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Bi 1 : . Cho hai na pin vi cc th chun :
Fe 2+ +2e Fe,E 0 =-0,44V
Cu 2+ +2e Cu,E 0 =0,34V
Thit lp s pin in , tnh E0 ca pin, v cho bit chiu ca phn ng.
Bi 2 : Cho 2 na pin sau : Zn/ Zn(NO 3)2 0,1 M , Ag / AgNO 3 0,1 M c th chun tng ng bng -0,76 V,
0,8 V.
a. Thit lp s pin vi du cc in cc .
b. Vit phn ng khi pin hot ng
c. Tnh E ca pin.
d. Tnh nng cc ion khi pin ngng hot ng .
Bi 3 : E0 pin Zn-Cu l 1,10 V 25 0C. Tnh nng lng t do chun ca phn ng xi ha kh lm c s
cho pin.
A : -212 KJ
Bi 4 : Cho phn ng sau : Pb (r) + 2Ag + Pb2+ + 2Ag (r) . Tnh hng s cn bng K v G0 250C.Bit :
Mn IV
1,70V
1,20V
Mn 2+
-1,18V
Mn .Tnh th in cc chun ca bn
+
2+
phn ng sau : MnO 4 +8H +5e Mn +4H 2 O
A : 1,5 V
Bi 8 : Vng trng thi s oxh = + 1 c t phn hy theo s phn ng sau khng?
3Au + 2Au+Au 3+ , bit : Au 3+ 1,41V
Au + 1,68V Au .
A : E0phn ng l : 0,27 V=> t xy ra
TcO
4
0,7V
2 TcO
4
Re O
4
0,7V
2
Re O
4
Mn IV
1,70V
0,8V
TcO 2
0,3V
Tc
0,4V
Re O2
0,3V
Re
a. Tnh th in cc chun ca cc cp :
1,20V
Mn 2+
-1,18V
0
0
E 0MnO- /Mn 2+ ;E TcO
;E
/TcO
ReO- /ReO
4
Mn
b. Xt trng thi xi ha no ca Mn, Tc, Re c kh nng t phn hy. Vit phng trnh phn ng,
tnh th ca phn ng.
c. Ion MO 4 ( M= Mn, Tc, Re) no c kh nng xi ha mnh nht?
d. Zn c y c Mn2+ ra khi dung dch mui ca n khng ?
A : a. 1,5 V; 0,76 V ; 0,50 V b. ch c TcO 4 xy E = 0,10 V. c. MnO 4 mnh nht 1,7 V d. E= -0,42 V
Bi 10 : . Cho cc bn phn ng sau:
MnO-4 +8H + +5e Mn 2+ +4H 2 O;E 0 =1,51V
MnO 2 +4H + +2e Mn 2+ +2H 2 O;E 0 =1,23V
Xc nh E0 ca bn phn ng sau:
MnO-4 +4H + +3e MnO 2 +2H 2 O.
Bi 15: Tnh th ca cp Ag+/Ag so vi cp Cu2+/Cu ca nng ca Ag+ v Cu2+ tng ng bng 4,2.10-6
0
0
v 1,3.10-3M. Tnh G khi 1 mol e trao i iu kin cho. Bit E Ag / Ag 0,8V ; ECu 2 / Cu 0,34V .
Bi 16: Cho cc phn ng: S + 2H++2e H2S ; E0 = -0,14 V.
SO2 + 4H++ 4e S + 2H2O ; E0 = 0,45 V. Tnh K cn bng ca phn ng : SO2 + 2H2S 3S + 2H2O.
B i 17 : Mt pin in c hnh thnh t 2 in cc . Mt n cc gm 1 tm Cu nhng trong dd CuSO 4
2
3
0,50 M . in cc th hai gm 1 thanh Pt nhng vo dd Fe 2+, Fe3+ vi lng sao cho Fe 2 Fe
.Dng mt dy dn ni 2 u thanh Cu v Pt .
a. Cho bit du cc in cc ca pin. Vit cc phn ng in cc .Tnh sc in ng ban u ca pin. Bit
th tch dd CuSO4 kh ln.
Fe3
b. Tnh t s
khi pin ngng hot ng. cho : Fe3 / Fe 2 0,77V , Cu 2 / Cu 0,34V .
Fe3
Bi 18: Cho 2 na pin sau : Zn/ Zn(NO3)2 0,1 M , Ag / AgNO3 0,1 M c th chun tng ng bng -0,76 V,
0,8 V.
a. Thit lp s pin vi du cc in cc .
b. Vit phn ng khi pin hot ng
c. Tnh E ca pin.
d. Tnh nng cc ion khi pin ngng hot ng .
0
0
Bi 19: Tnh Tt ca AgCl 250C bit : E Ag / Ag 0,80V ; E AgCl / Ag 0,22V .
