Su tm v bin son : Thy Nguyn Minh Tun - Trng THPT chuyn Hng Vng - Ph Th - T : 01223 367 990

THI TH THPT QUC GIA LN 1, NM 2015

MN : HA HC
Thi gian lm bi:90 pht;
(50 cu trc nghim)
M thi 132
H, tn th sinh : .....................................................................
S bo danh : ..........................................................................
Cho bit nguyn t khi ca cc nguyn t : H = 1; O = 16; C = 12; N =14; Cl = 35,5; S = 32; Na = 23; K = 39;
Fe = 56; Al = 27; Ag = 108; Cu = 64
Cu 1: Nhn xt no sau y khng ng?
A. Nhm v crom u b th ng ha bi HNO3 c, ngui.
B. Vt dng lm bng nhm v crom u bn trong khng kh v nc v c mng oxit bo v.
C. Crom l kim loi cng nht trong tt c cc kim loi.
D. Nhm v crom u phn ng vi HCl theo cng t l s mol.
Cu 2: Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2;
CH3CH=CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l :
A. 3.
B. 2.
C. 4.
D. 1.
Cu 3: Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng
c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km
nhau l 2. Nguyn t X, Y ln lt l :
A. kim loi v kim loi. B. phi kim v kim loi.
C. kh him v kim loi. D. kim loi v kh him.
Cu 4: Cho 13,8 gam hn hp gm axit fomic v etanol phn ng ht vi Na d, thu c V lt kh H2 (ktc). Gi
tr ca V l
A. 6,72
B. 4,48
C. 3,36
D. 7,84.
Cu 5: Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l :
A. HCl, O3, H2S.
B. H2O, HF, H2S.
C. O2, H2O, NH3.
D. HF, Cl2, H2O.
Cu 6: Cho 7,8 gam kali tc dng vi 1 lt dung dch HCl 0,1M, sau phn ng thu c dung dch X v V lt H2
(ktc). C cn dung dch X thu c m gam cht rn khan. Gi tr ca V v m ln lt l
A. 2,24 v 7,45.
B. 1,12 v 3,725.
C. 1,12 v 11,35.
D. 2,24 v 13,05.
Cu 7: Poli(etylen terephtalat) c iu ch bng phn ng vi axit teraphtalic vi cht no sau y?
A. Etilen.
B. Etylen glicol.
C. Glixerol.
D. Ancol etylic.
Cu 8: Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este
X tha mn tnh cht trn l
A. 5.
B. 6.
C. 4.
D. 3.
Cu 9: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l :
A. Na, K, Ba.
B. Mg, Ca, Ba.
C. Na, K , Ca.
D. Li , Na, Mg.
Cu 10: un nng 24 gam axit axetic vi lng d ancol etylic (xc tc H2SO4 c), thu c 26,4 gam este.
Hiu sut ca phn ng este ha l
A. 44%.
B. 75%.
C. 60%.
D. 55%.
Cu 11: Thy phn hon ton triglixerit X trong NaOH, thu c 46 gam glixerol v hn hp gm hai mui ca
hai axit bo l stearic v oleic c t l mol 1 : 2. Khi lng mui thu c l :
A. 459 gam.
B. 457 gam.
C. 458 gam.
D. 456 gam.
Cu 12: C cc dung dch ring bit sau b mt nhn : NH4Cl, AlCl3, MgCl2, FeCl3, Na2SO4. Ho cht cn thit
dng nhn bit tt c cc dung dch trn l dung dch :
A. BaCl2.
B. Na2SO4.
C. NaOH.
D. AgNO3.
Cu 13: Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l :
A. CH3CHO, C2H5OH, C2H6, CH3COOH.
B. CH3COOH, C2H6, CH3CHO, C2H5OH.
C. C2H6, C2H5OH, CH3CHO, CH3COOH.
D. C2H6, CH3CHO, C2H5OH, CH3COOH.
Cu 14: Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2
(ktc) v dung dch X. Nh t t dung dch NH3 n d vo dung dch X, thu c kt ta, lc ht lng kt ta,
nung n khi lng khng i thu c 2,04 gam cht rn. Gi tr ca V l :
A. 0,672.
B. 0,224.
C. 0,448.
D. 1,344.
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Cu 15: Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t C3H9O2N (sn phm
duy nht). S cp cht X v Y tha mn iu kin trn l
A. 2.
B. 3.
C. 4.
D. 1.
Cu 16: Cho ba mu v (100% CaCO3) c cng khi lng: mu 1 dng khi, mu 2 dng vin nh, mu 3
dng bt mn vo ba cc ng cng th tch dung dch HCl (d, cng nng , iu kin thng). Thi gian
vi tan ht trong ba cc tng ng l t1, t2, t3 giy. So snh no sau y ng?
A. t 3 < t 2 < t1
B. t 2 < t1 < t 3
C. t1 < t 2 < t 3
D. t1 = t 2 = t 3
Cu 17: in phn mt dung dch gm a mol CuSO4 v b mol NaCl. Nu b > 2a m catot cha c kh thot ra th
dung dch sau in phn cha
A. Na+, SO 4 2 , Cu2+.
B. Na+, SO 4 2 , Cu2+, Cl .
C. Na+, SO 4 2 , Cl .

