Trng THPT K Thut L Thy

Ti liu luyn thi H-C

CHUYN SO SNH NHIT SI TAN V TNH

AXIT-BAZ
A- Nhit si ,nng chy ca cc cht
Cc yu t nh hng n nhit si , ngha l nh hng n lc ht gia cc phn t gm c:
- Khi lng phn t ; Lin kt H ; momen lng cc ca phn t ;Lc phn tn london (1dng ca lc Van
der Waals)
- Cc yu t trn cng nh hng ng k n tan trong nc ca cc cht hu c , m quan trng nht l
lin kt H. Gc R (ankyl ) cng ln kh nng k nc cng ln.
- Cu trc mng tinh th cng cht kht , gi gm st sao = > nhit nng chy cao.
1- nh hng ca lin kt H n nhit si :
- Lin kt gip cc phn t rng buc vi nhau cht ch hn => nhit si cao hn
2 - Lc van der waals
- Lc ht van der waals l lc ht tnh in gia cc phn t do s phn cc tm thi trong phn t
- Lc ht van der waals cng thuc loi lc tng tc yu , nh hng dn nhit si tng t nh lc lk H c lin
kt van der waals th nhit si cao hn .
3 - Mmen lng cc :
Xut hin khi c s phn b in tch ko u , c trng tm tch in dng v m ko trng nhau , nn xut hin
lng cc s c nhit si cao ,tan tt trong cc dung mi phn cc . VD : aminoacid hoc mui amoniclorua
4 - Lc phn tn London: Lc ny xut hin khi mmen lng cc tm thi gy ra do cm ng t cc phn t k
cn khi chng tin n gn nhau
+ Din tch b mt cng ln phn t cng ln th lc ht cng mnh lc london cng mnh -> t0 cao
+ Lc phn tn london gii thch cho chng ta hin tng cc ng phn c nhit si khc nhu ( do ng phn
no c mnh di hn ->lc london mnh hn nhit si cao hn )
+ phn nhnh cng cao > phn t cng i xng cu > din tch tip xc gia cc b mt phn t gim > nhit
si cng gim.
Bi 1: So snh nhit nc ca ng phn hnh hc

CH3COOCH2
CH2CH2CH3
C C
H
H
cis-

CH3COOCH2
H
C C
H
CH2CH2CH3
trans-

*Dng trans- c nhit nng chy cao hn do cu trc tinh th ca dng trans- bn vng sp xp cht kht hn so
vi dng cis- (dng trans- vn gi nguyn cu trc zic-zac ca mch cacbon, dng cis- ph v cu trc zic-zac ny).
Bi 2: Di y l cc gi tr nhit nng chy v nhit si ca n-pentan v neopentan. Gii thch s khc bit
nhit nng chy v nhit si gia cc cht ny.
n-Pentan Neopentan
Nhit si (oC)
36
9,5
Nhit nng chy (oC)
-130
-17
* Nhit si ca neopentan thp hn n-pentan v khi phn t c cng nhiu nhnh, tnh i xng cu ca phn t
cng tng, din tch b mt phn t cng gim, lm cho bn tng tc lin phn t gim v nhit si tr nn
thp hn.
* Tri li, tnh i xng cu li lm cho mng tinh th cht rn tr nn c kht hn v bn vng hn, nn nhit
nng chy cao hn.
Bi tp 3: So snh v gii thch vn tt:
(a) Nhit si ca pentan-1-ol, 2-metylbutan-2-ol v 3-metylbutan-2-ol.
(b) Tnh tan trong nc ca pentan-1,5-diol v pentan-1-ol
(c) mnh tnh axit ca CH4, C6 H5OH, CH3OH, CH3COOH, CH3SO2OH
Gii: (a) Trt t tng dn nhit si:

CH3

OH
C CH2 CH3
CH3

CH3 CH CH CH3
CH3 OH

CH3CH2CH2CH2CH2OH

Khi s mch nhnh tng th cu trc c xu hng thu gn tr thnh dng cu, lm gim bn lin kt lin phn t.
(b) pentan-1,5-diol tan tt hn pentan-1-ol, do c nhiu nhm -OH to c lin kt hidro a phng, a chiu hn.

