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BI TP PIN IN HA -TH IN CC-CN BNG TRONG IN HA

IN PHN
Bi 1 : . Cho hai na pin vi cc th chun :
Fe 2+ +2e Fe,E 0 =-0,44V
Cu 2+ +2e Cu,E 0 =0,34V
Thit lp s pin in , tnh E0 ca pin, v cho bit chiu ca phn ng.
Bi 2 : Cho 2 na pin sau : Zn/ Zn(NO 3)2 0,1 M , Ag / AgNO 3 0,1 M c th chun tng ng bng -0,76 V,
0,8 V.
a. Thit lp s pin vi du cc in cc .
b. Vit phn ng khi pin hot ng
c. Tnh E ca pin.
d. Tnh nng cc ion khi pin ngng hot ng .
Bi 3 : E0 pin Zn-Cu l 1,10 V 25 0C. Tnh nng lng t do chun ca phn ng xi ha kh lm c s
cho pin.
A : -212 KJ
Bi 4 : Cho phn ng sau : Pb (r) + 2Ag + Pb2+ + 2Ag (r) . Tnh hng s cn bng K v G0 250C.Bit :

E 0Ag+ /Ag =0,8V,E 0Pb2+ /Pb =-0,13V


A : K = 2,6.1031 , G0 = 1,8.102 KJ
0
0
3+
2+
Bi 5 : Tnh K ca phn ng sau : 2Fe +2I 2Fe +I 2 , bit : E Fe3+ /Fe2+ =0,77V,E I2 /2I- =0,77V
A : K = 9,3. 107
Bi 6 : Tnh th ca bn phn ng : Tl3+ + 3e Tl(r)
0
0
Bit : E Tl+ /Tl =-0,336V,E Tl3+ /Tl+ =1,25V
A : 0,72 V
Bi 7 : Cho s sau : MnO
4

Mn IV

1,70V

1,20V

Mn 2+

-1,18V

Mn .Tnh th in cc chun ca bn

+
2+
phn ng sau : MnO 4 +8H +5e Mn +4H 2 O
A : 1,5 V
Bi 8 : Vng trng thi s oxh = + 1 c t phn hy theo s phn ng sau khng?
3Au + 2Au+Au 3+ , bit : Au 3+ 1,41V
Au + 1,68V Au .
A : E0phn ng l : 0,27 V=> t xy ra

Bi 9 : Cho cc s sau : MnO


4
-

TcO
4

0,7V

2 TcO
4

Re O
4

0,7V

2
Re O
4

Mn IV

1,70V

0,8V

TcO 2

0,3V

Tc

0,4V

Re O2

0,3V

Re

a. Tnh th in cc chun ca cc cp :

1,20V

Mn 2+

-1,18V

0
0
E 0MnO- /Mn 2+ ;E TcO
;E
/TcO
ReO- /ReO
4

Mn

b. Xt trng thi xi ha no ca Mn, Tc, Re c kh nng t phn hy. Vit phng trnh phn ng,
tnh th ca phn ng.
c. Ion MO 4 ( M= Mn, Tc, Re) no c kh nng xi ha mnh nht?
d. Zn c y c Mn2+ ra khi dung dch mui ca n khng ?
A : a. 1,5 V; 0,76 V ; 0,50 V b. ch c TcO 4 xy E = 0,10 V. c. MnO 4 mnh nht 1,7 V d. E= -0,42 V
Bi 10 : . Cho cc bn phn ng sau:
MnO-4 +8H + +5e Mn 2+ +4H 2 O;E 0 =1,51V
MnO 2 +4H + +2e Mn 2+ +2H 2 O;E 0 =1,23V
Xc nh E0 ca bn phn ng sau:
MnO-4 +4H + +3e MnO 2 +2H 2 O.

