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Bin son : Gio vin Nguyn Minh Tun T Ha Trng THPT Chuyn Hng Vng
NGUYN MINH TUN

Gio vin trng THPT Chuyn Hng Vng
BI TP TRC NGHIM
HO HU C 11
MC LC
Trang
Phn 1: Bi tp
2 - 62
Chuyn 1 : i cng ho hu c
Chuyn 2 : Hirocacbon no
10
Chuyn 3 : Hirocacbon khng no
16
Chuyn 4 : Hirocacbon thm - Ngun hirocacbon

thin nhin
29
Chuyn 5 : Dn xut halogen - Phenol - Ancol
35
Chuyn 6 : Anehit - Xeton - Axitcacboxylic
49
Phn 2 : p n
63- 65
Phn 1: Bi tp
CHUYN 1 : I CNG HA HC HU C
Cu 1: Thnh phn cc nguyn t trong hp cht hu c
A. nht thit phi c cacbon, thng c H, hay gp O, N sau n halogen, S, P...
B. gm c C, H v cc nguyn t khc.
C. bao gm tt c cc nguyn t trong bng tun hon.
D. thng c C, H hay gp O, N, sau n halogen, S, P.
Cu 2: c im chung ca cc phn t hp cht hu c l
1. thnh phn nguyn t ch yu l C v H.
2. c th cha nguyn t khc nh Cl, N, P, O.
3. lin kt ha hc ch yu l lin kt cng ho tr.
4. lin kt ho hc ch yu l lin kt ion.
5. d bay hi, kh chy.
6. phn ng ho hc xy ra nhanh.
Nhm cc ng l:
A. 4, 5, 6.
B. 1, 2, 3.
C. 1, 3, 5.
D. 2, 4, 6.
Cu 3: Cu to ho hc l
A. s lng lin kt gia cc nguyn t trong phn t.
B. cc loi lin kt gia cc nguyn t trong phn t.
C. th t lin kt gia cc nguyn t trong phn t.
D. bn cht lin kt gia cc nguyn t trong phn t.
Cu 4: Pht biu no sau c dng nh ngha cng thc n gin nht ca hp cht hu c ?
A. Cng thc n gin nht l cng thc biu th s nguyn t ca mi nguyn t trong phn t.
B. Cng thc n gin nht l cng thc biu th t l ti gin v s nguyn t ca cc nguyn
t trong phn t.
C. Cng thc n gin nht l cng thc biu th t l phn trm s mol ca mi nguyn t
trong phn t.
D. Cng thc n gin nht l cng thc biu th t l s nguyn t C v H c trong phn t.
Cu 5: Cho cht axetilen (C2H2) v benzen (C6H6), hy chn nhn xt ng trong cc nhn xt sau :
A. Hai cht ging nhau v cng thc phn t v khc nhau v cng thc n gin nht.
B. Hai cht khc nhau v cng thc phn t v ging nhau v cng thc n gin nht.
C. Hai cht khc nhau v cng thc phn t v khc nhau v cng thc n gin nht.
D. Hai cht c cng cng thc phn t v cng cng thc n gin nht.
Cu 6: c im chung ca cc cacbocation v cacbanion l:
A. km bn v c kh nng phn ng rt km.
B. chng u rt bn vng v c kh nng phn ng cao.
C. c th d dng tch c ra khi hn hp phn ng.
D. km bn v c kh nng phn ng cao.
Cu 7: Phn ng ha hc ca cc hp cht hu c c c im l:
A. thng xy ra rt nhanh v cho mt sn phm duy nht.
B. thng xy ra chm, khng hon ton, khng theo mt hng nht nh.
C. thng xy ra rt nhanh, khng hon ton, khng theo mt hng nht nh.
D. thng xy ra rt chm, nhng hon ton, khng theo mt hng xc nh.
Cu 8: Pht biu no sau y l sai ?
A. Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr.
B. Cc cht c cu to v tnh cht tng t nhau nhng v thnh phn phn t khc nhau mt
hay nhiu nhm -CH2- l ng ng ca nhau.
C. Cc cht c cng khi lng phn t l ng phn ca nhau.
D. Lin kt ba gm hai lin kt v mt lin kt .
Cu 9: Kt lun no sau y l ng ?
A. Cc nguyn t trong phn t hp cht hu c lin kt vi nhau khng theo mt th t nht nh.
B. Cc cht c thnh phn phn t hn km nhau mt hay nhiu nhm -CH 2-, do tnh cht
ha hc khc nhau l nhng cht ng ng.
C. Cc cht c cng cng thc phn t nhng khc nhau v cng thc cu to c gi l cc
cht ng ng ca nhau.
D. Cc cht khc nhau c cng cng thc phn t c gi l cc cht ng phn ca nhau.
Cu 10: Hin tng cc cht c cu to v tnh cht ho hc tng t nhau, chng ch hn km
nhau mt hay nhiu nhm metylen (-CH2-) c gi l hin tng
A. ng phn.
B. ng v.
C. ng ng.
D. ng khi.
Cu 11: Hp cht cha mt lin kt trong phn t thuc loi hp cht
A. khng no.
B. mch h.
C. thm.
D. no hoc khng no.
Cu 12: Hp cht hu c c phn loi nh sau:
A. Hirocacbon v hp cht hu c c nhm chc.
B. Hirocacbon v dn xut ca hirocacbon.
C. Hirocacbon no, khng no, thm v dn xut ca hirocacbon.
D. Tt c u ng.
Cu 13: Pht biu khng chnh xc l:
A. Tnh cht ca cc cht ph thuc vo thnh phn phn t v cu to ha hc.
B. Cc cht c cng khi lng phn t l ng phn ca nhau.
C. Cc cht l ng phn ca nhau th c cng cng thc phn t.
D. S xen ph trc to thnh lin kt , s xen ph bn to thnh lin kt .
Cu 14: Nung mt hp cht hu c X vi lng d cht oxi ha CuO ngi ta thy thot ra kh
CO2, hi H2O v kh N2. Chn kt lun chnh xc nht trong cc kt lun sau :
A. X chc chn cha C, H, N v c th c hoc khng c oxi.
B. X l hp cht ca 3 nguyn t C, H, N.
C. Cht X chc chn c cha C, H, c th c N.
D. X l hp cht ca 4 nguyn t C, H, N, O.
Cu 15: Cho hn hp cc ankan sau : pentan (si 36oC), heptan (si 98oC), octan (si 126oC),
nonan (si 151oC). C th tch ring cc cht bng cch no sau y ?
A. Kt tinh.
B. Chng ct
C. Thng hoa.
D. Chit.
Cu 16: Cc cht trong nhm cht no di y u l dn xut ca hirocacbon ?
A. CH2Cl2, CH2Br-CH2Br, NaCl, CH3Br, CH3CH2Br.
B. CH2Cl2, CH2Br-CH2Br, CH3Br, CH2=CHCOOH, CH3CH2OH.
C. CH2Br-CH2Br, CH2=CHBr, CH3Br, CH3CH3.
D. HgCl2, CH2Br-CH2Br, CH2=CHBr, CH3CH2Br.
Cu 17: Cho cc cht : C6H5OH (X) ; C6H5CH2OH (Y) ; HOC6H4OH (Z) ; C6H5CH2CH2OH (T).
Cc cht ng ng ca nhau l:
A. Y, T.
B. X, Z, T.
C. X, Z.
D. Y, Z.
Cu 18: Trong nhng dy cht sau y, dy no c cc cht l ng phn ca nhau ?
A. C2H5OH, CH3OCH3.
B. CH3OCH3, CH3CHO.
C. CH3CH2CH2OH, C2H5OH.
D. C4H10, C6H6.
Cu 19: Cc cht hu c n chc Z1, Z2, Z3 c CTPT tng ng l CH2O, CH2O2, C2H4O2. Chng
thuc cc dy ng ng khc nhau. Cng thc cu to ca Z3 l
A. CH3COOCH3.
B. HOCH2CHO.
C. CH3COOH.
D. CH3OCHO.
Cu 20: Nhng cht no sau y l ng phn hnh hc ca nhau ?
A. (I), (II).
B. (I), (III).
C. (II), (III).
D. (I), (II), (III).
Cu 21: Cho cc cht sau : CH2=CHCCH (1) ; CH2=CHCl (2) ; CH3CH=C(CH3)2 (3) ;
CH3CH=CHCH=CH2 (4) ; CH2=CHCH=CH2 (5) ; CH3CH=CHBr (6). Cht no sau y c ng
phn hnh hc?
A. 2, 4, 5, 6.
B. 4, 6.
C. 2, 4, 6.
D. 1, 3, 4.
Cu 22: Hp cht hu c no sau y khng c ng phn cis-trans ?
A. 1,2-icloeten.
B. 2-metyl pent-2-en. C. but-2-en.
D. pent-2-en.
Cu 23: Hp cht (CH3)2C=CHC(CH3)2CH=CHBr c danh php IUPAC l
A. 1-brom-3,5-trimetylhexa-1,4-ien.
B. 3,3,5-trimetylhexa-1,4-ien-1-brom.
C. 2,4,4-trimetylhexa-2,5-ien-6-brom.
D. 1-brom-3,3,5-trimetylhexa-1,4-ien.
Cu 24: Hp cht (CH3)2C=CH-C(CH3)3 c danh php IUPAC l:
A. 2,2,4- trimetylpent-3-en.
B. 2,4-trimetylpent-2-en.
C. 2,4,4-trimetylpent-2-en.
D. 2,4-trimetylpent-3-en.
Cu 25: Hp cht CH2=CHC(CH3)2CH2CH(OH)CH3 c danh php IUPAC l:
A. 1,3,3-trimetylpent-4-en-1-ol.
B. 3,3,5-trimetylpent-1-en-5-ol.
C. 4,4-imetylhex-5-en-2-ol.
D. 3,3-imetylhex-1-en-5-ol.
Cu 26: Cho cng thc cu to sau : CH3CH(OH)CH=C(Cl)CHO. S oxi ha ca cc nguyn t
cacbon tnh t phi sang tri c gi tr ln lt l:
A. +1 ; +1 ; -1 ; 0 ; -3.
B. +1 ; -1 ; -1 ; 0 ; -3.
C. +1 ; +1 ; 0 ; -1 ; +3.
D. +1 ; -1 ; 0 ; -1 ; +3.
Cu 27: Trong cng thc CxHyOzNt tng s lin kt v vng l:
A. (2x-y + t+2)/2.
B. (2x-y + t+2).
C. (2x-y - t+2)/2.
D. (2x-y + z + t+2)/2.
Cu 28: a. Vitamin A cng thc phn t C20H30O, c cha 1 vng 6 cnh v khng c cha lin kt
ba. S lin kt i trong phn t vitamin A l
A. 7.
B. 6.
C. 5.
D. 4.
b. Licopen, cng thc phn t C40H56 l cht mu trong qu c chua, ch cha lin kt i v lin
kt n trong phn t. Hiro ha hon ton licopen c hirocacbon C40H82. V y licopen c
A. 1 vng; 12 ni i.
B. 1 vng; 5 ni i.
C. 4 vng; 5 ni i.
D. mch h; 13 ni i.
Cu 29: Metol C10H20O v menton C10H18O chng u c trong tinh du bc h. Bit phn t metol
khng c ni i, cn phn t menton c 1 ni i. V y kt lu n no sau y l ng ?
A. Metol v menton u c cu to vng.
B. Metol c cu to vng, menton c cu to mch h.
C. Metol v menton u c cu to mch h.
D. Metol c cu to mch h, menton c cu to vng.
Cu 30: Trong hp cht CxHyOz th y lun lun chn v y 2x+2 l do:
A. a 0 (a l tng s lin kt v vng trong phn t).
B. z 0 (mi nguyn t oxi to c 2 lin kt).
C. mi nguyn t cacbon ch to c 4 lin kt.
D. cacbon v oxi u c ha tr l nhng s chn.
Cu 31: Tng s lin kt v vng ng vi cng thc C5H9O2Cl l:
A. 0.
B. 1.
C. 2.
D. 3.
Cu 32: Tng s lin kt v vng ng vi cng thc C5H12O2 l:
A. 0.
B. 1.
C. 2.
D. 3.
Cu 33: Cng thc tng qut ca dn xut iclo mch h c cha mt lin kt ba trong phn t l
A. CnH2n-2Cl2.
B. CnH2n-4Cl2.
C. CnH2nCl2.
D. CnH2n-6Cl2.
Cu 34: Cng thc tng qut ca dn xut ibrom khng no mch h cha a lin kt l
A. CnH2n+2-2aBr2.
B. CnH2n-2aBr2.
C. CnH2n-2-2aBr2.
D. CnH2n+2+2aBr2.
Cu 35: Hp cht hu c c cng thc tng qut CnH2n+2O2 thuc loi
A. ancol hoc ete no, mch h, hai chc.
B. anehit hoc xeton no, mch h, hai chc.
C. axit hoc este no, n chc, mch h.
D. hiroxicacbonyl no, mch h.
Cu 36: Ancol no mch h c cng thc tng qut chnh xc nht l
A. R(OH)m.
B. CnH2n+2Om.
C. CnH2n+1OH.
D. CnH2n+2-m(OH)m.
Cu 37: Cng thc tng qut ca anehit n chc mch h c 1 lin kt i C=C l:
A. CnH2n+1CHO.
B. CnH2nCHO.
C. CnH2n-1CHO.
D. CnH2n-3CHO.
Cu 38: Anehit mch h c cng thc tng qut CnH2n-2O thuc loi
A. anehit n chc no.
B. anehit n chc cha mt lin kt i trong gc hirocacbon.
C. anehit n chc cha hai lin kt trong gc hirocacbon.
D. anehit n chc cha ba lin kt trong gc hirocacbon.
Cu 39: Cng thc tng qut ca ancol n chc mch h c 2 ni i trong gc hirocacbon l
A. CnH2n-4O.
B. CnH2n-2O.
C. CnH2nO.
D. CnH2n+2O.
Cu 40: Anehit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon l:
A. 0.
B. 1.
C. 2.
D. 3.
Cu 41: Cng thc phn t tng qut ca axit hai chc mch h cha mt lin kt i trong gc
hirocacbon l:
A. CnH2n-4O4.
B. CnH2n-2O4.
C. CnH2n-6O4.
D. CnH2nO4.
Cu 42: Axit mch h CnH2n 4O2 c s lng lin kt trong gc hirocacbon l:
A. 0.
B. 1.
C. 2.
D. 3.
Cu 43: Tng s lin kt v vng trong phn t axit benzoic l:
A. 3.
B. 4.
C. 5.
D. 6.
Cu 44: S lng ng phn ng vi cng thc phn t C6H14
A. 6.
B. 7.
C. 4.
D. 5.
Cu 45: S lng ng phn mch h ng vi cng thc phn t C5H10 l:
A. 2.
B. 3.
C. 6.
D. 5.
Cu 46: S lng ng phn cu to ng vi cng thc phn t C5H10 l:
A. 7.
B. 8.
C. 9.
D. 10.
Cu 47: S lng ng phn mch h ng vi cng thc phn t C5H8 l:
A. 7.
B. 8.
C. 9.
D. 10.
Cu 48: S lng ng phn cha vng benzen ng vi cng thc phn t C9H12 l:
A. 7.
B. 8.
C. 9.
D. 10.
Cu 49: S lng ng phn cha vng benzen ng vi cng thc phn t C9H10 l:
A. 7.
B. 8.
C. 9.
D. 6.
Cu 50: S lng ng phn ng vi cng thc phn t C3H5Br3 l:
A. 3.
B. 4.
C. 5.
D. 6.
Cu 51: S lng ng phn ng vi cng thc phn t C3H5Cl l:
A. 3.
B. 4.
C. 5.
D. 6.
Cu 52: Hp cht C4H10O c s ng phn ancol v tng s ng phn l:
A. 7 v 4.
B. 4 v 7.
C. 8 v 8.
D. 10 v 10.
Cu 53: S lng ng phn mch h ng vi cng thc phn t C3H6O l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 54: S lng ng phn mch h ng vi cng thc phn t C 4H6O2 tc dng c vi
NaHCO3 l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 55: S lng ng phn ng vi cng thc phn t C4H11N l:
A. 7.
B. 8.
C. 9.
D. 10.
Cu 56: Mt hp cht hu c X c khi lng phn t l 26. em t X ch thu c CO 2 v H2O.
CTPT ca X l:
A. C2H6.
B. C2H4.
C. C2H2.
D. CH2O.
Cu 57: Mt hp cht hu c A c M = 74. t chy A bng oxi thu c kh CO2 v H2O. C bao
nhiu cng thc phn t ph hp vi A?
A. 4.
B. 2.
C. 3.
D. A.1.
Cu 58: Mt hp cht hu c A c t khi so vi khng kh bng bng 2. t chy hon ton A
bng kh O2 thu c CO2 v H2O. C bao nhiu cng thc phn t ph hp vi A ?
A. 2.
B. A. 1.
C. 3.
D. 4.
Cu 59: Hp cht X c thnh phn % v khi lng : C (85,8%) v H (14,2%). Hp cht X l
A. C3H8.
B. C4H10.
C. C4H8.
D. kt qu khc.
Cu 60: Hp cht X c %C = 54,54% ; %H = 9,1%, cn li l oxi. Khi lng phn t ca X bng
88. CTPT ca X l:
A. C4H10O.
B. C5H12O.
C. C4H10O2.
D. C4H8O2.
Cu 61: Phn tch hp cht hu c X thy c 3 phn khi lng cacbon li c 1 phn khi lng
hiro, 7 phn khi lng nit v 8 phn lu hunh. Trong CTPT ca X ch c 1 nguyn t S, vy
CTPT ca X l
A. CH4NS.
B. C2H2N2S.
C. C2H6NS.
D. CH4N2S.
Cu 62: a. Hp cht X c CTGN l CH3O. CTPT no sau y ng vi X ?
A. C3H9O3.
B. C2H6O2.
C. C2H6O.
D. CH3O.
b. Cng thc thc nghim ca cht hu c c dng (CH3Cl)n th cng thc phn t ca hp cht l
A. CH3Cl.
B. C2H6Cl2.
C. C2H5Cl.
D. C3H9Cl3.
Cu 63: Mt hp cht hu c gm C, H, O ; trong cacbon chim 61,22% v khi lng. Cng
thc phn t ca hp cht l:
A. C3H6O2.
B. C2H2O3.
C. C5H6O2.
D. C4H10O.
Cu 64: Cht hu c X c M = 123 v khi lng C, H, O v N trong phn t theo th t t l vi
72 : 5 : 32 : 14. CTPT ca X l:
A. C6H14O2N.
B. C6H6ON2.
C. C6H12ON.
D. C6H5O2N.
Cu 65: t chy hon ton 0,6 gam hp cht hu c X ri cho sn phm chy qua bnh ng dung
dch Ca(OH)2 d thy c 2 gam kt ta v khi lng bnh tng thm 1,24 gam. T khi ca X so
vi H2 bng 15. CTPT ca X l:
A. C2H6O.
B. CH2O.
C. C2H4O.
D. CH2O2.
Cu 66: Khi t 1 lt kh X cn 6 lt O 2 thu c 4 lt CO2 v 5 lt hi H2O (cc th tch kh o
cng iu kin nhit , p sut). CTPT ca X l:
A. C4H10O.
B. C4H8O2.
C. C4H10O2.
D. C3H8O.
Cu 67: t chy hon ton 3 gam hp cht hu c X thu c 4,4 gam CO 2 v 1,8 gam H2O. Bit
t khi ca X so vi He (MHe = 4) l 7,5. CTPT ca X l:
A. CH2O2.
B. C2H6.
C. C2H4O.
D. CH2O.
Cu 68: t chy 1 lt hi hirocacbon vi mt th tch khng kh (lng d). Hn hp kh thu
c sau khi hi H2O ngng t c th tch l 18,5 lt, cho qua dung dch KOH d cn 16,5 lt, cho
hn hp kh i qua ng ng photpho d th cn li 16 lt. Xc nh CTPT ca hp cht trn bit
cc th tch kh o cng iu kin nhit , p sut v O2 chim 1/5 khng kh, cn li l N2.
A. C2H6.
B. C2H4.
C. C3H8.
D. C2H2.
Cu 69: t 0,15 mol mt hp cht hu c thu c 6,72 lt CO2 (ktc) v 5,4 gam H2O. Mt khc
t 1 th tch hi cht cn 2,5 th tch O2. Cc th tch o cng iu kin nhit , p sut.
CTPT ca hp cht l:
A. C2H6O2.
B. C2H6O.
C. C2H4O2.
D. C2H4O.
Cu 70: t chy hon ton mt hp cht hu c X (C, H, N) bng lng khng kh va (gm
1/5 th tch O2, cn li l N2) c kh CO2 , H2O v N2. Cho ton b sn phm chy qua bnh ng
dung dch Ba(OH)2 d thy c 39,4 gam kt ta, khi lng dung dch gim i 24,3 gam. Kh thot
ra khi bnh c th tch 34,72 lt (ktc). Bit d X O < 2. CTPT ca X l:
A. C2H7N.
B. C2H8N.
C. C2H7N2.
D. C2H4N2.
Cu 71: Oxi ha hon ton 4,02 gam mt hp cht hu c X ch thu c 3,18 gam Na2CO3 v
0,672 lt kh CO2. CTGN ca X l:
A. CO2Na.
B. CO2Na2.
C. C3O2Na.
D. C2O2Na.
Cu 72: t chy hon ton mt hirocacbon trong 0,5 lt hn hp ca n vi CO2 bng 2,5 lt O2
thu c 3,4 lt kh. Hn hp ny sau khi ngng t ht hi nc cn 1,8 lt, tip tc cho hn hp kh
2
cn li qua dung dch kim d th cn li 0,5 lt kh. Cc th tch c o cng iu kin nhit ,
p sut. CTPT ca hirocacbon l:
A. C4H10.
B. C3H8.
C. C4H8.
D. C3H6.
Cu 73: t chy hon ton 1,605 gam hp cht hu c A thu c 4,62 gam CO2 ; 1,215 gam H2O
v 168 ml N2 (ktc). T khi hi ca A so vi khng kh khng vt qu 4. Cng thc phn t ca A
l:
A. C5H5N.
B. C6H9N.
C. C7H9N.
D. C6H7N.
Cu 74: Oxi ha hon ton 6,15 gam hp cht hu c X thu c 2,25 gam H2O ; 6,72 lt CO2 v
0,56 lt N2 (kc). Phn trm khi lng ca C, H, N v O trong X ln lt l:
A. 58,5% ; 4,1% ; 11,4% ; 26%.
B. 48,9% ; 15,8% ; 35,3% ; 0%.
C. 49,5% ; 9,8% ; 15,5% ; 25,2%.
D. 59,1 % ; 17,4% ; 23,5% ; 0%.
Cu 75: Phn tch 0,31gam hp cht hu c X ch cha C, H, N to thnh 0,44 gam CO2. Mt khc,
nu phn tch 0,31 gam X ton b N trong X chuyn thnh NH3 ri dn NH3 va to thnh vo
100 ml dung dch H2SO4 0,4M th phn axit d c trung ha bi 50 ml dung dch NaOH 1,4M.
Bit 1 lt hi cht X (ktc) nng 1,38 gam. CTPT ca X l:
A. CH5N.
B. C2H5N2.
C. C2H5N.
D. CH6N.
Cu 76: t chy 200 ml hi mt hp cht hu c X cha C, H, O trong 900 ml O2, th tch hn
hp kh thu c l 1,3 lt. Sau khi ngng t hi nc ch cn 700 ml. Tip theo cho qua dung dch
KOH d ch cn 100 ml kh bay ra. Cc th tch kh o cng iu kin nhit , p sut. CTPT
ca Y l:
A. C3H6O.
B. C3H8O2.
C. C3H8O.
D. C3H6O2.
Cu 77: Phn tch 1,5 gam cht hu c X thu c 1,76 gam CO2 ; 0,9 gam H2O v 112 ml N2 o
0oC v 2 atm. Nu ha hi cng 1,5 gam cht Z 127o C v 1,64 atm ngi ta thu c 0,4 lt kh
cht Z. CTPT ca X l:
A. C2H5ON.
B. C6H5ON2.
C. C2H5O2N.
D. C2H6O2N.
Cu 78: t chy hon ton m t th tch hi hp cht hu c A cn 10 th tch oxi (o cng iu
kin nhit v p sut), sn phm thu c ch gm CO2 v H2O vi mCO2 : mH2O = 44 : 9. Bit
MA < 150. A c cng thc phn t l:
A. C4H6O.
B. C8H8O.
C. C8H8.
D. C2H2.
Cu 79: Cho 400 ml mt hn hp gm nit v mt hirocacbon vo 900 ml oxi (d) ri t. Th
tch hn hp thu c sau khi t l 1,4 lt. Sau khi cho nc ngng t cn 800 ml hn hp, ngi
ta cho li qua dung dch KOH thy cn 400 ml kh. Cc th tch kh u o cng iu kin nhit
, p sut. Cng thc phn t ca cht hu c l:
A. C3H8.
B. C2H4.
C. C2H2.
D. C2H6.
Cu 80: t chy 0,282 gam hp cht hu c X, cho sn phm i qua cc bnh ng CaCl2 khan v
KOH d. Thy bnh ng CaCl2 tng thm 0,194 gam cn bnh ng KOH tng thm 0,8 gam. Mt
khc nu t chy 0,186 gam cht X th thu c 22,4 ml kh N2 ( ktc). Bit rng hp cht X ch
cha mt nguyn t nit. Cng thc phn t ca hp cht X l:
A. C6H6N2.
B. C6H7N.
C. C6H9N.
D. C5H7N.
Cu 81: t chy hon ton hp cht hu c cha C, H, Cl sinh ra 0,22 gam CO2, 0,09 gam H2O.
Mt khc khi xc nh clo trong hp cht bng dung dch AgNO3 ngi ta thu c 1,435 gam
AgCl. T khi hi ca hp cht so vi hiro bng 42,5. Cng thc phn t ca hp cht l:
A. CH3Cl.
B. C2H5Cl.
C. CH2Cl2.
D. C2H4Cl2.
Cu 82: t chy hon ton 0,4524 gam hp cht A sinh ra 0,3318 gam CO2 v 0,2714 gam H2O.
un nng 0,3682 gam cht A vi vi ti xt chuyn tt c nit trong A thnh amoniac, ri dn
kh NH3 vo 20 ml dung dch H2SO4 0,5 M. trung ho axit cn d sau khi tc dng vi NH3 cn
dng 7,7 ml dung dch NaOH 1M. Bit MA= 60. Cng thc phn t ca A l:
A. CH4ON2.
B. C2H7N.
C. C3H9N.
D. CH4ON.
Cu 83*: t chy hon ton 0,01 mol cht hu c X cn va 0,616 lt O2. Sau th nghim thu
c hn hp sn phm Y gm : CO2, N2 v hi H2O. Lm lnh ngng t hi H2O ch cn 0,56
lt hn hp kh Z (c t khi hi vi H2 l 20,4). Bit th tch cc kh u o ktc. Cng thc phn
t X l:
A. C2H5ON.
B. C2H5O2N.
C. C2H7O2N.
D. A hoc C.
Cu 84: X l m t ancol no, mch h. t chy 0,05 mol X cn 4 gam oxi. X c cng thc l:
A. C3H5(OH)3.
B. C3H6(OH)2.
C. C2H4(OH)2.
D. C4H8(OH)2.
Cu 85: Khi t chy hon ton mt amin n chc X, thu c 16,80 lt kh CO2 ; 2,80 lt N2 (cc
th tch o ktc) v 20,25 gam H2O. CTPT ca X l:
A. C4H9N.
B. C3H7N.
C. C2H7N.
D. C3H9N.
Cu 86: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam
CO2, 12,6 gam H2O v 69,44 lt N2 (ktc). Gi thit khng kh ch gm N2 v O2 trong oxi chim
20% th tch khng kh. X c cng thc l:
A. C2H5NH2.
B. C3H7NH2.
C. CH3NH2.
D. C4H9NH2.
Cu 87: Trong m t bnh kn cha hi este no n chc h A v m t lng O2 gp i lng O2 cn
thit t chy ht A nhi t 140oC v p sut 0,8 atm. t chy hon ton A ri a v nhi t
ban u, p sut trong bnh lc ny l 0,95 atm. A c cng thc phn t l:
A. C2H4O2.
B. C3H6O2.
C. C4H8O2.
D. C5H10O2.
Cu 88: t chy hon ton 0,12 mol cht hu c X mch h cn dng 10,08 lt kh O 2 (ktc). Dn
ton b sn phm chy (gm CO2, H2O v N2) qua bnh ng dung dch Ba(OH)2 d, thy khi
lng bnh tng 23,4 gam v c 70,92 gam kt ta. Kh thot ra khi bnh c th tch 1,344 lt
(ktc). Cng thc phn t ca X l:
A. C2H5O2N.
B. C3H5O2N.
C. C3H7O2N.
D. C2H7O2N.
Cu 89: t chy hon ton 0,1 mol cht X cn 6,16 lt kh O 2 (ktc), thu c 13,44 lt (ktc) hn
hp CO2, N2 v hi nc. Sau khi ngng t ht hi nc, cn li 5,6 lt kh (ktc) c t khi so vi
hiro l 20,4. Cng thc phn t ca X l:
A. C2H7O2N.
B. C3H7O2N.
C. C3H9O2N.
D. C4H9N.
Cu 90: t chy hon ton 0,1 mol mt ancol mch h ba ln cha mt lin kt ba trong gc
hirocacbon thu c 0,6 mol CO2. Cng thc phn t ca ancol l:
A. C6H14O3.
B. C6H12O3.
C. C6H10O3.
D. C6H8O3.
Cu 91: t chy hon ton 1,18 gam cht Y (C xHyN) bng mt lng khng kh va . Dn ton
b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH) 2 d, thu c 6 gam kt ta v c
9,632 lt kh (ktc) duy nht thot ra khi bnh. Bit khng kh cha 20% oxi v 80% nit v th
tch. Cng thc phn t ca Y l:
A. C2H7N.
B. C3H9N.
C. C4H11N.
D. C4H9N.
Cu 92: Phn tch 1,47 gam cht hu c Y (C, H, O) bng CuO th thu c 2,156 gam CO 2 v
lng CuO gim 1,568 gam. CTGN ca Y l:
A. CH3O.
B. CH2O.
C. C2H3O.
D. C2H3O2.
Cu 93: t chy hon ton mt hp cht hu c n chc X thu c sn phm chy ch gm
CO2 v H2O vi t l khi lng tng ng l 44 : 27. Cng thc phn t ca X l:
A. C2H6.
B. C2H6O.
C. C2H6O2.
D. C2H4O.
Cu 94: Mt hp cht hu c Y khi t chy thu c CO 2 v H2O c s mol bng nhau v lng
oxi cn dng bng 4 ln s mol ca Y. Cng thc phn t ca Y l:
A. C2H6O.
B. C4H8O.
C. C3H6O.
D. C3H6O2.
Cu 95: t chy hon ton 0,2 mol mt axit cacboxylic no 2 ln thu c 1,2 mol CO 2. Cng thc
phn t ca axit l:
A. C6H14O4.
B. C6H12O4.
C. C6H10O4.
D. C6H8O4.
Cu 96: t chy hon ton 5,8 gam mt hp cht hu c n chc X cn 8,96 lt kh O 2 (ktc),
thu c CO2 v H2O c s mol bng nhau. CTGN ca X l:
A. C2H4O.
B. C3H6O.
C. C4H8O.
D. C5H10O.
Cu 97: t chy hon ton 0,2 mol hirocacbon X. Hp th ton b sn phm chy vo nc vi
trong c 20 gam kt ta. Lc b kt ta ri un nng phn nc lc li c 10 gam kt ta na.
V y X khng th l:
A. C2H6.
B. C2H4.
C. CH4.
D. C2H2.
Cu 98: Hn hp X gm mt s hirocacbon l ng ng k tip. Tng khi lng phn t ca
cc hirocacbon trong A l 252, trong khi lng phn t ca hirocacbon nng nht bng 2 ln
khi lng phn t ca hirocacbon nh nht. Cng thc phn t ca hirocacbon nh nht v s
lng hirocacbon trong X l:
A. C3H6 v 4.
B. C2H4 v 5.
C. C3H8 v 4.
D. C2H6 v 5.
Cu 99: t chy hon ton 5,80 gam cht X thu c 2,65 gam Na 2CO3 ; 2,26 gam H2O v 12,10
gam CO2. Cng thc phn t ca X l:
A. C6H5O2Na.
B. C6H5ONa.
C. C7H7O2Na.
D. C7H7ONa.
Cu 100: t chy hon ton 1,88 gam hp cht hu c Z (cha C, H, O) cn 1,904 lt kh O 2
(ktc), thu c CO2 v H2O vi t l mol tng ng l 4 : 3. Cng thc phn t ca Z l:
A. C4H6O2.
B. C8H12O4.
C. C4H6O3.
D. C8H12O5.
10
CHUYN 2 :
HIROCACBON NO
Cu 1: Hp cht hu c X c tn gi l: 2 - clo - 3 - metylpentan. Cng thc cu to ca X l:

A. CH3CH2CH(Cl)CH(CH3)2.
B. CH3CH(Cl)CH(CH3)CH2CH3.
C. CH3CH2CH(CH3)CH2CH2Cl.
D. CH3CH(Cl)CH3CH(CH3)CH3.
Cu 2: C bao nhiu ng phn cu to c cng thc phn t C5H12 ?
A. 3 ng phn.
B. 4 ng phn.
C. 5 ng phn.
D. 6 ng phn
Cu 3: C bao nhiu ng phn cu to c cng thc phn t C6H14 ?
A. 3 ng phn.
B. 4 ng phn.
C. 5 ng phn.
D. 6 ng phn
Cu 4: C bao nhiu ng phn cu to c cng thc phn t C4H9Cl ?
A. 3 ng phn.
B. 4 ng phn.
C. 5 ng phn.
D. 6 ng phn.
Cu 5: C bao nhiu ng phn cu to c cng thc phn t C5H11Cl ?
A. 6 ng phn.
B. 7 ng phn.
C. 5 ng phn.
D. 8 ng phn.
Cu 6: Phn trm khi lng cacbon trong phn t ankan Y bng 83,33%. Cng thc phn t ca
Y l:
A. C2H6.
B. C3H8.
C. C4H10.
D. C5H12.
Cu 7: Cng thc n gin nht ca hirocacbon M l CnH2n+1. M thuc dy ng ng no ?
A. ankan.
B. khng d kin xc nh.
C. ankan hoc xicloankan.
D. xicloankan.
Cu 8: a. 2,2,3,3-tetrametylbutan c bao nhiu nguyn t C v H trong phn t ?
A. 8C,16H.
B. 8C,14H.
C. 6C, 12H.
D. 8C,18H.
b. Cho ankan c CTCT l: (CH3)2CHCH2C(CH3)3. Tn gi ca ankan l:
A. 2,2,4-trimetylpentan.
B. 2,4-trimetylpetan.
C. 2,4,4-trimetylpentan.
D. 2-imetyl-4-metylpentan.
Cu 9: Phn ng c trng ca hirocacbon no l
A. Phn ng tch.
B. Phn ng th.
C. Phn ng cng.
D. C A, B v C.
Cu 10: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu
c l:
A. 2.
B. 3.
C. 5.
D. 4.
Cu 11: Iso-hexan tc dng vi clo (c chiu sng) c th to ti a bao nhiu dn xut monoclo ?
A. 3.
B. 4.
C. 5.
D. 6
Cu 12: Khi cho 2-metylbutan tc dng vi Cl2 theo t l mol 1:1 th to ra sn phm chnh l:
A. 1-clo-2-metylbutan. B. 2-clo-2-metylbutan. C. 2-clo-3-metylbutan. D. 1-clo-3-metylbutan.
Cu 13: Khi clo ha C5H12 vi t l mol 1:1 thu c 3 sn phm th monoclo. Danh php IUPAC
ca ankan l:
A. 2,2-imetylpropan. B. 2-metylbutan.
C. pentan.
D. 2-imetylpropan.
Cu 14: Khi clo ha metan thu c mt sn phm th cha 89,12% clo v khi lng. Cng thc
ca sn phm l:
A. CH3Cl.
B. CH2Cl2.
C. CHCl3.
D. CCl4.
Cu 15: Cho 4 cht: metan, etan, propan v n-butan. S lng cht to c mt sn phm th
monoclo duy nht l:
A. 1.
B. 2.
C. 3.
D. 4.
Cu 16: khi clo ha mt ankan c cng thc phn t C 6H14, ngi ta ch thu c 2 sn phm th
monoclo. Danh php IUPAC ca ankan l:
A. 2,2-imetylbutan. B. 2-metylpentan.
C. n-hexan.
D. 2,3-imetylbutan.
Cu 17: Khi clo ha hn hp 2 ankan, ngi ta ch thu c 3 sn phm th monoclo. Tn gi ca
2 ankan l:
A. etan v propan.
B. propan v iso-butan.
11
C. iso-butan v n-pentan.
D. neo-pentan v etan.
Cu 18: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i
vi hiro l 75,5. Tn ca ankan l:
A. 3,3-imetylhecxan.
C. isopentan.
B. 2,2-imetylpropan.
D. 2,2,3-trimetylpentan
Cu 19: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng
vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng
phn ca nhau. Tn ca X l:
A. 3-metylpentan.
B. 2,3-imetylbutan. C. 2-metylpropan.
D. butan.
Cu 20: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc
ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO 2 ( cng iu kin nhit
, p sut). Khi cho X tc dng vi Cl 2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra
l:
A. 3.
B. 4.
C. 2.
D. 5.
Cu 21: Khi tin hnh phn ng th gia ankan X vi kh clo c chiu sng ngi ta thu c hn
hp Y ch cha hai cht sn phm. T khi hi ca Y so vi hiro l 35,75. Tn ca X l
A. 2,2-imetylpropan. B. 2-metylbutan.
C. pentan.
D. etan.
Cu 22: Ankan no sau y ch cho 1 sn phm th duy nht khi tc dng vi Cl 2 (as) theo t l mol
(1 : 1): CH3CH2CH3 (a), CH4 (b), CH3C(CH3)2CH3 (c), CH3CH3 (d), CH3CH(CH3)CH3(e)
A. (a), (e), (d).
B. (b), (c), (d).
C. (c), (d), (e).
D. (a), (b), (c), (e), (d)
Cu 23: Khi th monoclo mt ankan A ngi ta lun thu c mt sn phm duy nht. Vy A l:
A. metan.
B. etan
C. neo-pentan
D. C A, B, C u ng.
Cu 24: Sn phm ca phn ng th clo (1:1, nh sng) vo 2,2- imetyl propan l :
(1) CH3C(CH3)2CH2Cl;
(2) CH3C(CH2Cl)2CH3 ;
(3) CH3ClC(CH3)3
A. (1); (2).
B. (2); (3).
C. (2).
D. (1)
Cu 25: C bao nhiu ankan l cht kh iu kin thng khi phn ng vi clo (c nh sng, t l
mol 1:1) to ra 2 dn xut monoclo ?
A. 4.
B. 2.
C. 5.
D. 3.
Cu 26: Ankan Y phn ng vi brom to ra 2 dn xut monobrom c t khi hi so vi H2 bng
61,5. Tn ca Y l:
A. butan.
B. propan.
C. Iso-butan.
D. 2-metylbutan.
Cu 27: t chy mt hn hp gm nhiu hirocacbon trong cng mt dy ng ng nu ta thu
c s mol H2O > s mol CO2 th CTPT chung ca dy l:
A. CnHn, n 2.
B. CnH2n+2, n 1 (cc gi tr n u nguyn).
C. CnH2n-2, n 2.
D. Tt c u sai.
Cu 28: t chy cc hirocacbon ca dy ng ng no di y th t l mol H2O : mol CO2
gim khi s cacbon tng.
A. ankan.
B. anken.
C. ankin.
D. aren
Cu 29: Khi t chy ankan thu c H2O v CO2 vi t l tng ng bin i nh sau:
A. tng t 2 n + . B. gim t 2 n 1.
C. tng t 1 n 2.
D. gim t 1 n 0.
Cu 30: Khng th iu ch CH4 bng phn ng no ?
A. Nung mui natri malonat vi vi ti xt.
B. Canxicacbua tc dng vi nc.
C. Nung natri axetat vi vi ti xt.
D. in phn dung dch natri axetat.
Cu 31: Trong phng th nghim c th iu ch metan bng cch no sau y ?
A. Nhit phn natri axetat vi vi ti xt.
B. Crackinh butan
C. T phn ng ca nhm cacbua vi nc. D. A, C.
Cu 32: Thnh phn chnh ca kh thin nhin l:
12
A. metan.
B. etan.
C. propan.
D. n-butan.
Cu 33: Xicloankan (ch c mt vng) A c t khi so vi nit bng 3. A tc dng vi clo c chiu
sng ch cho mt dn xut monoclo duy nht, xc nh cng thc cu to ca A ?
CH3
CH3
CH3
CH3
A.
.
B.
.
C. H3C
.
D. H3C
.
Cu 34: Hai xicloankan M v N u c t khi hi so vi metan bng 5,25. Khi tham gia phn ng
th clo (as, t l mol 1:1) M cho 4 sn phm th cn N cho 1 sn phm th. Tn gi ca cc
xicloankan N v M l:
A. metyl xiclopentan v imetyl xiclobutan. B. Xiclohexan v metyl xiclopentan.
C. Xiclohexan v n-propyl xiclopropan.
D. C A, B, C u ng.
Cu 35: (A) l cht no trong phn ng sau y ?
A + Br2 Br-CH2-CH2-CH2-Br
A. propan.
B. 1-brompropan.
C. xiclopopan.
D. A v B u ng.
Cu 36: Dn hn hp kh A gm propan v xiclopropan i vo dung dch brom s quan st c
hin tng no sau y :
A. Mu ca dung dch nht dn, khng c kh thot ra.
B. Mu ca dung dch nht dn, v c kh thot ra.
C. Mu ca dung dch mt hn, khng cn kh thot ra.
D. Mu ca dung dch khng i.
Cu 37: Cho hn hp 2 ankan A v B th kh, c t l s mol trong hn hp: n A : nB = 1 : 4. Khi
lng phn t trung bnh l 52,4. Cng thc phn t ca hai ankan A v B ln lt l:
A. C2H6 v C4H10.
B. C5H12 v C6H14.
C. C2H6 v C3H8.
D. C4H10 v C3H8
Cu 38: Khi tin hnh craking 22,4 lt kh C4H10 (ktc) thu c hn hp A gm CH4, C2H6, C2H4,
C3H6, C4H8, H2 v C4H10 d. t chy hon ton A thu c x gam CO 2 v y gam H2O. Gi tr ca x
v y tng ng l:
A. 176 v 180.
B. 44 v 18.
C. 44 v 72.
D. 176 v 90.
Cu 39: Craking n-butan thu c 35 mol hn hp A gm H 2, CH4, C2H4, C2H6, C3H6, C4H8 v mt
phn butan cha b craking. Gi s ch c cc phn ng to ra cc sn phm trn. Cho A qua bnh
nc brom d thy cn li 20 mol kh. Nu t chy hon ton A th thu c x mol CO2.
a. Hiu sut phn ng to hn hp A l:
A. 57,14%.
B. 75,00%.
C. 42,86%.
D. 25,00%.
b. Gi tr ca x l:
A. 140.
B. 70.
C. 80.
D. 40.
Cu 40: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch
kh o cng iu kin nhit v p sut); t khi ca Y so vi H 2 bng 12. Cng thc phn t
ca X l:
A. C6H14.
B. C3H8.
C. C4H10.
D. C5H12.
Cu 41: Khi crackinh hon ton mt ankan X thu c hn hp Y (cc th tch kh o cng iu
kin nhit v p sut); t khi ca Y so vi H2 bng 29. Cng thc phn t ca X l:
A. C6H14.
B. C3H8.
C. C4H10.
D. C5H12
Cu 42: Craking 8,8 gam propan thu c hn hp A gm H2, CH4, C2H4, C3H6 v mt phn propan
cha b craking. Bit hiu sut phn ng l 90%. Khi lng phn t trung bnh ca A l:
A. 39,6.
B. 23,16.
C. 2,315.
D. 3,96.
Cu 43: Craking 40 lt n-butan thu c 56 lt hn hp A gm H2, CH4, C2H4, C2H6, C3H6, C4H8 v
mt phn n-butan cha b craking (cc th tch kh o cng iu kin nhit v p sut). Gi s
ch c cc phn ng to ra cc sn phm trn. Hiu sut phn ng to hn hp A l:
A. 40%.
B. 20%.
C. 80%.
D. 20%.
13
Cu 44: Craking m gam n-butan thu c hp A gm H 2, CH4, C2H4, C2H6, C3H6, C4H8 v mt
phn butan cha b craking. t chy hon ton A thu c 9 gam H 2O v 17,6 gam CO2. Gi tr
ca m l
A. 5,8.
B. 11,6.
C. 2,6.
D. 23,2.
Cu 45: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng
kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO 2 ( ktc) v 9,9 gam nc.
Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
Cu 46: t chy mt hn hp hirocacbon ta thu c 2,24 lt CO2 (ktc) v 2,7 gam H2O th th
tch O2 tham gia phn ng chy (ktc) l:
A. 5,6 lt.
B. 2,8 lt.
C. 4,48 lt.
D. 3,92 lt.
Cu 47: Hn hp kh A gm etan v propan. t chy hn hp A thu c kh CO2 v hi H2O theo
t l th tch 11:15. Thnh phn % theo khi lng ca hn hp l:
A. 18,52% ; 81,48%.
B. 45% ; 55%.
C. 28,13% ; 71,87%.
D. 25% ; 75%.
Cu 48: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X
tc dng vi kh clo thu c 4 sn phm monoclo. Tn gi ca X l:
A. 2-metylbutan.
B. etan.
C. 2,2-imetylpropan.
D. 2-metylpropan.
Cu 49: Mt hn hp 2 ankan lin tip trong dy ng ng c t khi hi vi H2 l 24,8.
a. Cng thc phn t ca 2 ankan l:
A. C2H6 v C3H8.
B. C4H10 v C5H12.
C. C3H8 v C4H10.
D. Kt qu khc
b. Thnh phn phn trm v th tch ca 2 ankan l:
A. 30% v 70%.
B. 35% v 65%.
C. 60% v 40%.
D. 50% v 50%
Cu 50: iu kin tiu chun c 1 hn hp kh gm 2 hirocacbon no A v B, t khi hi ca hn
hp i vi H2 l 12.
a. Khi lng CO2 v hi H2O sinh ra khi t chy 15,68 lt hn hp ( ktc).
A. 24,2 gam v 16,2 gam.
B. 48,4 gam v 32,4 gam.
C. 40 gam v 30 gam.
D. Kt qu khc.
b. Cng thc phn t ca A v B l:
A. CH4 v C2H6.
B. CH4 v C3H8.
C. CH4 v C4H10.
D. C A, B v C.
3
3
Cu 51: t 10 cm mt hirocacbon bng 80 cm oxi (ly d). Sn phm thu c sau khi cho hi
nc ngng t cn 65 cm3 trong c 25 cm3 oxi d. Cc th tch trong cng iu kin. CTPT
ca hirocacbon l:
A. C4H10.
B. C4H6.
C. C5H10.
D. C3H8
Cu 52: t chy hon ton hn hp X gm hai ankan k tip trong dy ng ng c 24,2 gam
CO2 v 12,6 gam H2O. Cng thc phn t 2 ankan l:
A. CH4 v C2H6.
B. C2H6 v C3H8.
C. C3H8 v C4H10.
D. C4H10 v C5H12
Cu 53: X l hn hp 2 ankan. t chy ht 10,2 gam X cn 25,76 lt O 2 (ktc). Hp th ton b
sn phm chy vo nc vi trong d c m gam kt ta.
a. Gi tr m l:
A. 30,8 gam.
B. 70 gam.
C. 55 gam.
D. 15 gam
b. Cng thc phn t ca A v B l:
A. CH4 v C4H10.
B. C2H6 v C4H10.
C. C3H8 v C4H10.
D. C A, B v C.
Cu 54: Hirocacbon X chy cho th tch hi nc gp 1,2 ln th tch CO 2 (o cng k). Khi tc
dng vi clo to m t dn xut monoclo duy nht. X c tn l:
A. isobutan.
B. propan.
C. etan.
D. 2,2- imetylpropan.
Cu 55: t chy hon ton hn hp X gm 2 hirocacbon l ng ng lin tip, sau phn ng thu
c VCO2:VH2O =1:1,6 (o cng k). X gm:
A. CH4 v C2H6.
B. C2H4 v C3H6.
C. C2H2 v C3H6.
D. C3H8 v C4H10.
14
Cu 56: t chy hon ton 0,2 mol hirocacbon X. Hp th ton b sn phm chy vo nc vi
trong c 20 gam kt ta. Lc b kt ta ri un nng phn nc lc li c 10 gam kt ta na.
V y X khng th l:
A. C2H6.
B. C2H4.
C. CH4.
D. C2H2
Cu 57: n gin ta xem xng l hn hp cc ng phn ca hexan v khng kh gm 80% N 2
v 20% O2 (theo th tch). T l th tch xng (hi) v khng kh cn ly l bao nhiu xng c
chy hon ton trong cc ng c t trong ?
A. 1: 9,5.
B. 1: 47,5.
C. 1:48.
D. 1:50
Cu 58: t chy hon ton hn hp hai hirocacbon ng ng c khi lng phn t hn km
nhau 28 vC, ta thu c 4,48 l CO2 (ktc) v 5,4 gam H2O. CTPT ca 2 hirocacbon trn l:
A. C2H4 v C4H8.
B. C2H2 v C4H6.
C. C3H4 v C5H8.
D. CH4 v C3H8.
Cu 59: Cho 224,00 lt metan (ktc) qua h quang c V lt hn hp A (ktc) cha 12% C 2H2 ;
10% CH4 ; 78%H2 (v th tch). Gi s ch xy ra 2 phn ng:
2CH4 C2H2 + 3H2 (1)
CH4 C + 2H2
(2)
Gi tr ca V l:
A. 407,27.
B. 448,00.
C. 520,18.
D. 472,64.
Cu 60: t chy hon ton 2,24 lt hn hp A (ktc) gm CH 4, C2H6 v C3H8 thu c V lt kh
CO2 (ktc) v 7,2 gam H2O. Gi tr ca V l:
A. 5,60.
B. 6,72.
C. 4,48.
D. 2,24.
Cu 61: t chy hon ton 6,72 lt hn hp A (ktc) gm CH4, C2H6, C3H8, C2H4 v C3H6, thu
c 11,2 lt kh CO2 (ktc) v 12,6 gam H2O. Tng th tch ca C2H4 v C3H6 (ktc) trong hn hp
A l:
A. 5,60.
B. 3,36.
C. 4,48.
D. 2,24.
Cu 62: t chy hon ton hn hp A gm CH4, C2H2, C3H4, C4H6 thu c x mol CO2 v 18x
gam H2O. Phn trm th tch ca CH4 trong A l:
A. 30%.
B. 40%.
C. 50%.
D. 60%.
Cu 63: t chy hon ton hn hp kh X gm 2 hirocacbon A v B l ng ng k tip thu
c 96,8 gam CO2 v 57,6 gam H2O. Cng thc phn t ca A v B l:
A. CH4 v C2H6.
B. C2H6 v C3H8.
C. C3H8 v C4H10.
D. C4H10 v C5H12
Cu 64: Hn hp kh X gm 2 hirocacbon A v B l ng ng k tip. t chy X vi 64 gam O 2
(d) ri dn sn phm thu c qua bnh ng Ca(OH) 2 d thu c 100 gam kt ta. Kh ra khi
bnh c th tch 11,2 lt 0oC v 0,4 atm. Cng thc phn t ca A v B l:
A. CH4 v C2H6.
B. C2H6 v C3H8. C. C3H8 v C4H10.
D. C4H10 v C5H12
Cu 65: Khi t chy hon ton V lt hn hp kh gm CH4, C2H6, C3H8 (ktc) thu c 44 gam
CO2 v 28,8 gam H2O. Gi tr ca V l:
A. 8,96.
B. 11,20.
C. 13,44.
D. 15,68.
Cu 66: Khi t chy hon ton 7,84 lt hn hp kh gm CH 4, C2H6, C3H8 (ktc) thu c 16,8 lt
kh CO2 (ktc) v x gam H2O. Gi tr ca x l:
A. 6,3.
B. 13,5.
C. 18,0.
D. 19,8.
Cu 67: Khi t chy hon ton hn hp 2 ankan l ng ng k tip thu c 7,84 lt kh CO 2
(ktc) v 9,0 gam H2O. Cng thc phn t ca 2 ankan l:
A. CH4 v C2H6.
B. C2H6 v C3H8.
C. C3H8 v C4H10.
D. C4H10 v C5H12.
Cu 68: Np mt hn hp kh c 20% th tch ankan A v 80% th tch O 2 (d) vo kh nhin k.
Sau khi cho n ri cho hi nc ngng t nhit ban u th p sut trong kh nhin k gim i
2 ln. Thit lp cng thc phn t ca ankan A.
A. CH4.
B. C2H6.
C. C3H8 .
D.C4H10.
Cu 69: t chy mt s mol nh nhau cua 3 hirocacbon K, L, M ta thu c lng CO 2 nh
nhau v t l s mol nc v CO 2 i vi s mol ca K, L, M tng ng l 0,5 : 1 : 1,5. Xc nh
CT K, L, M (vit theo th t tng ng):
A. C2H4 , C2H6 , C3H4.
B. C3H8 , C3H4 , C2H4.
C. C3H4 , C3H6 , C3H8.
D. C2H2 , C2H4 , C2H6
15
Cu 70: Nung m gam hn hp X gm 3 mui natri ca 3 axit no n chc vi NaOH d thu c

cht rn D v hn hp Y gm 3 ankan. T khi ca Y so vi H2 l 11,5. Cho D tc dng vi H2SO4
d thu c 17,92 lt CO2 (ktc).
a. Gi tr ca m l:
A. 42,0.
B. 84,8.
C. 42,4.
D. 71,2.
b. Tn gi ca 1 trong 3 ankan thu c l:
A. metan.
B. etan.
C. propan.
D. butan.
16
CHUYN 3 :
HIROCACBON KHNG NO
BI TP V ANKEN
Cu 1: Anken X c cng thc cu to: CH3CH2C(CH3)=CHCH3. Tn ca X l

A. isohexan.
B. 3-metylpent-3-en. C. 3-metylpent-2-en. D. 2-etylbut-2-en.
Cu 2: S ng phn ca C4H8 l
A. 7.
B. 4.
C. 6.
D. 5.
Cu 3: Hp cht C5H10 mch h c bao nhiu ng phn cu to ?
A. 4.
B. 5.
C. 6.
D. 10.
Cu 4: Hp cht C5H10 c bao nhiu ng phn anken ?
A. 4.
B. 5.
C. 6.
D. 7.
Cu 5: Hp cht C5H10 c bao nhiu ng phn cu to ?
A. 4.
B. 5.
C. 6.
D. 10.
Cu 6: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi
lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankin.
B. ankan.
C. ankaien.
D. anken.
Cu 7: Anken X c c im: Trong phn t c 8 lin kt xch ma. CTPT ca X l
A. C2H4.
B. C4H8.
C. C3H6.
D. C5H10.
Cu 8: Vitamin A cng thc phn t C20H30O, c cha 1 vng 6 cnh v khng c cha lin kt ba.
S lin kt i trong phn t vitamin A l
A. 7.
B. 6.
C. 5.
D. 4.
Cu 9: Licopen, cng thc phn t C40H56 l cht mu trong qu c chua, ch cha lin kt i
v lin kt n trong phn t. Hiro ha hon ton licopen c hirocacbon C 40H82. V y licopen
c
A. 1 vng; 12 ni i.
B. 1 vng; 5 ni i.
C. 4 vng; 5 ni i.
D. mch h; 13 ni i.
Cu 10: Cho cc cht sau: 2-metylbut-1-en (1); 3,3-imetylbut-1-en (2); 3-metylpent-1-en (3);
3-metylpent-2-en (4); Nhng cht no l ng phn ca nhau ?
A. (3) v (4).
B. (1), (2) v (3).
C. (1) v (2).
D. (2), (3) v (4).
Cu 11: Hp cht no sau y c ng phn hnh hc ?
A. 2-metylbut-2-en.
B. 2-clo-but-1-en.
C. 2,3- iclobut-2-en.
D. 2,3- imetylpent-2-en.
Cu 12: Nhng hp cht no sau y c ng phn hnh hc (cis-trans) ?
CH3CH=CH2 (I); CH3CH=CHCl (II); CH3CH=C(CH3)2 (III); C2H5C(CH3)=C(CH3)C2H5 (IV);
C2H5C(CH3)=CClCH3 (V).
A. (I), (IV), (V).
B. (II), (IV), (V).
C. (III), (IV).
D. (II), III, (IV), (V).
Cu 13: Cho cc cht sau: CH2=CHCH2CH2CH=CH2; CH2=CHCH=CHCH2CH3;
CH3C(CH3)=CHCH2; CH2=CHCH2CH=CH2; CH3CH2CH=CHCH2CH3; CH3C(CH3)=CHCH2CH3;
CH3CH2C(CH3)=C(C2H5)CH(CH3)2; CH3CH=CHCH3.
S cht c ng phn hnh hc l:
A. 4.
B. 1.
C. 2.
D. 3.
Cu 14: p dng quy tc Maccopnhicop vo trng hp no sau y ?
A. Phn ng cng ca Br2 vi anken i xng.
C. Phn ng cng ca HX vo anken i xng.
B. Phn ng trng hp ca anken.
D. Phn ng cng ca HX vo anken bt i xng.
17
Cu 15: Khi cho but-1-en tc dng vi dung dch HBr, theo qui tc Maccopnhicop sn phm no
sau y l sn phm chnh ?
A. CH3-CH2-CHBr-CH2Br.
C. CH3-CH2-CHBr-CH3.
B. CH2Br-CH2-CH2-CH2Br .
D. CH3-CH2-CH2-CH2Br.
Cu 16: Anken C4H8 c bao nhiu ng phn khi tc dng vi dung dch HCl ch cho mt sn
phm hu c duy nht ?
A. 2.
B. 1.
C. 3.
D. 4.
Cu 17: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy
gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l:
A. xiclobutan, cis-but-2-en v but-1-en.
B. but-1-en, 2-metylpropen v cis-but-2-en.
C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis -but-2-en v xiclobutan.
Cu 18: Cho hn hp tt c cc ng phn mch h ca C 4H8 tc dng vi H2O (H+,to) thu c ti
a bao nhiu sn phm cng ?
A. 2.
B. 4.
C. 6.
D. 5
Cu 19: C bao nhiu anken th kh (kt) m khi cho mi anken tc dng vi dung dch HCl
ch cho mt sn phm hu c duy nht ?
A. 2.
B. 1.
C. 3.
D. 4.
Cu 20: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2).
C. eten v but-2-en (hoc buten-2).
D. eten v but-1-en (hoc buten-1).
Cu 21: Anken thch hp iu ch ancol sau y (CH3 CH2)3C-OH l
A. 3-etylpent-2-en.
B. 3-etylpent-3-en.
C. 3-etylpent-1-en.
D. 3,3- imetylpent-1-en.
Cu 22: Hirat ha hn hp X gm 2 anken thu c ch thu c 2 ancol. X gm
A. CH2=CH2 v CH2=CHCH3.
B. CH2=CH2 v CH3CH=CHCH3.
C. B hoc D.
D. CH3CH=CHCH3 v CH2=CHCH2CH3.
Cu 23: S cp ng phn cu to anken th kh (kt) tho mn iu kin: Khi hirat ho to
thnh hn hp gm ba ancol l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 24: S cp ng phn anken th kh (kt) tho mn iu kin: Khi hirat ho to thnh hn
hp gm ba ancol l:
A. 6.
B. 7.
C. 5.
D. 8.
Cu 25: Hp cht X c CTPT C 3H6, X tc dng vi dung dch HBr thu c mt sn phm hu c
duy nht. Vy X l:
A. propen.
B. propan.
C. ispropen.
D. xicloropan.
Cu 26: Hai cht X, Y c CTPT C3H6 v C4H8 v u tc dng c vi nc brom. X, Y l
A. Hai anken hoc xicloankan vng 3 cnh. C. Hai anken hoc xicloankan vng 4 cnh.
B. Hai anken hoc hai ankan.
D. Hai anken ng ng ca nhau.
Cu 27: C hai ng nghim, mi ng cha 1 ml dung dch brom trong nc c mu vng nht.
Thm vo ng th nht 1 ml hexan v ng th hai 1 ml hex-1-en. Lc u c hai ng nghim, sau
yn hai ng nghim trong vi pht. Hin tng quan st c l:
A. C s tch lp cc cht lng c hai ng nghim.
B. Mu vng nht vn khng i ng nghim th nht
C. ng nghim th hai c hai lp cht lng u khng mu.
D. A, B, C u ng.
Cu 28: Trng hp eten, sn phm thu c c cu to l:
A. (-CH2=CH2-)n .
B. (-CH2-CH2-)n .C. (-CH=CH-)n.
D. (-CH3-CH3-)n .
Cu 29: Oxi ho etilen bng dung dch KMnO4 thu c sn phm l:
A. MnO2, C2H4(OH)2, KOH.
C. K2CO3, H2O, MnO2.
B. C2H5OH, MnO2, KOH.
D. C2H4(OH)2, K2CO3, MnO2.
Cu 30: X l hn hp gm 2 hirocacbon. t chy X c nCO 2 = nH2O. X c th gm
A. 1xicloankan + anken.
B. 1ankan + 1ankin.
18
C. 2 anken.
D. A hoc B hoc C.
Cu 31: iu ch etilen trong phng th nghim t C 2H5OH, (H2SO4 c, 170oC) thng ln cc

