Tr.

THPT Chuyen Thang Long E THI CHON HSG

OLIMPIC 30.4
To Hoa! ho"# E SO$ % &
L'(P )0 HO*(
Nga+y ,h-. )/.3.%000
Thi gian lam bai:
180 phut

Cau I (4 iem)
I.1. Theo thuyet VB co ton ta cac phan t sau hay khong? Ga
thch. SF
6
, NF
5
, FI
7
, A
2
C
6
.
I.2. Cho bo bon so ng t cua eectron chot cung tren
nguyen t cua cac nguyen to A, X, Z nh sau:
A: n = 3, = 1, m = - 1, s = -1/2
X: n = 2, = 1, m = - 1, s = -1/2
Z: n = 2, = 1, m = 0, s = +1/2
I.2.1 Vet cau hnh eectron cua X, A, Z va xac nh v tr cua
cac nguyen to X, A, Z trong bang HTTH cac nguyen to hoa hoc.
I.2.2 Vet cong thc cau tao, cho bet trang tha a hoa cua
nguyen t trung tam va cau truc hnh hoc cua cac phan t
va on sau: ZA
2
, AX
2
, AX
3
2-
, AX
4
2-
.
I.2.3 Bang thuyet a hoa ga thch s tao thanh phan t ZX.
Ga thch v sao ZX co kha nang tao phc phc manh v km
oa chuyen tep. Lay Fe va N am v du mnh hoa.
I.2.4 Ga thch v sao AX
3
2-
co kha nang hoa tan A e tao thanh
A
2
X
3
2-
.
Cau II (4 iem)
II.1. Nghen cu ong hoc cua phan ng: NO
2
+ CO CO
2
+
NO
Ng ta thay nhet o tren 500
0
C phng trnh toc o phan
ng co dang:
v = k|NO
2
|.|CO|
Con d 500
0
C phng trnh toc o phan ng co dang: v =
k|NO
2
|
2
.
Hay ga thet c che thch hp cho mo trng hp.
II. 2. Phan ng: 2NO + H
2
2NOH co the theo c che sau:
NO + H
2
` `
``
NOH
2
NOH
2
+ NO 2NOH
Hay thet ap phng trnh ong hoc thc nghem cua phan
ng tren.
II.3. No tan cua Mg(OH)
2
trong nc 12
0
C a 8,2.10
-3
g/ con
70
0
C a 1,2.10
-2
g/.
II.3.1. Tnh tch so tan cua Mg(OH)
2
ha nhet o va pH cua cac
dung dch bao hoa.
1
II.3.2. Tnh cac a ng H
0
298
, G
0
298
va S
0
298
cua phan ng hoa
tan, co H
0
va S
0
khong thay o theo nhet o trong khoang
nhet o ang xet.
Cau III (4 iem)
III.1 Co kha nang hoa tan het 0,01 mo AgSCN trong 0,5 t dung
dch NH
3
1,2M c khong? Cho T
AgSCN
= 1,1.10
-12
va hang so phan
cua phc |Ag(NH
3
)
2
|
+
bang 6.10
-8
.
III.2 Tnh the tch dung dch KOH 1.10
-3
M can cho vao 100 m dung
dch H
3
PO
4
0,01M e thu c dung dch co pH = 7,21.
Bet axt H
3
PO
4
co pK
1
= 2,15; pK
2
= 7,21; pK
3
= 12,32.
III.3 Cho cac ham nhet ong:
Ag
+
(aq)
I
-
(aq)
AgI
(r)
H
0
298
(K|.mo
-1
) + 105,58 - 55,90 - 62,00
S
0
298
(|.mo
-1
) + 72,68 + 109,40 +115,00
III.3.1 Tnh tch so tan cua AgI 298K
III.3.2 Phan ng cua NaI v AgNO
3
trong dung dch tao thanh
ket tua va ga phong nang ng. Ta co the tao ra mot pn
snh cong en nh phan ng o.
Vet cong thc cua pn va cac na phan ng en cc ta
anot va catot. Tnh E
0
298
cua pn.
Cau I1 (4 iem2
Hon hp A gom 3 chat ran Na
2
CO
3
, FeS
2
va K
2
SO
3
. Cho 250 m dung
dch H
2
SO
4
0,77M tac dung het v 21,25 gam hon hp (A) ch co
kh E thoat ra kho bnh phan ng. Cho tep vao bnh phan ng
150 m dung dch BaC
2
th va u, phan ng xong thu c
48,0525 gam chat ran (B) va dung dch (D). Lam kho kh (E) ro
dung ng ox va u ox hoa co xuc tac ta 450
0
C, 1atm th
thu c 16,314 t kh (G).
IV.1 Vet ay u cac phng trnh phan ng xay ra.
IV.2 Tnh kho ng mo chat trong hon hp (A). Bet rang
khong co phan ng ga cac chat trong (E).
Cau 1 (4 iem)
I.1 Chon cac chat thch hp e hoan thanh cac phng trnh
phan ng d ay:
1. X
1
+ X
2
I
2
+ MnI
2
+ H
2
O
2. X
3
+ X
4
+ X
5
HC + H
2
SO
4

3. D
1
+ D
2
+ D
3
C
2
+ MnSO
4
+ K
2
SO
4
+ Na
2
SO
4
+ H
2
O
4. Fe
3
O
4
+ HI E
1
+ E
2
+ E
3
I.2 Tron 1 m dung dch MgC
2
0,02 M v 1m dung dch hon hp
cha NH
3
0,2M va NH
4
C 2M. Co ket tua Mg(OH)
2
xuat hen hay
khong? Bet
NH
3
co pK
b
= 4,76; Mg(OH)
2
co pT = 10,9.
2
I.3 Mot phan ng co nang ng hoat hoa a E = 84K|.mo
-1

25
0
C. Van toc cua phan ng se thay o nh the nao neu
nang ng hoat hoa gam 10 K|.mo
-1
.
I.4 Thc nghem cho bet mot mau a co ty e kho ng
206
Pb :
238
U = 1 : 19. Chu ky ban huy cua
238
U a 4,6.10
9
nam. Hay
tnh tuo cua mau a o.
3