GV: HU NH

T: 0942235658

NHN DY N THI H

Este
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A- Kim tra
Cu 1: Trung ha a mol axit hu c A cn 2a mol NaOH. t chy a mol A c 2a mol CO2. A l
A. CH3COOH
B. HOOCCOOH.
C. Axit n chc no. D. Axit n chc khng no.
Hng Dn
Gi CT axit l R(COO)k
T/d vi NaOH
R(COO)k + k NaOH R(COONa)k + k H2O
a
ka
ka = 2a k = 2
P chy a mol A c 2a mol CO2 A c 2 cacbon v 2 nhn chc B
Cu 2: Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca
Z). t chy hon ton a mol X, sau P thu c a mol H 2O. Mt khc, nu a mol X T/d vi lng
d dd NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l
A. 46,67%
B. 40,00%
C. 25,41%
D. 74,59%
Hng dn:
a mol X a mol H2O ch s H = 2 vi a mol X 1,6 mol CO2 c 1 axit 2 chc
HCOOH x mol
x + y = 1 v x + 2y = 1,6 x = 0,4 v y = 0,6

HOOC COOH y mol

%Y =

0,4.46
= 25,41%
0,4.46 0,6.90

Cu 3: t chy hon ton 0,1 mol cht X l mui Na ca mt axit hu c thu c 0,15 mol CO2,
hi H2O v Na2CO3. CTCT ca X l
A. C3H7COONa.
B. CH3COONa.
C. CH3CH2COONa
D. HCOONa.
Hng dn:
Nhn v p n th y l mui ca axit hu c no n chc
2CnH2n+1 COONa + O2 (2n + 1)CO2 + (2n + 1) H2O + Na2CO3
0,1
0,05.(2n+1)
mol
Vy 0,05(2n+1) = 0,15 n = 1 B
Cu 4: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h
l ng ng lin tip. t chy hn hp X v cho sn phm chy ln lt qua bnh 1 ng H2SO4
c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y
cn li sau khi t l Na2CO3 cn nng 2,65 gam. CTPT ca hai mui natri l
A. C2H5COONa v C3H7COONa.
B. C3H7COONa v C4H9COONa.
C. CH3COONa v C2H5COONa.
D. CH3COONa v C3H7COONa.
Hng dn:
2H COONa + O2 CO2 + H2O + Na2CO3

GV: HU NH
T: 0942235658

0,01
2CnH2n+1 COONa +
a

NHN DY N THI H

0,005 0,005 0,005

O2 (2n + 1)CO2 + (2n + 1) H2O + Na2CO3
0,5.a (2n+1) 0,5.a (2n+1) 0,5.a mol

mol

CO2 0, 005 0,5a (2n 1)

26 0, 005 0,5a(2n 1) 3,51

mCO2 mH 2O 3,51
H 2O 0, 005 0,5a(2n 1)

2, 65
m

2,
65
0,
005

0,5
a

Na
CO
Na CO 0, 005 0,5a

2
3
106

2
3

Cu 5: B sung dy chuyn ho sau:

3
(1)
(2)
( t oCaO
C2H5OH
A
B
C
HCHO.
)
A. (A). CH3CHO ; (B) CH3COONa, (C) C2H4
B. (A) CH3CHO ; (B) CH3COONa , (C), CH4
C. (A). CH3CHO ; (B): HCOONa , (C) CH4
D. (A). CH3COOH; (B).C2H3COONa; (C)CH4
Cu 6: Chia 23,6 gam hn hp gm HCHO v cht X l ng ng ca HCHO thnh 2 phn bng
nhau. Phn 1, cho T/d vi H2 d (t0C, xc tc), sau P thu c 12,4 gam hn hp ancol. Phn 2,
cho T/d vi dd AgNO3/NH3 d thu c 108 gam bc. CTPT ca X l
A. C2H3CHO
B. (CHO)2
C. CH3CHO
D. C2H5CHO
Hng Dn
Cch 1: Loi A v B v X l ng ng ca HCHO, ti y c th th nghim chn c D.
Cch 2: HCHO ( x mol); RCHO ( y mol), c x + y = (12,4 23,6 : 2) : 2 = 0,3 mol
V 4x + 2y = 1 mol; 30x + My = 11,8; gii h c M =58 vC => RCHO l C2H5CHO
Cu 7: Cho cc pht biu:
(1) Ru bc 1 oxi ha khng hon ton ra Anehit
(2) Tt c cc axit cacboxylic u khng tham gia P trng bc
(3) P thy phn este trong mi trng axit l P thun nghch
(3) Tt c cc ancol no, a chc u ha tan c Cu(OH)2
Pht biu ng l
A. (2) v (4)
B. (3) v (4)
C. (1) v (3)
D. (1) v (2)
Cu 8: Chia hn hp X gm hai anehit no, n chc, mch h thnh hai phn bng nhau :
- Phn 1 : em t chy hon ton thu c 5,4 gam H2O.
- Phn 2 : Cho T/d ht vi H2 d (Ni, to) thu c hn hp Y. t chy hon ton hn hp Y, thu c V
lt CO2 (ktc). Gi tr ca V l
A. 3,36 lt
B. 4,48 lt
C. 1,12 lt
D. 6,72 lt
Hng Dn
- Theo LBT nguyn t Cacbon
- nCO2 ( P1 ) nCO2 ( P2 ) nH 2O 0,3 mol
VCO2 = 0,3.22,4 = 6,72 lt
Cu 9: Cho s chuyn ho sau: HCOONa A C2H5OH B D (COOH)2
Cc cht A, B, D c th l
A. H2 ; C4H6 ; C2H4(OH)2
B. H2 ; C2H4 ; C2H4(OH)2
C. CH4 ; C2H2 ; (CHO)2.
D. C2H6 ; C2H4(OH)2.
Hng Dn
HCOONa

NaOH
xt Cao ,t o

H 2 SO4
H2
CH3CHO
C 2 H 5OH 170
o
C

C2 H 4

KMnO4

C2 H 4 OH 2

CuO

COOH 2

Cu 10: Cho 19,8 gam m t anehit n chc A P hon ton vi dd AgNO3/NH3 (d). Lng Ag
sinh ra P ht vi dd HNO3 long c 6,72 lt NO ktc. A c CTPT l

GV: HU NH
T: 0942235658

A. C2H4O.

NHN DY N THI H

B. C3H6O.

C. C3H4O.

D. C4H8O.

Hng Dn
19,8
(mol )
R 29
Ag2O NH 3
RCOOH

Goi CT l RCHO:
RCHO

+ 2Ag

19,8
2.19,8

R 29
R 29
T/d HNO3
3Ag + 4HNO3 3 AgNO3 + NO + 2H2O
2.19,8
2.19,8

3( R 29)
R 29
2.19,8
6, 72

R 15 CH 3CHO
Ta c
3( R 29) 22, 4
Cu 11: un nng 66,4 gam hn hp 3 ancol n chc vi H2SO4 c thu c 55,6 gam hn hp
6 ete vi s mol bng nhau. S mol ca mi ete l
A. 0,1 mol
B. 0,2 mol
C. 0,5 mol.
D. 0,3 mol
Hng Dn
p dung LBTKL:
mAcol mete mH 2O mH 2O 66, 4 55, 6 10,8 gam nH 2O 0, 6 mol
Ta c
0, 6
0,1 mol
6
Cu 12: A c CTPT l C8H8, T/d vi dd KMnO4 nhit thng to ra ancol 2 chc. 1 mol A tc
dng ti a vi:
A. 4 mol H2; 1 mol brom.
B. 3 mol H2; 1 mol brom.
C. 3 mol H2; 3 mol brom.
D. 4 mol H2; 4 mol brom.
Cu 13: Cho cc pht biu sau:
(a) Anehit va c tnh oxi ha, va c tnh kh.
(b) Phenol tham gia P th brom kh hn benzen.
(c) Anehit T/d vi H2 (d) c xc tc Ni, un nng, thu c ancol bc I.
(d) Dd axit axetic T/d c vi Cu(OH)2.
(e) Dd phenol trong nc lm qu tm ha .
(f) Trong cng nghip, axeton c sn xut t cumen.
S pht biu ng trong s cc pht biu trn l:
A. 4 .
B. 3.
C. 5.
D. 2.

ete

nH 2O 0, 6 mol n1ete

Cu 14: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy
ng ng T/d vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t
hn c trong X l
A. 3,0 gam.
B. 4,6 gam.
C. 7,4 gam.
D. 6,0 gam.
Hng Dn
Gi CTTB ca 2 axit no, n chc, mch h, k tip trong cng dy ng ng Cn H 2 n 1COOH
T/d Na

GV: HU NH
T: 0942235658

Cn H 2 n 1COOH Na Cn H 2 n 1COONa

NHN DY N THI H

1
H2
2

13, 4
13, 4

14n 45
14n 45
13, 4
17,8

n
14n 45 14n 68

mol

Cu 15: Cho 4 hp cht c CTPT l M : C3H6O ; N : C3H6O2 ; P : C3H4O ; Q : C3H4O2.

Bit : M v P cho P trng gng ; N v Q P c vi dd NaOH ; Q P vi H2 to thnh N ; oxi
ha P thu c Q.
a) M v P theo th t l
A. C2H5COOH ; CH2=CHCOOH.
B. C2H5CHO ; CH2=CHCHO.
C. CH2=CHCOOH ; C2H5COOH .
D. CH2=CHCHO ; C2H5CHO.
b) N v Q theo th t l
A. C2H5COOH ; CH2 = CHCOOH.
B. CH2=CHCOOH ; C2H5COOH.
C. C2H5CHO ; CH2=CHCHO.
D. CH2=CHCHO ; C2H5CHO.
B- L thuyt
1) CTCT
- Ca este n chc : RCOOR
- Ca este no n chc : CnH2nO2
2) Danh php
Tn Este = Tn gc hirocacbon ca ru + Tn axit ( trong ui oic i thnh at)

3) ng phn
- ng phn Axit
- ng phn este
- ng tp chc
- ng phn mch vng
Lu : CnH2nO2 c th c cc ng phn sau:
- ng phn cu to:
+ ng phn este no n chc
+ ng phn axit no n chc
+ ng phn ru khng no c mt ni i hai chc
+ ng phn ete khng no c mt ni i hai chc
+ ng phn mch vng (ru hoc ete)
+ ng phn cc hp cht tp chc:
Cha 1 chc ru 1 chc anehit

GV: HU NH
T: 0942235658

NHN DY N THI H

Cha 1 chc ru 1 chc xeton

Cha 1 chc ete 1 chc anehit
Cha 1 chc ete 1 chc xeton
Mt ru khng no v mt ete no
Mt ete khng no v mt ru no
- ng phn cis tran (ng phn ru khng no c mt ni i hai chc - ng phn ete khng
no c mt ni i hai chc - Mt ru khng no v mt ete no - Mt ete khng no v mt ru no)

- S ng phn este no n chc =2n-2 (1< n < 5)

- Cng thc tnh s triglixerit to bi glixerol vi n axit carboxylic bo =n2(n+1)*1/2
4) T/c vt l
- Cc este l cht lng hoc cht rn trong iu kin thng,
- Cc este hu nh khng tan trong nc.
- C nhit si thp hn hn so vi cc axit hoc cc ancol c cng khi lng mol phn t hoc
c cng s nguyn t cacbon. do gia cc phn t este khng to c lin kt hiro vi nhau v
lin kt hiro gia cc phn t este vi nc rt km.
Th d:
CH3CH2CH2COOH
CH3[CH2]3CH2OH
CH3COOC2H5
0
(M = 88) ts =163,50C

(M = 88), ts0 = 1320C

0
(M = 88), ts = 770C

Tan nhiu trong nc

Khng tan trong nc
Tan t trong nc
- Cc este thng c mi c trng
Iso amyl axetat c mi chui chn
Etyl butirat v etyl propionat c mi da
Geranyl axetat c mi hoa hng
5) T/c ha hc
a) Thy phn trong mi trng kim(P x phng ha)
0
R-COO-R + Na-OH t
R COONa + ROH
b) Thy phn trong mi trng axit:
0
H ,t
R-COO-R + H-OH
R COOH + ROH
* Nu Phng php P chuyn dich theo chiu thun
c) Ch :
- Este + NaOH to 1Mui + 1 anehit
Este ny khi P vi dd NaOH to ra ru c nhm -OH lin kt trn cacbon mang ni i bc
1, khng bn ng phn ha to ra anehit.
VD:
R-COOCH=CH2 + NaOH to R-COONa + CH2=CH-OH
p ha
CH3-CH=O
- Este + NaOH to 1 Mui + 1 xeton
Este ny khi P to ru c nhm -OH lin kt trn cacbon mang ni i bc 2 khng bn ng
phn ha to xeton.
to
RCOOC=CH + NaOH R-COONa + CH2=CHOH-CH3
2

CH3

p ha
CH3-CO-CH3
Este + NaOH to 2 Mui + H2O
Este ny c gc ru l phenol hoc ng ng phenol..

