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Title: Practice Test 2
Started: October 27, 2009 12:47 AM
Submitted: October 27, 2009 2:07 AM
Time spent: 01:20:20
Total score: 12/20 = 60% Total score adjusted by 0.0 Maximum possible score: 20

1.
Consider the gas-phase reaction, Cl2(g) + Br2(g) <=> 2 BrCl(g), for which Kp = 32 at 500 K.
If the mixture is analyzed and found to contain 1.2 bar of Cl2, 1.6 bar of Br2 and 7.9 bar of
BrCl, describe the situation:

Student Correct
Value Feedback
Response Answer
1. Q < K and 0%
more
reactants
will be
made to
reach
equilibrium.
2. Q < K and 0%
more
products
will be
made to
reach
equilibrium.
3. Q > K and 100%
more
reactants
will be
made to
reach
equilibrium.
4. Q > K and 0%
more
products
will be
made to
reach
equilibrium.
5. Within 1 0%
decimal
place, Q =
K and the
reaction is
at
equilibrium

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Score: 1/1

2.
At a given temperature, Kp for the reaction below is 0.24. In a given experiment, 0.10 atm
of each product and 0.0020 atm of NOBr are intoduced into a container. In which direction
will the reaction proceed, or is it at equilibrium?

2 NOBr(g) <=> 2 NO(g) + Br2(g)

Student Correct
Value Feedback
Response Answer
1. Reaction 100%
will go to
the left
2. Reaction 0%
will go to
the right
3. Reaction is 0%
an
equilibrium

Score: 1/1

3.
At a certain temperature, Kp for the reaction,
H2(g) + Br2(g) <=> 2 HBr(g) is 0.00738.
Calculate the value of Kp for the reaction,
HBr(g) <=> 1/2 H2(g) + 1/2 Br2(g)

Student Response Value Correct Answer

Answer 11.6 100% 12

Score: 1/1

4.
Calculate Kc for the following reaction,
H2(g) + I2(g) <=> 2 HI(g);
Kp = 61.40 at 25.0 o C

Student Response Value Correct Answer

Answer 61.40 100% 61.4

Score: 1/1

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5.
At a particular temperature, an equilibrium mixture the reaction below was found to contain
0.741 atm of I2, 0.644 atm of Cl2 and 4.81 atm of ICl. Calculate the value of the equilibrium
constant, Kp at this temperature.
I2(g) + Cl2(g) <=> 2 ICl(g)

Student Response Value Correct Answer

Answer .485 0% 48.48

Score: 0/1

6.
At a given temperature, 1.33 atm of H2 and 1.79 atm of Cl2 are mixed and allowed to come
to equilibrium. The equilibrium pressure of HCl is found to be 1.573 atm. Calculate Kp for the
reaction at this temperature.
H2(g) + Cl2(g) <=> 2 HCl(g)

Student Response Value Correct Answer

Answer 4.54 100% 4.537

Score: 1/1

7.
In the reaction below, 2 atm of H2 and 4 atm of Cl2 were placed into a 1.00 L flask and
allowed to react:
H2(g) + Cl2(g) <=> 2 HCl(g)
Given that Kp at 700 K = 54, calculate the equilibrium pressure of HCl.

Student Response Value Correct Answer

Answer .705 0% 3.75

Score: 0/1

8.
Consider the reaction Cl2(g) + Br2(g) <=> 2 BrCl(g), which is endothermic as written. What
would be the effect on the equilibrium position of removing Br2(g)?

Student Correct
Value Feedback
Response Answer

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1. Reaction 0%
would go
to the
right,
making
more
"products"
2. Reaction 100%
would go
to the left,
making
more
"reactants"
3. Reaction 0%
would go
to the left,
making
more
"products"
4. Reaction 0%
would go
to the
right,
making
more
"reactants"
5. No change 0%
on the
equilibrium
position

Score: 1/1

9.
Consider the reaction 2 NO2(g) <=> N2O4(g), which is exothermic as written. What would
be the effect on the equilibrium position of increasing the temperature?

