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I. Ni dung thi
- Tt c cc kin thc trong chng trnh trung hc ph thng
- Cc php tnh c s dng:
1. Php tnh cng, tr, nhn, chia thng thng
2. Php tnh hm lng phn trm
3. Php tnh cng tr cc phn s
4. Php tnh bnh phng, s m, khai cn
5. Php tnh logarit (log; ln) v i logarit
6. Gii phng trnh bc nht mt n
7. Php tnh cc hm s lng gic sin, cos, tg, cotg
8. Gii h hai phng trnh bc nht mt n
9. Gii h ba phng trnh bc nht mt n
10. Gii phng trnh bc hai mt n
11. Gii phng trnh bc ba mt n
12. Cc php tnh v vi phn, tch phn, o hm
II. Cu trc bn thi
Phn th nht: HS trnh by li gii v ni dung ha hc
Phn th hai: HS trnh by cch s dng my tnh b ti gii phng trnh v
tnh ton
Phn th ba: HS trnh by kt qu
III. Hng dn cch lm bi v tnh im
gii mt bi ton Ho hc, th sinh phi ghi tng ng tm tt li gii v ni
dung ha hc, cch s dng my tnh b ti gii phng trnh v tnh ton kt qu vo
cc phn tng ng c sn trong bn thi.
Mi bi ton c chm im theo thang im 5. im ca mt bi ton bng tng
im ca 3 phn trn.
im ca bi thi l tng im th sinh lm c (khng vi phm qui ch thi) ca 10
bi ton trong bi thi.
IV. V d bi ton v cch trnh by bi gii
V d 1:
Hai nguyn t ha hc X v Y iu kin thng u l cht rn. S mol ca X c
trong 8,4 gam X nhiu hn so vi s mol ca Y c trong 6,4 gam Y l 0,15 mol. Bit khi
lng mol nguyn t ca X nh hn khi lng mol nguyn t ca Y l 8 gam. Xc nh
k hiu ha hc ca X v Y?
Phn th nht: HS trnh by li gii v ha hc
187
6,4
8,4
8,4 6,4
; nB =
ta c phng trnh
= 0,15
y
y
x
x
Theo gi thit: x + 8 = y
Ghp hai phng trnh cho: 0,15x2 - 0,8x - 67,2 = 0
Phn th hai: HS trnh by cch s dng my tnh b ti gii phng trnh
Bm MODE hai ln mn hnh my tnh hin ln EQN
1
Bm nt s 1 mn hnh my tnh hin ln Unknowns
2
189
Tt (1) = 10-33
Al3+ + 3OH-
Al(OH)3 + OH-
AlO2- + 2H2O
Tt (2) = 40
Vit biu thc biu th tan ton phn ca Al(OH)3 (S) = [Al3+] + [AlO 2 ] di
dng mt hm ca [H3O+]. pH bng bao nhiu th S cc tiu. Tnh gi tr S cc tiu.
Phn th nht: HS trnh by li gii v ha hc
Xt 2 cn bng:
Al(OH)3
Al(OH)3 + OH -
T Tt(1):
v t Tt(2):
Al 3+ + 3OH
10-33
3+
[Al ] =
[AlO 2
AlO 2
OH
-
AlO-2
Tt(2) = OH - = 40
10-33 H 3O+
-14 3
(10 )
= 10 9[H3O+]3;
10-14
] = 40[OH ] = 40 H O+
3
3+
Do S = [Al ] +
[AlO 2
10-14
] = 10 [H3O ] + 40
H 3O+
9
+ 3
4.10-13
dS
9
+ 2
2 = 0
S cc tiu khi o hm
= 3.10 [H3O ] d H 3O+
H 3O+
[H3O+]4 =
190
4 1013
= 1,5. 10-7 mol/l
3,4 106
V d 4:
Hy xc nh khong cch gia 2 nguyn t iot trong 2 ng phn hnh hc ca
C2H2I2 vi gi thit 2 ng phn ny c cu to phng. (Cho di lin kt C I l 2,10
v C=C l 1,33 ).
Phn th nht: HS trnh by li gii v ha hc
ng phn cis- :
H
H
C
C
I
1200
300
0
dcis = d C= C + 2 d C - I sin 30 .