RCOO

HCOOR

+ 2AgNO3

+ 2NaOH

t RCOONa
o

+ C6H5ONa + H2O

Este + AgNO3/ NH3 P trng gng

+ 3NH3 + H2O ROCOONH4 + 2Ag

+ 2NH4NO3

GV: HU NH
T: 0942235658

NHN DY N THI H

- Este no n chc khi chy thu c nCO2 nH2O

d) P chy
0
3n 2
CnH2nO2
O2 t nCO
2 nH2O
2
6) iu ch
a) P ca ancol vi axit cacboxylic
0
H ,t
RCOOH + ROH
RCOOR + H2O
b) P ca ancol vi anhirit axit hoc anhirit clorua
+ u im: P xy ra nhanh hn v mt chiu
(CH3CO)2O + C2H5OH CH3COOC2H5 + CH3COOH
CH3COCl + C2H5OH CH3COOC2H5 + HCl
c) /c cc este ca phenol t P ca phenol vi anhirit axit hoc anhirit clorua(v phenol khng
T/d vi axit cacboxylic)
(CH3CO)2O + C6H5OH CH3COOC6H5 + CH3COOH
CH3COCl
+ C6H5OH CH3COOC6H5 + HCl
d) P cng vo hirocacbon khng no ca axit cacboxylic
+ An Ken
0
CH3COOH + CH=CH xt, t
CH3COOCH2 CH3
+ Ankin
0
CH3COOH + CHCH xt, t
CH3COOCH=CH2
C- Bi tp
V d - L thuyt
Cu 1: C cc nhn nh sau :
(1) Este l sn phm ca P gia axit v ancol
(2) Este l hp cht hu c trong phn t c nhm - COO (3) Este no, n chc, mch h c CTPT l CnH2nO2, vi n 2
(4) Hp cht CH3COOC2H5 thuc loi este
(5) Sn phm ca P gia axit v ancol l este
Cc nhn nh ng l:
A. (1), (2), (3), (4), (5).
B. (1), (3), (4), (5) .
C. (1), (2), (3), (4).
D. (2), (3), (4), (5).
Cu 2: Pht biu no sau y l ng?
A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn
dng thuc th l nc brom.
B. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng
nghip thc phm, m phm.
C. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c
mi thm ca chui chn.
D. Trong phn ng este ha gia CH3COOH vi CH3OH, H2O to nn t -OH trong nhm
-COOH ca axit v H trong nhm -OH ca ancol.
Cu 3: Metyl propionat l tn gi ca hp cht:
A. CH3COOC2H5
B. CH3COOC3H7
C. C3H7COOCH3
D. C2H5COOCH3
Cu 4: Mt este n chc no mch h c 48,65 % C trong phn t th s ng phn este l:
A. 1
B. 2
C. 3
D. 4
Cu 5: C3H6O2 c 2 ng phn T/d c vi NaOH, khng T/d c vi Na. CTCT ca 2 ng
phn
A. CH3COOCH3 v HCOOC2H5
B.CH3CH2COOH v HCOOC2H5
C. CH3CH2COOH v CH3COOCH3
D. CH3CH(OH)CHO v CH3COCH2OH
Cu 6: S hp cht n chc c cng CTPT C4H8O2, u T/d vi dd NaOH

GV: HU NH
T: 0942235658

NHN DY N THI H

A.3
B.4
C.5
D.6
Cu 7: Cc ng phn ng vi CTPT C8H8O2 (u l n xut ca benzen) T/d vi NaOH to ra
mui v Ancol l:
A. 2
B. 3
C. 4
D. 7
Hng Dn
C6H5COOCH3
HCOOCH2C6H5
Cu 8: Thu phn este c CTPT: C4H8O2 ( xt H+ ), thu c 2 sn phm hu c X, Y.T X c th
iu ch trc tip ra Y. Vy cht X l:
A. ancol metylic
B. Etyl axetat
C. axit fomic
D. ancol etylic
Cu 9: Este c CTPT l C4H6O2, khi thu phn trong mi trng axit thu c hn hp cc cht
u c kh nng trng gng. CTCT thu gn ca este l
A. HCOO-C(CH3) = CH2
B. HCOO-CH=CH-CH3.
C. CH3COO-CH=CH2.
D. CH2 =CH-COO-CH3.
Cu 10: Mt este c CTPT l C4H6O2 khi thy phn trong mi trng axit thu c imetyl xeton.
CTCT thu gn ca C4H6O2 l cng thc no
A. HCOO-CH=CH-CH3
B. CH3COO-CH=CH2
C. HCOO-C(CH3)=CH2
D.CH2=CH-COOCH3
Cu 11: Thu phn cht hu c X trong dd NaOH (d), un nng, c sn phm gm 2 mui
v ancol etylic. Cht X l
A. CH3COOCH2CH2Cl.
B. CH3COOCH2CH3.
C. ClCH2COOC2H5.
D. CH3COOCH(Cl)CH3.
Cu 12: Cht hu c X c CTPT l C4H6O2Cl2. Khi cho X P vi dd NaOH thu c
CH2(OH)COONa, etylenglicol v NaCl. CTCT ca X l:
A. CH2ClCOOCHClCH3.
B. CH3COOCHClCH2Cl.
C. CHCl2COOCH2CH3.
D. CH2ClCOOCH2CH2Cl.
Cu 13: Hp cht hu c X cha m t loi nhm chc, c CTPT l C6H10O4. Khi thu phn X trong
NaOH thu c m t mui v 2 ancol ng ng lin tip nhau. X c CTCT l:
A. HOOC (CH2)2 COOH
B. CH3OOC CH2 COO C2H5
C. HOOC (CH 2)3 COO CH3
D. C2H5OOC CH2 - CH2 COOH
Cu 14: Cho s P : A (C3H6O3) + KOH Mui + Etylen glicol.
CTCT ca A l :
A. HOCH2COOCH3.
B. CH3COOCH2OH.
C. CH3CH(OH) COOH.
D. HCOOCH2CH2OH.
Cu 15: Cho s : C4H8O2 X Y Z C2H6. CTCT ca X l
A. CH3CH2CH2COONa.
B. CH3CH2OH.
C. CH2=C(CH3)-CHO.
D. CH3CH2CH2OH.
Cu 16: Cho cht X T/d vi mt lng va dd NaOH, sau c cn dd thu c cht rn Y v
cht hu c Z. Cho Z T/d vi dd AgNO3/NH3 thu c cht hu c T. Cho T T/d vi dd NaOH li
thu c cht Y. Cht X c th l:
A.HCOOCH=CH2
B.CH3COOCH=CH2
C.HCOOCH3
D.CH3COOCH=CH-CH3
Cu 17: Cho chui bin i sau: C2H2 X Y Z CH3COOC2H5 .X, Y, Z ln lt l
A. C2H4, CH3COOH, C2H5OH
B. CH3CHO, C2H4, C2H5OH
C. CH3CHO, CH3COOH, C2H5OH
D. CH3CHO, C2H5OH, CH3COOH
Hng Dn
H 2O
H2
O2 , xt
5 OH
C 2 H 2
xt HgSO

CH
CHO

H
CH 3COOH xtCH2 2HSO
CH 3COOC 2 H 5
3
2 5 OH
,80o C
xt Ni ,t o
4d
4

Cu 18: Thy phn hon ton este X bng dd NaOH. Sau khi P kt thc th s mol NaOH dng
gp i s mol X. C

GV: HU NH
T: 0942235658

NHN DY N THI H

(1) X l este ca axit n chc v ancol hai chc

(2) X l este ca ancol n chc v axit hai chc
(3) X l este ca ancol n chc v axit n chc
(4) X l este c CTCT thu gn l RCOOC6H5
(5) X l este ca ancol hai chc v axit hai chc
Cc pht biu ng l:
A. (1) (2) (3)
B. (3) (4) (5)
C. (1) (2) (3) (5)
D.(1) (2) (4) (5)
Cu 19. Cht X T/d vi NaOH cho dd X1. C cn X1 c cht rn X2 v hn hp X3. Chng ct X3
thu c X4. Cho X4 trng gng thu c X5. Cho X5 T/d vi NaOH li thu c X2.Vy CTCT
ca X l
A. HCOO- C(CH3)=CH2
B. HCOO-CH=CH-CH3
C. CH2=CH-CH2-OCOH
D. CH2=CH-OCOCH3
Cu 20: Dy cht no sau y c sp xp theo chiu nhit si ca cc cht tng dn
A. CH3COOH, CH3COOC2H5, CH3CH2CH2OH B. CH3COOH, CH3CH2CH2OH CH3COOC2H5
C. CH3CH2CH2OH , CH3COOH, CH3COOC2H5 D. CH3COOC2H5 ,CH3CH2CH2OH , CH3COOH
Cu 21: Sp xp cc cht sau theo trt t tng dn nhit si: CH3COOH; CH3COOCH3;
HCOOCH3; C2H5COOH; C3H7OH. Trng hp no sau y ng
A. HCOOCH3 < CH3COOCH3 < C3H7OH < CH3COOH < C2H5COOH.
B. CH3COOCH3 < HCOOCH3 < C3H7OH < CH3COOH < C2H5COOH.
C. C2H5COOH< CH3COOH < C3H7OH < CH3COOCH3 < HCOOCH3
D. HCOOCH3< CH3COOCH3 < C3H7OH < C2H5COOH< CH3COOH
Cu 22: Cho s phn ng:
AgNO3 / NH 3
NaOH
NaOH
Este X (C4HnO2)
Y
Z
C2H3O2Na.
t0
t0
t0
CTCT ca X tha mn s cho l
A. CH2=CHCOOCH3.
B. CH3COOCH2CH3.
C. HCOOCH2CH2CH3.
D. CH3COOCH=CH2.
V D - Bi Tp
Dng 1: P chy
Cu 1: Khi t chy hon ton este no, n chc th nCO2 nO2 P. Tn gi ca este l
A. Metyl fomiat.
B. Etyl axetat.
C. Metyl axetat.
D. n- Propyl axetat.
Hng Dn
Goi CT CnH2nO2
0
3n 2
CnH2nO2
O2 t
nCO
2
nH2O
2
3n 2
n2 A
Ta c nCO2 nO2 n
2
Cu 2: t chy hon ton 7,4 gam hn hp hai este ng phn, thu c 6,72 lt CO2 (ktc) v 5,4
gam H2O. CTPT ca hai este l
A. C3H6O2
B. C2H4O2
C. C4H6O2
D. C4H8O2
Hng Dn
nC nCO2 0,3 (mol )

nH 2nH 2O 0, 6 (mol )

nC : nH : nO 3 : 6 : 2

n 7, 4 0,3.12 0, 6.1 0, 2 ( mol )

O
16
CTG ng thi cng l CTPT ca hai este l C3H6O2.