Bi 11 : Vit cc phng trnh phn ng xy ra khi trn ln ba dd sau vi nhau:


25 ml dd Fe(NO3)2 0,1 M , 25 ml dd Fe(NO3)3 1 M , 50 ml AgNO3 0,6 M, trong c th mt mnh Ag vn
0
0
. Bit : E Ag / Ag 0,8V ; EFe3 / Fe2 0,77V .
0
0
10
Bi 12: Cho : E Ag / Ag 0,8V ; ECu 2 / Cu 0,34V , TAgCl 1,8.10 .Tnh th in cc Ag/AgCl, KCl khi

Cl 1,0 M . Xc nh chiu ca dng in trong pin to thnh bi in cc ny v in cc ng tiu


chun . Vit phng trnh ca phn ng ny xy ra trong pin v tnh hng s cn bng ca phn ng .
15. Xc nh Tt ca AgBr , bit rng pin c to thnh bi in cc hydro tiu chun v in cc
0
Ag/AgBr, Br- (0,1 M ) c sc in ng bng 0,14 V. Cho : E Ag / Ag 0,8V .
Bi 13 : Hai cc 1 , 2 cha cc dd vi nng ca cc ion nh sau: - cc 1:
Fe3 0, 2M ; Fe 2 0,1M
3
2
0, 2M .
-cc 2 : Fe 0,1M ; Fe
a.Nhng vo 2 dd hai thanh Pt v ni 2 dd bng mt cu mui . Xc nh sc in ng ca pin.
b. Ni 2 in cc bng dy dn , tnh nng ca cc ion Fe 2+, Fe3+ trong mi cc ng 1 lt dd th in
lng i qua dy dn l bao nhiu ?
Bi 14 : . Xc nh sc in ng ca pin tiu chun c to thnh bi cc in cc : Sn 2 / Sn; Pb 2 / Pb .
2
2
105 M th sc in ng ca pin l bao nhiu ? Bit :
Nu : Sn 1M ; Pb
0
0
ESn
0,14V ; EPb
0,126V .
2
2
/ Sn
/ Pb

Bi 15: Tnh th ca cp Ag+/Ag so vi cp Cu2+/Cu ca nng ca Ag+ v Cu2+ tng ng bng 4,2.10-6
0
0
v 1,3.10-3M. Tnh G khi 1 mol e trao i iu kin cho. Bit E Ag / Ag 0,8V ; ECu 2 / Cu 0,34V .
Bi 16: Cho cc phn ng: S + 2H++2e H2S ; E0 = -0,14 V.
SO2 + 4H++ 4e S + 2H2O ; E0 = 0,45 V. Tnh K cn bng ca phn ng : SO2 + 2H2S 3S + 2H2O.
B i 17 : Mt pin in c hnh thnh t 2 in cc . Mt n cc gm 1 tm Cu nhng trong dd CuSO 4
2
3
0,50 M . in cc th hai gm 1 thanh Pt nhng vo dd Fe 2+, Fe3+ vi lng sao cho Fe 2 Fe
.Dng mt dy dn ni 2 u thanh Cu v Pt .
a. Cho bit du cc in cc ca pin. Vit cc phn ng in cc .Tnh sc in ng ban u ca pin. Bit
th tch dd CuSO4 kh ln.
Fe3
b. Tnh t s
khi pin ngng hot ng. cho : Fe3 / Fe 2 0,77V , Cu 2 / Cu 0,34V .
Fe3
Bi 18: Cho 2 na pin sau : Zn/ Zn(NO3)2 0,1 M , Ag / AgNO3 0,1 M c th chun tng ng bng -0,76 V,
0,8 V.
a. Thit lp s pin vi du cc in cc .
b. Vit phn ng khi pin hot ng
c. Tnh E ca pin.
d. Tnh nng cc ion khi pin ngng hot ng .
0
0
Bi 19: Tnh Tt ca AgCl 250C bit : E Ag / Ag 0,80V ; E AgCl / Ag 0,22V .
Bi 20: Tnh hng s cn bng ca phn ng: Cu + Br 2 Cu2+ + 2Br- . Bit Cu 2 / Cu 0,34V ,
0
EBr
1,09V .
/ Br
2

