BI TP ANKYLBENZEN

Bi tp l thuyt.
- CTTQ, ng phn, danh
301/ Trong phn t benzen:
a.6 nguyn t H v 6 C u nm trn 1 mt phng.
b.6 nguyn t H nm trn cng 1 mt phng khc vi mp ca 6 C
c.Ch c 6 C nm trong cng 1 mt phng.*
d. Ch c 6 H mm trong cng 1 mt phng.
302/ Cho cc CT :
H

(1)
(2)
(3)
Cu to no l ca benzen:
a.(1) v (2)
c.(2) v (3)
b.(1) v (3)
d.(1) ; (2) v (3)*
303/ Dy ng ng ca benzen c cng thc chung l:
a.CnH2n+6 ; n6
c. CnH2n-6 ; n6
b. CnH2n-6 ; n3
d. CnH2n-6 ; n6*
304/ Cho cc cht C6H5CH3 (1) p-CH3C6H4C2H5 (2)
C6H5C2H3 (3) o-CH3C6H4CH3 (4)
Dy gm cc cht l ng ng ca benzen l:
a.(1);(2) v (3)
c.(1);(3) v (4)*
b.(2);(3) v (4)
d.(1);(2) v (4)
305/ Cho cu to sau:C tn gi g sau y:
CH3

CH3

a.o-xilen
b.m-xilen*
306/ CH3C6H2C2H5 c tn gi l:
a.etyl,metylbenzen
b. metyl,etylbenzen
307/ (CH3)2CHC6H5 c tn gi l:
a.propylbenzen
b.n-propylbenzen
308/ Ankylbenzen l HC c cha :
a.vng benzen
b.gc ankyl v vng benzen

c.p-xilen
d.1,5-imetylbenzen
c.p-etyl,metylbenzen*
d.p-metyl,etylbenzen
c.i-propylbenzen*
d.imetylbenzen
c.gc ankyl v 1 benzen
d.gc ankyl v 1 vng benzen*

309/ iu no sau u khng ng kh ni v 2 v tr trn 1 vng benzen:

a. v tr 1,2 gi l ortho
c. 1,3-meta
b. 1,4-para
d. 1,5-ortho*
311/Mt ankylbenzen A (C12H18)cu to c tnh i xng cao.A l:

a.1,3,5-tri etylbenzen
c. 1,2,3-tri metylbenzen
b. 1,2,4-tri etylbenzen
d. 1,2,3,4,5,6-hexametylbenzen*
313. C7H8 c s ng phn thm l:
a.1*
b.2
c.3
d.4
314. A l ng ng ca benzen c cng thc nguyn l: (C3H4)n. Cng thc phn t ca A
l:
a.C3H4
b.C6H8
c.C9H12*
d.C12H16
315. ng vi cng thc C9H12 c bao nhiu ng phn c cu to cha vng benzen?
a.6
b.7
c.8*
d.9
Cu 342/ Cht no sau y c th cha vng benzen:
a.C10H16
b. C9H14BrCl
c. C8H6Cl2*
d. C7H12
Cu 343/ Cu to ca 4-cloetylbenzen l:
C2H5

C2H5

C2H5

C2H5
Cl

Cl
a.
b.
c.
d.
Cu 344/ ng vi cng thc phn t C8H10 c bao nhiu cu to cha vng benzen?
a.2
b.3*
c.4
d.5
Cu 345/ Cht no sau y khng th cha vng benzen
a.C8H10
b. C6H8*
c. C8H10
d. C9H12
Cu 352/ Gc C6H5-CH2- c tn gi l:
a.Phenyl
b.Vinyl
c.anlyl
d.benzyl*
Cu 360/ Cho cc cht (1)benzen ; (2) toluen; (3)xiclohexan;(4)hex-5-trien; (5)xilen;(6) Cumen
Dy gm cc HC thm l:
a.(1);(2);(3);(4)
c. (2);(3);(5) ;(6)
b. (1);(2);(5;(6)*
d. (1);(5);(6);(4)
Cu 374/ Cng thc tng qut ca hirocacbon CnH2n+2-2a.i vi stiren ,gi tr ca n v a ln
lt l:
a. 8 v 5
b.5 v 8
c.8 v 4
d.4 v 8
Cu 375/ Cng thc tng qut ca hirocacbon CnH2n+2-2a.i vi naptalen ,gi tr ca n v a ln
lt l:
a.10 v 5
b.10 v 6
c.10 v 7*
d.10 v 8
Cl

