben GmbH
5. Technical data
The technical data listed in table 1 are valid for all Buchholz relays manufactured by EMB.
More options are mentioned in table 2 on page 21. These additional special designs should be coded
with the relevant identification number when ordering Buchholz relays.
Table 1
20
6. Special designs
Table 2
Degree of protection IP 56 38
Degree of protection IP 66 39
* These identification numbers you can use also for ordering gas sampling device ZG 1.2.
Attention: For constructional reasons the following special designs are not combined possible in
the same device:
21
Elektromotoren und
Gerätebau Barleben GmbH
The functional test using compressed air results from British Standard B.E.B.S. T2 of 1966.
250
100
22
7. Ordering data
For placing orders, please, use the following key:
XX - XX ... XX .- X 0 X XX - XX ... XX .- XX X X
Type code no. Type code no.
(see para. 4) (see para. 4)
Special design
Special design (see table 2)
(see table 2) (There are several
(There are several identif. no. possible,
identif. no. possible, always separated by
always separated by a dot.)
a dot.)
9 = three NO-contacts
For possible switching designs, please, see for single- Important remark:
float Buchholz relays on page 9 and for double-float NO = normally-open contact
Buchholz relays on page 16-18. NC = normally-closed contact
CO = change-over contact
Ordering example:
Buchholz relay 10-25.28.44.-0313 10 = double-float Buchholz relay type 10 (BF 80/Q)
25 = lower switching system equipped with 2 magnet contact tubes
28 = oil drain plug
44 = colour RAL 7033
03 = damper setting of 1.50 m/s
1 = contact setting of upper switching system - 1 NO-contact
3 = contact setting of lower switching system - 2 NO-contacts
23
Elektromotoren und
Gerätebau Barleben GmbH
Technical data:
Gas outlet opening: R 1/8“ others on request
Oil outlet opening: R 1/8“ others on request
Viscosity of the insulation liquid: <1100 mm²/s
Temperature of the insulation liquid: -40°C to +115°C others on request
Ambient temperature: -40°C to +55°C others on request
Weight without tubing: 2.2 kg
Dimensions:
Ordering data:
90 XX ... XX . X XX,XXm
type code special design 0 = without box tubing length
for ZG 1.2. (see table 2, page 21) 1 = with box in meter
(There are several
identif. no. possible,
always separated by
a dot.)
Ordering example:
Gas sampling device 90-34.44.-0-10,50m 90 = ZG 1.2.
34 = extreme frigidal open-air climates below -40°C
44 = colour RAL 7033
0= without box
10,50m = tubing length of 10,50 m
24
designation description
Reflux lock
ZG 4.1.
The device prevents that the insulation liquid gets into the
Gas testing device. The device is arranged between the
Buchholz relay or gas sampling device and gas testing device.
25
Elektromotoren und
Gerätebau Barleben GmbH
designation description
Buchholzgas - Sampler
BGS The Buchholz gas sampler serves to safely take and
Transport gas samples from the Buchholz relay or the
gas sampling device. Its capacity is 100 ml. The gas
sampled can be stored up to five days.
Buchholzgas - Tester
BGT The Buchholz gas tester serves to measure the hydrogen
concentration of the Buchholz gases. Measurement can be
performed directly on site. For any other gas testing equipment,
please, contact us.
For any other information, please, ask for special reference material.
26
9. Further protection devices
designation description
SG 25 Flow indicator
For any other information or data required for placing an order, please, ask for
special catalogues.
27
Elektromotoren und
Gerätebau Barleben GmbH
Bahnhofstraße 27/28
39179 Barleben / Germany
e-mail: info@emb-online.de
Internet: http://www.emb-online.de
Due to technical improvement of our products, the information contained in this brochure may be
subjected to change without notice.
28
NOTICE
THIS DRAWING IS THE PROPERTY OF QUALITROL/QUALITROL AKM AND IS LOANED ONLY ON THE
MODEL
CONDITION THAT IT WILL BE USED TO FACILITATE THE PURPOSE FOR WHICH INTENDED AND NOT
BE REPRODUCED, COPIED OR OTHERWISE DISPOSED OF, AND IS NOT TO BE USED IN WHOLE
OR PART FOR FURNISHING INFORMATION RELATIVE TO THE MAKING OF DRAWINGS, PARTS
NO. AKM345-CS100617
APPARATUS OR PARTS THEREOF, EXCEPT BY WRITTEN ORDER FROM QUALITROL/QUALITROL AKM.
