S GD-T Tnh Bnh nh

Trng THPT Tay sn

KIM TRA HC K II - Nm hc 2010-2011

Mn: Ha 11 - Ban KHTN
Thi gian: 45 pht
A. Phn trc nghim: (05 im) Chn phng n ng
Cu 1. Mt ankan c t khi hi so vi khng kh bng 2. Cng thc phn t ca ankan l?
A. C5H12
B. C3H8
C. C6H14
D. C4H10
Cu 2. un nng Ancol iso-butylic 170oC, c mt ca H2SO4 c lm cht xc tc, thu c bao nhiu
anken?
A. 1
B. 3
C. 2
D. Khng thu c anken
Cu 3. Tn gi ca hp cht hu c c CTCT: CH3-CH(CH2-CH3)-CH2-CH(CH2-CH3)-COOH l?
A. Axit-2-etyl-4-metylhexanoic
B. Axit-2-metyl-5-cacboxiheptan
C. Axit-2-metyl-4-etylhexanoic
D. Axit-2,4-ietylpentanoic
Cu 4. X l ancol mch h c 1 ni i C=C Cng thc phn t no sau y khng ng vi X:
A. C3H6O
B. C2H4O
C. C4H8O
D. C4H8O2.
Cu 5. Cho 7 gam hn hp gm hai anken M v N l ng ng k tip ca nhau qua nc brom lm mt
mu va 32 gam Brom. M v N l cng thc no sau y?
A. C4H8 v C5H10
B. C3H6 v C4H8
C. C5H10 v C6H12
D. C2H4 v C3H6
Cu 6. Cho cc cht Na, dd NaOH, CH3COOH, Na2CO3, C2H5OH. Hy cho bit c my cp cht tc dng
c vi nhau?
A. 5
B. 6
C. 3
D. 4
Cu 7. Hirocacbon c CTPT C4H6 c bao nhiu ng phn tham gia c phn ng vi dung dch
AgNO3/NH3 to ra kt ta mu vng nht?
A. 3
B. 2
C. 4
D. 1
Cu 8. Ancol no n chc mch h X to ete Y. T khi hi ca Y so vi X gn bng 1,61. Tn ca X l?
A. metanol
B. propan-2-ol
C. etanol
D. propanol
Cu 9. C my dn xut C4H9Br khi tc dng vi dung dch KOH, etanol trong mi trng hp ch to ra
anken duy nht
A. Hai cht
B. Ba cht
C. Mt cht
D. Bn cht
Cu 10. Cho 15,6 gam C6H6 tc dng ht vi Cl2 (xc tc bt Fe). Nu hiu sut phn ng l 80% th khi
lng clobenzen thu c l bao nhiu ?
A. 19 gam
B. 20 gam
C. 21 gam
D. 18,16 gam
Cu 11. Chon trnh t thuoc th nhan biet cac chat : Axit acrylic, Axit axetic, Anehit
axetic, Phenol .
A. Tat ca eu ung.
ddBr2, ddAgNO3/NH3

B. ddBr2, Quy tm.

C. Quy tm, ddBr2.

D.

Cu 12. Ten goi cua hp chat hu c co CTCT CH=CHBr-CH(CH3)-CH3 la :

A. 2-brom-3-metylbut-3-in B. 2-brom-3-metylbut-1-en C. 3-brom-2-metylbut-3en
D. 3-brom-2-metylbut-1-in
Cu 13. Hay chon phat bieu ung ?
A. Axit cacboxylic no n chc la nhng hp chat hu c trong phan t
co nhom COOH lien ket vi goc hirocacbon khong no .
B. Axit cacboxylic la nhng hp chat hu c trong phan t co nhom
COOH lien ket trc tiep vi goc hirocacbon hoac nguyen t H.
C. Axit cacboxylic khong no , n chc, goc hirocacbon co mot lien ket
oi co CTPT chung la CnH2n+1COOH.
D. Axit cacboxylic la nhng hp chat hu c trong phan t co nhom
CHO lien ket trc tiep vi goc hirocacbon hoac nguyen t H.
Cu 14. Hp chat hu c co CTPT C7H8O co bao nhieu ong phan thm tac dung
c vi kim loai Na ?
A. 1
B. 2
C. 3
D. 4
Cu 15. t chy hon ton 1,3 gam hidrocacbon X th lng thu c 2,24 lt kh CO2 (ktc). Cng thc

phn t ca X l:
A. C2H2

B. C6H6

C. C4H4

D. C6H12

B. T lun: (05 im)

Cu 1: (02 im)
Vit cc phng trnh phn ng ha hc di dng cng thc cu to thu gn, theo dy chuyn ha
sau. Xc nh A1, A2, A3, A4
2 ,as
Toluen Cl