Gio vin: Nguyn Cao Chung

-1-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

(c) Trt t tng dn mnh tnh axit:

Ti liu luyn thi H-C

O H
CH3-H

CH3O-H

O H CH
3

CH3

O
khng
phn
cc

phn cc yu
do CH3- y
electron

CH3-

CH3O-

phn cc mnh do
C6H5- ht electron

O
phn cc mnh
nht do c hai
nhm SO ht
electron

phn cc mnh
hn do CO ht
electron mnh
hn

O 1/3-

1/2-

O-

O
CH3

CH3

1/2-

km bn,
khng c gii
ta in tch

bn do c s gii
ta in tch

S O 1/3O 1/3-

O
km
bn

S O H

bn do c s gii
ta in tch trn
hai O

bn do c s gii
ta in tch trn
ba O

B - So snh tnh axit - baz

a) Tnh axit: - Khi mt axit kt hp vi mt nguyn t (hoc nhm nguyn t) c m in ln hn (phn cc)
cng gn nhm chc -COOH th tnh axit ca axit s ln hn axit tng ng. Lc ht e gim theo m in : (
F>Cl>Br>I)
V d: CH3COOH < Cl-CH2COOH < F-CH2COOH
- Mch cacbon ca axit cng di v cng phn nhnh th tnh axit cng gim.
-Khi c thm cc nhm th y e ( (CH3)3 C- > (CH3)2CH- > C2H5 - > CH3- > H-) gn vo mch C ca axit th lm
gim tnh axit
- Khi c thm cc nhm th ht e ( CN- >F- >Cl- >Br- >CH3O- >C6H5- >CH2 =CH-) gn vo mch C ca axit th lm
tng tnh axit.
- Axit khng no thng c tnh axit mnh hn axit no. CH3 CH2COH < CH2=CH-COOH < CH C-COOH
- ng phn cis c tnh axit mnh hn trans do c momen lng cc ln hn.
b) Tnh baz: Nguyn nhn gy ra tnh baz ca cc amin l do trn nguyn t N cn mt cp e t do c th nhng
cho proton H+. Mi yu t lm tng linh ng ca cp e t do s lm cho tnh baz tng v ngc li.
Nu R l gc y e s lm tng mt e trn N tnh baz tng.
Nu R l gc ht e s lm gim mt e trn N tnh baz tng.
Amin bc 3 kh kt hp vi proton H+ do s n ng khng gian ca nhiu nhm R cn tr s tn cng ca
H vo nguyn t N => nn trong dung mi H2O (phn cc) amin b1 < amin b2 > amin b3
S liu v pKa ca axit lin hp vi amin (pKa cng ln th tnh baz cng mnh):
(C6H5)2NH:0,9; C6H5NHC(CH3)3:3,78; C6H5NH2: 4,58; C6H5NHCH3: 4,85; C6H5NHC2H5: 5,11; NH3: 9,25;
C3H5NH2: 9,7; (CH3)3 N: 9,80; n- C4H9NH2 : 10,60; CH3NH2: 10,62; C2H5NH2 v n-C12 H25NH2: 10,63; n- C8H17NH2:
10,65; (CH3)2NH: 10,77; (C2H5)3N: 10,87; (C2H5)2NH: 10,93.
+

V d : So snh (c gii thch) mnh tnh axit ca axit molonic HOOC-CH2-COOH vi

(a) axit oxalic HOOC-COOH ; (b) axit sucxinic. HOOC-CH2-CH2- COOH
(a) K1 (axit oxalic) > K1 (axit malonic) do khi mch cacbon tng, hiu ng (-I) ca nhm cacboxyl gim lm
phn cc ca lin kt O-H v gim bn ca baz lin hp. K2 (axit oxalic) > K2 (axit malonic) do ion oxalat c
bit bn nh s cng hng.
(b) K1 (axit malonic) > K1 (axit sucxinic) do khi mch cacbon tng, hiu ng (-I) ca nhm cacboxyl gim lm
phn cc ca lin kt O-H gim v bn ca baz lin hp gim. K2 (axit malonic) < K2 (axit sucxinic) do ion
sucxinat bn hn ion malonat nh mch cacbon ln hn, th nng tng tc gia cc nhm COO- nh hn.

