CAU HOI Li THUYET VE HOA HOC HOU CO’ THPT Vai sue “giao heu” va sding tao trong nhitng ném gan déy, cdc cdu hoi li theyét hitu co trong dé thi thit DH ngay cing gay ra nhiing khé khan khing nhé voi cc si ti. Khéng con chi kiém tra cdc kién thiee co ban va noi bat, cic dé thi gio déy bit déu tim dén mang kién thie ma hoc sinh cting nu gido vién it quan tém truéc déy nhue céu tric phn tir, tinh chat vg i, diéu kign phan img, img dung thyc té,... Diéu dé doi hoi hoc sinh hon bao gic hét phai doc ki va thyc sv hiéu cdc tri thitc diege cung cdp trong sdch gido khoa THPT dé khong bj be ngé trude cae edu hoi trong dé thi. (lemongrass.31.08@gmail.com) PHAN 1. CAU HOI VA BAL TAP ‘(CAu 1. Cho so dé chuyén héa sau: Benzen + etilen "> X —22"_5 y_8*0._ hon hop ZH khi' T Vay khi Ta A. COs B.CH, C.hdn hgp CO: vaCh —-D. CsHsCOOH (Cau 2. Cho CHsBr phan mg v6i NHs, san pham tao ra amin la A. CH\NHe B. (CH)):NH C. (CHs)3N D. hin hop CHsNHb, (CHs):NH, (CHs)N (Cau 3. Cho so dé chuyén héa sau: cr, yy, 6s yy, || EX Xl x, Trong so dé trén, X5 la: A. Caosu cloropren B. Cao su Buna C. Cao su thign nhign D. (-CH-CH=CH-CHz-CH2-CCI=CH-CH2-)y ‘Cau 4, Phin tir ndo sau day c6 gée CCC 66 d6 lin xdp xi 90°? A. Xiclopropan B. Propen . Xiclobutan D. Propan Cau. Chon nhan dinh diing dui day. A, Hidrocacbon no la hidrocacbon khong e6 phan ing eng thém hidro. B. Hidrocacbon no Ia hidrocacbon ma trong phan tit chi e6 C lai hia sp’ C. Do chi e6 lién két o, ankan trong 46% hoat dng héa hoe. D, Phan ting flo ha C;Hio t90 ra 4 Jogi din xuét mono khée nhau. Céiu 6. Cho cfc chit sau: Bro, HBr, A.2 Bl phan ung v6i xiclohexan la: D.4 ‘Cfu 7. Trong s6 cic hidrocacbon cé ti khdi so véi Hy bing 20, thi sé Iugng chat lim mat mau dung dich thude tim la, Al B.2 C3 D4(Cu 8, Phan img nao sau diy tao ra HBr? (1) Benzen + Bry > (3) CH=CHBr + KOH 2 (5) CH; -OCH, +Br > A. (23,4) B.(DQV4) Ciiu 9, Hidrocacbon X 06 CTPT Ii C;2Hio, khéng kim mat mau dung dich KMnOs 6 nhiét d9 thong va (2) Xiclopentan + Bry ——> (4) CH}CH=CHCH;Br + HO —> C.(IQ)BKS) D.()GB\4) hi dun néng. Cho X phan ting véi HNOs/H:SO, thu duge sin phim CisHeNOs. $6 lugng chat C)2HyNO> 6 thé tgo ra la: AL B.2 Cfu 10. Cho so dé chuyén héa sau: C3 D4 ‘Cumen %"* > C,H, Br 22" > C, Hy, "> X(C, HB) Vay chat X 1a: A, L-brom-2-phenylpropen C. p-bromisopropenylbenzen Cu 11. Cho so dé chuyén héa sau: B. 3-brom-2-phenylpropen D. o-bromisopropenylbenzen CH,OH+CO—*\> X(duy nhat) HA" 5 yHseunnrwe , 720,180.60, yg Vay chit M la: A. CoH B. CHs-CHs C. CHsCHO. D. CH;COOGHs (Cau 12. Chuyén héa hidrocacbon X (CsHio) theo so dé sau: X22 C1,0, 2! 50,140, Vay chat X la: A. Naphtalen Cfiu 13. Hidrocacbon X eé ki B. o-Xilen C. Dimetylbenzen D. Etylbenzen Iugng mol bing 100 gam, khi phan img véi clo tao ra hn hop gom 3 dong phan monoclo cia X. $é lugng hgp chat thoa man tinh chat trén cua X 1a: A2 B.3 C4 DS Cfu 14. Khi 6 vong benzen di c6 sin nhém thé day electron cing manh thi phan img vao vong cang dé xiy ra, Trong s6 ede nhém ~CHs, ~OH, -NHz, ~OCHs, nhém nio diy electron yéu mht? A.-NH> B.-CHy Cfiu 18. Cho eée phan img sau: (1) Gala + KMn0, > (3) CH;COOC(CHs)(C)CH:CI + NaOH ——> (5) CHsCLCH:-CCI + NaOH —> ‘Sé phan img tao ra ancol hode axit da chite li: A2 BA Cf 16. Cho ede phin img cong sau diy: 1) CHy=CH + HCL 3) CH\CH-CH + HI Phan tng xay ra dé dang nhat la phan img: A) B.Q) C.-OH D.-OCH; (2) Benzen-1,2-diamin + HNO, —*° (4) Tripanmitin + NaOH — (6) 3-clopropen + H>O “> cs D3 2) CHsCH=CHy + HC] 4) CHy=CH + HBr ©.) D.