A1
(1)

NaOH,t

(2)

A2

CuO,t o
(3)

A3

Ag 2 O,dd NH 3 ,t o
(4)

A4

Cu 2: (03 im)
Trn hirocacbon X (ng ng ca C 2H2) vi mt hirocacbon Y, ri t chy v dn ton b sn
phm vo bnh nc vi c 35 gam kt ta v dung dch c khi lng tng 12,4 gam so vi ban u.
Dung dch ny khi tc dng vi kim d li cho 20 gam kt ta na.
a/ Xc nh dy ng ng ca Y.
b/ Xc nh cng thc phn t ca X v Y, bit chng l cht lng iu kin thng v c t l mol
l 1:2.
c/ Tm CTCT X,Y, bit X c mch cacbon phn nhnh; khi Clo ha Y bng Clo theo t l mol 1:1
300oC thu c mt sn phm duy nht. Gi tn X, Y.
( Cho Ca = 40, C = 12, O = 16 )

A/ P N TRC NGHIM
01.D; 02. A; 03. D; 04. D; 05. D; 06. A; 07. D; 08. C; 09. A; 10. D; 11A, 12B,13B,14A,15B
B/ T LUN: 5 im
Lu : HS gii ng theo cch khc vn tnh im ti a
Cu
1

p n
Mi pthh vit ng c 0,5 im. Nu thiu iu kin hoc thiu cn bng
phn ng hoc thiu c 2 th tr na s im ca pthh .
1/ C6H5CH3 + Cl2
as
C6H5CH2Cl + HCl
t0

2/ C6H5CH2Cl + NaOH
3/ C6H5CH2OH + CuO
4/ C6H5CHO + Ag2O
2

t0
dd NH3, t0

im
0,5 im

C6H5CH2OH + NaCl

0,5 im

C6H5CHO + Cu + H2O

0,5 im

C6H5COOH + 2Ag

0,5 im

a/ )
nCO2 = 0,75
mCO2 + mH2O = mCaCO3 + mdd tng
mH2O = 14,4 gam , nH2O = 0,8 mol

V X l an kin, nH2O = 0,8 mol > nCO2 = 0,75

Y l an kan

b/ t X: CnH2n-2 (a mol) Y: CmH2m+2 ( 2a mol ) ( n,m >= 5)

CnH2n-2 + (3n-1)/2 O2
n CO2 + (n-1) H2O
a
an
(n-1) a
CmH2m+2 + (3m+1)/2 O2
mCO2 + (m+1) H2O
2a
2am
(m+1)2a
Ta c: an + 2am = 0,75 (1)
(n-1)a + (m+ 1) 2a = 0,8 (2)
T 1,2 => a= 0,05 mol
0,05 n + 0,1 m = 0,75

n + 2m = 15

n = 15-2m ; m = (15 n) /2

15 -2m >= 5 => m = 5

(15 n) /2 >= 5 => n = 5

X: C5H8 Y: C5H12

c/ Do X c mch cacbon phn nhnh nn X c cu to l:

CH = C-CH(CH3)2
3- metyl but-1-in
Do Y Tc dng vi clo vi t l mol 1:1 ch cho 1 sp th duy nht nn CTCT
Y l: C(CH3)4
neo pen tan

0,25 im
0,25 im
0,25 im
0,25 im

0,25 im
0,25 im
0,25 im
0,25 im
0,25 im
0,25 im
0,25 im
0,25 im

C/ MA TRN KIM TRA HOC K II. MN HA HC 11-BAN KHTN.

Chu e
1.Hidrocacbon

Nhan biet
TN
TL
3

1.0
xuat 2

2.

Dan
halogen,ancol,ph
enol
0.7
3. Andehit-xeton-axit 1
cacboxylic

4.

