TRNG I HC NGOI THNG H NI

THI TH QUC GIA NM 2015

CU LC B GIA S HA HC
MN HA HC
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Nguyn Anh Phong
Cu 1 : Hn hp X gm 3 peptit A,B,C u mch h c tng khi lng l m v c t l s mol l
n A : n B : n C 2 : 3 : 5.Thy phn hon ton X thu c 60 gam Glyxin ; 80,1gam Alanin v 117 gam
Valin.Bit s lin kt peptit trong C,B,A theo th t to nn 1 cp s cng c tng l 6. Gi tr ca m
l :
A.226,5
B.262,5
C.256,2
D.252,2
Cu 2: Nhng nguyn t no sau y l nguyn t kim loi: X(Z=3); Y(Z=7); M(Z=12); N(Z=19).
A. X;M;N.
B. X;Y;N.
C. X;Y; M
D. Y;M;N
Cu 3 : Lin kt ha hc trong phn t HCl thuc loi lin kt.
A. cng ha tr khng cc.
B. cng ha tr c cc
C. ion
D. hiro
Cu 4 : Cho 5,1 gam hn hp bt gm Mg v Al c t l mol 1 : 1 vo dung dch hn hp 150ml
cha AgNO3 1M , Fe(NO3)3 0,8M ,Cu(NO3)2 0,6M sau khi cc phn ng xy ra hon ton thy c m
gam rn xut hin.Gi tr ca m l :
A.24,32
B.23,36
C.25,26
D.22,68
Cu 5 : Hn hp X gm metan, propan, etilen, buten c tng s mol l 0,57 mol tng khi lng l
m.t chy hon ton m gam X cn va 54,88 lit O2 (ktc).Mt khc cho m gam X qua dung dch
Br2 d th thy s mol Br2 phn ng l 0,35 mol.Gi tr ca m l :
A. 22,28
B. 22,68
C. 24,24
D. 24,42
Cu 6 : Ho tan hon ton 13,8 gam hn hp X gm 2 kim loi Fe, Al vo dung dch HNO3 d thu c
dung dch Y v 5,6 lt kh NO (kc). C cn cn thn dung dch Y thu c 81,9 gam mui khan.S mol
HNO3 tham gia phn ng l :
A. 1,0 mol
B. 1,25 mol
C. 1,375 mol
D. 1,35 mol
Cu 7 : Sn phm ca phn ng nhit phn hon ton KNO3 l:
A. KNO2, O2.
B. KNO2, N2, O2.
C. KNO2, NO2, O2.
D. KNO2, NO, O2.
Cu 8 : Nh rt t t 400ml dung dch HCl 0,5M vo 100ml dung dch hn hp cha NaHCO3 0,5M
v Na2CO3 1M.Sau khi cc phn ng xy ra hon ton thy c V lt kh thot ra ktc.Gi tr ca V
l :
A.4,48
B.3,36
C.2,688
D.2,24
Cu 9 : Natri silicat c th c to thnh bng cch :
A.un SiO2 vi NaOH nng chy.
B.Cho SiO2 tc dng vi dung dch KOH long.
C.Cho dung dch K2SiO3 tc dng vi dung dch NaHCO3.
D.Cho Si tc dng vi dung dch NaCl.