I
ng phn trans-:
I
H
C
I
C
H
1200
d trans = 2 IO
IO = I C2 +CO2 - 2I C CO cos1200=
2,12 +(
1,33 2
1,33
) -2 x 2,1 x
cos1200
2
2
Bm 1 sin 30 = 0,5
Bm 2,1 x2 + 0,67 x2 4,2 0,67 cos 120
= 2,5
191
kJ/mol
N-H
O=O
N N
H-O
N-O
389
493
942
460
627
N2 + 3 H2O (1)
Hng dn gii :
Tnh hiu ng nhit:
E1 = (6EN-H +
3
EO=O) - (EN N + 6EO-H)
2
= 6 389 +
E2 = (6EN-H +
3
493 - 942 - 6 460 = - 626,5 kJ
2
5
EO=O)- (2EN-O + 6EO-H)
2
= 6 389 +
5
493 - 2 627 - 6 460 =- 447,5 kJ
2
Hng dn gii :
a) S mol Fe trong FexOy = s mol Fe trong Fe(NO3)3 = 0,075
192
Fe 0,075 3
5,8 0,075 56
=
=
= 0,1
O
0,1
4
16
nFe =nH 2 =
0,672
=0,03(mol)
22,4
ta c :
a b
0,03 + + = 0,035
b = 0,015
3 3
%mFe =
0,03.56
.100% = 32,56%
5,16
Hng dn gii :
Theo biu thc v = -
dN
= kN = 3,7.1010 Bq
dt
ln2
N=
3,7.1010
. T1/2)
0,693
10
226N
226.3,7.1010.5,014.1010
mRa =
=
= 1 gam
6,022.1023
0,693.6,022.1023
Bi 4. Nung FeS2 trong khng kh, kt thc phn ng thu c mt hn hp kh c
thnh phn: 7% SO2; 10% O2; 83% N2 theo s mol. un hn hp kh trong bnh kn (c
xc tc) 800K, xy ra phn ng:
2SO3
2SO2 + O2
Kp = 1,21.105.
a) Tnh chuyn ho (% s mol) SO2 thnh SO3 800K, bit p sut trong bnh lc ny
l 1 atm, s mol hn hp kh ban u (khi cha un nng) l 100 mol.
b) Nu tng p sut ln 2 ln, tnh chuyn ho SO2 thnh SO3, nhn xt v s
chuyn dch cn bng.
Hng dn gii :
193
a) Cn bng:
2SO2
2SO3
+ O2
Ban u:
7
10
0
(mol)
lc cn bng: (7-x) (10 - 0,5x)
x (x: s mol SO2 phn ng).
Tng s mol cc kh lc cn bng: 100 - 0,5x = n.
p sut ring ca cc kh:
Kp =
(PSO3 )
2
(PSO2 ) .PO2
x2(100- 0,5x)
2
do K >> x 7 Ta c :
49.96,5
(7 x)2.6,5
= 1,21. 105
= 1,21. 105
Gii c x = 6,9225.
Vy chuyn ha SO2 SO3:
6,9225.100%
= 98,89%.
7
6,9452.
chuyn ho SO2 SO3: (6,9452 . 100)/7 = 99,21%
Kt qu ph hp nguyn l Lsatlie: tng p sut phn ng chuyn theo chiu v
pha c s phn t kh t hn.
Bi 5. t chy hon ton 3 gam mt mu than c cha tp cht S. Kh thu c cho
hp th hon ton bi 0,5 lt dung dch NaOH 1,5M c dung dch A, cha 2 mui v
c xt d. Cho kh Cl2 (d) sc vo dung dch A, sau khi phn ng xong thu c dung
dch B, cho dung dch B tc dng vi dung dch BaCl 2 d thu c a gam kt ta, nu
ho tan lng kt ta ny vo dung dch HCl d cn li 3,495 gam cht rn.
a) Tnh % khi lng C; S trong mu than, tnh a.
b) Tnh nng mol/lt cc cht trong dung dch A, th tch kh Cl 2 (ktc) tham
gia phn ng.
Hng dn gii :
a) Phng trnh phn ng: C + O2 CO2 (1)
x
x
S + O2 SO2 (2)
y
y
Gi s mol C trong mu than l x, s mol S trong mu than l y
12x + 32y = 3.