@) Cau héi Ii thuyét vé héa hoc hitu co 2012 ‘emonGrass.31.08@Gmall.com — Trang 2/14CA 17. Cho eée nhén dinh sau: (J) Phan tng céng He vao anken la phiin tmg toa nhigt, (2) Tron hex-2-en long voi muse brom, lc ki rdi dé yén thi mau vang cam cia dung dich bj nhgt di. (3) Aken cng nude ludn tgo it nhit 2 ancol. (4) Suc etilen vao dung dich thudc tim thay xuat hign két tia den, (5) Trong phong thi nghiém, etilen due diéu ché tir etanol. han dinh ding ta: AS B.3 c.2 D4 ‘Cau 18. Cho day bién hoa: Cumen 2-9 X—HS0.2% yy HON, 7 “HON ng Biét M lam mat mau dung dich nue brom. Vay M la: A. phenol B. axit metacrylic . isopropenylbenzen 1D. axit-2-hidroxylisobutirie ‘Cfiu 19, Hop chat X 6 cng thie cau tao nhu sau: CH, ~CH = CH ~CH, ~CH, ~CH =C(Cl)-CH,+, Hay cho biét qua trinh diéu ché chat X tir axetilen (cdc chat v6 co céin thiét c6 dit) phai trai qua it nhdt bao mhiéu giai doan: A.2 B.3 C4 DS Cfu 20. Khi dun néng mdi chit toluen, stiren, phenol, anilin v6i dung dich KMnO, dae thi e6 phan img héa ge xy ra véi A. toluen B. toluen va stiren C. toluen, stiren va phenol D. ca 4 chat toluen, stiren, phenol va anilin Cfu 21. Hop chit X khong no mgch har cé céng thie phan tir CsHyO:, khi tham gia phan img xd phong hoa thu duge 1 andebit va 1 mudi cita axit hit co. Cé bao nhiéu céng thite céu tao phii hop v6i X (khong ké dng phan cis, trans)? A2 B3 C4 DS Cf 22. Cho cée dung dich lam 46; A.2 B.3 C4 DS At long hoe dung dich sau: phenol, anilin, natri phenolat, axit axetic, kali axetat. S6 au phenolphtalein li ‘Céiu 23. Cho anilin tic dung voi nude brom duge két tia A. Cho A téc dung voi HNO, ban dau & 0°C ~ 5°C, sau d6 dun néng nhe duge ket tia B, Vay B la: A. Axit picric B. Mudi cia A voi HNO2 ~~ C. 2,4,6-tribromphenol __D. anilin Cfiu 24, Chat A chia C, H, O, mach hé cé nguén géc tir thye vat va thuong gip trong doi sing. Khi lay cing sé mol ctia A cho phan ing hét voi NazCOs hoje vai Na thi ti 1 sé mol CO; va sé mol Hz thu duge tuong img li 3:4. Biét A c6 khéi Iugng mol phan tir ki 192 gam va chi chira ede nhom chite phin img v6i Na. Tén goi cia A 06 thé li: A. axit laurie (trong qua dita) B. axit tactaric (trong qua nho) CC. axit malic (trong qui téo) D. axit xitrie (trong qua chanh) C4u 25. Chon nhjin xét sai? A. Cie chit hiu co ¢6 % s6 mol trong hén hgp bing % kh6i lugng trong hn hgp a6 duge ggi la dong phan cia nhau. Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass,31,08@Gmail.com — Trang 3/14B. Gée lign két HCH trong phan tir C3Hy < CHy < CoH. C. C63 cach bigu dign cng thite cu tao ciia hyp chat hiru co. D. Lién két héa hoc trong phan tir hop chat khi chit yéu la lin két cng héa tr). ‘Ciiu 26. Cho cae chat sau: CHy)OH, C:HsOH, CHsCHO, C>H>, C2Ha, CsHio, CH;}COONa, CH;CN. S6 chai 6 thé tgo duge CH\COOH chi bing 1 phan img la: AB B.S c4 D.6 (Cf 27. Chon nhin xét ding. A. Nhiing quy tim vio dung djch axit a-aminoaxetic thay quy tim 46i miu. B. Cac aminoaxit la hgp chat hiru co nén nhigt 46 néng chay tuong doi thip. C. Khi cho a-aminoaxetie tée dung vii C2HsOH (xt: HCI khi) thu duge CI HyN°CHsCOOC2Hs. D. c-aminoenantoic 1a nguyén ligu dé sin xudt to nilon-6. (Cfu 28. Chon nbn xét ding. A. Nhigt d s6i etia CHs;COOC:IIs < CHsCHCH2COON < CIis[CUz]sCHZO1. B. Gidng nhur xa phong, chit giat rira tong hgp khong thé git rim trong nude eimg. C. Ngay nay xa phong cdn duge san xudt tir ankan. D. MG bj Gi Ia do lign két C-C cita gc axit béo bj oxi héa chim béi oxi trong khong khi. ‘Cfiu 29. Cho so dé phan img: CH, ny, — hs s.sH40 swe a, y, sche, y, sane yy, Biét cdc chit trong so dé trén déu mach hé va c6 sé C nhw nhau. Phat biéu ndo sau day khong ding’ A. Xa khdng e6 kha niing tham gia phan ting tring hop. B. X; tic dung duge véi Na va gidi phong Ho. C. X, cng voi HO (xt H’) thu duge san pham chinh la propan-2-ol. D. Khi thity phan chat béo ta luén thu duge Xs. ‘CAu 30. Chon nhiin xét ding? A. Trong dung dich, andehit c6 ca lién két hido lién phan tir va lién két hidro véi nude, xeton chi cé lién &t hidro voi nuse. B. Day sip xép theo chiéu gid dan nhiét d6 sdi tir trdi sang phdi la: n-hexan > isohexan > neohexan. C. Thity phan khong hoin toan n-peptit e6 thé thu duge (n-2) tripeptit. D. Benzen ¢6 mii thom nhe nén dure goi li hidrocacbon thom. CAu 31. Chon nhjn xét ding. A. Khi dun néng hdn hop gdm C:HsBr, KOH, C2HsOH thi khong c6 khi thoat ra. {du mach khi phn tng voi AgNOs/NHs thi khdi lurgng phan tir thay B. Trir etin, ee ankin e6 