You are on page 1of 2

Ge/RT = x1ln(1)+x2ln(2) = .

1x1x2

d(Ge/RT)/dx1 =
.1(1-2x1)
ln(1) =
.1x1(1-x1)+(1-x1)(.1(1-2x1))
ln(2) =
.1x1^2
x1=
0.3954832
x2=
0.6045168
G =
-1000 J
T=
298.15 K
R=
8.314 J/molK
K=
a.
b.

.1x1(1-x1)

(1-x1)^2

ln(1) =
ln(2) =

0.036544
0.015641

.1x2^2
1 =
2 =

1.03722
1.015764

x22/x11
exp(-G/RT)
=
Since both gamma values are dependent on x1, the only degree of freedom is x1
If T is specified, calculate K from the deltaG value for the reaction. Then use this value to find xa, and from this ca

alue to find xa, and from this calculate ya

You might also like