194
(7)
%S = 16%
mC = 2,52 g %C = 84%
a gam kt ta = 3,495 +
2,52
(137 + 60) = 41,37 g
12
Hng dn gii :
195
3x + 7y + 8z = 2,94
(a)
ng cn d c cc phn ng:
Cho e:
Nhn e:
2+
(1)
3+
(2)
3+
Cu - 2e = Cu2+
(3)
Mg - 2e = Mg
Fe - 3e = Fe
2+
Cu + Fe = Cu + Fe
2+
(4)
(5)
(6)
0,044.5.3
= 0,165 mol
4
Theo cc phng trnh (1), (2), (3), (4), (5): s mol e cho bng s mol e nhn:
2(x + y + z - 0,165) = [3,4.0,2 - 2(x + y + z - 0,165)].3
x + y + z = 0,255 + 0,165 = 0,42 (b)
T khi lng cc oxit MgO; Fe2O3; CuO, c phng trnh:
x
y
z
.40 + .160 + . 80 = 15,6 (c)
2
4
2
H phng trnh rt ra t (a), (b), (c):
3x + 7y + 8z = 2,94
x + y + z = 0,42
x + 2y + 2z = 0,78
Gii c: x = 0,06;
y = 0,12;
z = 0,24.
0,06
= 0,246 M;
0,244
[Fe2+] = 0,492 M;
[Cu2+] = 0,984 M;
[SO42-] = 0,9 M;
[NO3-] = 1,64 M
Hng dn gii :
a) [ H+].0,5.10-7 do nng nh phi tnh n cn bng ca H2O
H2O
196
H+ + OH -
HCl
H+ + Cl -
-7
H2O
H+ + OH-
KW = 10-14
(1)
HA
H+ + A-
KHA = 10-375
(2)
KB = KHA-1. KW = 10-10,25
(3)
A- + H2O
HA + OH-
0,1
mui
= 3,75 + lg
= 3,75
0,1
[ axit]
0,001
(mol)
0,01 +0,001
0,01 - 0,001
= 0,0275 M v [KA] =
= 0,0225M.
0,4
0,4
0,0225
= 3,66
0,0275
Bi 8. Ho tan 8,862 gam hn hp: Al, Mg trong 500ml dd HNO3 long thu c dd
A v 3,316 lt (ktc) hn hp 2 kh khng mu c khi lng 5,18g trong c 1 kh b
ho nu trong khng kh.
197
a) Tnh thnh phn % theo khi lng mi kim loi trong hn hp.
b) C cn dd A c bao nhiu gam mui khan.
c) Tnh nng mol/lt ca dd HNO3 tham gia phn ng.
d) Ho tan dd A vo dd NaOH d tnh khi lng kt ta to thnh.
Hng dn gii :
a) M 2kh =
5,18.22,4
= 37. Do MNO = 30 nn kh th 2 l N2O (c M = 44)
3,136
3x + 2y = 0,77
27x + 24y = 8,862
Suy ra:
%mAl =
x = 0,042 ;
y = 0,322
0,042.27
. 100% = 12,8% v %mMg = 87,2%
8,862
c) [HNO3] =
0,98
= 1,96M;
0,5
Hng dn gii :
CHF = 0,1M; [H+] = 10 -3, gi nng NaF trong dd ban u l x
HF
[]
H+
(10 -1- 10 -3 )
3,17.10 - 4 =
F-
10-3
)=
103 x + 10 3
101 10 3
x + 10-3
10
x +10
99.10
x + 10 -3 = 313,83.10 -4
x = 303,83.10 -4
nNaF = 3,03.10 -4
198
x + 103
=
99
Bi 10. Ho tan m gam Cu trong lng d dung dch HNO 3. Kt thc phn ng thu
c 5,97 lt hn hp gm NO v NO2 (kh A), v dung dch c khi lng khng thay
i so vi khi lng axit ban u. Thc hin 2 th nghim sau:
Th nghim 1: ly 11,94 lt kh A cho i qua dung dch KOH 0,5 M phn ng va ,
thu c dung dch B (th tch khng thay i so vi th tch dung dch KOH).
