Cng ng ha hc v ng dng

DIN N BOOKGOL

thi th s 2
( thi gm c 7 trang)

bring about change

THI THPT QUC GIA CHUNG

LN 2 NM 2015
Mn: HA HC
Thi gian lm bi: 90 pht
(Khng k thi gian pht )
Ngy thi: 15/03/2015
M thi BK02

H v tn th sinh:. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
S bo danh: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t :
H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K =39; Ca =
40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137; Pb = 207.
Cu 1. Khi ni v nguyn t 14
7 X, iu no sau y l khng ng ?
A. X thuc chu k 2, nhm VA trong bng h thng tun hon.
B. Nguyn t nguyn t X c tng cng 21 ht trng thi c bn.
C. Oxit cao nht ca X l X2 O5 .
D. Nguyn t X trong XH3 v trong XH4+ c ha tr l 3.
Cu 2. Mt dung dch X gm 0,10 mol M n+ ; 0,30 mol K + ; 0,35 mol N O3 v 0,25 mol Cl . C cn dung
dch X thu c 47,875 gam cht rn khan. S electron c trong ion M n+ l:
A. 22.
B. 54.
C. 23.
D. 24.
Cu 3. Dung dch glixerin trong nc khng dn in, dung dch kali hiroxit dn in tt. iu ny c
gii thch l:
A. Phn t glixerin cha lin kt cng ho tr cn lin kt trong KOH l lin kt ion.
B. Glixerin l cht hu c cn KOH l cht v c.
C. Trong dung dch, kali hiroxit phn li thnh cc ion, cn glixerin khng b phn li.
D. Glixerin l cht lng cn KOH l cht rn.
Cu 4. Dung dch X cha ng thi cc ion: N a+ ; Ca2+ ; M g 2+ ; Cl ; HCO3 v SO42 . un nng dung
dch X ti khi phn ng xy ra hon ton thu c 3, 68(g) kt ta, dung dch Y v 2, 24 lt kh thot ra
(dktc).em c cn dung dch Y th thu c 13, 88 (g) rn khan. Tng khi lng mui c trong dung dch
X ban u l:
A. 23,76(g).
B. 22,84(g).
C. 17,76 (g).
D. 35,76(g).
Cu 5. Cho s iu ch v thu kh nh hnh v:

Pht biu no sai trong cc pht biu di y:

A. Ming ng nghim phi c b tr li sao cho hi nghing xung phng ha cht b m.
B. Khi ngng thu kh ta phi tt n cn trc khi tho ng nghim.
C. Ngoi KM nO4 ta c th dng KClO3 ; H2 O2 iu ch O2 .
D. Phng php thu kh trn cng c th p dng cho cc cht kh nh : CO2 ; N2 ; CH4 .
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Cu 6. Cho 4, 8(g) hn hp M g; Al phn ng vi 0, 1(l) hn hp dung dch 2 axit H2 SO4 v HCl c cng
nng mol l 1M. Sau phn ng dn ton b lng kh sinh ra cho i qua ng s ng 14,4 g hn hp hai
oxit CuO; F eO nung nng, kt thc qu trnh trong ng cn li m(g) rn. Bit cc phn ng xy ra hon
ton. Gi tr ca m l :
A. 26,08.
B. 12,00.
C. 14,02.
D. 22,05.
Cu 7. Cho dung dch F e(N O3 )2 ln lt tc dng vi cc dung dch: N a2 S; H2 S; CH3 N H2 ; AlCl3 ;
AgN O3 ; N a2 CO3 ; H2 SO4 long; H2 SO4 c; nc Br2 . S trng hp xy ra phn ng ha hc l:
A. 6.
B. 7.
C. 8.
D. 9.
Cu 8. Hai cc ng dung dch HCl t trn hai a cn A v B. Cn trng thi cn bng. Cho 10(g)
CaCO3 vo cc A v 8, 221(g) M2 CO3 vo cc B. Sau khi mui tan ht, cn tr li v tr cn bng. Kim
loi M l :
A. Na.
B. Li.
C. Rb.
D. K.
Cu 9. phn bit cc kh sau (ng trong cc l ring bit): CO2 ; HCl; H2 S; HI c th dng:
A. Dung dch KOH.
B. Dung dch BaCl2 .
C. Dung dch N aBr.
D. Dung dch AgN O3 .
Cu 10. Ha tan hon ton 14(g) hn hp X gm F eS2 ; Cu2 S trong V (lt) dung dch HN O3 2M, thu
c kh N O2 (sn phm kh duy nht ca N +5 ) v dung dch Y. Tc dng ht vi cc cht trong Y cn
175ml dung dch Ba(OH)2 1 M , kt ta to thnh em nung trong khng kh n khi lng khng i
c 46,95 (g) rn Z Gi tr ca V l :
A. 1,30.
B. 2,40.
C. 0,65.
D. 4,80.
Cu 11. Trong thnh phn ca thuc chut c hp cht ca photpho l Zn3 P2 . Khi b chut bng loi
thuc ny th chut thng cht gn ngun nc bi v khi Zn3 P2 vo d dy chut th s hp thu mt lng
nc ln v sinh ra ng thi lng ln kh X v kt ta Y khin cho d dy chut v ra. Pht biu no sau
y khng ng?
A. Kt ta Y c th tan trong dung dch N H3 .
B. Kh X c th c iu ch trc tip t cc n cht nhit thng.
C. Kt ta Y c th tan c trong dung dch NaOH c.
D. Kh X thng xut hin cc ngha trang, d bc chy to thnh ngn la lp le.
Cu 12. Chia 43,15 (g) hn hp gm Al, F e2 O3 , Cr2 O3 thnh 2 phn.
- Cho 1, 344(l) kh CO (ktc) i qua phn 1 nung nng, sau mt thi gian thu c 25,41 (g) rn v hn hp
kh A c t khi so vi H2 bng 18.
- Thc hin phn ng nhit nhm phn 2 trong kh tr, thu c hn hp rn X. Bit X tc dng ti a
vi 180ml dung dch N aOH 1M v kt thc qu trnh ny thu c V (l) kh H2 (ktc), dung dch Y, cht
khng tan Z. Cho Z tc dng vi dung dch HCl long ngui th thy thot ra 1, 344(l) kh H2 (ktc). Bit
cc phn ng xy ra hon ton. Gi tr ca V l :
A. 0,672.
B. 0,448.
C. 0,896.
D. 1,120.
Cu 13. Cho cc pht biu sau:
(1) CuSO4 khan c th c dng nhn bit C2 H5 OH vi ru 960
(2) Khi pin in ha Zn-Cu phng in th tng v gim khi lng ca hai in cc khng bng nhau
(3) Amophot l hn hp gm (N H4 )2 HP O4 v N H4 H2 P O4 thu c khi cho N H3 tc dng vi H3 P O4
(4) N a2 CO3 dng ty sch vt du m bm trn chi tit my trc khi sn.
(5) Tt c cc mui trong dy: KCl; CH3 COOK; N a2 HP O3 ; N aHSO3 ; BaCO3 u l mui trung ha.
(6) Zn(OH)2 tan trong dung dch N H3 long l do Zn(OH)2 c tnh lng tnh.
(7) Trong mi trng axit H2 SO4 long, ion Cr2 O72 oxi ha c I thnh I2
S pht biu ng l:
A. 2.
B. 5.
C. 4.
D. 3.
Cu 14. Cho 4, 58(g) hn hp A cha cc kim loi Zn ,Cu,Fe tc dng vi 0, 085 lt dung dch CuSO4 1M.
Sau khi cc phn ng xy ra hon ton thu c dung dch B v cht rn C. Cho B tc dung vi dung dch
NaOH d, lc ly kt ta em nung trong khng kh n khi lng khng i thu c 5,2 (g) rn E. Ha
tan hon ton C trong dung dch H2 SO4 c nng thu c 1, 68(l) kh SO2 (ktc). Phn trm khi lng
ca Cu trong hn hp ban u gn vi gi tr no nht trong cc gi tr sau :
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A. 41,92.
B. 27,95.
C. 28,59.
D. 34,93.
Cu 15. t chy hon ton hn hp X gm F eS2 ; Cu2 S; F e(N O3 )2 bng 1,792 lt O2 (ktc) thu c
hn hp rn gm F e2 O3 ; Cu2 O v hn hp T ch cha hai kh c s mol bng nhau. Hp th hon ton
T bng 160 ml dung dch NaOH 1M sau phn ng thu c dung dch A. Cho A tc dng va vi 40
ml dung dch BaCl2 1M, lc b kt ta , c cn dung dch thu c ri nung trong kh tr n khi lng
khng i c rn B v hn hp kh. Mt khc, cho ton b Y vo bnh ng 240 ml dung dch H2 SO4
1M, sau khi cc phn ng xy ra hon ton th khi lng rn cn li l m(g). Bit rng khi cho Cu2 O tc
dng vi H2 SO4 long to Cu2+ v Cu. Gi tr m l:
A. 1,28.
B. 2,56.
C. 4,02.
D. 5,01.
Cu 16. Cho cc qung sau : xinvinit,criolit,cao lanh ,apatit . Cng thc cc qung ln lt l :
A. N aCl.KCl, N a3 AlF6 , Al2 O3 .2SiO2 .2H2 O, 3.Ca3 (P O4 )2 .CaF2 .
B. N aCl.KCl, N a3 AlF6 , N a2 O.Al2 O3 .6SiO2 , 3.Ca3 (P O4 )2 .CaF2 .
C. KCl.M gCl2 , N a3 AlF6 , Al2 O3 .2SiO2 .2H2 O, Ca3 (P O4 )2 .
D. KCl.M gCl2 , N a3 AlF6 , N a2 O.Al2 O3 .6SiO2 , Ca3 (P O4 )2 .
Cu 17. Khi ni v nhm Nito pht biu no sau y khng ng :
A. Lp electron ngoi cng ca nguyn t l ns2 np3 .
B. T nito n bitmut , tnh phi kim ca nguyn t gm dn.
C. Cc nguyn t ca nguyn t ch th hin tnh kh.
D. T nito n bitmut , tnh axit ca cc oxit tng ng gim dn.
Cu 18. Khi ni v qu trnh mm in ha hp kim ca st (Gang , thp) trong khng kh m .Qu trnh
no sau y c xy ra cc dng :
A. F e2+ F e + 2e.
B. H2 O 4H + + 4e + O2 .
C. F e F e2+ + 2e.
D. O2 + 2H2 O + 4e 4OH .
Cu 19. Cho cc cht : etilen , axetilen ,propanal,axit oxalic , axit fomic,andhit axetic .S cht tham gia
phn ng trng bc l :
A. 2.
B. 3.
C. 1.
D. 4.
Cu 20. Cho cc pht biu sau y :
1. Fomanehit l cht kh khng mu , tan rt tt trong nc .
2. Nhit si ca axetanehit ln hn fomanhit.
3. Axit cacboxylic l nhng hp cht hu c m phn t c nhm cacbonyl lin kt trc tip vi nguyn t
cacbon hoc nguyn t hidro.
4. iu kin thng , tt c cc axit cacboxylic u l nhng chat lng hoc rn.
5. i vi cc axit cacboxylic khi s nguyn t C tng ln th tan trong nc cng tng.
S pht biu ng l :
A. 1.
B. 2.
C. 4.
D. 3.
Cu 21. Hn hp X gm andehit oxalic, axit oxalic, OHC-COOH . t chy m gam X thu c a(gam)
CO2 . Mt khc nu cng lng X trn tac dng vi N aHCO3 thu c 2,24 lt (ktc) kh CO2 .Nu cng
m(g) X tc dng viAgN O3 /N H3 th thu c 43,2 gam ta. Gi tr ca a l :
A. 13,2.
B. 26,4.
C. 10,00.
D. 39,6.
Cu 22. X l este no, n chc, Y l axit cacboxylic n chc , khng no cha mt lin kt i C=C; Z l
este 2 chc to bi etylen glicol v axit Y (X, Y, Z, u mch h,s mol Y bng s mol Z). t chy a(gam)
hn hp E cha X, Y, Z cn dng 0,335 mol O2 thu c tng khi lng v l 19,74gam. Mt khc a (gam)
E lm mt mu va dung dch cha 0,14 mol . Bit X c kh nng trng bc.Khi lng ca X trong E
l:
A. 8,6.
B. 6,6.
C. 6,8.
D. 7,6.
Cu 23. Trong s chuyn ho: S F eS H2 S H2 SO4 SO2 S c t nht bao nhiu phn
ng thuc loi phn ng oxi ho-kh ?
A. 4.
B. 3.
C. 5.
D. 2.
Cu 24. Cho cc cn bng sau trong cc bnh ring bit:
H2 (k, khng mu) +I2 (k, tm)  2HI(k,khng mu) (1)
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2N O2 (k, nu )  N2 O4 (k,khng mu) (2)

Nu lm gim th tch bnh cha c hai h trn,so vi ban u th mu ca:
A. h (1) khng thay i, h (2) nht i.
B. h (1) v h (2) u nht i.
C. h (1) v h (2) u m ln.
D. h (1) m ln, h (2) nht i.
Cu 25. Cho cc phn ng:
t0