HO

OH
C C

O-

HO
C C

O 2-

O
C C
O

O
-

HOOC(CH2)nCOOH HOOC(CH2)nCOO OOC(CH2)nCOO-

Gio vin: Nguyn Cao Chung

-2-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

Ti liu luyn thi H-C

BI TP RN LUYN
Cu 1: Nhit si ca cc cht CH3CHO, CH3COOH, CH3CH2COOH, CH4 c sp xp theo chiu tng dn l :
A. CH3CHO, CH3COOH, CH3CH2COOH, CH4 . B. CH3COOH, CH3CHO, CH3CH2COOH, CH4 .
C. CH4, CH3CHO, CH3COOH, CH3CH2COOH . D. CH3CHO, CH3CH2COOH, CH3COOH, CH4 .
Cu 2: Nhit si ca cc cht c sp xp theo th t tng dn :
A. C 2H5Cl < CH3 COOH < C2H5OH .
B. C2H5OH < C2H5Ci < CH3COOH .
C. C2H5Cl < C2H5OH < CH3COOH .
D. CH3COOH < C2H5OH < C2H5Ci .
Cu 3: Cht c nhit si cao nht l :
A. CH3COOH
B. CH3CHO
C. C2H5OH
D. CH3COCH3
Cu 4: Nhit si ca cc cht : (1) axit fomic ; (2) anehit fomic ; (3) ru metylic . c xp theo th t tng
dn l :
A. 1, 2, 3
B. 2, 1, 3
C. 2, 3, 1
D. 3, 2, 1
Cu 5: Trong cc cch sp xp tng dn nhit si ca cc cht sau, th t ng l:
A. HCOOCH3 < CH3COOCH3 < n- C3H7OH < CH3COOH < C2H5COOH
B. HCOOCH3 < CH3COOH < n- C3H7OH < CH3COOCH3< C2H5COOH
C. HCOOCH3 < CH3COOCH3 < CH3COOH < n- C3H7OH < C2H5COOH
D. n- C 3H7OH <HCOOCH3 < CH3 COOH < C2H5COOH < CH3COOCH3
Cu 6: Cc cht sau c sp xp theo chiu tng nhit si l :
A. ru etylic, anehit axetic, axit axetic, ru metylic .
B. anehit axetic, ru metylic,ru etylic, axit axetic.
C. ru metylic,ru etylic, axit axetic, anehit axetic.
D. axit axetic,ru metylic,ru etylic, anehit axetic.
Cu 7: Trong dy ng ng ca ru no n chc khi mch cacbon tng ni chung:
A. si tng , kh nng tan trong nc tng .
B. si gim , kh nng tan trong nc gim .
C. si tng , kh nng tan trong nc gim .
D. si gim , kh nng tan trong nc tng .
Cu 8: Trong hn hp etanol v phenol lin kt hiro bn hn c l :

A. O - H ... O - H

B. O - H ... O - H

C2H5
C2H5
C. O - H ... O - H

C2H5
C6H5
D. O - H ... O - H

C6H5

C6H5

C6H5

C2H5

Cu 9: Cht t tan trong nc nht l :

A. CH3COOCH3
B. CH3COOH
C. C2H5OH
D. CH2OH - CH2OH
Cu 10: Cho cc cht sau : CH3COOH, CH3CHO, C2H5OH, C2H6 , Cht c nhit si cao nht l :
A. CH3CHO
B. CH3 COOH
C. C2H6
D. C2H5OH
Cu 11: Cho cc cht sau : CH3COOH, C2H5COOH, CH3COOCH3 , CH3CH2CH2OH
Chiu tng dn nhit si ( t tri qua phi ) ca cc cht trn l
A. CH3CH2CH2OH, CH3COOH, CH3COOCH3 , C2H5COOH
B. CH3COOCH3 ,CH3CH2 CH2OH, CH3COOH, C2H5COOH
C. CH3COOH,CH3COOCH3 ,CH3CH2CH2OH, C2H5COOH
D. CH3CH2CH2OH, CH3COOH, CH3COOCH3 , C2H5COOH
Cu 12 : Sp xp th t nhit si ca cc cht : ancol etylic , axit axetic , etyl axetat ?
A. Ancol etylic < axit axetic < etyl axetat
B. Etyl axetat < Ancol etylic < axit axetic
C. Ancol etylic > axit axetic > etyl axetat
D. Ancol etylic > etyl axetat > axit axetic
Cu 13: Cho cc cht sau : CH3COOH, CH3CHO, C6H6, C6H5COOH
Chiu gim dn ( t tri qua phi ) kh nng ho tan trong nc ca cc cht trn l :
A. CH3COOH, CH3CHO, C6H5COOH, C6H6 .
B. CH3COOH, C6H5COOH,CH3CHO, C6H6 .
C. C6H5COOH,CH3COOH, CH3CHO, C6H6 .
D. CH3COOH, C6H5COOH, C6H6,CH3CHO .
Cu 14: Cho 3 axit :
Axit pentanoic
CH3[CH2 ]2CH2COOH
(1)
Axit hexanoic
CH3[CH2]3CH2COOH
(2)
Axit heptanoic
CH3[CH2 ]4CH2COOH
(3)
Chiu gim dn tan trong nc ( t tri qua phi ) ca 3 axit cho l
A. (1) , (3) , (2) . B. (1) , (2) , (3)
C. (3) , (2) , (1) .
D. C 3 axit trn u khng tan trong nc
Cu 15: Cho cc cht sau : C2H5OH , CH3COOH, HCOOH , C6H5OH
Chiu tng dn linh ng ca nguyn t H trong cc nhm chc ca 4 cht l :
A. C 2H5OH , C6H5OH, HCOOH , CH3COOH. B. C2H5OH , C6H5OH, CH3COOH, HCOOH .
C. C6H5OH,C2 H5OH , HCOOH, CH3COOH.
D. C6H5OH,C2H5 OH, CH3COOH , HCOOH.
Cu 16: Hy sp xp cc cht sau y theo trt t tng dn nhit si :