Th nghim 2: Ly 5,97 lt kh A cho i qua Cu bt d thu c kh C.
a) Tnh m.
b) Tnh th tch dung dch KOH v nng mol/lt ca dung dch B.
c) Tnh th tch kh C thu c. Cc th tch kh o iu kin tiu chun.
Hng dn gii :
Phng trnh phn ng: 3Cu + 8HNO3 = 3Cu(NO3)2 + 2NO + 4H2O
Cu + 4HNO3 = Cu(NO3)2 + 2NO2 + 2H2O
2NO2 + 2KOH = KNO2 + KNO3 + H2O
0
t
NO + Cu
CuO + 1/2N2
2x
+ 46 . 2y
3
hay 7y = 11x
Gii c x = 0,07
2x
+ 2y = 0,2665
3
a) Tnh m:
a = 11,52 gam
b) S mol NO2 tham gia phn ng (3) : 0,11 4 = 0,44 (mol)
S mol KOH tham gia phn ng : 0,44 mol Th tch dung dch KOH 0,5M =
0,44
= 0,88 (lt)
0,5
Nng cc mui trong dung dch B: [KNO2] = [KNO3] =
0,44
= 0,25 (M)
0,88.2
1
1 0,07.2
s mol (NO + NO2) = (
+ 0,11 . 2) = 0,13335 (mol)
3
2
2
Hng dn gii :
Gi s ht proton, ntron, s khi ca nguyn t a l: Za ; Na ; Aa
Gi s ht proton, ntron, s khi ca nguyn t b l: Zb ; Nb ; Ab
Gi s ht proton, ntron, s khi ca nguyn t c l: Zc ; Nc ; Ac
T cc d kin ca u bi thit lp c cc phng trnh:
2(Za + Zb + Zc) + (Na + Nb + Nc) = 82
(1)
2(Za + Zb + Zc) - (Na + Nb + Nc) = 22
(2)
Ab - Ac = 10 Aa
Ab + Ac = 27Aa
T (1) v (2) : (Za + Zb + Zc) = 26; (Na + Nb + Nc) = 30 => Aa + Ab + Ac = 56
Gii c: Aa = 2 ; Ab = 37 ; Ac = 17. Kt hp vi (Za + Zb + Zc) = 26
Tm c : Za = 1, Zb = 17 ; Zc = 8 cc nguyn t l: 1H2 ; 17Cl37 ; 8O17
Cng thc X: HClO.
Bi 12.
a) Cho n-butan phn ng vi Clo ( t l mol 1:1), chiu sng c hn hp 2 sn
phm hu c A v B cng kh C.
* Vit phng trnh phn ng.
* Kh C c ho tan trong nc, trung ho dung dch cn 800 ml dung dch
NaOH 0,75M. Tnh khi lng sn phm A, B , bit nguyn t Hidro Cc bon bc II
c kh nng phn ng cao hn 3 ln so vi nguyn t Hidro Cc bon bc I.
b) C 4 hidrocacbon thm: C8H10 (A); C8H10 (B); C9H12 (C); C9H12 (D). Thc hin
phn ng cc hidrocacbonvi Br2/Fe (t l mol 1:1) c cc dn xut mono Brom.
A cho 1 sn phm th.
B cho 3 sn phm th.
C cho 1 sn phm th.
D cho 2 sn phm th.
Vit cng thc cu to ca A; B; C; D.
Hng dn gii :
a) * Vit phng trnh:
CH3-CH2-CH2-CH3 + Cl2
CH3-CHCl-CH2-CH3 + HCl
(A)
CH3-CH2-CH2-CH3 + Cl2
CH3-CH2-CH2-CH2Cl + HCl
(B)
200
(C)
(C)
100.r A .4 100.3.4
100.3.4 0,6
=
=> nA =
.