Bi 20: Tnh hng s cn bng ca phn ng: Cu + Br 2 Cu2+ + 2Br- . Bit Cu 2 / Cu 0,34V ,
0
EBr
1,09V .
/ Br
2
Bi 23: Cho phn ng sau : Pb 2+ + 2Cr2+ 2Cr3+ + Pb ; E0 = 0,28 V.Tnh E ca phn ng ,bit:
[Pb2+]=[Cr2+] = 0,1 M; [Cr3+] = 0,01 M .
A : - 0,04 V.
Bi 24 : Tnh E ca pin gm in cc Zn2+/ Zn v 2H+/H2 iu kin sau : [Zn2+] = 0,01 M, [H+] = 2,5 M;
p sut kh hydro l 0,3 atm. E0Zn2+/ Zn = -0,76 V.
A : 0,86 V
Bi 25 : Cho phn ng sau: Ag (r) + H + (aq) + I-(aq) AgI (r) + 1/2H2 (k) ; trng thi chun. Phn ng
0
-17
c xy ra khng? Bit : E Ag+ /Ag =0,8V,TAgI =8,3.10 .
0
0
A : Phn ng xy ra do E AgI/Ag =-0,15V < E 2H + /H 2 =0,0V
Bi 27 : Trn 10 ml dung dch SnCl2 0,1 M vi 10 ml dung dch FeCl3 0,1 M. Xc nh thnh phn cht tan
trong dung dch ca h ti cn bng. T suy ra th xi ha kh cc cp trong dung dch
A : nng thic II = nng thit IV = 0,025 M. nng st II = 0,05 M; nng st III = 2,3.10-12 M .
Ecb = 0,15 V
Bi 28: Nhng mt si Ag vo dung dch Fe 2 (SO4)3 0,05 M. Xc nh thnh phn cui ca h. T suy ra
th in cc ca cc cp trong dung dch.
A : K = 0,32 , nng cc ion st II v bc = 0,08 M ,ion st III = 0,02 M. Ecb = 0,72 V
0
E 0Fe3+ /Fe2+ =0,77V;E Sn
=0,15V;E 0Ag+ /Ag =0,80V .
4+
/Sn 2+
0
0
Bi 29 : Tnh hng s cn bng ca phn ng kh H2S bng Fe3+ . Cho E Fe3+ /Fe2+ =0,77V ; E S /S2- =-0,48V
i vi H2S c pK1 = 7,02 ; pK2 = 12,9 .
A : 1022,5
0
0
-12
Bi 30 : nh gi kh nng phn ng gia Cu2+ v I-.Cho E Cu 2+ /Cu =0,34V ; E I3- /3I- =0,5355V ; TCuI =10 .
to I3 v CuI.
Bi 31 : nh gi thnh phn cn bng trong hn hp gm Ag + 10-3M, NH3 1 M v Cu. Cho hng s bn
0
0
+
7,24
2+
12,03
cc phc : Ag(NH3 ) 2 =10 ; Cu(NH 3 ) 4 =10 ; E Cu 2+ /Cu =0,337V ; E Ag+ /Ag =0,8V , 250C
A : Tnh K ca phn ng 2Ag+ + Cu 2 Ag + Cu2+ pK = 15,61.
+
7,24
Vi hng s khng bn (phn ly ca phc Ag(NH 3 )2 =10 ), phn ng to phc bn ca Cu2+, ri t hp
+
2+
3 qu trnh . Tnh thnh phn cc cht ti cn bng t hp. Vy Ag(NH 3 )2 = 5,9.10-9 M. Cu(NH 3 ) 4 = 5.10-4
0
0
Bi 32 : Cho : E Au3+ /Au =1,5V ; E Au + /Au =1,68V .Tnh :
a. Nng mol Au+ ln nht trong dung dch Au3+ 0,001 M
b. Trong dung dch c d ion X-, Au+ to phc AuX 2 c hng s khng bn K1, Au3+ to phc AuX 4
c hng s khng bn K2 ,d ion X- c cn bng sau : 3AuX 2 AuX 4 +2X +2Au;K' . Vit biu
thc tnh K theo K1 , K2 ,K. Bit X- l : Br- , pK1 = 12 , pK2 = 32; CN- , pK1 = 38 , pK2 = 56 . Da
vo tnh ton a ra kt lun g ?
c. Vng c th tan trong dung dch KCN 1 M c bo ha kh oxi. Da vo kt qu tnh c, gii thch
0
hin tng ny ( pH = 0, E O2 /H 2O =1,23V , HCN c pK = 9,4 , p sut O 2 = 1 atm, lc cn bng
nng [Au(CN) 2 ]=1M )
A : a. 3 Au+ Au3+ + 2Au c lg K = 9,317. [Au+] = 9.10-5.