Student Correct
Value Feedback
Response Answer
1. Reaction 0%
would go
to the
right,
making
more
"products"
2. Reaction 100%
would go
to the left,
making

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more
"reactants"
3. Reaction 0%
would go
to the left,
making
more
"products"
4. Reaction 0%
would go
to the
right,
making
more
"reactants"
5. No change 0%
on the
equilibrium
position

Score: 1/1

10.
What is the pOH of a 0.05848 M solution of HNO3?

Student Response Value Correct Answer

Answer 12.77 100% 12.77

Score: 1/1

11.

Give the conjugate base of H3PO4. Write it ignoring super and subscripts (so, HPO42- would
be HPO42- HSO4-)

Student Response Value Correct Answer

Equals H2PO4- (100%)
1. HPO43- 0%
Equals H2PO41- (100%)

Score: 0/1

12.
Is an aqueous solution of LiClO4 acidic, basic or neutral (use A, B or N)?

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Student Response Value Correct Answer

1. N 100% Equals N (100%)

Score: 1/1

13.
Is an aqueous solution of K3PO4 acidic, basic or neutral (use A, B or N)?

Student Response Value Correct Answer

1. B 100% Equals B (100%)

Score: 1/1

14.

What is the pH of 0.418 M ammonium iodide, NH4I? The Kb of ammonia is 1.8 x 10-5.

Student Response Value Correct Answer

Answer 1.14 0% 4.82

Score: 0/1

15.
6What is the pH of 0.355 M triethylammonium bromide, (C2H5)3NHBr.
The Kb of triethylamine, (C2H5)3N, is 5.2 x 10-4.

Student Response Value Correct Answer

Answer 1.21 0% 5.58

Score: 0/1

16.

The Ka of formic acid, HCOOH is 1.8 x 10-4. What is [OH-] in a 0.289 M solution of HCOOH?
Use E notation and 3 significant figures.

Student Response Value Correct Answer

Answer 7.08E-6 0% 1.39E-12 (1.39 × 10-12)

Score: 0/1

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17.

Calculate the [OH-] in a solution of 0.550 M diethylamine, Kb = 8.6 x 10-4?

Student Response Value Correct Answer

Answer 2.17E-2 100% 0.0217

Score: 1/1

18.
Select the stronger acid from each of the following pairs:

I. HI or HBr
II. H3AsO3 or H2SeO3
III. HNO3 or HNO2

Student Correct
Value Feedback
Response Answer
1. I. HBr II. 0%
H2SeO3
III. HNO2
2. I. HBr II. 0%
H3AsO3
III. HNO2
3. I. HBr II. 0%
H3AsO3
III. HNO3
4. I. HI II. 0%
H3AsO3
III. HNO2
5. I. HI II. 100%
H2SeO3
III. HNO3

Score: 1/1

19.

A first order reaction has a rate constant of 0.730 at 25 o C and 8.03 at 50 o C. Calculate the
value of the activation energy in KILOJOULES (enter answer in E format to 3 significant
figures. Remember - 2.41 would be 2.41E0)

Student Response Value Correct Answer

Answer not answered 0% 76.8

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Score: 0/1

20.
The proposed mechanism for a reaction is

Cl2 => Cl+ + Cl- Slow

Cl- + H2S => HCl + HS- Fast

Cl+ + HS- => HCl + S Fast

Which of the following would be a rate law for the reaction?

Student Correct
Value Feedback
Response Answer
1. rate = k[Cl2] 100%
2. rate = 0%
k[Cl2][H2S]
3. rate = 0%
k[Cl2]1/2[H2S]
4. rate = 0%
k[Cl-][H2S]
5. rate = 0%
[Cl+][Cl-]

Score: 0/1

Done

8 of 8 27-Oct-09 2:22 AM