oxit nh SO2, CO2. Cht dng lm sch etilen l:
A. dd brom d.
B. dd NaOH d.
C. dd Na2CO3 d.
D. dd KMnO4 long d.
Cu 32: Sn phm chnh ca s ehirat ha 2-metylbutan-2-ol l cht no ?
A. 3-Metylbut-1-en. B. 2-Metylbut-1en.
C. 3-Metylbut-2-en. D. 2-Metylbut-2-en.
Cu 33: Khi tch nc t ru (ancol) 3-metylbutanol-1 (hay 3-metylbutan-1-ol), sn phm chnh
thu c l:
A. 2-metylbuten-3 (hay 2-metylbut-3-en).
B. 3-metylbuten-2 (hay 3-metylbut-2-en).
C. 3-metylbuten-1 (hay 3-metylbut-1-en).
D. 2-metylbuten-2 (hay 2-metylbut-2-en).
Cu 34: Hp cht 2-metylbut-2-en l sn phm chnh ca phn ng tch t cht no ?
A. 2-brom-2-metylbutan.
B. 2-metylbutan -2- ol.
C. 3-metylbutan-2- ol.
D. Tt c u ng.
Cu 35: Khi lng etilen thu c khi un nng 230 gam ru etylic vi H2SO4 m c, hiu
sut phn ng t 40% l:
A. 56 gam.
B. 84 gam.
C. 196 gam.
D. 350 gam.
Cu 36: Cho 3,36 lt hn hp etan v etilen (ktc) i chm qua qua dung dch brom d. Sau phn
ng khi lng bnh brom tng thm 2,8 gam. S mol etan v etilen trong hn hp ln lt l:
A. 0,05 v 0,1.
B. 0,1 v 0,05.
C. 0,12 v 0,03.
D. 0,03 v 0,12.
Cu 37: 2,8 gam anken A lm mt mu va dung dch cha 8 gam Br 2. Hirat ha A ch thu
c m t ancol duy nht. A c tn l:
A. etilen.
B. but - 2-en.
C. hex- 2-en.
D. 2,3-dimetylbut-2-en.
Cu 38: 0,05 mol hirocacbon X lm mt mu va dung dch cha 8 gam brom cho ra sn phm
c hm lng brom t 69,56%. Cng thc phn t ca X l:
A. C3H6.
B. C4H8.
C. C5H10.
D. C5H8.
Cu 39: Dn t t 8,4 gam hn hp X gm but-1-en v but-2-en li chm qua bnh ng dung dch
Br2, khi kt thc phn ng thy c m gam brom phn ng. m c gi tr l:
A. 12 gam.
B. 24 gam.
C. 36 gam.
D. 48 gam.
Cu 40: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d,
thy khi lng bnh tng thm 7,7 gam. Thnh phn phn % v th tch ca hai anken l:
A. 25% v 75%.
B. 33,33% v 66,67%. C. 40% v 60%.
D. 35% v 65%.
Cu 41: Hn hp X gm 2 anken l ng ng lin tip c th tch 4,48 lt ( ktc). Nu cho hn
hp X i qua bnh ng nc brom d, khi lng bnh tng ln 9,8 gam. % th tch ca mt trong
2 anken l:
A. 50%.
B. 40%.
C. 70%.
D. 80%.
Cu 42: Dn 3,36 lt (ktc) hn hp X gm 2 anken l ng ng k tip vo bnh nc brom d,
thy khi lng bnh tng thm 7,7 gam. CTPT ca 2 anken l:
A. C2H4 v C3H6.
B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. C5H10 v C6H12.
Cu 43: Mt hn hp X c th tch 11,2 lt (ktc), X gm 2 anken ng ng k tip nhau. Khi cho
X qua nc Br2 d thy khi lng bnh Br 2 tng 15,4 gam. Xc nh CTPT v s mol mi anken
trong hn hp X.
A. 0,2 mol C2H4 v 0,3 mol C3H6.
B. 0,2 mol C3H6 v 0,2 mol C4H8.
C. 0,4 mol C2H4 v 0,1 mol C3H6.
D. 0,3 mol C2H4 v 0,2 mol C3H6.
Cu 44: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B
u th kh ( ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, khi lng bnh brom
tng ln 2,8 gam; th tch kh cn li ch bng 2/3 th tch hn hp X ban u. CTPT ca A, B v
khi lng ca hn hp X l:
19
A. C4H10, C3H6 ; 5,8 gam.
B. C3H8, C2H4 ; 5,8 gam.
C. C4H10, C3H6 ; 12,8 gam.
D. C3H8, C2H4 ; 11,6 gam.
Cu 45: Mt hn hp X gm ankan A v mt anken B c cng s nguyn t C v u th kh
ktc. Cho hn hp X i qua nc Br 2 d th th tch kh Y cn li bng na th tch X, cn khi
lng Y bng 15/29 khi lng X. CTPT A, B v thnh phn % theo th tch ca hn hp X l
A. 40% C2H6 v 60% C2H4.
B. 50% C3H8v 50% C3H6
C. 50% C4H10 v 50% C4H8.
D. 50% C2H6 v 50% C2H4
Cu 46 : Hn hp X gm metan v 1 olefin. Cho 10,8 lt hn hp X qua dung dch brom d thy c
1 cht kh bay ra, t chy hon ton kh ny thu c 5,544 gam CO 2. Thnh phn % v th tch
metan v olefin trong hn hp X l:
A. 26,13% v 73,87%.
B. 36,5% v 63,5%.
C. 20% v 80%.
D. 73,9% v 26,1%.
Cu 47: Cho 8960 ml (ktc) anken X qua dung dch brom d. Sau phn ng thy khi lng bnh
brom tng 22,4 gam. Bit X c ng phn hnh hc. CTCT ca X l:
A. CH2=CHCH2CH3.
B. CH3CH=CHCH3.
C. CH3CH=CHCH2CH3.
D. (CH3)2C=CH2.
Cu 48: a. Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c
cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm
hu c khc nhau. Tn gi ca X l:
A. but-1-en.
B. but-2-en.
C. Propilen.
D. Xiclopropan.
b. Hirocacbon X c ng HCl theo t l mol 1:1 to sn phm c hm lng clo l 55,04%. X c
cng thc phn t l:
A. C4H8.
B. C2H4.
C. C5H10.
D. C3H6.
Cu 49: Hn hp X gm metan v anken, cho 5,6 lt X qua dung dch brom d thy khi lng
bnh brom tng 7,28 gam v c 2,688 lt kh bay ra (ktc). CTPT ca anken l:
A. C4H8.
B. C5H10.
C. C3H6.
D. C2H4
Cu 50: Dn 3,36 lt (ktc) hn hp X gm 2 anken l vo bnh nc brom d, thy khi lng
bnh tng thm 7,7 gam. CTPT ca 2 anken l:
A. C2H4 v C4H8.
B. C3H6 v C4H8.
C. C4H8 v C5H10.
D. A hoc B.
Cu 51: Cho 10 lt hn hp kh (54,6 oC; 0,8064 atm) gm 2 olefin li qua bnh dung dch brom d
thy khi lng bnh brom tng 16,8 gam. CTPT ca 2 anken l (Bit s C trong cc anken khng
vt qu 5)
A. C2H4 v C5H10.
B. C3H6 v C5H10.
C. C4H8 v C5H10.
D. A hoc B.
Cu 52: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn
khi lng clo l 45,223%. Cng thc phn t ca X l:
A. C3H6.
B. C4H8.
C. C2H4.
D. C5H10.
Cu 53: Cho hn hp X gm etilen v H 2 c t khi so vi H2 bng 4,25. Dn X qua bt niken nung
nng (hiu sut phn ng 75%) thu c hn hp Y. T khi ca Y so vi H 2 (cc th tch o cng
iu kin) l:
A. 5,23.
B. 3,25.
C. 5,35.
D. 10,46.
Cu 54: Cho H2 v 1 olefin c th tch bng nhau qua Niken un nng ta c hn hp A. Bit t
khi hi ca A i vi H 2 l 23,2. Hiu sut phn ng hiro ho l 75%. Cng thc phn t olefin
l
A. C2H4.
B. C3H6.
C. C4H8.
D. C5H10.
Cu 55: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy
nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon
ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H 2 bng 13.
Cng thc cu to ca anken l:
A. CH3CH=CHCH3. B. CH2=CHCH2CH3. C. CH2=C(CH3)2.D. CH2=CH2.
Cu 56: Cho hn hp X gm anken v hiro c t khi so vi heli bng 3,33. Cho X i qua bt
niken nung nng n khi phn ng xy ra hon ton, thu c hn hp Y c t khi so vi heli l 4.
CTPT ca X l:
20
A. C2H4.
B. C3H6.
C. C4H8.
D. C5H10.
Cu 57: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu
c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l:
A. 20%.
B. 25%.
C. 50%.
D. 40%.
Cu 58: t chy hon ton a gam hn hp eten, propen, but-2-en cn dng va b lt oxi (
ktc) thu c 2,4 mol CO2 v 2,4 mol nc. Gi tr ca b l:
A. 92,4 lt.
B. 94,2 lt.
C. 80,64 lt.
D. 24,9 lt.
Cu 59: t chy hon ton V lt (ktc) hn hp X gm CH 4, C2H4 thu c 0,15 mol CO2 v 0,2
mol H2O. Gi tr ca V l:
A. 2,24.
B. 3,36.
C. 4,48.
D. 1,68.
Cu 60: t chy hon ton 0,1 mol hm hp gm CH4, C4H10 v C2H4 thu c 0,14 mol CO2 v
0,23mol H2O. S mol ca ankan v anken trong hn hp ln lt l:
A. 0,09 v 0,01.
B. 0,01 v 0,09.
C. 0,08 v 0,02.
D. 0,02 v 0,08.
Cu 61: Mt hn hp kh gm 1 ankan v 1 anken c cng s nguyn t C trong phn t v c
cng s mol. Ly m gam hn hp ny th lm mt mu va 80 gam dung dch 20% Br2 trong
dung mi CCl4. t chy hon ton m gam hn hp thu c 0,6 mol CO 2. Ankan v anken
c cng thc phn t l:
A. C2H6 v C2H4.
B. C4H10 v C4H8.
C. C3H8 v C3H6.
D. C5H12 v C5H10.
Cu 62: t chy hon ton 10ml hirocacbon X cn va 60 ml kh oxi, sau phn ng thu
c 40 ml kh cacbonic. Bit X lm mt mu dung dch brom v c mch cacbon phn nhnh.
CTCT ca X
A. CH2=CHCH2CH3.
B. CH2=C(CH3)2.
C. CH2=C(CH2)2CH3.
D. (CH3)2C=CHCH3.
Cu 63: Cho 0,2 mol hn hp X gm etan, propan v propen qua dung dch brom d, thy khi
lng bnh brom tng 4,2 gam. Lng kh cn li em t chy hon ton thu c 6,48 gam nc.
Vy % th tch etan, propan v propen ln lt l:
A. 30%, 20%, 50%. B. 20%, 50%, 30%.
C. 50%, 20%, 30%. D. 20%, 30%, 50%.
Cu 64: Mt hn hp X gm 2 hirocacbon A, B c cng s nguyn t cacbon. A, B ch c th l
ankan hay anken. t chy 4,48 lt (kc) hn hp X thu c 26,4 gam CO 2 v 12,6 gam H2O. Xc
nh CTPT v s mol ca A, B trong hn hp X.
A. 0,1 mol C3H8 v 0,1 mol C3H6.
B. 0,2 mol C2H6 v 0,2 mol C2H4.
C. 0,08 mol C3H8 v 0,12 mol C3H6.
D. 0,1 mol C2H6 v 0,2 mol C2H4.
Cu 65: Mt hn hp X gm 1 anken A v 1 ankin B, A v B c cng s nguyn t cacbon. X c
khi lng l 12,4 gam, c th tch l 6,72 lt. Cc th tch kh o ktc. CTPT v s mol A, B
trong hn hp X l:
A. 0,2 mol C2H4 v 0,1 mol C2H2.
B. 0,1 mol C3H6 v 0,1 mol C3H4.
C. 0,2 mol C3H6 v 0,1 mol C3H4.
D. 0,1 mol C2H4 v 0,2 mol C2H2.
Cu 66: Mt hn hp A gm 2 hirocacbon X, Y lin tip nhau trong cng dy ng ng. t
chy 11,2 lt hn hp X thu c 57,2 gam CO2 v 23,4 gam CO2. CTPT X, Y v khi lng ca X,
Y l:
A. 12,6 gam C3H6 v 11,2 gam C4H8.
B. 8,6 gam C3H6v 11,2 gam C4H8.
C. 5,6 gam C2H4 v 12,6 gam C3H6.
D. 2,8 gam C2H4 v 16,8 gam C3H6.
Cu 67: t chy hon ton 0,05 mol mt anken A thu c 4,48 lt CO 2 (ktc). Cho A tc dng
vi dung dch HBr ch cho mt sn phm duy nht. CTCT ca A l:
A. CH2=CH2.
B. (CH3)2C=C(CH3)2. C. CH2=C(CH3)2.D. CH3CH=CHCH3.
Cu 68: Hn hp X gm propen l ng ng theo t l th tch 1:1. t 1 th tch hn hp X cn
3,75 th tch oxi (cng k). Vy B l:
A. eten.
B. propan.
C. buten.
D. penten.
Cu 69: em t chy hon ton 0,1 mol hn hp X gm 2 anken l ng ng k tip nhau thu
c CO2 v nc c khi lng hn km nhau 6,76 gam. CTPT ca 2 anken l:
A. C2H4 v C3H6.
B. C3H6 v C4H8.C. C4H8 v C5H10.
D. C5H10 v C6H12.
21
Cu 70: X, Y, Z l 3 hirocacbon k tip trong dy ng ng, trong M Z = 2MX. t chy hon
ton 0,1 mol Y ri hp th ton b sn phm chy vo 2 lt dung dch Ba(OH)2 0,1M c m t
lng kt ta l:
A. 19,7 gam.
B. 39,4 gam.
C. 59,1 gam.
D. 9,85 gam.
Cu 71: Chia hn hp gm C3H6, C2H4, C2H2 thnh hai phn u nhau.
Phn 1: t chy hon ton thu c 2,24 lt CO2 (ktc).
Phn 2: Hiro ho ri t chy ht th th tch CO2 thu c (ktc) l bao nhiu ?
A. 1,12 lt.
B. 2,24 lt.
C. 4,48 lt.
D. 3,36 lt.
Cu 72: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th
tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi
ca X so vi kh H2 l:
A. 12,9.
B. 25,8.
C. 22,2.
D. 11,1
Cu 73: t chy hon ton 0,1 mol anken X thu c CO2 v hi nc. Hp th hon ton sn
phm bng 100 gam dung dch NaOH 21,62% thu c dung dch mi trong nng ca NaOH
ch cn 5%. Cng thc phn t ng ca X l:
A. C2H4.
B. C3H6.
C. C4H8.
D. C5H10.
Cu 74: X l hn hp gm hirocacbon A v O 2 (t l mol tng ng 1:10). t chy hon ton X
c hn hp Y. Dn Y qua bnh H 2SO4 c d c hn Z c t khi so vi hiro l 19. A c cng
thc phn t l:
A. C2H6.
B. C4H8.
C C4H6.
D. C3H6.
Cu 75: m gam hn hp gm C3H6, C2H4 v C2H2 chy hon ton thu c 4,48 lt kh CO 2 (ktc).
Nu hiro ho hon ton m gam hn hp trn ri t chy ht hn hp thu c V lt CO 2 (ktc).
Gi tr ca V l:
A. 3,36.
B. 2,24.
C. 4,48.
D. 1,12.
Cu 76: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau
khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy
hon ton 1,68 lt X th sinh ra 2,8 lt kh CO 2. Cng thc phn t ca hai hirocacbon l (bit cc
th tch kh u o ktc)
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 77: Hn hp X gm C3H8 v C3H6 c t khi so vi hiro l 21,8. t chy ht 5,6 lt X (ktc)
th thu c bao nhiu gam CO2 v bao nhiu gam H2O ?
A. 33 gam v 17,1 gam.
B. 22 gam v 9,9 gam.
C. 13,2 gam v 7,2 gam.
D. 33 gam v 21,6 gam.
Cu 78: Hin nay PVC c iu ch theo s sau:
C2H4 CH2ClCH2Cl C2H3Cl PVC.
Nu hiu sut ton b qu trnh t 80% th lng C2H4 cn dng sn xut 5000 kg PVC l:
A. 280 kg.
B. 1792 kg.
C. 2800 kg.
D. 179,2 kg.
Cu 79: Thi 0,25 mol kh etilen qua 125 ml dung dch KMnO4 1M trong mi trng trung tnh
(hiu sut 100%) khi lng etylen glicol thu c bng
A. 11,625 gam.
B. 23,25 gam.
C. 15,5 gam.
D. 31 gam.
Cu 80: kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt
kh C2H4 ( ktc). Gi tr ti thiu ca V l:
A. 2,240.
B. 2,688.
C. 4,480.
D. 1,344.
Cu 81: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z
gp i khi lng phn t X. t chy 0,1 mol cht Z, sn phm kh hp th hon ton vo dung
dch Ca(OH)2 (d), thu c s gam kt ta l:
A. 20.
B. 40.
C. 30.
D. 10.
Cu 82: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon
ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l:
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
22
Cu 83: X l hn hp C4H8 v O2 (t l mol tng ng 1:10). t chy hon ton X c hn hp
Y. Dn Y qua bnh H2SO4 c d c hn Z. T khi ca Z so vi hiro l
A.18.
B. 19.
C. 20.
D. 21.
Cu 84: Hn hp X gm 2 anken kh phn ng va vi dung dch cha 48 gam brom. Mt khc
t chy hon ton hn hp X dng ht 24,64 lt O2 (ktc). Cng thc phn t ca 2 anken l:
A. C2H4 v C3H6.B. C2H4 v C4H8. C. C3H6 v C4H8.D. A v B u ng.
Cu 85: t chy mt s mol nh nhau ca 3 hirocacbon K, L, M ta thu c lng CO 2 nh
nhau v t l s mol nc v CO 2 i vi s mol ca K, L, M tng ng l 0,5 ; 1 ; 1,5. CTPT ca
K, L, M (vit theo th t tng ng) l:
A. C2H4, C2H6, C3H4. B. C3H8, C3H4, C2H4. C. C3H4, C3H6, C3H8. D. C2H2, C2H4, C2H6.
BI TP V ANKAIEN -TECPEN - ANKIN

Cu 1: S ng phn thuc loi ankaien ng vi cng thc phn t C5H8 l
A. 4.
B. 5.
C. 6.
D. 7.
Cu 2: C5H8 c bao nhiu ng phn ankaien lin hp ?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 3: Trong cc hirocacbon sau: propen, but-1-en, but-2-en, penta-1,4- ien, penta-1,3- ien
hirocacbon cho c hin tng ng phn cis - trans ?
A. propen, but-1-en.
B. penta-1,4-dien, but-1-en.
C. propen, but-2-en.
D. but-2-en, penta-1,3- ien.
Cu 4: Cng thc phn t ca buta-1,3-ien (ivinyl) v isopren (2-metylbuta-1,3-ien) ln lt l
A. C4H6 v C5H10.
B. C4H4 v C5H8.
C. C4H6 v C5H8.
D. C4H8 v C5H10.
Cu 5: Hp cht no trong s cc cht sau c 9 lin kt xch ma v 2 lin kt ?
A. Buta-1,3-ien.
B. Penta-1,3- ien.
C. Stiren.
D. Vinyl axetilen.
Cu 6: Hp cht no trong s cc cht sau c 7 lin kt xch ma v 3 lin kt ?
A. Buta-1,3-ien.
B. Tuloen.
C. Stiren.
D. Vinyl axetilen.
o
Cu 7: Cho phn ng gia buta-1,3-ien v HBr -80 C (t l mol 1:1), sn phm chnh ca phn
ng l
A. CH3CHBrCH=CH2.
B. CH3CH=CHCH2Br.
C. CH2BrCH2CH=CH2.
D. CH3CH=CBrCH3.
Cu 8: Cho phn ng gia buta-1,3-ien v HBr 40oC (t l mol 1:1), sn phm chnh ca phn
ng l
A. CH3CHBrCH=CH2.
B. CH3CH=CHCH2Br.
C. CH2BrCH2CH=CH2.
D. CH3CH=CBrCH3.
Cu 9: 1 mol buta-1,3-ien c th phn ng ti a vi bao nhiu mol brom ?
A. 1 mol.
B. 1,5 mol.
C. 2 mol.
D. 0,5 mol.
Cu 10: Isopren tham gia phn ng vi dung dch Br 2 theo t l mol 1:1 to ra ti a bao nhiu sn
phm ?
A. 4.
B. 1.
C. 3.
D. 2.
Cu 11: Isopren tham gia phn ng vi dung dch HBr theo t l mol 1:1 to ra ti a bao nhiu sn
phm cng ?
A. 8.
B. 5.
C. 7.
D. 6.
Cu 12: Cht no sau y khng phi l sn phm cng gia dung dch brom v isopren (theo t l
mol 1:1) ?
A. CH2BrC(CH3)BrCH=CH2.
B. CH2BrC(CH3)=CHCH2Br.
C. CH2BrCH=CHCH2CH2Br.
D. CH2=C(CH3)CHBrCH2Br.
Cu 13: Ankaien A + brom (dd)

CH3C(CH3)BrCH=CHCH2Br. Vy A l
A. 2-metylpenta-1,3-ien.
B. 2-metylpenta-2,4-ien.
C. 4-metylpenta-1,3-ien.
D. 2-metylbuta-1,3-ien.
23
Cu 14: Ankaien B + Cl2 CH2ClC(CH3)=CH-CH2Cl-CH3. Vy A l
A. 2-metylpenta-1,3-ien.
C. 2-metylpenta-1,4-ien.
D. 4-metylpenta-2,3-ien.
Cu 15: Cho 1 Ankaien A + brom(dd) 1,4-ibrom-2-metylbut-2-en. Vy A l
A. 2-metylbuta-1,3-ien.
C. 3-metylbuta-1,3-ien.
D. 3-metylpenta-1,3-ien.
Cu 16: Trng hp ivinyl to ra cao su Buna c cu to l ?
A. (-C2H-CH-CH-CH2-)n.
B. (-CH2-CH=CH-CH2-)n.
C. (-CH2-CH-CH=CH2-)n.
D. (-CH2-CH2-CH2-CH2-)n.
Cu 17: ng trng hp ivinyl v stiren thu c cao su buna-S c cng thc cu to l
A. (-CH2-CH=CH-CH2-CH(C6H5)-CH2-)n.
B. (-C2H-CH-CH-CH2-CH(C6H5)-CH2-)n.
C. (-CH2-CH-CH=CH2- CH(C6H5)-CH2-)n.
D. (-CH2-CH2-CH2-CH2- CH(C6H5)-CH2-)n .
Cu 18: ng trng hp ivinyl v acrylonitrin (vinyl xianua) thu c cao su buna-N c cng
thc cu to l
A. (-C2H-CH-CH-CH2-CH(CN)-CH2-)n.
B. (-CH2-CH2-CH2-CH2- CH(CN)-CH2-)n.
C. (-CH2-CH-CH=CH2- CH(CN)-CH2-)n.D. (-CH2-CH=CH-CH2-CH(CN)-CH2-)n .
Cu 19: Trng hp isopren to ra cao su isopren c cu to l
A. (-C2H-C(CH3)-CH-CH2-)n .
C. (-CH2-C(CH3)-CH=CH2-)n .
B. (-CH2-C(CH3)=CH-CH2-)n.
D. (-CH2-CH(CH3)-CH2-CH2-)n .
Cu 20: Tn gi ca nhm hirocacbon khng no c cng thc chung l (C5H8)n (n 2) l
A. ankaien.
B. cao su.
C. anlen.
D. tecpen.
Cu 21: Caroten (licopen) l sc t mu ca c rt v c chua chn, cng thc phn t ca
caroten l
A. C15H25.
B. C40H56.
C. C10H16.
D. C30H50.
Cu 22: Oximen c trong tinh du l hng qu, limonen c trong tinh du chanh. Chng c cng
cng thc phn t l
A. C15H25.
B. C40H56.
C. C10H16.
D. C30H50.
Cu 23: C4H6 c bao nhiu ng phn mch h ?
A. 5.
B. 2.
C. 3.
D. 4.
Cu 24: C bao nhiu ankin ng vi cng thc phn t C5H8 ?
A. 1.
B. 2.
C. 3.
D. 4
Cu 25: Ankin C4H6 c bao nhiu ng phn cho phn ng th kim loi (phn ng vi dung dch
cha AgNO3/NH3)
A. 4.
B. 2.
C. 1.
D. 3.
Cu 26: C bao nhiu ng phn ankin C5H8 tc dng c vi dung dch AgNO3/NH3 to kt ta
A. 3.
B. 2.
C. 4.
D. 1.
Cu 27: Ankin C6H10 c bao nhiu ng phn phn ng vi dung dch AgNO3/NH3 ?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 28: Trong phn t ankin X, hiro chim 11,111% khi lng. C bao nhiu ankin ph hp
A. 1.
B. 2.
C. 3.
D. 4
Cu 29: Cho ankin X c cng thc cu to sau :
CH3C C CH CH3
Tn ca X l
CH3
A. 4-metylpent-2-in. B. 2-metylpent-3-in. C. 4-metylpent-3-in. D. 2-metylpent-4-in.
Cu 30: Cho phn ng : C2H2 + H2O

A
A l cht no di y
A. CH2=CHOH.
B. CH3CHO.
C. CH3COOH.
D. C2H5OH.
Cu 31: Cho s phn ng sau: CH3-CCH + AgNO3/ NH3 X + NH4NO3
X c cng thc cu to l?
A. CH3-CAgCAg.
B. CH3-CCAg.
C. AgCH2-CCAg.
D. A, B, C u c th ng.
24
Cu 32: Trong s cc hirocacbon mch h sau: C4H10, C4H6, C4H8, C3H4, nhng hirocacbon no
c th to kt ta vi dung dch AgNO3/NH3 ?
A. C4H10 ,C4H8.
B. C4H6, C3H4.
C. Ch c C4H6.
D. Ch c C3H4.
Cu 33: Hn hp A gm hiro v cc hirocacbon no, cha no. Cho A vo bnh c niken xc tc,
un nng bnh mt thi gian ta thu c hn hp B. Pht biu no sau y sai ?
A. t chy hon ton hn hp A cho s mol CO2 v s mol nc lun bng s mol CO2 v
s mol nc khi t chy hon ton hn hp B.
B. S mol oxi tiu tn t hon ton hn hp A lun bng s mol oxi tiu tn khi t hon
ton hn hp B.
C. S mol A - S mol B = S mol H2 tham gia phn ng.
D. Khi lng phn t trung bnh ca hn hp A bng khi lng phn t trung bnh ca hn
hp B.
Cu 34: Cht no trong 4 cht di y c th tham gia c 4 phn ng: Phn ng chy trong oxi,
phn ng cng brom, phn ng cng hiro (xc tc Ni, to), phn ng th vi dd AgNO3 /NH3
A. etan.
B. etilen.
C. axetilen.
D. xiclopropan.
Cu 35: Cu no sau y sai ?
A. Ankin c s ng phn t hn anken tng ng.
B. Ankin tng t anken u c ng phn hnh hc.
C. Hai ankin u dy khng c ng phn.
D. Butin c 2 ng phn v tr nhm chc.
Cu 36: Cho cc phn ng sau:
(1)
askt
CH4 + Cl 2
(2) C2H4 + H2
(3) 2 CHCH
(4) 3 CHCH
(5) C2H2 + Ag2O
(6) Propin + H2O
S phn ng l phn ng oxi ho kh l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 37: Cho dy chuyn ho sau: CH4