D. Na+, Cl .

Cu 18: Cho cc phng trnh phn ng sau :

(a) Fe + 2HCl FeCl2 + H2
(b) Fe3O4 + 4H2 SO4 Fe2 (SO4 )3 + FeSO4 + 4H 2 O
(c) 2KMnO4 + 16HCl 2KCl + 2MnCl2 + 5Cl2 + 8H2 O
(d) FeS + H 2 SO 4 FeSO4 + H 2 S
(e ) 2Al + 3H2 SO4 Al 2 (SO4 )3 + 3H2
Trong cc phn ng trn, s phn ng m ion H + ng vai tr cht oxi ha l
A. 1.
B. 2.
C. 4.
D. 3.
Cu 19: Este no sau y khi phn ng vi dung dch NaOH d, un nng khng to ra hai mui?
B. CH3COO[CH2]2OOCCH2CH3.
A. C6H5COOC6H5 (phenyl benzoat).
C. CH3OOCCOOCH3.
D. CH3COOC6H5 (phenyl axetat).
Cu 20: Cho mt lng st tan trong dung dch HNO3 long n khi phn ng xy ra hon ton, thu c dung
dch X c mu nu nht v c kh nng lm mt mu dung dch KMnO4/H2SO4. Cht tan trong dung dch l
B. Fe(NO3)2.
C. Fe(NO3)2, HNO3.
D. Fe(NO3)2, Fe(NO3)3.
A. Fe(NO3)3, HNO3.
Cu 21: t chy hon ton 0,1 mol hn hp X gm cc cht : metan, metanol, anehit axetic v metyl fomat.
Hp th sn phm chy vo bnh cha 200 ml dung dch NaOH 1M, thu c dung dch c cha 8,48 gam
Na2CO3 v b gam NaHCO3. Khi lng bnh tng ln l :
A. 8,24 gam.
B. 8,88 gam.
C. 8,46 gam.
D. 7,89 gam.
Cu 22: Trong c th nghim sau :
(1) Cho SiO2 tc dng vi axit HF.
(2) Cho kh SO2 tc dng vi kh H2S.
(3) Cho kh NH3 tc dng vi CuO un nng.
(4) Cho CaOCl2 tc dng vi dung dch HCl c.
(5) Cho Si n cht tc dng vi dung dch NaOH.
(6) Cho kh O3 tc dng vi Ag.
S th nghim to ra n cht l :
A. 6.
B. 7.
C. 4.
D. 5.
Cu 23: Tripeptit X c cng thc sau C8H15O4N3. Thy phn hon ton 0,1 mol X trong 400 ml dung dch NaOH
1M. Khi lng cht rn thu c khi c cn dung dch sau phn ng l
A. 28,6 gam
B. 35,9 gam.
C. 22,2 gam.
D. 31,9 gam.
Cu 24: Dung dch phenol ( C6 H 5 OH ) khng phn ng c vi cht no sau y?
A. NaCl.

B. NaOH.

C. Na.

D. Br2 .

Cu 25: Cho hnh v m t qu trnh iu ch dung dch X trong phng th nghim

Cho hnh v m t qu trnh iu ch dung dch X trong phng th nghim

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Su tm v bin son : Thy Nguyn Minh Tun - Trng THPT chuyn Hng Vng - Ph Th - T : 01223 367 990

kh X
HCl
(1)