GV: HU NH
T: 0942235658

NHN DY N THI H

Cu 3: t chy hon ton hn hp 2 este, cho sn phm chy qua bnh P2O5d khi lng bnh
tng ln 6,21 gam, sau cho qua dd Ca(OH)2 d c 34,5 gam kt ta. Cc este trn thuc loi :
A. Este no
B. Este khng no
C. Este no , n chc , mch h
D. Este a chc
Hng Dn:
6, 21
34,5
nH 2O
0,345 mol nCO2 nCaCO3
0,345 mol nn hai este l no n chc mch h.
18
100
Cu 4: Hp cht X T/d c vi dd NaOH un nng v vi dd AgNO 3 /NH3.Th tch ca 3,7
gam hi cht X bng th tch ca 1,6 gam O2 (cng k v nhit v p sut). t chy hon
ton 1 gam X th th tch CO2 thu c vt qu 0,7 lt ( ktc). CTCT ca X
C. CH3COOCH3
D. HCOOC2H5
A. O=CH-CH2 CH2OH
B. HOOC-CHO
Hng Dn
1, 6
3, 7
0, 05 mol M x
= 74 vc
Do cng k v nhit v p sut nX nO2
32
0, 05
t chy hon ton 1 gam X th th tch CO2 thu c vt qu 0,7 lt ( ktc) D
Cu 5: t chy hon ton 11,6 gam este X thu c 13,44 lt CO2(ktc) v 10,8 gam H2O. Mt
khc Cho 11,6 gam este T/d vi dd NaOH thu c 9,6 gam mui khan. CT ca X l :
A. C3H7COOC2H5
B. C2H5COOC2H5
C. C2H5COOC3H7 D. CH3COOC3H7
Hng Dn
10,8
13, 44
0, 6 mol nCO2
0, 6 mol nn este l no n chc c CTTQ: CnH2nO2
18
22, 4

CnH2nO2
nCO2
11, 6
11, 6
.n 0, 6
14n 32
14n 32
11, 6
n= 6 C6H12O2 neste
0,1 mol
116
RCOOR
+ NaOH
RCOONa + ROH
Pt
0,1
0,1
0,1
Ta c 0,1.(R+67)=9,6=> R=29: C2H5Vy CTCT ca este l C2H5COOC3H7
nH 2O

Cu 6: Hn hp X gm hai este no, n chc, mch h. t chy hon ton X cn 3,976 lt

O2 (ktc) c 6,38 gam CO2. Mt khc X T/d vi dd NaOH c mt mui v hai ancol l
ng ng k tip. CTPT ca hai este trong X
A. C2H4O2 v C5H10O2
B. C2H4O2 v C3H6O2
C. C3H4O2 v C4H6O2
D. C3H6O2 v C4H8O2
Hng Dn
Do X l este no n chc v T/d vi dd NaOH, c mt mui v hai ancol l ng ng k tip
Goi CTca hai este l Cn H 2 nO2
3,976
6,38
0,1775 mol v nCO2
0,145 mol
Ta c nO2
22, 4
44

GV: HU NH
T: 0942235658

CnH2nO2
Phn ng chy

NHN DY N THI H

3n 2
O2
2

t0

nCO
2

nH2O

0,1775n
mol
3n 2
2
CHO
0,1775n
0,145 n 3,625 3 6 2 D
Ta c 3n 2
C4H8O2
2
Cu 7: X l hn hp 2 este ca cng 1 ancol no, n chc v 2 axit no, n chc ng ng k tip.
t chy han ton 0,1 mol X cn 6,16 lt O2(ktc). un nng 0,1 mol X vi 50 gam dd NaOH
20% n P han ton, ri c cn dd sau P c m gam cht rn. Gi tr ca m l:
A. 13,5
B. 7,5
C. 15
D. 37,5
Hng Dn
Do X l este ca cng 1 ancol no, n chc v 2 axit no, n chc ng ng k tip.
Goi CTca hai este l Cn H 2 nO2
0,1775

0
3n 2
O2 t
nCO
2
nH2O
2
3n 2
0,1
0,1.
mol
2
n 2,5 HCOOCH3 V CH3COOCH3
Cu 8: t chy hon ton 6,8 gam mt este A no n chc cha vng benzen thu c CO2 v
H2O. Hp th ton b sn phm ny vo bnh ng dd Ca(OH)2 ly d thy khi lng bnh tng
21,2 gam ng thi c 40 gam kt ta. Xc nh CTPT, CTCT c th c ca A
A. 2
B. 3
C. 4
D. 5
Hng Dn
Tm CTG: d dng tm c CTPT C8H8O2
4 CTCT: phenyl axetat; 3 p: o, m, p -metyl phenyl fomat

CnH2nO2

Cu 9: Hn hp Z gm hai este X v Y to bi cng m t ancol v hai axit cacboxylic k tip nhau

trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt O2 (ktc), thu c
5,6 lt CO2 (ktc) v 4,5 gam H2O. CT este X v gi tr ca m tng ng l
A. CH3COOCH3 v 6,7
B. HCOOC2H5 v 9,5
C. HCOOCH3 v 6,7
D. (HCOO)2C2H4 v 6,6
Hng Dn

nCO2 nH 2O 0,25 X, Y l 2 este no n chc

6,16
.32 = 6,7 (gam)
p dng LBTKL : m = 0,25.44 + 4,5 22,4
1
0,25
t cng thc ca X, Y : Cn H 2 nO2 nC H O2 nCO2
n 2n
n
n
14n 32

6, 7n
26,8n n 2,5 n = 2 ; n = 3
0, 25

X : C2H4O2

HCOOCH3

Y : C3H6O2 CH3COOCH3
Cu 10: t chy hon ton hn hp hai este X, Y, n chc, no, mch h cn 3,976 lt oxi(ktc)
thu c 6,38 gam CO2. Cho lng este ny T/d va vi KOH thu c hn hp hai ancol k
tip v 3,92 gam mui ca mt axit hu c. CTCT ca X, Y ln lt l

GV: HU NH
T: 0942235658

A. C2H5COOC2H5 v C2H5COOC3H7
C. CH3COOCH3 v CH3COOC2H5

NHN DY N THI H

B. C2H5COOCH3 v C2H5COOC2H5
D. HCOOC3H7 v HCOOC4H9
Hng Dn

t CTTB ca 2 este X, Y l: CnH2n+1COO C mH 2m1

V X, Y u l este n chc, no, mch h nn: n H O = nCO = 6,38/44 = 0,145 mol
meste + mO2 = 44. nCO2 + 18. n H 2O meste = 3,31 gam
Ta c : mO (trong este) = meste mC mH = 3,31 12.0,145 2.1.0,145 = 1,28 gam
nO = 1,28/16 = 0,08 mol neste = 0,04 mol
nmui = neste = 0,04 mol Mmui = 14n + 84 = 3,92/0,04 = 98 n = 1
Mt khc: M este = 3,31/0,04 = 82,75 12.1 + 46 + 14 m = 82,75 m= 1,77
Vy: X l CH3COOCH3 v Y l CH3COOC2H5 p n C
Cu 11: Este X no, n chc, mch h, khng c P trng bc. t chy 0,1 mol X ri cho sn
phm chy hp th hon ton vo dd nc vi trong c cha 0,22 mol Ca(OH) 2 th vn thu c kt
ta. Thu phn X bng dd NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t
bng nhau. Phn trm khi lng ca oxi trong X l:
A. 43,24%
B. 53,33%
C. 37,21%
D. 36,26%
Hng Dn
Cn nCO2
0,1
0,1n
CO2 + Ca(OH)2 CaCO3 + H2O
(1)
0,22 0,22 0,22
CO2 + CaCO3 + H2O Ca(HCO3)2
(2)

0,22
0,22
Theo (1), (2): thu c kt ta th: nCO2 < 0,22+0,22 = 0,44
Hay: 0,1n < 0,44 n < 4,4
X + NaOH to 2 cht c C = nhau X c 2 hoc 4 C
X khng c P trng gng n = 4 C4H8O2
Cu 12: Hn hp X gm hai cht hu c no, n chc T/d va vi 100 mldd KOH 0,4M, thu
c mt mui v 336 ml hi mt ancol (ktc). Nu t chy hon ton lng hn hp X trn, sau
hp th ht sn phm chy vo bnh ng dd Ca(OH)2(d) th khi lng bnh tng 6,82 gam.
CT ca hai hp cht hu c trong X l
A. CH3COOH v CH3COOC2H5.
B. C2H5COOH v C2H5COOCH3.
C. HCOOH v HCOOC2H5.
D. HCOOH v HCOOC3H7.
2

Hng Dn
Nhn vo p n cho thy hn hp X gm 1 axit v 1 este
Goi CT hn hp X l: CnH2n+1COOH x mol v CnH2n+1COOCmH2m+1 y mol
Tc dng KOH
x y 0, 04
x 0, 025

0,336

y 22, 4 0, 015 y 0, 015

P chy hp th ht sn phm chy vo bnh ng dd Ca(OH)2(d) th khi lng bnh tng 6,82
gam mCO2 mH 2O 6,82
Cu 13: t chy hon ton 1 mol axit cacboxylic n chc X cn 3,5 mol O2. Trn 7,4 gam X
vi lng ancol no Y (bit t khi hi ca Y so vi O2 nh hn 2). un nng hn hp vi H2SO4
lm xc tc. P hon ton c 8,7 gam este Z(trong Z khng cn nhm chc khc). CTCT ca Z
A. C2H5COOCH2CH2OCOC2H5
B. C2H3COOCH2CH2OCOC2H3
C. CH3COOCH2CH2OCOCH3
D. HCOOCH2CH2OCOH
Bi gii:

GV: HU NH
T: 0942235658

NHN DY N THI H

Phn ng chy: CXHyO2 + (x +

y
y
-1)O2 xCO2 +
H2O
4
2

y
y
Theo (1), ta c : x +
-1= 3,5 x +
= 4,5
4
4

(1)

x3
X : C H COOH

y 6
2

Ancol no Y : CnH2n+2-m (OH)m (1 m n) este Z : (C2H5COO)mCnH2n+2-m

8,7

Meste = 73m + 14n + 2 m = 0,1 .m hay 14n + 2 = 15m

(2)
Mt khc d Y O < 2 hay 14n + 2 + 16m < 64 30m + 2 < 64 (v m n) m < 2,1
2

n 2
T (2)
ancol Y : C H (OH)
m 2
2

Z : C2H5COOCH2CH2OCOC2H5
Cu 14: Hn hp X gm axit axetic, etyl axetat v metyl axetat. Cho m gam hn hp X T/d va
vi 200 ml dd NaOH 1M. Mt khc, t chy hon ton m gam hn hp X cn V lt O2(ktc) sau
cho ton b sn phm chy vo dd NaOH d thy khi lng dd tng 40,3 gam. Gi tr ca V l:
A. 17,36 lt
B. 19,04 lt
C. 19,60 lt
D. 15,12 lt
Hng Dn
X c cng thc chung CnH2nO2 vi nX = 0,2 mol
m dd tng = mCO2 + mH2O = 0,2.n.44 + 0,2.n.18 = 40,3 n = 3,25
nO2 = (3n-2)/2 = (3.3,25-2)/2 V = 17,36
Cu 15: t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit
oleic, ri hp th ton b sn phm chy vo dd Ca(OH)2 (d). Sau P thu c 18 gam kt ta v
dd X. Khi lng X so vi khi lng dd Ca(OH)2 ban u thay i nh th no
A. Tng 2,70 gam.
B. Gim 7,74 gam.
C. Tng 7,92 gam.
D. Gim 7,38 gam.
Hng Dn
hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic u c CT l: Cn H 2 n 2O2

nCn H 2 n2O2 nCO2 nH 2O 0,18 a . p dng LBT khi lng v nguyn t ta c:

mCn H 2 n2O2 0,18.12 2.a (0,18 a ).2.16 3, 42 a 0,15 mol
Khi lng X so vi khi lng dd Ca(OH)2 ban u s gim l:
mCaCO3 (mCO2 mH 2O ) 18 (0,18.44 0,15.18) 7, 38 gam => D ng.
Cu 16: t chy hon ton 10 ml hi mt este X cn va 45ml O2 thu c kh CO2 v hi
nc c t l th tch l 4: 3. Ngng t sn phm chy th th tch gim i 30 ml . Bit cc th tch
o cng iu kin. Cng thc X l:
A. C4H6O2
B. C4H6O4
C. C4H8O2
D. C8H6O4
Hng Dn
Do cc th tch o cng iu kin nn th tch chnh l s mol
Gi CT este l CxHyOz
y z
y
o
CxHyOz + ( x ) O2 t
xCO2 +
H2O
4 2
2
y z
10x 5y
( x ) 10
10
4 2
y z
Ta c ( x ) 10 = 45 (1)
4 2

GV: HU NH
T: 0942235658

NHN DY N THI H

10 x 4

(2)
5y 3
Ngng t sn phm chy th th tch gim i 30 ml : 10x + 5y 30 = 10x y = 6 (3)
x4