lin két 481 107 dve. C. Khi dun hon hop C:HsOH va axit HBr dén khi két thic phan tmg ta duge dung dich déng nhat, D. Cie ancol CHsOH, CHsCH:CH:0H, CH:CH:CH.CH,OH tan v6 han trong nurse. Ciiu 32. Hop chit CsHys khi tic dung voi clo c6 chiéu sang tao ra hén hgp 2 chat dong phn CsH)3Cl. Néu thay 2 nguyén tir H ca CoHj3 trén bing 2 nguyén tir clo sé tao ra hon hop gom sé lrgng dong phn la: Ad BS C6 D.7 Céiu 33. Cho cic chit sau: CHy=CH-CH,-CHs; CHy-CH=C(C:Hs)-CHs; CICH=CHBr; HOOC-CH=CH- (CHy; (CHs)sC=CH-CHs; CHBr=CH-CHh, 86 chat 66 ding phan hinh hoe li AQ B.3 C4 DS Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31,08@Gmail.com — Trang 4/14Cau 34, Khi thye hign phan img tich nude déi voi rugu X, chi thu duye 1 anken duy nhdt, Oxi hoa hoan toan lugng chit X thu duge 5,6 lit CO» (dkte) va 5,4 gam nude. Cé bao nhiéu cong thik x: A2 B.3 C4 DS edu tao phit hyp vi ‘Cu 35. Cho naphtalen tic dung véi brom c6 Fe xic tac. Sé lugng din xuat monobromnaphtalen thu duge ki: Al B.2 c.3 D4 ‘Cfu 36. Dé dit chy hoan toan | mol ancol X no, da chit, mach hé cé kha ning hda toan Cu(OH); cin mot Iugng vita di 5,5 mol O2. S6 cng thite cau tao théa man diéu kign ca X la: A6 B.S C3 D4 Cfu 37. Hop chat hitu eo X tig véi céng thie phin tir CsHiO2N2. Cho X vao dung dich NaOH dun néng thiy tao ra NHs. Mat khée khi X tic dung voi dung dich HC! tao ra hn hgp sin phim trong d6 ¢6 mudi tia aminoaxit. $6 CTCT théa man diéu A3 B4 cl D.2 cotia X as ‘Cfu 38. Khang dinh khong ding vé chat béo 1a: A. Chit béo la trieste cia glixerol véi axit béo. B. Dun chat béo voi dung dich NaOH thi thu duge san pham c6 kha nang hoa tan Cu(OH)». C. Chat béo va dau mé béi tron my cé cing thanh phan nguyén t6. D. Chat béo nhe hon nuée. ‘Cau 39, Hop chat hitu co X c6 CTPT CsHsBrs. Khi dun néng X voi dung dich NaOH dur tao sin pham hiru co cé kha nang tham gia phan img trang bac. $6 CTCT théa man diéu kign cia X la: Ad B.3 C4 D.2 Cfu 40. DHV). Khi dun néng stiren v6i dung dich KMnO, rdi axit héa thi thu durge axit hifu eo X. Sye khi etilen vao dung dich KMnO, thu duge ancol da chire Y. Thyc hign phan img este héa gitta X va Y thu duge este Z khOng 6 kha ning tic dung voi Na. Cong thie phan tir ca Z ta A. CigHsOu, B. CioHi202 C. CrotigOu D. CoHoOs Cfu 41. Cho cic chit: phenol, anilin, axit glutamic, axetilen, dimetylamin, axit axetic, axit acrylic, vinyl axetat. S6 lugng cae chat tac dung duge voi HCI la: A.6 B.4 Gs DS ‘Cfu 42. Axit cacboxylic X mach cacbon phan nhanh va c6 kha ning Lim mat mau dung dich KMnOy. X c6 tn goi li: A. axit metacrylic B. axit acrylic C. axit fomic D. axit isobutylic ‘Cau 43. Cho phan img X + aH, —““->CH, ~CH, —CH, -OH . Biét rang X mach ha, a la 86 lién ket x cia X. Sé CTCT thoa man digu kign cia X la: A2 B3 C4 DS (Cfiu 44, Nhin xét nio sau day khdng ding vé glucozo? A. Lén men glucozor chi thu dugc C2HsOH va CO>. B. Vong 6 canh cia glucozo e6 duge la do phan img eng cha nhém -OH & Cs vao lién két C=O cha hom chite andehit. C. Glucoze 06 thé tao este chita 5 gc CHsCOO trong phan tir khi tham gia phin img véi anhidrit axetic e6 mit piridin. D. Glucozo tac dung duge voi Hz (xite tée Ni, dun ndng), Cu(OH)s, dung dich AgNOs trong NH3 Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass 31,08@Gmail.com ~ Trang 5/14Cu 45. Trong cdc chit sau: amoniac, hidroflorua, metylamin, ancol etylic, axit axetic, axeton, axetandehit, glixerol, etylclorua, tristearin. Cé bao nhiéu chat trong cic chat trén ma gitta céc phin tir cia nd 66 thé cd lign két hidro? A.6. B.S. C4 D.8. Cu 46, Trong nhiing chat sau: C2Ho, CoHs, CH\OH, HCHO, CsHo, CHsCOOH 6 bao nhiéu chit duge sinh ra ti CH, bing mot pha i Al G2; D4. Cu 47. Hai hyp chat hitu co mach hé 6 céng thite phén tir ln lugt li CHsO3N2 va C3H;O2N déu téc dung. voi dung dich NaH dun néng, cho hai amin don chiie bée | thodt ra, Nhin xét ndo sau day diing vé hai hop chat hitu co trén? A. Ching déu tac dung véi dung dich brom, B. Chiang déu 1a chat ludmg