(1) F2 + H2O

(2) N a2 S2 O3 + H2 SO4 (long)

(3) KI + F eCl3

t0
(4) Ca3 (P O4 )2 + SiO2 + CO

t0

(5) KN O3 + C + S

(6) CaOCl2 + HCl(c)

(7) Si + N aOH + H2 O

(8) H2 S + KM nO4 + H2 SO4

S phn ng to thnh n cht l:

A. 4.
B. 6.
C. 8.
D. 9.
Cu 26. Cho cc nhn nh sau:
(1). Ch dng thm dung dch H2 SO4 long c th nhn ra c nhiu nht 8 cht trong s cc mu cht
rn ring bit: Ba, M g, F e, Al, ZnO, M gO, Al2 O3 , CuO, Ag, Zn.
(2). Cng thc ca phn chua l : N a2 SO4 .Al2 SO4 .24H2 O.
(3). Thnh phn ch yu c trong g st l F e3 O4 .nH2 O.
(4). Kim loi c nhit nng chy thp nht l thy ngn (Hg), kim loi mm nht l Cs.
(5). Khi s dng phng php bo v in ha chng n mn kim loi ta dng mt kim loi lm vt hi
sinh l kim loi yu hn kim loi cn c bo v.
(6). Hp kim khng b n mn l : Fe- Cr- Mn (thp inoc).
(7). Nhit nng chy, nhit si ca cc nguyn t kim loi kim th bin i tun hon do cc nguyn
t ny u c cu trc mng tinh th ging nhau.
S nhn nh ng l:
A. 2.
B. 5.
C. 4.
D. 6.
Cu 27. Hp cht X c hai nguyn t cacbon trong phn t v c khi lng phn t nh hn 62. Khi t
chy X ch thu c CO2 v H2 O. C ti a my cht X m khi phn ng vi dung dch AgN O3 thu c
kt ta ?
A. 5.
B. 4.
C. 3.
D. 2.
Cu 28. Hn hp X gm ancol A, axit B , este C ( u n chc v c s C ln hn 1). t chy hon ton
0,25 mol X thu c 10,08 lt kh CO2 v 5,4 gam nc .Cng 1 lng X trn phn ng ti a vi 0,3 mol
Br2 .Phn trm v s mol ca B trong X :
A. 0,6.
B. 0,2.
C. 0,12.
D. 0,4.
Cu 29. Cho cc nhn xt sau :
1. dng vng Glucozo kt tinh to ra hai dng tinh th ng vi hai dng cu trc vng khc nhau .
2. Khi tc dng vi axit axetic, glucozo c th to ra este cha 5 gc axetat trong phn t .
3. Trong dung dch, fructozo tn ti ch yu dng, vng 5 cch hoc 6 cch.
4. Saccarozo l cht rn kt tinh, khng mu, v ngt .
S pht biu ng l :
A. 1.
B. 2.
C. 3.
D. 4.
Cu 30. Thy phn hon ton 0,3 mol hn hp X gm saccarozo, mamtozo thu c hn hp Y. Cho hn
Y tham gia phn ng trng bc thu c m(g) Ag (Bit cc cht trong X c s mol bng nhau) .Gi tr ca
m l :
A. 108.
B. 54.
C. 81.
D. 129,6.
Cu 31. Cho cc Polime sau : xenlulozo, polietilen , t vicco, xenlulozo trinitrat . Cc Polime nhn to l :
A. Xenlulozo, Polietilen.
B. Polietilen, t vicco.
C. T vicco, xenlulozo trinitrat.
D. Xenlulozo, xenlulozo trinitrat.
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Cu 32. Cho cc pht biu:

a. iu ch etanol trong cng nghip thng c 2 cch :Hidrat ha etilen v Ln mem tinh bt.
b. Phn ln phenol c dng sn xut poli(phenol-fomandehit).
c. Phng php chung iu ch andehit v xeton l oxi ha nh ancol tng ng bng CuO.
d. Oxi ha anhit axetic l phng php hin i sn xut axit axetic.
e. nng cao hiu sut ca phn ng este ha c th lm gim nng cc sn phm.
f. Thng thng cc amin c iu ch bng cch oxi ha hp cht nitro.
g. C th iu ch polimem bng cc phn ng trng hp hoc trng ngng.
S pht biu ng l :
A. 3.
B. 4.
C. 5.
D. 6.
Cu 33. t chy hon ton hn hp X gm : axit axetic, saccarozo, tinh bt cn dng 11,2 lt O2 thu c
m gam CO2 .Gi tr ca m l :
A. 22.
B. 44.
C. 16,5.
D. 19,8.
Cu 34. Cho cc nhn xt:
1. Flo tan nhiu trong nc.
2. Polisaccarit l cacbonhidrat thy phn sinh ra nhiu phn t monosaccarit .
3. Trong qu trnh in phn qu trnh iu ch Al trong cng nghip ,cc dng s b n mn dn v
c h thp xung.
4. Ancol bc II l hp cht hu c phn t cha nhm OH lin kt vi C bc II trong phn t.
5. Trong hp cht , s OXH ca nguyn t lun khc 0.
6. Phenol v anilin l cc hp cht thm lu trong khng kh b ha en.
S nhn xt ng l :
A. 2.
B. 5.
C. 1.
D. 3.
Cu 35. Cho cc cht sau : etilen, propan, benzen, axeton, axit fomic, andhit axetic, axetilen. S cht lm
mt mu dung dch brom trong CCl4 :
A. 2.
B. 3.
C. 4.
D. 5.
Cu 36. Qua t nht my qua trnh iu ch vinyl clorua t metan:
A. 1.
B. 3.
C. 2.
D. 4.
Cu 37. Hn hp X gm Al v 1 oxit Fe .Nung nng m(g) X sau mt thi gian thu c 31,3 rn Y .Rn
Y phn ng va vi 300ml dung dch NaOH 1M . Mt khc cho Y tac dng vi axit HN O3 long thu
c 2,24 lt) kh N2 (sn phm kh duy nht ) v m gam mui .Gi tr ca m l :
A. 136,5.
B. 68,25.
C. 204,75.
D. 102,375.
Cu 38. Mt hc sinh tin hnh cc th nghim sau:
TN1: Cho t t n d dung dch HCl v a mol dung dch N aAlO2 .
TN2: Cho t t n d dung dch NaOH vo b mol dung dch AlCl3 .
TN3: Cho t t n d dung dch AlCl3 vo c mol dung dch N aAlO2 dun nh.
TN4: Cho t t n d dung dch ha tan N H3 vo d mol dung dch AlCl3 .
ng vi mi th nghim hc sinh u tin v th biu din lng kt ta thu c theo dung dch cho
vo.Do trong qu trnh lm th nghim hc sinh ny qun khng nh du cc th ng vi tng TN.
Bng kin thc ca mnh , anh ch anh gip hc sinh chn ng th vi tng th nghim:

A. TN1-a; TN2-b; TN3-d; TN4-c.

C. TN1-c; TN2-a; TN3-d; TN4-b.
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B. TN1-a; TN2-c; TN3-b; TN4-d.

D. TH1-c; TN2-d; TN3-a; TN4-b.
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Cu 39. Khi tin hnh th nghim mt trong nhng bc quan trng nh hng khng nh n kt qu thu
c l bc c kt ta th nghim . Anh ch hy cho bit cch t mt c th tch ca mt cht
lng trong ng ong ca hc sinh no l ng nht.