Bong

H2SO4 ac

(2)
NaCl
H2O

Trong iu kin thch hp, dung dch X c th phn ng c vi my cht trong s cc cht sau : KMnO4,
Na2CO3, Fe3O4, NaHCO3, Ag2O, Cu, Al, Al(OH)3, dung dch AgNO3, dung dch Ba(NO3)2 ?
A. 10.
B. 7.
C. 9.
D. 8.
Cu 26: Trong cc dung dch CH3-CH2-NH2, H2N-CH2-COOH, H2N-CH2-CH(NH2)-COOH, HOOC-CH2-CH2CH(NH2)-COOH, s dung dch lm xanh qu tm l
A. 2.
B. 4.
C. 1.
D. 3.
Cu 27: Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4,
Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp to ra kt ta l
A. 5.
B. 6.
C. 4.
D. 7.
Cu 28: Dn V lt (ktc) hn hp X gm axetilen v hiro c khi lng l m gam i qua ng s ng bt niken
nung nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dung dch NH3, thu c 12 gam kt ta. Kh i ra
khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z, thu c 2,24 lt
kh CO2 (ktc) v 4,5 gam H2O. Gi tr ca V l:
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
Cu 29: Cho s cc phn ng :
o

t
Y + Z
X + NaOH (dung dch)
o

CaO, t
Y + NaOH (rn)
T + P
o

1500 C
T
Q + H2

(1)
(2)
(3)

t , xt
Q + H2O
Z
(4)
Trong s trn, X v Z ln lt l
A. HCOOCH=CH2 v HCHO.
B. CH3COOCH=CH2 v HCHO.
C. CH3COOC2H5 v CH3CHO.
D. CH3COOCH=CH2 v CH3CHO.
Cu 30: t chy hon ton m gam mt ancol no X, thu c m gam H2O. Bit khi lng phn t ca X nh hn
100 (vC). S ng phn cu to ca X l
A. 6.
B. 3.
C. 5.
D. 4.
Cu 31: un nng a gam mt hp cht hu c X (cha C, H, O), mch khng phn nhnh vi dung dch cha
11,2 gam KOH n khi phn ng xy ra hon ton, thu c dung dch A, trung ho KOH d trong A cn
dng 80 ml dung dch HCl 0,5M. Lm bay hi hn hp sau khi trung ho mt cch cn thn, ngi ta thu c
7,36 gam hn hp hai ancol n chc Y v 18,34 gam hn hp hai mui Z. Gi tr ca a l :
A. 14,86 gam.
B. 16,64 gam.
C. 13,04 gam.
D. 13,76 gam.
Cu 32: Cho cc phn ng sau :
o

t
H2S + O2 (d)
Kh X + H2O
o

850 C, Pt
NH3 + O2

Kh Y + H2O
o

t
NH4HCO3 + HCl long
Kh Z + NH4Cl + H2O
Cc kh X, Y, Z thu c ln lt l :
A. SO2, N2, NH3.
B. SO2, NO, CO2.
C. SO3, NO, NH3.

D. SO3, N2, CO2.

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Cu 33: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch
NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to
thu gn ca X l :
C. CH2=CHCOONH4.
D. H2NCH2COOCH3.
A. HCOOH3NCH=CH2. B. H2NCH2CH2COOH.
Cu 34: trung ha 20 ml dung dch HCl 0,1M cn 10 ml dung dch NaOH nng x mol/l. Gi tr ca x l
A. 0,3.
B. 0,1.
C. 0,2.
D. 0,4.
Cu 35: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong
phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit
A. khng no c mt ni i, n chc.
B. khng no c hai ni i, n chc.
C. no, hai chc.
D. no, n chc.
Cu 36: Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3, thu
c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht
khng tan. Gi tr ca m l :
A. 21,6.
B. 55,2.
C. 61,78.
D. 41,69.
Cu 37: Cho m gam Fe vo 1 lt dung dch X gm H2SO4 0,1M, Cu(NO3)2 0,1M, Fe(NO3)3 0,1M. Sau khi phn
ng xy ra hon ton thu c 0,69m gam hn hp kim loi, dung dch Y v kh NO (sn phm kh duy nht). Gi
tr m v khi lng cht rn khan thu c khi c cn dung dch Y l:
A. 25,8 v 78,5.
B. 25,8 v 55,7.
C. 20 v 78,5.
D. 20 v 55,7.
Cu 38: Hn hp A gm 2 este n chc X, Y. Cho 0,05 mol A tc dng va vi dung dch NaOH thu c
hn hp sn phm hu c B. t chy ht ton b B thu c 2,688 lt CO2; 3,18 gam Na2CO3. Khi lm bay hi B
thu c m gam cht rn. Gi tr ca m l
A. 4,56 gam.
B. 3,4 gam.
C. 5,84 gam.
D. 5,62 gam.
Cu 39: in phn 2 lt dung dch hn hp gm NaCl v CuSO4 n khi H2O b in phn hai cc th dng li,
ti catot thu 1,28 gam kim loi v anot thu 0,336 lt kh (ktc). Coi th tch dung dch khng i th pH ca dung
dch thu c l :
A. 13.
B. 3.
C. 12.
D. 2.
Cu 40: Cho V lt Cl2 tc dng vi dung dch NaOH va iu kin thng, c cn dung dch thu c m1 gam
mui khan. Cng ly V lt Cl2 cho tc dng vi dung dch NaOH va , un nng 80oC, c cn dung dch thu
c m2 gam mui. Th tch kh Cl2 o cng iu kin. T l m1 : m2 l
A. 1 : 2.
B. 1 : 1,5.
C. 1 : 1.
D. 2 : 1.
Cu 41: Pht biu no sau y l ng ?
A. Glucoz b kh bi dung dch AgNO3 trong NH3. B. Saccaroz c phn ng trng gng.
C. Amilopectin c cu trc mch phn nhnh.
D. Xenluloz c cu trc mch phn nhnh.
Cu 42: Hp th hon ton 13,44 lt CO2 (ktc) bng 500 ml dung dch NaOH aM, thu c dung dch X. Cho t
t 200 ml dung dch HCl 1M vo X, thu c 1,12 lt kh (ktc) v dung dch Y. Gi tr ca a l :
A. 1,5M.
B. 1,2M.
C. 2,0M.
D. 1,0M.
Cu 43: Trong gi thc hnh ho hc, mt nhm hc sinh thc hin phn ng ca kim loi Cu tc dng vi HNO3
c v HNO3 long. Hy chn bin php x l tt nht trong cc bin php sau y chng nhim khng kh
trong phng th nghim
A. Sau th nghim nt ng nghim bng bng c tm nc.
B. Sau th nghim nt ng nghim bng bng c tm gim n.
C. Sau th nghim nt ng nghim bng bng c tm nc vi.
D. Sau th nghim nt ng nghim bng bng c tm cn.
Cu 44: Dung dch X cha a mol Ba(OH)2. Cho
n
m gam NaOH vo X sau sc CO2 (d) vo ta
thy lng kt ta bin i theo th (Hnh
bn). Gi tr ca m v a ln lt l :
a