Bi 21: in phn dd SnCl2 1 M vi 2 in cc bng Pt trn nhn. Vit cc phn ng xy ra trn cc in


0
0
cc. Tnh sc in ng phn cc bit : ESn2 / Sn 0,14V ; ECl2 / Cl 1,36V .
in phn c th xy ra th th phn hy bng bao nhiu ?
0
0
7
Bi 22: Cho bit : ECu 2 / Cu 0,16V ; ECu / Cu 0,52V ; TCuCl 1,0.10 .Mt dd cha CuSO4 0,10 M , NaCl
0,20 M v bt Cu d. Phn ng sau c xy ra khng : Cu (r) + Cu 2+ + 2Cl- 2CuCl . Tnh hng s cn
bng ca phn ng v tnh nng mol cc ion trng thi cn bng.

Bi 23: Cho phn ng sau : Pb 2+ + 2Cr2+ 2Cr3+ + Pb ; E0 = 0,28 V.Tnh E ca phn ng ,bit:
[Pb2+]=[Cr2+] = 0,1 M; [Cr3+] = 0,01 M .
A : - 0,04 V.
Bi 24 : Tnh E ca pin gm in cc Zn2+/ Zn v 2H+/H2 iu kin sau : [Zn2+] = 0,01 M, [H+] = 2,5 M;
p sut kh hydro l 0,3 atm. E0Zn2+/ Zn = -0,76 V.
A : 0,86 V
Bi 25 : Cho phn ng sau: Ag (r) + H + (aq) + I-(aq) AgI (r) + 1/2H2 (k) ; trng thi chun. Phn ng
0
-17
c xy ra khng? Bit : E Ag+ /Ag =0,8V,TAgI =8,3.10 .
0

0
A : Phn ng xy ra do E AgI/Ag =-0,15V < E 2H + /H 2 =0,0V

Bi 26: Cho phn ng sau : 2Ag + 4HCN 2H[Ag(CN)2] + H2


0
Bit : Ag+ + 2CN- [Ag(CN)2]- ; Kb = 7.1019 , nng cc cht 1 M , E Ag + /Ag =0,80V
0
0
A : E Ag(CN)2- /Ag =-0,37V < E 2H + /H 2 =0,0V , phn ng xy ra .

Bi 27 : Trn 10 ml dung dch SnCl2 0,1 M vi 10 ml dung dch FeCl3 0,1 M. Xc nh thnh phn cht tan
trong dung dch ca h ti cn bng. T suy ra th xi ha kh cc cp trong dung dch
A : nng thic II = nng thit IV = 0,025 M. nng st II = 0,05 M; nng st III = 2,3.10-12 M .
Ecb = 0,15 V
Bi 28: Nhng mt si Ag vo dung dch Fe 2 (SO4)3 0,05 M. Xc nh thnh phn cui ca h. T suy ra
th in cc ca cc cp trong dung dch.
A : K = 0,32 , nng cc ion st II v bc = 0,08 M ,ion st III = 0,02 M. Ecb = 0,72 V
0
E 0Fe3+ /Fe2+ =0,77V;E Sn
=0,15V;E 0Ag+ /Ag =0,80V .
4+
/Sn 2+
0
0
Bi 29 : Tnh hng s cn bng ca phn ng kh H2S bng Fe3+ . Cho E Fe3+ /Fe2+ =0,77V ; E S /S2- =-0,48V
i vi H2S c pK1 = 7,02 ; pK2 = 12,9 .
A : 1022,5
0
0
-12
Bi 30 : nh gi kh nng phn ng gia Cu2+ v I-.Cho E Cu 2+ /Cu =0,34V ; E I3- /3I- =0,5355V ; TCuI =10 .

