S bo danh: H v tn:

1

K thi Ho hc Quc t ln th 37
Phiu tr li bi thi thc hnh


Th nghim 1. Tng hp D,L-Phenylglixin v tch ng phn quang hot

Tng im: 100 im
1-1 1-2 1-3 1-4 1-5
im tng 25 15 25 5 30 100
im chm



Th nghim 2. Xc nh cc mu v c cha bit
Tng im : 100 im
2-1 2-2
im tng 96 4 100
im chm

S bo danh: H v tn:


2
Th nghim 1

Tng hp D,L-Phenylglixin v tch ng phn quang hot

Tng im: 100 im
1-1 1-2 1-3 1-4 1-5
im tng 25 15 25 5 30 100
im chm

Bc 1. iu ch (D,L)-phenylglixin

1-1 Xc nhn v ch k
ca ngi hng dn


Khi lng ca axit benzoylfomic dng: g g /
Khi lng ca phu lc thy tinh xp: g g /

Sau khi lm kh hon ton:
Khi lng sn phm + phu thy tinh xp: g g /
[Cn c chnh xc ti centigam (0.01g)].

Khi lng ca D,L-phenylglicin thu c: g
Hiu sut phn ng: %
Tnh hiu sut phn ng (hiu sut %; trnh by cc tnh ton).











S bo danh: H v tn:


3
1-2
Np sn phm (l thy tinh c nhn mu xanh cha sn phm).

Ch k ca hc sinh:

Ch k ca ngi hng dn:

[Ban t chc s cn mt lng mu thch hp (khong 0.01g) phn tch ph
1
H NMR.]

Bc 2. Tch ng phn quang hot ca D,L-phenylglixin bng axit (+)-camphosunfonic
[(+)-CSA]

1-3 Xc nhn v ch k
ca ngi hng dn

Khi lng ca D,L-phenylglixin dng: g g /

Khi lng ca phu lc thy tinh xp: g g /

Sau khi sy kh hon ton:
Khi lng sn phm + phu lc thy tinh xp: g g /
[Cn chnh xc n centigam (0.01g)].

Khi lng ca mui phenylglixin (+)-CSA thu c: g
Hiu sut phn ng: %
Tnh hiu sut phn ng (hiu sut theo %; trnh by cch tnh ton).








S bo danh: H v tn:


4

1-4
V cc loi cng thc cu trc ha lp th ng ca ng phn phenylglixin tch c.










1-5
quay cc ring ca phenylglixin (+) CSA i quang (c xc nh bi ban t chc)

Np sn phm (l thy tinh c nhn mu hng cha sn phm).

Ch k ca hc sinh:


Ch k ca ngi hng dn:

[Ban t chc s cn mt mu khong 0.055 ~ 0.065g o tinh khit quang hc.]

S bo danh: H v tn:


5
Th nghim 2
Nhn bit cc mu cht v c cha bit
Tng im: 100 im
2-1 2-2
im tng 96 4 100
im chm

2-1

Hp cht
cha bit
M s**
Hp cht
cha bit
M s **
Hp cht
cha bit
M s**
HCl , H
2
SO
4
, NH
4
SCN ,
NaOH , BaCl
2
, K
4
Fe(CN)
6
,
Na
2
CO
3
, ZnCl
2
,

Na
2
SO
3
, H
2
O
2
,

**Ct th 2 ch dng ghi mu lp.

2-2
A. Vit phng trnh phn ng in phn dng ion rt gn c ghi trng thi tn ti gip em
khng nh mu cha bit l dung dch ZnCl
2
.


B. Vit mt phng trnh phn ng c th dng lm sch kt ta Zn trn b mt in cc (gii
hn cc dng c v thuc th dng trong bi).