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CO 2
= 0,1x =
H2 O
y
z
) O2 xCO2
4
2
0,1x
y
H2O
2
0,05y
t N2.
0,05t
6,72
0,3 x 3
22,4
6,3
= 0,05y = 18 0,35 y 7
1,12
N2
x:y:z:t=
24 5 16 14
2 : 5 :1:1
12 1 16 14
12 x y 45
mC m H 12 x y 76,27
x
1
2
3
y
33
21
9
Cp nghim tho mn l: x = 3; y = 9.
CTPT ca amnin n gin: C3H7NH2.
4. Cho 0,1 mol cht X ( C 2H8O3N2, M = 108) tc dng vi dung dch cha 0,2
mol NaOH un nng thu c cht kh lm xanh giy qu m v dung dch Y.
C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l:
A. 5,7g
B. 12,5g
C. 15g
D.
21,8g.
Gii.
C2H5NH3NO3 + NaOH C2H5NH2 + NaNO3.
0,1
0,1
0,1
Cht kh lm xanh qu m l: CH3CH2NH2.
Nguyn xun ho
= 4 : 9 : 2 : 1.
CTPT trng vi CTGN nn CTPT l: C4H9O2N.
6. A l - amino axit cha mt nhm NH 2 v mt nhm - COOH. Cho
8,9g A tc dng vi dung dch HCl d thu c 12,55g mui. CTCT ca A l:
B. CH2 - CH2 - COOH
A. CH3 - CH - COOH
NH2
NH2
C. CH3 - CH2 - CH - COOH
D. CH3 - CH - CH2 - COOH
NH2
NH2
Gii.
CTPT ca aminoaxit l: HOOC R NH2.
HOOC R NH2 + HCl HOOC R NH3Cl.
Ta c:
R 61 R 97,5
R 28
8,9
12,55
Nguyn xun ho
NH2
CH3 NH2
D.
CH3 - C - COOH
NH2
Gii.
CTCT X :
R - CH - COOH
NH2
Ptp :
R - CH - COOH + HCl
NH2
R - CH - COOH
R - CH - COOH +2 NaOH
NH3Cl
HCl d +NaOH
(1)
NH3Cl
NaCl + H2O
(2)
(3)
= R + 74 =
8,9
89
0,1
NaOH
R = 15 R: CH3 -
CTPT ca X l: CH3CH(NH2)COOH.
9. Mt aminoaxit Y cha 1 nhm COOH v 2 nhm - NH 2. Cho 1 mol Y tc
dng ht vi dung dch HCl thu c 205g mui khan. CTPT ca Y l:
A. C4H10N2O2
B. C5H12N2O2
C. C6H14N2O2
D. C5H10N2O2.
Gii.
Gi CTPT ca Y l: CxHy2COOH(NH2).
Ptp:
CxHyCOOH(NH2)2 + HCl CxHyCOOH(NH3Cl)2 .
1 mol
1 mol.
Ta c:
12x + y + 45 + 2.52,5 = 205 12x + y = 55.
Nghim ng: x = 4; y = 7.
CTPT: C5H12N2O2.
10. t chy hon ton hn hp 2 amin bc I, mch h, no n chc k tip
nhau trong dy ng ng thu c CO2 v H2O vi t l s mol n CO 2 : nH 2
= 1:2. Hai amin c CTPT ln lt l:
A. CH3NH2 v C2H5NH2
B. C2H5NH2 v C3H7NH2
C. C3H7NH2 v C4H9NH2
D. C4H9NH2 v C5H11NH2.
Gii.
Gi cng thc phn t ca hai amin n chc , no l: C n H 2 n 1 NH2.
Nguyn xun ho
C n H 2 n 1 NH2 + (
4n 3
)O2 n CO2
2
mol
2n 3
H2O.
2
Ta c: n
CO 2
:n
H2 O
= n:
2.
2n 3
1: 2 n =
2
1,5.
CxHyNt + ( x +
CO 2
(*)
a
t
.
2
12,6
0,7 ay 1,4 mol. (2)
18
y
1,4
n O 2 = ax + 4 = 0,4 + 4 0,75 mol.
N2
= n
N 2 khng kh
+n
N 2 (*)
69,44
3,1.
22,4
at = 0,2.
(3).
T (1), (2), (3) ta c:
x : y : t = 0,4 : 1,4 : 0,2 = 2 : 7 : 1.