A. Hc sinh A.
B. Hc sinh C.
C. Hc sinh D.
D. Hc sinh B.
Cu 40. Cho hn hp A gm mt hexapeptit X ( c cu to t nhng alpha aminoaxit c 1 nhm
N H2 , v 1 nhm COOH) v mt este no n chc Y ( nX : nY = 1 : 1). t chy m gam hn hp A
cn va 41,44 lt kh O2 ktc. Mt khc em m gam A tc dng va vi 700ml dung dch NaOH
1M va . C cn dung dch sau phn ng thu c mui khan B. em B i t chy hon ton cn 34,72
lt O2 % (ktc), sn phm thu c a v ktc thu c 30,24 lt kh. Tnh khi lng m ca hn hp A :
A. 81,9 gam.
B. 44,8gam.
C. 49,3 gam.
D. 53,9 gam.
Cu 41. Cho hn hp kh A gm mt anken X v H2 c t l mol l 2:1. Dn hn hp kh A qua Ni nung
nng thu c hn hp B. B c t khi so vi He l 12. t chy hon ton V lt hn hp B cho sn phm
chy qua 128 gam dung dch H2 SO4 98% sau phn ng nng axit cn 46,12% . Tnh V ca hn hp kh
B:
A. 47, 29lit.
B. 94, 58lt.
C. 85, 12lit.
D. 80, 64lit.
Cu 42. Cho cc pht biu sau:
1. Al; Cr; Fe; Cu u b th ng ha bi dung dch HN O3 ; H2 SO4 c ngui.
2. Trong dy cc cht Al, Al2 O3 , AlCl3 , Al(OH)3 , N aHCO3 , (N H4 )2 CO3 . S cht u phn ng c
vi dung dch HCl v dung dch NaOH l 5; s cht c tnh lng tnh l 4.
3. Al c tnh dn in, dn nhit tt nn c dng lm dy cp dn in thay th ng.
4. phn bit 4 cht rn ng trong 4 bnh ring bit mt nhn gm Mg, Al2O3, Al v Na ta c th dung
thuc th l H2 O.
5. Phn chua c cng thc KAl(SO4 )2 .12H2 O c dng lm trong nc c, dit khun, kh mi.
6. Sau khi phn ng nhit nhm gia Al v F e2 O3 xy ra th bnh cha phn lm hai lp trong Al2 O3
di cn Fe trn.
7. Mc ch chnh ca vic trn criolit trong qu trnh in phn nng chy Al2 O3 l to ra c cht lng
c tnh dn in tt hn Al2 O3 nng chy.
S pht biu sai l:
A. 2.
B. 3.
C. 4.
D. 5.
Cu 43. Cho 16, 26(g) hn hp X gm ancol n chc Y; ancol hai chc Z tc dng hon ton vi Na d
thu c 5, 712(l) kh H2 (ktc). Bit Y;Z u l ancol no, mch h v cng s nguyn t C; nZ > 0, 5nX .
Cho cc pht biu sau:
1. C hai cp cht (Y;Z) tha mn bi ton.
2. t chy hon ton X bng lng O2 va th nO2 > 1, 5nCO2 .
3. Oxi ha hon ton Z bng CuO d thu c hp cht hu c T (c tham gia trng gng) vi MT 6=
MC2 H5 CHO .
4. Y c th tc dng vi ancol trong cng dy ng ng nhng khng tc dng c vi Z.
5. Phn trm v khi lng ca Z trong X lun ln hn 91%.
S pht biu ng l:
A. 1.
B. 2.
C. 3.
D. 4.
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Cng ng ha hc v ng dng

bring about change

Cu 44. Cho cht hu c A no ch cha 1 nhm chc duy nht, c thnh phn C,H,O em t chy hon
ton 1 mol A thu c 18 gam H2 O. S cht tha mn A l
A. 4.
B. 5.
C. 6.
D. 3.
Cu 45. Dn hn hp kh A gm N H3 v Cl2 vo bnh kn ri nung nng. Sau a v nhit thng
thi thu c mt cht rn B v hn hp gm 2 kh C. Kh C c t khi hi so vi H2 l 32,25 . Tnh th l
th tch ca N H3 vi Cl2 hn hp A
7
3
5
3
A. .
B. .
C. .
D. .
3
7
3
5
Cu 46. Cho 200ml dung dch cha N a[Al(OH)4 ] 0,25M v NaOH 0,1M tc dng vi V (ml) dung dch
HCl 1M thu c 2,34 gam kt ta. Gi tr ln nht ca V l
A. 130.
B. 260.
C. 650.
D. 1200.
Cu 47. (1).Khi cho t t dung dch N H4 Cl vo dung dch mui natri aluminat trn ngn la n cn th
thy xut hin kt ta trng khng tan v c bt kh bay ra.
(2).Kh sufur c dng ty trng nc ng trong qu trnh sn xut ng saccaroz t cy ma.
(3.) Tt c cc hidrocacbon va th hin tnh kh, va th hin tnh oxi ha.
(4.) Ancol isobutylic v isobutylamin khng cng bc.
(5). Phn ng gia etilen vi dung dch thuc tm v phn ng gia axetylen vi H2 O u l phn ng t
oxi ha t kh.
(6).Axit malic cng thc cu to nh sau HOOC CH(OH) CH2 COOH, tn gi khc ca axit ny
l: Axit 2-hiroxibutan-1,4-icacboxylic.
(7).Dy cc dung dch v cht lng :Etylamin, natri phenolat, phenylamoni clorua, axit glutamic, axit axetic
u lm i mu qu tm tm nc ct.
(8). Khng th dng dung dch NaOH phn bit anlin v ancol metylic.
S pht biu sai l :
A. 2.
B. 3.
C. 4.
D. 5.
Cu 48. Hiu ng nh knh l hin tng tri t nng dn ln , do cc bc x c bc sng di trong vng
hng ngoi b gi li, m khng bc x ra ngoi v tr. Kh no di y l nguyn nhn chnh gy hiu
hng nh knh?
A. CO2 .
B. H2 .
C. H2 S.
D. HCl.
Cu 49. Cho hi etanol i qua xc tc (MgO + ZnO) nung nng nhit cao thu c cht hu c X.
Khi lng X thu c t 250 lt etanol 92 % ( D=0,8 g/ml) vi hiu sut l 80% l :
A. 84.6Kg.
B. 86, 4Kg.
C. 64, 8Kg.
D. 68, 4Kg.
Cu 50. Nung nng V lt kh (ktc) hn hp X gm C3 H4 , H2 vi Ni, sau mt thi gian thu c 0,25 mol
hn hp kh Y. Cho Y li qua dung dch AgN O3 /N H3 d, kh i ra khi dung dch lm mt mu 100 ml
dung dch Br2 1M v cn li hn hp kh Z. t chy hon ton Z thu c 4,5 gam H2 O. Mt khc t
chy hon ton Y thu c thu c 30,8 gam CO2 . Gi tr ca V l ?
A. 10, 36lit.
B. 9, 8lit.
C. 9, 1lit.
D. 8, 12lit.
Ht
Th sinh khng c s dng ti liu
Gim tr coi thi khng gii thch g thm.