= 0,4 (mol) => nB = 0,2 (mol)
4r A +6r B
4.3 + 6
4.3 + 6 100
CH3
CH3
CH3
CH3
H3C
CH3
H3C
CH3
CH3
CH3
hoc
CH3
(A)
(B)
CH2-CH3
(C)
(D)
Hng dn gii :
Tng s mol ca cc kh trong bnh kn
n=
S mol O2 l:
P.V
16.0,98
=
= 0,5 mol
R.T (109,2 + 273).0,082
13,44
=0,42 mol
32
201
y +1
CxHyOH + x + - O2 xCO2 +
H2O
4
4
2
a
y' 1
y' +1
CxHyOH + x' + - O2 xCO2 +
H2O
4 4
2
b
y" 1
y" +1
CxHyOH + x" + - O2 xCO2 +
H2O
4
4
2
c
Ta c: a + b + c = 0,08
S mol CO2 thot ra: xa + xb + xc =
6,16
=0,14 mol
44
S mol H2O
y +1
y' +1
y" +1
2 a + 2 b + 2 c =0,21 mol
ya + yb + yc = 0,34
x +4 - 4 a +
y' 1
x' + 4 - 4 b +
y" 1
x" + 4 - 4 c =
xa + xb + xc +
ya +y'b +y"c a +b +c
=
4
4
P.V
RTn 0,082(136,5 +273).0,565
P=
=
RT
V
16
P = 1,186 atm
Vy p sut sau phn ng l 1,186 atm.
b) Do s cacbon ca ru B, C bng nhau nn ta gi
202
CnH2n+1-2xOH
CmH2m+1-2yOH
(A)
CmH2m+1-2zOH
(B)
(C)
3n - x
O2 nCO2 + (n + 1 - x) H2O
2
CmH2m+1-2yOH +
3m - y
O2 mCO2 + (m + 1 - y) H2O
2
CmH2m+1-2zOH +
3m - z
O2 mCO2 + (m + 1 - z) H2O
2
Ta c tng s mol 3 ru
a + b + c = 0,08
Do
nA =
(1)
5
5
(nB + nC) a = (b + c)
3
3
(2)
(3)
(4)
na + m(b + c) + a + b + c - xa - yb - zc = 0,21
xa + yb + zc = 0,01
T (1) (2)
(5)
= 0,05
b + c = 0,03
T (3) 0,05n + 0,03m = 0,14 5n + 3m = 14
n
<0
n = 1, m = 3
Ru (A) ch c 1C, ru (B), (C) c 3C
Do (A) ch c 1C nn khng c ni i hay ni ba trong mch (A) l ru n no,
suy ra: x = 0
Vy cng thc (A): CH3 - OH
T (5) yb + zc = 0,01
(*)
Thay vo (4)
na + m(b + c) + a + b + c - xa - yb - zc = 0,22 0,21
Khng tha mn.
+ (B), (C) c th l 1 ru n no v 1 ru c mt ni i, suy ra trong phn t (C)
c cha 1 ni i
y = 0, z = 1
T (*) yb + zc = 0,01 c = 0,01
b = 0,02
Trng hp ny tha mn
Vy cng thc ca (B), (C) l: C3H7OH v C3H5OH
+ (B), (C) l 2 ru n no c ni i y = z = 1
Lc yb + zc = b + c = 0,01 0,03 (loi)
+ (B), (C) l 2 ru n c 1 ni ba y = z = 2
T (*) 2(b + c) = 0,01 b + c = 0,005 loi
+ (B) c 1 ni i, (C) c mt ni ba.
y = 1, z = 2
T (*)
b + 2c = 0,01
b + c = 0,03 b = 0,03 - c
c + 0,03 = 0,01 loi
yb + zc = 2b = 0,01 b = 0,005
c = 0,025 tha mn
Cng thc (B), (C) l: C3H3OH, C3H7OH
Vy cng thc ca (A): CH3OH, cng thc ca (B) v (C) l: C3H7OH v C3H5OH
hoc C3H7OH v C3H3OH.
Bi 14. Mt hn hp (X) gm 1 ru no n chc (A) v 1 axit no (B) 2 ln axit.
Khi lng ca (X) l mX = x gam. Chia (X) lm 3 phn bng nhau:
- Phn 1 cho tc dng vi natri d cho ra y lt hiro (ktc).
- Phn 2 t chy ht cho ra z gam CO2.
a) Tnh s mol a (nA), b (nB) theo x, y, z.
b) Cho x = 34,8 gam, y = 3,36 lt v z = 15,4 gam
* Xc nh cng thc cu to ca (A), (B).
* Tnh thnh phn phn trm theo khi lng ca hn hp (X).
c) Phn 3 un nng vi H2SO4 (xc tc). Tnh khi lng este thu c vi hiu sut
phn ng l 80%.