E 0Cu 2+ /Cu + =0,153V


0
0
0
0
A: Tnh E Cu 2+ /CuI so snh vi E I3- /3I- =0,5355V . Thy E Cu 2+ /CuI > E I3- /3I- =0,5355V ,nn Cu2+ xi ha d dng I-

to I3 v CuI.
Bi 31 : nh gi thnh phn cn bng trong hn hp gm Ag + 10-3M, NH3 1 M v Cu. Cho hng s bn
0
0
+
7,24
2+
12,03
cc phc : Ag(NH3 ) 2 =10 ; Cu(NH 3 ) 4 =10 ; E Cu 2+ /Cu =0,337V ; E Ag+ /Ag =0,8V , 250C
A : Tnh K ca phn ng 2Ag+ + Cu 2 Ag + Cu2+ pK = 15,61.
+
7,24
Vi hng s khng bn (phn ly ca phc Ag(NH 3 )2 =10 ), phn ng to phc bn ca Cu2+, ri t hp
+
2+
3 qu trnh . Tnh thnh phn cc cht ti cn bng t hp. Vy Ag(NH 3 )2 = 5,9.10-9 M. Cu(NH 3 ) 4 = 5.10-4
0
0
Bi 32 : Cho : E Au3+ /Au =1,5V ; E Au + /Au =1,68V .Tnh :
a. Nng mol Au+ ln nht trong dung dch Au3+ 0,001 M
b. Trong dung dch c d ion X-, Au+ to phc AuX 2 c hng s khng bn K1, Au3+ to phc AuX 4
c hng s khng bn K2 ,d ion X- c cn bng sau : 3AuX 2 AuX 4 +2X +2Au;K' . Vit biu
thc tnh K theo K1 , K2 ,K. Bit X- l : Br- , pK1 = 12 , pK2 = 32; CN- , pK1 = 38 , pK2 = 56 . Da
vo tnh ton a ra kt lun g ?
c. Vng c th tan trong dung dch KCN 1 M c bo ha kh oxi. Da vo kt qu tnh c, gii thch
0
hin tng ny ( pH = 0, E O2 /H 2O =1,23V , HCN c pK = 9,4 , p sut O 2 = 1 atm, lc cn bng
nng [Au(CN) 2 ]=1M )
A : a. 3 Au+ Au3+ + 2Au c lg K = 9,317. [Au+] = 9.10-5.
b. X- = Br- c K = 1,37.105 ; X- = CN- c 1,37. 10-49. khi Au+ to phc th n t tham gia phn ng oxi ha
kh

0
0
c. tnh nng ion CN - ti cn bng, E Au(CN)-2 /Au =-0,566V ; E O2 /H 2O =0,539V ; E Au(CN)-2 /Au =-0,566V <

E O2 /H 2O =0,539V , Au c th tan trong dung dch KCN theo phn ng ha hc sau :


4Au + 8 KCN + 2H2O + O2 4K[Au(CN)2 + 4 KOH
Bi 33 : Cho 4 g PbSO4 nguyn cht vo 150 ml nc n khi cn bng c thit lp ,nhng vo mt
in cc Pb v mt in cc i chiu c E0 = 0,237 V. 298K c mt hiu in th 0,478 V.
a. Cho bit in cc no trong 2 in trn c th ln hn. in cc no l catot, anot. Tnh TPbSO4 .Bit
E 0Pb2+ /Pb =-0,126V
b.

Cho PbSO4 nguyn cht vo 150 ml dung dch H 2SO4 c pH = 3 . Th hiu in th gia in cc
Pb v in cc i chiu. Ti mt nhit c nh th TPbSO4 = 1,1. 10-8