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DIN N BOOKGOL

THI THPT QUC GIA CHUNG

LN 2 NM 2015
Mn: HA HC
Thi gian lm bi: 90 pht
(Khng k thi gian pht )
Ngy thi: 15/03/2015

thi th s 2
( thi gm c 7 trang)

M thi BK02

p n trc nghim
Cu 1. D

Cu 11. B

Cu 21. A

Cu 31. C

Cu 41. A

Cu 2. C

Cu 12. A

Cu 22. B

Cu 32. B

Cu 42. B

Cu 3. C

Cu 13. C

Cu 23. A

Cu 33. A

Cu 43. A

Cu 4. A

Cu 14. D

Cu 24. A

Cu 34. C

Cu 44. C

Cu 5. B

Cu 15. A

Cu 25. D

Cu 35. A

Cu 45. A

Cu 6. B

Cu 16. A

Cu 26. A

Cu 36. C

Cu 7. B

Cu 17. C

Cu 27. A

Cu 37. A

Cu 8. D

Cu 18. D

Cu 28. D

Cu 38. B

Cu 9. D

Cu 19. B

Cu 29. B

Cu 39. D

Cu 10. C

Cu 20. D

Cu 30. D

Cu 40. B

Cu 46. A
Cu 47. B
Cu 48. A
Cu 49. B
Cu 50. A

Ht
Th sinh khng c s dng ti liu
Gim tr coi thi khng gii thch g thm.

bring about change

Cng ng ha hc v ng dng

DIN N BOOKGOL

THI THPT QUC GIA CHUNG

LN 2 NM 2015

thi th s 2
( thi gm c 7 trang)

Mn: HA HC
Thi gian lm bi: 90 pht
(Khng k thi gian pht )
Ngy thi: 15/03/2015
M thi BK02

HNG DN GII CHI TIT

Cu 1. Li gii.
p n D
2 2
3
14
7 X X l N (Z = 7) : 1s 2s 2p
T d dng thy:A,B,C ng
D. Sai v: Trong hp cht cng ha tr, ha tr ca mt nguyn t c xc nh bng s lin kt ca nguyn
t nguyn t trong phn t v c gi l cng ha tr, do :N trong phn t N H3 c ha tr 3 cn
trong ion N H4+ c ha tr 4.
Cu 2. Li gii.
p n C
Bo ton khi lng ta c:
47, 875 = 0, 1.M + 0, 3.39 + 0, 35.62 + 0, 25.35, 5 M = 56
BTT, ta c: 0, 1n + 0, 3 = 0, 35 + 0, 25 n = 3
Do : M n+ = F e3+ c s e bng 26 3 = 23
Cu 3. Li gii.
p n C
Cu 4. Li gii.
p n A
un nng X: 2HCO3 CO32 + CO2 + H2 O
nCO2 = nH2 O = 0, 1(mol)
mX = m + mrn + mCO2 + mH2 O
= 13, 88 + 3, 68 + 0, 1.(44 + 18) = 23, 76(g)
Cu 5. Li gii.
p n B
A. ng. Ming ng nghim c b tr hi nghing xung phng ha cht b m do trong qu trnh
nhit phn c hi nc sinh ra s chy ngc xung lm v ng nghim.
* Ch : Nu thu bng phng php y khng kh th ming ng nghim c b tr hi nghing xung
ngoi nguyn nhn trn cn v O2 nng hn khng kh.
B. Sai. Khi ngng thu kh ta phi tho ng nghim trc khi tt n cn. V nu tt n cn trc p sut
kh trong ng nghim gim t ngt, nc s chy ngc ln ng nghim, gy v ng nghim.
C. ng. Ngi ta iu ch oxi bng phn ng phn hy nhng hp cht cha oxi v km bn vi nhit nh:
KM nO4 ; KClO3 ; H2 O2
D.ng. Phng php c dng nh trn l phng php y nc, c dng cho cc cht kh khng tan
trong nc ( hoc t tan) v khng tc dng vi H2 O iu kin thng nh: CO2 ; CO; H2 ; N2 ; N2 O; CH4 ; C2 H2 ; ...
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Cng ng ha hc v ng dng

Cu 6. Li gii.
p n B
"

M g : ne cho = 0, 2.2 = 0, 4
8
Al : ne cho =
15
V thc t hn hp gm c M g v Al nn:
8
0, 3 = nH + < 0, 4 < ne cho <
T , suy ra: H + ht, kim loi d.
15
nH2 = 0, 15 Xt phn ng: H2 + RO H2 O + R
14, 4
14, 4
nH + < 0, 18 =
< n2 oxit <
= 0, 2 Do , H2 ht, oxit d.
80
72
m = 14, 4 mO phn ng = 14, 4 16.0, 15 = 12(g)
Gi s hn hp ch gm :