Cl

- Tnh cht vt l
Cu 319. Tnh cht no sau y khng phi ca ankyl benzen
a.Khng mu sc
c.Khng tan trong nc
b.Khng mi v*
d.Tan nhiu trong cc dung mi hu c
Cu 320. Hot tnh sinh hc ca benzen, toluen l:
a.Gy hi cho sc khe*
c.Gy nh hng tt cho sc khe
b.Khng gy hi cho sc khe
d.C th gy hi hoc khng gy hi

- Tnh cht ho hc
Cu 321. Tnh cht no khng phi ca benzen?
a.Tc dng vi dung dch Br2 (Fe)
b.Tc dng vi HNO3 /H2SO4()

c.Tc dng vi dung dch KMnO4*

d.Tc dng vi Cl2 (as)

Cu 322. Tnh cht no khng phi ca toluen?

a.Tc dng vi dung dch Br2 (Fe)
c.Tc dng vi dung dch KMnO4, t0
b.Tc dng vi Cl2 (as)
d.Tc dng vi dung dch Br2 *
Cu 324. Toluen + Cl2 (as) xy ra phn ng:
a.Cng vo vng benzen
c.Th nhnh, kh khn hn CH4
b.Th vo vng benzen, d dng hn
d.Th nhnh, d dng hn CH4*
Cu 325. Tin hnh th nghim cho nitro benzen tc dng vi HNO3/H2SO4 (), nng ta thy:
a.Khng c phn ng xy ra
b.Phn ng d hn benzen, u tin v tr meta
c.Phn ng kh hn benzen, u tin v tr meta*
d. Phn ng kh hn benzen, u tin v tr ortho
Cu 326. Dy cc nhm th lm cho phn ng th vo vng benzen d dng hn v u tin v tr
o- v p- l:
a.-CnH2n+1, -OH, -NH2, *
c.CH3, -NH2, -COOH
b.OCH3, -NH2, -NO2
d.NO2, -COOH, -SO3H
Cu 327. Dy gm cc nhm th lm cho phn ng th vo vng benzen u tin v tr m- l:
a.-CnH2n+1, -OH, -NH2
c.CH3, -NH2, -COOH
b.OCH3, -NH2, -NO2
d.NO2, -COOH, -SO3H*
Cu 317. A l dn xut benzen c cng thc nguyn (CH)n. 1 mol A cng ti a 4 mol H2 hoc 1
mol Br2(dd). Vy A l:
a.etyl benzen
c.vinyl benzen*
b.metyl benzen
d.ankyl benzen
Cu 336. Tnh cht no khng phi ca benzen?
a.D th
c.Bn vi cht oxi ha
b.Kh cng
d.Km bn vi cc cht oxi ha
Cu 337. A xt ,t
toluen + 4H2. Vy A l:
a.metyl xiclo hexan
c.n-hexan
b.metyl xiclo hexen
d.n-heptan
Cu 338. Benzen + X etyl benzen. Vy X l
a.axetilen
b.etilen
c.etyl clorua
d.etan
Cu 339. C6H6 + Y xt ,t
etyl benzen + 4 HCl. Vy Y l:
a.CH2ClCH2Cl
c.CH3CH2Cl
b.CH2=CHCl
d.CH2=CH-CH2Cl
Cu 346/ Phn ng chng minh tnh cht no;khng no ca benzen ln lt l:
a.th,cng*
c.chy,cng
b.cng,nitro ho
d.cng,brom ho
Cu 347/ phn bit c cc cht Hex-1-in,Toluen,Benzen ta dng 1 thuc th duy nht l:
a. dd AgNO3/NH3
b.dd Brom
c.dd KMnO4*
d.dd HCl
Cu 348/ D phn bit d dng Hex-1-in,Hex-1-en,benzen ta ch dng 1 thuc th duy nht l:
a. dd Brom *
c.dd [Ag(NH3)2]OH
b. dd AgNO3/NH3
d.dd HCl
Cu 350/ Phn ng Benzen tc dng vi clo to C6H6Cl6 xy ra trong iu kin:
a. c bt Fe xc tc
c.c dung mi nc
b.c nh snh khuych tn*
d.c dung mi CCl4
as
Cu 361/ 1 mol Toluen + 1 mol Cl2
A . A l:
o