2-1
Cho : PbSO 4 (r)+2I PbI 2 +SO 4 ;K1 =4,6.10

PbI 2 +CrO 42- PbCrO 4 +2I - ;K 2 =4,3.1012


PbS+CrO 2-4 PbCrO 4 (r)+S2- ;K 3 =7,5.10-8
c. Tnh tch s tan ca PbS.
C 2+
0, 059
log Pb => nng mol Pb2+ =1,288.10-4.
2
1
-8
2+
-5
TPbSO4 =1,66.10 . pH = 3 nng Pb = 3,318.10 . T phng trnh Nec tnh E = E/ch - E Pb2+ /Pb = 0,495 V
TPbS = 4,2.10-28 .
Bi 34: Tnh nng ban u ca HSO4- , bit khi o sut in ng ca pin Pt/I- 0,1 M ; I3 0,02 M//
0
A : E Pb2+ /Pb =-0,241V , mt khc : E Pb2+ /Pb =E 0Pb2+ /Pb

MnO-4 0,05 M , Mn2+ 0,01 M, HSO4- C (M) 25 0C c gi tr l 0,824 V.


0
0
-2
Bit : E MnO-4 =1,51V;E I3- =0,5355V;K HSO4- =10 .
A : 0,364 M. Tnh th in cc tng cp xi ha- kh theo iu kin phn ng . tnh c [H +] = 0,054 M
. T cn bng HSO4- tnh c nng HSO4- ban u.
Bi 35 : a. Thit lp mt pin theo phn ng sau : Pb (r) + CuBr2 (dd) 0,01 M PbBr2 (r) + Cu (r).
0
b. Nu 250C sut in ng ca pin l 0,442 V, th TPbBr2 bng bao nhiu? E Pb2+ /Pb =-0,126V ,

E 0Cu 2+ /Cu =0,34V .


A : a. (-) Pb/ PbBr2(r) , Br- // CuBr2 / Cu (+) .
b. tnh E ca cc in cc theo iu kin c . Lp biu thc tnh E ca pin , suy ra TPbBr2 = 2,5.10-5
Bi 36 : 1. Phn ng gia AgNO3 vi KCl trong dung dch to thnh kt ta AgCl v gii phng nng
lng. Ta c th to ra mt t bo in ho (pin) sinh cng in nh phn ng .
a) Vit cng thc ca t bo in ho theo quy tc IUPAC v cc na phn ng in cc ti anot v catot.
0
0
b) Tnh G298 ca phn ng kt ta AgCl v E 298 ca t bo in ho.
Cho: TAgCl 250C bng 1,6. 10 10 .
2. in phn 50 ml dung dch HNO3 c pH = 5,0 vi in cc than ch trong 30 gi, dng in 1A.
a) Vit na phn ng ti cc in cc v phng trnh phn ng chung.
b) Tnh pH ca dung dch sau khi in phn.
c) Tnh th tch dung dch NaOH 0,0001 mol/L cn trung ha dung dch sau khi in phn.
d) Hy cho bit nn dng cht ch th no xc nh im dng ca phn ng trung ha.
Coi khi lng ring ca dung dch HNO3 long l 1 g/ml

A : 1.
a) Na phn ng oxi ho anot:
Na phn ng kh catot:

Ag e + Cl AgCl
Ag+ + e
Ag .
Ag+ +

Cl

AgCl (r)

Cng thc ca t bo in ho:


(Anot) Ag dd KCl
dd AgNO3 Ag
0
0
b) Tnh G298 v E 298 :
Xt phn ng Ag + Cl AgCl (r)
1
1
Kc =
=
= 6,25.109
TAgCl
1,6.1010

(Catot)