Cu 7. Li gii.
p n B
+Phn ng to cc kt ta F eS; F eCO3 ; F e(OH)2 bn trong mi trng trung tnh hoc kim :
(1)N a2 S + F e(N O3 )2 F eS + 2N aN O3
(2)F e(N O3 )2 + 2CH3 N H2 + 2H2 O F e(OH)2 + 2CH3 N H3 N O3
(3)F e(N O3 )2 + N a2 CO3 F eCO3 + 2N aN O3
+F e2+ b oxi ha thnh F e3+ :
F e(N O3 )2 +H2 SO4 (long ; c)
(4)6F e2+ + 2N O3 + 8H + 6F e3+ + 2N O + 4H2 O
(5)2F e2+ + SO42 + 4H + 2F e3+ + SO2 + 2H2 O
(6) F e(N O3 )2 + AgN O3 : F e2+ + Ag + F e3+ + Ag
(7)F e(N O3 )2 + 3Br2 3F e(N O3 )3 + 2F eBr3
Ch : -Cc mui cacbonat ca kim loi ha tr III nh Al2 (CO3 )3 ; F e2 (CO3 )3 ; Cr2 (CO3 )3 khng tn ti
trong nc. Chng b thy phn hon ton to hidroxit kt ta v kh CO2
-Mui sunfua ca kim loi ha tr III nh Al2 S3 ; F e2 S3 ; Cr2 S3 khng tn ti trong nc. Chng b thy
phn hon ton to hidroxit kt ta v kh H2 S
Cu 8. Li gii.
p n D
Cn thng bng khi tng v khi lng ca hai cc l nh nhau. Mt khc, mui tan ht nn ton b
lng C trong CO32 chuyn ht cho CO2 .Do , ta c :
8, 221
10
.44 = 8, 441
.44 M = 39 : K
10 mCO2 (A) = 8, 221 mCO2 (B) 10
100
2M + 60
Cu 9. Li gii.
p n D
Vi thuc th l dung dch AgN O3 khi ta thu c cc kt qu nh sau:
- Bnh xut hin kt ta mu en (Ag2 S) l bnh cha kh H2 S
- Bnh xut hin kt ta mu trng (AgCl) l bnh cha kh HCl
- Bnh xut hin kt ta mu vng m (AgI) l bnh cha kh HI
- Bnh khng c hin tng g l bnh ng kh CO2 .
Cu 10. Li gii.
p n C
-V X c ha tan hon ton nn dung dch Y cha F e3+ ; Cu2+ ; SO42 ;ngoi ra cn c th cha H + hoc
N O3 hoc c hai.
V Ba(OH)2 cn dng tc dng ht vi cc cht trong Y nn
Y : @ N O3
TH1 :nBa2+ = nSO42
nBaSO4 = nBa2+

14 = 120x + 160y
T mX v mran ta c:
23, 475.2 = 80(x + 2y) + 233.0, 175

x>0

y < 0 (loai)
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bring about change

TH 2 :
nBa2+ > nSO42

Cng ng ha hc v ng dng
Y : N O3
nBaSO4 = nSO42

 T mX v mran ta c:
120x + 160y = 14
x = y = 0, 05 p dng LBT e, BTNT (Ba; N) ta c:
80(x + 2y) + 233(2x + y) = 46, 95
(10 + 15).0, 05 = nN O2

P hnpn : DngthnmtnhtdilnnBa(OH)2 = nBa(N O3 )2 + nBaSO4

nHN O3 = nN O2 + 2nBa(N O3 )2

nN O2 = 1, 25(mol)

nBa(N O3 )2 = 0, 025(mol)

nHN O3 = 1, 3 V = 0, 65(l)
Cu 11. Li gii.
p n B
Phn ng: Zn3 P2 + 6H2 O 3Zn(OH)2 (Y ) + 2P H3 (X)
P H3 khng th iu ch t n cht nhit thng (tng t nh N H3 ) nn B sai
Ch : Cng nhiu nc a vo c th chut th P H3 thot ra cng nhiu dn n chut cng mau cht.
Nu khng c nc chut s lu cht hn.
Cu 12. Li gii.
p n A
mP1 = 25, 41 + mA mCO(ban u) = 25, 41 + 0, 48 = 25, 89(g)
Xt phn 2, ta c : mP2 = 43, 15 25, 89 = 17, 26(g) X+NaOH c kh H2 thot ra chng t Al d ; oxit
kim loi ht (do phn ng xy ra hon ton)

H2

N a[Al(OH)4 ]
Al : x
Ald

t0
N aOH
S phn ng : F e2 O3 : y Al2 O3 max

F eCl2
HCl

H2
Cr2 O3 : z
F e; Cr
F e; Cr

long ngui

Cr
p
m ta c :
dung nh lut bo ton nguyn t, bo ton

x =nnN a[Al(OH)4 ] = nN aOH = 0, 18

x = 0, 18
Fe
y=
= 0, 03(nF e = nH2 = 0, 06) y = 0, 03 p dng LBT e c qu trnh ta c :
2

z = 0, 05
27x + 160.y + 152z = 17, 26


V
+ 0, 06 V = 0, 672(l)
3nAl = 2nF e2 O3 + 6nCr2 O3 + 2nH2 3.0, 18 = 2.0, 03 + 6.0, 05 + 2.
22, 4
Ch :
-Nu X tc dng vi NaOH ( lng ti a) th ton b Al trong Al2 O3 v Al d ( nu c ) chuyn ht vo
N a[Al(OH)4 ] - Cr khng tc dng vi dung dch HCl long ngui (long lnh), ch tc dng vi dung dch
HCl long nng.
Cu 13. Li gii.
p n C
(1) ;(3);(4) ng
(2)Sai. Khi pin in ha Zn-Cu phng in th tng v gim khi lng ca hai in cc lun bng nhau
(5). Sai. V N aHSO3 vn cn H c kh nng phn li ra ion H + .
Ch : Mt s mui nh N aH2 P O3 ; N aH2 P O2 mc d vn cn H nhng khng c kh nng phn li ra
ion H + nn l mui trung ha
(6). Sai. V Zn(OH)2 tan trong dung dch N H3 long l do to phc cht tan [Zn(N H3 )4 ](OH)2 ( khng
mu)
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Cng ng ha hc v ng dng

(7). ng. Phng trnh minh ha:

K2 Cr2 O7 + 6KI + 7H2 SO4 Cr2 (SO4 )3 + 4K2 SO4 + 3I2 + 7H2 O
Cu 14. Li gii.
p n D
4, 58
= 0, 082 < 0, 085 = nCu2+
56
Zn;Fe phn nght;CuSO
2+4d. S phn ng :
(

y
Zn

0
F e2 O3 :
F
e(OH)
N
aOH
t

2
2+

2
Zn : x
B F e
Cu(OH)2
CuSO4
2+ d
CuO : (0, 085 x y)
Cu
F e : y
 +

Cu : z
H ; SO42 ; Cu2+
H
SO

2
4

Cu : (x + y + z)