tinh. CC. Phan tir cia chiing déu c6 lién két ion. D. Ching déu téc dung véi Ha (xe tie Cau 48. Phit biéu nio sau day khng ding A. Chat git rira téng hop rira t vét ban bam trén vai, da,...do lim giam stre cing bé mat cua cic chit ban. B, Chat gigt rita tong hop c6 thé gidt rita ed trong nude cig. C. Thinh phin chinh cia chét gige rira tong hgp thudng 12 natri lauryl sunfat hoge natri dodeeylbenzen- sunfonat D. Cée logi bot gidt phd bién hign nay déu c6 thinh phan chinh li hin hgp mudi natri hoge kali cua axit béo. , dun néng). Cfiu 49, Nhiing nbn xét ndo trong cée nbn xét sau Li ding? (1) Metyl-, dimetyl-, trimetyl- va etylamin 1a nhiing chit khi mii khai kh6 chiu, dc (2) Cac amin déng ding cia metylamin c6 d6 tan trong nuée giam din theo chiéu ting cia khé phan tt, (3) Anilin ¢6 tinh baz va kim xanh quy (4) Lye bazo cua ede amin ludn én hon le bazo cia amoniac. A. (1), 2). B. (2), 3), (4). C. (1), @), B). D. (1), (2), (4). Cfu 0. Khi tich nude cia glixerol 6 digu kign thich hop thu duge hyp chat hitu co X e6 cng thire CsH,O. Nhan xét nao sau day khéng ding vé X? A. Cé phan ing véi brom trong dung méi nucée B. Cong HCI theo quy tie cng Maccopnhicop. C. Cé phan ting tring hop. D. Cé phan tg tring bac. lngng Am. (Cu 51. Phat bigu sai la A. Nuéc ép tir qua chanh khdng hoa tan duge CaCOs, B. Gidm an lam quy tim hod 4a. C. Chit tay mau lam sach ede vét bin nhér nhimng phan img hoa hoe. D. Léng tring trimg gap Cu(OH); tgo thanh hgp chat c6 mau tim. Cfu 52. Khing dinh diing la A. Toluen lim mat mau dung dich thude tim ngay & nhigt d6 thudng, B, Etylamin khong e6 lign két hidro lign phan ti C. Fomandehit c6 thé tham gia phan tg trig hop. D. Lue axit ciia o-nitrophenol manh hon Ite axit ctia m-nitrophenol, Cau hoi li thuyét vé héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com - Trang 6/14Cau $3. Phat bidu dhing 1a A. Sé ding phan cdu tao mach hé, ben va tham gia phan mg trang bac img voi cng thite B. Cac axit cacboxylic no, don chire, mach ho déu khéng kim mat mau nude brom. C. Cie andehit no, mach hi déu c6 phan img e6ng hyp voi nude brom, D, Axeton khong tao duge lién két hidro yéi nude. (Cau 54, bt chiy hodn toan 0,1 mol hidrocacbon X, thu duye 0,4 mol COs va 0,4 mol HO. X kin # dung dich brom. $6 céng thite edu tg0 (khéng ké dng phan hinh hgc) thoa man diéu kign trén ctia X AL2. B.S. C4. D.3. ‘Cfiu 55. Cho cde dng phin mach nhanh cua penten tac dung v6i nude thi tao thanh san pham chinh gom: A. Hai nirgu bac 2 B. Hai rugu bie 3. C. Hai rugu bée 2 va mot rugu bie 3, D. Mot ragu be 2 va mot rugu ba 3 ‘Cfiu 56. Dot chay cdc rugu trong cing mét day dng ding thi ti 1é sé mol H2O : CO> tang din khi sé nguyén tir cacbon ting, H6i chiing cé theé nim & day ding ding nao? A, Rugu no don chire B. Rugu khong no C. Rugu thom D. Rugu no da chite ‘Cf $7. Thity phan hoan ton | tetrapeptit X thu duge 2 mol Gly, | mol Ala, 1 mol Vé tao cata peptit X la A.10 B.24 C8 D.12 |. $6 ding phan céiu ‘Cfiu 58. M6t hidrocacbon A cé céng thie la (CsHs)s, khong lim mat mau dung dich brom. S6 lién két o vi 6 lién két x trong mét phn tir A tong tg 1a: A. 18 va3 BIT va3 C.i7vad D.18 vad Cfiu 59. Phit biéu nao sau diy khdng diing? A. Metyl a-glucozit khong thé chuyén sang dang mach hé duge. B. Cé thé phan biét glucoza va fructozo bing dung dich brom. C. Cé thé phan biét glucozo va fructozo bing phan img trang guong. D. Glucozo va Fructozo la ding phan cia nhau. (Cu 60. Cho phurong trinh sau: C\H,CH=CH, +KMnO, +H,SO, > C,H,COOH + CO, + MnSO, +K,SO, +H,0 ‘Téng hé s6 nguyén, t6i gin cita céc chat tham gia phan img khi cn bang li: AI8 B14 Cs D.21 Cfu 61. Cho céc chat sau: isopren, stiren, xilen, axetilen, caprolactam, xiclohexan, xenlulozo. C6 bao nhiéu chat khong cé kha nang tham gia phan img tring hop. Al Ba C2 D.3 Cu 62. Hop chit hitu eo X e6 Ong thie phiin tir CHsO:Ch. Khi thay phan X trong moi trudng kiém thu duge nhiéu sin phim, trong 46 6 ha tao phi hop v6i X li AS B.2 C4 D3 ft c6 kha