T (1),(2),(3) y 6 C4 H 6O 2 A
z2

T l kh CO2 v hi nc:

Cu 17: Mt este A (khng cha chc no khc) mch h c to ra t 1 axit n chc v ru

no. Ly 2,54 gam A t chy hon ton thu c 2,688 lt CO2 (ktc) v 1,26 gam H2O. 0,1 mol A
P va vi 12 gam NaOH to ra mui v ru. t chy ton b lng ru ny c 6,72 lt
CO2 (ktc). Xc nh CTPT, CTCT ca A
A. C3H5(OOCCH3)3.
B. C3H5(OOCC2H5)3.
C. C2H4(OOCCH3)3.
D. C3H5(OOCCH = CH2)3.
Hng Dn
nA:nNaOH = 1:3
(RCOO)3R + 3NaOH 3RCOONa + R(OH)3

0,1
0,1
S nguyn t cacbon ca ru n

0,3
3 C3H5(OH )3
0,1

Khi t chy A => CTG: C6H7O3 . V este 3 chc => CTPT A: C12H14O6= 254
Ta c: 3(R1 + 44) + 41 = 254 R1= 27 CH2 CH
Vy A: (C2H3COO)3C3H5
Cu 18: em ha hi 6,7 gam hn hp X gm CH3COOH, CH3COOC2H5, CH3COOCH3 v
HCOOC2H5 thu c 2,24 lt hi (ktc). t chy hon ton 6,7 gam X thu c khi lng nc
A. 4,5 gam.
B. 3,5 gam.
C. 5 gam.
D. 4 gam.
Hng dn

Gi cng thc
chung ca X l CnH2nO2 MX = 14n + 32 =

= 67 n = 2,5

S chy : CnH2nO2 nCO2 + nH2O

H O = 0,25.18 = 4,5 gam
Hn O = 2,5.0,1 = 0,25 mol m
2

Dng 2: Xc nh CTPT da vo t khi hi

Cu 1: Este A iu ch t ancol metylic c t khi so vi oxi l 2,3125. CT ca A l:
A. C2H5COOC2H5.
B. CH3COOCH3.
C. CH3COOC2H5.
D. C2H5COOCH3
Hng Dn
RCOOCH 3 d Este 2,3125 M Este 74 R 15
Do Este A iu ch t ancol metylic
O
2

Cu 2: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v tham gia P x phng
ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu CT ph hp vi X
A.2
B.3
C.4
D.5
Hng Dn
CT Este RCOOR ' d Este 3,125 M Este 100 R R ' 56
O2

P x phng ho to ra mt anehit v mt mui ca axit hu c

GV: HU NH
T: 0942235658

NHN DY N THI H

R ' 27 R 29 C2 H 5COOC2 H 3
R ' 41 R 15 CH 3COOC3 H 5
R ' 55 R 1 HCOOC4 H 7 (c 2 CTCT )
Cu 3: X l mt este no n chc, c t khi hi so vi CH4 l 5,5. Nu em un 2,2 gam este X
vi dd NaOH d, thu c 2,05 gam mui. CTCT ca X l:
A. HCOOCH2CH2CH3
B. HCOOCH(CH3)2
C. C2H5COOCH3
D. CH3COOC2H5
Hng Dn
'
CT Este RCOOR d Este 5,5 M Este 88 R R ' 44
CH 4

2, 2
0, 025 mol
88
'
RCOOR ' + NaOH RCOONa R OH
0,025
0,025
mol
'
( R 44)0, 025 2, 05 R 15 R 29 CH 3COOC 2 H 5
Cu 4: Este n chc X c t khi hi so vi CH4 l 6,25.Cho 20 gam X T/d vi 300 ml dd KOH
1M (un nng). C cn dd sau P thu c 28 gam cht rn khan. CTCT ca X l
A.CH2=CH-CH2COOCH3
B.CH2=CH-COOCH2CH3
C.CH3COOCH=CH-CH3
D.CH3-CH2COOCH=CH2
Hng Dn
CT Este RCOOR ' d Este 6, 25 M Este 100 R R ' 56
2,2 gam este X nX

CH 4

Cho 0,2 mol X T/d vi 0,3 mol KOH 28 gam cht rn khan gm mui v KOH d
'
RCOOR ' + KOH RCOONa R OH
0,2
0,2
0,2
mol
'
( R 44 39)0, 2 0,1(39 17) 28 R 29 R 27 C 2 H 5COOC 2 H 3 D
Cu 5: Mt este to bi axit n chac v Ancol n chc c t khi hi so vi CO2 bng 2. Khi
un nng este ny vi NaOH to ra mui c khi lng ln hn este P. CTCT ca este l:
A. CH3COOCH3
B. HCOOC3H7
C. CH3COOC2H5
D. C2H5COOCH3.
Hng Dn
CT Este RCOOR ' d Este 2 M Este 88 R R ' 44
CO2
'
RCOOR + NaOH RCOONa R OH
Ta c mui c khi lng ln hn este P
M RCOONa M RCOOR' R 67 R 44 R ' R ' 23 R ' 15 R 29 C 2 H 5COOCH 3
'

Cu 6: Este to bi axit n chc v Ancol n chc c t khi hi so vi CO2 bng 2. Khi un

nng este ny vi dd NaOH to mui c khi lng bng 93,18% lng este P. CTCT ca este
A. CH3COOCH3
B. HCOOC3H7
C. CH3COOC2H5.
D. C2H5COOCH3
Hng Dn
CT Este RCOOR ' d Este 2 M Este 88 R R ' 44(1)
CO2
'
RCOOR ' + NaOH RCOONa R OH
Ta c mui c khi lng bng 93,18% lng este P
M
R 67
RCOONa .100 93,18
0,9318(2)
M RCOOR'
R 44 R '

GV: HU NH
T: 0942235658

NHN DY N THI H

R 15

CH 3COOC 2 H 5 C
'
R

29

Cu 7: Mt este ca ancol metylic T/d vi nc brom theo t l mol 1 : 1 thu c sn phm trong
brom chim 35,08% theo khi lng . Este l:
A. metyl propyonat
B. metyl panmitat
C. metyl oleat
D. metyl acrylat
Hng Dn
T (1) v (2)

Theo gi thit 1 mol este + 1 mol Br2 . Gi M l khi lng mol este ta c :
160
0,35087 M 296 RCOOCH 3 R 59 R 237
M 160
R l C17H33 . Vy este l: metyl oleat
Cu 8: X phng ha hon ton 20,4 gam cht hu c X n chc bng dd NaOH thu mui Y v
Z .Cho Z T/d vi Na d thu c 2,24 lt H2 ( ktc) . Nung Y vi NaOH rn thu c mt kh R,
dR/O2=0,5 , Z T/d vi CuO nung nng cho sn phm khng c P trng bc . Tn gi ca X l :
A. Etyl axetat
B. Iso Propyl axetat
C. Propyl propinoat
D. Isopropyl fomat
Hng Dn
X l este n chc to bi acid c mui Y l R-COONa v ancol n chc Z , R- OH.
S mol R-OH= s mol H =2,24 : 11,2= 0,2 mol nn s mol X= 0,2 mol .
Kh R c khi lng mol = 32.0,5= 16 : CH4 nn mui Y l CH3COONa.
Khi lng mol ca X = 20,4 : 0,2 = 102g/mol
Ta c : CH3COOR = 59 + R= 102.
=> R= 43 nn R l C3H7 v este X l CH3-COOC3H7.
Cu 9: Thc hin P x phng ho cht hu c X n chc vi dd NaOH thu c mt mui Y v
ancol Z. t chy hon ton 2,07 gam Z cn 3,024 lt O 2 (ktc) thu c lng CO2 nhiu hn khi
lng nc l 1,53 gam. Nung Y vi vi ti xt thu c kh T c t khi so vi khng kh bng
1,03. CTCT ca X l:
A. C2H5COOCH3
B. CH3COOC2H5
C. C2H5COOC3H7
D. C2H5COOC2H5
Hng Dn
- Theo bi: X n chc, tc dng vi NaOH sinh ra mui v ancol
X l este n chc: RCOOR.
Mt khc: mZ + mO = mCO + m H O 44. nCO + 18. n H O = 2,07 + (3,024/22,4).32 = 6,39
gam
V 44. nCO2 - 18. n H 2O = 1,53 gam nCO2 = 0,09 mol ; n H 2O = 0,135 mol
n H O > nCO Z l ancol no, n chc, mch h c cng thc: CnH2n+1OH (n 1)
2

T phn ng t chy Z

n H 2O
nCO2

n 1 0,135
= 0,09 n = 2.
n

Y c dng: CxHyCOONa T: CxHy+1 MT = 12x + y + 1 = 1,03.29

x2

C H COOC H
y6
2

p n D

Dng 3: P x phng ha
TH1: Thy Phn Este n chc
Cu 1: Cho este X c CTPT l C4H8O2 T/d vi NaOH un nng c mui Y c phn t khi ln
hn phn t khi ca X. Tn gi ca X l:
A. Metylpropionat
B. Etyl axetat
C. Propyl fomat
D. Iso Propyl fomat

GV: HU NH
T: 0942235658

NHN DY N THI H

Hng Dn
C4H8O2 (X) =88 < C2H5ONa (Y) => CTCT l C2H5-COOCH3 Metylpropionat
Cu 2: Thu phn hon ton 8,8 gam mt este n chc, mch h X vi 100 ml dd KOH 1M (va
) thu c 4,6 gam mt ancol Y. Tn gi ca X l:
A. Etyl Fomat
B. Etyl Propionat
C. Etyl Axetat
D.Propyl Axetat
Hng Dn
Nhn vo p n nhn thy este X l no n chc, mch h
Gi CTCT este l CnH2n + 1COOCmH2m + 1
4, 6
46 14m 18 46 m 2 C2 H 5OH
nru = nKOH = 0,1 mol M Cm H 2 m 1OH
0,1
8,8
88 14n 74 88 n 1 este l CH 3COOC2 H 5
neste=nKOH =0,1 mol M este
0,1
Cu 3: Cho 12,9 gam mt este n chc, mch h T/d ht vi 150ml dd KOH 1M. Sau P thu
c mt mui v anehit. S CTCT ca este tho mn tnh cht trn l:
A. 1
B. 2
C. 3
D. 4
Hng Dn:
HCOOCH=CH-CH3 v CH3COOCH=CH2
Cu 4: Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y)
v este Z c to ra t X v Y. Cho hn hp M T/d va vi dd cha 0,2 mol NaOH, to ra 16,4
gam mui v 8,05 gam ancol. Cng thc ca X v Y l
A. HCOOH v CH3OH
B. CH3COOH v CH3OH
C. HCOOH v C3H7OH
D. CH3COOH v C2H5OH
Hng Dn:
Gi s mol: RCOOH a
ROH
a
RCOOR b
Theo gi thit: nRCOONa = a + b = 0,2 mol. MRCOONa = 82 R = 15. (CH3). X l CH3COOH
Loi p n: A v C. (a + b) < nROH = a + b < a + b 0,1 < nROH < 0,2
40,25 < Mancol < 80,5. Loi p n B.
Cu 5: t chy hon ton 1 este n chc mch h X ( phn t c s lin kt < 3) c th tch
CO2 bng 6/7 th tch O2 P ( cc th tch kh o cng iu kin) Cho m gam X T/d vi 200 ml
dd KOH 0,7M c dd Y . C cn dd Y c 12,88 gam cht rn khan. Gi tr m l:
A. 8,88
B. 6,66
C. 10,56
D. 7,20
Hng Dn:
CTPT ca este l : CnH2n-2kO2 vi k<3
3n k 2
O2
CnH2n-2kO2 +
nCO2 + (n-k)H2O
2
6 3n k 2
2
k n 2
T PT v gi thit ta c: n= .
7
2
3
2
V k 3 nn n 2 3 n 7,5 n 7, 6,5, 4,3, 2
3
Mun cho k nguyn dng th n phi chia ht cho 3
Nu n= 6 th k=2 nn cng thc l C6H8O2
-