G2098 = RTlnKc = 8,314 298 ln (6,25.109) = 55884 J/mol = 55,884 kJ/mol


55884
G0
0
E 298 =
=+
= + 0,5792 (V) + 0,58 V
1 96487
nF
2.
1
a) Na phn ng oxi ho anot: H2O - 2e 2H+ +
O2
2
Na phn ng kh catot:
2H+ + 2 e H2 .
1
H2O H2 +
O2
2
S mol nc b in phn l 0,556 mol.
Khi lng nc b in phn: 0,556 mol x 18 g/mol = 10,074 g
Khi lng dung dch trc khi in phn l 50 ml
Khi lng dung dch sau khi in phn l 50 - 10,074 = 39,926 (g) ~ 40 g
40 g
Th tch dung dch sau khi in phn l: V =
= 40 ml = 0,04 L
1 g/mL
S mol HNO3 = 0,051 x 10-5 = 5. 10-7 (mol)
5.107 mol
+
CHNO3 = [H ] =
= 1,25 . 10-5 M
0,04 L
+
pH = lg [H ] = lg (1,25. 10-5) = 4,903 ~ 4,9
c) Phn ng: NaOH + HNO3 = NaNO3 + H2O
nNaOH = nHNO3 = 5 . 10-7 mol
V ddNaOH = 5. 10-3 L = 0,005 L = 5 mL
d) Phn ng xy ra gia axit mnh v baz mnh nn c th dng cht ch th l phenolphtalein c khong
chuyn mu (pH) 8 - 10.
Bi 37: Dung dch A gm AgNO3 0,050 M v Pb(NO3)2 0,100 M.
1. Tnh pH ca dung dch A.
2. Thm 10,00 ml KI 0,250 M v HNO3 0,200 M vo 10,00 ml dung dch A. Sau phn ng ngi ta nhng
mt in cc Ag vo dung dch B va thu c v ghp thnh pin (c cu mui tip xc hai dung dch) vi
mt in cc c Ag nhng vo dung dch X gm AgNO3 0,010 M v KSCN 0,040 M.
a) Vit s pin .
b) Tnh sc in ng E pin ti 250C .
c) Vit phng trnh phn ng xy ra khi pin hot ng.
d) Tnh hng s cn bng ca phn ng .
Cho bit : Ag+ + H2O
AgOH + H+ (1) ; K1= 10 11,70
Pb2+ + H2O
PbOH+ + H+ (2) ; K2= 10 7,80
Ch s tch s tan pKs : AgI l 16,0 ; PbI2 l 7,86 ; AgSCN l 12,0 .
RT
0
ln = 0,0592 lg
EAg
;
=
0
,799
V
+
F
/Ag

3. Epin s thay i ra sao nu: a) thm mt lng nh NaOH vo dung dch B ; b) thm mt lng nh
Fe(NO3)3 vo dung dch X?
A :
1. Ag+ + H2O AgOH + H+ ; K1 = 10-11,7
(1)
2+
+
+
-7,8
Pb + H2O ? PbOH + H
; K2 = 10
(2)
Do K2 >> K1 nn cn bng 2 quyt nh pH ca dung dch
Pb2+ + H2O
PbOH + H+ ; K2 = 10-7,8 (2)
C
0,10

0,10 x
x
x
x2
10 7 ,8
0,1 x

x = 10-4,4 = H+

pH = 4,40

2.a) Dung dch B: Thm KI : CAg+ = 0,025 M; CPb2+ = 0,050


CI- = 0,125M ; CH+ = 0,10M
Ag+
+
I
AgI
0,025
0,125
0,10
2+
Pb
+
2 I
PbI2
0,05
0,10
Trong dung dch c ng thi hai kt ta AgI v PbI2
AgI
Ag+ + I ;
Ks1 = 1.10-16 (3)
PbI2
Pb2+ + 2 I ;
Ks2 = 1.10-7,86 (4)
Ks1 << Ks2, vy trong dung dch cn bng (4) l ch yu. S to phc
hiroxo ca Pb2+ l khng ng k v c H+ d:
Pb2+ + H2O PbOH + H+ ; K2 = 10-7,8
PbOH 10 7,8

10 6,8 PbOH Pb 2
2
1
Pb
10
Trong dung dch
PbI2
Pb2+ + 2 I
Ks2 = 1.10-7,86
x
2x
2
-7,86
-3
(2x) x = 10
x = 1,51.10 M
2x = [I] = 2,302 . 10-3M

.10
Ag KI 31,02
.10

s1

16
3

3,31.10 14 M .