SO2
du
Ta c :nZn;Cu < nA <

ta c :
T gi thit v p dng inh lut bo ton electron

65x + 56y + 64z = 4, 58(= mX )

x = 0, 02
80y + 80(0, 085 x y) = 5, 2(= mE ) y = 0, 03

x + y + z = 0, 075(= nSO2 )
z = 0, 025
Do : %mCu = 34, 93%
Cu 15. Li gii.
p n A
V X + O2 thu c hn hp ch cha hai kh nn O2 ban u cng vi O2 sinh ra va tc dng ht vi
cc cht trong X.
Trong A cha N aN O2 ; N aN O3 ; N a2 SO3 v (N aHSO3 hoc NaOH d)
Mt khc c cn B ri nung trong kh tr thu c hn hp kh chng t trong A c cha N aHSO3
S phn ng:

(
x + z)

F
e
O
:

2 3

Cu
O
:
y

2
F
eS
:
x

2
O2 :0,08
N aN O2 : a

Cu2 S : y 0 

N aN O3 : a
SO2 : 2x + y N aOH
F e(N O3 )2 : z

N a2 SO3 : 0, 04
N O2 : 2z

N aHSO3 : b

BaSO

N aN O2 : a

N aN O2
N
aN
O

N aN O3 : a BaCl2

N aCl p dng inh lut BT NT Na ;N; S, ta c:

N aN O2 t0
A

N a2 SO3 : 0, 04 0,04

N a2 SO3

N aCl

N aHSO3 : b

O2 ; SO2
N
aHSO3

2a + 0, 08 + b = 0, 16
a = 0, 03

2a = 0, 04 + b (nSO2 = nN O2 )
b = 0, 02
p
dng LBT nguyn t O;N;S ta c:

6z + 0, 08.2 = 1, 5(x + z) + y + 4x + 2y + 4z()

x = 0, 01
2z = 0, 06
y = 0, 04 Khi : nF e2 O3 = 0, 02; nCu2 O =

2x + y = 0, 06
z = 0, 03
0, 04 (mol)
Mt khc: nH + phn ng = 2nO2 = 2(0, 02.3 + 0, 04) < 2.0, 24 = nH + ban u Do : Oxittan ht cn H+ d
nF e3+
nF e3+ = 0, 04; nCu = nCu2+ = 0, 04(mol) Li c: 2nCu > nF e3+ m = mCu d = nCu
.64 =
2
1, 28(g)
PTHH minh ha: F e2 O3 + 6H + 2F e3+ + 3H2 O
Cu2 O + 2H + Cu2+ + H2 O + Cu ()
2F e3+ + Cu 2F e2+ + Cu2+
Ch :
-Phng trnh (*) c th c thay th bng nh lut bo ton electron cho phn ng t chy hn hp:
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Cng ng ha hc v ng dng

11x + 6y = z + 4nO2 vi nO2 = 0, 08 (mol) Khi t nht mt nguyn t trong hp cht thay i s oxi ha so
vi trc phn ng; ta coi s oxi ha ca cc nguyn t cu to nn hp cht ban u u bng 0, vic xc
nh s e nhng nhn khi s ch ph thuc vo s oxi ha ca cc nguyn t sau phn ng t chy.
C th nh sau: (F eS2 )0 F e3+ + 2S +4 + (3 + 8)e
(Cu2 S)0 2Cu+1 + S +4 + (2 + 4)e
[F e(N O3 )2 ]0 F e+3 + 2N +4 + 6O2 + (3 + 8 12)e
-Phn ng (**) l phn ng t oxi ha -t kh.
Cu 16. Li gii.
p n A
Cu 17. Li gii.
p n C
Cu 18. Li gii.
p n D
Cu 19. Li gii.
p n B
B (propanal, axit fomic, andhit axetic)
Lu :axetilen ch to ta khng dng trng bc
Cu 20. Li gii.
p n D
ng : 1,2,4 3 sai v sai nhm cacbonyl sa thnh cacboxyl 5, sai v i vi cc axit cacboxylic khi s
nguyn t C tng ln th tan trong nc gim
Cu 21. Li gii.
p n A
Nhn thy s C chnh bng s nhm CHO v COOH
+ 2,24
= 0, 3
nC = nCO2 = nCHO + nCOOH = 0, 5. 43,2
108
22,4
=> mCO2 = 0, 3.44 = 13, 2
Cu 22. Li gii.
p n B
Theo bi : X c dng HCOOR x mol
Gi y,a,b ln lt l s mol ca Y,CO2 ,H2 O
Khi tc dng vi Br2 ta c : x + (2 1)y + (4 2)y = 0, 14
Bo ton O : 2a + b = 0, 335.2 + 2 (x + y + 2y) = 0, 95. Theo :44a + 18b = 19, 74
=> a = 0, 33; b = 0, 29
Theo cng thc:(1 1) x + (2 1) y + (4 1) y = 0, 33 0, 29 y = 0, 01 x = 0, 11

0,33
2
= 0,11+0,01+0,01
=
Ctb = nCO
E
Vy :m = 0, 11 60 = 6, 6

33
14

X : C 2 X : HCOOCH3 0, 11(mol)

Cu 23. Li gii.
p n A
Cu 24. Li gii.
p n A
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Cng ng ha hc v ng dng

Cu 25. Li gii.
p n D

Cu 26. Li gii.
p n A

Cu 27. Li gii.
p n A

Cu 28. Li gii.
p n D
nCO2 = 0, 45mol; nH2 O = 0, 3mol
+ 1 = 1, 6
ktb = 0,450,3
0,25
n = 1, 6.0, 25 = 0, 4mol
lng phn ng vi Br2 t ti a th C c dng HCOOR.
Gi x l s mol ca B:
Ta c : 0, 4 x = 0, 3 => x = 0, 1 => % = 0, 1/0, 25 = 0, 4
Cu 29. Li gii.
p n B
1,4 ng
2 sai : tc dng anhidrit
3 sai : dng

Cu 30. Li gii.
p n D
V sn phm thu c sau khi thy phn u c kh nng trng bc .
nY = 0, 3.2 = 0, 6mol => m = 0, 6.2.108 = 129, 6(g)
Cu 31. Li gii.
p n C

Cu 32. Li gii.
p n B
a,b,e,g ng
c. c,Oxi ha cc ancol c th thu c cc andehit hoc xeton tng ng .
d,Sai phng php hin i l cho methanol tc dng CO.
f, Sai Mt trong s cch iu ch amin l kh hp cht nitro.

Cu 33. Li gii.
p n A
D thy cc cht trong X khi t chy lng CO2 sinh ra chnh bng lng O2 => nCO2 = 11, 2/22, 4 =>
m = 22
Cu 34. Li gii.
p n C

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bring about change

Cng ng ha hc v ng dng

1,Sai. Flo tan t trong nc v b phn hy rt mnh.

