S GD-T Vnh Phc

Trng THPT Chuyn Vnh Phc

KHO ST THI I HC LN 4 NM HC 2009-2010

Mn: HO HC LP 11
Thi gian 90 pht

Bi 1 (1,5im)
Hon thnh s phn ng (ghi r cht phn ng v iu kin ca tng phn ng)
(1)
(2)
(3)
CH4
X1
X2
HCHO
(4)
(6)
(7)
(5)
(8)
X3
X4
X5
X6
C6H5OH
Bi 2 (1,0im)
T Butan vit s phn ng iu ch Glixerol (ghi r iu kin phn ng).
Bi 3 (1,0im)
Vit cng thc cu to v gi tn cc ng phn ancol c cng thc phn t C4H10O.
Bi 4 (1,5im)
Cho hn hp gm ru etylic v phenol (hn hp A) tc dng vi natri (d). Sau phn ng thy bnh
ng natri tng thm 16,38gam. Nu cho A phn ng vi nc brom n khi khng cn xut hin kt ta
trng th dng ht 900ml dung dch Br2 0,2M.
a) Vit phng trnh ho hc ca cc phn ng xy ra.
b) Tnh phn trm khi lng ca mi cht trong A.
Bi 5 (0,75im)
Mt ru X tc dng vi axitbromhidric d thu c sn phm X 1, trong phn t X1 brom chim
58,39% khi lng. un X vi H2SO4 1700C thu c ba anken Y, Y1, Y2. Hy vit cng thc cu to ca
X, X1, Y, Y1, Y2.
Bi 6 (1,0im)
t chy hon ton 0,7mol mt ancol no mch h X cn dng va ht 62,72 lt oxi (ktc). Xc
nh cng thc phn t, cng thc cu to v gi tn ca X .
Bi 7 (1,0im)
Hirat ho hn hp Y gm etilen v propilen c t khi so vi hiro l 16,8 iu kin thch hp thu
c hn hp ru Z, trong ru bc hai chim 34,88% khi lng. Xc nh phn trm khi lng cc
ru cn li c trong hn hp Z.
Bi 8 (1,0im)
Hirocacbon X th lng, lm mt mu thuc tm, c M X < 110 v phn trm khi lng cacbon xp
x bng 92,3%. Xc nh cng thc phn t v vit cng thc cu to ca X. ( Bit X thuc hirocacbon
hc)
Bi 9 (0,75im)
un nng ba ru X, Y, Z (u c s nguyn t cacbon ln hn 1) vi H 2SO4 1700C thu c hn
hp hai olefin l ng ng lin tip. Ly hai trong s ba ru un vi H 2SO4 c 1400C c 1,32gam
h hp ba ete. Mt khc, lm bay hi ba ete ny c th tch ng bng th tch ca 0,48gam oxi (o cng
iu kin). Xc nh cng thc cu to ca X, Y, Z.
Bi 10 (0,5im)
oxi ho a gam mt ancol no, n chc cn va 3,2gam CuO. Sau phn ng hon ton, thu
c hn hp hi c t khi i vi metan l 1,9375. Xc nh gi tr ca a.

(Cho H = 1 ; O =16; C =12 ; Ag =108; Cu =60 ; Br =80.)

S GD-T Vnh Phc

Trng THPT Chuyn Vnh Phc

P N KS THI I HC LN 4 NM HC 2009-2010
Mn: HO HC LP 11
Thi gian 90 pht

Bi 1 (1,5im)
Hon thnh s phn ng (ghi r cht phn ng v iu kin ca tng phn ng)
(1)
(2)
(3)
CH4
X1
X2
HCHO
(4)
(6)
(7)
(5)
(8)
X3
X4
X5
X6
C6H5OH
Gii
im
0

1500

CH4

C2H2

+ Cl2/as

C, 6000C

CH3Cl

+ NaOH
T0C

C6H6

+ NaOH d
+Cl2, Fe,
0
C
H
Cl
C6H5ONa
6
5
T0C
tC

CH3OH

+ CuO
T0 C

HCHO

0,5
+ CO2
H2O

C6H5OH

Bi 2 (1,0im)
T Butan vit s phn ng iu ch Glixerol (ghi r iu kin phn ng).
Gii
+ H2O+ Cl2
+ t0C
+ Cl2
a) C4H10crackinh CH2=CH-CH3 4500C
CH2=CH-CH2Cl T0C
CH2Cl-CH2OH-CH2Cl
+ NaOH
CH2Cl-CH2OH-CH2Cl T0C

1,0

im
0,75

CH2OH-CHOH-CH2OH

Bi 3 (1,0im)
Vit cng thc cu to v gi tn cc ng phn ancol c cng thc phn t C4H10O.
Cng thc cu to
Tn gi
CH3-CH2-CH2-CH2-OH
Butan 1-ol hay ru butylic
CH3-CH2-CHOH-CH3
Butan 2-ol hay ru sec-butylic
CH3 COH(CH3)2
2-metylpropan 2- ol hay ru tert- butylic
(CH3)2-CH-CH2-OH
2-metylpropan -1-ol hay ru isobutylic

im
0,25
0,25
0,25
0,25

Bi 4 (1,5im)
Cho hn hp gm ru etylic v phenol (hn hp A) tc dng vi natri (d). Sau phn ng thy bnh
ng natri tng thm 16,38gam. Nu cho A phn ng vi nc brom n khi khng cn xut hin kt ta
trng th dng ht 900ml dung dch Br2 0,2M.
a)Vit phng trnh ho hc ca cc phn ng xy ra.
b)Tnh phn trm khi lng ca mi cht trong A.
Gii
a)phng trnh phn ng:
im
C2H5OH + Na -> C2H5ONa + 1/2H2
0,25
C6H5OH + Na -> C6H5ONa + 1/2H2
0,25
C6H5OH + 3Br2 -> C6H2OH(Br)3 + 3HBr
0,25
b) S mol phenol = 0,9.0,2: 3 = 0,06mol -> Khi lng phenol = 0,06.94 = 5,64gam
0,25