Ra : Ch nhim CLB Nguyn Anh Phong 0975 509 422

Cu 10 : Cho 26,88 gam bt Fe vo 600ml dung dch hn hp A gm Cu(NO3)2 0,4M v NaHSO4

1,2M. Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn B v kh NO (sn phm kh
duy nht, ktc).Gi tr ca m l :
A.17,04
B.15,36
C.15,92
D.13,44
Cu 11:Trong dung dch H3PO4 c th cha tng s loi ion l(khng k s phn li ca H2O):
A.2
B.3
C.4
D.5
Cu 12: Trong s cc pht biu sau v phenol (C6H5OH):
(1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl.
(2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm.
(3) Phenol dng sn xut keo dn, cht dit nm mc.
(4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l:
A. (1), (2), (4).
B. (2), (3), (4).
C. (1), (2), (3).
D. (1), (3), (4).
Cu 13 : t chy hon ton m gam mt hn hp nhiu ancol no A thu c 0,3 mol CO2 v 0,5 mol
H2O.Mt khc,m gam A tc dng vi Na d thu c mui.Khi lng mui ln nht c th l :
A.12,1 gam
B.12,2 gam
C.16,0 gam
D.14,0 gam
Cu 14: Cho 13,25 gam hn hp gm Al v Fe vo 500 ml dung dch Cu(NO3)2 0,75M v Fe(NO3)3
0,4M thu c dung dch X v m gam rn Y. Cho dung dch NaOH d vo dung dch X, ly kt ta
nung ngoi khng kh n khi lng khng i thu c 20,0 gam oxit duy nht. Gi tr m l.
A. 24,0 gam
B. 21,2 gam
C. 26,8 gam
D. 22,6 gam
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Ra : Nguyn Anh Phong 0975 509 422
Cu 15 : Cho 31,15 gam hn hp bt Zn v Mg (t l mol 1 : 1) tan ht trong dung dch hn hp
gm NaNO3 v NaHSO4 thu c dung dch A ch cha m gam hn hp cc mui v 4,48 lt (ktc)
hn hp kh B gm N2O v H2 .Kh B c t khi so vi H2 bng 11,5.Gi tr ca m l :
A.123,4
B.240,1
C.132,4
D.p n khc
Cu 16: Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH), Anehit oxalic,
mantoz, ancol anylic, vinyl axetat. S cht trong dy c kh nng lm mt mu nc brom l
A. 4.
B. 5.
C. 7.
D. 6.
Cu 17: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5)
(C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l :
A. (4), (1), (5), (2), (3).
B. (3), (1), (5), (2), (4).
C. (4), (2), (3), (1), (5).
D. (4), (2), (5), (1), (3).
Cu 18: Cho cc pht biu sau v cacbohirat:
(a) Tt c cc cacbohirat u c phn ng thy phn.
(b) Thy phn hon ton tinh bt thu c glucoz.
(c) Glucoz, fructoz v mantoz u c phn ng trng bc.
(d) Glucoz lm mt mu nc brom.
(e) Thy phn mantozo thu c glucoz v fructoz
S pht biu ng l:
A. 2.
B. 4.
C. 3.
D. 1.
Cu 19: Cho 0,15 mol tristearin ((C17H35COO)3C3H5) tc dng hon ton vi dung dch NaOH d,
un nng, thu c m gam glixerol. Gi tr ca m l
A. 27,6.
B. 9,2.
C. 14,4.
D. 13,8.
Ra : Ch nhim CLB Nguyn Anh Phong 0975 509 422

Cu 20: Thy phn hn hp gm 0,8 mol saccaroz v 0,6 mol mantoz mt thi gian thu c dd
X (hiu sut phn ng thy phn mi cht ln lt l 60% v 75%). Khi cho ton b X (sau khi
trung ha axit ) tc dng vi dd AgNO3/NH3 d th lng Ag thu c l:
A. 3,72 mol
B. 4,02 mol
C. 4,22 mol
D. 2,73 mol
Cu 21: Cho cc pht biu sau:
(a) Anehit va c tnh oxi ha va c tnh kh
(b) Phenol tham gia phn ng th brom kh hn benzen
(c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt
(d) Dung dch axit axetic tc dng c vi Cu(OH)2
(e) Dung dch phenol trong nc lm qu tm ha
(f) Trong cng nghip, axeton c sn xut t cumen
(g) Etylamin tc dng vi axit nitro nhit thng to ra etanol.
(h) Metylamin tan trong nc to dung dch c mi trng bazo.
S pht biu ng l
A. 5
B. 4
C. 7
D. 6
Cu 22: Hn hp A gm 0,3 mol hai ancol ng ng lin tip.t chy hon ton A thu c 0,5
mol CO2.Mt khc oxi ha A th thu c hn hp B gm cc axit v andehit tng ng (Bit 60
% lng ancol bin thnh andehit phn cn li bin thnh axit).Cho B vo dung dch AgNO3/NH3
d thu c m gam Ag.Gi tr ca m l :
A.38,88 gam
B.60,48 gam
C.51,84 gam
D.64,08 gam
Cu 23 : Cho K d vo 75 gam dung dch CH3COOH 16% thy c V lt kh (ktc) thot ra.Gi tr
ca V l :
A.41,44
B.2,24
C.4,48
D.6,16
Cu 24 : Cho 16,5gam cht A c CTPT l C2H10O3N2 vo 200 gam dung dch NaOH 8%.Sau khi cc
phn ng xy ra hon ton thu c dung dch B v kh C.Tng nng % cc cht tan c trong B
gn nht vi:
A.8%
B.9%
C.10%
D.11%
Cu 25: T hn hp cha 13,5 gam axit aminoaxetic, 13,35 gam axit 2-aminopropanoic ,20,6 gam
axit 3aminobutanoic v 25,74 gam axit 2 amino 3 metylbutanoic ngi ta c th tng hp c
ti a m gam tetrapeptit. Gi tr m l:
A. 65,350
B. 63,065
C. 45,165
D. 54,561
Cu 26: Cho 9,3 gam cht X c CTPT l C2 H 7 O 3 N tc dng vi dung dch cha 8,4 gam KOH.Sau
phn ng c cn dung dch thu c m gam cht rn.Gi tr ca m l :
A.9,7 gam
B.7,3 gam
C.12,4 gam
D.10,24gam
Cu 27: Cho mt l st nh tc dng vi dung dch H2SO4 , thy c kh H2 thot ra. Th tch kh H2
thu c tng ng vi thi gian o c nh sau:

Ra : Ch nhim CLB Nguyn Anh Phong 0975 509 422

 th biu din s ph thuc th tch H2 vo thi

gian

th tch H2 (ml)

100
80

90

89

85

78

90

60
50
40
20
10

0
0

10

thi gian(pht)

Trong thi gian 1 pht lng H thot ra ln nht l bao nhiu ml:

Trong thi gian 1 pht lng H2 2thot ra ln nht l bao nhiu ml:
A.40
B.68
C.47
A.40
B.68
C.47
Cu 28: Cho hnh v sau:
dd H2SO4 c
Hin tng xy ra trong bnh eclen cha Br2:
A.C kt ta xut hin
B.Dung dch Br2 b mt mu
C.Va c kt ta va mt mu dung dch Br2
D.Khng c phn ng xy ra
Na2SO3

D.42
D.42

dd Br2

tt

Cu 29: Thy phn hon ton m gam hn hp hai este n chc mch h A,B (MA < MB) trong 700
ml dung dch KOH 2M thu c dung dch X v hn hp Y gm 2 ancol l ng ng lin tip.Thc
hin tch nc Y trong H2SO4 c 1400 C thu c hn hp Z.Trong Z tng khi lng ca cc ete l
8,04 gam (Hiu sut ete ha ca cc ancol u l 60%).C cn dung dch X c 54,48 gam cht
rn. Nung cht rn ny vi CaO cho n khi phn ng xy ra hon ton, thu c 6,72 lt hn hp kh
T (ktc). Phn trm khi lng ca A trong hn hp ban u l:
A.66,89%
B.48,96
C.49,68
D.68,94
Cu 30 :Cho 22,56 gam hn hp A gm kim loi M v MO (c ha tr khng i) tan hon ton
trong dung dch HNO3 thu c 2,24(lt) hn hp kh B gm hai kh c t khi vi H2 l 7 v dung
dch C.C cn cn thn dung dch C thu c 69,4 gam cht rn . Bit rng qu trnh kh HNO3 ch
to ra 1 sn phm kh duy nht.% s mol ca cht tan c s mol t nht trong C l:
A.28%
B.24%
C.32%
C.30%
Cu 31: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc
th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l :
A. C3H7N.
B. C2H7N.
C. C3H9N.
D. C4H9N.
Cu 32: X phng ha 7,4 gam metyl axetat bng 200 ml dung dch KOH 0,8M. Sau khi phn ng
xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l :
A.9,8 gam.
B. 13,28 gam.
C. 10,4 gam.
D. 13,16 gam.
Cu 33: Hn hp X gm axit C2H5COOH v axit CH3COOH (t l mol 1:1). Ly 26,8 gam hn hp
X tc dng vi 27,6 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut
ca cc phn ng este ho u bng 75%). Gi tr ca m l :
A. 28,5.
B. 38,0.
C. 25,8.
D. 26,20.