2,Sai . ng l Thy phn hon ton
3, ng
4 .sai phi gn vo C no
5, Sai ,Vi d C(CH3 )4
6, sai Ch c anilin b ha en .

Cu 35. Li gii.
p n A
A : etilen , axetilen
Cu 36. Li gii.
p n C
2CH4 2C2 H2 + 3H2 C2 H2 + HCl C2 H3 Cl
Cu 37. Li gii.
p n A
Y ( Al ,Fe x,O y)
Khi cho Y tc dng vi NaOH 0,3 mol => nA l = nN aOH = 0, 3mol
Bo
 ton KL v e ,ta c h:

x = 0, 3
0, 3.27 + 56.x + 16y = 31, 3
=>
=> mmui = 0, 3.56 + 0, 3.27 + (0, 3.3 + 0, 3.3).62 =
0, 3.3 + x.3 = 2.y + 0, 1.10
y = 0, 4
136, 5(g)
Cu 38. Li gii.
p n B

Cu 39. Li gii.
p n D

Cu 40. Li gii.
p n B
0,1 mol CH3 COOC2 H5 v 0,1 mol C12 H20 O7 N6
Cu 41. Li gii.
p n A
X l C4 H8 do khi lng Mol trung bnh ca B l 48. Mt khc hn hp th kh nn s C ti a l 4. Suy ra
p n
Cu 42. Li gii.
p n B
1.Sai v Cu khng b th ng ha 5. Sai v phn chua ch c kh nng lm trong nc c nhng khng
c kh nng dit khun, kh mi. 6. Sai, Hn hp gm Al v F e2 O3 khi xy ra phn ng s t to nhit
vi hiu ng nhit ca phn ng rt ln, nng nhit ca h n nhit nng chy ca Fe vo khong
35000 C. Phn oxit nhm ni ln thnh x trn b mt Fe ngn cn Fe nng chy khng b oxi ha bi khng
kh. 7. Sai v mc ch chnh ca vic trn thm vo criolit l nhm h thp nhit nng chy ca Al2 O3
(t 20500 C xung cn 9000 C ) gip tit kim nng lng m cc hp cht khc khng thay th c.
Cu 43. Li gii.
p n A
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Cng ng ha hc v ng dng


14n(y + z) + 18y + 34z = 16, 26

y + 2z = 0, 255.2 (2)

(1)

Mt khc: nZ > 0, 5nX z > y Do :


(2)
(2)
y = 0, 17
2z < 0, 255.2 = y + 2z < 3y 0, 17 < z < 0, 255 Vi z = 0, 17
53 Vi z = 0, 255
n = 34
(1)
(1)
(
y=0
253 nN
53
253 Do ,
<n<
n = 2 Khi , Y : C2 H5 OH; Z : C2 H4 (OH)2
n=
34
119
119
(1). Sai v Y : C2 H5 OH; Z : C2 H4 (OH)2 u ch c 1 ng phn nn c duy nht 1 cp cht tha mn
(2) Sai.Nhn thy, nO2 = 0, 69 < 0, 81 = 1, 5.0, 51 = 1, 5nCO2 (mol) (3) Sai. T c cng thc HOC- CHO
(anhit oxalic) do MT = MC2 H5 CHO = 58 (4) Sai. V c phn ng tch nc xy ra gia cc ancol no Y
v Z. (5) ng. T gi thit v CTPT Y,Z ta tm c: y = 0, 03; z = 0, 24 (mol) Do : %mZ = 91, 51%
C th bn bit: C s phng php ca vic tm min gi tr ca n thng qua gi tr ti bin thc cht
7, 08 + 2z
= f (z) Bi ton quy
xut pht t phng php hm s. Tht vy, t gi thit ta suy ra: n =
14(0, 51 z)
7,08+2z
v tm chn trn v chn di ca n thng qua kho st hm s f (z) = 14(0,51z)
trn (0, 17; 0, 255) Nhn
0
thy: f (z) > 0; z (0, 17; 0, 255) f(z) ng bin trn khong (0, 17; 0, 255) Do : 53
= f (0, 17) <
34
253
V n N nn n = 2 T y, khi gp bi ton tm min gi tr ca mt i
n = f (z) < f (0, 255) =
119
lng ri rc A (Nhn hu hn gi tr trn mt tp s xc nh) viA = f (x) = ax+b
(c cc iu kin thch
cx+d
hp ca bin s) th ta lm theo cch xt gi tr ti bin s rt ngn thi gian so vi lm theo phng php
hm s.
T gi thit, ta c h:

Cu 44. Li gii.
p n C
Cu 45. Li gii.
p n A
Hai kh thu c l N2 v HCl.
Ptpu:
2N H3 + 3Cl2 N2 + 6HCl
N H3 + HCl N H4 Cl
T khi ca hn hp kh C so vi H2 l 32,25 T l mol N2 : HCl= 1:1
T suy ra p n A
Cu 46. Li gii.
p n A
V lng HCl cn tnh l ln nht nn xy ra hin tng ha tan mt phn kt ta. nH + = nOH +
4n[Al(OH)4 ] 3nAl(OH)3 = 0, 02 + 4.0, 05 3.0, 03 = 0, 13(mol) Do : V=130 ml
Cu 47. Li gii.
p n B
(4) Sai. Ancol isobutylic v isobutylamin cng bc (6) Sai. Tn gi khc ca axit malic l: Axit 2-hiroxibutanioic.
(8) Sai. phn bit anlin v ancol metylic ta c th dng dung dch NaOH. Cho mt t mi mu th vo 2
bnh ng dung dch NaOH ring bit. Khi , bnh ng thy c hin tng phn lp l bnh cha anilin
(do anlin khng tan trong dung dch NaOH), cn bnh c dung dch ng nht l bnh cha ancol meylic
(do ancol metylic tan v hn trong dung dch kim.)
Cu 48. Li gii.
p n A
Cu 49. Li gii.
p n B
Pt: 2C2 H5 OH CH2 = CH CH = CH2 + H2 + 2H2 O
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bring about change

Cng ng ha hc v ng dng

Cu 50. Li gii.
p n A
nCO2 = 0, 675 nC3 Hx = 0, 225 (mol) => nH2 = 0, 025 (mol).
Suy ra nC3 H8 = (nH2 O nH2 )/4 = 0, 05625 (mol)
=> nH2 ban u = 2nC3 H8 + nC3 H6 + 0, 025 = 0, 2375 (mol). => nX = 0, 4625(mol)
=> V=10,36 lt
Ht
Th sinh khng c s dng ti liu
Gim tr coi thi khng gii thch g thm.

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