CTGN : C2H7N. CTN: (C2H7N)n . Nghim thch hp l: n = 1. V amin
bc I nn CPT l: CH3CH2NH2.
:nH 2 O = 2: 3. Tn ca X l:
A. Etylamin
B. Etylmetylamin C. trietylamin
imetylamin.
Gii.
CTPT amin no, c chc: CnH2n+3N.
CO 2
CnH2n+3N +
mol
n CO 2 : nH 2
4n 3
2n 3
1
O2 n CO2 +
H2O +
N2.
2
2
2
=n:
D.
2n 3
= 2 : 3 n = 3.
2
3.
Nguyn xun ho
A. H2NCH2COOH B. H2N[CH2]2COOH
H2NCH[COOH]2.
Gii.
CTPT ca amino axit: CxHyOzNt.
CxHyOzNt O xCO2 +
2
CO 2
H2 O
= ax = 2a
= a.
C. H2N[CH2]3COOH
D.
y
t
H2O +
N2 .
2
2
x = 2 X c hai nguyn t C.
t
1
=
.a t = 1 X c mt nguyn t N.
2
2
X : H2NCH2COOH.
14. A l mt - amino axit no, c mch cacbon khng phn nhnh, cha 1
nhm NH2 v 2 nhm COOH. Khi t chy hon ton mt mol A th thu
c hn hp kh trong
4,5 mol < nCO 2 < 6 mol. CTCT ca A l:
COOH
NH2
B. HOOC - CH - CH2 - COOH
A. H2N - CH - CH - CH3
COOH
NH2
C.
D.
COOH
Gii.
Gi CTPT ca amino axit trn l: CnH2n 1 (NH2)(COOH)2.
CnH2n 1 (NH2)(COOH)2 O (n + 2) CO2
1 mol
(n + 2) mol.
Theo bi ra ta c:
4,5 < n + 2 < 6 n = 3.
CTPT ca amino axit l: C3H5(NH2)(COOH)2.
CTCT ca amino axit no, mch thng khng phn nhnh l:
HOOC - CH - CH2 - CH2 - COOH
2
NH2
A khng hp l v mch cacbon phn nhnh.
Nguyn xun ho
86g
xg
100g
150.
100
g
60
86.150 100
.
215 (g).
100
60
150.32 100
.
80 (g).
100
60
1
1
( 6. mp + 6. mn) =
(6.0,6726.10-- 23 + 6. 0,6748.1023)
12
12
= 0,166.1023(g)].
Theo bi ra ta c:
m = 113n.0,166.1023 (g) = 2,494 (g)
n = 0,133.1023 mt xch.
17. Cho 100 ml dung dch amino axit A 0,2M tc dng va vi 80 ml
dung dch NaOH 0,25M. Mt khc, 100 ml dung dch A trn tc dng va
vi 80 ml dung dch HCl 0,5M. Bit A c t khi vi H 2 l 52. CTPT ca A
l:
A. (H2N)2C2H3COOH
.
B . H2NC2H3(COOH)2.
C. (H2N)2C2H2(COOH)2.
D. H2NC3H5(COOH)2.
Gii.
n A = 0,02 mol; n NaOH = 0,08.0,25 = 0,02 mol;
n HCl =
0,08.0,5 = 0,04 mol.
Do nA = nNaOH A c cha 1 nhm COOH.
n HCl = 2nNaOH A c cha hai nhm - NH2.
CTPT ca A: R(NH2)2(COOH)2.
MA = 52.2 = 104 R = 27 R: C2H3.
CTCT: NH2C2H3(COOH)2.
18. Mt amino axit no X tn ti trong t nhin (cha 1 nhm NH 2 v 1
nhm COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui.
CTCT ca X l:
A. H2NCH2COOH
B. CH3CH(NH2)COOH
C. H2NCH2CH2COOH
D. B v C ng.
Gii.
CTPT X: CnH2n(NH2)(COOH).
CnH2n(NH2)(COOH)2 + HCl CnH2n(NH3Cl)(COOH).
0,89g
1,255.
14 n 60 14n 96,5
n2.
0,89
1,255
Nguyn xun ho
CTPT X: C2H4(NH2)(COOH).
Cch khc:
C 1 mol X chuyn thnh mui khi lng tng 36,5 g.