A
B
C
Cao su buna. Cng thc phn t
ca B l
A. C4H6.
B. C2H5OH.
C. C4H4.
D. C4H10.
Cu 38: C chui phn ng sau:
KOH
N + H2 B D HCl E (spc) D
Xc nh N, B, D, E bit rng D l mt hidrocacbon mch h, D ch c 1 ng phn.
A. N : C2H2 ; B : Pd ; D : C2H4 ; E : CH3CH2Cl.
B. N : C4H6 ; B : Pd ; D : C4H8 ; E : CH2ClCH2CH2CH3.
C. N : C3H4 ; B : Pd ; D : C3H6 ; E : CH3CHClCH3.
D. N : C3H4 ; B : Pd ; D : C3H6 ; E : CHCH2CH2Cl.
Cu 39: Cht no sau y khng iu ch trc tip c axetilen ?
A. Ag2C2.
B. CH4.
C. Al4C3.
D. CaC2.
Cu 40: lm sch etilen c ln axetilen ta cho hn hp i qua dd no sau y ?
A. dd brom d.
B. dd KMnO4 d.
C. dd AgNO3 /NH3 d.
D. cc cch trn u ng.
Cu 41: nhn bit cc bnh ring bit ng cc kh khng mu sau y: SO2, C2H2, NH3 ta c
th dng ho cht no sau y ?
A. Dung dch AgNO3/NH3.
B. Dung dch Ca(OH)2
C. Qu tm m.
D. Dung dch NaOH
Cu 42: X l mt hirocacbon kh ( ktc), mch h. Hiro ho hon ton X thu c hirocacbon
no Y c khi lng phn t gp 1,074 ln khi lng phn t X. Cng thc phn t X l
A. C2H2.
B. C3H4.
C. C4H6.
D. C3H6.
Cu 43: Cht hu c X c cng thc phn t C6H6 mch thng. Bit 1 mol X tc dng vi AgNO3
d trong NH3 to ra 292 gam kt ta. CTCT ca X c th l
A. CH CCCCH2CH3.
C. CHCCH2CH=C=CH2.
B. CHCCH2CCCH3.
D. CHCCH2CH2CCH.
1:1
25
Cu 44: Mt hirocacbon A mch thng c CTPT C6H6. Khi cho A tc dng vi dung dch
AgNO3/NH3 d thu c hp cht hu c B c MB - MA=214 vC. Xc nh CTCT ca A ?
A. CHCCH2CH2CCH.
B. CH3C CCH2CCH.
C. CHCCH(CH3)CCH.
D. CH3CH2CCCCH.
Cu 45: A l hirocacbon mch h, th kh (kt), bit A 1 mol A tc dng c ti a 2 mol Br 2
trong dung dch to ra hp cht B (trong B brom chim 88,88% v khi lng. V y A c cng thc
phn t l
A. C5H8.
B. C2H2.
C. C4H6.
D. C3H4.
Cu 46: 4 gam mt ankin X c th lm mt mu ti a 100 ml dung dch Br2 2M. CTPT X l
A. C5H8 .
B. C2H2.
C. C3H4.
D. C4H6.
Cu 47: X l mt hirocacbon khng no mch h, 1 mol X c th lm mt mu ti a 2 mol brom
trong nc. X c % khi lng H trong phn t l 10%. CTPT X l
A. C2H2.
B. C3H4.
C. C2H4.
D. C4H6.
Cu 48: X l hn hp gm 2 hirocacbon mch h (thuc dy ng ng ankin, anken, ankan).
Cho 0,3 mol X lm mt mu va 0,5 mol brom. Pht biu no di y ng
A. X c th gm 2 ankan.
B. X c th gm2 anken.
C. X c th gm1 ankan v 1 anken.
D. X c th gm1 anken v mt ankin.
Cu 49: Hn hp X gm 1 ankin th kh v hiro c t khi hi so vi CH 4 l 0,425. Nung nng
hn hp X vi xc tc Ni phn ng hon ton thu c hn hp kh Y c t khi hi so vi CH 4
l 0,8. Cho Y i qua bnh ng dung dch brom d, khi lng bnh tng ln bao nhiu gam ?
A. 8.
B. 16.
C. 0.
D. Khng tnh c.
Cu 50: Hn hp A gm C2H2 v H2 c dA/H2 = 5,8. Dn A (ktc) qua bt Ni nung nng cho n
khi cc phn ng xy ra hon ton ta c hn hp B. Phn trm th tch mi kh trong hn hp A
v dB/H2 l
A. 40% H2; 60% C2H2; 29.
B. 40% H2; 60% C2H2 ; 14,5.
C. 60% H2; 40% C2H2 ; 29.
D. 60% H2; 40% C2H2 ; 14,5.
Cu 51: Mt hn hp gm etilen v axetilen c th tch 6,72 lt (ktc). Cho hn hp qua dung
dch brom d phn ng xy ra hon ton, lng brom phn ng l 64 gam. Phn % v th tch
etilen v axetilen ln lt l
A. 66% v 34%.
B. 65,66% v 34,34%.
C. 66,67% v 33,33%.
D. Kt qu khc.
Cu 52: Cho 10 lt hn hp kh CH4 v C2H2 tc dng vi 10 lt H2 (Ni, to). Sau khi phn ng xy ra
hon ton thu c 16 lt hn hp kh (cc kh u o cng iu kin nhit p sut). Th tch
ca CH4 v C2H2 trc phn ng l
A. 2 lt v 8 lt.
B. 3 lt v 7 lt.
C. 8 lt v 2 lt.
D. 2,5 lt v 7,5 lt.
Cu 53: Cho 28,2 gam hn hp X gm 3 ankin ng ng k tip qua mt lng d H 2 (to, Ni)
phn ng xy ra hon ton. Sau phn ng th tch th tch kh H 2 gim 26,88 lt (ktc). CTPT ca 3
ankin l
A. C2H2, C3H4, C4H6.
B. C3H4, C4H6, C5H8.
C. C4H6, C5H8, C6H10.
D. C A, B u ng.
Cu 54: Hn hp X gm propin v mt ankin A c t l mol 1:1. Ly 0,3 mol X tc dng vi dung
dch AgNO3/NH3 d thu c 46,2 gam kt ta. A l
A. But-1-in.
B. But-2-in.
C. Axetilen.
D. Pent-1-in.
Cu 55: Trong bnh kn cha hirocacbon X v hiro. Nung nng bnh n khi phn ng hon ton
thu c kh Y duy nht. cng nhit , p sut trong bnh trc khi nung nng gp 3 ln p sut
trong bnh sau khi nung. t chy mt lng Y thu c 8,8 gam CO 2 v 5,4 gam nc. Cng thc
phn t ca X l
A. C2H2.
B. C2H4.
C. C4H6.
D. C3H4.
Cu 56: t chy hon ton mt ankin X th kh thu c H2O v CO2 c tng khi lng l 23
gam. Nu cho sn phm chy i qua dung dich Ca(OH) 2 d, c 40 gam kt ta. Cng thc phn
t ca X l
A. C3H4.
B. C2H2.
C. C4H6.
D. C5H8.
26
Cu 57: t chy hon ton 5,4 gam mt hirocacbon A ri cho sn phm chy i qua bnh 1 ng
dd H2SO4 c, d; bnh 2 ng dung dch Ba(OH)2 d thy khi lng bnh 1 tng 5,4 gam; bnh 2
tng 17,6 gam. A l cht no trong nhng cht sau ? (A khng tc dng vi dd AgNO3/NH3)
A. But-1-in.
B. But-2-in.
C. Buta-1,3-ien.
D. B hoc C.
Cu 58: Hn hp X gm C2H2 v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht
xc tc thch hp, un nng c hn hp Y gm 4 cht. Dn Y qua bnh ng nc brom thy
khi lung bnh tng 10,8 gam v thot ra 4,48 lt kh Z (ktc) c t khi so vi H2 l 8. Th tch O2
(ktc) cn t chy hon ton hn hp Y l
A. 33,6 lt.
B. 22,4 lt.
C. 16,8 lt.
D. 44,8 lt.
Cu 59: Cho 17,92 lt hn hp X gm 3 hirocacbon kh l ankan, anken v ankin ly theo t l mol
1:1:2 li qua bnh ng dd AgNO 3/NH3 ly d thu c 96 gam kt ta v hn hp kh Y cn li.
t chy hon ton hn hp Y thu c 13,44 lt CO2. Bit th tch o ktc. Khi lng ca X l
A. 19,2 gam.
B. 1,92 gam.
C. 3,84 gam.
D. 38,4 gam.
Cu 60: Mt hn hp gm 2 ankin khi t chy cho ra 13,2 gam CO2 v 3,6 gam H2O. Tnh khi
lng brom c th cng vo hn hp trn
A. 16 gam.
B. 24 gam.
C. 32 gam.
D. 4 gam.
Cu 61: Cho canxi cacbua k thut (ch cha 80% CaC2 nguyn cht) vo nc d, th thu c
3,36 lt kh (ktc). Khi lng canxi cacbua k thut dng l
A. 9,6 gam.
B. 4,8 gam
C. 4,6 gam.
D. 12 gam
Cu 62: C 20 gam mt mu CaC2 (c ln tp cht tr) tc dng vi nc thu c 7,4 lt kh
axetilen (20oC, 740mmHg). Cho rng phn ng xy ra hon ton. tinh khit ca mu CaC2 l
A. 64%.
B. 96%.
C. 84%.
D. 48%.
Cu 63: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom
(d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X
tc dng vi lng d dung dch AgNO 3 trong NH3, thu c 36 gam kt ta. Phn trm th tch
ca CH4 c trong X l
A. 40%.
B. 20%.
C. 25%.
D. 50%.
Cu 64: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn
hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N
ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,1 mol C3H6 v 0,2 mol C3H4.
C. 0,2 mol C2H4 v 0,1 mol C2H2.
D. 0,2 mol C3H6 v 0,1 mol C3H4.
Cu 65: Trong m t bnh kn cha hirocacbon A th kh (kt) v O2 (d). B t tia la i n t
chy ht A a hn hp v iu kin ban u trong % th tch ca CO 2 v hi nc ln lt l
30% v 20%. Cng thc phn t ca A v % th tch ca hirocacbon A trong hn hp l
A. C3H4 v 10%.
B. C3H4 v 90%.
C. C3H8 v 20%.
D. C4H6 v 30%.
Cu 66: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO 2 v 2
lt hi H2O (cc th tch kh v hi o trong cng iu kin nhit v p sut). Cng thc phn t
ca X l
A. C2H4.
B. CH4.
C. C2H6.
D. C3H8.
Cu 67: Hn hp X c t khi so vi H 2 l 21 gm propan, propen v propin. Khi t chy hon
ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l
A. 18,60 gam.
B. 18,96 gam.
C. 20,40 gam.
D. 16,80 gam.
Cu 68: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo
s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh
thin nhin v hiu sut ca c qu trnh l 50%)
A. 224,0.
B. 448,0.
C. 286,7.
D. 358,4.
Cu 69: un nng hn hp kh gm 0,06 mol C 2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi
gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d)
th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O 2 l 0,5. Khi lng bnh dung dch
brom tng l
A. 1,20 gam.
B. 1,04 gam.
C. 1,64 gam.
D. 1,32 gam.
27
Cu 70: t chy hon ton m gam hirocacbon th kh, mch h, nng hn khng kh thu c
7,04 gam CO2. Sc m gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c
25,6 gam brom phn ng. Gi tr ca m l
A. 2 gam.
B. 4 gam.
C. 10 gam
D. 2,08 gam
Cu 71: t chy hon ton m gam hirocacbon th kh, mch h thu c 7,04 gam CO 2. Sc m
gam hirocacbon ny vo nc brom d n khi phn ng hon ton, thy c 25,6 gam brom phn
ng. Gi tr ca m l
A. 2 gam.
B. 4 gam.
C. 2,08 gam.
D. A hoc C.
Cu 72: Dn V lt ( ktc) hh X gm axetilen v hiro i qua ng s ng bt niken nung nng,
thu c kh Y. Dn Y vo lng d AgNO3 trong dd NH3 thu c 12 gam kt ta. Kh i ra khi
dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z c 2,24
lt kh CO2 (ktc) v 4,5 gam H2O. Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
Cu 73: Cho 4,48 lt hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt
dung dch Br2 0,5M. Sau khi p hon ton, s mol Br2 gim i mt na v m bnh tng thm 6,7
gam. CTPT ca 2 hirocacbon l
A. C3H4 v C4H8.
B. C2H2 v C3H8. C. C2H2 v C4H8.
D. C2H2 v C4H6.
Cu 74: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dd brom (d). Sau khi
phn ng hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton
1,68 lt X th sinh ra 2,8 lt kh CO2 (ktc). CTPT ca hai hirocacbon l
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 75: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO 2
bng s mol H2O. Thnh phn % v s mol ca X v Y trong hn hp M ln lt l
A. 35% v 65%.
B. 75% v 25%.
C. 20% v 80%.
D. 50% v 50%.
Cu 76: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th
tch CH4), thu c 24,0 ml CO2 (cc kh o cng iu kin t o, p). T khi ca X so vi kh hiro
l
A. 25,8.
B. 12,9.
C. 22,2.
D. 11,1.
Cu 77: Mt hn hp X gm 1 ankan A v 1 ankin B c cng s nguyn t cacbon. Trn X vi
H2 c hn hp Y. Khi cho Y qua Pt nung nng th thu c kh Z c t khi i vi CO 2
bng 1 (phn ng cng H 2 hon ton). Bit rng V X = 6,72 lt v VH = 4,48 lt. CTPT v s mol
A, B trong hn hp X l (Cc th tch kh o kc)
A. 0,1 mol C2H6 v 0,2 mol C2H2.
B. 0,1 mol C3H8 v 0,2 mol C3H4.
C. 0,2 mol C2H6 v 0,1 mol C2H2.
D. 0,2 mol C3H8 v 0,1 mol C3H4.
Cu 78: Mt hn hp X gm C2H2, C3H6, CH4. t chy hon ton 11t hn hp X thu c 12,6
gam H2O. Nu cho 11,2 lt hn hp X (ktc) qua dung dch brom d thy c 100 gam brom phn
ng. Thnh phn % th tch ca X ln lt l
A. 50%; 25% ; 25%.
B. 25% ; 25; 50%.
C.16% ; 32; 52%.
D. 33,33%; 33,33; 33,33%.
Cu 79: Dn 4,032 lt (ktc) hn hp kh A gm C2H2, C2H4, CH4 ln lt qua bnh 1 cha dung dc
AgNO3 trong NH3 ri qua bnh 2 cha dung dch Br2 d trong CCl4. bnh 1 c 7,2 gam kt ta.
Khi lng bnh 2 tng thm 1,68 gam. Th tch (ktc) hn hp A ln lt l:
A. 0,672 lt; 1,344 lt; 2,016 lt.
B. 0,672 lt; 0,672 lt; 2,688 lt.
C. 2,016; 0,896 lt; 1,12 lt.
D. 1,344 lt; 2,016 lt; 0,672 lt.
Cu 80: X, Y, Z l 3 hirocacbon th kh trong iu kin thng, khi phn hu mi cht X, Y, Z
u to ra C v H2, th tch H2 lun gp 3 ln th tch hirocacbon b phn hu v X, Y, Z khng
phi l dng phn. CTPT ca 3 cht l
A. C2H6 ,C3H6 C4H6. B. C2H2 ,C3H4 C4H6. C. CH4 ,C2H4 C3H4.
D. CH4 ,C2H6 C3H8.
Cu 81: Hn hp X gm 0,1 mol C2H2; 0,15 mol C2H4 ; 0,2 mol C2H6 v 0,3 mol H2. un nng X
vi bt Ni xc tc 1 thi gian c hn hp Y. t chy hon ton hn hp Y c s gam CO2 v
H2O ln lt l
A. 39,6 v 23,4.
B. 3,96 v 3,35.
C. 39,6 v 46,8.
D. 39,6 v 11,6.
2
28
Cu 82: Hn hp ban u gm 1 ankin, 1 anken, 1 ankan v H 2 vi p sut 4 atm. un nng bnh
vi Ni xc tc thc hin phn ng cng sau a bnh v nhit ban u c hn hp Y, p
sut hn hp Y l 3 atm. T khi hn hp X v Y so vi H2 ln lt l 24 v x. Gi tr ca x l
A. 18.
B. 34.
C. 24.
D. 32.
Cu 83: Hn hp A gm H2, C3H8, C3H4. Cho t t 12 lt A qua bt Ni xc tc. Sau phn ng c
6 lt kh duy nht (cc kh o cng iu kin). T khi hi ca A so vi H2 l
A. 11.
B. 22.
C. 26.
D. 13.
Cu 84: un nng hn hp X gm 0,1 mol C 3H4 ; 0,2 mol C2H4 ; 0,35 mol H2 vi bt Ni xc tc
c hn hp Y. Dn ton b Y qua bnh ng dung dch KMnO 4 d, thy thot ra 6,72 l hn hp
kh Z (ktc) c t khi so vi H2 l 12. Bnh ng dung dch KMnO4 tng s gam l:
A. 17,2.
B. 9,6.
C. 7,2.
D. 3,1.
Cu 85: t chy m gam hn hp C2H6, C3H4, C3H8, C4H10 c 35,2 gam CO2 v 21,6 gam H2O.
Gi tr ca m l
A. 14,4.
B. 10,8.
C. 12.
D. 56,8.
Cu 86: t chy 1 hirocacbon A c 22,4 lt kh CO2 (ktc) v 27 gam H2O. Th tch O2 (ktc)
(l) tham gia phn ng l:
A. 24,8.
B. 45,3.
C. 39,2.
D. 51,2.
Cu 87: Mt hn hp X gm 1 ankin v H 2 c V = 8,96 lt (kc) v m X = 4,6 gam. Cho hn hp X
i qua Ni nung nng, phn ng hon ton cho ra hn hp kh Y, c t khi d Y X = 2. S mol H2 phn
ng; khi lng; CTPT ca ankin l
A. 0,16 mol; 3,6 gam; C2H2.
B. 0,2 mol; 4 gam; C3H4.
C. 0,2 mol; 4 gam; C2H2.
D. 0,3 mol; 2 gam; C3H4.
Cu 88: t chy mt hirocacbon M thu c s mol nc bng s mol CO 2 v s mol CO2
nh hn hoc bng 5 ln s mol M. Xc nh CTPT v CTCT ca M bit rng M cho kt ta vi
dung dch AgNO3/NH3.
A. C4H6 v CH3CH2C CH.
B. C4H6 v CH2=C=CHCH3.
C. C3H4 v CH3C CH.
D. C4H6 v CH3C CCH3.
29
CHUYN 4 : HIROCACBON THM NGUN

HIROCACBON THIN NHIN
Cu 1: Trong phn t benzen, cc nguyn t C u trng thi lai ho :
A. sp.
B. sp2.
C. sp3.
D. sp2d.
Cu 2: Trong vng benzen mi nguyn t C dng 1 obitan p cha tham gia lai ho to ra :
A. 2 lin kt pi ring l.
B. 2 lin kt pi ring l.
C. 1 h lin kt pi chung cho 6 C.
D. 1 h lin kt xigma chung cho 6 C.
Cu 3: Trong phn t benzen:
A. 6 nguyn t H v 6 C u nm trn 1 mt phng.
B. 6 nguyn t H nm trn cng 1 mt phng khc vi mt phng ca 6 C.
C. Ch c 6 C nm trong cng 1 mt phng.
D. Ch c 6 H mm trong cng 1 mt phng.
Cu 4: Cho cc cng thc :
H
(1)
(2)
(3)
Cu to no l ca benzen ?
A. (1) v (2).
B. (1) v (3).
C. (2) v (3).
D. (1) ; (2) v (3).
Cu 5: Dy ng ng ca benzen c cng thc chung l:
A. CnH2n+6 ; n 6.
B. CnH2n-6 ; n 3.
C. CnH2n-6 ; n 6.
D. CnH2n-6 ; n 6.
Cu 6: Cng thc tng qut ca hirocacbon CnH2n+2-2a. i vi stiren, gi tr ca n v a ln lt l:
A. 8 v 5.
B. 5 v 8.
C. 8 v 4.
D. 4 v 8.
Cu 7: Cng thc tng qut ca hirocacbon CnH2n+2-2a. i vi naptalen, gi tr ca n v a ln lt
l:
A. 10 v 5.
B. 10 v 6.
C. 10 v 7.
D.10 v 8.
Cu 8: Cht no sau y c th cha vng benzen ?
A. C10H16.
B. C9H14BrCl.
C. C8H6Cl2.
D. C7H12.
Cu 9: Cht no sau y khng th cha vng benzen ?
A. C8H10.
B. C6H8.
C. C8H10.
D. C9H12.
Cu 10: Cho cc cht: C6H5CH3 (1)
p-CH3C6H4C2H5 (2)
C6H5C2H3 (3)
o-CH3C6H4CH3 (4)
Dy gm cc cht l ng ng ca benzen l:
A. (1); (2) v (3).
B. (2); (3) v (4).
C. (1); (3) v (4).
D. (1); (2) v (4).
CH3
Cu 11: Cht cu to nh sau c tn gi l g ?

A. o-xilen.
B. m-xilen.
Cu 12: CH3C6H2C2H5 c tn gi l:
A. etylmetylbenzen.
C. p-etylmetylbenzen.
Cu 13: (CH3)2CHC6H5 c tn gi l:
A. propylbenzen.
C. iso-propylbenzen.
Cu 14: iso-propyl benzen cn gi l:
A.Toluen.
B. Stiren.
30
CH3
C. p-xilen.
D. 1,5-imetylbenzen.
B. metyletylbenzen.
D. p-metyletylbenzen.
B. n-propylbenzen.
D. imetylbenzen.
C. Cumen.
D. Xilen.
Cu 15: Cu to ca 4-cloetylbenzen l:
C2H5
C 2H 5
C2H5
C2H5
Cl
Cl
A. Cl
B.
C.
D.
Cu 16: Ankylbenzen l hirocacbon c cha :
A. vng benzen.
B. gc ankyl v vng benzen.
C. gc ankyl v 1 benzen.
D. gc ankyl v 1 vng benzen.
Cu 17: Gc C6H5-CH2- v gc C6H5- c tn gi l:
A. phenyl v benzyl.
B. vinyl v anlyl.
C. anlyl v Vinyl.
D. benzyl v phenyl.
Cu 18: iu no sau u khng ng kh ni v 2 v tr trn 1 vng benzen ?
A. v tr 1, 2 gi l ortho.
B. v tr 1,4 gi l para.
C. v tr 1,3 gi l meta.
D. v tr 1,5 gi l ortho.
Cu 19: Mt ankylbenzen A c cng thc C9H12, cu to c tnh i xng cao. Vy A l:
A. 1,2,3-trimetyl benzen.
B. n-propyl benzen.
C. iso-propyl benzen.
D. 1,3,5-trimetyl benzen.
Cu 20: Mt ankylbenzen A (C12H18) cu to c tnh i xng cao. A l:
A. 1,3,5-trietylbenzen.
B. 1,2,4-tri etylbenzen.
C. 1,2,3-tri metylbenzen.
D. 1,2,3,4,5,6-hexaetylbenzen.
Cu 21: C7H8 c s ng phn thm l:
A. 1.
B. 2.
C. 3.
D. 4.
Cu 22: ng vi cng thc phn t C8H10 c bao nhiu cu to cha vng benzen ?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 23: ng vi cng thc C9H12 c bao nhiu ng phn c cu to cha vng benzen ?
A. 6.
B. 7.
C. 8.
D. 9.
Cu 24: S lng ng phn cha vng benzen ng vi cng thc phn t C9H10 l
A. 7.
B. 8.
C. 9.
D. 6.
Cu 25: A l ng ng ca benzen c cng thc nguyn l: (C3H4)n. Cng thc phn t ca A l:
A. C3H4.
B. C6H8.
C. C9H12.
D. C12H16.
Cu 26: Cho cc cht (1) benzen ; (2) toluen; (3) xiclohexan; (4) hex-5-trien; (5) xilen; (6) cumen.
Dy gm cc hirocacbon thm l:
A. (1); (2); (3); (4).
B. (1); (2); (5; (6).
C. (2); (3); (5) ; (6).
D. (1); (5); (6); (4).
Cu 27: Hot tnh sinh hc ca benzen, toluen l:
A. Gy hi cho sc khe.
B. Khng gy hi cho sc khe.
C. Gy nh hng tt cho sc khe.
D. Ty thuc vo nhit c th gy hi hoc khng gy hi.
Cu 28: Tnh cht no sau y khng phi ca ankyl benzen
A. Khng mu sc.
B. Khng mi v.
C. Khng tan trong nc.
D. Tan nhiu trong cc dung mi hu c.
Cu 29: Phn ng no sau y khng xy ra:
A. Benzen + Cl2 (as).
B. Benzen + H2 (Ni, p, to).
C. Benzen + Br2 (dd).
D. Benzen + HNO3 () /H2SO4 ().
Cu 30: Tnh cht no khng phi ca benzen ?
A. D th.
B. Kh cng.
C. Bn vi cht oxi ha.
D. Km bn vi cc cht oxi ha.
Cu 31: Cho benzen + Cl2 (as) ta thu c dn xut clo A. Vy A l:
A. C6H5Cl.
B. p-C6H4Cl2.
C. C6H6Cl6.
D. m-C6H4Cl2.
Cl
31
Cu 32: Phn ng chng minh tnh cht no; khng no ca benzen ln lt l:
A. th, cng.
B. cng, nitro ho.
C. chy, cng.
D. cng, brom ho.
Cu 33: Tnh cht no khng phi ca benzen
A. Tc dng vi Br2 (to, Fe).
B. Tc dng vi HNO3 () /H2SO4().
C. Tc dng vi dung dch KMnO4.
D. Tc dng vi Cl2 (as).
Cu 34: Benzen + X
etyl benzen. Vy X l
A. axetilen.
B. etilen.
C. etyl clorua.
D. etan.
Cu 35: Tnh cht no khng phi ca toluen ?
A. Tc dng vi Br2 (to, Fe).
B. Tc dng vi Cl2 (as).
C. Tc dng vi dung dch KMnO4, to.
D. Tc dng vi dung dch Br2.
Cu 36: So vi benzen, toluen + dung dch HNO3()/H2SO4 ():
A. D hn, to ra o nitro toluen v p nitro toluen.
B. Kh hn, to ra o nitro toluen v p nitro toluen.
C. D hn, to ra o nitro toluen v m nitro toluen.
D. D hn, to ra m nitro toluen v p nitro toluen.
Cu 37: Toluen + Cl2 (as) xy ra phn ng:
A. Cng vo vng benzen.
B. Th vo vng benzen, d dng hn.
C. Th nhnh, kh khn hn CH4.
D. Th nhnh, d dng hn CH4.
as
Cu 38: 1 mol Toluen + 1 mol Cl2
A . A l:
A. C6H5CH2Cl.
B. p-ClC6H4CH3.
C. o-ClC6H4CH3.
D. B v C u ng.
Cu 39: Tin hnh th nghim cho nitro benzen tc dng vi HNO3 ()/H2SO4 (), nng ta thy:
A. Khng c phn ng xy ra.
B. Phn ng d hn benzen, u tin v tr meta.
C. Phn ng kh hn benzen, u tin v tr meta.
D. Phn ng kh hn benzen, u tin v tr ortho.
Cu 40: Khi trn vng benzen c sn nhm th -X, th nhm th hai s u tin th vo v tr o- v
p- . Vy -X l nhng nhm th no ?
A. -CnH2n+1, -OH, -NH2.
B. -OCH3, -NH2, -NO2.
C. -CH3, -NH2, -COOH.
D. -NO2, -COOH, -SO3H.
Cu 41: Khi trn vng benzen c sn nhm th -X, th nhm th hai s u tin th vo v tr m - .
Vy -X l nhng nhm th no ?
A. -CnH2n+1, -OH, -NH2.
B. -OCH3, -NH2, -NO2.
C. -CH3, -NH2, -COOH.
D. -NO2, -COOH, -SO3H.
H 2 SO4 d
Cu 42: 1 mol nitrobenzen + 1 mol HNO3