190 100
58 98
280
80
140
M25
25 BSP 1"
AKM 3440615X-6.0 SERIES 34
Ø14
4 = 4 contacts 118
X = Measuring range -10 to 150°C
15 = Bulb type
6.0 = Capillary length
Output = TD119-3 10
Label = 46894 OTI
Protection class = IP54 160
Cable Entry = Adapter with M25 cable glands
Certificates = Calibration Cert, Bulb type 15 shown 11 12 14 21 22 24 31 32 34 41 42 44 61 62 63
190 100
58 98
280
80
140
M25
25 BSP 1"
AKM 3540615X-6.0 SERIES 35
Ø14
4 = 4 contacts 118
X = Measuring range -10 to 150°C
15 = Bulb type
6.0 = Capillary length
Output = TD119-3 10
Label = 46895 WTI
Protection class = IP54 160
Cable Entry = Adapter with M25 cable glands
Certificates = Calibration Cert, Bulb type 15 shown 5 5 11 12 14 21 22 24 31 32 34 41 42 44 61 62 63
Product Summary
Description Capillary based, mechanical, remote
The next generation thermometer • Over 75 years of experience designing mechanical temperature
from the global leader measurement devices for transformers
• Over 250,000 capillary type thermometers in service worldwide in all
environmental conditions
• Improved connection ease with a greater number of cable glands;
3xM25 style and 2xM20 style
• Improved switching flexibility with up to 6 fully configurable switches
• New and improved swing out case design allows for easy cable
connection, switch configuration and testing without removal of the cover
Accomplish the most demanding • Up to 6 fully independent switches flexible enough for most
control and alarm configurations control and alarm schemes
• Each switch can be specified by switch type, hysteresis range, and
set point, without limitation of sequential set points
• Standard switch rated for up to 15 Amps AC and up to 10 Amp DC,
switches also available for higher VDC (magnetic blow out, M.B.O.),
and switches for milliamp loads-- see technical specifications for
more information
• Various analog outputs also available (mA, Pt 100, and Cu 10) -- see
technical specifications for more information
• Each switch can be specified with adjustable hysteresis (5 to 25°C)
Reduce failure costs with reliable • Non-pressurized bellows system avoids problems due to leakage
AKM bellows operation • Integrated heating element in bellows for winding temperature
indication eliminates extra cost and complexity of accessories to
simulate the winding
• AKM bellows system provides a 260° dial deflection (angle the pointer
travels from minimum to maximum) making it easier to interpret
temperature reading from a distance
Minimize installation complexity • Single enclosure design minimizes need for additional accessories
with all-in-one design such as matching units and heated wells commonly used by other
mechanical temperature solutions
• New hinged cover enables easy access to switch settings and
connections during installation while shielding device from elements.
Features all captive screws and can be completely removed, if necessary
• Same installation footprint and mounting options as the previous
generation AKM 345
• Improved wiring installation with addition of 2 cable glands (for a total
of 5) and an increase in size to 3xM25 and 2xM20 versus the
previous generation
Simplify operations by using one • Wide range of options allow for standard use of one thermometer
family of thermometer for series across a wide array of applications and operating conditions
all environmental conditions • Extreme temperature survivability with polar executions for use
down to -60°C
• Enclosures with IP55 or IP65 rating with numerous mounting
configurations available
• The most flexible switching capabilities available for implementation
of any control and alarm configuration
?
Don’t see what you need?
QUALITROL regularly creates models with special customer requirements.
Contact your local sales representative or QUALITROL Application Engineer
to review your special requirements.
maximum readability
System provides a 260° dial deflection
(angle the pointer travels from
minimum to maximum) making it easier
to interpret temperature
reading from a distance
NEW Electronic output KITS
AKM bellows technology Various analog outputs available (mA,
Low-pressure bellows system Pt 100, and Cu 10) - user upgrade
avoids problems due to possible via rear access panel
leakage for life long accuracy
NEW 6 switch capability
integrated winding Up to 6 fully independent
simulation switches flexible enough for the
Integrated heating element in AKM most demanding control and
bellows for winding temperature alarm schemes
indication eliminates extra cost and
complexity of accessories to
simulate winding temperature
Remote indicators • Digital and analog indicators available for remote display of
temperature measurement
• For use with 4-20 mA output option
Power supply • For use with remote indicators and remote electronic outputs
when 24 VDC is not available
• Universal power supply
• DIN rail mounting
Pass through capillary gland • For environmental isolation when capillary needs to pass
through an enclosure such as the control cabinet
Electronic output user upgrade kit • Add electronic output capability to units previously purchased
without output
• Upgrade possible through back access panel
• Boards capable of mA, Pt100, Cu10, and voltage outputs for
remote indication and integration with SCADA systems
Email info@qualitrolcorp.com
www.qualitrolcorp.com
TECHNICAL SPECIFICATIONS
Winding thermal image Internal winding simulation: TD50 (up to 2.2A CT max) or
TD76 (up to 2.65A CT max)
External winding simulation: (AKM 44678) up to 2A CT or
(AKM 44674) up to 1,2A CT max, matching unit (AKM 44677)
for up to 5A CT max
Cover Swing up cover design, fully detachable, with all captive hardware
Switching differential (hysteresis) 10° to 14°C for most dial ranges, optional adjustable
differential from 5° to 25°C
Dielectric isolation (hi pot) 2500 VAC at 50Hz, 60 seconds, all terminals to ground
Ambient operating temperature -40°C to 70°C (-40°F to 158°F), polar execution available for
-60°C to 70°C (-76°F to 158°F)
Email info@qualitrolcorp.com
www.qualitrolcorp.com
Standard mounting
To further improve reliability, QUALITROL provides comprehensive education and on-site commissioning services, main-
tenance contracts and technical support to all customers worldwide. Emergency response is available on all products
and services.