GV: HU NH
T: 0942235658

NHN DY N THI H

Nu n= 3 th k=0 nn cng thc l C3H6O2=74

V li gii qu di v phc tp nn ta m nghim bng cch cho este l CH3COOCH3
S mol KOH= 0,2. 0,7= 0,14 mol
CH3COOCH3
+ KOH CH3COOK + CH3OH
x
x
x
Gi x l s mol este ta c: (0,14- x). 56 + 98x=12,88
x = 0,12 mol nn m= 0,12. 74 = 8,88 gam.
Cu 6: t chy hon ton 17 gam hn hp X gm 1 ancol n chc v 1 este no, n chc, mch
h c 12,32 lt CO2 (ktc) v 14,4 gam H2O. Mt khc, nu un 17 gam hn hp X vi 150 ml dd
KOH 0,8M, ri c cn dd sau phn ng th khi lng cht rn khan thu c l
A. 8,16 gam.
B. 10,08 gam.
C. 9,96 gam.
D. 11,88 gam.
Hng Dn
- Tnh s mol Ancol
nCO2 0,55 mol
nAcol 0,8 0,55 0, 25 mol

nH 2O 0,8 mol
- P chy
Cn H 2n 2 O 0, 25 mol O2
nCO2 0, 25n mol

0,55 mol

0, 25n bm 0,55 (1)

mol
Cm H 2m O 2 b
mCO2 bm mol
0, 25 14n 18 b 14m 32 17 14 0, 25.n b.m 0, 25.18 32b 17 (2)
(1), (2) b 0,15
0,25n+0,15m=0,55 5n+3m=11; gi tr ph hp n=1;m=2 HCOOCH3 0,15 mol
- P thy phn: nKOH 0,12 mol
o
HCOOCH3 + KOH t
HCOOK + CH3OH
0,12
0,12
mol
mHCOOK 0,12.84 10, 08 gam B
Cu 7: X phng ha hon ton 20,4 gam cht hu c X n chc bng dd NaOH thu mui Y v
Z . Cho Z T/d vi Na d thu c 2,24 lt H2 ( ktc) . Nung Y vi NaOH rn thu c mt kh R ,
dR/O2=0,5 , Z T/d vi CuO nung nng cho sn phm khng c P trng bc . Tn gi ca X l :
A. Etyl axetat
B. Iso Propyl axetat
C. Propyl propinoat
D. Isopropyl fomat.
Hng Dn
X l este n chc to bi mui Y l R-COONa v ancol n chc Z , R- OH.
S mol R-OH= s mol H =2,24 : 11,2= 0,2 mol nn s mol X= 0,2 mol .
Kh R c khi lng mol = 32.0,5= 16 : CH4 nn mui Y l CH3COONa.
Khi lng mol ca X = 20,4 : 0,2 = 102g/mol
Ta c : CH3COOR = 59 + R= 102.
=> R= 43 nn R l C3H7 v este X l CH3-COOC3H7.
Cu 8: Cho 27,6 gam hp cht thm X c CT C7H6O3 T/d vi 800 ml dd NaOH 1M c dd Y.
Trung ha Y cn 100 ml dd H2SO4 1M c dd Z. Khi lng cht rn thu c khi c cn dd Z l
A. 31,1 gam.
B. 56,9 gam.
C. 58,6 gam.
D. 62,2 gam.
Hng Dn

n C7 H6O3 = 0,2; n NaOH = 0,8; n H = 0,2 0,6 mol NaOH phn ng vi C7H6O3.
o

HCOO-C6H4 OH + 3NaOH t
HCOONa + C6H4(ONa)2 + 3H2O
0,2
0,6
0,2
0,2
Khi lng cht rn = 0,2.68 + 0,2.154 + 0,1.142 = 58,6 gam

GV: HU NH
T: 0942235658

NHN DY N THI H

Cu 9: Cho axit salixylic (axit o-hiroxibenzoic) P vi anhirit axetic c axit axetylsalixylic (oCH3COO-C6H4-COOH). P hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dd
KOH 1M. Gi tr ca V l
A. 0,72.
B. 0,48.
C. 0,96.
D. 0,24.
Hng Dn
o-CH3COO-C6H4-COOH + 3KOH = CH3COOK +o-KO-C6H4-COOK+ 2H2O (1)
theo (1) nKOH 3.naxetylsalixylic 3.

43, 2
0, 72 mol VKOH 0, 72 lt
180

TH2: Thy phn hn hp Este n chc

Cu 1: X phng ha hon ton 1,99 gam hn hp hai este bng dd NaOH thu c 2,05 gam mui
ca mt axit v 0,94 gam hn hp hai ancol l ng ng k tip nhau. CTCT ca hai este l:
A. HCOOCH3 v HCOOC2H5.
B. C2H5COOCH3 v C2H5COOC2H5.
C. CH3COOC2H5 v CH3COOC3H7.
D. CH3COOCH3 v CH3COOC2H5
Hng Dn
Goi CTTB ca 2 Este l RCOO R
o
RCOO R
+ NaOH t
RCOONa + R OH
p dng LBTKL: meste + mNaOH = mmui + mru
1,99 + mNaOH = 2,05 + 0,94 mNaOH 1 nNaOH 0, 025 mol
2, 05

CH 3COOCH 3
nRCOONa nNaOH 0, 025 M RCOONa 0, 025 82 R 15 CH 3

CH 3
0,94
n
nNaOH 0, 025 M ROH
37, 6 R 20, 6
CH 3COOC2 H5
ROH
0, 025
C2 H 5
Cu 2: X phng ha han ton 14,55 gam hn hp 2 este n chc X,Y cn 150 ml dd NaOH
1,5M. C cn dd thu c hn hp 2 ancol ng ng k tip v mt mui duy nht. CT 2 este l:
A. HCOOCH3, HCOOC2H5.
B. CH3COOCH3, CH3COOC2H5
C. C2H5COOCH3, C2H5COOCH3
D. C3H7COOCH3, C2H5COOCH3
Hng Dn
Goi CTTB ca 2 Este l RCOO R
o
RCOO R
+ NaOH t
RCOONa + R OH
0,225
0,225
mol
HCOOCH 3
14,55
R 1
65 R 44 R 65 R R 21

A
Ta c M este
0, 225
R 20 HCOOC 2 H5
Cu 3: X l hn hp hai este ca cng mt ancol, no n chc v hai axit no, n chc, ng ng
k tip. t chy hon ton 0,1 mol X cn 6,16 lt O2(ktc). un nng 0,1 mol X vi 50 gam dd
NaOH 20% P hon ton, ri c cn dd sau P thu c m gam cht rn. Gi tr ca m l
A. 15 gam.
B. 7,5 gam
C. 37,5 gam
D. 13,5 gam
Hng Dn
Do hai este ca cng mt ancol, no n chc v hai axit no, n chc, ng ng k tip
Gi CTTB ca hai este l Cn H 2 nO2 n=2,5
Cn H 2 nO2
P chy
0,1

3n 2
O2 nCO2
2
0,1(3n 2)
2

nH 2O

GV: HU NH
T: 0942235658

Ta c
nNaOH

NHN DY N THI H

HCOOCH 3 x mol
x y 0,1
x
0,1(3n 2) 6,16

n 2,5

2
22, 4
2 x 3,5 y 0, 275 y
CH 3COOCH 3 y mol
50.20

0, 25 mol nNaOH du 0, 25 0,1 0,15 mol

100.40

Cu 4: Hn hp X gm hai cht hu c. Cho hn hp X P va vi dd KOH th cn ht 100 ml

dd KOH 5M. Sau P thu c hn hp hai mui ca hai axit no n chc v c mt ru no n
chc Y. Cho ton b Y T/d vi Na c 3,36 lt H2 (ktc). Hai hp cht hu c thuc loi cht g
A. 1 axit v 1 este
B. 1 este v 1 ancol
C. 2 este
D. 1 axit v 1 ancol
Ta c: nKOH 0,1.5 0,5 mol
Ancol no n chc Y: CnH2n+1OH

Hng Dn

1
H2
2

0,3 mol
0,15 mol
Thu phn hai cht hu c thu c hn hp hai mui v mt ancol Y vi nY < nKOH
Vy hai cht hu c l: este v axit
Cu 5: Hn hp M gm hai hp cht hu c mch thng X v Y ch cha T/d va ht 8 gam
NaOH c ru n chc v hai mui ca hai axit hu c n chc k tip nhau trong dy ng
ng. Ru thu c cho T/d vi Na d c 2,24 lt H2 (ktc). X, Y thuc lai hp cht g
A.1 axit v 1 este
B.1 este v 1 ancol
C.2 este
D. 1 axit v 1 ancol
Hng Dn
nNaOH 0, 2 mol
Thu phn hai X, Y v thu c nAncol = nNaOH. Vy X, Y l hai este.

nAcol 0, 2 mol
Cu 6: Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong
dy ng ng) T/d ht vi Na c 6,72 lt H2 (ktc). Nu un nng hn hp X (c H2SO4 c lm
xc tc) th cc cht trong hn hp P va vi nhau to thnh 25 gam este (gi thit P este ho
t hiu sut 100%). Hai axit trong hn hp X l
A. C3H7COOH v C4H9COOH.
B. CH3COOH v C2H5COOH.
C. C2 H5COOH v C3H7COOH.
D. HCOOH v CH3COOH.
Hng Dn
CH
OH

3
Gi CT hn hp X l
RCOOH
CnH2n+1OH + Na CnH2n+1ONa +

Do un nng hn hp X th cc cht P va vi nhau nCH3OH nRCOOH x mol

x x 6, 72
0,3 mol x 0,3 mol
T/d ht vi Na
2 2 22, 4
R COOH + CH3OH
0,3

H ,t 0

R COOCH3
0,3

mol

CH3COOH
25
83,33 R 44 15 83,33 R 24,333
0,3
C 2 H 5COOH
Cu 7: Mt hn hp X gm 2 este n chc thy phn hon ton trong mi trng NaOH d cho
hn hp Y gm 2 ru ng ng lin tip v hn hp mui Z
- t chy hn hp Y th thu c CO2 v hi H2O theo t l th tch 7:10
- Cho hn hp Z T/d vi lng va axit sunfuric c 2,08 gam hn hp A gm 2 axit hu c
no. Hai axit ny va Pvi 1,59 gam natricacbonat
M este

GV: HU NH
T: 0942235658

NHN DY N THI H

Xc nh CT ca 2 este bit rng cc este u c s nguyn t cacbon < 6 v khng tham gia phn
ng vi AgNO3/NH3.
A. C2H5COOC2H5, CH3COOC3H7.
B. CH3COOCH3, CH3COOC2H5
C. C2H5COOCH3, C2H5COOCH3
D. C3H7COOCH3, C2H5COOCH3
Hng Dn
C: RCOOR RCOONa RCOOH + Na2CO3
0,015
0,03
t Y: nH2O > nCO2 => C n H2 n +1OH T ti l => n = 2,33
=> 2 ru l: C2H5OH v C3H7OH (1)
M axit = 2,08/0,03 = 69,3 => R = 24,3 (2)
Do C < 6 v kt hp (1),(2) => C2H5COOC2H5, CH3COOC3H7 (khng c P vi AgNO3/NH3).
TH3: Thy phn Ete ng phn ca nhau
Cu 1: Hn hp X gm hai este n chc l ng phn ca nhau. ung nng m gam X vi 300 ml
dd NaOH 1M, kt thc cc P thu c dd Y v (m 8,4) gam hn hp hi gm hai anehit no,
n chc, ng ng k tip c t khi hi so vi H 2 l 26,2. C cn dd Y thu c (m 1,1) gam
cht rn. Cng thc ca hai este l
A.CH3COOCH=CHCH3 v CH3COOC(CH3)=CH2 B. HCOOC(CH3)=CH2 v HCOOCH=CHCH3
C. C2H5COOCH=CH2 v CH3COOCH=CHCH3.
D. HCOOCH=CHCH3 v CH3COOCH=CH2.
Hng Dn
M RCHO = 52,4 CH3-CHO, C2H5-CHO loi p n A, B,
p dng BTKL ta c:
m + 0,3.40 = m 8,4 + 1,1 m = 21,5,
44x 58y 13,1
CH CHO x mol
mRCHO m 8, 4 21,5 8, 4 13,1 gam C H3 CHO y mol 44x 58 y 26, 2.2 x y
2 5

x 0,1
neste 0,1 0,15 0, 25 mol M Este 86 D

y 0,15
Cu 2: Hn hp A gm ba cht hu c X, Y, Z n chc ng phn ca nhau, u T/d c vi
NaOH. un nng 13,875 gam hn hp A vi dd NaOH va thu c 15,375 gam hn hp mui
v hn hp ancol c t khi hi so vi H2 bng 20,67. 136,50C, 1 atm th tch hi ca 4,625 gam
X bng 2,1 lt. Phn trm khi lng ca X, Y, Z (theo th t KLPT gc axit tng dn) ln lt l:
A. 40%; 40%; 20%
B. 40%; 20%; 40%
C. 25%; 50%; 25%
D. 20%; 40%; 40%
Hng Dn
1.2,1
4,625
0,0625
mol MX =
74
0,082(273 136,5)
0,0625
Mt khc: X, Y, Z n chc, tc dng c vi NaOH X, Y, Z l axit hoc este
x3
CTPT dng: CxHyO2, d dng
y6
Ta c : nX