B + H2O. B l:
to
A. m-initrobenzen.
B. o-initrobenzen.
C. p-initrobenzen.
D. B v C u ng.
Cu 43: C2H2 A B m-brombenzen. A v B ln lt l:
A. benzen ; nitrobenzen.
B. benzen,brombenzen.
C. nitrobenzen ; benzen.
D. nitrobenzen; brombenzen.
Cu 44: Benzen A o-brom-nitrobenzen. Cng thc ca A l:
A. nitrobenzen.
B. brombenzen.
C. aminobenzen.
D. o-ibrombenzen.
Cu 45: 1 ankylbenzen A(C9H12),tc dng vi HNO3 c (H2SO4 ) theo t l mol 1:1 to ra 1 dn
xut mononitro duy nht . Vy A l:
A. n-propylbenzen.
B. p-etyl,metylbenzen.
D. iso-propylbenzen
D. 1,3,5-trimetylbenzen.
trung / hop
Cu 46: Cho phn ng A
1,3,5-trimetylbenzen . A l:
A. axetilen.
B. metyl axetilen.
C. etyl axetilen.
D. imetyl axetilen.
32
Cu 47: Stiren khng phn ng c vi nhng cht no sau y ?
A. dd Br2.
B. khng kh H2 ,Ni,to.
C. dd KMnO4.
D. dd NaOH.
Ni , p ,t o
Cu 48: A + 4H2
etyl xiclohexan. Cu to ca A l:
A. C6H5CH2CH3.
B. C6H5CH3.
C. C6H5CH2CH=CH2.
D. C6H5CH=CH2.
Cu 49: Phn ng no sau y khng dng iu ch benzen ?
A. tam hp axetilen.
B. kh H2 ca xiclohexan.
C. kh H2, ng vng n-hexan.
D. tam hp etilen.
Cu 50: Phn ng no khng iu ch c toluen ?
o
A. C6H6 + CH3Cl
B. kh H2, ng vng benzen
AlCl3 ;t
C. kh H2 metylxiclohexan
D. tam hp propin
xt ,t o
Cu 51: A
toluen + 4H2. Vy A l:
A. metyl xiclo hexan.
B. metyl xiclo hexen.
C. n-hexan.
D. n-heptan.
Cu 52: ng dng no benzen khng c:
A. Lm dung mi.
B. Tng hp monome.
C. Lm thuc n.
D. Dng trc tip lm dc phm.
Cu 53: Thuc n TNT c iu ch trc tip t
A. benzen.
B. metyl benzen.
C. vinyl benzen.
D. p-xilen.
Cu 54: phn bit benzen, toluen, stiren ta ch dng 1 thuc th duy nht l:
A. Brom (dd).
B. Br2 (Fe).
C. KMnO4 (dd).
D. Br2 (dd) hoc KMnO4(dd).
Cu 55: phn bit c cc cht Hex-1-in, Toluen, Benzen ta dng 1 thuc th duy nht l:
A. dd AgNO3/NH3.
B. dd Brom.
C. dd KMnO4.
D. dd HCl.
Cu 56: A l dn xut benzen c cng thc nguyn (CH) n. 1 mol A cng ti a 4 mol H 2 hoc 1
mol Br2 (dd). Vy A l:
A. etyl benzen.
B. metyl benzen.
C. vinyl benzen.
D. ankyl benzen.
Cu 57: a. Mt hn hp X gm 2 aren A, R u c M < 120, t khi ca X i vi C 2H6 l 3,067.
CTPT v s ng phn ca A v R l
A. C6H6 (1 ng phn) ; C7H8 (1 ng phn).
B. C7H8 (1 ng phn) ; C8H10 (4 ng phn).
C. C6H6 (1 ng phn) ; C8H10 (2 ng phn).
D. C6H6 (1 ng phn) ; C8H10 (4 ng phn).
b. Mt hp cht hu c c vng benzen c CTGN l C 3H2Br v M = 236. Gi tn hp cht ny
bit rng hp cht ny l sn phm chnh trong phn ng gia C6H6 v Br2 (xc tc Fe)
A. o-hoc p-ibrombenzen.
B. o-hoc p-ibromuabenzen.
C. m-ibromuabenzen.
D. m-ibrombenzen.
Cu 58: Hn hp C6H6 v Cl2 c t l mol 1 : 1,5. Trong iu kin c xc tc bt Fe, t o, hiu sut
100%. Sau phn ng thu c cht g ? bao nhiu mol ?
A.1 mol C6H5Cl ; 1 mol HCl ; 1 mol C6H4Cl2.
B. 1,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5mol C6H4Cl2.
C. 1 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2.
D. 0,5 mol C6H5Cl ; 1,5 mol HCl ; 0,5 mol C6H4Cl2.
Cu 59: Cho 100 ml bezen (d = 0,879 g/ml) tc dng vi m t lng va brom lng (xc tc b t
st, un nng) thu c 80 ml brombenzen (d = 1,495 g/ml). Hi u sut brom ha t l
A. 67,6%.
B. 73,49%.
C. 85,3%.
D. 65,35%
33
Cu 60: Cho benzen vo 1 l ng Cl2 d ri a ra nh sng. Sau khi phn ng xy ra hon ton
thu c 5,82 kg cht sn phm. Tn ca sn phm v khi lng benzen tham gia phn ng l:
A. clobenzen; 1,56 kg.
B. hexacloxiclohexan; 1,65 kg.
C. hexacloran; 1,56 kg.
D. hexaclobenzen; 6,15 kg.
Cu 61: A c cng thc phn t l C 8H8, tc dng vi dung dch KMnO4 nhit thng to ra
ancol 2 chc. 1 mol A tc dng ti a vi:
A. 4 mol H2; 1 mol brom.
B. 3 mol H2; 1 mol brom.
C. 3 mol H2; 3 mol brom.
D. 4 mol H2; 4 mol brom.
Cu 62: A l hirocacbon c %C (theo khi lng) l 92,3%. A tc dng vi dung dch brom d
cho sn phm c %C (theo khi lng) l 36,36%. Bit MA < 120. V y A c cng thc phn t l
A. C2H2.
B. C4H4.
C. C6H6.
D. C8H8.
Cu 63: Tin hnh trng hp 10,4 gam stiren c hn hp X gm polistiren v stiren (d). Cho X
tc dng vi 200 ml dung dch Br2 0,15M, sau cho dung KI d vo thy xut hi n 1,27 gam iot.
Hi u sut trng hp stiren l
A. 60%.
B. 75%.
C. 80%.
D. 83,33%.
Cu 64: hiro ho etylbenzen ta c stiren; trng hp stiren ta c polistiren vi hiu sut
chung 80%. Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l:
A.13,52 tn.
B. 10,6 tn.
C. 13,25 tn.
D. 8,48 tn.
Cu 65: a. t chy hon ton m gam A (CxHy), thu c m gam H2O. Cng thc nguyn ca A l:
A. (CH)n.
B. (C2H3)n.
C. (C3H4)n.
D. (C4H7)n.
b. t chy hon ton 1,3 gam A (CxHy) to ra 0,9 gam H2O. Cng thc nguyn ca A l:
A. (CH)n.
B. (C2H3)n.
C. (C3H4)n.
D. (C4H7)n.
Cu 66: t chy hon ton hirocacbon X cho CO 2 v H2O theo t l mol 1,75 : 1 v th tch. Cho
bay hi hon ton 5,06 gam X thu c mt th tch hi ng bng th tch ca 1,76 gam oxi trong
cng iu kin. Nhn xt no sau y l ng i vi X ?
A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung dch KMnO4 un nng.
B. X tc dng vi dung dch Br2 to kt ta trng.
C. X c th trng hp thnh PS.
D. X tan tt trong nc.
Cu 67: t chy hon ton m gam hirocacbon A, thu c m gam H2O. Cng thc phn t ca A
(150 < MA < 170) l:
A. C4H6.
B. C8H12.
C. C16H24.
D. C12H18.
Cu 68: t chy hon ton 6 gam cht hu c A, ng ng ca benzen thu c 10,08 lt CO 2
(ktc). Cng thc phn t ca A l:
A. C9H12.
B. C8H10.
C. C7H8.
D. C10H14.
Cu 69: t chy hon ton 0,1 mol C xHy thu c 20,16 lt CO 2 (ktc) v 10,8 gam H2O (lng).
Cng thc ca CxHy l:
A. C7H8.
B. C8H10.
C. C10H14.
D. C9H12.
Cu 70: A (CxHy) l cht lng iu kin thng. t chy A to ra CO 2 v H2O v mCO2 : mH2O =
4,9 : 1. Cng thc phn t ca A l:
A. C7H8.
B. C6H6.
C. C10H14.
D. C9H12.
Cu 71: t chy hon ton hi A (CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi. Cng thc
phn t ca A l:
A. C7H8.
B. C8H10.
C. C10H14.
D. C9H12.
Cu 72: Cho a gam cht A (CxHy) chy thu c 13,2 gam CO 2 v 3,6 gam H2O. Tam hp A thu
c B, mt ng ng ca ankylbenzen. Cng thc phn t ca A v B ln lt l:
A. C3H6 v C9H8.
B. C2H2 v C6H6.
C. C3H4 v C9H12.
D. C9H12 v C3H4.
Cu 73: 1,3 gam cht hu c A chy hon ton thu c 4,4 gam CO 2 v 0,9 gam H2O. T khi hi
ca A i vi oxi l d tha mn iu kin 3<d<3,5. Cng thc phn t ca A l:
A. C2H2.
B. C8H8.
C. C4H4.
D. C6H6.
34
Cu 74: t chy hon ton m t th tch hi hp cht hu c A cn 10 th tch oxi (o cng iu
kin nhit v p sut), sn phm thu c ch gm CO2 v H2O vi mCO2 : mH2O = 44 : 9. Bit
MA < 150. A c cng thc phn t l
A. C4H6O.
B. C8H8O.
C. C8H8.
D. C2H2.
Cu 75: t chy ht m gam 2 ng ng ca benzen A, B thu c 4,05 gam H 2O v 7,728 lt
CO2 (ktc). Gi tr ca m v s tng s mol ca A, B l:
A. 4,59 v 0,04.
B. 9,18 v 0,08.
C. 4,59 v 0,08.
D. 9,14 v 0,04.
Cu 76: t chy ht 9,18 gam 2 ng ng ca benzen A, B thu c 8,1 gam H 2O v V lt CO2
(ktc). Gi tr ca V l:
A. 15,654.
B. 15,465.
C. 15,546.
D. 15,456.
Cu 77: t chy ht 2,295 gam 2 ng ng ca benzen A, B thu c 2,025 gam H 2O v CO2.
Dn ton b lng CO2 vo 250 ml dung dch NaOH 1M thu c m gam mui. Gi tr ca m v
thnh phn ca mui
A. 16,195 (2 mui).
B. 16,195 (Na2CO3).
C. 7,98 (NaHCO3)
D. 10,6 (Na2CO3).
Cu 78: t chy ht 9,18 gam 2 ng ng k tip thuc dy ca benzen A, B thu c H 2O v
30,36 gam CO2. Cng thc phn t ca A v B ln lt l:
A. C6H6 ; C7H8.
B. C8H10 ; C9H12.
C. C7H8 ; C9H12.
D. C9H12 ; C10H14.
Cu 79: t 0,13 gam mi cht A v B u cng thu c 0,01 mol CO 2 v 0,09 gam H2O. T khi
hi ca A so vi B l 3; t khi hi ca B so vi H2 l 13. Cng thc ca A v B ln lt l:
A. C2H2 v C6H6.
B. C6H6 v C2H2.
C. C2H2 v C4H4.D. C6H6 v C8H8.
Cu 80: A, B, C l ba cht hu c c %C, %H (theo khi lng) ln lt l 92,3% v 7,7%, t l
khi lng mol tng ng l 1: 2 : 3. T A c th iu ch B ho c C bng m t phn ng. C khng
lm mt mu nc brom. t 0,1 mol B ri dn ton b sn phm chy qua bnh ng dung dch
nc vi trong d.
a. Khi lng bnh tng ho c gim bao nhiu gam ?
A. Tng 21,2 gam.
B. Tng 40 gam.
C. Gim 18,8 gam.
D. Gim 21,2 gam.
b. Khi lng dung dch tng ho c gim bao nhiu gam ?
A. Tng 21,2 gam.
B. tng 40 gam.
C. gim 18,8 gam.
D. gim 21,2 gam.
35
CHUYN 5 : DN XUT HALOGEN - PHENOL - ANCOL

Cu 1 : S ng phn ca C4H9Br l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 2: S ng phn dn xut halogen bc I c CTPT C4H9Cl l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 3: S ng phn mch h (k c ng phn hnh hc) ca cht c CTPT l C3H5Br l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 4: Mt hp cht hu c Z c % khi lng ca C, H, Cl ln lt l : 14,28% ; 1,19% ; 84,53%.
CTPT ca Z l
A. CHCl2.
B. C2H2Cl4.
C. C2H4Cl2.
D. mt kt qu khc.
Cu 5: Dn xut halogen khng c ng phn cis-trans l
A. CHCl=CHCl.
B. CH2=CH-CH2F.
C. CH3CH=CBrCH3. D.
CH3CH2CH=CHCHClCH3.
Cu 6: Danh php IUPAC ca dn xut halogen c cng thc cu to : ClCH2CH(CH3)CHClCH3 l
A. 1,3-iclo-2-metylbutan.
B. 2,4-iclo-3-metylbutan.
C. 1,3-iclopentan.
D. 2,4-iclo-2-metylbutan.
Cu 7: Cho cc cht sau: C6H5CH2Cl ; CH3CHClCH3 ; Br2CHCH3 ; CH2=CHCH2Cl. Tn gi ca
cc cht trn ln lt l
A. benzyl clorua ; isopropyl clorua ; 1,1-ibrometan ; anlyl clorua.
B. benzyl clorua ; 2-clopropan ; 1,2-ibrometan ;1-cloprop-2-en.
C. phenyl clorua ; isopropylclorua ; 1,1-ibrometan ; 1-cloprop-2-en.
D. benzyl clorua ; n-propyl clorua ; 1,1-ibrometan ; 1-cloprop-2-en.
Cu 8: Cho cc dn xut halogen sau : C2H5F (1) ; C2H5Br (2) ; C2H5I (3) ; C2H5Cl (4) th t
gim dn nhit si l
A. (3)>(2)>(4)>(1).
B. (1)>(4)>(2)>(3).
C. (1)>(2)>(3)>(4).
D. (3)>(2)>(1)>(4).
Cu 9: Nh dung dch AgNO3 vo ng nghim cha mt t dn xut halogen CH2=CHCH2Cl, lc
nh. Hin tng xy ra l
A. Thot ra kh mu vng lc.
B. xut hin kt ta trng.
C. khng c hin tng.
D. xut hin kt ta vng.
Cu 10: a. Sn phm chnh ca phn ng tch HBr ca CH3CH(CH3)CHBrCH3 l
A. 2-metylbut-2-en. B. 3-metylbut-2-en.
C. 3-metyl-but-1-en. D. 2-metylbut-1-en.
b. Sn phm chnh to thnh khi cho 2-brombutan tc dng vi dung dch KOH/ancol, un nng
A. metylxiclopropan. B. but-2-ol.
C. but-1-en.
D. but-2-en.
Cu 11: un nng 13,875 gam mt ankyl clorua Y vi dung dch NaOH, tch b lp hu c, axit
ha phn cn li bng dung dch HNO3, nh tip vo dd AgNO3 thy to thnh 21,525 gam kt ta.
CTPT ca Y l
A. C2H5Cl.
B. C3H7Cl.
C. C4H9Cl.
D. C5H11Cl.
Cu 12: S tch hiro halogenua ca dn xut halogen X c CTPT C 4H9Cl cho 3 olefin ng
phn, X l cht no trong nhng cht sau y ?
A. n- butyl clorua.
B. sec-butyl clorua. C. iso-butyl clorua.
D. tert-butyl clorua.
o
Cu 13: Cho hp cht thm : ClC6H4CH2Cl + dung dch KOH (long, d, t ) ta thu c cht no ?
A. HOC6H4CH2OH. B. ClC6H4CH2OH.
C. HOC6H4CH2Cl.
D. KOC6H4CH2OH.
Cu 14: Cho hp cht thm : ClC6H4CH2Cl + dung dch KOH (c, d, to, p) ta thu c cht no?
A. KOC6H4CH2OK. B. HOC6H4CH2OH. C. ClC6H4CH2OH.
D. KOC6H4CH2OH.
Cu 15: Thy phn dn xut halogen no sau y s thu c ancol ?
(1) CH3CH2Cl.
(2) CH3CH=CHCl.
(3) C6H5CH2Cl.
(4) C6H5Cl.
A. (1), (3).
B. (1), (2), (3).
C. (1), (2), (4).
D.(1), (2), (3), (4).
Cu 16: a. un si dn xut halogen X vi nc mt thi gian, sau thm dung dch AgNO3 vo
thy xut hin kt ta. X l
A. CH2=CHCH2Cl.
B. CH3CH2CH2Cl.
C. C6H5CH2Br.
D. A hoc C.
36
b. un si dn xut halogen X vi dung dch NaOH long mt thi gian, sau thm dung dch
AgNO3 vo thy xut hin kt ta. X khng th l
A. CH2=CHCH2Cl.
B. CH3CH2CH2Cl.
C. C6H5CH2Cl.
D. C6H5Cl.
Cu 17: Khi un nng dn xut halogen X vi dung dch NaOH to thnh hp cht anehit axetic.
Tn ca hp cht X l
A. 1,2- ibrometan.
B. 1,1- ibrometan.
C. etyl clorua.
D. A v B ng.
Cu 18: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c
(to cao, p cao) thu c cht Y c CTPT l C7H7O2Na. Hy cho bit X c bao nhiu CTCT ?
A. 3.
B. 5.
C. 4.
D. 2.
Cu 19: Cho s phn ng sau:
CH3
Br2/as
Br2/Fe, to
dd NaOH
NaOH n/c, to, p
X, Y, Z, T c cng thc ln lt l
A. p-CH3C6H4Br, p-CH2BrC6H4Br, p-HOCH2C6H4Br, p-HOCH2C6H4OH.
B. CH2BrC6H5, p-CH2Br-C6H4Br, p-HOCH2C6H4Br, p-HOCH2C6H4OH.
C. CH2Br-C6H5, p-CH2Br-C6H4Br, p-CH3C6H4OH, p-CH2OHC6H4OH.
D. p-CH3C6H4Br, p-CH2BrC6H4Br, p-CH2BrC6H4OH, p-CH2OHC6H4OH.
Cu 20: Cho s phn ng sau : CH4 X Y Z T C 6H5OH. (X, Y, Z l cc cht hu
c khc nhau). Z l
A. C6H5Cl.
B. C6H5NH2.
C. C6H5NO2.
D. C6H5ONa.
Cu 21: X l dn xut clo ca etan. un nng X trong NaOH d thu c cht hu c Y va tc
dng vi Na va tc dng vi Cu(OH)2 nhit thng. Vy X l
A. 1,1,2,2-tetracloetan.
B. 1,2-icloetan.
C. 1,1-icloetan.
D. 1,1,1-tricloetan.
Cu 22: Cho 5 cht: CH3CH2CH2Cl (1); CH2=CHCH2Cl (2); C6H5Cl (3); CH2=CHCl (4);
C6H5CH2Cl (5). un tng cht vi dung dch NaOH long, d, sau gn ly lp nc v axit ho
bng dung dch HNO3, sau nh vo dung dch AgNO3 th cc cht c xut hin kt ta trng
l
A. (1), (3), (5).
B. (2), (3), (5).
C. (1), (2), (3), (5).
D. (1), (2), (5).
Cu 23: Cho s chuyn ho : Benzen A B C A axit picric. B l
A. phenylclorua.
B. o Crezol.
C. Natri phenolat.
D. Phenol.
Cu 24: Cho s phn ng : X Cl ,500 C Y NaOH
ancol anlylic. X l cht no sau y ?
A. Propan.
B. Xiclopropan.
C. Propen.
D. Propin.
, ete
CO 2
HCl
Cu 25: Cho s sau : C2H5Br Mg
A
B
C.
C
c
cng
thc
l

A. CH3COOH.
B. CH3CH2COOH.
C. CH3CH2OH.
D. CH3CH2CH2COOH.
Cu 26: Cho bt Mg vo ietyl ete khan, khuy mnh, khng thy hin tng g. Nh t t vo
etyl bromua, khuy u th Mg tan dn thu c dung dch ng nht. Cc hin tng trn c
gii thch nh sau:
A. Mg khng tan trong ietyl ete m tan trong etyl bromua.
B. Mg khng tan trong ietyl ete, Mg phn ng vi etyl bromua thnh etyl magiebromua tan
trong ete.
C. Mg khng tan trong ietyl ete nhng tan trong hn hp ietyl ete v etyl bromua.
D. Mg khng tan trong ietyl ete, Mg phn ng vi etyl bromua thnh C2H5Mg tan trong ete.
Cu 27: Cho s : C6H6 X Y Z m-HOC6H4NH2. X, Y, Z tng ng l
A. C6H5NO2, m-ClC6H4NO2, m-HOC6H4NO2.
B. C6H5NO2, C6H5NH2, m-HOC6H4NO2.
C. C6H5Cl, m-ClC6H4NO2, m-HOC6H4NO2.
D. C6H5Cl, C6H5OH, m-HOC6H4NO2.
Cu 28: Cng thc dy ng ng ca ancol etylic l
A. CnH2n + 2O.
B. ROH.
C. CnH2n + 1OH.
D. Tt c u ng.
2
37
Cu 29: Cng thc no di y l cng thc ca ancol no, mch h chnh xc nht ?
A. R(OH)n.
B. CnH2n + 2O.
C. CnH2n + 2Ox.
D. CnH2n + 2 x (OH)x.
Cu 30: un nng mt ancol X vi H2SO4 c nhit thch hp thu c mt olefin duy nht.
Cng thc tng qut ca X l (vi n > 0, n nguyn)
A. CnH2n + 1OH.
B. ROH.
C. CnH2n + 2O.
D. CnH2n + 1CH2OH.
Cu 31: Tn quc t ca hp cht c cng thc CH3CH(C2H5)CH(OH)CH3 l
A. 4-etyl pentan-2-ol. B. 2-etyl butan-3-ol. C. 3-etyl hexan-5-ol. D. 3-metyl pentan-2-ol.
Cu 32: Mt ancol no c cng thc thc nghim l (C2H5O)n. CTPT ca ancol c th l
A. C2H5O.
B. C4H10O2.
C. C4H10O.
D. C6H15O3.
Cu 33: Ancol no, n chc c 10 nguyn t H trong phn t c s ng phn l
A. 5.
B. 3.
C. 4.
D. 2.
Cu 34: Mt ancol no n chc c %H = 13,04% v khi lng. CTPT ca ancol l
A. C6H5CH2OH.
B. CH3OH.
C. C2H5OH.
D. CH2=CHCH2OH.
Cu 35: Mt ancol no n chc c %O = 50% v khi lng. CTPT ca ancol l
A. C3H7OH.
B. CH3OH.
C. C6H5CH2OH.
D. CH2=CHCH2OH.
Cu 36: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m
phn t ca chng c phn trm khi lng cacbon bng 68,18% ?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 37: C bao nhiu ng phn c cng thc phn t l C4H10O ?
A. 6.
B. 7.
C. 4.
D. 5.
Cu 38: C bao nhiu ancol b c III, c cng thc phn t C6H14O ?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 39: C bao nhiu ancol thm, cng thc C8H10O ?
A. 5.
B. 6.
C. 7.
D. 8.
Cu 40: C bao nhiu ancol thm, cng thc C8H10O khi tc dng vi CuO un nng cho ra anehit?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 41: C bao nhiu ancol C5H12O khi tch nc ch to m t anken duy nht?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 42: S ng phn ancol ng vi CTPT C5H12O l
A. 8.
B. 7.
C. 5.
D. 6.
Cu 43: S ng phn ancol ti a ng vi CTPT C3H8Ox l
A. 4.
B. 5.
C. 6.
D. khng xc nh c.
Cu 44: X l ancol mch h c cha 1 lin kt i trong phn t. khi lng phn t ca X nh
hn 60. CTPT ca X l
A. C3H6O.
B. C2H4O.
C. C2H4(OH)2.
D. C3H6(OH)2.
Cu 45: A, B, D l 3 ng phn c cng cng thc phn t C 3H8O. Bit A tc dng vi CuO un
nng cho ra andehit, cn B cho ra xeton. V y D l
A. Ancol b c III.
B. Cht c nhi t si cao nht.
C. Cht c nhi t si thp nht.
D. Cht c kh nng tch nc to anken duy nht.
Cu 46: X, Y, Z l 3 ancol lin tip trong dy ng ng, trong MZ = 1,875MX. X c c im l
A. Tch nc to 1 anken duy nht.
B. Ha tan c Cu(OH)2.
C. Cha 1 lin kt trong phn t.
D. Khng c ng phn cng chc ho c khc chc.
Cu 47: Ancol X n chc, no, mch h c t khi hi so vi hiro bng 37. Cho X tc dng vi
H2SO4 c un nng n 180oC thy to thnh mt anken c nhnh duy nht. X l
A. propan-2-ol.
B. butan-2-ol.
C. butan-1-ol.
D. 2-metylpropan-2-ol.
38
Cu 48: Mt ancol n chc X mch h tc dng vi HBr c dn xut Y cha 58,4% brom v
khi lng. un X vi H2SO4 c 170oC c 3 anken. Tn X l
A. pentan-2-ol.
B. butan-1-ol.
C. butan-2-ol.
D. 2-metylpropan-2-ol.
Cu 49: Mt cht X c CTPT l C4H8O. X lm mt mu nc brom, tc dng vi Na. Sn phm
oxi ha X bi CuO khng phi l anehit. Vy X l
A. but-3-en-1-ol.
B. but-3-en-2-ol.
C. 2-metylpropenol. D. tt c u sai.
Cu 50: Bc ca ancol l
A. bc cacbon ln nht trong phn t.
B. bc ca cacbon lin kt vi nhm -OH.
C. s nhm chc c trong phn t.
D. s cacbon c trong phn t ancol.
Cu 51: Bc ancol ca 2-metylbutan-2-ol l
A. bc 4.
B. bc 1.
C. bc 2.
D. bc 3.
Cu 52: Cc ancol c phn loi trn c s
A. s lng nhm OH.
B. c im cu to ca gc hirocacbon.
C. bc ca ancol.
D. Tt c cc c s trn.
Cu 53: Cc ancol (CH3)2CHOH ; CH3CH2OH ; (CH3)3COH c bc ancol ln lt l
A. 1, 2, 3.
B. 1, 3, 2.
C. 2, 1, 3.
D. 2, 3, 1.
Cu 54: Cu no sau y l ng ?
A. Hp cht CH3CH2OH l ancol etylic.
B. Ancol l hp cht hu c trong phn t nhm -OH.
C. Hp cht C6H5CH2OH l phenol.
D. Tt c u ng.
Cu 55: Ancol etylic tan tt trong nc v c nhit si cao hn hn so vi ankan v cc dn xut
halogen c khi lng phn t xp x vi n v
A. Trong cc hp cht trn ch c ancol etylic tc dng vi Na.
B. Trong cc hp cht trn ch c ancol etylic c lin kt hiro vi nc.
C. Trong cc hp cht trn ch c ancol etylic c lin kt hiro lin phn t.
D. B v C u ng.
Cu 56: A, B, C l 3 cht hu c c cng cng thc CxHyO. Bit % O (theo khi lng) trong A l
26,66%. Cht c nhi t si thp nht trong s A, B, C l
A. propan-2-ol.
B. propan-1-ol.
C. etylmetyl ete.
D. propanal.
Cu 57: Ancol etylic c ln mt t nc, c th dng cht no sau y lm khan ancol ?
A. CaO.
B. CuSO4 khan.
C. P2O5.
D. tt c u c.
Cu 58: Phng php iu ch ancol etylic t cht no sau y l phng php sinh ha ?
A. Anehit axetic.
B. Etylclorua.
C. Tinh bt.
D. Etilen.
Cu 59: Anken thch hp iu ch 3-etylpentan-3-ol bng phn ng hirat ha l
A. 3,3-imetyl pent-2-en.
B. 3-etyl pent-2-en.
C. 3-etyl pent-1-en.
D. 3-etyl pent-3-en.
Cu 60: Hirat ha 2-metyl but-2-en thu c sn phm chnh l
A. 2-metyl butan-2-ol. B. 3-metyl butan-1-ol. C. 3-metyl butan-2-ol. D. 2-metyl butan-1-ol.
Cu 61: Hirat ha propen v mt olefin A thu c 3 ancol c s C trong phn t khng qu 4.
Tn ca A l
A. etilen.
B. but-2-en.
C. isobutilen.
D. A, B u ng.
Cu 62: X l hn hp gm hai anken ( th kh trong k thng). Hirat ha X c hn hp Y
gm 4 ancol (khng c ancol b c III). X gm
A. propen v but-1-en.
B. etilen v propen.
C. propen v but-2-en.
D. propen v 2-metylpropen.
Cu 63: Hirat ha 2 anken c hn hp Z gm 2 ancol lin tip trong dy ng ng. t chy
hon ton 0,53 gam Z ri hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,05M c
dung dch T trong nng ca NaOH l 0,025M (Gi s th tch dung dch thay i khng ng
k). Cng thc cu to ca2 anken l
A. CH2=CH2 v CH2=CHCH3.
B. CH2=CHCH3 v CH2=CHCH2CH3.
C. CH2=CHCH3 v CH3CH=CHCH3.
D. CH2=CHCH3 v CH2=C(CH3)2.
39
Cu 64: Mt chai ng ancol etylic c nhn ghi 25o c ngha l
A. c 100 ml nc th c 25 ml ancol nguyn cht.
B. c 100 gam dung dch th c 25 ml ancol nguyn cht.
C. c 100 gam dung dch th c 25 gam ancol nguyn cht.
D. c 75 ml nc th c 25 ml ancol nguyn cht.
Cu 65: Pha a gam ancol etylic (d = 0,8 g/ml) vo nc c 80 ml ancol 25o. Gi tr a l
A. 16.
B. 25,6.
C. 32.
D. 40.
Cu 66: Dy gm cc cht u tc dng vi ancol etylic l
A. HBr (to), Na, CuO (to), CH3COOH (xc tc).
B. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH.
C. NaOH, K, MgO, HCOOH (xc tc).
D. Na2CO3, CuO (to), CH3COOH (xc tc), (CHCO)2O.
Cu 67: Cho cc hp cht sau :
(a) HOCH2CH2OH.
(b) HOCH2CH2CH2OH.
(c) HOCH2CH(OH)CH2OH.
(d) CH3CH(OH)CH2OH.
(e) CH3CH2OH.
(f) CH3OCH2CH3.
Cc cht u tc dng c vi Na, Cu(OH)2 l
A. (a), (b), (c).
B. (c), (d), (f).
C. (a), (c), (d).
D. (c), (d), (e).
Cu 68: a. Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng) :
Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l
A. CH3COOH, CH3OH.
B. C2H4, CH3COOH.
C. C2H5OH, CH3COOH.
D. CH3COOH, C2H5OH.
b. Cho s chuyn ho : Glucoz X Y CH3COOH. Hai cht X, Y ln lt l
A. CH3CH2OH v CH=CH.
B. CH3CH2OH v CH3CHO.
C. CH3CHO v CH3CH2OH.
D. CH3CH(OH)COOH v CH3CHO.
Cu 69: Cho Na tc dng va vi 1,24 gam hn hp 3 ancol n chc X, Y, Z thy thot ra
0,336 lt kh H2 (kc). Khi lng mui natri ancolat thu c l
A. 2,4 gam.
B. 1,9 gam.
C. 2,85 gam.
D. 3,8 gam.
Cu 70: Cho 7,8 gam hn hp 2 ancol n chc k tip nhau trong dy ng ng tc dng ht vi
4,6 gam Na c 12,25 gam cht rn. l 2 ancol
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D. C3H7OH v C4H9OH.
Cu 71: 13,8 gam ancol A tc dng vi Na d gii phng 5,04 lt H 2 ktc, bit MA < 100. V y A
c cng thc cu to thu gn l
A. CH3OH.
B. C2H5OH.
C. C3H6(OH)2.
D. C3H5(OH)3.
Cu 72: C hai th nghi m
sau
:
TN 1: Cho 6 gam ancol no, mch h, n chc A tc dng vi m gam Na, thu c 0,075 gam H2.
TN 2: Cho 6 gam ancol no, mch h, n chc A tc dng vi 2m gam Na, thu c khng ti 0,1
gam H2. A c cng thc l
A. CH3OH.
B. C2H5OH.
C. C3H7OH.
D. C4H7OH.
Cu 73: Cho 12,8 gam dung dch ancol A (trong nc) c nng 71,875% tc dng vi lng Na
d thu c 5,6 lt kh (ktc). Cng thc ca ancol A l
A. CH3OH.
B. C2H4 (OH)2.
C. C3H5(OH)3.
D. C4H7OH.
Cu 74: Ancol A tc dng vi Na d cho s mol H 2 bng s mol A dng. t chy hon ton A
c mCO2 = 1,833mH2O. A c cu to thu gn l
A. C2H4(OH)2.
B. C3H6(OH)2.
C. C3H5(OH)3.
D. C4H8(OH)2.
Cu 75: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t
ti trng thi cn bng thu c 11 gam este. Hiu sut ca phn ng este ho l
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
Cu 76: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht
thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol
CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit )
A. 0,342.
B. 2,925.
C. 2,412.
D. 0,456.
40
Cu 77: Khi un nng butan-2-ol vi H2SO4 c 170oC th nhn c sn phm chnh l
A. but-2-en.
B. ibutyl ete.
C. ietyl ete.
D. but-1-en.
Cu 78: Khi un nng 2 trong s 4 ancol CH4O, C2H6O, C3H8O vi xc tc, nhit thch hp ch
thu c 1 olefin duy nht th 2 ancol l
A. CH4O v C2H6O. B. CH4O v C3H8O. C. A, B ng.
D. C3H8O v C2H6O.
Cu 79: Khi tch nc ca ancol C4H10O c hn hp 3 anken ng phn ca nhau (tnh c ng
phn hnh hc). Cng thc cu to thu gn ca ancol l
A. CH3CHOHCH2CH3.
B. (CH3)2CHCH2OH.
C. (CH3)3COH.
D. CH3CH2CH2CH2OH.
Cu 80: Hp cht hu c X c cng thc phn t l C5H12O, khi tch nc to hn hp 3 anken
ng phn (k c ng phn hnh hc). X c cu to thu gn l
A. CH3CH2CHOHCH2CH3.
B. (CH3)3CCH2OH.
C. (CH3)2CHCH2CH2OH.
D. CH3CH2CH2CHOHCH3.
Cu 81: Khi un nng hn hp ancol etylic v ancol isopropylic vi H2SO4 c 140oC c th thu
c s ete ti a l
A. 2.
B. 4.
C. 5.
D. 3.
Cu 82: Khi un nng hn hp gm C2H5OH v C3H7OH vi H2SO4 c 140oC c th thu c
s ete ti a l
A. 6.
B. 4.
C. 5.
D. 3.
Cu 83: un nng hn hp gm 3 ancol l AOH, BOH v ROH vi H2SO4 c 140oC th thu
c ti a bao nhiu ete ?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 84: un nng hn hp n ancol n chc khc nhau vi H2SO4 c 140oC th s ete thu c
ti a l
2
n(n 1)
2n(n 1)
A.
.
B.
.
C. n .
D. n!
2
2
2
A NaOH

