CHAPTER 10-KELOMPOK 9

HERSA MILAWATI 140210130057

1)
R=
O=
n=
E0=

Ce4+
Ce3+
1
1.61

[R]

[O]

[R]/[O]

1.00E-05

1.00E+00

1.00E-05

0.000025

0.75

3.33E-05

0.00005

0.5

1.00E-04

0.000075

0.25

3.00E-04

0.0001

0.1

1.00E-03

0.00025

0.075

3.33E-03

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

0.0025

0.0075

3.33E-01

0.005

0.005

1.00E+00

0.0075

0.0025

3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0

E
1.91E+00
1.88E+00
1.85E+00
1.82E+00
1.79E+00
1.76E+00
1.73E+00
1.70E+00
1.67E+00
1.64E+00
1.61E+00
1.58E+00
1.55E+00
1.52E+00

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

R=
O=
n=
E0=

Co3+
CO2+
1
1.81

[R]

[O]

[R]/[O]

1.00E-05

1.00E+00

1.00E-05

0.000025

0.75

3.33E-05

0.00005

0.5

1.00E-04

0.000075

0.25

3.00E-04

0.0001

0.1

1.00E-03

0.00025

0.075

3.33E-03

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0

1.49E+00
1.46E+00
1.43E+00
1.40E+00
1.37E+00
1.34E+00
1.31E+00

E
2.11E+00
2.08E+00
2.05E+00
2.02E+00
1.99E+00
1.96E+00
1.93E+00
1.90E+00
1.87E+00

0.0025

0.0075

3.33E-01

0.005

0.005

1.00E+00

0.0075

0.0025

3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

R=
O=
n=
E0=

Ti3+
Ti+
2
-1.37

[R]

[O]

[R]/[O]

1.00E-05

1.00E+00

1.00E-05

0.000025

0.75

3.33E-05

0.00005

0.5

1.00E-04

0.000075

0.25

3.00E-04

0.0001

0.1

1.00E-03

0.00025

0.075

3.33E-03

-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0

1.84E+00
1.81E+00
1.78E+00
1.75E+00
1.72E+00
1.69E+00
1.66E+00
1.63E+00
1.60E+00
1.57E+00
1.54E+00
1.51E+00

E
-1.22E+00
-1.24E+00
-1.25E+00
-1.27E+00
-1.28E+00
-1.30E+00

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

0.0025

0.0075

3.33E-01

0.005

0.005

1.00E+00

0.0075

0.0025

3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

R=
O=
n=
E0=

Ti3+
Ti2+
1
-0.9

[R]

[O]

[R]/[O]

1.00E-05

1.00E+00

1.00E-05

0.000025

0.75

3.33E-05

0.00005

0.5

1.00E-04

2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0

-1.31E+00
-1.32E+00
-1.34E+00
-1.36E+00
-1.37E+00
-1.38E+00
-1.40E+00
-1.42E+00
-1.43E+00
-1.44E+00
-1.46E+00
-1.47E+00
-1.49E+00
-1.50E+00
-1.52E+00

E
-6.04E-01
-6.35E-01
-6.63E-01

0.000075

0.25

3.00E-04

0.0001

0.1

1.00E-03

0.00025

0.075

3.33E-03

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

0.0025

0.0075

3.33E-01

0.005

0.005

1.00E+00

0.0075

0.0025

3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

R=
O=
n=
E0=

V3+
V2+
1
-0.255

[R]

[O]

[R]/[O]

3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

log([R]/
[O])

-6.91E-01
-7.22E-01
-7.53E-01
-7.82E-01
-8.10E-01
-8.41E-01
-8.72E-01
-9.00E-01
-9.28E-01
-9.59E-01
-9.90E-01
-1.02E+00
-1.05E+00
-1.08E+00
-1.11E+00
-1.14E+00
-1.17E+00
-1.20E+00

1.00E-05

1.00E+00

1.00E-05

0.000025

0.75

3.33E-05

0.00005

0.5

1.00E-04

0.000075

0.25

3.00E-04

0.0001

0.1

1.00E-03

0.00025

0.075

3.33E-03

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

0.0025

0.0075

3.33E-01

0.005

0.005

1.00E+00

0.0075

0.0025

3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0

4.10E-02
1.00E-02
-1.82E-02
-4.64E-02
-7.74E-02
-1.08E-01
-1.37E-01
-1.65E-01
-1.96E-01
-2.27E-01
-2.55E-01
-2.83E-01
-3.14E-01
-3.45E-01
-3.73E-01
-4.02E-01
-4.33E-01
-4.64E-01
-4.92E-01
-5.20E-01
-5.51E-01