About QUALITROL ®
QUALITROL Company LLC manufactures substation and transformer monitoring and protection devices used by electric
utilities and manufacturing companies. It is the global leader in sales and installations of transformer asset protection
equipment, fault recorders and fault locators. Established in 1945, QUALITROL Company produces thousands of differ-
ent types of products on demand, each customized to customers’ unique requirements.
©2008 QUALITROL® Company LLC, an ISO 9001 system certified company. All rights reserved. Information subject to change without notice.
All trademarks are properties of their respective companies, as noted herein. AP-T02-03L-01E.
Email info@qualitrolcorp.com
www.qualitrolcorp.com
n250
(4) n13
60°
n102 B.C. 13.00
49.50
99
21°
470
4 60°
252
29
71° FLOAT ROD STOP
n36
MIN 11 21 MAX
TITLE:
14 24 NOTICE
THIS DRAWING IS THE PROPERTY OF QUALITROL/QUALITROL AKM
ON LOWERING LEVEL, 11 CLOSES AND IS LOANED ONLY ON THE CONDITION THAT IT WILL BE USED MATERIAL:
TO FACILITATE THE PURPOSE FOR WHICH IT WAS INTENDED
ON 14 AND OPENS ON 12 AT "MIN" AND NOT BE REPRODUCED, COPIED OR OTHERWISE DISPOSED OF,
AND IS NOT TO BE USED IN WHOLE OR PART FOR FURNISHING
ON RISING LEVEL, INFORMATION RELATIVE TO THE MAKING OF DRAWINGS, PARTS,
APPARATUS OR PARTS THEREOF, EXCEPT BY WRITTEN ORDER
21 CLOSES ON 24 AND OPENS ON FROM QUALITROL/QUALITROL AKM. - 08-17-09 UPDATED WIRING PRELIMINARY
22 AT 0°C "MAX" FINISH:
LET DATE ALTERATION C.N.
| ,g,s
{+
Unteres Schul
-i l = sruFFtNG-cLANDS TERMINALBOX
f*
I I l
470-4 50
sK470-4
sK 1343 2,0811,20 525 2,25 69,0
sK 470-4 60 1580 3,20/1,85 850 2,63 145 73,5
sK470-6
sK 470-6 50 ges
963 \2110,70 260 1,61 54 62r0
sK470-6 60 1118 l,4llo,82 330 1,87 72 65,5
470-8I 50
sK470-8
sK 720 i 1,18i0,68 155 1,25 30 53,0
sK 470-8 60 830 1,04/0,60 180 l,4l 4l 58,0
2. Chemical
3. Electrical
Dielectric dissipation
factor (DDF) at 90°C IEC 60247 0,005 <0,001
Interfacial tension mN/m ISO 6295 40 49
Breakdown voltage
- Before treatment kV IEC 60156 30 40-60
- After treatment kV IEC 60296/60156 70 >70
4. Oxidation Stability
Nytro Libra is an uninhibited transformer oil, meeting IEC 60296 (03) General specifications.
Naphthenics Safety Data Sheet 21.11.2006
P. O. Box 10701
S-121 29 STOCKHOLM
Sweden
Telephone No: +46-8-602 1200 Fax: +46-8-81 62 02
Composition/Information of Ingredients
2.
3. Hazards identification
Human Health: Inhalation of vapours and/or mists might irritate respiratory tract.
Prolonged skin contact will cause defatting and possible irritation. Eye contact might cause irritation.
Environment: Slow biodegradation, the product will remain for long time in the environment. Risk for contamination
of earth, soil and water.
Physical and chemical hazard: At elevated temperatures flammable vapours and decomposition products will be released. Risk for
slippery floors if spilled out.
First Aid Measures
4.
General advice:
Inhalation: If inhalation of mists, fumes or vapours occur causing irritation, move to fresh air. If the symptoms
persist, obtain medical advice.
Skin contact: Remove immediately adhering matter and wash off with soap and plenty of water.
Ingestion: Clean mouth with water. Obtain medical advice if a large amount has been swallowed. Do not induce
vomiting.