a.C6H5CH2Cl*
c. o-ClC6H4CH3
b. p-ClC6H4CH3
d.B v C u ng
H SO d

Cu 362/ 1 mol nitrobenzen + 1 mol HNO3

B + H2O. B l:
t
a.m-initrobenzen
c. p-initrobenzen
b. o-initrobenzen
d.B v C u ng.
Cu 364/ Stiren khng phn ng c vi nhng cht no sau y:
a.dd Br2
b.khh H2 ,Ni,to
c.dd KMnO4
d.dd NaOH
trung / hop
Cu 372/ Cho phn ng A
1,3,5-trimetylbenzen .A l:
a.axetilen
c.etyl axetilen
b.metyl axetilen *
d.imetyl axetilen
Cu 376/ Benzen A o-brom-nitrobenzen.Cng thc ca A l:
a.nitrobenzen
c.aminobenzen
b.brombenzen*
d.o-ibrombenzen
Cu 377/ C2H2 A B m-brombenzen .A v B ln lt l:
a.benzen ; nitrobenzen*
c. nitrobenzen ; benzen
b.benzen,brombenzen
d. nitrobenzen; brombenzen
Cu 378/ Phn ng ng trng hp gia stiren v buta-1,3-ien to ra sn phm l:
a.cao su buna
c.cao su buna-S*
b.cao su buna-N
d.cao su isopren
2

- ng dng, iu ch.
Cu 340. ng dng no benzen khng c:
a.Lm dung mi
c.Lm nhin liu
b.Tng hp monome
d.Dng trc tip lm dc phm
Cu 341. Thuc n TNT c iu ch trc tip t
a.benzen
b.metyl benzen
c.vinyl benzen
d.p-xilen
Cu 349/ Phn ng no sau y khng dng iu ch Benzen:
a.tam hp axetilen
c.kh H2,ng vng n-hexan
b.kh H2 ca xiclohexan
d.tam hp etilen*
Cu 351/ Phn ng no khng iu ch c Toluen?
c.kh H2 metylxiclohexan
a.C6H6 + CH3Cl
AlCl ;t
d.tam hp propin*
b. kh H2,ng vng benzen
3

Bi tp tnh ton.
Cu 381/ Cho m g HC (A) chy thu c 0,396 g CO2 v 0,108 g H2O.Trng hp 3 phn t A
thu c cht B l ng ng ca benzen.A v B thuc dy no sau?
a.A,B u l ankin
c.A:ankylbenzen;B:ankin
b.A,B u l ankylbenben
d. A:ankin ; B:ankylbenzen*
Cu 363/ A(CxHy) l cht lng iu kin thng c dA/kk l 2,7. A chy mCO2 : mH2O = 4,9 :
1.Cng thc phn t ca A l:
a. C7H8
b. C6H6*
c. C10H14
d. C9H12
312/ t chy hon ton m (g) A (CxHy) m g H2O; 150 < MA < 170. Cng thc phn t ca A
l:

a.C4H6
b.C8H12
c.C16H24
d.C12H18*
313/ t chy hon ton a (g) hp cht hu c A ch thu c CO2 v H2O.Trong khi
lng H2O bng a g.Cng thc nguyn ca A l:
a.(CH)n
b.(C2H3)n*
c.(C3H4)n
d.(C4H7)n
310/ t chy 16,2 g 1 cht hu c (A) thu c 1,2 mol CO2 ; 0,9 mol H2O. 150 < MA <
170.Cng thc phn t ca A l:
a.C8H10
b.C9H12
c.C10H14
d.C12H18*
Cu 334. t chy hon ton 10,8g mt ankyl benzen A thu c 39,6g CO2. Cng thc phn t
ca A l:
a.C6H6
b.C8H8
c.C8H10
d.C9H12
Cu 335. t chy 10,8g A (CxHy) 10,8g H2O. A c cha 1 vng benzen. Cng thc phn t
ca A l:
a.C3H4
b.C6H8
c.C9H12
d.C12H16
Cu 353/ Cho benzen vo 1 l ng Cl2 d ri a ra asng .Sau khi phn ng xy ra hon ton
thu c 5,82 kg benzen.Tn ca sn phm v khi lng benzen tham gia phn ng l:
a.clobenzen;1,56kg
c.hexacloran;1,56kg*
b.hexacloxiclohexan;1,65kg
d.hexaclobenzen;6,15kg
Cu 354/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c 8,1 g H2O v V (l) CO2
(ktc).Gi tr ca V l:
a.15,654
b.15,465
c.15,546
d.15,456*
Cu 355/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c 8,1 g H2O v CO2.Dn
ton b lng CO2 vo 100ml dd NaOH 1M thu c m g mui.Gi tr ca m v thnh phn ca
mui:
a.64,78 g (2 mui)*
c.31,92g(NaHCO3)
b.64,78g (Na2CO3)
d.10,6g (Na2CO3)
Cu 356/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c H2O v 30,36 g CO2 .Cng
thc phn t ca A v B ln lt l:
a.C8H10 ; C9H14
c. C8H12 ; C9H14
b. C8H10 ; C9H12*
d. C8H14 ; C9H16
Cu 357/ t chy hon ton 12 g cht hu c A , ng ng ca benzen thu c 20,16 lt CO2
(ktc)
Cng thc phn t ca A l:
a. C9H12*
b. C8H10
c. C7H8
d. C10H14
Cu 358/ t chy hon ton m g A ng ng ca benzen thu c 20,16 lt CO2 (ktc) v 10,8
ml H2O (lng).Cng thc ca A l:
a. C7H8
b. C8H10
c. C9H12*
d. C10H14
Cu 359/ t chy hon ton 0,1 mol CxHy thu c 20,16 lt CO2 (ktc) v 10,8 g H2O
(lng).Cng thc ca CxHy l:
a. C7H8
b. C8H10
c. C10H14
d. C9H12*
Cu 365/ Hiro ho etylbenzen ta c stiren;trng hp stiren ta c polistiren vi hiu
sut chung 80%.Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l:
a.13,52 tn
c.13,25 tn*
b.10,6 tn
d.8,48 tn