ning tham gia phan dng tring guong. $6 cdng thite edu Cfu 63. Trong cic phin tir polime: tinh bét (amilozo) (1); xenluloze (2); tinh bot (amilopectin) (3); poli(vinyl clorua) (4); nhya phenolfomandehit (5); nhing phan tt polime c6 edu tao mach thing la: A. (3), (4) va (2) B. (2), (4) va(5) C. (2), 3) va (4) D. (1), (4) va (2) Cfiu 64, Dau m6 dé lau bj 6i thiu li do: ‘A. Chit béo bj pln hy thal ee andehit &6 mdi kh ehju, Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass 31,08@Gmail.com ~ Trang 7/14B. Chat béo bj thiy phan voi nude trong khong khi. C. Chat béo bj hidro hoa. D. Chat béo bj oxi héa cham béi oxi khong khi. ‘Cfiu 65. Chat nao sau day duge ding lam thuéc né khong khoi: A. Xenlulozo triaxetat, B. Glicogen. C. Sobitol. D. Xenlulozo tri Cfiu 66. C6 4 chat hitu co ki: CHsCOOH (1); C:HsOH (2); CeHsOH (3); CICHs-COOH (4). Thir tur ede chit trén theo chiéu gidm dan tinh axit tir trai qua phai la: A.2),8),4),() B. (1), 4), 3), 2) C.4),(1), 8), 2) D.2),G),(4),() ‘Cfiu 67. Nhan xét no sau day khong ding? A. Brom tham gia phan ting véi ankan wu tién thé yao Cacbon bac cao. B. Khong thé tgo ra din xuat iot cia hidrocacbon bing cdich cho iot phan img voi ankan, C. Propan tic dung véi clo theo ti 18 1:1 thu duge sin phim chinh n-propylelorua. D. Benzylclorua dé thiy phan hon so véi metylclorua. t. (Cfu 68. Nguyén nhan ndo sau day gay ra tinh bazo eta amin? A. Do phan tir amin bj phan eve. B. Do amin dé tan trong nue. C. Do amin 6 kha ning téc dung voi axit. D. Do nguyén tir nite cén ep electron ty do. (Cfiu 69. Trong thyc té, phenol duge ding dé san xudt cac chat trong day: A. poli(phenol fomandehit), chit diét 6 2.4-D va axit pieric. B. nhya poli(vinylclorua), nhya novolac va chat diét co 2,4-D_ C. nhua rezol, nhya rezit va thude tri siu 666 D. nhya rezit, chat digt c6 2,4-D vi thue nd TNT. ‘Cau 70, Chat hiru co X thinh phan chita C, H, Cl trong dé clo chiém 71,72% vé khéi lugng. Chat X 6 sé dng phan mach ho lit Ad B.3 C4 D.S (CA 71. Cho ba chat hiru co mach ha: CoH (X), C3Hy (Y), CH (Z). Nhain xét nao sau day ding? ALX, Y,Z la ding ding ké B. Ba chit trén khong thé la dng diing ciia nhau. C.X va la dong Z 6 thé ciing day dong dang voi X, Y. D. Ba chat trén c6 thé ciing day déng ding hoje khong phai la déng ding cia nhau, (Cfu 72. Chit 3-MCPD thudng lin trong nude tuong va 6 thé gay ung ther. Chit nay 06 edng thite ed A, CH(OH)2-CH-CH,Cl B. CH,OH-CHCI-CH2OH C. CH CHCLCH(OH): D. CHsCl-CHOH-CH;OH Cfu 73. Anken diéu kign thudng 6 thé khi, khi cong HBr chi thu duge mét sin pham duy nhat c6: A. L chat B. 2 chat C.3 chit D.4 chat ‘Cfu 74. Oxi héa hoan toan ancol sec butylic bing CuO nung néng, thu duge chit hitu co X. Tén goi cua X is A.etyl metyl xeton —_B. 2-metylpropanal C. dimetyl xeton D. metyl propanon Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31,08@Gmail.com - Trang 8/14CAu 75. Khi oxi héa regu etylic bing dung dich KMnO, thu duge mot két ta mau ndu den, phan ting nhur sau: KMnO, + C3HsOH —+ CH:COOK +... ‘Sau khi can bang phuong trinh tng cac hé sé nguyén tdi gidin 1a: AAS B19 C.22 D.20 CAu 76. Trong cae céng thite phan tir sau; CHyO2, CsHsO2, CsHsO2, CxH¢Os, CyHyO2, C2HeO2. $6 chit 06 dng phan este la: AB B.S C4 D.6 Cau 77. Hn hgp g6m hidrocacbon X va oxi cé ti Ig sé mol tuong img la 1:10. Dot chiy hoan toan hén hop trén thu duge hén hop Khi Y. Cho Y qua dung dich H»SOs dic thu duge hin hop Khi Z ¢6 ti kh6i v6i hidro bing 19. Sé dng phin céu tao cia X e6 kha nding lim mat mau dung dich brom li: AS B.6 C4 D.3 Cfiu 78, X 06 c6ng thire phin tit CsH)20sNe, khi cho X téc dung véi dung dich NaOH dur, dun néng thi phan hoi thu duge mét chat hit co no, don chite, bée 1, mach hé va phan rin chi chira chat v6 co. $6 céng thire cu tgo phu hyp X la: Ad B.S C7 D.10 Céu 79. Triglixerit la este ba ln este ciia glixerol. Khi dun néng glixerol v6i hdn hop 4 axit CisHs)COOH, (CipHysCOOH, CysHs;COOH vai CiHy;COOH thi thu duge t6i da bao nhiéu triglixerit? A.40 