Gio vin: Nguyn Cao Chung

-3-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

Ti liu luyn thi H-C
CH3COOH , CH3COOCH3 , HCOOCH3 , C2H5COOH , C3H7OH . Trng hp no sau y ng ?
A. HCOOCH3 < CH3COOCH3 < C3H7OH < CH3COOH < C2H5COOH
B. CH3COOCH3 <HCOOCH3 < C3H7OH < CH3COOH < C2H5COOH
C. HCOOCH3 < CH3COOCH3 < C3H7OH < C2H5COOH < CH3 COOH
D. Tt c u sai .
Cu 17: a) Hy sp xp cc cht sau y theo trt t tng dn nhit si : C2H5OH
( t 10) , C3 H7OH ( t 20 ) , etyl clorua ( t 30) , axit axetic ( t 40) , imetyl ete ( t 50) ?
A. ( t 50 ) < ( t 30) < ( t 20) < ( t 10) < ( t 40) B. ( t 3 0) < ( t 50) < ( t 1 0) < ( t 20 ) < ( t 40)
C. ( t 5 0) < ( t 30) < ( t 1 0) < ( t 20 ) < ( t 40) D. ( t 50 ) < ( t 30) < ( t 40) < ( t 20) < ( t 10)
b) Sp xp nhit si theo th t tng dn ca ihroxxibenzen
(1)
(2)
(3)

OH

OH

OH
OH

OH
A. (1) < (2) < (3);
C. (1) < (3) < (2);

B. (1) < (2) = (3);

D. (3) < (2) < (1).

OH

Cu 18: Lin kt hiro ca CH3OH trong dung dch nc l phng n no ?

A. ... O H... O H...
|
|
CH3
H

B. ... O H... O H...

|
H

|
CH3

C. ... O H... O H...

|
|
CH3
CH3

D. C A, B, C

Cu 19: Cht no sau y c nhit si cao nht ?

A. CH3 - CH2 - OH

B. CH3 - CH2 - CH2 - OH

C. CH3 - CH2 - Cl D.CH3 - COOH

Cu 20: So vi cc axit v ancol c cng s nguyn t cacbon th este c nhit si

A. Cao hn
B. Thp hn
C. ngang bng
Cu 21: Th t cc cht xp theo chiu tng dn lc axit l
A. HCOOH<CH3COOH<CH3CHClCOOH<CH2ClCH2COOH.
B. CH2ClCH2COOH<CH3CHClCOOH<CH3 COOH<HCOOH
C. HCOOH<CH3COOH<CH2ClCH2COOH<CH3CHClCOOH.
D. CH3COOH<HCOOH<CH2ClCH2COOH<CH3CHClCOOH.

D. khng so snh c

Cu 22: Nhit si ca ru etylic (1), ru metylic (2), axeton (3) dimetyl ete (4) xp theo trt t gim dn l:
A. (1) > (2) > (3) > (4)

B. (1) > (2) > (4) > (3)

C. (1) > (3) > (4) > (2)

D. (4) > (3) > (2) > (1)

Cu 23: Ru etylic (1), etyl bromua (2) v etan (3), trt t v tan trong nc gim dn l:
A. (1), (3), (2)

B. (1), (2), (3)

C. (3), (2), (1)

D. (2), (1), (3)

Cu 24: So snh nhit si ca cc cht sau Ru etylic (1) , etyl clorua (2), ietyl ete (3) v axit axetic (4) ta
c:
A. (1 ) > (2) > (3) > (4)

B. (4) > (3) > (2) > (1 )

C. (4) > (1) > (3) > (2)

D. (1) > (2) > (3) > (4)

Cu 25: . Sp xp cc cht sau y theo trnh t tng dn nhit si :

CH3COOH (1) , HCOOCH3 (2) , CH3CH2COOH (3) , CH3COOCH3 (4) , CH3CH2CH2OH (5)
A. (3) > (5) > (1) > (2) > (4)

B. (1) > (3) > (4) > (5) > (2)

C. (3) > (1) > (4) > (5) > (2)

D. (3) > (1) > (5) > (4) > (2)

Cu 26: .Cho 4 cht : X (C2H5OH) ; Y (CH3CHO) ; Z (HCOOH) ; G (CH3COOH).