Cu 85: Cho s chuyn ha : But-1-en HCl
B H SO , 170 C E
Tn ca E l
A. propen.
B. ibutyl ete.
C. but-2-en.
D. isobutilen.
Cu 86: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng
ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v
1,8 gam nc. Cng thc phn t ca hai ru trn l
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D. C3H7OH v C4H9OH.
Cu 87: un nng t t hn hp etanol v propan-2-ol vi H2SO4 c c th thu c ti a s sn
phm hu c l
A. 3.
B. 2.
C. 5.
D. 4.
Cu 88: C bao nhiu ng phn ng vi cng thc phn t C8H10O, u l dn xut ca benzen,
khi tch nc cho sn phm c th trng hp to polime ?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 89: A l ancol n chc c % O (theo khi lng) l 18,18%. A cho phn ng tch nc to 3
anken. A c tn l
A. Pentan-1-ol.
B. 2-metylbutan-2-ol.
C. pentan-2-ol.
D. 2,2-imetyl propan-1-ol.
Cu 90: hirat ha 14,8 gam ancol thu c 11,2 gam anken. CTPT ca ancol l
A. C2H5OH.
B. C3H7OH.
C. C4H9OH.
D. CnH2n + 1OH.
Cu 91: un nng hn hp X gm 2 ancol n chc lin tip trong dy ng ng vi H 2SO4 c
140oC. Sau phn ng c hn hp Y gm 5,4 gam nc v 19,4 gam 3 ete. Hai ancol ban u l
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH.
D. C3H7OH v C4H9OH.
Cu 92: un nng hn hp X gm 0,1 mol CH3OH v 0,2 mol C2H5OH vi H2SO4 c 140oC,
khi lng ete thu c l
2
4 c
41
A. 12,4 gam.
B. 7 gam.
C. 9,7 gam.
D. 15,1 gam.
Cu 93: un nng ancol n chc X vi H 2SO4 c 140oC thu c Y. T khi hi ca Y i vi
X l 1,4375. X l
A. CH3OH.
B. C2H5OH.
C. C3H7OH.
D. C4H9OH.
Cu 94: un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc
ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v
7,2 gam H2O. Hai ancol l
A. C2H5OH v CH2=CHCH2OH.
B. C2H5OH v CH3OH.
C. CH3OH v C3H7OH.
D. CH3OH v CH2=CHCH2OH.
Cu 95: Khi un nng mt ancol n chc no A vi H2SO4 c iu kin nhit thch hp thu
c sn phm B c t khi hi so vi A l 0,7. Vy cng thc ca A l
A. C4H7OH.
B. C3H7OH.
C. C3H5OH.
D. C2H5OH.
Cu 96: un nng mt ru (ancol) n chc X vi dung dch HSO4 c trong iu kin nhit
thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l
A. C3H8O.
B. C2H6O.
C. CH4O.
D. C4H8O.
Cu 97: Ch ra dy cc cht khi tch nc to 1 anken duy nht ?
A. Metanol ; etanol ; butan -1-ol.
B. Etanol; butan -1,2-iol ; 2-metylpropan-1-ol.
C. Propanol-1; 2-metylpropan-1-ol; 2,2 imetylpropan-1-ol.
D. Propan-2-ol ; butan -1-ol ; pentan -2-ol.
Cu 98: Ancol X tch nc ch to m t anken duy nht. t chy m t lng X c 11 gam CO2
v 5,4 gam H2O. X c th c bao nhiu cng thc cu to ph hp ?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 99: un nng hn hp X gm 2 ancol n chc no (c H 2SO4 c lm xc tc) 140oC. Sau
khi phn ng c hn hp Y gm 21,6 gam nc v 72 gam ba ete c s mol bng nhau. Cng
thc 2 ancol ni trn l
A. CH3OH v C2H5OH.
B. C2H5OH v C3H7OH.
C. C2H5OH v C3H7OH.
D.
C3H7OH v C4H9OH.
Cu 100: un nng V (ml) ancol etylic 95o vi H2SO4 c 170oC c 3,36 lt kh etilen (ktc).
Bit hiu sut phn ng l 60% v ancol etylic nguyn cht c d = 0,8 g/ml. Gi tr ca V (ml) l
A. 8,19.
B. 10,18.
C. 12.
D. 15,13.
Cu 101: Ancol no b oxi ha to xeton ?
A. propan-2-ol.
B. butan-1-ol.
C. 2-metyl propan-1-ol.
D. propan-1-ol.
Cu 102: Ancol no n chc tc dng c vi CuO to anehit l
A. ancol bc 2.
B. ancol bc 3.
C. ancol bc 1.
D. ancol bc 1 v ancol bc 2.
Cu 103: Oxi ha 6 gam ancol no X thu c 5,8 gam anehit. CTPT ca ancol l
A. CH3CH2OH.
B. CH3CH(OH)CH3. C. CH3CH2CH2OH.
D. Kt qu khc.
Cu 104: Cho m gam ancol n chc, no, mch h qua bnh ng CuO (d) nung nng. Sau khi
phn ng xy ra hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp thu c c t
khi hi i vi H2 l 19. Gi tr m l
A. 1,48 gam.
B. 1,2 gam.
C. 0,92 gam.
D. 0,64 gam.
Cu 105*: Oxi ha 4 gam ancol n chc A bng oxi khng kh (c xc tc v un nng) thu c
5,6 gam hn hp anehit, ancol d v nc. A c cng thc l
A. CH3OH.
B. C2H5OH.
C. C3H5OH.
D. C3H7OH.
Cu 106: Oxi ha 6 gam ancol n chc A bng oxi khng kh (c xc tc v un nng) thu c
8,4 gam hn hp anehit, ancol d v nc. Phn trm A b oxi ha l
A. 60%.
B. 75%.
C. 80%.
D. 53,33%.
Cu 107: Dn m gam hi ancol n chc A qua ng ng CuO (d) nung nng. Sau khi phn ng
hon ton thy khi lng cht rn trong ng gim 0,5m gam. Ancol A c tn l
A. metanol.
B. etanol.
C. propan-1-ol.
D. propan-2-ol.
42
Cu 108: Dn hi C2H5OH qua ng ng CuO nung nng c hn hp X gm anehit, ancol d
v nc. Cho X tc dng vi Na d c 4,48 lt H 2 ktc. Khi lng hn hp X l (bit ch c
80% ancol b oxi ha)
A. 13,8 gam
B. 27,6 gam.
C. 18,4 gam.
D. 23,52 gam.
Cu 109: Dn hi C2H5OH qua ng ng CuO nung nng c 11,76 gam hn hp X gm anehit,
ancol d v nc. Cho X tc dng vi Na d c 2,24 lt H2 ( ktc). % ancol b oxi ho l
A. 80%.
B. 75%.
C. 60%.
D. 50%.
n
n
Cu 110: t chy mt ancol X c H O
CO . Kt lun no sau y l ng nht?
A. X l ancol no, mch h.
B. X l ankaniol.
C. X l ankanol n chc.
D. X l ancol n chc mch h.
Cu 111: Khi t chy ng ng ca ancol n chc thy t l s mol n CO 2 : n H 2O tng dn.
Ancol trn thuc dy ng ng ca
A. ancol khng no.
B. ancol no.
C. ancol thm.
D. khng xc nh c.
Cu 112: t chy hon ton m gam ancol n chc A c 6,6 gam CO 2 v 3,6 gam H2O. Gi tr
m l
A. 10,2 gam.
B. 2 gam.
C. 2,8 gam.
D. 3 gam.
Cu 113: t chy mt ancol n chc, mch h X thu c CO2 v hi nc theo t l th tch
VCO : VH O 4 : 5 . CTPT ca X l
A. C4H10O.
B. C3H6O.
C. C5H12O.
D. C2H6O.
Cu 114: t chy mt ancol a chc thu c H2O v CO2 c t l mol n H 2 O : n CO 2 3 : 2 .
Vy ancol l
A. C3H8O2.
B. C2H6O2.
C. C4H10O2.
D. tt c u sai.
Cu 115: Khi t chy mt ancol a chc thu c nc v kh CO2 theo t l khi lng
m H O : m CO 27 : 44 . CTPT ca ancol l
A. C5H10O2.
B. C2H6O2.
C. C3H8O2.
D. C4H8O2.
Cu 116: t chy hon ton 5,8 gam ancol n chc X thu c 13,2 gam CO 2 v 5,4 gam H2O.
Xc nh X
A. C4H7OH.
B. C2H5OH.
C. C3H5OH.
D. tt c u sai.
Cu 117: Ba ancol X, Y, Z u bn v c khi lng phn t khc nhau. t chy mi cht u
sinh ra CO2 v H2O theo t l mol n CO 2 : n H 2O = 3 : 4. Vy CTPT ba ancol l
A. C2H6O ; C3H8O ; C4H10O.
B. C3H8O ; C3H8O2 ; C3H8O3.
C. C3H8O ; C4H10O ; C5H10O.
D. C3H6O ; C3H6O2 ; C3H6O3.
Cu 118: t chy ru A bng O2 va nh n thy: nCO2 : nO2 : nH2O = 4 : 5: 6. A c cng thc
phn t l
A. C2H6O.
B. C2H6O2.
C. C3H8O.
D. C4H10O.
Cu 119: t chy ancol ch cha mt loi nhm chc A bng O2 va nh n thy :
nCO2 : nO2 : nH2O = 6: 7: 8. A c c im l
A. Tc dng vi Na d cho nH2 = 1,5nA.
B. Tc dng vi CuO un nng cho ra hp cht a chc.
C. Tch nc to thnh m t anken duy nht.
D. Khng c kh nng ha tan Cu(OH)2.
Cu 120: Ancol n chc A chy cho mCO2 : mH2O = 11: 9. t chy hon ton 1 mol A ri hp
th ton b sn phm chy vo 600 ml dung dch Ba(OH)2 1M th lng kt ta l
A. 11,48 gam.
B. 59,1gam.
C. 39,4gam.
D. 19,7gam.
2
Cu 121: X l m t ancol no, mch h. t chy 0,05 mol X cn 4 gam oxi. X c cng thc l
A. C3H5(OH)3.
B. C3H6(OH)2.
C. C2H4(OH)2.
D. C4H8(OH)2.
Cu 122: t chy hon ton ancol X c CO2 v H2O c t l mol tng ng l 3: 4, th tch oxi
cn dng t chy X bng 1,5 ln th tch CO2 thu c (o cng k). X l
43
A. C3H8O.
B. C3H8O2.
C. C3H8O3.
D. C3H4O.
Cu 123: X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu
c hi nc v 6,6 gam CO2. Cng thc ca X l
A. C3H5(OH)3.
B. C3H6(OH)2.
C. C2H4(OH)2.
D. C3H7OH.
Cu 124*: X l hn hp 2 ancol n chc, cng dy ng ng, c t l khi lng 1:1. t chy
ht X c 21,45 gam CO2 v 13,95 gam H2O. V y X gm 2 ancol l
A. CH3OH v C2H5OH.
B. CH3OH v C4H9OH.
C. CH3OH v C3H7OH.
D. C2H5OH v C3H7OH.
Cu 125: t chy hon ton a gam ancol X ri hp th ton b sn phm chy vo bnh nc vi
ab
trong d thy khi lng bnh tng b gam v c c gam kt ta. Bit b = 0,71c v c = 1,02 . X c
cu to thu gn l
A. C2H5OH.
B. C2H4(OH)2.
C. C3H5(OH)3.
D. C3H6(OH)2.
Cu 126: t chy hon ton a gam hn hp gm metanol v butan-2-ol c 30,8 gam CO 2 v 18
gam H2O. Gi tr a l
A. 30,4 gam.
B. 16 gam.
C. 15,2 gam.
D. 7,6 gam.
Cu 127: t chy hon ton 0,4 mol hn hp X gm ancol metylic, ancol etylic v ancol
isopropylic ri hp th ton b sn phm chy vo nc vi trong d c 80 gam kt ta. Th tch
oxi (ktc) ti thiu cn dng l
A. 26,88 lt.
B. 23,52 lt.
C. 21,28 lt.
D. 16,8 lt.
Cu 128: t chy hn hp X gm 2 ancol c s mol bng nhau thu c hn hp CO2 v H2O
theo l mol tng ng 2 : 3. X gm
A. CH3OH v C2H5OH.
C. C2H5OH v C2H4(OH)2.
B. C3H7OH v C3H6(OH)2.
D. C2H5OH v C3H7OH.
Cu 129: t chy hon ton a mol ancol A c b mol CO2 v c mol H2O. Bit a = c - b. Kt lu n
no sau y ng ?
A. A l ancol no, mch vng.
B. A l ancol no, mch h.
C. A la 2ancol cha no.
C. A l ancol thm.
Cu 130: t chy m t lng ancol A cn va 26,88 lt O2 ktc, thu c 39,6 gam CO 2 v
21,6 gam H2O. A c cng thc phn t l
A. C2H6O.
B. C3H8O.
C. C3H8O2.
D. C4H10O.
Cu 131: Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy
hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l
A. C3H5(OH)3 v C4H7(OH)3.
B. C2H5OH v C4H9OH.
C. C2H4(OH)2 v C4H8(OH)2.
D. C2H4(OH)2 v C3H6(OH)2.
Cu 132: Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt
kh CO2( ktc) v a gam H2O. Biu thc lin h gia m, a v V l
A. m = 2a - V/22,4.
B. m = 2a - V/11,2.
C. m = a + V/5,6.
D. m = a - V/5,6.
Cu 133: t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O 2 (
ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH) 2 th to thnh dung dch c
mu xanh lam. Gi tr ca m v tn gi ca X tng ng l
A. 9,8 v propan-1,2-iol.
B. 4,9 v propan-1,2-iol.
C. 4,9 v propan-1,3-iol.
D. 4,9 v glixerol.
Cu 134: a. Kh CO2 sinh ra khi ln men ru mt lng glucoz c dn vo dung dch Ca(OH) 2
d to c 40g kt ta. Khi lng ancol etylic thu c l
A. 18,4 gam.
B. 16,8 gam.
C. 16,4 gam.
D. 17,4 gam.
b. Nu hiu sut phn ng ln men l 80% th khi lng glucoz dng l bao nhiu gam ?
A. 45 gam.
B. 90 gam.
C. 36 gam.
D. 40 gam.
Cu 135: Cho m gam tinh b t ln men thnh C2H5OH vi hi u sut 81%, hp th ht lng CO2
sinh ra vo dung dch Ca(OH)2 c 55 gam kt ta v dung dch X. un nng dung dch X li c
10 gam kt ta na. Gi tr m l
A. 75 gam.
B. 125 gam.
C. 150 gam.
D. 225 gam.
44
Cu 136: Th tch ancol etylic 92o cn dng l bao nhiu iu ch c 2,24 lt C2H4 (ktc). Cho
bit hi u sut phn ng t 62,5% v d = 0,8 g/ml.
A. 8 ml.
B. 10 ml.
C. 12,5ml.
D. 3,9 ml.
Cu 137: i t 150 gam tinh b t s iu ch c bao nhiu ml ancol etylic 46o bng phng php
ln men ancol? Cho bit hi u sut phn ng t 81% v d = 0,8 g/ml.
A. 46,875 ml.
B. 93,75 ml.
C. 21,5625 ml.
D. 187,5 ml.
Cu 138: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol)
etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht
l 0,8 g/ml)
A. 5,4 kg.
B. 5,0 kg.
C. 6,0 kg.
D. 4,5 kg.
Cu 139: Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu
trnh ny c hp th ht vo dung dch Ca(OH) 2 d to ra 40 gam kt ta. Nu hiu sut ca qu
trnh ln men l 75% th gi tr ca m l
A. 60.
B. 58.
C. 30.
D. 48.
Cu 140: Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dung
dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so
vi khi lng dung dch nc vi trong ban u. Gi tr ca m l
A. 20,0.
B. 30,0.
C. 13,5.
D. 15,0.
Cu 141: X l hn hp gm phenol v ancol n chc A. Cho 25,4 gam X tc dng vi Na (d)
c 6,72 lt H2 ( ktc). A l
A. CH3OH.
B. C2H5OH.
C. C3H5OH.
D. C4H9OH.
Cu 142: C bao nhiu hp cht hu c C7H8O va tc dng vi Na, va tc dng vi NaOH ?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 143: A l hp cht c cng thc phn t C 7H8O2. A tc dng vi Na d cho s mol H 2 bay ra
bng s mol NaOH cn dng trung ha cng lng A trn. Ch ra cng thc cu to thu gn ca
A.
A. C6H7COOH.
B. HOC6H4CH2OH. C. CH3OC6H4OH.
D. CH3C6H3(OH)2.
Cu 144: Khi t chy 0,05 mol X (dn xut benzen) thu c di 17,6 gam CO 2. Bit 1 mol X
phn ng va vi 1 mol NaOH ho c vi 2 mol Na. X c cng thc cu to thu gn l
A. CH3C6H4OH.
B. CH3OC6H4OH.
C. HOC6H4CH2OH. D.C6H4(OH)2.
Cu 145: Ha cht no di y dng phn bi t 2 l mt nhn cha dung dch phenol v
benzen.
1. Na.
2. dd NaOH.
3. nc brom.
A. 1 v 2.
B. 1 v 3.
C. 2 v 3.
D. 1, 2 v 3.
Cu 146: A l hp cht hu c cng thc phn t l C 7H8O2. A tc dng vi NaOH theo t l 1 : 2.
V y A thu c loi hp cht no di y ?
A. i phenol.
B. Axit cacboxylic
C. Este ca phenol.
D. Va ancol, va phenol.
Cu 147: C bao nhiu ng phn (cha vng bezen), cng thc phn t C 8H10O, khng tc dng
vi Na?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 148: A l cht hu c c cng thc phn t C xHyO. t chy hon ton 0,1 mol A ri hp th
ton b sn phm chy vo nc vi trong thy c 30 gam kt ta. Lc b kt ta em un nng
phn nc lc thy c 20 gam kt ta na. Bit A va tc dng Na, va tc dng NaOH. Ch ra
cng thc phn t ca A.
A. C6H6O.
B. C7H8O.
C. C7H8O2.
D. C8H10O.
Cu 149: Ch ra th t tng dn mc linh ca nguyn t H trong nhm -OH ca cc hp
cht sau: phenol, etanol, nc.
A. Etanol < nc < phenol.
C. Nc < phenol < etanol.
B. Etanol < phenol < nc.
D. Phenol < nc < etanol.
45
Cu 150: T 400 gam bezen c th iu ch c ti a bao nhiu gam phenol. Cho bit hi u sut
ton b qu trnh t 78%.
A. 376 gam.
B. 312 gam.
C. 618 gam.
D. 320 gam.
Cu 151: Ha cht no di y c th dng phn bi t cc l mt nhn cha cc dung dch :
C6H5ONa, NaCl, BaCl2, Na2S, Na2CO3 l
A. dd NaOH.
B. dd HCl.
C. Na.
D dd KCl.
Cu 152: So vi etanol, nguyn t H trong nhm -OH ca phenol linh ng hn v :
A. M t electron vng benzen tng ln, nht l cc v tr o v p.
B. Lin kt C-O ca phenol bn vng.
C. Trong phenol, c p electron cha tham gia lin kt ca nguyn t oxi tham gia lin hp
vo vng benzen lm lin kt -OH phn cc hn.
D. Phenol tc dng d dng vi nc brom to kt ta trng 2, 4, 6-tri brom phenol.
Cu 153: C bao nhiu phn ng xy ra khi cho cc cht C 6H5OH ; NaHCO3 ; NaOH ; HCl tc
dng vi nhau tng i m t ?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 154: Dy gm cc cht u phn ng vi phenol l
A. dung dch NaCl, dung dch NaOH, kim loi Na.
B. nc brom, axit axetic, dung dch NaOH.
C. nc brom, anhirit axetic, dung dch NaOH.
D. nc brom, anehit axetic, dung dch NaOH.
Cu 155: Hi n tng ln lt xy ra khi nh vi git dung dch HCl c vo ng nghi m cha
m t t dung dch HCOONa v m t t dung dch C6H5ONa ri lc mnh l
A. C s phn lp ; dung dch trong sut ha c.
B. Dung dch trong sut ha c.
C. C phn lp ; dung dch trong sut.
D. Xut hi n s phn lp c 2 ng nghi m.
Cu 156: nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng
gia phenol vi
A. dung dch NaOH. B. Na kim loi.
C. nc Br2.
D. H2 (Ni, nung nng).
Cu 157: Cht c cng thc phn t no di y c th tc dng c c Na, c NaOH ?
A. C5H8O.
B. C6H8O.
C. C7H10O.
D. C9H12O.
Cu 158: Ba hp cht thm X, Y, Z u c cng thc phn t C7H8O. X tc dng vi Na v NaOH ;
Y tc dng vi Na, khng tc dng NaOH ; Z khng tc dng vi Na v NaOH Cng thc cu to
ca X, Y, Z ln lt l
A. C6H4(CH3)OH ; C6H5OCH3 ; C6H5CH2OH.
B. C6H5OCH3 ; C6H5CH2OH ; C6H4(CH3)OH.
C. C6H5CH2OH ; C6H5OCH3 ; C6H4(CH3)OH.
D. C6H4(CH3)OH ; C6H5CH2OH ; C6H5OCH3.
Cu 159: Cho ln lt cc cht C2H5Cl, C2H5OH, C6H5OH, C6H5Cl vo dung dch NaOH long un
nng. Hi my cht c phn ng ?
A. C bn cht.
B. Mt cht.
C. Hai cht.
D. Ba cht.
Cu 160: a. S ng phn ca C3H5Cl3 l
A. 5.
B. 6.
C. 3.
D. 4.
b. Trong s cc ng phn ca C3H5Cl3 c th c bao nhiu ng phn khi thu phn trong mi
trng kim cho sn phm phn ng c c vi Na v dung dch AgNO3/NH3 to ra Ag ?
A. 1.
B. 4.
C. 3.
D. 2.
Cu 161: Hp cht X c cha vng benzen v c CTPT l C7H6Cl2. Thy phn X trong NaOH c,
to cao, p cao thu c cht Y c CTPT l C7H6O. Hy cho bit X c bao nhiu CTCT?
A. 3.
B. 1.
C. 4.
D. 2.
Cu 162: Cho cc hp cht sau : (I) CH3CH2OH.
(II) C6H5OH.
(III) NO2C6H4OH.
46
Chn pht biu sai
A. C 3 cht u c nguyn t H linh ng.
B. C 3 u phn ng c vi dung dch baz iu kin thng.
C. Cht (III) c nguyn t H linh ng nht.
D. Th t linh ng ca nguyn t H c sp xp theo chiu nh sau : III > II > I.
Cu 163: Cho cc cht sau A : CH4O ; B: C2H6O2 ; C: C3H8O3.
iu no sau y lun ng ?
A. A, B, C l cc ancol no, mch h.
B. A, B, C u lm mt mu dd thuc tm.
C. A, B, C l cc hp cht hu c no.
D. A, B, C u l este no, n chc.
Cu 164: Cho 2 phn ng :(1) 2CH3COOH + Na2CO3
2CH3COONa + H2O + CO2
(2) C6H5ONa + CO2 + H2O
C6H5OH + NaHCO3
Hai phn ng trn chng t lc axit theo th t CH3COOH, H2CO3, C6H5OH, HCO3- l
A. Tng dn.
B. Gim dn.
C. Khng thay i.
D. Va tng va gim.
Cu 165: Cho dy cc cht : phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht
trong dy phn ng c vi NaOH (trong dung dch) l
A. 4.
B. 3.
C. 1.
D. 2.
Cu 166: X l hn hp gm phenol v metanol. t chy hon ton X c nCO 2 = nH2O. V y %
khi lng metanol trong X l
A. 25%.
B. 59,5%.
C. 50,5%.
D. 20%.
Cu 167: Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4.
Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc
loi hp cht thm ng vi cng thc phn t ca X l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 168: Cho X l hp cht thm ; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt
khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc).
Cng thc cu to thu gn ca X l
A. HOC6H4COOCH3. B. CH3C6H3(OH)2.
C. HOC6H4COOH.
D. HOCH2C6H4OH.
Cu 169: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng
c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol
X tham gia phn ng v X tc dng c vi NaOH theo t l s mol 1 : 2. Cng thc cu to thu gn
ca X l
A. C6H5CH(OH)2.
B. CH3C6H3(OH)2.
C. CH3OC6H4OH.
D. C. HOCH2C6H4OH.
Cu 170: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc)
thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau
hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng
ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Th tch dung dch thay i
khng ng k)
A. C4H9OH v C5H11OH.
B. C3H7OH v C4H9OH.
C. C2H5OH v C3H7OH.
D. C2H5OH v C4H9OH.
Cu 171: t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca
nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na
(d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l
A. C3H6O, C4H8O.
B. C2H6O, C3H8O.
C. C2H6O2, C3H8O2.
D. C2H6O, CH4O.
Cu 172: Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol
d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi
lng etanol b oxi ho to ra axit l
A. 1,15 gam.
B. 4,60 gam.
C. 2,30 gam.
D. 5,75 gam.
Cu 173: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu : Tng khi
lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng
thc phn t ca X l
A. 3.
B. 4.
C. 2.
D. 1.
47
Cu 174: Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht
l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l
B. CH3COCH3.
D. CH3CH2CHOHCH3.
A. CH3CHOHCH3.
C. CH3CH2CH2OH.
Cu 175: Mt hp cht hu c A gm C, H, O c 50% oxi v khi lng. Ngi ta cho A qua ng
ng 10,4 gam CuO nung nng thu c 2 cht hu c v 8,48 gam cht rn. Mt khc cho hn
hp 2 cht hu c trn tc dng vi dung dch AgNO3(d) trong NH3 to ra hn hp 2 mui v
38,88 gam Ag. Khi lng ca A cn dng l
A. 1,28 gam.
B. 4,8 gam.
C. 2,56 gam.
D. 3,2 gam.
Cu 176: un nng ancol A vi hn hp NaBr v H 2SO4 c thu c cht hu c B, 12,3 gam hi
cht B chim mt th tch bng th tch ca 2,8 gam N 2 cng nhit 560oC ; p sut 1 atm. Oxi
ho A bng CuO nung nng thu c hp cht hu c c kh nng lm mt mu dung dch nc
brom. CTCT ca A l
A. CH3OH.
B. C2H5OH.
C. CH3CHOHCH3.
D. CH3CH2CH2OH.
Cu 177: un mt ancol A vi dung dch hn hp gm KBr v H2SO4 c th trong hn hp sn
phm thu c c cht hu c B. Hi ca 12,5 gam cht B ni trn chim 1 th tch ca 2,80 gam
nit trong cng iu kin. Cng thc cu to ca A l
A. C2H5OH.
B. CH3CH2CH2OH.
C. CH3OH.
D. HOCH2CH2OH.
Cu 178: Anken X c cng thc phn t l C5H10. X khng c ng phn hnh hc. Khi cho X tc
dng vi KMnO4 nhit thp thu c cht hu c Y c cng thc phn t l C5H12O2. Oxi ha
nh Y bng CuO d thu c cht hu c Z. Z khng c phn ng trng gng. Vy X l
A. 2-metyl buten-2.
B. But-1-en.
C. 2-metyl but-1-en. D. But-2-en.
Cu 179: t chy hon ton 1 th tch hi ancol no n chc A thu c CO 2 v H2O c tng th
tch gp 5 ln th tch hi ancol A dng ( cng iu kin). Vy A l
A. C2H5OH.
B. C4H9OH.
C. CH3OH.
D. C3H7OH.
Cu 180: Cho 30,4 gam hn hp gm glixerol v mt ru n chc, no A phn ng vi Na th thu
c 8,96 lt kh (ktc). Nu cho hn hp trn tc dng vi Cu(OH)2 th ho tan c 9,8 gam
Cu(OH)2. Cng thc ca A l
A. C2H5OH.
B. C3H7OH.
C. CH3OH.
D. C4H9OH.
Cu 181: Hn hp X gm ancol metylic v mt ancol no, n chc A, mch h. Cho 2,76 gam X
tc dng vi Na d thu c 0,672 lt H 2 (ktc), mt khc oxi ha hon ton 2,76 gam X bng CuO
(to) thu c hn hp anehit. Cho ton b lng anehit ny tc dng vi dung dch AgNO 3/NH3
d thu c 19,44 gam cht kt ta. Cng thc cu to ca A l
A. C2H5OH.
B. CH3CH2CH2OH.
C. CH3CH(CH3)OH.
D. CH3CH2CH2CH2OH.
Cu 182: Ancol no mch h A cha n nguyn t C v m nhm OH trong cu to phn t. Cho 7,6
gam A tc dng ht vi Na cho 2,24 lt H2 (ktc). Mi quan h gia n v m l
A. 2m = 2n + 1.
B. m = 2n + 2.
C. 11m = 7n + 1.
D. 7n = 14m + 2.
Cu 183: Cht hu c X mch h c to ra t axit no A v etylen glicol. Bit rng a gam X th
hi chim th tch bng th tch ca 6,4 gam oxi cng iu kin nhit v p sut; a gam X
phn ng ht vi xt to ra 32,8 gam mui. Nu cho 200 gam A phn ng vi 50 gam etilenglicol
ta thu c 87,6 gam este. Tn ca X v hiu sut phn ng to X l
A. Etylen glicol iaxetat ; 74,4%.
B. Etylen glicol ifomat ; 74,4%.
C. Etylen glicol iaxetat ; 36,3%.
D. Etylen glicol ifomat ; 36,6%.
Cu 184: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s
khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1 cho tc dng vi Na d, thu
c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120 ml. Hiu sut
phn ng oxi ho ancol etylic l:
A. 42,86%.
B. 66,7%.
C. 85,7%.
D. 75%.
Cu 185: t chy hon ton mt lng hn hp 2 ancol no n chc X, Y l ng ng lin tip
thu c 11,2 lt CO2 cng vi lng hn hp trn cho phn ng vi Na d th thu c 2,24 lt H 2
( ktc). Cng thc phn t ca 2 ancol trn l
A. C2H5OH; C3H7OH.
B. CH3OH; C3H7OH.
48
C. C4H9OH; C3H7OH.
D. C2H5OH ; CH3OH.
Cu 186*: Oxi ho 9,2 gam ancol etylic bng CuO un nng thu c 13,2 gam hn hp gm
anehit, axit, ancol d v nc. Hn hp ny tc dng vi Na sinh ra 3,36 lt H 2 ( ktc). Phn trm
ancol b oxi ho l
A. 25%.
B. 50%.
C. 75%.
D. 90%.
Cu 187: Thc hin cc th nghim sau:
TN 1 : Trn 0,015 mol ru no X vi 0,02 mol ru no Y ri cho tc dng ht vi Na th thu c
1,008 lt H2.
TN 2 : Trn 0,02 mol ru X vi 0,015 mol ru Y ri cho hp tc dng ht vi Na th thu c
0,952 lt H2.
Th nghim 3 : t chy hon ton mt lng hn hp ru nh trong th nghim 1 ri cho tt c
sn phm chy i qua bnh ng CaO mi nung, d thy khi lng bnh tng thm 6,21 gam. Bit
th tch cc khi o ktc. Cng thc 2 ru l
A. C2H4(OH)2 v C3H6(OH)2.
B. C2H4(OH)2 v C3H5(OH)3.
C. CH3OH v C2H5OH.
D. Khng xc nh c.
CHUYN 6: ANEHIT-XETON-AXIT CACBOXYLIC