B.27 C.48 D.54 (Cu 80. Ba hidrocacbon X, Y, X ké tiép nhau trong cing day déng dang, khOi lnong phan te cia Z gap d6i khdi hrong phan tir ctia X. Khi cho cée déng phén cdu tao cia ba chit nay cng HBr, sé déng phan céu too cchi sinh ra mt sn phim duy nit Li A3 B.2 ca DS Cfu 81. To nilon-6,6 gidng nhur ec logi to thude logi poliamit Khae, duge sit dung rng rdi trong nbigu Tinh ‘vue cita di séng vi ching 6 dae tinh: A. bén voi méi truéng kiém B. bén voi méi truing axit C. 06 d6 ben co hoc cao D. bén voi nhigt (Cfu 82. Khi dun néng glixerol véi chat xtc tic thich hgp né téch nude dé tao thanh sin phim hi co. Ti khdi cia X so véi hidro la 28. Tén goi ciia X la: A. propenal B. propinol C. propenol D. propenon ‘Cfu 83. DSPs. Cho propin tic dung vai dung dich KMnO, sau khi phan img xay ra hoan toan, sin phim thu duge gbm: A. CHCOOK, KHCOs, MnOs, HO B, CH}COOH, CO», KOH, Mn0s, HO C. CHsCOOK, K2COs, KOH, MnO», H2O. D. CHsCOOK, K:COs, KHCOs, MnO, HO (Cfiu 84, Vai cong thie CsHsO, s6 dong phin cau tao, mach ho, lim mat mau dung dich brom 6 diéu kign thudmg Li: AT B.6 ca DS ‘Cfu 85, Mét andehit no, mach hé A o6 cng thire (CH;O),. Tir A diéu ché caosubuna tdi thiéu qua: A.3 phi img B.4 phin img C.2 phan ting D. 5 phan img ‘Cfiu 86. X la hop chat thom c6 céng thie phan tir C7HsO> tic dung véi dung dich Br tao ra duge din xuat tribrom. X tée dung voi dung dich NaOH theo t1@ mol 1:1. $6 déng phn X bi: Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass 31,08@Gmail.com — Trang 9/14Ad B.S C6 D.2 CAu 87. Nhgn dinh nao sau day khng ding? A. Phin tit mantoze do 2 géc a-glucozo lién két véi nhau qua nguyén tir oxi, géc thir nhat 6 C;, géc thir hai 6 CAC1-O-Cs) B. Phan tir saccarozo do 2 gc a-glucozo va B-fructozo lién két voi nhau qua nguyén tir oxi, gdc o- glucozo 6 Ci, ge PHfiuctoze 6 C(C1-O-Cs) C. Tinh bét 6 2 loai lién két a-[1,4]}-glicozit va a-[1,6}-glicozit D. Xenlulozo c6 cdc lién két B-[1,4]}-glicozit Cfiu 8. Chon phat biéu ding. A. Hidrocacbon C;Hon ¢6 3n— I lién két 6 trong I phan ti. B. Céc andchit no, don chtte, mach hé phan img véi brom trong nude tgo thanh axit eacboxylic. C. Tritetilen, cde anken mgch thing e6 ndi doi 6 C2 tée dung vi HBr déu tgo 3 ding phan. D. Cae déng phin este cia CsHsO2 déu phan img voi NaOH theo ti Ig mol 1:2 ‘Cfiu 89. Cho cde polime sau: PE (1), PVC (2), cao su buna (3), poli isopren (4), amilozo (5), amilopectin (6), xenlulozo (7), cao su Iu hoa (8), nhya rezit (9). Cie polime 6 cau trite Midng phan nhdinh i A. 1,2,3,4,6,7. B. 1,3,4,5,8. C.12,4,68. D.1,2,3,4,5,7. Cfiu 90, CNH). Trong c: it : propen (I); 2-metylbut-2-en(II) ; 3,4-dimetylhex-3-en(III) ; 3-cloprop-1- en(IV) ; 1,2-dicloeten (V), chat nao c6 déng phan hinh hge : AJAY B.1, 11, IL IV C1, V DLV Cfu 91. Nhan dinh nao sau day khéng ding? A. Axeton khong Lim mat miu dung dich KMnO, 6 digu kign thuring. B. Cac xeton khi cho phan img véi Hp déu sinh ra ancol bic 2. . Trit axetilen, cic ankin khi cong nude déu cho sin phim chinh la xeton, 6 chtra nhém ~CH=O cé thé phan ing hofic khong phan tng véi dung dich Br. D. Cie hop cl Cfiu 92. C6 cac nh§n xét sau: 1- Chat béo thuge loai chat este. 2- To nilon, to capron, to enang déu diéu ché bing phan img tring ngung. 3- Vinyl axetat khong diéu ché duge truc tip tir axit va ancol twong tng. 4- Nitro benzen phan tmg vii HNO; da (xtc tac H2SO, dac) tao thanh m-dinitrobenzen. 