X : C 2H 5COOH: a mol

A Y : CH3COOCH3 : b mol
Z : HCOOC H : c mol
2 5

mol
nA a b c 0,1875
32b 46c
dancol/ H2
20,67

2(b c)
mmui 96a 82b 68c 15,375gam

a 0,075

b 0,0375 p n B
c 0,075

Cu 3: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2,
c 23,52 lt CO2 v 18,9 gam H2O. Cho m gam X T/d ht vi 400 ml dd NaOH 1M, c cn dd

GV: HU NH
T: 0942235658

NHN DY N THI H

sau P c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (My < Mz). Cc th
tch kh u o ktc. T l a : b l
A. 2 : 3
B. 4 : 3
C. 3 : 2
D. 3 : 5
Hng Dn
D dng c n CO2 = n H2O = 1,05 mol => Este no, n chc c cng thc chung CnH2nO2
C nhhX = (3.1,05 2.1,225) : 2 = 0,35 mol (bo ton oxi) => n = 1,05 : 0,35 = 3
Hai este l HCOOC2H5 a mol; CH3COOCH3 b mol.
C a + b = 0,35 v 68a + 82b + 0,05.40 = 27,9
a = 0,2 mol ; b = 0,15 mol => a : b = 4 : 3
Cu 4: t chy hon ton m gam hn hp X gm hai este ng phn cn 6,272 lt O2(ktc), thu
c 5,376 lt CO2(ktc) v 4,32 gam H2O. Thy phn hon ton m gam hn hp X bng lng va
dd NaOH , Oxi ha hon ton ancol sinh ra ri cho sn phm to thnh T/d dd AgNO3/NH3 d
thu c 23,76 gam Ag. Cc P xy ra hon ton. % khi lng hai este l
A. 62,5% v 37,5%
B. 60% v 40%
C. 50% v 50%
D. 70% v 30%
Hng Dn
p dng nh lut bo ton khi lng mX = 5,92 (g).
m CO2 = n H 2O = 0,24 (mol ) este no n chc, mch h (CnH2nO2).
Da vo phn ng t chy gii c n = 3, nX = 0,08 (mol).
HCOOC2 H 5
CH 3COOCH 3

CTPT: C3H6O2 CTCT

x (mol)
y (mol)

x + y = 0,08 (*).

HCOOC2H5 C2H5OH CH3CHO 2Ag

x
2x
CH3COOCH3 CH3OH HCHO 4Ag
y
4y

2x + 4y = 0,22 (**).
Gii h (*) v (**), ta c: x = 0,05; y = 0,03.

S hp thc:

hu c Z ; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l
TH4: Thy phn Este a chc
Cu 1: Hp cht hu c X cha C, H, O mch thng c phn t khi l 146. X khng T/d Na. Ly
14,6 gam X T/d 100ml dd NaOH 2M thu c 1 mui v 1 ru. CTCT X l:
A. C2H4(COOCH3)2
B. (CH3COO)2C2H4
C. (C2H5COO)2
D. A v B ng
Hng Dn
nX:nNaOH = 1:2 =>CT X: R(COOR)2 hoc (RCOO)2R
TH1: R + 2R = 58 => R = 28 (-C2H4) v R = 15 (-CH3)
TH2: 2R + R = 58 => R = 28 (-C2H4) v R = 15 (-CH3)
Cu 2: Thy phn hon ton 0,05 mol este ca 1 axit a chc vi 1 ancol n chc cn 5,6 gam
KOH. Mt khc, khi thy phn 5,475 gam este th cn 4,2 gam KOH v thu c 6,225 gam
mui. CTCT ca este l:
A. (COOC2H5)2
B. (COOC3H7)2
C. (COOCH3)2
D. CH2(COOCH3)2
Hng Dn
Thy phn 0,05 mol este ca 1 axit a chc vi 1 ancol n chc
nKOH 0,1 mol 2neste CT este : R (COOR ' ) 2
P thy phn 5,475 gam

GV: HU NH
T: 0942235658

NHN DY N THI H

R (COOR ' ) 2 2 KOH R(COOK) 2 2 R 'OH

0, 0375 0, 075 0,0375
mol
M R (COOK )2 166 R 0

COOC2 H 5 2 A
'
M R (COOR' )2 146 R 29
Cu 3: Este X c to thnh t etylen glycol v hai axit cacboxylic n chc. Trong phn t este,
s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X T/d vi dd NaOH (d) th
lng NaOH P l 10 gam. Gi tr ca m l
A. 14,5.
B. 17,5.
C. 15,5.
D. 16,5.
Hng Dn
S nguyn t cacbon nhiu hn s nguyn t oxi l 1 nn c 4 nguyn t O th X c 5 C. Cng thc
X l: HCOO CH 2 CH 2 OOCCH 3
HCOO CH 2 CH 2 OOCCH 3 2 NaOH HCOONa CH 3COONa C2 H 4 (OH )2
1
1 10
nX = .nNaOH .
0,125 mol mX 132.0,125 16, 5 gam chon D
2
2 40

Cu 4: Cho 0,01 mol mt este X P va vi 100 ml dd NaOH 0,2 M, sn phm to thnh ch

gm mt ancol Y v mt mui Z vi s mol bng nhau. Mt khc, khi x phng ho hon ton 1,29
gam este bng mt lng va l 60 ml dd KOH 0,25 M, sau khi P kt thc em c cn dd
c 1,665 gam mui khan. CT ca este X l:
A. C2H4(COO)2C4H8
B. C4H8(COO)2C2H4
C. C2H4(COOC4H9)2 D. C4H8(COO C2H5)2
Hng Dn
Ta c: nZ = nY X ch cha chc este
n NaOH 0,1.0,2
S nhm chc este l:
=
= 2 CT ca X c dng: R(COO)2R
nX
0,01
R(COO)2R + 2KOH R(COOK)2 + R(OH)2
1

T phn ng thy phn: naxit = nmui = 2 nKOH = 2 .0,06.0,25 = 0,0075 mol

1,665

M mui = MR + 83.2 = 0,0075 = 222 MR = 56 R l: -C4H81,29

Meste = 0,0075 = 172 R + 2.44 + R = 172 R = 28 (-C2H4-)

Vy X l: C4H8(COO)2C2H4 p n B.
Cu 5: Mt hp cht hu c X c CT C7H12O4. Bit X ch c 1 loi nhm chc, khi cho 16 gam X
T/d va 200 gam dd NaOH 4% th thu c mt ancol Y v 17,8 gam hn hp 2 mui. Xc nh
CTCT thu gn ca X.
A. CH3OOC-COOC2H5
B. CH3COO-( CH2)2-COOC2H5
C. CH3COO-(CH2)2-OCOC2H5
D. CH3OOC-COOCH3
Hng Dn
p dng DDLBTKL tn khi lng Ancol
Cu 6: Cho 32,7 gam cht hu c X ch cha mt loi nhm chc T/d vi 1,5 lt dd NaOH 0,5M
thu c 36,9 gam mui v 0,15 mol Ancol. Lng NaOH d c th trung ha ht 0,5 lt dd HCl
0,6M. CTCT ca X l
A. CH3COOC2H5
B. (CH3COO)2C2H4
C. (CH3COO)3C3H5
D. C3H5(COOCH3)3
Hng Dn
nNaOH du 0,3mol nNaOH Pu 0,45 mol mnAncol 0,15 mol X : (RCOO)3 R'
PT T/d dd NaOH

GV: HU NH
T: 0942235658

NHN DY N THI H

(RCOO)3 R' 3NaOH

0,45

to

3RCOONa

R' (OH )3

0,45

0,15

mol

0,45(R 67) 36,9 R 15 CH3COO 3 C3H5 C

Cu 7: un nng m gam hn hp X gm cc cht cng mt loi nhm chc vi 600 ml dd NaOH
1,15M c dd Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z gm cc ancol.
Cho ton b Z T/d vi Na d, thu c 5,04 lt kh H2 (ktc). C cn dd Y, nung nng cht rn thu
c vi CaO cho n khi P xy ra hon ton c 7,2 gam mt cht kh. Gi tr ca m l
A. 40,60
B. 22,60
C. 34,30
D. 34,51
Hng Dn
(R1COO)xR2 + x NaOH xR1COONa + R2(OH)x
0,45 0,45
0,45/x
R2(OH)x x/2 H2
0,225
0,45/x
RCOONa + NaOH CaO
Na2CO3 + RH

0,45
0,24
0,24
n ancol = 2n H2 = 0,45 mol
C n NaOH d = 0,6.1,15 0,45 = 0,24 mol
M kh = 7,2 : 0,24 = 30 => C2H6 => R1 = 29
Vy m = 0,45.96 + 15,4 0,45.40 = 40,6 gam
Chn A.
(RCOONa + NaOH => RH + Na2CO3)
Dng 4: Hiu sut P Este
Phn ng este ha:
RCOOH
+
ROH
RCOOR +
H2O
B/
a mol
b mol
P/
x mol
x mol
x mol
x mol
Sau p/ (a-x) mol
(b-x) mol
1. Tnh hiu sut ca P este ha:
H b
x 100
x
* Nu a b => H = b . 100 => x =
; b=
100
H
H

a
x
100
x
* Nu a < b => H = a . 100 => x =
a=
100
H
2. Tnh hng s cn bng:
x x

[ RCOOR ' ][ H 2 O]
x2
V V

KC =
a x b x a x b x
[ RCOOH ][ R ' OH ]

V
V
Cu 1: un 12 gam axit axetic vi 1 lung d ancol etylic ( c H2SO4 c lm xc tc). n khi P dng li
thu c 11 gam este. Hiu sut ca P este ho l bao nhiu
A. 70%
B. 75%
C. 62,5%
D. 50%
Cu 2: Tnh khi lng este metyl metacrylat thu c khi un nng 215 gam axit metacrylat vi 100 gam
ancol metylic. Gi thit P este ho t hiu sut 60%.
A. 125 gam
B. 175 gam
C. 150 gam
D. 200 gam
Cu 3: Khi un nng 25,8 gam hn hp ancol etylic v axit axetic c H2SO4 c lm xc tc thu c 14,08
gam este. Nu t chy hon ton lng hn hp thu c 23,4 ml H2O. Tm thnh phn trm mi cht
trong hn hp u v hiu sut ca phn ng este ho.

