n thi i hc mn ha: K thut gii nhanh 2014-2015

Gv: Hong Trng Hin

CH 05: PHNG PHP PHNG TRNH ION THU GN

I. BI TP MINH HA
1. (H B-2009): Trng 100ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100ml
dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M thu c dung dch X. Dung dch X c
pH l:
A. 1,2
B. 1,0
C. 12,8
D. 13,0
HD: 147-XH
2. (H A-2010): Ha tan hon ton 8,94g hn hp gm Na, K, v Ba vo nc c dung dch X
v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4 t l mol tng ng l 4:1. Trung ha
dung dch X bi dung dch Y, tng khi lng cc mui c to ra l:
A. 13,70g
B. 18,46g
C. 12,78g
D. 14,62g
HD:146-XH
3.(H A-2010): Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt
dung dch X. Ly 1 lt dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82g kt ta.
Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn
ng thu c 7,0g kt ta. Ga tr ca a,m tng ng l:
A. 0,04 v 4,8
B. 0,07 v 3,2
C. 0,08 v 4,8
D. 0,14 v 2,4
HD: 23-NXTr
4.(H B-2008): Trn 100ml dung dch pH=1 gm HCl v HNO3 vi 100ml dung dch NaOH
nng a (mol/l) thu c 200ml dung dch c pH=12. Ga tr ca a l: (bit trong mi dung
dch [H+][OH-]=10-14)
A. 0,15
B. 0,30
C. 0,03
D. 0,12
HD: 150-XH
5. (H A-2007): Cho m gam hn hp Mg v Al vo 250ml dung dch X cha hn hp axit HCl
1M v axit H2SO4 0,5M thu c 5,32 lt H2 (ktc) v dung dch Y( coi th tch dung dch khng
i). Dung dch Y c pH?
A. 7
B. 1
C. 2
D.6
HD: 152-XH
6. Cho 2,4g hn hp bt kim loi Mg v Fe vo 130ml dung dch HCl 0,5M. Th tch kh (ktc)
thot ra l:
A. 0,336 lt
B. 0,728 lt
C. 2,912 lt
D. 0,672 lt
HD: 153-XH
II. BI TP RN LUYN
7. (C-A,B 2009): Cho dung dch cha 0,1mol (NH4)2CO3 tc dng vi dung dch cha 34,2g
Ba(OH)2. Sau phn ng thu c m gam kt ta. Ga tr ca m l:
A. 17,1g
HD: 148-XH

B. 19,7g

C. 15,5g

D. 39,4g

n thi i hc mn ha: K thut gii nhanh 2014-2015

Gv: Hong Trng Hin

8. (C-A,B 2008): Trn ln Vml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03M c
2V ml dung dch Y. Dung dch Y c pH l:
A. 4
B. 3
C. 2
D. 1
HD: 150-XH
9. (H B-2007): Cho 1 mu hp kim Ba-Na tc dng vi nc d thu c dung dch X v 3,36
lt H2 (ktc). Th tch dung dch axit H2SO4 2M cn dng trung ha dung dch X l:
A. 150ml
B. 75ml
C. 60ml
D. 30ml
HD: 151-XH
10. (H B-2007): Trn 100ml dung dch gm Ba(OH)2 0,1M v NaOH 0,1M vi 400ml dung
dch gm H2SO4 0,0375M v HCl 0,0125M thu c dung dch X. Ga tr pH ca dung dch X l:
A. 2
B. 1
C. 6
D. 7
HD: 151-XH
11. Cho m(g) hn hp A gm Fe v Zn vo 2 lt dung dch HCl c 0,4 mol kh, thm tip 1 lt
dung dch HCl th kh thot ra thm 0,1 mol. Nng mol ca dung dch HCl l:
A. 0,4M
B. 0,8M
C. 0,5M
D. 0,25M
HD: 154-XH
12. Ly cng khi lng kim loi R tc dng vi H2SO4 c nng v vi H2SO4 long thy s
mol SO2 gp 1,5 ln s mol H2. Vy R l kim loi:
A. Mn
B. Al
C. Mg
D. Fe
HD: 154-XH
13. Cho 3,9g hn hp X gm Al v Mg tc dng vi 100ml dung dch Y cha HCl 3M v H2SO4
1M. Kt lun no sau y hp l nht?
A. X tan khng ht
B. Axit cn d
C. X v axit va
D. Khng kt lun c
HD: 154-XH
14. Trn dung dch X cha NaOH 0,1M, Ba(OH)2 0,2M vi dung dch (HCl 0,2M; H2SO4 0,1M)
theo t l no v th tch dung dch thu c c pH = 13?
A. VX:VY = 5:4
B. VX:VY= 4:5
C. VX:VY = 5:3
D. VX:VY = 6:4
HD: 156-XH
15. Cho m gam hn hp X gm Na-Ba tc dng vi nc thu c dung dch Y v 3,36 lt
H(ktc). Th tch dung dch axit HCl 2M cn dng trung ha lng dung dch Y l:
A. 0,15 lt
B. 0,3 lt
C. 0,075 lt
D. 0,1 lt
HD: 156-XH
16. Cho 200ml dung dch A cha HC 1M v HNO3 2M tc dng vi 300ml dung dch cha
NaOH 0,8M v KOH (cha bit nng ) th thu c dung dch C. Bit rng trung ha dung
dch C cn 60ml HCl 1M. Nng mol ca dung dch KOH l:
A. 0,7M
B. 0,5M
C. 1,4M
D. 1,6M
HD: 158-XH
17. 100ml dung dch X cha H2SO42M v HCl 2M trung ha va bi 100ml dung dch Y gm
2 bazo NaOH v Ba(OH)2 to ra 23,3g kt ta. Nng mol mi bazo trong Y l:
A. [NaOH]=0,4M; [Ba(OH)2]=1M
B. [NaOH]=4M;[Ba(OH)2]=0,1M
C. [NaOH]=0,4M; [Ba(OH)2]=0,1M
D. [NaOH]=4M; [Ba(OH)2]=1M