5- Phenyl amoni clorua phan img véi nude brom dur tao thanh (2,4,6-tribromphenyl) amoni clorua. Nhiing cau dhing la: A.1,3,4. B. 2, 3,4. C. Tat ca. D.1,2,4, 5. Cu 93. Cho cic chit sau: axetilen, axit oxalic, axit acrylic, fomandehit, phenyl fomat, vinyl axctilen, glucézo, andehit axetic, metyl axetat, saccaroza, natri fomat, axeton, $6 chit ¢6 thé tham gia phan img tring gurong la A6 B8 C7 DS Cfiu 94. Cho cae phan img: a) HBr + C)HsOH — b) CHy + Br: > ¢) CzHy + HBr — d) GH, + Bry 5h) CoH> + 2HBr > 9) GoH,Br; + Mg > 'Sé phan img tao ra ety! bromua la Ad B.2 c.3 mt ‘Cu 95. Cho ede phat biéu sau: Cau héi Ii thuyét v8 héa hac hitu co 2012 LemonGrass.31,08@Gmail,com ~ Trang 10/14a) Chat béo la trieste ctia glixerol vGi cdc axit monocacboxylic cé sé chin nguyén tir cacbon, mach ccacbon dai khong phan nhnh, b) Lipit gdm chat béo, sip, steroit, photpholipi ©) Chit béo la ede chat long d) Chat béo chita chi yéu cde gée khong no cita axit béo thudng la chat long 6 nhigt 6 phong va duge goi La dau ) Phan img thay phan chat béo trong moi trdng kiém ta phan img thugn nghich g) Chat béo la thanh phin chinh cita diu, mo déng thye vat Nhiing phat biéu diing la Ac, de B.a,b, de C.a,b,d.g D.a,b,e Cfiu 96. Cho cée nhin dinh sau: a) Sacearozo va glucozo déu cé phan ting trang bac b) C6 thé ding chi Cu(OH)2 dé nhan biét ede lo mat nhan chita Glixerol, Glucozo, Fructozo, Etanal ©) Trong sor dd digu ché: Xentulozo—“°"_5 xs", y_BOMOsWE 7 Vay 1a divinyl 4) G dang mgch he, glucozo e6 § nhém -OH canh nhau ©) Trong phan tir amilopectin, ce ge a-glucozo lién két vii nhau béi cic glicozit g) Xenlulozo c6 cdu tric mach phan nhanh. h) Nho dung dich H,SO, dae vio vai soi bong, vai bi den va thing ngay do phin ing H:SO, oxi hoa tinh bot Ce nhan dinh ding 1a Acde B.aboh Cdeh D.bdeg Cf 97. Cho amin X tée dung v6i CHsI thu duge amin Y bée Ill e6 eéng thite phan tir i CsHisN. Hay cho biét X c6 bao nhiéu cng thie edu tao? AS B3 C2 D4 én ket a-1,4- va -1,6- CA 98, Sé hidrocacbon 6 thé khi ¢6 thé tic dung duge voi dung dich AgNO trong NHs la: A2 Bd C3 DS Ciu 99, Cho cic chit sau: divinyl, toluen, etilen, xiclopropan, stiren, vinylaxctilen, propilen, benzen. Sé chat lam mat mau dung dich KMnO, & nhiét 46 thurng 1a: Ad. B.5. C.7. D.6 Céu 100. X c6 cng thire phan tir i CsHsCh. Thily phan X trong dung dich NaOH dun néng thu durge chit hitu co ¥ ¢6 kha nang téc dung vi Cu(OH):. Hay cho biét X ¢6 bao nhiéu cOng thire edu tao théa main tinh cchat trén? AB BS Ga D4 Cfiu 101, Nhjin xét nio sau day khdng ding? A. To poliamit kém bén trong cic méi trudng axit va bazo. B. Khi cho fomandehit dur te dung véi phenol, c6 bazo xite tac thu durge nhura novolac. C, Saccarozo khong tao két tia khi cho vao dung dich AgNO; trong NH D, To xenluloza axetat thude loai to héa hoc Cfiu 102. Cac chat déu khéng bj thuy phan trong dung dich H2SO, loang, néng 1a A. poli (vinyl axetat); polietilen, cao su buna B. to capron; nilon-6,6, polietylen C. nilon-6,6; poli(etylen-terephtalat); polistiren D. polietilen; cao su buna; polistiren Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com—Trang 11/14CAu 103. Cho cée chat sau: CHsCOOCH;CHSCI, CIHsN-CH;COOH, CHCl (thom), HCOOCsHs (thom), CéHsCOOCHS (thom), HO-CsHy-CH:OH (thom), CHsCCh, CHsCOO(CI)>-CHs, HCOOC«HACI (thom). Co bao nhiéu chat khi tac dung voi NaOH dac du, & nhiét dO va ap suat cao tao ra san phim cé chira 2 mi AS B4 C6 D.7 CAu 104. So sinh tinh bazo eiia cée chét sau: (1) Natri axetat; (2) Natri phenolat; (3) Natri etylat; (4) Natri hidroxit: A.Q)<(). (8) Axit no da chite €6 céng thire don gidn la (C3H,Os)p. Cong thite edu tgo phit hop v6i edng thire nay 1a CH(COOH) -CH(COOH)-CH(COOH), 86 phat biéu diing la Cau hoi li thuyét vé héa hoc hitu co 2012 kemonGrass.31.08 @Gmail.com - Trang 12/14AS B.4 C6 D.2 Cafu 111. Tir etilen va benzen, chat vo co va diéu kign phan img c6 dit. Tong s6 phan tig it nhat dé c6 thé digu ché duge polibutadien, polistiren, poli (butadien - stiren), poli (vinyl clorua) li: AOI B.12 c.13 D.10 ‘CAu 112. Cho céc phat biéu sau: (a) Thye hién phan img este héa gitta butan-1,2-4-triol va hén hgp axit axetic, axit fomic trieste t6i da thu durge la 8. (b) Dé digu ché CHsCH;-C(OH)(C2Hs)CHs ta cé thé diing anken thich hgp 1a 3-etylbut-2en. (c) Taco thé diing it nhat 4 phan ting dé tir nhm cacbua diéu ché but-1,3-dien. (d) Ta c6 thé ding it nhat 2 phan ing dé tach anilin khdi hn hop anilin, benzen, phenol. (e) Ta ¢6 thé ding nude brom hoge dung dich thudc tim dé nhin biét propilen hoc xiclopropan hat bigu diing li: A.2 B3 