R=
O=
n=
E0=

Hg2+
Hg2 2+
2
0.92

[R]

[O]

[R]/[O]

1.00E-05

1.00E+00

1.00E-05

0.000025

0.75

3.33E-05

0.00005

0.5

1.00E-04

0.000075

0.25

3.00E-04

0.0001

0.1

1.00E-03

0.00025

0.075

3.33E-03

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

0.0025

0.0075

3.33E-01

0.005

0.005

1.00E+00

0.0075

0.0025

3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0

E
1.07E+00
1.05E+00
1.04E+00
1.02E+00
1.01E+00
9.93E-01
9.79E-01
9.65E-01
9.50E-01
9.34E-01
9.20E-01
9.06E-01
8.90E-01
8.75E-01
8.61E-01
8.47E-01

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

2)

Cell potentials and equilibrium constans for simple reactions

8.31E-01
8.16E-01
8.02E-01
7.87E-01
7.72E-01

Reaction are O + ne- R

No protons or extra species
Cell
Fe2+/Fe3+//V3+/V2
Fe(CN)63-/Fe(CN)64-//Cr
3+/Cr2+
2V(OH)4+/
TI+/TI3+//2Fe/2Fe3+
Pb2+/Pb//2Ag/2Ag+

[R]
left
1.E+
00

[O]
left
2.E02

E
left
8.E01

nleft

Eleft

[O]
right

1.E+
00

7.E01

2.E-02

1.E+
00

2.E02

4.E01

1.E+
00

3.E01

2.E-02

1.E+0
0

1.E+
00

2.E02

1.E+
00

1.E+0
0

2.E02

9.E01
1.E+
00

2.E-02

1.E+
00

1.E+
00
1.E+
00

E
right
-3.E01
4.E+0
2
-3.E01

2.E-02

2.E+0
0

-4.E02

2.E+0
0

1.E+
00

2.E02

-1.E01

1.E+
00

2.E-02

1.E+0
0

2.E+0
0

1.E+0
0

2.E+
00

-2.E01

[R]
right
1.E+0
0

3)
R=
O=
n=
E0=

Cd2+
Cd
2
-0.403

[R]
1.00E05

[O]

[R]/[O]

1.00E+00

1.00E05

0.0000
25

0.75

3.33E05

0.0000
5

0.5

1.00E04

0.0000
75

0.25

3.00E04

0.0001

0.1

1.00E03

0.0002
5
0.0005

0.075
0.05

3.33E03
1.00E02

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0

Log M

-2.55E-01

1.00E-07

-7

-2.70E-01

1.00E-06

-6

-2.85E-01

1.00E-05

-5

-2.99E-01

1.00E-04

-4

-3.14E-01

1.00E-03

-3

-3.30E-01
-3.44E-01

1.00E-02
1.00E-01

-2
-1

n right
1.E+0
0
1.E+0
0
2.E+0
0

0.0007
5

0.025

0.001

0.01

0.0025

0.0075

0.005

0.005

0.0075

0.0025

0.01

0.001

0.025

0.00075

0.05

0.0005

0.075

0.00025

0.1

0.0001

0.25

0.000075

0.5

0.00005

0.75

0.000025

1.0

0.00001

R=
O=
n=
E0=

Pb2+
Pb

0.0000
25
0.0000
5

1.00E01
3.33E01
1.00E+
00
3.00E+
00
1.00E+
01
3.33E+
01
1.00E+
02
3.00E+
02
1.00E+
03
3.33E+
03
1.00E+
04
3.00E+
04
1.00E+
05

4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

[R]/[O]

log([R]/
[O])

-3.58E-01

1.00E+00

-3.73E-01
-3.89E-01
-4.03E-01
-4.17E-01
-4.33E-01
-4.48E-01
-4.62E-01
-4.76E-01
-4.92E-01
-5.07E-01
-5.21E-01
-5.36E-01
-5.51E-01