Cho: C = 12, H = 1, O = 16, N = 14, Cl = 35,5, Na = 23, K = 39, S = 32, Ca = 40,
Br = 80.
204
Hng dn gii :
- t cng thc tng qut: A: CnH2n+1OH
v B: CmH2m(COOH)2
1
Gi: a = nA, b = nB trong
hn hp X.
3
V khi lng ca hn hp X l x nn ta c :
x
a(14n + 18) + b(14m + 90) =
3
x
Hay:
14(na + mb) + 18(a + 2b) + 54b =
3
- Phn 1 vi Na:
Ta c phn ng: CnH2n+1-OH + Na CnH2n+1-ONa +
(1)
1
H2
2
a
2
Hay:
na + mb + 2b =
(3)
na + mb =
z
44
z
- 2b
44
(3)
(3)
x
z
18y
- 2b +
+54b =
T (1) (2) (3) 14
3
44
11,2
Hay:
26b =
x 9y 7z
3 5,6 22
205
b=
1 x 9y 7z
26 3 5,6 22
(2)
a=
y
y
1 x 9y 7z
- 2b =
11,2
11,2 13 3 5,6 22
b)
* Thay cc gi tr ca x = 34,8 ; y = 3,36 ; z = 15,4
Ta c: a = 0,2 mol
b = 0,05 mol
T (3), ta c:
z
15,4
na + mb =
- 2b =
- 0,1 = 0,25
44
44
0,2n + 0,05m = 0,25
Hay: 4n + m = 5
n
(-)
COOCH 3
CH 2(COOH)2 +2CH 3 - OH CH 2
+2H 2O
COOCH 3
0,05 mol
0,1 mol
0,05 mol
80
= 5,28 gam
100
Bi 15. t chy 1,6 gam mt este (E) n chc c 3,52 gam CO 2 v 1,152 gam
H2O.
a) Tm cng thc phn t ca (E).
b) Cho 10 gam (E) tc dng vi lng NaOH va . C cn dung dch sau phn
206
ng c 14 gam mui khan. Tm cng thc cu to ca (E), bit (E) khng phn nhnh.
c) (F) l mt ng phn ca (E), (F) tc dng vi NaOH to ra mt ru m khi t
chy mt th tch hi ru ny cn ba th tch oxi o cng iu kin. Tm cng thc
cu to ca (F)
(Cho: Na = 23; Ba = 137; C = 12; H = 1; O = 16)
Hng dn gii :
1. Gi cng thc phn t (E) l CxHyO2, ta c phng trnh
y
to
CxHyO2 + x + - 1 O2
xCO2
a mol
ax mol
y
H2O
2
ay
mol
2
Gi nE = a mol
nCO2 =
m 3,52
1,152
= 0,08 mol; nH O =
= 0,064 mol
=
2
M
44
18
ta c h sau:
a(12x + y + 16 2) = 1,6
(I)
ax = 0,08
(II)
ay
= 0,064 ay = 0,128
2
(III)
0,08
=5
0,016
y=
0,128
=8
0,016
nE =
10
= 0,1 mol
100
0,1
0,1
CH 2 - CH 2
CH 2
O
CH 2 - C
O
Tnh =
2.5- 8 +2
=2
2
Tht vy
CH 2 - CH 2
CH 2
O
CH 2 - C O
t
+ NaOH
HO - CH2 - CH2 - CH2 - CH2 - COONa
[A] mol/l
[B] mol/l
V [mol.l-1.s-1]
0,2
0,2
4.10-4
0,2
0,3
9.10-4
0,8
0,8
256.10-4
(0oC)
(g)
35
72,45
45
66,80
c hp cht B; t chy 1,24 gam cht B thu c 1,76 gam CO2; cn khi cho 1,24
gam B tc dng vi Na th thu c 448 ml H2 (ktc). Vit cc phng trnh phn ng
xy ra v gi tn ca A.
p s: OH - CH2 - CHO
7. Cho bit tan ca canxi sunfat l 0,2 gam trong 100 gam nc ( 20 oC) v khi
lng ring ca dung dch CaSO4 bo ha d = 1g/ml. Hi khi trn 50 ml dung dch CaCl2
0,012 M vi 150 ml dung dch Na2SO4 0,004 M ( 20oC) c kt ta xut hin khng?
2
211