49
Cu 1: Mt anehit c cng thc tng qut l CnH2n + 2 2a m (CHO)m. Cc gi tr n, a, m ln lt
c xc nh l
A. n > 0, a 0, m 1.
B. n 0, a 0, m 1.
C. n > 0, a > 0, m > 1.
D. n 0, a > 0, m 1.
Cu 2: C bao nhiu ng phn cu to C5H10O c kh nng tham gia phn ng trng gng ?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 3: C bao nhiu xeton c cng thc phn t l C5H10O ?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 4: C bao nhiu ng phn cu to C6H12O tham gia phn ng trng gng ?
A. 6.
B. 7.
C. 8.
D. 9.
Cu 5: C bao nhiu ancol C5H12O khi tc dng vi CuO un nng cho ra anehit ?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 6: CTGN ca 1 anehit no, a chc, mch h l C2H3O. CTPT ca n l
A. C8H12O4.
B. C4H6O.
C. C12H18O6.
D. C4H6O2.
Cu 7: CTGN ca anehit no, a chc, mch h l C2H3O. Anehit c s ng phn l
A. 2.
B. 4.
C. 1.
D. 3.
Cu 8: (CH3)2CHCHO c tn l
A. isobutyranehit.
B. anehit isobutyric.
C. 2-metyl propanal.
D. A, B, C u ng.
Cu 9: CTPT ca ankanal c 10,345% H theo khi lng l
A. HCHO.
B. CH3CHO.
C. C2H5CHO.
D. C3H7CHO.
Cu 10: Anehit A (ch cha mt loi nhm chc) c %C v %H (theo khi lng) ln lt l
55,81 v 6,97. Ch ra pht biu sai
A. A l anehit hai chc.
B. A cn c ng phn l cc axit cacboxylic.
C. A l anehit no.
D. Trong phn ng trng gng, m t phn t A ch cho 2 electron.
Cu 11: Trong cng iu ki n nhi t v p sut, 1 lt hi anehit A c khi lng bng khi
lng 1 lt CO2. A l
A. anehit fomic.
B. anehit axetic.
C. anehit acrylic.
D. anehit benzoic.
Cu 12: t chy hon ton p mol anehit X c q mol CO 2 v t mol H2O. Bit p = q - t. M t
khc 1 mol X trng gng c 4 mol Ag. X thu c dy ng ng anehit
A. n chc, no, mch h.
C. hai chc cha no (1 ni i C=C).
B. hai chc, no, mch h.
D. nh chc cha no (1 ni ba CC).
Cu 13: Anehit a chc A chy hon ton cho mol CO2 - mol H2O = mol A. A l
A. anehit no, mch h.
B. anehit cha no.
C. anehit thm.
D. anehit no,
mch vng.
Cu 14: t chy anehit A c mol CO2 = mol H2O. A l
A. anehit no, mch h, n chc.
B. anehit n chc, no, mch vng.
C. anehit n chc c 1 ni i, mch h.
D. anehit no 2 chc, mch h.
Cu 15: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon
ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit
, p sut). Ngng t Y thu c cht Z ; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol
Z phn ng. Cht X l anehit
A. no, hai chc.
B. khng no (cha mt ni i C=C), hai chc.
C. no, n chc.
D. khng no (cha mt ni i C=C), n chc.
Cu 16: Cho cc cht : HCN, H2, dung dch KMnO4, dung dch Br2/H2O, dung dch Br2/CH3COOH
a. S cht phn ng c vi (CH3)2CO iu kin thch hp l
A. 2.
B. 3.
C. 4.
D. 5.
50
b. S cht phn ng c vi CH3CH2CHO iu kin thch hp l
A. 4.
B. 2.
C. 3.
D. 5.
Cu 17: CH3CHO c th to thnh trc tip t
A. CH3COOCH=CH2. B. C2H2.
C. C2H5OH.
D. Tt c u ng.
Cu 18: Qu trnh no sau y khng to ra anehit axetic ?
A. CH2=CH2+ H2O (to, xc tc HgSO4).
B. CH2=CH2 + O2 (to, xc tc).
o
C. CH3COOCH=CH2 + dung dch NaOH (t ). D. CH3CH2OH + CuO (t0).
Cu 19: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l
A. C2H5OH, C2H2, CH3COOC2H5.
B. HCOOC2H3, C2H2, CH3COOH.
C. C2H5OH, C2H4, C2H2.
D. CH3COOH, C2H2, C2H4.
Cu 20: Mt axit cacboxylic c cng thc tng qut l C nH2n + 2 2a m (COOH)m. Cc gi tr n, a, m
ln lt c xc nh l
A. n > 0, a 0, m 1.
B. n 0, a 0, m 1.
C. n > 0, a > 0, m > 1.
D. n 0, a > 0, m 1.
Cu 21: A l axit no h, cng thc CxHyOz. Ch ra mi lin h ng
A. y = 2x-z +2.
B. y = 2x + z-2.
C. y = 2x.
D. y = 2x-z.
Cu 22: A l axit cacboxylic mch h, cha no (1 ni i C=C), cng thc C xHyOz. Ch ra mi lin
h ng
A. y = 2x.
B. y = 2x + 2-z.
C. y = 2x-z.
D. y = 2x + z-2.
Cu 23: Axit khng no, n chc c mt lin kt i trong gc hirocacbon c cng thc ph hp
l
A. CnH2n+1-2kCOOH ( n 2).
B. RCOOH.
C. CnH2n-1COOH ( n 2).
D. CnH2n+1COOH ( n 1).
Cu 24: Axit cacboxylic A c cng thc n gin nht l C3H4O3. A c cng thc phn t l
A. C3H4O3.
B. C6H8O6.
C. C18H24O18.
D. C12H16O12.
Cu 25: CTGN ca mt axit hu c X l CHO. t chy 1 mol X thu c di 6 mol CO 2.
CTCT ca X l
A. CH3COOH.
B. CH2=CHCOOH.
C. HOOCCH=CHCOOH.
D. Kt qu khc.
Cu 26: Mt axit no A c CTGN l C2H3O2. CTPT ca axit A l
A. C6H9O6.
B. C2H3O2.
C. C4H6O4.
D. C8H12O8.
Cu 27: C4H6O2 c s ng phn mch h thuc chc axit l
A. 4.
B. 3.
C. 5.
D. tt c u sai.
Cu 28: Axit cacboxylic n chc mch h phn nhnh (A) c % O (theo khi lng) l 37,2. Ch
ra pht biu sai
A. A lm mt mu dung dch brom.
B. A l nguyn li u iu ch thy tinh hu c.
C. A c ng phn hnh hc.
D. A c hai lin trong phn t.
Cu 29: Axit hu c A c thnh phn nguyn t gm 40,68% C ; 54,24% O. trung ha 0,05 mol
A cn 100ml dung dch NaOH 1M. CTCT ca A l
A. HOOCCH2CH2COOH.
B. HOOCCH(CH3)CH2COOH.
C. HOOCCH2COOH.
D. HOOCCOOH.
Cu 30: Hp cht CH3CH2(CH3)CH2CH2CH(C2H5)COOH c tn quc t l
A. axit 2-etyl-5-metyl hexanoic.
B. axit 2-etyl-5-metyl nonanoic.
C. axit 5-etyl-2-metyl hexanoic.
D. tn gi khc.
Cu 31: Gim n l dung dch axit axetic c nng l
A. 2% 5%.
B. 59%.
C. 912%.
D. 1215%.
Cu 32: Axit axetic tc dng c vi dung dch no ?
A. natri etylat.
B. amoni cacbonat.
C. natri phenolat.
D. C A, B, C.
51
Cu 33: Trong dy ng ng ca cc axit n chc no, HCOOH l axit c mnh trung bnh,
cn li l axit yu (in li khng hon ton). Dung dch axit axetic c nng 0,001 mol/l c pH l
A. 3 < pH < 7.
B. < 3.
C. 3.
D. 10-3
Cu 34: in li ca 3 dung dch CH3COOH 0,1M ; CH3COOH 0,01M v HCl c sp xp
theo th t tng dn l
A. CH3COOH 0,01M < HCl < CH3COOH 0,1M.
B. CH3COOH 0,01M < CH3COOH 0,1M < HCl.
C. HCl < CH3COOH 0,1M < CH3COOH 0,01M.
D. CH3COOH 0,1M < CH3COOH 0,01M < HCl.
Cu 35: Th t sp xp theo s tng dn tnh axit ca CH3COOH ; C2H5OH ; CO2 v C6H5OH l
A. C6H5OH < CO2 < CH3COOH < C2H5OH.
B. CH3COOH < C6H5OH < CO2 < C2H5OH.
C. C2H5OH < C6H5OH < CO2 < CH3COOH.
D. C2H5OH < CH3COOH < C6H5OH < CO2.
Cu 36: Cho 3 axit ClCH2COOH , BrCH2COOH, ICH2COOH, dy sp xp theo th t tng dn
tnh axit l
A. ClCH2COOH < ICH2COOH < BrCH2COOH.
B. ClCH2COOH < BrCH2COOH < ICH2COOH.
C. ICH2COOH < BrCH2COOH < ClCH2COOH.
D. BrCH2COOH < ClCH2COOH < ICH2COOH.
Cu 37: Gi tr pH ca cc axit CH3COOH, HCl, H2SO4 c sp xp theo th t tng dn l
A. H2SO4, CH3COOH, HCl.
B. CH3COOH, HCl , H2SO4.
C. H2SO4, HCl, CH3COOH.
D. HCl, CH3COOH, H2SO4.
Cu 38: Trong cc phn ng este ha gia ancol v axit hu c th cn bng s chuyn dch theo
chiu thun khi ta
A. dng cht ho nc tch nc.
B. chng ct ngay tch este ra.
C. cho ancol d hoc axit d.
D. tt c u ng.
Cu 39: t chy hon ton hn hp X gm 2 axit cacboxylic c mol CO2 = mol H2O. X gm
A. 1 axit n chc, 1 axit a chc.
B. 1 axit no, 1 axit cha no.
C. 2 axit n chc no mch vng
D. 2 axit no, mch h n chc.
Cu 40: trung ha 0,2 mol hn hp X gm 2 axit cacboxylic cn 0,3 mol NaOH. X gm c
A. 2 axit cng dy ng ng.
B. 1 axit n chc, 1 axit hai chc.
C. 2 axit a chc.
D. 1 axit n chc, 1 axit a chc.
Cu 41: t chy hon ton axit cacboxylic A bng lng va oxi c hn hp (kh v hi) c
t khi so vi H2 l 15,5. A l axit
A. n chc no, mch h
B. n chc c 1 ni i (C = C), mch h.
C. a chc no, mch h.
D. axit no,mch h, hai chc,
Cu 42: t chy ht 1 th tch hi axit A thu c 2 th tch CO2 o cng iu kin, A l
A. HCOOH.
B. HOOCCOOH.
C. CH3COOH.
D. B v C ng.
Cu 43: C th iu ch CH3COOH t
A. CH3CHO.
B. C2H5OH.
C. CH3CCl3.
D. Tt c u ng.
Cu 44: Cho cc cht : CaC2 (I), CH3CHO (II), CH3COOH (III), C2H2 (IV). S chuyn ha ng
iu ch axit axetic l
A. I IV II III.
B. IV I II III.
C. I
II
IV
III.
D. II I IV III.
Cu 45: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. CH3CHO, C6H12O6 (glucoz), CH3OH.
C. CH3OH, C2H5OH, CH3CHO.
D. C2H4(OH)2, CH3OH, CH3CHO.
Cu 46: Cho s chuyn ha : CH3CH2Cl + KCN X (1); X + H3O+ (un nng) Y(2)
Cng thc cu to ca X, Y ln lt l
52
A. CH3CH2NH2, CH3CH2COOH.
B. CH3CH2CN, CH3CH2CHO.
C. CH3CH2CN, CH3CH2COOH.
D. CH3CH2CN, CH3CH2COONH4.
Cu 47: Cht c nhit si cao nht l
A. CH3CHO.
B. C2H5OH.
C. CH3COOH.
D. C2H6.
Cu 48: Nhit si ca mi cht tng ng trong dy cc cht sau y, dy no hp l nht ?
C2H5OH HCOOH CH3COOH
A. 118,2oC 78,3oC
100,5oC
B. 118,2oC 100,5oC
78,3oC
o
o
C. 100,5 C 78,3 C
118,2oC
D. 78,3oC 100,5oC
118,2oC
Cu 49: Ch ra th t tng dn nhi t si ca cc cht ?
A. CH3CHO; C2H5OH ; CH3COOH.
C. C2H5OH ; CH3COOH ; CH3CHO.
B. CH3CHO ;CH3COOH ; C2H5OH.
D. CH3COOH ; C2H5OH ; CH3CHO.
Cu 50: Nhit si ca cc cht c sp xp theo th t tng dn l
A. CH3OH < CH3CH2COOH < NH3 < HCl.
B. C2H5Cl < CH3COOH < C2H5OH.
C. C2H5Cl < CH3COOCH3 < C2H5OH < CH3COOH.
D. HCOOH < CH3OH < CH3COOH < C2H5F.
Cu 51: Cho cc cht CH3CH2COOH (X) ; CH3COOH ( Y) ; C2H5OH ( Z) ; CH3OCH3 (T). Dy
gm cc cht c sp xp tng dn theo nhi t si l
A. T, X, Y, Z.
B. T, Z, Y, X.
C. Z, T, Y, X.
D. Y, T, Z, X.
Cu 52: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV)
sp xp theo th t gim dn l
A. IV > I > III > II.
B. IV > III > I > II.
C. II > III > I > IV.
D. I > II > III > IV.
Cu 53: A l ancol n chc no h, B l axit cacboxylic no h n chc. Bit M A=MB. Pht biu
ng l
A. A, B l ng phn
B. A, B c cng s cacbon trong phn t.
C. A hn B m t nguyn t cacbon.
D. B hn A m t nguyn t cacbon.
Cu 54: Hai hp cht hu c X v Y c cng CTPT C 3H4O2. X tc dng vi CaCO3 to ra CO2. Y
tc dng vi dung dch AgNO3/NH3 to Ag. CTCT thu gn ph hp ca X, Y ln lt l
A. HCOOCH=CH2, CH3COOCH3.
B. CH3CH2COOH, HCOOCH2CH3.
C. HCOOCH=CH2, CH3 CH2COOH.
D. CH2=CHCOOH, HOCCH2CHO.
Cu 55: Cho chui phn ng : C2H6O X axit axetic CH OH Y.
CTCT ca X, Y ln lt l
A. CH3CHO, CH3CH2COOH.
B. CH3CHO, CH3COOCH3.
C. CH3CHO, CH2(OH)CH2CHO.
D. CH3CHO, HCOOCH2CH3.
Cu 56: Cho s phn ng sau :
butin-1,4-iol H , xt Y - H O Z
CH CH 2HCHO
Y v Z ln lt l
A. HOCH2CH2CH2CH3 ; CH2=CHCH=CH2.
B. HOCH2CH2CH2CH2OH ; CH2=CHCH2CH3.
C. HOCH2CH2CH2CH2OH ; CH2=CHCH = CH2.
D. HOCH2CH2CH2CH2OH ; CH3CH2CH2CH3.
Cu 57: Cho s chuyn ha sau:
C CuO
D O , Mn
Hirocacbon A Br , as B NaOH
HOOCCH2COOH. Vy A l
3
A.
B. C3H8.
C. CH2=CHCH3.
D. CH2=CHCOOH.
Cu 58: Cho chui phn ng sau
O , Cu
C3H6 H , Ni B1 Cl , as B2 (spc) OH
/H O B3 B4 . Vy B4 l
A. CH3COCH3.
B. A v C ng.
C. CH3CH2CHO.
D. CH3CHOHCH3.
2
53
Cu 59: Xt cc chui bin ha sau:
a. A H , Ni B - H2O, - H 2 , xt
C
cao su Buna.
CTCT ca A l
A. OHCCH2CH2CHO. B. CH3CHO.
C. OHC(CH2)2CH2OH. D. A, B, C u ng.
b. A H , Ni B
C
cao su Buna.
CTCT ca A l
A. OHCCH2CH2CHO.
B. CH3CHO.
C. HOC(CH2)2CH2OH.
D. A, B, C u ng.
Cu 60: Cho s chuyn ha sau :
O , Cu
C2H6 Br , as A OH
/H O B C O , Mn
D. Vy D l
A. CH3CH2OH.
B. CH3CHO.
C. CH3COCH3.
D. CH3COOH.
Cu 61: Cho s chuyn ha sau
A2 CuO
A3 Cu(OH)
C2H4
A1 NaOH
, NaOH
A4 H SO A5.
Br2
Chn cu tr li sai
A. A5 c CTCT l HOOCCOOH.
B. A4 l mtianehit.
C. A2 l mt iol.
D. A5 l mt iaxit.
Cu 62: Cho chui bin ha sau :
2
a. Cht A c th l
A. natri etylat.
B. anehit axetic.
C. etyl axetat.
D. A, B, C u ng.
b. Cht B c th l
A. etilen.
B. tinh bt.
C. glucoz.
D. A, B, C u sai.
c. Cht C c th l
A. etanal.
B. axetilen.
C. etylbromua.
D. A, C u ng.
Cu 63: Mt hp cht c thnh phn l 40% C ; 6,7% H v 53,3% O. Hp cht c CTGN l
A. C6H8O.
B. C2H4O.
C. CH2O.
D. C3H6O.
Cu 64: Pht biu ng l
A. Axit cha no khi chy lun cho s mol CO2 ln hn s mol H2O.
B. anehit tc dng vi H2 (xc tc Ni) lun to ancol bc nht.
C. anehit va c tnh kh va c tnh oxi ha.
D. A, B, C u ng.
Cu 65: Cho cc cht sau : (1) CH2=CHCH2OH ; (2) CH3CH2CHO ; (3) CH3COCH3.
Pht biu ng l
A. 1, 2, 3 l cc ng phn.
B. 3 tc dng vi H2 (xc tc Ni) to 1 ancol bc 2.
C. 1, 2 tc dng vi H2 (xc tc Ni) u to ra 1 ancol.
D. A, B, C u ng.
Cu 66: Cho 4 hp cht c CTPT l M : C3H6O ; N : C3H6O2 ; P : C3H4O ; Q : C3H4O2.
Bit : M v P cho phn ng trng gng ; N v Q phn ng c vi dung dch NaOH ; Q phn ng
vi H2 to thnh N ; oxi ha P thu c Q.
a. M v P theo th t l
A. C2H5COOH ; CH2=CHCOOH.
B. C2H5CHO ; CH2=CHCHO.
C. CH2=CHCOOH ; C2H5COOH .
D. CH2=CHCHO ; C2H5CHO.
b. N v Q theo th t l
A. C2H5COOH ; CH2 = CHCOOH.
C. C2H5CHO ; CH2=CHCHO.
54
B. CH2=CHCOOH ; C2H5COOH.
D. CH2=CHCHO ; C2H5CHO.
Cu 67: Cho cc cht sau: (1) CH2=CHCH2OH ; (2) HOCCH2CHO ; (3) HCOOCH=CH2.
Pht biu ng l
A. 1, 2, 3 tc dng c vi Na.
B. Trong A, B, C c 2 cht cho phn ng trng gng.
C. 1, 2, 3 l cc ng phn.
D. 1, 2, 3 chy u cho s mol H2O b hn s mol CO2.
Cu 68: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi
Na ; X tc dng c vi NaHCO 3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu
to ca X v Y ln lt l
A. C2H5COOH v HCOOC2H5.
B. HCOOC2H5 v HOCH2OCH3.
C. HCOOC2H5 v HOCH2CH2CHO.
D. C2H5COOH v CH3CH(OH)CHO.
Cu 69: Cho dy cc cht : HCHO, CH3COOH, HCOONa, HCOOH, C2H5OH, HCOOCH3. S cht
trong dy tham gia phn ng trng gng l
A. 3.
B. 6.
C. 4.
D. 5.
Cu 70: Cho cc cht sau : phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc
dng c vi nhau l
A. 4.
B. 3.
C. 2.
D. 1.
Cu 71: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn
ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng
thc cu to ca X1, X2 ln lt l
A. CH3COOH, CH3COOCH3.
B. (CH3)2CHOH, HCOOCH3.
C. HCOOCH3, CH3COOH.
D. CH3COOH, HCOOCH3.
Cu 72: Cho tt c cc ng phn mch h, c cng cng thc phn t C2H4O2 ln lt tc dng
vi : Na, NaOH, NaHCO3. S phn ng xy ra l
A. 2.
B. 5.
C. 4.
D. 3.
Cu 73: Cho cc cht sau : CH3CH2CHO (1) ; CH2=CHCHO (2) ; CHCCHO (3) ;
CH2=CHCH2OH (4) ;(CH3)2CHOH (5). Nhng cht phn ng hon ton vi lng d H2 (Ni, to)
cng to ra mt sn phm l
A. (2), (3), (4), (5).
B. (1), (2), (4), (5).
C. (1), (2), (3).
D. (1), (2), (3), (4).
Cu 74: Cho cc hp cht hu c : C2H4 ; C2H2 ; CH2O ; CH2O2 (mch h); C3H4O2 (mch h, n
chc). Bit C3H4O2 khng lm chuyn mu qu tm m.
a. S cht tc dng c vi dung dch AgNO3/NH3 to ra Ag l
A. 2.
B. 4.
C. 3.
D. 5.
b. S cht tc dng c vi dung dch AgNO3/NH3 to ra kt ta l
A. 2.
B. 4.
C. 3.
D. 5.
Cu 75: C th phn bi t 3 l mt nhn cha: HCOOH ; CH3COOH ; C2H5OH vi ha cht no
di y ?
A. dd AgNO3/NH3.
B. NaOH.
C. Na.
D. Cu(OH)2/OH-.
Cu 76: Ch dng thuc th no di y c th phn bi t 4 l mt nhn cha : fomon ; axit
fomic ;
axit axetic ; ancol etylic ?
A. dd AgNO3/NH3.
B. CuO.
C. Cu(OH)2/OH-.
D. NaOH.
Cu 77: Ch dng thuc th no di y c th phn bi t 4 l mt nhn cha : etylen glicol ; axit
fomic ; fomon ; ancol etylic ?
A. dd AgNO3/NH3
B. CuO.
C. Cu(OH)2/OH-.
D. NaOH.
Cu 78: Ch dng qu tm v nc brom c th phn bi t c nhng cht no sau y ?
A. axit fomic ; axit axetic ; axit acrylic ; axit propionic.
B. Axit axetic; axit acrylic; anilin; toluen; axit fomic.
C. Ancol etylic; ancol metylic; axit axetic; axit propionic.
D. Ancol etylic; ancol metylic ; phenol ; anilin.
Cu 79: phn bit 3 mu ha cht ring bit : phenol, axit acrylic, axit axetic bng mt thuc
th, ngi ta dng thuc th
55
A. dung dch Na2CO3.
B. CaCO3.
C. dung dch Br2.
D. dung dch AgNO3/NH3.
Cu 80: phn bit axit propionic v axit acrylic ta dng
A. dung dch Na2CO3. B. dung dch Br2.
C. dung dch C2H5OH. D. dung dch NaOH.
Cu 81: C th phn bit CH3CHO v C2H5OH bng phn ng vi
A. Na.
B. Cu(OH)2/NaOH.
C. AgNO3/NH3.
D. Tt c u ng.
Cu 82: phn bit 3 dung dch ring bit : axit axetic, axit acrylic, axit fomic ngi ta dng theo
th t cc thuc th sau
A. dung dch Br2/CCl4.
B. dung dch Br2/H2O.
C. dung dch Na2CO3.
D. dung dch AgNO3/NH3 d.
Cu 83: phn bit HCOOH v CH3COOH ta dng
A. Na.
B. AgNO3/NH3.
C. CaCO3.
D. NaOH.
Cu 84: Trng gng hon ton hp cht hu c X bng AgNO 3/NH3 thu c hn hp sn phm
ch gm cc cht v c. X c cu to
A. HCHO.
B. HCOONH4.
C. HCOOH.
D. Tt c u ng.
Cu 85: C th phn bit HCOOCH3 v CH3COOH bng
A. AgNO3/NH3
B. CaCO3.
C. Na.
D. Tt c u ng.
Cu 86: Cht to c kt ta gch khi un nng vi Cu(OH)2 l
A. HCHO.
B. HCOOCH3.
C. HCOOH.
D. Tt c u ng.
Cu 87: Ch dng 1 ha cht no sau y phn bit cc dung dch : ancol etylic, glixerol,
fomalin ?
A. Cu(OH)2 , toC.B. Na.
C. AgNO3 / NH3.
D. A, B, C u ng.
Cu 88: Hiro ha hon ton 2,9 gam m t anehit A c 3,1 gam ancol. A c cng thc phn t
l
A. CH2O.
B. C2H4O.
C. C3H6O.
D. C2H2O2.
Cu 89: Th tch H2 (0oC v 2 atm) va tc dng vi 11,2 gam anehit acrylic l
A. 4,48 lt.
B. 2,24 lt.
C. 0,448 lt.
D. 0,336 lt.
Cu 90: Cho 14,6 gam hn hp 2 anehit n chc, no lin tip tc dng ht vi H 2 to 15,2 gam
hn hp 2 ancol.
a. Tng s mol 2 ancol l
A. 0,2 mol.
B. 0,4 mol.
C. 0,3 mol.
D. 0,5 mol.
b. Khi lng anehit c KLPT ln hn l
A. 6 gam.
B. 10,44 gam.
C. 5,8 gam.
D. 8,8 gam.
Cu 91: Cho 7 gam cht A c CTPT C 4H6O tc dng vi H2 d c xc tc to thnh 5,92 gam ancol
isobutylic.
a. Tn ca A l
A. 2-metyl propenal. B. 2-metylpropanal. C. but-2-en-1-ol.
D. but-2-en-1-al.
b. Hiu sut ca phn ng l
A. 85%.
B. 75%.
C. 60%.
D. 80%.
Cu 92: Oxi ha 1,76 gam mt anehit n chc c 2,4 gam mt axit tng ng. Anehit l
A. anehit acrylic.
B. anehit axetic.
C. anehit propionic. D. anehit fomic.
Cu 93: Oxi ha 17,4 gam m t anehit n chc c 16,65 gam axit tng ng (H = 75%).
Anehit c cng thc phn t l
A. CH2O.
B. C2H4O.
C. C3H6O.
D. C3H4O.
Cu 94: t chy a mol mt anehit A thu c a mol CO2. Anehit ny c th l
A. CH3CHO.
B. HCHO.
C. C2H5CHO.
D. A, B, C u ng.
Cu 95: t chy hon ton 1,46 gam hn hp 2 anehit no, n chc ng ng k tip thu c
1,568 lt CO2 (ktc).
a. CTPT ca 2 anehit l
56
A. CH3CHO v C2H5CHO.
B. HCHO v CH3CHO.
C. C2H5CHO v C3H7CHO.
D. Kt qu khc.
b. Khi lng gam ca mi anehit l
A. 0,539 v 0,921.
B. 0,88 v 0,58.
C. 0,44 v 1,01.
D. 0,66 v 0,8.
Cu 96: t chy hon ton m t anehit n chc no, mch h A cn 17,92 lt O2 (ktc). Hp th
ht sn phm chy vo nc vi trong c 40 gam kt ta v dung dch X. un nng dung dch X
li c 10 gam kt ta na. Cng thc phn t A l
A. CH2O.
B. C2H4O.
C. C3H6O.
D. C4H8O.
Cu 97: X, Y, Z, T l 4 anehit no h n chc ng ng lin tip, trong M T = 2,4MX. t chy
hon ton 0,1 mol Z ri hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 d thy khi
lng dung dch tng hay gim bao nhiu gam?
A. tng 18,6 gam.
B. tng 13,2 gam.
C. Gim 11,4 gam.
D. Gim 30 gam.
Cu 98: t chy hon ton m t lng aehit A cn va 2,52 lt O2 (ktc), c 4,4 gam CO2 v
1,35 gam H2O. A c cng thc phn t l
A. C3H4O.
B. C4H6O.
C. C4H6O2.
D. C8H12O.
Cu 99: t chy hon ton 1 anehit A mch h, no thu c CO2 v H2O theo t l
n A : n CO : n H O 1 : 3 : 2 . Vy A l
A. CH3CH2CHO.
B. OHCCH2CHO.
C. HOCCH2CH2CHO.
D. CH3CH2CH2CH2CHO.
Cu 100: Cho 1,97 gam dung dch fomalin tc dng vi dung dch AgNO 3/NH3 d thu c 10,8
gam Ag. Nng % ca anehit fomic trong fomalin l
A. 49%.
B. 40%.
C. 50%.
D. 38,07%.
Cu 101: Hp cht A cha 1 loi nhm chc v phn t ch cha cc nguyn t C, H, O trong
oxi chim 37,21% v khi lng, 1 mol A trng gng hon ton cho 4 mol Ag. Vy A l
A. C2H4(CHO)2.
B. HCHO.
C. HOCCH2CHO.
D. CH3CHO.
Cu 102: Cho 10,4 gam hn hp gm metanal v etanal tc dng vi mt lng va d
AgNO3/NH3 thu c 108 gam Ag. Khi lng metanal trong hn hp l
A. 4,4 gam.
B. 3 gam.
C. 6 gam.
D. 8,8 gam.
Cu 103: Cho bay hi ht 5,8 gam mt hp cht hu c X thu c 4,48 lt hi X 109,2 oC v 0,7
atm. Mt khc khi cho 5,8 gam X phn ng ca AgNO3/NH3 d to 43,2 gam Ag. CTPT ca X l
A. C2H2O2.
B. C3H4O2.
C. CH2O.
D. C2H4O2.
Cu 104: Cho 5,8 gam anehit A tc dng ht vi mt lng d AgNO 3/NH3 thu c 43,2 gam
Ag. Tm CTPT ca A
A. CH3CHO.
B. CH2=CHCHO.
C. OHCCHO.
D. HCHO.
Cu 105: Cho 8,7 gam anehit X tc dng hon ton vi lng dung dch AgNO 3/NH3 (d) c
64,8 gam Ag. X c cng thc phn t l
A. CH2O.
B. C2H4O.
C. C2H2O2.
D. C3H4O.
Cu 106: 8,6 gam anehit mch khng nhnh A tc dng vi lng (d) dung dch AgNO3/NH3 to
43,2 gam Ag. A c cng thc phn t l
A. CH2O.
B. C3H4O.
C. C4H8O.
D.C4H6O2.
Cu 107: X l hn hp gm 2 anehit ng ng lin tip. Cho 0,1 mol X tc dng vi lng d
dung dch AgNO3/NH3 c 25,92 gam bc. % s mol anehit c s cacbon nh hn trong X l
A. 20%.
B. 40%.
C. 60%.
D. 75%.
Cu 108: Cho 0,1 mol m t anehit X tc dng ht vi dung dch AgNO3/NH3 (d) c 43,2 gam
Ag. Hiro ha hon ton X c Y. Bit 0,1 mol Y tc dng va vi Na va c 12 gam
rn. X c cng thc phn t l
A. CH2O.
B. C2H2O2.
C. C4H6O.
D. C3H4O2.
2
Cu 109: X l hn hp 2 anehit n chc. Chia 0,12 mol X thnh hai phn bng nhau :
- t chy ht phn 1 c 6,16 gam CO2 v 1,8 gam H2O.
- Cho phn 2 tc dng vi lng d dung dch AgNO3/NH3 c 17,28 gam bc.
57
X gm 2 anehit c cng thc phn t l
A. CH2O v C2H4O. B. CH2O v C3H6O. C. CH2O v C3H4O. D. CH2O v C4H6O.
Cu 110: Oxi ha 48 gam ancol etylic bng K 2Cr2O7 trong H2SO4 c, tch ly sn phm hu c ra
ngay khi mi trng v dn vo dung dch AgNO 3/NH3 d thy c 123,8 gam Ag. Hiu sut ca
phn ng oxi ha l
A. 72,46 %.
B. 54,93 %.
C. 56,32 %.
D. Kt qu khc.
Cu 111: Dn m gam hi ancol etylic qua ng ng CuO d un nng. Ngng t phn hi thot ra
c hn hp X gm anehit, ancol etylic v H2O. Bit lng X tc dng vi Na (d) gii phng
3,36 lt H2 ( ktc), cn 1/2 lng X cn li tc dng vi d dung dch AgNO 3/NH3 to c 25,92
gam Ag.
a. Gi tr m l
A. 13,8 gam
B. 27,6 gam
C. 16,1 gam
D. 6,9 gam
b. Hiu sut phn ng oxi ho ancol etylic l
A. 20%.
B. 40%.
C. 60%.
D. 75%.
Cu 112: Cho m gam ancol n chc no (h) X qua ng ng CuO (d) nung nng. Sau khi phn
ng hon ton thy khi lng cht rn trong ng gim 0,32 gam. Hn hp hi thu c (gm hi
anehit v hi nc) c t khi so vi H2 l 19. Gi tr m l
A. 1,2 gam.
B. 1,16 gam.
C. 0,92 gam.
D.0,64 gam.
Cu 113: X l hn hp 2 ancol n chc ng ng lin tip. Cho 0,3 mol X tc dng hon ton
vi CuO un nng c hn hp Y gm 2 anehit. Cho Y tc dng vi lng dung dch
AgNO3/NH3 c 86,4 gam Ag. X gm
A. CH3OH v C2H5OH.
B. C3H7OH v C4H9OH.
C. C2H5OH v C3H7OH.
D. C3H5OH v C4H7OH.
Cu 114: Dn 4 gam hi ancol n chc A qua ng ng CuO, nung nng. Ngng t phn hi thot
ra c hn hp X. Cho X tc dng vi lng d dung dch AgNO3/NH3 c 43,2 gam bc. A l
A. ancol metylic.
B. ancol etylic.
C. ancol anlylic.
D. ancol benzylic.
Cu 115: X l hn hp gm m t ancol n chc no, mch h A v m t anehit no, mch h n
chc B (A v B c cng s cacbon). t chy hon ton 13,4 gam X c 0,6 mol CO 2 v 0,7 mol
H2O. S nguyn t C trong A, B u l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 116: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc
AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to
thnh l
A. 43,2 gam.
B. 10,8 gam.
C. 64,8 gam.
D. 21,6 gam.
Cu 117: Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy
ng ng tc dng vi lng d dung dch AgNO 3 trong NH3, un nng thu c 32,4 gam Ag.
Hai anehit trong X l
A. HCHO v C2H5CHO.
B. HCHO v CH3CHO.
C. C2H3CHO v C3H5CHO.
D. CH3CHO v C2H5CHO.
Cu 118: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip
nhau trong dy ng ng (MX < My), thu c hn hp hai ancol c khi lng ln hn khi lng
M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca
X ln lt l
A. HCHO v 50,56%.
B. CH3CHO v 67,16%.
C. CH3CHO v 49,44%.
D. HCHO v 32,44%.
Cu 119: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3,
un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6
gam Na. Cng thc cu to thu gn ca X l
A. HCHO.
B. OHCCHO.
C. CH3CHO.
D. CH3CH(OH)CHO.
58
Cu 120: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng
trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu
to ca X v Y tng ng l
A. HOCH2CHO v HOCH2CH2CHO.
B. HOCH2CH2CHO v HOCH2CH2CH2CHO.
C. HCOOCH3 v HCOOCH2CH3.
D. HOCH(CH3)CHO v HOOCCH2CHO.
Cu 121: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch
AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu
kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu
0,7 lt ( ktc). Cng thc cu to ca X l
A. HCOOC2H5.
B. CH3COOCH3.
C. HOOCCHO.
D. OHCCH2CH2OH.
Cu 122: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip
nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon
ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l
A. 10,5.
B. 8,8.
C. 24,8.
D. 17,8.
Cu 123: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng
ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t
khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong
dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l
A. 7,8.
B. 8,8.
C. 7,4.
D. 9,2.
Cu 124: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc
AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng
dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l
A. C3H7CHO.
B. HCHO.
C. C4H9CHO.
D. C2H5CHO.
Cu 125: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn
phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc
AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l
A. 76,6%.
B. 80,0%.
C. 65,5%.
D. 70,4%.
Cu 126: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong
NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X
phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l
A. CnH2n-3CHO (n 2).
B. CnH2n-1CHO (n 2).
C. CnH2n+1CHO (n 0).
D. CnH2n(CHO)2 (n 0).
Cu 127: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi
phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu
c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l
A. 35,00%.
B. 65,00%.
C. 53,85%.
D. 46,15%.
Cu 128: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi
ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c
hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu
c 54 gam Ag. Gi tr ca m l
A. 13,5.
B. 8,1.
C. 8,5.
D. 15,3.
Cu 129: 1,72 gam hn hp anehit acrylic v anehit axetic tham gia phn ng cng va 1,12
lt H2 (ktc). Cho thm 0,696 gam anehit B l ng ng ca anehit fomic vo 1,72 gam hn hp
2 anehit trn ri cho hn hp thu c tham gia phn ng trng bc hon ton c 10,152 gam
Ag. Cng thc cu to ca B l
A. CH3CH2CHO.
B. C4H9CHO.
C. CH3CH(CH3)CHO. D. CH3CH2CH2CHO.
Cu 130*: 17,7 gam hn hp X gm 2 anehit n chc phn ng hon ton vi dung dch AgNO 3
trong NH3 (dng d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d
c 0,45 mol CO2. Cc cht trong hn hp X l
A. C2H3CHO v HCHO.
B. C2H5CHO v HCHO.
C. CH3CHO v HCHO.
D. C2H5CHO v CH3CHO.
59
Cu 131: A l axit cacboxylic n chc cha no (1 ni i C=C). A tc dng vi brom cho sn
phm cha 65,04% brom (theo khi lng). V y A c cng thc phn t l
A. C3H4O2.
B. C4H6O2.
C. C5H8O2.
D. C5H6O2.
Cu 132: Mun trung ha 6,72 gam mt axit hu c A cn dng 200 gam dung dch NaOH 2,24%.
A l
A. CH3COOH.
B. CH3CH2COOH.
C. HCOOH.
D. CH2=CHCOOH.
Cu 133: trung ha 40 ml gim n cn 25 ml dung dch NaOH 1M. Bit khi lng ring ca
gim l 1 g/ml. V y mu gim n ny c nng l
A. 3,5%.
B. 3,75%.
C. 4%.
D. 5%.
Cu 134: Trung ha 9 gam axit cacbonxylic A bng NaOH va c cn dung dch c 13,4 gam
mui khan. A c cng thc phn t l
A. C2H4O2.
B. C2H2O4.
C. C3H4O2.
D. C4H6O4.
Cu 135: Trung ha 2,7 gam axit cacboxylic A cn va 60 ml dung dch NaOH 1M. A c cng
thc phn t l
A. C2H4O2.
B. C3H4O2.
C. C4H6O4.
D. C2H2O4.
Cu 136: Trung ha hon ton 1,8 gam mt axit hu c n chc bng dung dch NaOH va ri
c cn dung dch sau phn ng c 2,46 gam mui khan. Axit l
A. HCOOH.
B. CH2=CHCOOH.
C. CH3CH2COOH.
D. CH3COOH.
Cu 137: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch
gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan.
Cng thc phn t ca X l
A. C2H5COOH.
B. CH3COOH.
C. HCOOH.
D. C3H7COOH.
Cu 138: A v B l 2 axit cacboxylic n chc. Trn 1,2 gam A vi 5,18 gam B c hn hp X.
trung ha ht X cn 90 ml dung dch NaOH 1M. A, B ln lt l
A. Axit propionic, axit axetic.
B. axit axetic, axit propionic.
C. Axit acrylic, axit propionic.
D. Axit axetic, axit acrylic.
Cu 139: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH tc dng va vi 400 ml
dung dch NaOH 1M. Tng khi lng mui thu c sau phn ng l
A. 3,54 gam.
B. 4,46 gam.
C. 5,32 gam.
D. 11,26 gam.
Cu 140: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28
gam mui ca axit hu c. Cng thc cu to thu gn ca X l
A. CH2=CHCOOH.
B. CH3COOH.
C. HCCCOOH.
D. CH3CH2COOH.
Cu 141: Cho 0,1 mol axit hu c X tc dng vi 11,5 gam hn hp Na v K thu c 21,7 gam
cht rn v thy thot ra 2,24 lt kh H2 (ktc). Cng thc cu to ca X l
A. (COOH)2.
B. CH3COOH.
C. CH2(COOH)2.
D. CH2=CHCOOH.
Cu 142: Cho 16,6 gam hn hp gm HCOOH, CH3COOH tc dng ht vi Mg thu c 3,36 lt
H2 (ktc). Khi lng CH3COOH l
A. 12 gam.
B. 9 gam.
C. 6 gam.
D. 4,6 gam.
Cu 143: X l hn hp gm HCOOH v CH 3COOH (t l mol 1:1). Ly 21,2 gam X tc dng vi
23 gam C2H5OH (xc tc H2SO4 c , un nng) thu c m gam hn hp este (hi u sut este ha
u t 80%). Gi tr m l
A. 40,48 gam.
B. 23,4 gam.
C. 48,8 gam.
D. 25,92 gam.
Cu 144: un nng 6 gam CH3COOH vi 9,2 gam C2H5OH (c H2SO4 c lm xc tc) n khi
phn ng t ti trng thi cn cn bng th c 5,5 gam este. Hi u sut phn ng este ha l
A. 55%.
B. 62,5%.
C. 75%.
D. 80%.
Cu 145: Cho 0,3 mol axit X n chc trn vi 0,25 mol ancol etylic em thc hin phn ng este
ha thu c thu c 18 gam este. Tch ly lng ancol v axit d cho tc dng vi Na thy thot
ra 2,128 lt H2. Vy cng thc ca axit v hiu sut phn ng este ha l
A. CH3COOH, H% = 68%.
B. CH2=CHCOOH, H%= 78%.
C. CH2=CHCOOH, H% = 72%.
D. CH3COOH, H% = 72%.
Cu 146: Oxi ho anehit OHCCH2CH2CHO trong iu kin thch hp thu c hp cht hu c
X. un nng hn hp gm 1 mol X v 1 mol ancol metylic vi xc tc H 2SO4 c thu c 2 este Z
60
v Q (MZ < MQ) vi t l khi lng mZ : mQ = 1,81. Bit ch c 72% ancol chuyn thnh este. S
mol Z v Q ln lt l
A. 0,36 v 0,18.
B. 0,48 v 0,12.
C. 0,24 v 0,24.
D. 0,12 v 0,24.
Cu 147: t chy hon ton 2,22 gam mt axit hu c no A thu c 1,62 gam H2O. A l
A. C3H7COOH.
B. C2H5COOH.
C. HCOOH.
D. CH3COOH.
Cu 148: t chy hon ton 0,1 mol axit n chc cn V lt O2 ktc, thu c 0,3 mol CO2 v
0,2 mol H2O. Gi tr V l
A. 6,72 lt.
B. 8,96 lt.
C. 4,48 lt.
D. 5,6 lt.
Cu 149: t chy hon ton m t axit A thu c 0,2 mol CO2 v 0,15 mol H2O. A c cng thc
phn t l
A. C3H4O4.
B. C4H8O2.
C. C4H6O4.
D. C5H8O4.
Cu 150: t chy hon ton 4,38 gam mt axit E no, mch thng thu c 4,032 lt CO 2 (kc) v
2,7 gam H2O. CTCT ca E l
A. CH3COOH.
B. C17H35COOH.
C. HOOC(CH2)4COOH.
D. CH2=C(CH3)COOH.
Cu 151: t chy hon ton 0,1 mol axit cacboxylic A thu c cha n 8 gam hn hp CO 2 v
H2O. A l
A. axit fomic.
B. axit axetic.
C. axit acrylic.
D. axit oxalic.
Cu 152: Z l mt axit hu c. t chy 0,1 mol Z cn 6,72 lt O2 (ktc). CTCT ca Z l
A. CH3COOH.
B. CH2=CHCOOH.
C. HCOOH.
D. Kt qu khc.
Cu 153: t chy ht 1 th tch hi axit hu c A c 3 th tch hn hp CO2 v hi nc khi o
cng iu kin. CTPT ca A l
A. HCOOH.
B. CH3COOH.
C. HOOCCOOH.
D. HOOCCH2COOH.
Cu 154: t chy hon ton 0,44 gam mt axit hu c, sn phm chy cho hp th hon ton vo
bnh 1 ng P2O5, bnh 2 ng dung dch KOH. Sau th nghim thy khi lng bnh 1 tng 0,36
gam v bnh 2 tng 0,88 gam. CTPT ca axit l
A. C4H8O2.
B. C5H10O2.
C. C2H6O2.
D. C2H4O2.
Cu 155: t chy ht 10ml th tch hi mt hp cht hu c A cn dng 30 ml O 2, sn phm
thu c ch gm CO2 v H2O c th tch bng nhau v u bng th tch O 2 phn ng. CTPT
ca A l
A. C2H4O2.
B. C3H6O3.
C. C3H6O2.
D. C4H8O2.
Cu 156: X l hn hp 2 axit cacboxylic no, h, phn t mi axit cha khng qu 2 nhm -COOH.
t chy hon ton 9,8 gam X c 11 gam CO2 v 3,6 gam H2O. X gm
A. HCOOH v CH3COOH.
B. HCOOH v HOOCCH2COOH.
C. HCOOH v HOOCCOOH.
D. CH3COOH v HOOCCH2COOH.
Cu 157: Cc sn phm thu c khi t chy hon ton 3 gam axit hu c X c dn ln lt
qua bnh 1 ng H2SO4 c v bnh 2 ng dung dch NaOH. Sau th nghim thy khi lng bnh
1 tng 1,8 gam v khi lng bnh 2 tng 4,4 gam. CTCT ca A l
A. HCOOH.
B. C2H5COOH.
C. CH3COOH.
D. A hoc B hoc C.
Cu 158: Oxi ha 0,125 mol ancol n chc A bng 0,05 mol O2 (xt, to) c 5,6 gam hn hp X
gm axit cacboxylic ; anehit ; ancol d v nc. A c cng thc phn t l
A. CH4O.
B. C2H6O.
C. C3H6O.
D. C3H8O.
Cu 159: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon).
Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 (
ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm
v khi lng ca Z trong hn hp X ln lt l
A. HOOCCOOH v 42,86%.
B. HOOCCOOH v 60,00%.
C. HOOCCH2COOH v 70,87%.
D. HOOCCH2COOH v 54,88%.
61
Cu 160: Cht A c ngun gc t thc vt v thng gp trong i sng (cha C, H, O), mch h.
Ly cng s mol ca A cho phn ng ht vi Na2CO3 hay vi Na th thu c s mol CO2 bng 3/4
s mol H2. Cht A l
A. axit malic : HOOCCH(OH)CH2COOH.
B. axit xitric : HOOCCH2C(OH)(COOH)CH2COOH.
C. axit lauric : CH3(CH2)10COOH.
D. axit tactaric : HOOCCH(OH)CH(OH)COOH.
Cu 161: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc
vi NaHCO3 th u sinh ra a mol kh. Cht X l
A. ancol o-hiroxibenzylic.
B. axit aipic.
C. axit 3-hiroxipropanoic.
D. etylen glicol.
Cu 162: Chia 0,3 mol axit cacobxylic A thnh hai phn bng nhau.
- t chy phn 1 c 19,8 gam CO2.
- Cho phn 2 tc dng hon ton vi 0,2 mol NaOH, thy sau phn ng khng cn NaOH.
V y A c cng thc phn t l
A. C3H6O2.
B. C3H4O2.
C. C3H4O4.
D. C6H8O4.
Cu 163: Cho 10 gam hn hp X gm HCHO v HCOOH tc dng vi lng (d) dung dch
AgNO3/NH3 c 99,36 gam bc. % khi lng HCHO trong hn hp X l
A. 54%.
B. 69%.
C. 64,28%.
D. 46%.
Cu 164: trung ha a mol axit cacboxylic A cn 2a mol NaOH. t chy hon ton a mol A thu
c 3a mol CO2. A c cng thc phn t l
A. C3H4O2.
B. C3H6O2.
C. C6H10O4.
D. C3H4O4.
Cu 165: t chy hon ton 3,12 gam axit cacboxylic A c 3,96 gam CO2. Trung ha cng
lng axit ny cn 30 ml dung dch NaOH 2M. A c cng thc phn t l
A. C2H4O2.
B. C4H6O2.
C. C3H4O2.
D. C3H4O4.
Cu 166: Hn hp X gm 2 axit no A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt CO 2
(kc). trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. CTCT ca 2 axit l
A. HCOOH v C2H5COOH.
B. CH3COOH v C2H5COOH.
C. HCOOH v HOOCCOOH.
D. CH3COOH v HOOCCH2COOH.
Cu 167: Trung ha a mol axit hu c A cn 2a mol NaOH. t chy ht a mol A c 2a mol
CO2. A l
A. CH3COOH.
B. HOOCCOOH.
C. axit n chc no.
D. axit n chc khng no.
Cu 168: Hp cht hu c E mch h c CTPT C 3H6O3 c nhiu trong sa chua. E c th tc dng
vi Na v Na2CO3, cn khi tc dng vi CuO nung nng th to ra hp cht hu c khng tham gia
phn ng trng gng. CTCT ca E l
A. CH3COOCH2OH.
B. CH3CH(OH)COOH.
C. HOCH2COOCH3.
D. HOCH2CH2COOH.
Cu 169: t chy hon ton 0,1 mol cht X l mui Na ca mt axit hu c thu c 0,15 mol
CO2, hi H2O v Na2CO3. CTCT ca X l
A. C3H7COONa.
B. CH3COONa.
C. CH3COONa.
D. HCOONa.
Cu 170: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch
h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO 2, hi nc) ln lt qua
bnh 1 ng H2SO4 c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51
gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai
mui natri l
A. C2H5COONa v C3H7COONa.
B. C3H7COONa v C4H9COONa.
62
C. CH3COONa v C2H5COONa.
D. CH3COONa v C3H7COONa.
Cu 171: Khi lng axit axetic thu c khi ln men 1 lt ancol etylic 8 o l bao nhiu ? Cho d =
0,8 g/ml v hi u sut phn ng t 92%.
A. 76,8 gam.
B. 90,8 gam.
C. 73,6 gam.
D. 58,88 gam.
Cu 172: Thc hin phn ng oxi ha m gam ancol etylic nguyn cht thnh axit axetic (hiu sut
phn ng t 25%) thu c hn hp Y, cho Y tc dng vi Na d thu c 5,6 lt H2 (ktc). Gi tr
ca m l
A. 18,4 gam.
B. 9,2 gam.
C. 23 gam.
D. 4,6 gam.
Cu 173: Cho s phn ng sau:
+ HCN
+ H3O+, to + H2SO4 , to
xt, to, p
CH3CH=O
A
B
C3H4O2
C
C3H4O2 c tn l
A. axit axetic.
B. axit metacrylic.
C. axit acrylic.
D. anehit acrylic.
Mg, ete
CO 2
HCl
Cu 174: Cho s sau : C2H5Br A B C .
C c cng thc l
A. CH3COOH.
B. CH3CH2COOH.
C. CH3CH2OH.
D. CH3CH2CH2COOH.
(COOH)2
B
D
C2H5OH
Cu 175: Cho s chuyn ho sau: HCOONa
A
Cc cht A, B, D c th l
A. H2 ; C4H6 ; C2H4(OH)2.
B. H2 ; C2H4 ; C2H4(OH)2.
C. CH4 ; C2H2 ; (CHO)2.
D. C2H6 ; C2H4(OH)2.
Cu 176 : Cho 19,8 gam m t anehit n chc A phn ng hon ton vi dung dch AgNO3/NH3
(d). Lng Ag sinh ra phn ng ht vi dung dch HNO 3 long c 6,72 lt NO ktc. A c cng
thc phn t l
A. C2H4O.
B. C3H6O.
C. C3H4O.
D. C4H8O.
Cu 177: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na
thot ra 1,68 lt kh (ktc). Nu cho hn hp trn tham gia phn ng cng H 2 hon ton th khi
lng sn phm cui cng l
A. 11,1 gam.
B. 7,4 gam.
C. 11,2 gam.
D. 11,0 gam.
Cu 178: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt
mu hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml
dd NaOH 0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l
A. 35,24%.
B. 45,71%.
C. 19,05%.
D. 23,49%.
Cu 179: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c
dung dch X. Chia X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch
AgNO3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung
dch NaOH 1,0M. Cng thc ca hai axit l
A. HCOOH, C3H7COOH.
B. CH3COOH, C2H5COOH.
C. CH3COOH, C3H7COOH.
D. HCOOH, C2H5COOH.
Cu 180: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng
dy ng ng tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t
cacbon t hn c trong X l
A. 3,0 gam.
B. 4,6 gam.
C. 7,4 gam.
D. 6,0 gam.
Phn 2: p n
CHUYN 1 : I CNG HA HC HU C
63
1A
11A
21B
31B
41A
51B
61D
71A
81C
91B
2B
12D
22B
32A
42C
52B
62BA
72B
82A
92B
3C
13B
23D
33B
43C
53C
63C
73C
83D
93B
4B
14A
24C
34B
44D
54C
64D
74A
84C
94C
CHUYN 2 :
1B
11C
21A
31D
41C
51B
61D
2A
12B
22B
32A
42B
52C
62C
3C
13C
23D
33B
43A
53BD
63B
CHUYN 3 :
5B
15B
25C
35A
45C
55B
65B
75A
85D
95C
6D
16B
26A
36D
46D
56C
66A
76A
86A
96B
7B
17A
27A
37C
47D
57C
67D
77C
87B
97C
8C
18A
28CD
38B
48B
58C
68A
78C
88C
98A
9D
19D
29A
39B
49A
59C
69D
79D
89A
99B
10C
20C
30D
40B
50C
60D
70A
80B
90C
100D
8DA
18B
28A
38D
48A
58D
68B
9B
19B
29B
39BC
49CC
59A
69D
10D
20C
30B
40D
50BD
60B
70DA
9D
10D
HIROCACBON NO
4B
14C
24D
34B
44A
54D
64A
5D
15B
25D
35C
45A
55A
65C
6D
16D
26C
36A
46D
56C
66D
7A
17A
27B
37A
47A
57B
67B
HIROCACBON KHNG NO
BI TP V ANKEN
1C
64
2C
3B
4C
5D
6D
7C
8C
11C
21A
31B
41A
51D
61C
71B
81B
12B
22C
32D
42B
52A
62B
72A
82B
13A
23C
33C
43C
53A
63D
73A
83B
14D
24B
34D
44D
54C
64A
74B
84D
15C
25D
35A
45D
55A
65C
75C
85D
16A
26A
36A
46A
56D
66C
76C
17A
27D
37B
47B
57C
67D
77A
18B
28B
38C
48AB
58C
68A
78C
19C
29A
39B
49A
59A
69A
79A
20C
30D
40B
50D
60A
70A
80D
BI TP V ANKAIEN -TECPEN - ANKIN