2
-0.1262

[R]
1.00E05

3.00E02

0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0

[O]
1.00E+00

1.00E05

0.75

3.33E05

0.5

1.00E04

5.00E+0
0
4.48E+0
0
4.00E+0
0

Log M

2.18E-02

1.00E-07

-7

6.32E-03

1.00E-06

-6

-7.80E-03

1.00E-05

-5

0.0000
75

0.25

3.00E04

0.0001

0.1

1.00E03

0.0002
5

0.075

3.33E03

0.0005

0.05

1.00E02

0.0007
5

0.025

3.00E02

0.001

0.01

0.0025

0.0075

0.005

0.005

0.0075

0.0025

0.01

0.001

0.025

0.00075

0.05

0.0005

0.075

0.00025

0.1

0.0001

0.25

0.000075

0.5

0.00005

0.75

0.000025

1.0

0.00001

R=
O=
n=
E0=
[R]

Hg2 2+
Hg
2
-0.1262
[O]

1.00E01
3.33E01
1.00E+
00
3.00E+
00
1.00E+
01
3.33E+
01
1.00E+
02
3.00E+
02
1.00E+
03
3.33E+
03
1.00E+
04
3.00E+
04
1.00E+
05

[R]/[O]

3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0

-2.19E-02

1.00E-04

-4

-3.74E-02

1.00E-03

-3

-5.29E-02

1.00E-02

-2

-6.70E-02

1.00E-01

-1

-8.11E-02

1.00E+00

-9.66E-02

-4.77E-01
0.00E+0
0

-1.12E-01

4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

-1.40E-01

log([R]/

-1.26E-01

-1.56E-01
-1.71E-01
-1.85E-01
-2.00E-01
-2.15E-01
-2.30E-01
-2.45E-01
-2.59E-01
-2.74E-01

Log M

[O])
1.00E05

1.00E+00

1.00E05

0.0000
25

0.75

3.33E05

0.0000
5

0.5

1.00E04

0.0000
75

0.25

3.00E04

0.0001

0.1

1.00E03

0.0002
5

0.075

3.33E03

0.0005

0.05

1.00E02

0.0007
5

0.025

3.00E02

0.001

0.01

0.0025

0.0075

0.005

0.005

0.0075

0.0025

0.01

0.001

0.025

0.00075

0.05

0.0005

0.075

0.00025

0.1

0.0001

0.25

0.000075

0.5
0.75

0.00005
0.000025

1.00E01
3.33E01
1.00E+
00
3.00E+
00
1.00E+
01
3.33E+
01
1.00E+
02
3.00E+
02
1.00E+
03
3.33E+
03
1.00E+
04
3.00E+

5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0

2.18E-02

1.00E-07

-7

6.32E-03

1.00E-06

-6

-7.80E-03

1.00E-05

-5

-2.19E-02

1.00E-04

-4

-3.74E-02

1.00E-03

-3

-5.29E-02

1.00E-02

-2

-6.70E-02

1.00E-01

-1

-8.11E-02

1.00E+00

-9.66E-02
-1.12E-01
-1.26E-01
-1.40E-01
-1.56E-01
-1.71E-01
-1.85E-01
-2.00E-01
-2.15E-01
-2.30E-01
-2.45E-01
-2.59E-01

1.0

R=
O=
n=
E0=

0.00001

04
1.00E+
05

0
5.00E+0
0

-2.74E-01

half cell potential

Ag+
Ag
1
0.8

[R]
1.00E-05
0.000025
0.00005
0.000075
0.0001
0.00025
0.0005
0.00075
0.001
0.0025
0.005
0.0075
0.01
0.025
0.05
0.075
0.1
0.25
0.5
0.75
1.0

R=
O=
n=
E0=
[R]
1.00E05
0.0000
25
0.0000

[O]
1.00E+00
0.75
0.5
0.25
0.1
0.075
0.05
0.025
0.01
0.0075
0.005
0.0025
0.001
0.00075
0.0005
0.00025
0.0001
0.000075
0.00005
0.000025
0.00001

[R]/[O]
1.00E-05
3.33E-05
1.00E-04
3.00E-04
1.00E-03
3.33E-03
1.00E-02
3.00E-02
1.00E-01
3.33E-01
1.00E+00
3.00E+00
1.00E+01
3.33E+01
1.00E+02
3.00E+02
1.00E+03
3.33E+03
1.00E+04
3.00E+04
1.00E+05

log([R]/[O])
-5.00E+00
-4.48E+00
-4.00E+00
-3.52E+00
-3.00E+00
-2.48E+00
-2.00E+00
-1.52E+00
-1.00E+00
-4.77E-01
0.00E+00
4.77E-01
1.00E+00
1.52E+00
2.00E+00
2.48E+00
3.00E+00
3.52E+00
4.00E+00
4.48E+00
5.00E+00