a + 0,5

1,3

nCO2

A. 40 v 0,8
B. 40 v 0,4
C. 20 v 0,4
D. 20 v 0,8
Cu 45: Cho 45 gam hn hp bt Fe v Fe3O4 vo V lt dung dch HCl 1M, khuy u cc phn ng xy ra
hon ton, thy thot ra 4,48 lt kh (ktc) v 5 gam kim loi khng tan. Gi tr ca V l
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A. 1,4 lt
B. 0,4 lt
C. 1,2 lt
D. 0,6 lt
Cu 46: Nung hn hp gm 0,12 mol Al v 0,04 mol Fe3O4 mt thi gian, thu c hn hp rn X. Ha tan hon
ton X trong dung dch HCl d, thu c 0,15 mol kh H2 v m gam mui. Gi tr ca m l
A. 34,10.
B. 32,58.
C. 31,97.
D. 33,39.
Cu 47: Ho tan hon ton mt lng hn hp X gm Fe3O4 v FeS2 trong 63 gam HNO3, thu c 1,568 lt NO2
(ktc). Dung dch thu c cho tc dng va vi 200 ml dung dch NaOH 2M, lc kt ta em nung n khi
lng khng i thu c 9,76 gam cht rn. Nng phn trm ca dung dch HNO3 c gi tr l :
A. 47,2%.
B. 46,2%.
C. 46,6%.
D. 44,2%.
2+
+
2+
Cu 48: Cho cc ion : Fe (1), Ag (2), Cu (3). Th t sp xp theo chiu tng dn tnh oxi ho ca cc ion l:
A. (2), (1), (3).
B. (2), (3), (1)
C. (1), (2), (3).
D. (1), (3), (2).
Cu 49: Tin hnh cc th nghim sau
(a) Sc kh etilen vo dung dch KMnO4 long.
(b) Cho hi ancol etylic i qua bt CuO nung nng.
(c) Sc kh etilen vo dung dch Br2 trong CCl4.
(d) Cho dung dch glucoz vo dung dch AgNO3, trong NH3 d, un nng.
(e) Cho Fe2O3 vo dung dch H2SO4 c, nng.
Trong cc th nghim trn, s th nghim c xy ra phn ng oxi ha - kh l :
A. 3.
B. 5.
C. 4.
D. 2.
Cu 50: Trung ha 10,4 gam axit cacboxylic X bng dung dch NaOH, thu c 14,8 gam mui. Cng thc ca
X l
A. C2 H5COOH.
B. HOOC CH2 COOH.
C. HOOC COOH.

D. C3 H 7 COOH.

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mn Ha hc "
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