1D
11C
21B
31B
41C
51C
61D
71D
81A
2B
12C
22C
32B
42C
52C
62B
72A
82D
3D
13C
23D
33D
43D
53D
63D
73C
83A
4C
14A
24C
34C
44A
54A
64D
74C
84D
5A
15A
25C
35B
45D
55A
65B
75D
85C
6D
16B
26B
36C
46C
56C
66C
76B
86C
7A
17A
27B
37C
47B
57D
67A
77D
87B
8B
18D
28B
38C
48D
58A
68B
78A
88A
9C
19B
29A
39C
49C
59A
69D
79A
10A
20D
30B
40C
50D
60C
70A
80A
CHUYN 4 : HIROCACBON THM NGUN

HIROCACBON THIN NHIN
1B
11B
21A
31C
41D
51D
61A
71B
2C
12A
22C
32A
42A
52D
62D
72C
3D
13C
23C
33C
43A
53B
63B
73B
4D
14C
24A
34B
44B
54C
64C
74C
5D
15A
25C
35D
45D
55C
65BA
75A
6A
16D
26B
36A
46C
56C
66A
76D
7C
17D
27A
37C
47D
57DA
67D
77A
8C
18D
28B
38A
48D
58D
68A
78B
9B
19D
29C
39C
49D
59A
69D
79B
10D
20A
30D
40A
50D
60C
70B
80AC
CHUYN 5 : DN XUT HALOGEN-PHENOL-ANCOL

1A
11C
21B
31D
2A
12B
22D
32B
3C
13B
23C
33C
4B
14D
24C
34C
5B
15A
25B
35B
6A
16DD
26B
36B
7A
17B
27A
37B
8A
18A
28C
38C
9C
19B
29D
39A
10AD
20A
30D
40C
65
41D
51D
61D
71D
81D
91A
101A
111B
121C
131C
141A
151B
161B
171B
181B
42A
52D
62A
72D
82A
92C
102C
112D
122A
132D
142C
152C
162B
172A
182C
43B
53C
63A
73C
83D
93A
103C
113A
123A
133B
143B
153B
163A
173B
183A
44A
54A
64D
74B
84A
94D
104B
114B
124C
134AA
144C
154C
164B
174A
184D
45C
55D
65A
75C
85C
95B
105A
115B
125B
135A
145D
155B
165D
175D
185A
46D
56C
66A
76B
86A
96B
106C
116C
126C
136B
146A
156C
166C
176D
186A
47D
57D
67C
77A
87C
97C
107A
117B
127A
137D
147D
157D
167D
177D
187B
48C
58C
68CB
78C
88B
98C
108D
118B
128C
138D
148B
158D
168D
178A
49B
59B
69B
79A
89C
99A
109A
119A
129B
139D
149A
159C
169B
179A
50B
60A
70B
80D
90C
100D
110A
120C
130C
140D
150A
160AD
170C
180B
CHUYN 6 : ANEHIT-XETON-AXIT CACBOXILIC

1B
11B
21A
31A
41A
51B
61B
71D
81D
91AD
101A
111BB
121A
131B
141C
151A
161C
171A
2C
12B
22C
32D
42D
52B
62DAD
72B
82B
92B
102C
112A
122D
132A
142A
152B
162C
172A
3C
13A
23C
33A
43D
53C
63C
73D
83B
93C
103A
113A
123A
133B
143D
153C
163A
173C
4C
14A
24B
34D
44A
54D
64D
74CB
84D
94B
104C
114A
124A
134B
144B
154A
164D
174B
5D
15A
25C
35C
45C
55B
65D
75D
85D
95AB
105C
115B
125B
135D
145C
155B
165D
175B
6D
16BD
26C
36C
46C
56C
66BA
76C
86D
96C
106D
116C
126B
136D
146A
156B
166C
176A
7A
17D
27A
37C
47C
57A
67B
77C
87A
97C
107A
117B
127D
137B
147B
157C
167B
177A
8D
18A
28C
38D
48D
58A
68D
78B
88A
98C
108D
118A
128C
138B
148A
158A
168B
178C
9C
19C
29A
39D
49A
59BD
69C
79C
89A
99B
109C
119B
129A
139D
149C
159A
169B
179A
10D
20B
30A
40D
50C
60D
70A
80B
90CC
100D
110B
120A
130A
140A
150C
160B
170A
180D
CHUYN 6 : ANEHIT-XETON-AXIT CACBOXILIC

1B
11B
66
2C
12B
3C
13A
4C
14A
5D
15A
6D
16BD
7A
17D
8D
18A
9C
19C
10D
20B
21A
31A
41A
51B
61B
71D
81D
91AD
101A
111BB
121A
131B
141C
151A
161C
171A
22C
32D
42D
52B
62DAD
72B
82B
92B
102C
112A
122D
132A
142A
152B
162C
172A
23C
33A
43D
53C
63C
73D
83B
93C
103A
113A
123A
133B
143D
153C
163A
173C
24B
34D
44A
54D
64D
74CB
84D
94B
104C
114A
124A
134B
144B
154A
164D
174B
25C
35C
45C
55B
65D
75D
85D
95AB
105C
115B
125B
135D
145C
155B
165D
175B
26C
36C
46C
56C
66BA
76C
86D
96C
106D
116C
126B
136D
146A
156B
166C
176A
27A
37C
47C
57A
67B
77C
87A
97C
107A
117B
127D
137B
147B
157C
167B
177A
28C
38D
48D
58A
68D
78B
88A
98C
108D
118A
128C
138B
148A
158A
168B
178C
29A
39D
49A
59BD
69C
79C
89A
99B
109C
119B
129A
139D
149C
159A
169B
179A
30A
40D
50C
60D
70A
80B
90CC
100D
110B
120A
130A
140A
150C
160B
170A
180D
67

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Bin son : Gio vin Nguyn Minh Tun T Ha Trng THPT Chuyn Hng Vng

NGUYN MINH TUN

Chuyn 3 : Hirocacbon khng no

Chuyn 4 : Hirocacbon thm - Ngun hirocacbon

Chuyn 5 : Dn xut halogen - Phenol - Ancol

Chuyn 6 : Anehit - Xeton - Axitcacboxylic

Cu 1: Hp cht hu c X c tn gi l: 2 - clo - 3 - metylpentan. Cng thc cu to ca X l:

Cu 70: Nung m gam hn hp X gm 3 mui natri ca 3 axit no n chc vi NaOH d thu c

Cu 1: Anken X c cng thc cu to: CH3CH2C(CH3)=CHCH3. Tn ca X l

Cu 31: iu ch etilen trong phng th nghim t C 2H5OH, (H2SO4 c, 170oC) thng ln cc

BI TP V ANKAIEN -TECPEN - ANKIN

Cu 13: Ankaien A + brom (dd)

Cu 30: Cho phn ng : C2H2 + H2O

Cu 37: Cho dy chuyn ho sau: CH4

CHUYN 4 : HIROCACBON THM NGUN

Cu 11: Cht cu to nh sau c tn gi l g ?

Cu 42: 1 mol nitrobenzen + 1 mol HNO3

CHUYN 5 : DN XUT HALOGEN - PHENOL - ANCOL

NaOH n/c, to, p

CHUYN 6: ANEHIT-XETON-AXIT CACBOXYLIC

BI TP V ANKAIEN -TECPEN - ANKIN

CHUYN 4 : HIROCACBON THM NGUN

CHUYN 5 : DN XUT HALOGEN-PHENOL-ANCOL

CHUYN 6 : ANEHIT-XETON-AXIT CACBOXILIC

CHUYN 6 : ANEHIT-XETON-AXIT CACBOXILIC

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