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∆(A) = ∆(B)
=
∆t = ∆t
The minus (-) sign indicates that the concentration decreases when the time
increases. The realtionship between changes in concentration with time change can be
decribed as follows:
∆t
∆(B)
solubility
Time (t)
∆t = - =-
Because the reaction rate is always proportional to the concentration of reactants,
the law matematically raection rates for the following chemical reaction:
aA + bB cC + dD
V= k [A]x[B]y
Where :
V = the rate of reaction
K = decree of the reaction rate
[A] and [B] = concentration A and B
x and y = the level of response to A and B
Reaction rate constant defined as the rate of raction when the concentration of each
species in the only depends on the reaction order. Basic reacction is any reaction that provides
the necessary products to elucidate the mechanism of a reaction. While the number of molecules
taken part in a basic stage is moleculitas.
Order from a reaction which describes the mathematical form of experimental
results can be shown if the reaction mechanism is known. Throughout the reaction order can be
defined as the sum of the exponents of each reactant. Thus, the reaction order is the price of
exponents for a component in the reaction rate.
aA + bB cC + dD
Can be expressed
– = =
Differential rate law shows how reaction rates depend on the concentration of
reactants. To show how concentration depending on the time can be expressed by the integral
equation.
a. Reaction degree
Based on the results of the experiment is the N2O5 decomposition reaction of the
reaction rate as follows :
It can be stated
– = k [N2O5]
If concentration of N2O5 is expressed by A, then :
– = k [A]
– = K dt
– =k
– In A ] = kt ]
– = kt or
= o – kt
Thus, when graphed againts time in A will obtain a straight line with slope = -K and
intercept.
Slope = tan α = - k
time (t)
– = k [A]2
=k
=k
- = kt or = + kt
So that when graphed Z opponent with T will get a straight line with slope = -K,
intercept = 1/Ao
Slope = tan α = - k
Time (t)
– =k ↔- -
– = kt or A = Ao - kt
When graphed (A) opponent with t will get a sttraight line with slope = -K and
intercept = (Ao)
Ao
Slope = - k
Time ( t )
v. EQUIPMENT
1. TOOL
2. 2
Measurem
ent Glass
3.
Stopwatch 1
4.
Pippete
2
2. MATERIALS
N NAME AMOUNT
O
1. Aquades 33 ml
3. Solution HCl 3 M 29 ml
V. PROCEDURE
3. Repeat the above experiment using solution and aqudes as listed in table 1 and table
2.
a. against [ Na2S2O3 ]
b. against [Na2S2O3 ]2
c. against [ HCl ]
d. against [ HCl ]2
1. Determine the level of reaction to a solution of Na2S2O3 and reaction rates HCl
solution.
VI. OBSERVATION DATA
1. Table 1
2. Table 2
V1 × M1 = V2 × M2
M2 =
a) M2 = = = 0,15M
b) M2 = = = 0,12M
c) M2 = = = 0,09M
d) M2 = = = 0,06M
e) M2 = = = 0,03M
*(HCl) = constant
=
• Data 1 and 2
= ( )x
= (1,25)x
X = 0,424
• Data 1 dan 3
=
x
=
= (1,67)x
= 1.041
• Data 1 and 4
=
= x
=
(2,5)x
X = 1,105
• Data 1 dan 5
=
x
=
= (5)x
X = 1,349
• Data 2 and 3
=
= x
= (1,33)x
X = 1,520
• Data 2 dan 4
=
X
=
= (2)x
X = 1,324
• Data 2 and 5
=
X
=
= (4)x
= 1,498
• Data 3 and 4
=
X
=
= (1,5)x
X= 1,184
• Data 3 and 5
=
x
=
= (3)x
• Data 4 and 5
=
x
=
= (2)x
➢ X = = = 1,2611
V1 × M1 = V2 × M2
M2 =
a) M2 = = = =3
b) M2 = = = = 1,8
c) M2 = = = = 0,6
*(Na2S2O3) = constant
• Data 1 and 2
=
=
y = 0,216
• Data 1 and 3
=
y = 0,201
• Data 2 and 3
y = 0,395
➢ Y = = = 0,127
V = k (Na2S2O3)x (HCl)y
V = k (Na2S2O3)1,2611 (HCl)0,127
✔ Plot
a) vs [Na2S2O3]
x y
0,038
0,15 1
0,034
0,12 7
0,022
0,09 4
0,013
0,06 8
0,004
0,03 3
b) vs [Na2S2O3]2
x y
0,0225 0,0381
0,0144 0,0347
0,0081 0,0224
0,0036 0,0138
0,0009 0,0043
c) vs [HCl]
x y
3 0,0326
1,8 0,0364
0,6 0,0236
d) vs [HCl]2
x y
9 0,0326
3,24 0,0364
0,36 0,0236
B. Qualitative Analysis
The purpose of this experiment is determining the reaction order in the reaction
between sodium thlocykate (Na2S2O3) in Hydrochloric acid (HCl).
The principle of work in this experiment is; first, enter Na2S2O3 to beaker glass.
Then, add the HCl to the beaker glass containing the solution to step number 1. While
running the stopwatch and stop at the time of turbidity. And repeat the above
experiment using solution and aquades as listed in table. Make some graph showing
relation between and Na2S2O3. At the last, determine the reaction order to a
2. Experiment HCl reacting with a different molarity of Na2S2O3 the molarity same.
This experiment aims to determine thereaction order of HCl.
From the result of calculations experimental data, obtained the order of different
reactions in each experiment. So, the reaction order is taken the average and obtained
that the reaction order Na2S2O3 = 1,2611 and HCl reaction order = 0,127. So :
V = k (Na2S2O3)1,2611 (HCl)0,127
This is not in accordance with the theory, ie :
V = k (Na2S2O3)1 (HCl)2
This is affect by;
1. The mistake when observe the process of reaction and determine the final limit
reaction. Not only the certain standard that used to determine the find limit that
invalid.
2. The carelesly of practican in doing experiment when using the equipment such as
measuring glass and beaker glass, that the number is unread.
VIII. CONCLUSION
Speed of reaction is the reactant concetration reduced speed or velocity increased
concentration of the product per unit of time. The reaction order is the rank number of the
relationship with the concentration of the reation rate can be determined through experiments.
Graph showing the relationship between the concentration of the solution either by time or the
reverse reaction is the reaction time straight line.
From the experiment is known that the speed is almost always the same reaction is
proportional to the concentration of reactants.
Thus, for reaction:
Na2S2O3 (aq) + 2HCl (aq) → 2NaCl (aq) + SO2 (g) + S (s) + H2O (g)
Reaction speed :
V = k [Na2S2O3]x[HCl]y
So that the reaction rate law for the reaction of Na2S2O3 with HCl ;
V = k [Na2S2O3]1[HCl]1