GV: HU NH
T: 0942235658

NHN DY N THI H

A. 53,5% C2H5OH; 46,5% CH3COOH v hiu sut 80%

B. 55,3% C2H5OH; 44,7% CH3COOH v hiu sut 80%
C. 60,0% C2H5OH; 40,0% CH3COOH v hiu sut 75%
D. 45,0% C2H5OH; 55,0% CH3COOH v hiu sut 60%
Cu 4: un 12 gam axit axetic vi 13,8 gam etanol ( c H2SO4 c lm xc tc) n khi P t ti trng thi
cn bng, thu c 11 gam este. Hiu sut ca P este ho l:
A. 55%
B. 50%
C. 62,5%
D. 75%
Cu 5: Khi thc hin P este ha 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3
mol. t hiu sut cc i l 90% (tnh theo axit). Khi tin hnh este ha 1 mol CH3COOH cn s mol
C2H5OH l (bit cc P este ho thc hin cng nhit )
A. 2,115.
B. 2,925.
C. 2,412.
D. 0,456.
Hng Dn
Ban u
P
Cn bng

CH3COOH + C2H5OH

CH3COOC2H5 + H2O

CH3COOH + C2H5OH

CH3COOC2H5 + H2O

1
1
2/3
2/3
2/3
2/3
1/3
1/3
2/3
2/3

CH 3 COOC 2 H 5 H 2 O 2 / 3.2 / 3

4
Ta c K C
CH 3COOH C 2 H 5 OH 1 / 3.1 / 3
Hiu sut cc i l 90% (tnh theo axit) naxit p= 1.90%=0,9(mol)
Ban u
P
Cn bng

(mol)
(mol)

1
a
(mol)
0,9
0,9
0,9
0,9
(mol)
0,1
(a 0,9)
0,9
0,9
CH 3COOC 2 H 5 H 2 O 0,9.0,9 0,9.0,9 4 a 2,925 B
Ta c K C
CH 3COOH C 2 H 5 OH 0,1.(a 0,9) 0,1(a 0,9)
Cu 6: Hn hp X gm HCOOH v CH3COOH c s mol bng nhau. Ly 5,3 gam hn hp X cho
T/d vi 5,75 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam hn hp este (hiu sut cc
P este ha u bng 80%). Gi tr m l
A. 8,80
B. 7,04
C. 6,48
D. 8,10
Hng Dn
x mol
HCOOH
hh X
46 x 60 x 5,3 x 0, 05 mol nhh X 0,1 mol
CH 3COOH x mol
RCOOH + C2H5OH RCOOC2H5 + H2O
B 0,1
0,125
nRCOOC2H5 0,1.0,8 0, 08 m este 0, 08 8 44 29 6, 48 gam
Cu 7: Cho bit hng s cn bng ca phn ng este ho:
CH3COOH + C2H5OH

CH3COOC2H5 + H2O KC = 4

Nu cho hn hp cng s mol axit v ancol T/d vi nhau th khi P t n trng thi cn bng th % ancol v
axit b este ho l
A. 50%.
B. 66,7%.
C. 33,3%.
D. 65%.
Cu 8: Cho cn bng sau: CH3COOH + C2H5OH

CH3COOC2H5 + H2O KC = 4

Khi cho 1 mol axit T/d vi 1,6 mol ancol, khi h t n trng thi cn bng th hiu sut ca P l
A. 66,67%.
B. 33,33%.
C. 80%.
D. 50%.

GV: HU NH
T: 0942235658

NHN DY N THI H

Cu 9: un nng hn hp X gm 1 mol ancol etylic v 1 mol axit axetic (c 0,1 mol H2SO4 c lm xt), khi
P t n trng thi cn bng c hn hp Y trong c 0,667 mol etyl axetat. Hng s cn bng KC ca
phn ng l
A. KC = 2.
B. KC = 3.
C. KC = 4.
D. KC = 5.
Cu 10: Bit rng P este ho CH3COOH + C2H5OH

CH3COOC2H5 + H2O C hng s cn bng

KC = 4, tnh % Ancol etylic b este ho nu bt u vi [C2H5OH] = 1M, [CH3COOH] = 2 M.

A. 80%
B. 68%
C. 75%
D. 84,5%
Cu 11: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v
mt ancol n chc thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin P este ha 7,6 gam hn hp
trn vi hiu sut 80% thu c m gam este. Gi tr ca m l
A. 4,08.
B. 6,12.
C. 8,16.
D. 2,04.
Hng Dn
Do t axit no, n chc cho H2O = CO2 nn ancol cn tm l ancol no, n chc.
S mol ancol = 0,4 0,3 = 0,1 mol
S mol CO2 do ancol to ra s < 0,3 mol. Vy ancol A c mt hoc hai nguyn t C
TH1 Ancol c 1 nguyn t C vy ancol l CH3OH
S mol CO2 do axit to ra = 0,3 0,1 = 0,2 mol
Khi lng axit = 7,6 0,1.32 = 4,4 gam
CT axit : CnH2n+1COOH c s mol l x mol
Vy: (n+1).x = 0,2 v (14n+46)x = 4,4
Tm c: x = 0,05 v n = 3
Este: C3H7COOCH3 c s mol = 0,05.80% = 0,04 mol
Vy khi lng: 0,04.102 = 4,08 gam A.
TH2 Ancol c hai nguyn t C
Cu 12: Hn hp A gm axit axetic v etanol. Chia A thnh ba phn bng nhau.
+ Phn 1 T/d vi Kali d thy c 3,36 lt kh thot ra.
+ Phn 2 T/d vi Na2CO3 d thy c 1,12 lt kh CO2 thot ra. Cc th tch kh o ktc.
+ Phn 3 c thm vo vi git dd H2SO4, sau un si hn hp mt thi gian. Bit hiu sut ca
P este ho bng 60%. Khi lng este to thnh l bao nhiu
A. 8,80 gam
B. 5,20 gam
C. 10,56 gam
D. 5,28 gam
Hng Dn
CH3COOH: a mol

C 2H 5OH : b mol

Hn hp A

nA a b 2nH2 0,3 mol

a 2nCO2 0,1 mol

a 0,1 mol
b 0,2 mol

V a < b ( hiu sut tnh theo axit) s mol este thc t thu c: n = 0,1.60% = 0,06 mol
Khi lng este thc t thu c: m = 0,06.88 = 5,28 gam p n D
Cu 13: Khi thu phn este A (khng T/d Na, c cu to mch thng di) trong mi trng axit v
c c 2 cht hu c B v C. un 4,04 gam A vi dd cha 0,05 mol NaOH c 2 cht B v D.
Cho bit MD = MC + 44. Lng NaOH d c trung ho bi 100 ml dd HCl 0,1M. un 3,68 gam
B vi H2SO4 c, 170oC vi hiu sut 75% c 1,344 lit olfin (ktc). Tm CTCT A.
A. C3H5(OOCCH3)2.
B. C3H5(OOCC2H5)2.
C. C2H4(OOCCH3)2.
D. C4H8(COOC2H5)2
Hng Dn
C: R(COOH)x ; D: R(COONa)x
67x 45x = 44 => x = 2

GV: HU NH
T: 0942235658

NHN DY N THI H

A: R(COOC2H5)2
R(COOC2H5)2 + 2 NaOH

0,02
0,04
MA = 202 => R = 56 (-C4H8)
A: C4H8(COOC2H5)2
Cu 14: Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c
cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu
t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. M t khc, nu un
nng M vi H2SO4 c thc hi n P este ho (hi u sut l 80%) th s gam este thu c l
A. 34,20
B. 27,36
C. 22,80
D. 18,24
Hng Dn
S C = nCO2/nhh = 3 vy ancol l C3H7OH 4H2O . V nNc < nCO2 nn axit khng no.
Axit c 3C c 2TH:
CH2=CH-COOH 2H2O ; x + y = 0,5 v 4x + 2y = 1,4. Ta c x= 0,2 v
y = 0,3 (nhn)
CHC-COOH 1H2O ; x + y = 0,5 v 4x + y = 1,4. Ta c x= 0,3 v
y = 0,2 (loi nY < nX)
Este l CH2=CH-COOC3H7. Vi m CH2=CH-COOC3H7 = 0,2*0,8*114 = 18,24 (g)
Dng 5: Tnh khi lng cht bo hoc khi lng x phng

Ta c PTTQ: (RCOO)3C3H5 + 3 NaOH 3RCOONa +C3H5(OH)3

( cht bo)
(X phng)
p dng LBT KL:

( glixerol)

mcht bo + mNaOH = mx phng + mglixerol => m ca cht cn tm

Cu 1: Cho 40,3 gam Trieste X ca Glyxerol vi Axit bo T/d va vi 6 gam NaOH. S gam
mui thu c l:
A. 38,1 gam
B. 41,7 gam
C. 45,6 gam
D. 45,9 gam
Hng Dn
S mol NaOH = 6 : 40= 0,15 mol :
C3H5(O-OC- R )3 + 3NaOH C3H5(OH)3 + 3 R COONa
0,05
0,15
0,05
0,15 mol
40,3
6
0,05.92
m gam
Theo nh lut BTKL ta c: Khi lng mui R COONa =40,3+6-0,05.92=41,7 gam.
Cu 2: t chy hon ton m gam cht bo (triglixerit) cn 1,61 mol O2, sinh ra 1,14 mol CO2 v
1,06 mol H2O. Cng m gam cht bo ny T/d va vi dd NaOH th khi lng mui to thnh l
A. 23,00 gam.
B. 20,28 gam.
C. 18,28 gam.
D. 16,68 gam.
Hng Dn
nO/cht bo = 1,06+1,14*2 - 1,61*2= 0,12 mol suy ra ncht bo=0,02mol
mmui=mcht bo+0,06*40-0,02*92 =18,28.
Cu 3: Khi thy phn mt Lipit X ta thu c cc axit bo l Axit oleic, Axit panmetic, Axit
stearic. t chy hon ton 8,6 gam X cn th tch O2(ktc)

GV: HU NH
T: 0942235658

A. 16,128 lt

NHN DY N THI H

B. 20,16 lt

C. 17,472 lt
Hng Dn

D. 15,68 lt

X c CTCT l
Cu 4: un nng 44,5 gam cht bo l triglixerit ca 1 axit hu c no vi 70 ml dd NaOH 20%
(d=1,2g/ml). trung ho lng kim d cn 22,5ml HCl 36,5%(d=1,2g/ml).CTCT ca cht bo.
A.(C17H29COO)3C3H5
B.(C17H31COO)3C3H5
C.(C17H35COO)3C3H5
D.(C15H29COO)3C3H5
Cu 5: Thy phn hon ton 444 gam mt lipit thu c 46g glixerol v hai loi axit bo.Hai loi
axit bo l
A.C17H31COOH v C17H33COOH
B. C15H31COOH v C17H35COOH
C. C17H33COOH v C17H35COOH
D. C15H31COOH v C17H33COOH
Hng Dn
n glixerol = 0,5.
Triglixerit + 3H2O 3 RCOOH + Glixerol
1,5
1,5
0,5
Theo nh lut bo ton khi lng: m axit = 444 +1,5.18 46 = 425g
Vy M tb axit = 425: 1,5 = 283,3. phi c 1 a xit < 283,3 c th l C17H33COOH (282)hoc
C17H31COOH ( 280) hoc C15H31COOH (256)v 1 a xit > 283,3 l C17H35COOH (284)
Nhng th li ch c :0,5.282 + 0,5.2.284 = 425 l hp l. Chn C.
Cu 6: un nng 7,2 gam este X vi dd NaOH d. P kt thc thu c glixerol v 7,9 gam hn
hp mui. Cho ton b hn hp mui T/d vi H2SO4 long thu c 3 axit hu c no, n chc,
mch h Y, Z, T. Trong Z, T l ng phn ca nhau, Z l ng ng k tip ca Y. CTCT ca X
A.

C.

CH2

OCOC2H5

CH

OCOCH2CH2CH3

CH2

OCOCH(CH3)2

CH2

OCOCH2CH2CH3

CH

OCOCH(CH3)2

CH2

OCOC2H3

B.

D.