Fire-fighting Measures
5.
Suitable extinguishing media: Extinguish preferably with dry chemical, carbon dioxide (CO2), or foam. Waterspray / mist may be
used.
Extinguishing media which must not be Water jet, unless used by authorised people.(Stain risk caused by combustion).
used for safety reasons:
Personal precautions: Suitable protection equipment should be used. In case of large spillage, the cleaning procedure should
be carried out using suitable protective clothing such as overall, gloves and boots. Remove
contaminated clothes as soon as possible.
Handling: Handle in accordance with good industrial hygiene and safety practices. If handled at elevated
temperatures or with high speed mechanical equipment, vapours or mists might be released and require a
well ventilated workplace.
Storage: Store at ambient temperature or with lowest necessary heating as handling requires.
8. Exposure Controls/Personal Protection
Engineering measures to reduce exposure: Mechanical ventilation and local exhaust will reduce exposure via the air. Use oil resistant material in
construction of handling equipment. Store under recommended conditions and if heated, temperature
control equipment should be used to avoid overheating.
Personal protection equipment:
- Respiratory protection: If the product is heated under manual handling, use suitable mask with filter A1P2 or A2P2. Handling in
automatic production lines, with exhaust or ventilation, will not require mask.
- Hand protection: Wear oil-resistant protective gloves if there is a risk of repeated skin contact. Suitable gloves
are neoprene, nitrile- or acrylnitrilebutadiene rubber, or PVC. Take notice of CEN 420:94, CEN 374:1-
3:94 and CEN 388:94.
- Eye protection: Wear safety goggles / safe shield if splashes may occur.
- Skin and body protection: Wear protective clothing if there is a risk of skin contact and change them frequently, or when
contaminated.
Hygienic measures: Act in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
to IP346:
Hazardous decomposition products: Flammable gases which might also be noxious. With air present, there is a risk for auto ignition at
temperatures >270°C.
Toxicological Information
11.
Acute toxicity: Studies available indicate oral and dermal LD50 s of >5 000 mg/kg which is considered as low acute
toxicity.
Local effects:
- Inhalation: Prolonged and repeated inhalation of mist or vapour generated at elevated temperatures may irritate
respiratory tract.
- Oral: May cause nausea and eventually vomiting and diarrhoea.
- Skin contact: Prolonged or repeated exposure may lead to defatting of the skin and subsequent irritation.
Persistence/degradability: The baseoil is not readily biodegradable. Substances may not meet criteria for ready biodegradability.
Studies indicate inherent, primary
Disposal Considerations
13.
Residues of unused product is not regarded as hazardous waste. Residues of products/packageing must not be disposed of in the environment, but
taken care of in accordance with local regulations.
Emptying instructions:
Barrels and equals: Turn the barrel upside down and tilt it approximately 10° until nondripping.
Nondripping is less than one drop / minute at 15 °C. The product viscosity depends on temperature, and it is important that the emptying not is done
at to low temperature. It can be necessary to scrape out highviscous products.
When the barrel is nondripping send it for recycling. If the residue volume is more than 1% send it for destruction of barrels. Empty barrels with < 1
% residue is not dangerous goods. Notify local regulations.
Bags for one way use/multiple use: Follow instructions given by the bag manufacturer. The last residues in the bag can be removed by placing the
hose over the remaining residues or by lifting the bag so the product can run towards the hose.
Bottom residues; roll up the bag towards the hose to press out the oil
One way bags of polyethylene can be recycled or disposed of by incineration. Notify local regulations.
The product is not classified as hazardous goods for land, sea and air transport according to the respective regulations (ADR, IMDG, IATA-DGR).
15. Regulatory Information
Classified according to European directives on classification of hazardous substances and preparations. Not classified as hazardous. No statutory
label required.
Other Information
16.
The information for labelling and ecotoxicity is according to Concawe Report No. 95/59, 98/54, 05/6 and 01/54.
Classified according to the Dangerous Substance Directive, 67/548/EC up to the 29th ATP, the Dangerous Preparation Directive 1999/45/EC, and the
Safety Data Sheet Directive 2001/58/EC.
Component CAS no 64742-53-6 has DMSO extractible compounds according to IP 346 <3%.
Component CAS no 64742-55-8 has DMSO extractible compounds according to IP 346 <3%.
Component CAS no 64741-97-5 has DMSO extractible compounds according to IP 346 < 3%
Published: 2006-11-21
Nota L
The classification as a carcinogen need not apply if it can be shown that the substance contains less than 3 w%w
DMSO extract as measured by IP 346. This Nota applies only to certain complex oil-derived substances in Annex 1.
Nota N
The classification as a carcinogen need not apply if the full refining history is known and it can be shown that the substance from which it was
produced is not a carcinogen. This Nota applies only to certain complex oil-derived substances in Annex 1.