Thong hieu
TN
TL
3

Van dung
TN
TL
1

8
1,
5

1.0
1

1.5
1

0.33
1

0.33
1

1.5

0.33

0.33

0.33

2.0

2.0

1.0
1

1.7
1

2.0
3

2.0
18

1.0

5.0

10.0

Bai

toan
tnh
thanh
phan hon hp

Tong

Trng THPT Tay sn

2010 - 2011

2
3.0

Tong

E THI KIEM TRA HOC KY II NAM HOC

Ho va ten:
(khong tnh thi gian phat e)

Mon: Hoa hoc khoi 10 c ban

Thi gian: 45 phut

Lp:
A/ PHAN TRAC NGHIEM : (5) Chon phng an ung:
Cu 1. Day kim loai phan ng H2SO4 loang la:
A. Al, Fe, Zn, Mg, Ba, K.
B. Al, Fe, Zn, Mg, Au, K.
C. Al, Fe, Zn, Cu, Ba, K.
D. Al, Fe, Ag, Mg, Ba, K.
Cu 2. Hoa tan 0,2 mol kh hirosunfua vao nc c dd A. Cho 500ml dd NaOH
1M vao dd A tren. khi nhung giay qu tm vao dd thu c th giay qu tm
chuyen sang mau nao?
A. o
B. Xanh
C. Khong oi mau
D. Khong xac
nh
Cu 3. Day kim loai phan ng H2SO4 ac, nguoi la:
A. Cu, Fe, Al, Zn, Ba.
B. Cu, Ag, Mg, Zn,
Ba.
C. Cu, Ag, Fe, Zn, Ba.
D. Cu, Ag, Al, Zn,
Ba.
Cu 4. Hoa tan hoan toan 2,24 lt kh hiroclorua (KTC) vao 46,35 gam nc
thu c dung dch HCl co nong o la(H = 1; Cl = 35,5):
A. 73%
B. 67%
C. 7,3%
D. 6,7%
Cu 5. Muon pha loang axit H2SO4 ac , can lam nh sau:
A. Rot t t nc vao dung dch axit ac
B. Rot nc that nhanh
vao dung dch axt ac
C. Rot t t dung dch axt ac vao nc

D. Rot nhanh dung dch axit ac vao nc

Cu 6. Xet he can bang sau: H2(kh) + Cl2(kh)

2HCl(kh) ; H < 0; Can bang
chuyen dch sang ben trai khi:
A. Giam nhiet o
B. Tang nong o hiro C. Tang
nhiet o
D. Tang ap suat
Cu 7. o dung dch AgNO3 vao dung dch muoi nao sau ay se khong co
phan ng?
A. NaI
B. NaF
C. NaCl
D. NaBr
Cu 8. Nc Gia - ven la hon hp chat nao sau ay:
A. NaCl, NaClO, H2O
B. NaCl, NaClO3, H2O
C. HCl, HClO, H2O
D. NaCl, NaClO4, H2O
Cu 9. Mot chat co cha nguyen to oxi dung e lam sach nc, cha
sau rang va co tac dung bao ve cac sinh vat tren trai at khong b
bc xa cc tm. Chat nay la:
A. Ozon
B. Lu huynh ioxit
C. Oxi
D.
Cacbon ioxit
Cu 10. Hoa tan hoan toan 3,6 gam kim loai M co hoa tr II khong oi trong
H2SO4 ac nong d thu c 3,36 lt kh SO 2 (KTC) kim loai R la (Mg = 24; Zn =
65; Ba = 137; Ca = 40)
A. Zn
B. Ba
C. Mg
D. Ca
Cu 11. Cho day cac chat: H2S, S, SO2, H2SO4. So chat va co tnh kh, va
co tnh oxi hoa la:
A. 3
B. 2
C. 4
D. 1
Cu 12. Trong day cac axit: HCl, HBr, HI, HF, axit manh nhat la:
A. HF
B. HBr
C. HCl
D. HI
Cu 13. Trong phan ng: Br2 + H2O HBr + HBrO, brom ong vai tro:
A. Va la chat oxi hoa, va la chat kh
B. Chat tan
C. Chat kh
D. Chat oxi hoac
Cu 14. Chon trnh t thuoc th e nhan biet cac kh : H2S , HCl, CO2
A. Pb(NO3)2 , AgNO3
B. Quy tm, dung dch Ca(OH)2
C. Ca(OH)2 , Quy tm
D. Dung dch AgNO3,
NaOH
Cu 15. Trong nhom halogen, tnh oxi hoa thay oi theo th t:
A. F>Cl>Br>I
B. F<Cl<I<Br
C. F>Cl>I>Br
D. F<Cl<Br<I