n thi i hc mn ha: K thut gii nhanh 2014-2015

Gv: Hong Trng Hin

HD: 159-XH
18. Cho dung dch Ba(OH)2 n d vo 50ml dung dch X c cha cc ion NH4+; SO42-;NO3- th
c 11,65g kt ta c to ra v un nng c 4,48 lt kh bay ra (ktc). Nng mol mi mui
trong dung dch X l:
A.[(NH4)2SO4]=1M v [NH4NO3]=2M
B.[(NH4)2SO4]=2M v [NH4NO3]=1M
C. [(NH4)2SO4]=1M v [NH4NO3]=1M
D. [(NH4)2SO4]=0,5M v [NH4NO3]=2M
HD: 162-XH
19. Cho 8g canxi tan hon ton trong 200ml dung dch hn hp HCl 2M v H2SO4 0,75M thu
c kh H2 v dung dch X. C cn dung dch X thu c lng mui khan l:
A. 22,2<m<27,2
B. 22,2 m25,95
C. 25,95<m<27,2
D. 22,2m27,2
HD: 163-XH
20. Ha tan hon ton 17,88g hn hp X gm 2 kim loi kim A,B v kim loi kim th M vo
H2O thu c dung dch Y v 0,24 mol kh H2. Dung dch Z gm H2SO4 v HCl, trong s mol
HCl gp 4 ln s mol H2SO4. trung ha dung dch Y cn ht V lt dung dch Z.Tng khi
lng mui khan to thnh trong phn ng trung ha l:
A. 18,64g
B. 18,46g
C. 27,4g
D. 24,7g
HD: 164-XH
21. Trn 250ml dung dch hn hp HCl 0,08M v H2SO4 0,1M vi 250ml dung dch Ba(OH)2 aM
th thu c m gam kt ta v 500ml dung dch c pH = 12. Ga tr ca a v m ln lt l:
A. 0,3M v 5,825M
B. 0,15M v 5,825g
C. 0,12M v 6,99g
D.0,3M v 6,99g
HD: 165-XH
22. Ha tan mt mu hp kim Ba-Na (vi t l mo nBa: nNa =1:1) vo nc c dung dch A v
6,72 lt kh ( ktc). S ml dung dch HCl 0,1M trung ha 1/10 dung dch A l
A. 200ml
B. 400ml
C. 600ml
D. 800ml
HD: 184-NKTP
23. Mt dung dch X c cha cc ion Ca2+, Al3+, Cl-. lm kt ta ht ion Cl- trong 10ml dung
dch phi dng ht 70ml dung dch AgNO3 1M. Khi c cn 100ml dung dch X thu c 35,55g
hn hp hai mui khan. Nng CM ca CaCl2 l:
A. 1M
B. 1,5M
C. 2M
D. 2,5M
HD: 185-NKTP
24. Phi ly dung dch HCl(V1) c pH = 5 cho vo dung dch KOH (V2) c Ph = 9 theo t l th
tch nh th no c dung dch c pH = 8?
A. V1/V2=11/9
B. V1/V2=8/11
C. V1/V2=9/11
D. V1/V2=10/11
HD: 182-NKTP
25. Trn 100ml dung dch KOH c Ph = 12 vi 100ml dung dch HCl 0,012M. PH ca dung
dch thu c sau khi trn l:
A. pH=3
B. pH=4
C. pH=8
D. pH=11
HD: 182-NKTP
26. Dung dch X cha hn hp KOH v Ba(OH)2 c nng tng ng 0,2M v 0,1M. Dung
dch Y cha hn hp H2SO4 v HCl c nng ln lt l: 0,25M v 0,75M. Th tch dung dch
X cn trung ha va 40ml dung dch Y l bao nhiu ?