b. X- = Br- c K = 1,37.105 ; X- = CN- c 1,37. 10-49. khi Au+ to phc th n t tham gia phn ng oxi ha
kh
0
0
c. tnh nng ion CN - ti cn bng, E Au(CN)-2 /Au =-0,566V ; E O2 /H 2O =0,539V ; E Au(CN)-2 /Au =-0,566V <
Cho PbSO4 nguyn cht vo 150 ml dung dch H 2SO4 c pH = 3 . Th hiu in th gia in cc
Pb v in cc i chiu. Ti mt nhit c nh th TPbSO4 = 1,1. 10-8
2-1
Cho : PbSO 4 (r)+2I PbI 2 +SO 4 ;K1 =4,6.10
A : 1.
a) Na phn ng oxi ho anot:
Na phn ng kh catot:
Ag e + Cl AgCl
Ag+ + e
Ag .
Ag+ +
Cl
AgCl (r)
(Catot)
3. Epin s thay i ra sao nu: a) thm mt lng nh NaOH vo dung dch B ; b) thm mt lng nh
Fe(NO3)3 vo dung dch X?
A :
1. Ag+ + H2O AgOH + H+ ; K1 = 10-11,7
(1)
2+
+
+
-7,8
Pb + H2O ? PbOH + H
; K2 = 10
(2)
Do K2 >> K1 nn cn bng 2 quyt nh pH ca dung dch
Pb2+ + H2O
PbOH + H+ ; K2 = 10-7,8 (2)
C
0,10
0,10 x
x
x
x2
10 7 ,8
0,1 x
x = 10-4,4 = H+
pH = 4,40
10 6,8 PbOH Pb 2
2
1
Pb
10
Trong dung dch
PbI2
Pb2+ + 2 I
Ks2 = 1.10-7,86
x
2x
2
-7,86
-3
(2x) x = 10
x = 1,51.10 M
2x = [I] = 2,302 . 10-3M
.10
Ag KI 31,02
.10
s1
16
3
3,31.10 14 M .
E 1 0,001V
Dung dch X: Ag+ + SCN AgSCN ;
1012,0
0,010
0,040
0,030
0,010
+
AgSCN
Ag
+ SCN
;
10-12,0
0,030
x
(0,030 + x)
x0,030 + x) = 10-12
12
Ag x 310
3,33.10 11
2
x10
S pin:
(-) Ag
b)
AgI
PbI2
AgSCN
SCN 0,03 M
Ag (+)
AgI + e
AgSCN + e
Ag + SCN
AgSCN + I ? Ag + SCN
d)
K = KsAgSCN
KsAgI
12
= 1016
10
= 104
PbO2 + 2 H2O + 2 I
3+
3+
b) Thm t Fe vo dung dch X:
Fe
+ SCN FeSCN2+
Nng ion SCN gim, do nng ion Ag+ tng, E2 tng
Epin tng
Bi 38 : pH = 0 v 25oC th in cc tiu chun Eo ca mt s cp oxi ho - kh c cho nh sau:
2IO4/ I2 (r) 1,31 V ; 2IO3/ I2 (r) 1,19 V ; 2HIO/ I2 (r) 1,45 V ; I2 (r)/ 2I 0,54 V.
(r) ch cht trng thi rn.
1. Vit phng trnh na phn ng oxi ho - kh ca cc cp cho.
2. Tnh Eo ca cc cp IO4/ IO3 v IO3/ HIO
3. V phng din nhit ng hc th cc dng oxi ho - kh no l bn, cc dng no l khng bn? Ti
sao?
4. Thm 0,40 mol KI vo 1 lt dung dch KMnO4 0,24 M pH = 0
a) Tnh thnh phn ca hn hp sau phn ng.
b) Tnh th ca in cc platin nhng trong hn hp thu c so vi in cc calomen bo ho.
5. Tnh Eo ca cp IO3/ I2(H2O).
I2(H2O) ch it tan trong
nc.
0
Cho bit: E MnO-4 /Mn 2+ =1,51V ; E ca in cc calomen bo ho bng 0,244 V ;
0
3. V E IO3 / HIO < Eo HIO/ I2 ; nn HIO s t oxi ho - kh
Vy dng km bn nht v mt nhit ng hc l HIO, cc dng khc: IO4, IO3,
I2, I u bn pH = 0.
4. a . Thnh phn hn hp sau phn ng: IO3 0,16 M ; Mn2+ 0,24 M ;
104M ; I2 (r) 0,12 M ; pH = 0.
b. E so vi in cc calomen bo ho: 1,18 0,244 = 0,936 V
5. 1,17 V
I2 (H2O) 5.