a. C7366/
Cu
H8 t chy hon ton
b. Chi
* xHy) thu cc.8 C
lt10CO
H142 v cn dng 10,5
d.lt
C9oxi.Cng
H12
thc
8H10A(C
phn367/
Cu
t ca
t
A chy
l: hon ton 1,3 g A(CxHy) 0,9 g H2O .Cng thc nguyn ca A l:
a.(CH)n*
b.(C2H3)n
c.(C3H4)n
d.(C4H7)n
Cu 368/ A t 1 hp cht vng c to thnh t s trng hp axetilen,dA/kk l 3,59.C.thc
phn t A l:
a. C8H8*
b. C6H6
c. C10H14
d. C4H4
Cu 369/ A c cng thc phn t l C8H8 ,tc dng vi dd KMnO4 nhit thng to ra
ancol 2 chc.
1 mol A tc dng ti a vi:
a.4 mol H2; 1 mol brom*
c.3 mol H2; 3 mol brom
b. 3 mol H2; 1 mol brom
d. 4 mol H2; 4 mol brom
Cu 370/ 5,2 g stiren b trng hp 1 phn tc dng va vi dd cha 0,0125 mol
brom.Lng stiren cha b trng hp l:
a.25%
b.50%
c.52%
d.75%*
Cu 371/ 1 ankylbenzen A(C9H12),tc dng vi HNO3 c (c xt H2SO4 ) theo t l mol 1:1 to
ra 1 dn xut mononitro duy nht . Vy A l:
a. n-propylbenzen
c.i-propylbenzen
b.p-etyl,metylbenzen
d.1,3,5-trimetylbenzen*
Cu 373/ Cho A(CxHy) l 1 cht kh kthng .t chy hon ton 1 lng cht A thu c 1
sn phm cha 76,52% CO2 v khi lng.Cng thc phn t ca A l:
a. C2H6
b. C3H6
c. C4H6*
d. C6H6
Cu 373/ A l 1 HC mch h , cht kh iu kin thng .4,48 lt kh A ktc tc dng va
vi 0,4 mol Brom to ra sn phm B cha 85,562% brom v khi lng. Cng thc phn t ca
A l:
a. C2H6
b. C3H6
c. C4H6*
d. C6H6
Cu 382/ Cho a g cht A(CxHy) chy thu c 13,2 g CO2 v 3,6 g H2O.Tam hp A thu c
B,mt ng ng ca ankyn benzen.Cng thc phn t ca A v B ln lt l:
a.C3H6 v C9H8
b. C2H2 v C6H6
c. C3H4 v C9H12*
d. C9H12 v C3H4
Cu 384/ Mt cht hu c A c mC:mH:mCl = 1,2 : 0.1 : 3,55.Phn t c vng 6 cnh.Vy A l:
a.hexacolran
c.hexaclobenzen
b.hexacloxiclohexan
d.a,b,c u ng
Cu 385/ t 0,13 g mi cht A v B u cng thu c 0,01 mol CO2 v 0,09 g H2O.d A/B l
3; d B/C2H4 l 0,5.Cng thc ca A v B ln lt l:
a.C2H2 v C6H6
b. C6H6 v C2H2*
c. C2H2 v C4H4
d. C6H6 v C8H8
Cu 386/ 1,3 g cht hu c A chy hon ton thu c 4,4 g CO2 v 0,9 g H2O.T khi hi ca A
i vi oxi(d) tho mn iu kin 3<d<3,5.Cng thc phn t ca A l:
a.C2H2
b.C8H8*
c.C4H4
d.C6H6
Cu 387/ Cho 120 t n khng nguyn cht tc dng hon ton vi H2O thu c kh
A.Chuyn kh A thnh benzen vi hiu sut 60%,thu c 26 ml benzen(d=0,9 g/ml)% khi
lng tp cht trong t n l:
a.10%
b.20%*
c.30%
d.40%