E ca cc Ag trong dung dch A: Ag+ + e ? Ag


E 1 E 0Ag 0,0592 lg Ag 0,799 0,0592 lg 3,31.10 14
Ag

E 1 0,001V
Dung dch X: Ag+ + SCN AgSCN ;
1012,0
0,010
0,040
0,030
0,010
+
AgSCN
Ag
+ SCN
;
10-12,0
0,030
x
(0,030 + x)
x0,030 + x) = 10-12
12
Ag x 310
3,33.10 11
2
x10

E 2 0,799 0,0592 lg Ag 0,799 0,0592 lg 3,33.10 11


E 2 0,179V

V E2 > E1 , ta c pin gm cc Ag trong X l cc + , cc Ag trong B l cc

S pin:
(-) Ag

b)

AgI
PbI2

AgSCN
SCN 0,03 M

Ag (+)

Epin = 0,179 0,001 = 0,178V

c) Phng trnh phn ng: Ag + I

AgI + e

AgSCN + e
Ag + SCN
AgSCN + I ? Ag + SCN
d)

K = KsAgSCN

KsAgI

12
= 1016

10

= 104

3. a) Khi thm lng nh NaOH vo dung dch B , c th xy ra 3 trng hp:


- Lng NaOH qu t khng trung ho HNO 3: S to phc hiroxo ca Pb2+ vn
khng ng k, do Epin khng thay i.
- Lng NaOH trung ho HNO 3: C s to phc hiroxo ca Pb 2+ do Pb2+ gim,
Nng I - s tng ln, do nng Ag+ gim xung, E1 gim ; vy Epin tng.
- Lng NaOH d trung ho ht HNO3 v ho tan PbI2 to thnh PbO2, do Pb2+
gim v Epin tng.
PbI2 + 4 OH

PbO2 + 2 H2O + 2 I
3+
3+
b) Thm t Fe vo dung dch X:
Fe
+ SCN FeSCN2+
Nng ion SCN gim, do nng ion Ag+ tng, E2 tng
Epin tng
Bi 38 : pH = 0 v 25oC th in cc tiu chun Eo ca mt s cp oxi ho - kh c cho nh sau:
2IO4/ I2 (r) 1,31 V ; 2IO3/ I2 (r) 1,19 V ; 2HIO/ I2 (r) 1,45 V ; I2 (r)/ 2I 0,54 V.
(r) ch cht trng thi rn.
1. Vit phng trnh na phn ng oxi ho - kh ca cc cp cho.
2. Tnh Eo ca cc cp IO4/ IO3 v IO3/ HIO
3. V phng din nhit ng hc th cc dng oxi ho - kh no l bn, cc dng no l khng bn? Ti
sao?
4. Thm 0,40 mol KI vo 1 lt dung dch KMnO4 0,24 M pH = 0
a) Tnh thnh phn ca hn hp sau phn ng.
b) Tnh th ca in cc platin nhng trong hn hp thu c so vi in cc calomen bo ho.
5. Tnh Eo ca cp IO3/ I2(H2O).
I2(H2O) ch it tan trong
nc.
0
Cho bit: E MnO-4 /Mn 2+ =1,51V ; E ca in cc calomen bo ho bng 0,244 V ;

RT ln = 0,0592 lg ; tan ca it trong nc bng 5,0.10 4 M.


25oC,
F
A :
2. 1,125 V

0
3. V E IO3 / HIO < Eo HIO/ I2 ; nn HIO s t oxi ho - kh
Vy dng km bn nht v mt nhit ng hc l HIO, cc dng khc: IO4, IO3,
I2, I u bn pH = 0.
4. a . Thnh phn hn hp sau phn ng: IO3 0,16 M ; Mn2+ 0,24 M ;
104M ; I2 (r) 0,12 M ; pH = 0.
b. E so vi in cc calomen bo ho: 1,18 0,244 = 0,936 V
5. 1,17 V

I2 (H2O) 5.

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