C n (C2H5OH). 46 + n (C6H5OH).94 0,5. [(n (C2H5OH) + n (C6H5OH)] = 16,38

-> n (C2H5OH) = 0,24 mol -> m (C2H5OH) = 11,04gam
-> % m (C2H5OH) = 66,19% ; m (C6H5OH) = 33,81%

0,25
0,25

Bi 5 (0,75im)
Mt ru X tc dng vi axit bromhidric d thu c sn phm X 1, trong phn t X1 brom chim
58,39% khi lng. un X vi H2SO4 1700C thu c ba anken Y, Y1, Y2. Hy vit cng thc cu to ca
X, X1, Y, Y1, Y2.
Gii
un X vi axit H2SO4c 1700C -> 3 anken. X l ru no n chc.
im
Gi CT X1 l R-Br -> MX1= (80.100)/58,39 = 137 -> R = 57. (C4H9-)
0,25
X tch nc to ba anken -> CTCT X : CH3CH(OH)-CH2CH3 ; X1: CH3CHBr-CH2CH3
0,75
CTCT Y, Y1, Y2 : CH2=CH-CH2-CH3; CH3-CH=CH-CH3 (cis v trans)
Bi 6 (1,0im)
t chy hon ton 0,7mol mt ancol no mch h X cn dng va ht 62,72 lt oxi (ktc). Xc
nh cng thc phn t, cng thc cu to v gi tn ca X .
Gii
Gi cng thc ca ru l CnH2n+2Oa
im
CnH2n+2Oa + (3n + 1 -a)/2 O2 -> nCO2 + (n + 1) H2O
1
(3n + 1 -a)/2
0,7
2,8
-> 3n = 7 + a ; iu kin n a ; 3n>7 -> 2,33< n < 3,5 -> n =3 v a = 2
0,5
Vy CTPT ca X l: C3H8O2
CTCT HO-CH2-CH2-CH2-OH Propan- 1,3- iol
0,5
v CH3-CHOH-CH2-OH
Propan- 1,2- iol
Bi 7 (1,0im)
Hirat ho hn hp Y gm etilen v propilen c t khi so vi hiro l 16,8 iu kin thch hp thu
c hn hp ru Z, trong ru bc hai chim 34,88% khi lng. Xc nh phn trm khi lng cc
ru cn li c trong hn hp Z.
Gii
* T l mol ca C2H4 v C3H6 l 60% v 40%
im
Gi s c 1 mol hn hp kh -> C2H4 = 0,6mol; C3H6 = 0,4mol
0,25
-> Khi lng ru thu c l (p dng nh BTKL)
0,6.28 + 0,4.42 + 1.18 = 51,6 gam
0,25
-> % khi lng C2H5OH l : 53,49% ;
0,25
% khi lng n- C3H7OH l: 100% - 53,49 34,88 = 11,63%
0,25
Bi 8 (1,0im)
Hirocacbon X th lng, lm mt mu thuc tm, c M X < 110 v phn trm khi lng cacbon xp
x bng 92,3%. Xc nh cng thc phn t v vit cng thc cu to ca X. ( Bit X thuc mt trong cc
dy hirocacbon hc)
Gii
Xc nh c t l nguyn t C : nguyn t H = 1:1
im
Theo gi thit: CTPT ca X l C8H8
0,5
CTCT l : C6H5-CH=CH2
0,5
Bi 9 (0,75im)
un nng ba ru X, Y, Z (u c s nguyn t cacbon ln hn 1) vi H 2SO4 1700C thu c hn
hp hai olefin l ng ng lin tip. Ly hai trong s ba ru un vi H 2SO4 c 1400C c 1,32gam

h hp ba ete. Mt khc, lm bay hi ba ete ny c th tch ng bng th tch ca 0,48gam oxi (o cng
iu kin). Xc nh cng thc cu to ca X, Y, Z.
Gii
Theo d kin bi ton
im
- X, Y, Z phi l ru no, n chc. Trong c hai ru l ng phn ca nhau.
-Gi cn thc hai ru to ete l ROH
ROH ---> R2O + H2O
0,25
a mol
0,5 amol
-S mol ba ete = 0,5a = 0,48: 32 = 0,015.
0,25
Ta c: 2(R + 16).0,15 = 1,32 -> R = 36
-> 29 (C2H5) < R < 43 (C3H7).
0,25
Vy CTCT ca ba ru l: CH3-CH2OH ; CH3CH2CH2OH; CH3CHOH-CH3.
Bi 10 (0,5im)
oxi ho hon ton a gam mt ancol no, n chc cn va 3,2gam CuO. Sau phn ng thu
c hn hp hi c t khi i vi metan l 1,9375. Xc nh gi tr ca a.
Gii
S mol CuO p 0,04mol; -> m Cu = 2,56gam
im
S mol hn hp hi = 0,04.2 = 0,08
Khi lng hn hp hi = 0,08.16.1,9375 = 2,48gam
0,25
p dng LBTKL : a = (2,48 + 2,56) 3,2 = 1,84 gam
0,25