Ra : Ch nhim CLB Nguyn Anh Phong 0975 509 422

Cu 34: Trung ho 93,6 gam hn hp gm axit fomic, axit axetic, phenol v axit benzoic, cn dng
1000 ml dung dch KOH 1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c
khi lng l:
A. 88,64 gam.
B. 116,84 gam.
C. 131,6 gam.
D. 96,80 gam.
Cu 35 : Dng 19,04 lt khng kh ktc (O2 chim 20% v N2 chim 80% th tch) t chy
hon ton 3,21 gam hn hp A gm hai amoniaxit no,n chc k tip nhau trong dy ng ng .
Hn hp thu c sau phn ng em lm kh (hn hp B) ri dn qua dung dch nc vi trong d
thu 9,50 gam kt ta. Nu cho B vo bnh dung tch 2 lt, nhit 1270C th p sut trong bnh lc
ny l P(atm). Bit amoni axit khi chy sinh kh N2. Gi tr ca P gn nht vi :
A.13
B.14
C.15
D.16
Cu 36: Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3, Cr2O3, (NH4)2CO3,
K2HPO4. S cht trong dy c tnh cht lng tnh l
A. 4.
B. 5.
C. 6.
D. 7.
Cu 37: Tin hnh cc th nghim sau:
(1) Cho dung dch NaOH vo dung dch Ca(HCO3)2.
(2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(3) Sc kh H2S vo dung dch FeCl2.
(4) Sc kh NH3 ti d vo dung dch AlCl3.
(5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]).
(6) Sc kh etilen vo dung dch KMnO4.
(7) Cho Ba(OH)2 d vo ZnSO4.
(8) Sc kh H2S vo dung dch FeCl3.
Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta?
A. 4.
B. 6.
C. 7.
D. 5.
Cu 38: S ng phn cu to (mch h) ca C5H10 phn ng c vi dung dch brom l:
A. 5
B. 4
C. 3
D. 6
Cu 39 : un si hn hp dung dch gm etylclorua ,KOH ta c th thu c.
A.Etan
B.Etin
C.Etilen
D.Metan
Cu 40 : Cho 82,05 gam hn hp A gm Al v Al2O3 (c t l mol l 2,3:1) tan hon ton trong
dung dch B cha H2SO4 v NaNO3 thu c dung dch C ch cha 3 mui v m gam hn hp kh D
(trong D c 0,2 mol kh H2).Cho BaCl2 d vo C thy c 838,8 gam kt ta xut hin.Mt khc cho
23 gam Na vo dung dch C sau khi cc phn ng xy ra th thy khi lng dung dch gim 5,7
gam.Gi tr ca m gn nht vi :
A.16
B.13
C.12
D.15
Cu 41: Nguyn tc sp xp cc nguyn t trong bng tun hon no sau y l sai:
A. Cc nguyn t c cng s lp electron trong nguyn t c sp thnh mt hng.
B. Cc nguyn t c sp xp theo chiu tng dn ca in tch ht nhn.
C. Cc nguyn t c sp xp theo chiu tng dn s khi.
D. Cc nguyn t c s electron ha tr nh nhau c xp thnh mt ct.
Cu 42 : Nung m gam Fe trong khng kh thu c (m + 3,2) gam cc oxit st.Cho ton b lng
oxit ny tc dng va vi 500ml dung dch HCl aM.Gi tr ca a l :
A.1
B.1,2
C.0,8
D.0,75
Cu 43 : Thuc th no di y phn bit c kh O2 vi kh O3 bng phng php ha hc ?
A.Dung dch NaOH
B. Dung dch Kl + h tinh bt
C.Dung dch CuSO4
D. Dung dch H 2SO 4
Ra : Ch nhim CLB Nguyn Anh Phong 0975 509 422

Cu 44 : Cho phng trnh phn ng : N 2 3H 2

2NH3

( H

0)

Trong cc pht biu sau,pht biu no sai:

A.Tng nhit cn bng phn ng dch sang tri.
B.Tng p sut ca h phn ng th cn bng dch phi.
C.Cht xc tc khng nh hng ti cn bng phn ng.
D.Gim th tch ca h th tc phn ng thun tng v tc phn ng nghch gim.
Cu 45 : Cho dd FeSO4 nng 15% phn ng va vi dd KOH nng 20% un nng trong
kk p sy ra hon ton Tnh nng % ca mui trong dd sau p (coi nc bay hi ko ng k).
A.14,16%
B.14,82%
C.16,14%
D.16,28%
Cu 46: Khi nh t t n d dung dch NaOH vo dung dch hn hp gm a mol HCl v b mol
ZnCl2, kt qu th nghim c biu din trn th sau (s liu tnh theo n v mol) :

0,4

0,6

1,4

2,2

Tng gi tr ca a + b l
A. 1,4
B. 1,6
C. 1,2
Cu 47: Cho cc hnh v sau l 1 trong cc nguyn t Na, Mg, Al, K.

n OH
D. 1,3

a
b
c
d
a, b, c, d tng ng theo th t s l:
A. Na, Mg, Al, K
B. K, Na, Mg, Al
C. Al, Mg, Na, K
D. K, Al, Mg, Na
Cu 48 : Dy gm cc ion cng tn ti trong mt dung dch l
A. Cl ; Na ; NO3 v Ag

B. Fe2 ; Mg 2 ; H v NO3

C. K ; Mg 2 ; OH v NO3

D. K ; Ba2 ; Cl v NO3

Cu 49 :Cho 68,2 gam canxi photphat tc dng vi 39,2 gam dung dch H2SO4 80%.Sau khi cc
phn ng xy ra hon ton c cn dung dch sau phn ng thu c hn hp cht rn B.Trong B cht
c s mol t nht l :
A.0,1 mol
B.0,12 mol
C.0,14 mol
D.0,08 mol
Cu 50: t chy hon ton 1 mol mt hidrocacbon X th thu c 7 mol kh CO2.Mt khc cho 0,2
mol hidrocacbon ny phn ng hon ton vi AgNO3/NH3 d thy c m gam kt ta xut hin.Gi tr
ln nht ca m l :
A.88,8
B.81,8
C.72,2
D.78,4
thi th ln 4 s din ra vo th 7 ngy 6.12.2014
Thng tin chi tit v cu trc thi gian post cc em thoi di trn Group nh !
Nguyn Anh Phong
Ra : Ch nhim CLB Nguyn Anh Phong 0975 509 422