CH2

OCOCH2CH2CH3

CH

OCOC2H5

CH2

OCOCH(CH3)2

A hoc B

Hng Dn
V Y, Z l ng ng k tip v Z, T l ng phn ca nhau
c th t cng thc chung ca este X: C3H5(OCO C nH 2n1 )3
C3H5(OCO C nH 2n1 )3 + 3NaOH 3 C nH 2n1 COONa + C3H5(OH)3

(1)

7,2
7,9
.3
Theo (1), ta c : nmui = 3neste
41 3(45 14n)
14n 68
Y : C 2 H 5 COOH

n 2,67 CTCT cc cht: Z : CH 3 CH 2 CH 2 COOH

T : CH (CH ) COOH
3 2

p n D

Cu 7: Mt loi cht bo c cha 25% triolein ,25% tripanmitin v 50% tristearin v khi lng.
Cho m Kg cht bo trn P va vi dd NaOH un nng, thu c 1 tn x phng nguyn cht.
Gi tr ca m l
A. 972,75
B. 1004,2
C. 1032,33
D. 968,68
Hng Dn
(C17H33COO)3C3H5 + 3NaOH 3C17H33COONa+ C3H5(OH)3
(M=884)
(912)
(C15H31COO)3C3H5 + 3NaOH 3C16H33COONa+ C3H5(OH)3
(M=806)
(834)

GV: HU NH
T: 0942235658

NHN DY N THI H

(C17H35COO)3C3H5 + 3NaOH 3C17H35COONa+ C3H5(OH)3

(M=890)
(918)
912.0, 25 834.0, 25 918.0,5
x(

) 1 x 0,968679 968, 68(kg)

884
806
890
Cu 8: Mt loi m cha 40% triolein, 20% tripanmitin v 40% tristearin (v khi lng).. X
phng ha hon ton m gam m trn thu c 138 gam glixerol. Gi tr ca m l :
A. 1,326 kg
B. 1,335 kg
C. 1,304 kg
D. 1,209 kg
Hng Dn
M Triolein 884, M Trtearin 890, M Tripanmiti n 806
Ta co

0,4m 0,2m 0,4m

1,5 m 1,304 (kg )

884
806
890

Cu 9: A l mt este to bi 3 chc mch h. un nng 7,9 gam A vi NaOH d thu c 9,6 gam
mui D v Ancol B. Tch nc t B c th thu c propenal. Cho D T/d dd H2SO4 thu c 3 axit
no n chc mch h, trong 2 axit c phn t khi nh l ng phn ca nhau. CTPT ca axit c
phn t khi nh l
A. C5H10O2
B. C7H14O2
C. C4H8O2
D. C6H12O2
Hng Dn
- Ancol B tch nc c th thu c propenal. Vy B l Glixerol
- T/d dd NaOH
( RCOO ) 3 C 3 H 5 3 NaOH 3RCOONa C 3 H 5 (OH ) 5
3. 7,9
7,9

3R 173
3R 173
3.7,9
8,6

R 47,67
3R 173
R 67

2 axit c phn t khi nh l ng phn ca nhau l C3H7COOH

Cu 10: Mt este X pht xut t anol A v axit B n chc 0,01 mol X (m X = 8,90 gam) P va
vi 0,3 lt dd NaOH 0,1M cho ra ancol B v mui C (mC = 9,18 gam). Xc nh CTCT ca X.
A. C3H5(OOCC15H31)3.
B. C3H5(OOCC17H35)3.
C. C3H5(OOCC17H33)3.
D. C3H5(OOCC15H29)3.
Cu 11: Cho 2,4 gam este X bay hi trong mt bnh kn dung tch 0,6 lt. Khi este bay hi ht th p
sut trong bnh 136,50C l 425,6 mmHg. thy phn 25,4 gam X cn 0,3 mol NaOH thu c
28,2 gam mt mui duy nht. Xc nh CTCT ca X, bit rng X pht xut t ancol a chc.
A. C3H5(OOCCH3)3.
B. C3H5(OOCC2H5)3.
C. C2H4(OOCCH3)3.
D. C3H5(OOCCH = CH2)3.
Dng 6: Ch s axit v ch s x phng
Ch s axt ca cht bo: L s miligam KOH cn trung ho lng axit bo t do c trong 1
gam cht bo.
Vml . CM . 56
Ch s axt =
mcht bo ( gam)
Ch s x phng ho ca cht bo: l tng s miligam KOH cn trung ho lng axit t do v
x phng ho ht lng este trong 1 gam cht bo
Ch s x phng =

Vml . CM . 56
mcht bo ( gam)

Cu 1: X phng ho hon ton 2,5 gam cht bo cn 50 ml dd KOH 0,1 M. Ch

s x phng ho ca cht bo l:

GV: HU NH
T: 0942235658

NHN DY N THI H

A. 280
D. 224

B. 140

C. 112

Hng Dn
Vml . CM . 56 50.0,1.56

112 C
Ch s x phng =
mcht bo ( gam)
2,5
Cu 2: trung ho 14 gam mt cht bo cn 15 ml dd KOH 0,1 M. Ch s axit ca cht bo l
A. 6
B. 5
C. 7
D. 8
Hng Dn
Vml . CM . 56 15.0,1.56

6 A
Ch s axt =
mcht bo ( gam)
14
Cu 3: x phng ho hon ton 2,52 gam mt lipt cn dng 90 ml dd NaOH 0,1M. Tnh ch s
x phng ca lipit
A. 100
B. 200
C. 300
D. 400
Cu 4: trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dd cha a gam
NaOH. Gi tr ca a l
A. 0,150
B. 0,280
C. 0,075
D. 0,200
Hng dn:

KOH

m chtbeo . chi so axit

15.7

=1,875.10-3 = n NaOH => a = m NaOH =1,875.10 -3.40= 0,075

1000.56
1000.56

Cu 5: Cho 200 gam mt loi cht bo c ch s axit bng 7 T/d va vi mt lng NaOH, thu
c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam
B. 32,36 gam
C. 30 gam
D. 31,45 gam
Hng dn:
Gi s mol NaOH ban u l a
(RCOO)3C3H5 (Cht bo) +

3NaOH

RCOOH (t do)

NaOH

RCOONa +
H2O
0,025
0,025
mui (x phng) + C3H5(OH)3 + H2O (3)

Bo +

KOH

3RCOONa +

C3H5(OH)3

(1)
(2)
mol

Ch s axit l 7 nn s mol KOH dng trung ha axit l:

200.7.10-3/56 = 0,025mol = s mol NaOH
s mol H2O to ra: 0,025 mol
s mol NaOH phn ng vi trieste l : a 0,025 s mol glixerol thu c:

(a 0,025)
3

LBTKL: mX + m NaOH = m mui + mglixerol + mH2O

(a 0,025)
200 + 40a = 207,55 + 92
+ 18 . 0,025 a = 0,775 m NaOH = 31 gam
3
Cu 6: x phng ho hon ton 50 gam cht bo c ch s axit l 7 cn 0,16 mol NaOH. Tnh
khi lng glixerol thu c?
A. 9,43gam
B. 14,145gam
C. 4,715gam
D. 16,7 gam
Hng dn:

GV: HU NH
T: 0942235658

NHN DY N THI H

(RCOO)3C3H5 (Cht bo) +

3NaOH
3RCOONa +
C3H5(OH)3
(1)
RCOOH (t do)
+
NaOH

RCOONa +
H2O
(2)
Bo
+
NaOH
mui (x phng) + C3H5(OH)3 + H2O (3)
Cn nm r cc khi nim
1. Ch s axit: l s mg KOH (2) cn trung ho ht axit t do c trong 1 gam cht bo
2. Ch s este: l s mg KOH (1) cn thu phn ht este bo c trong 1 gam cht bo
3. Ch s x phng = ch s axit + ch s este
4. Khi lng x phng thu c khi x phng ha.
p dng nh lut bo ton khi lng cho phng trnh s (3)
mbo + mKOH = mx phng + mnc + mglixerol
mx phng = mbo + mKOH - mnc - mglixerol
Cu 7: X phng ha 1 kg cht bo c ch s axit bng 7 ,ch s x phng ha 200.Tnh khi lng
glixerol thu c
A. 9,43gam
B. 14,145gam
C. 4,715gam
D. 105,7 gam
Hng dn
Ch s este ha = 200 - 7 = 193
S mol KOH este ha = 1000*0,193/56 = 3,446429
==> mol Glyxerol = mol KOH/3 = 1,14881
==> khi lng glyxerol = 92*1,14881 = 105,7
Cu 8: X phng ho hon ton 12,5 gam cht bo c ch s x phng l 224, thu c 13,03 gam
mui( Gi thit gc axit trong este v axit t do l nh nhau). Ly ton b lng glyxerol sinh ra
em iu ch thuc n trinitro glyxerat. Ch s axit v khi lng thuc n thu c l:
A.6,5 v 5,942g
B. 5,6 v 4,125g
C. 5,6 v 5,942g
D. p n khc
(RCOO)3C3H5 (Cht bo) +
RCOOH (t do)

3NaOH
3a
NaOH
b

Hng dn
3RCOONa +

C3H5(OH)3
a
RCOONa +
H2O
b

(1)
(2)

n NaOH 3.224 12,5.1039 0,05(mol )

C3 H 5 (OH ) 3
H 2O

Goi

a(mol )
b(mol )

3a b 0,05(3)

LBTKL mChat beo m NaOH mmuoi m glyxerol m H 2O 12,5 0,05.40 13,03 92a 18b(4)
(3), (4) a 0,015 , b 0,05
Chi s Axit 0,005.56.1000.12,5 22,4
mC3H 5 (ONO2 )3 0,015.227 3,405 ( gam)
nNaOH=3.22412,5.1039 = 0,05mol.
gi s mol glyxerol= a v s mol H2O= b
3a + b = 0,05
BTKL: mchatbeo + mNaOH = mmuoi + mglyxerol + mH2O
12,5+0,05.40=13,03+92a+18b
a=0,015 va` b=0,005
Ch s axit: 0,005.56.100012,5=22,4

GV: HU NH
T: 0942235658

NHN DY N THI H

Thuc n l: C3H5(ONO2)3
m = 0,015.227=3,405 gam
Cu 9: Mt cht bo l trieste ca mt a xit v a xit t do cng l a xit cha trong cht bo.Ch s
x phng ca cht bo l 208,77 v ch s a xit l 7.Cng thc Axit trong 1gam cht bo l
A. Stearic
B.Oleic
C. panmitic
D. linoleic
Hng dn:
208,77mg = 0,20877g <=> 0,003728mol KOH
7mg = 0,007g <=> 0,000125mol KOH
(RCOO)3C3H5 + 3KOH 3RCOOK + C3H5(OH)3
0,001201
0,003603
RCOOH + KOH RCOOK + H2O
0,000125 0,000125
Bi cho: 0,001201.(3R +173) + 0,000125.(R+45) = 1
=>R= 211 vy a xit l 211+45 =256:panmitic =>Chn C.
Cu 10: x phng ha 100 kg cht bo c ch s axit l 7 cn dd cha 14,18 kg NaOH.Khi
lng x phng cha 28% cht ph gia thu c l
A.143,7kg
B. 14,37kg
C. 413,7kg
D.41,37kg
Hng dn:
nNaOH = 14180:40 = 354,5mol
n NaOH cn trung ha a xit bo d trong 100 kg l: 0,125.100 = 12,5 mol.
=> nNaOH x phng ha l: 354,5 -12,5= 342mol
(RCOO)3C3H5 + 3NaOH 3RCOONa + C3H5(OH)3
342
114
RCOOH + NaOH RCOONa + H2O
12,5
12,5
Theo nh lut bo ton khi lng c 2phng trnh:
mcht bo + mNaOH = mmui + m glixerol + m H2O
mmui = 100000 + 14180 114.92 12,5.18 =103467g
mx phng = 103467.100/72 = 143704,16g =143,7kg
Chn A.
Cu 11: x phng ho 35 kg triolein cn 4,939 kg NaOH thu c 36,207 kg x phng. Ch s
axit ca mu cht bo trn l:
A. 7
B. 8
C. 9
D. 10
Hng Dn
36,207.1000
119,102mol
304
nNaOH (dng x phng ho) = 119,102 mol
4,939.1000
119,102 4,375mol
nNaOH ( trung ho axit bo t do) =
40
nKOH ( trung ho axit bo t do) = 4,375 mol
4,375.56
.1000 7mg
mKOH (trong 1 g cht bo) =
35000
ch s axit = 7 p n A
Theo bi: nRCOONa (x phng) =

Cu 12: Mt loi cht bo c ch s x phng ho l 188,72 cha axit stearic v tristearin. trung
ho axit t do c trong 100 g mu cht bo trn th cn bao nhiu ml dung dch NaOH 0,05 M
A. 100 ml
B. 675 ml
C. 200 ml
D. 125 ml
Hng Dn

GV: HU NH
T: 0942235658

NHN DY N THI H

axp = 188,72.10-3 phn ng vi 100 g cht bo cn mKOH = 188,72.10-3 .100 = 18,872 g

18,872
0,337(mol ) nNaOH = 0,337 mol
nKOH =
56
n NaOH naxit 3ntristearin 0,337 mol
naxit 0,01mol

ntristearin 0,109mol
mchtbo 284n axit 890ntristearin 100 g
Vy: Trong 100 g mu cht bo c 0,01 mol axit t do nNaOH (p) = 0,01 mol
Vdd NaOH = 200 ml p n C