B/ PHAN T LUAN: (5)

Cau 1 (2): Thc hien nhng bien oi hoa hoc sau bang cach viet nhng
phng trnh hoa hoc, ghi ieu kien phan ng neu co:
H2S
SO2
H2SO4
CuSO4
CuCl2
3
2
4
1
Cau 2:(3): Hoa tan hoan toan 2,1 gam hon hp X gom Al va Al 2O3 trong
H2SO4 ac nong d thu c 1,344 lt kh SO2 duy nhat (KTC) va dung dch D.
a/ Viet cac phng trnh hoa hoc cac phan ng xay ra.
b/ Tnh khoi lng Al va Al2O3 trong 2,1 gam hon hp X?
c/ Neu hap thu hoan toan kh SO 2 thu c tren vao 80 ml dung dch
NaOH 1M th khoi lng muoi tao thanh sau phan ng bang bao nhieu ?
( Al = 27; O = 16; Na = 23; H = 1; S = 32)
(Hoc sinh khong s dung Bang tuan hoan cac nguyen to hoa hoc)
C/ MA TRN KIM TRA HOC K II. MN HA HC 10-C BN.

(NI DUNG: NHM HALOGEN NHOM OXI LU HUYNH-TOC O PHAN

NG VA CAN BANG HOA HOC))
Chu
e
1.Nho
m
Halogen
2.OxiLu
huynh
3.Toc
o
phan
ng
va
can
bang
hoa
hoc
4.Bai
toan
tnh
thanh
phan
hon
hp
5.Tong
hp
nhom
halogen
; oxi-lu
huynh
Tong

Nhan biet
TN
TL

Thong hieu
TN
TL

Van dung
TN
TL

Tong

1.0
2

0.33
2

0.33
1

1,7
5

0.7
1

0.7
1

0.33
1

1.7
3

0.33

0.33

1.0

1.7

2.0

2.0

0.7
6

0.33
3

2.0
3

3.0
18

2.0

2.0

1.0

5.0

10.0

ap an:
IPHAN TRAC NGHEM: 5 iem (mi cu ng 0,33 iem)
1A, 2C, 3B, 4C, 5C, 6C, 7B, 8A ,9A, 10C ,11B ,12D, 13A, 14A ,15A
IIPHAN T LUAN: (5 iem)
Cau 1: :( 2)
Moi PTHH ung 0,5 iem (neu can bang sai hoac thieu ieu kien
tr 0,25 iem/ 1 phan ng)
(1) 2H2S +3O2
2SO2+ 2H2O
( K : t0 )
(2) SO2 + Br2 +2H2O
H2SO4 +2HBr
(3) H2SO4 + CuO
CuSO4 + H2O.
(4) CuSO4 +BaCl2
BaSO4 + CuCl2
(Hoc sinh co the viet phan ng ung khac )
Cau 2:( 3)
a/ PTHH:
2Al+ 6H2SO4 (ac)
Al2(SO4)3 +3SO2 + 6H2O
(0,25 )
Al2O3+ 3H2SO4
Al2(SO4)3 + 3H2O
(0,25)
b/
n SO2 = 0,06 mol
(0,25)
n Al
= 0,04 mol
(0,25)
mAl
= 0,04x 27= 1,08 gam
(0,25)
m oxit
= 2,1 1,08== 1,02 gam
(0,25)
c/
nNaOH = 0,08 mol
nNaOH/ n SO2
= 0,08/0,06 => 2 muoi tao thanh
(0,25)
SO2 + NaOH
NaHSO3
x
x
x
( 0,25)
SO2 + 2NaOH
Na2SO3+ H2O
y
2y
y

x y 0,06

x 2 y 0,08

(0,5)

suy ra x=0,04 ; y=0,02 ( 0,25);

Khi lng NaHSO3 =4,16g
Na2SO3 = 2,52g ( 0,25)