C4 DS Cau 112. Cho diy chit: tip tgo ra CoHsCl las A> B.2 cl D4 “>He, CoHo, CoH, CoH, CH, CoHsOH. $6 chat trong day bing mét phan img tre ‘Cfu 113, Nhan dinh nao sau day sai: A. Ban chat cau tao cia sgi bing la xenlulozo. B. Ban chat cdu tao héa hoc cita to nilon la poliamit. C. Quan 4o nilon, len, to tim nén duge gigt véi xd phong c6 dé kiém cao. D. Cée nhan dinh khée déu ding. CA 114, Cho cée chit: C,H,OH, CH,COOH, C,H,OH, C,H,ONa, CH,COONa, C,H,ONa, H;0,HICI, Cu(OH), .CH, nhau li: A. 10 B.9 cil D. 12. ‘Cfiu 115, Cho cde phat biéu: (a) Este cita glixerol va axit béo duge goi la chat béo (b) Chit béo cé tn goi chung Ia glixer (©) Tripanmitin cn 6 tn goi khéc 1a tripanmitoylglixerol (d) Chat béo la thanh phan chinh cua dau mé dong thye vat (¢) Xa phong la mudi natri hoae kali cia axit béo. (0 Phan ting cia chit béo v6i dung dich kiém duge goi li phan img xa phéng hoa (g) Glixerol tan v6 han trong nude (h) Dau ma bj 6i do phan tng hidro hod cic géc axit béo khdng no 6 phit biéu khéng ding trong cde phat biéw trén 18: AQ Ba as Ds 'H —CH,, Trong s6 cic cap chit duge tao tir cde chat trén, s6 cap chat phan img voi ‘Cau 116. Cho cac phat biéu sau: (a) Thude trir situ 666 duge san x ing phan img thé clo vao phan tir benzen. (b) Benzen bj oxi héa bai thude tim 6 80-100°C. (c) Etylbenzen duge diéu ché bing phan img gitta etilen vi benzen. (a) Cé thé nhéin biét benzen bing phan ting véi hin hyp HNOs die vi H:SO, dm dic tao chat hiru co mau vang, mii hanh nhan. (€) Benzen e6 thé hoa tan duge brom, iot, hru hujnh, Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com Trang 13/14(1) Benzen e6 mii thom nhe, nhung ¢6 hai cho sire khoe. (g) Sau nguyén tir C trong benzen déu lai hoa sp’. 'Sé phat biéu ding 6 trén la: AB B4 co DS (Cf 117. Cho ede nh§n dink sau vé dn xuat halogen: (@) Khi goi theo tn thay thé, ta coi céc nguyen tir halogen trong phin tir chét din xult 1a ning, nbom the. (b) Cac din xuat halogen CHI, CCly, CH2Cl., CHC; & thé long trong diéu kign thudng. (c) Lign két trong phan tir dan xuat halogen khéng phan cye nén ching hau nhu kh6ng tan trong nude. (4) Ankyl halogenua khong phan ting véi nude 6 nhigt d6 thurimg cing nhu khi dun sai. (e) Dun séi dung dich gsm C,HsBr va KOH trong rugu etylic, rdi din sin phim qua dung dich brom thi xuit hign cdc gigt chat long khéng tan trong nude. () CCl, duge ding kim dung méi vi ching hoa tan duge nhieu hgp chat phan cye va khong phan eye. (g) Ding lam thude gay mé, ha chit digt siu bo, sit dung trong may lanh 1a mot s6 ing dung cia céc din xuit halogen. (h) Dun néng anlyl bromua véi nude & nhigt d6 thich hgp c6 xiic tée axit e6 thé thu duge propan-1,2-diol. ‘6 nhdn dinh ding o wén la: Ad BS er D.6 Cf 118. Nhin dinh no sau day king ding? A. Axeton khéng lim mat mau dung dich KMnO, 6 diéu kign thuong. B. Céc xeton khi cho phan img véi Hz déu sinh ra ancol bac 2. C. Trit axetilen, cde ankin khi cOng muée déu cho san phim chinh la xeton. D. Axetophenon cin cé tén goi Khe Li metyl benzyl xeton. Cfiu 119. Cho ede chat va dung dich sau: benzen, toluen, stiren, etilen, xiclopropan, o-crezol, dung dich natri phenolat, nitrobenzen, vinyl axetat, etyl acrylat, metyl fomiat, foocmon, axeton. $6 chat va dung dich cé thé Jam mat mau dung dich Br2 (chi diing xtic tac dnh séing hodie mhigt db) la AB. B11 C10 D9 (Chiu 120, Phat biéu Alidng ding la: A. Anken C:Hjo 6 5 déng phan edu tao. B. Dé phan biét cdc hidrocacbon no cé cng thie phan tir CsHs, ta c6 thé ding nude brom C. Bét chy hoan toan mdt hidrocacbon thi khéi Iugng CO? thu duge luén én hon khoi lrgng H2O D. Néu mét hidrocacbon tac dung voi AgNOYNHs durge két tiia vang hidrocacbon dé li ankin Version 1.0. Cie cétu héi lay tie dé thi thie dai hoc ctia cae truéng THPT trén cé med nim 2011-2012 va tie ce nguén dé hiv te Internet. Moi thac mac vé ctu hoi va dap dn xin lién hé lemongrass.3 1.08@gmail.com Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31.08@Gmail.com Trang 14/14