Sn2+
Sn
2
-0.14
[O]
1.00E+00
0.75
0.5

[R]/[O]

log([R]/[O])

1.00E-05

-5.00E+00

8.00E-03

3.33E-05
1.00E-04

-4.48E+00
-4.00E+00

-7.48E-03
-2.16E-02

E
1.10E+00
1.07E+00
1.04E+00
1.01E+00
9.78E-01
9.47E-01
9.18E-01
8.90E-01
8.59E-01
8.28E-01
8.00E-01
7.72E-01
7.41E-01
7.10E-01
6.82E-01
6.53E-01
6.22E-01
5.91E-01
5.63E-01
5.35E-01
5.04E-01

5
0.0000
75
0.0001
0.0002
5
0.0005
0.0007
5
0.001
0.0025
0.005
0.0075
0.01
0.025
0.05
0.075
0.1
0.25
0.5
0.75
1.0

R=
O=
n=
E0=

0.25
0.1

3.00E-04
1.00E-03

-3.52E+00
-3.00E+00

-3.57E-02
-5.12E-02

0.075
0.05

3.33E-03
1.00E-02

-2.48E+00
-2.00E+00

-6.67E-02
-8.08E-02

3.00E-02
1.00E-01
3.33E-01
1.00E+00
3.00E+00
1.00E+01
3.33E+01
1.00E+02
3.00E+02
1.00E+03
3.33E+03
1.00E+04
3.00E+04
1.00E+05

-1.52E+00
-1.00E+00
-4.77E-01
0.00E+00
4.77E-01
1.00E+00
1.52E+00
2.00E+00
2.48E+00
3.00E+00
3.52E+00
4.00E+00
4.48E+00
5.00E+00

-9.49E-02
-1.10E-01
-1.26E-01
-1.40E-01
-1.54E-01
-1.70E-01
-1.85E-01
-1.99E-01
-2.13E-01
-2.29E-01
-2.44E-01
-2.58E-01
-2.73E-01
-2.88E-01

0.025
0.01
0.0075
0.005
0.0025
0.001
0.00075
0.0005
0.00025
0.0001
0.000075
0.00005
0.000025
0.00001

Al3+
Al
3
-1.66

[R]
1.00E-05

[O]
1.00E+00

[R]/[O]
1.00E-05

0.00002
5

0.75

3.33E-05

0.00005

0.5

1.00E-04

0.00007
5

0.25

3.00E-04

0.0001
0.00025

0.1
0.075

1.00E-03
3.33E-03

log([R]/
[O])
5.00E+0
0
4.48E+0
0
4.00E+0
0
3.52E+0
0
3.00E+0
0
-

E
-1.56E+00
-1.57E+00
-1.58E+00
-1.59E+00
-1.60E+00
-1.61E+00

0.0005

0.05

1.00E-02

0.00075

0.025

3.00E-02

0.001

0.01

1.00E-01

0.0025

0.0075

3.33E-01

0.005
0.0075

0.005
0.0025

1.00E+00
3.00E+00

0.01

0.001

1.00E+01

0.025

0.00075

3.33E+01

0.05

0.0005

1.00E+02

0.075

0.00025

3.00E+02

0.1

0.0001

1.00E+03

0.25

0.000075

3.33E+03

0.5

0.00005

1.00E+04

0.75

0.000025

3.00E+04

1.0

0.00001

1.00E+05

2.48E+0
0
2.00E+0
0
1.52E+0
0
1.00E+0
0
-4.77E01
0.00E+0
0
4.77E-01
1.00E+0
0
1.52E+0
0
2.00E+0
0
2.48E+0
0
3.00E+0
0
3.52E+0
0
4.00E+0
0
4.48E+0
0
5.00E+0
0

-1.62E+00
-1.63E+00
-1.64E+00
-1.65E+00
-1.66E+00
-1.67E+00
-1.68E+00
-1.69E+00
-1.70E+00
-1.71E+00
-1.72E+00
-1.73E+00
-1.74E+00
-1.75E+00
-1.76E+00