C x mol . . . .. . . . . . . . . . . . . . . . . . . . . . . .. . . 1,255 0,89 = 0,365
g.
0,365
0,01 mol.
36,5
0,89
89 n = 2.
=
0,01
nA =
MA
CTPT X: C2H4(NH2)(COOH).
19. Cho X 0,01 mol amino axit X tc dng va ht 80 ml dung dch HCl
0,125M v thu c 1,835g mui khan. Mt khc, 0,01 mol X tc dng va
vi 25g dung dch NaOH 3,2% . CTCT ca X l:
A. H2NC3H6COOH
B. H2NC2H5COOH
C. H2NC3H5(COOH)2.
D. (H2N)2C3H4(COOH)2.
Gii.
n
HCl
NaOH
25.3,2
0,02 mol.
100.40
1,835
= 183,5
0,01
R = 41 R: C3H5.
CTCT X: NH2C3H5(COOH)2.
Gii.
NH2RCOOH + HCl (NH3Cl)RCOOH .
n
Mui
=n
= 0,1 mol
C. phenyl alanin.
M mui = R + + 45 =
11,15
111,5
0,1
D. valin.
R = 14
R : - CH2
A l H2NCH2COOH (glyxin).
21. Cho lng d anilin phn ng hon ton vi lng d dung dch long cha 0,05 mol
H2SO4. Lng mui thu c l:
A. 7,1g
B. 14,2g
C. 19,1g
D. 28,4g.
Gii.
2C6H5NH2 + H2SO4 (C6H5NH3)SO4.
n Mui = n H 2 SO 4 = 0,05 mol.
m Mui = 0,05. 284 = 14,2 g.
22. Cho 500g benzen phn ng vi hn hp gm HNO 3 dc v H2SO4 c. Lng
nitrobenzen to thnh c kh thnh anilin. Bit rng hiu sut phn ng u bng
78%. Khi lng anilin thu c l:
A. 1010,848g
B. 615g
C. 596,154g
D. 362,7g.
Gii.
C6H6 + HONO2 H 2 SO 4 C6H5NO2 + H2O
(1).
C6H5NO2 + 6H C6H5NH2 + 2H2O
(2).
Nguyn xun ho
Theo (1): m
Theo (2): mC 6 H 5 NH 2 =
500.123
615 kg.
78
615.93
465 kg.
123
78
362,7 kg.
100
B. 2.196
C. 2.1020
D. 2.1019.
Gii.
on t nilon 6,6 : [ - NH (CH2)5 NH (CH2)4 CO ] n.
Khi lng mt mt xch: m1 = 226 vC.
Khi lng on t: m2 = 226n vC = 226.n.0,166.1023 g = 0,0075 g.
n = 2.10 19.
24. Mt amino axit A c cha 40,4% C; 7,9% H; 15,7% N v M A = 89. CTPT ca A l:
A. C3H5O2N.
B. C3H7O2N.
C. C2H5O2N.
D. C4H9O2N.
Gii.
%O = 100 (40,4 + 15,7 + 7,9) = 36%.
Gi CTPT l: CxHyOzNt. Ta c:
y
89
12 x
16 z
14t
x = 3; y = 7; z = 2; t = 1.
100 40,4 7,9
36
15,7
CTPT l: C3H7O2N.
25. Cho 0,01 mol amino axit A tc dng va vi 80 ml dung dch HCl 0,125M. C
cn dung dch thu c 1,835g mui. Khi lng phn t ca A l:
A. 147
B. 150
C. 97
D. 120.
Gii.
n HCl = 0,125.0,08 = 0,01 mol.
Ap dng nh lut bo ton khi lng, ta c:
m Amin + m HCl = m mui m Amin = 1,835 0,01.36,5 = 1,47 g.
1,47
147 vC.
M amin =
0,01
27. Cho 0,1 mol amino axit A phn ng va vi 0,1 mol NaOH v 0,2 mol
HCl. Khi lng mui Na thu c khi tc dng vi NaOH l 13,9g. Khi lng
mui clorua khi cho tc dng vi HCl v CTCT ca A l:
A. 19,2g; HOOC (CH2)3 - NH2.
B. 18,4g; HOOC CH(NH2)
CH2 COOH.
C. 19g; HOOC CH(NH2) (CH2)2 NH2. D. 19,4g; HOOC CH
(NH2)CH3.