Nhit si sp theo th t tng dn nh sau:
A. Y < Z < X < G

B. Z < X < G < Y

C. X < Y < Z < G

D. Y < X < Z < G

Cu 27: . Dy cht no sau y c sp xp theo chiu nhit si ca cc cht tng dn?

A. CH3COOH, CH3COOC2H5, CH3CH2CH2OH

Gio vin: Nguyn Cao Chung

B. CH3COOH, CH3CH2CH2OH CH3COOC2H5,

-4-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

C. CH3CH2CH2OH , CH3COOH, CH3COOC2H5

Ti liu luyn thi H-C

D. CH3COOC2H5 ,CH3CH2 CH2OH , CH3COOH

Cu 28: .Cho 4 cht: X(andehit fomic), Y (axit axetic), Z (ru metylic), T (axit fomic). Nhit si c sp theo
th t tng dn nh sau:
A. Y < Z < X < T
B. X < Z < T < Y
C. Z < X < Y < T
D. X < Z < Y < T
Cu 29:. Cho cc cht : CH3CHO, CH3COOH, HCOOCH3 , CH3 CH2OH.
Cht c nhit si cao nht l :
A. CH3CHO
B. CH3COOH
C.HCOOCH3
D. CH3CH2OH
Cu 30: Dy sp xp theo th t tng dn nhit si ca cc hp cht c cng s nguyn t cacbon
A. Ankan, axit, anehit, ancol.
B. Anehit, ankan, ancol, axit.
C. Ankan, anehit, axit, ancol.
D. Ankan, anehit, ancol, axit.
Cu 31:. Trong dung dch, axit cacboxylic c lin kt hiro v c th :
A. dng polime.
B. dng ime.
C. to lin kt hiro vi nc.
D. C A, B, C.
Cu 32: Lin kt H no sau y biu din sai ?
A. ... O H ... O C 2 H5

|
C 2 H5
C.

Cu 33:

B. ... O H ... O H

|
C 2 H5

|
C 2 H5

HO ... H O
|
|
CH2
CH2

|
C 2 H5

D. H - C - OH .... H - C - OH

||
O

||
O

Cht no sau y c nhit si cao nht ?

A. CH3 - CH2 - OH

B. CH3 - CH2 - CH2 - OH

C. CH3 - CH2 - Cl

D. CH3 - COOH

Cu 35: Sp xp theo chiu tng dn nhit si cc cht : p-nirophenol (1), phenol (2), p- crezol(3).
A. (1) < (2) < (3)

B. (2) < (1) < (3)

C. (3) < (2) < (1)

D. (3) < (1) < (2).

Cu 36: Cho cc cht : p-NO2C6H4 COOH (1), m-NO2 C6H4 COOH (2), o-NO2C6H4 COOH (3)
Tnh axit tng dn theo dy no trong s cc dy sau y ?
A. (2) < (1) < (3)

B. (1) < (3) < (2)

C. (3) < (1) < (2)

D. (2) < (3) < (1)

Cu 37: Cht no sau y c nhit si cao nht ?

A. Propanol-1

B. Anehit propionic

C. Axeton

D. Axitpropionic.

Cu 38: Tm pht biu sai trong cc pht biu sau ?

A. Etylamin d tan trong H2O do c to lin kt H vi nc
B. Nhit si ca ru cao hn so vi hirocacbon c phn t khi tng ng do c lin kt H gia cc
phn t ru.
C. Phenol tan trong H2O v c to lin kt H vi nc.
D. Metylamin l cht lng c mi khai, tng t nh amoniac.
Cu 39: Cho cc cht sau : Ru etylic (1), etylamim (2), metylamim (3), axit axetic (4).
Sp sp theo chiu c nhit si tng dn :
A. (2) < (3) < (4) < (1)

C. (2) < (3) < (4) < (1)

B. (3) < (2) < (1) < (4)

D. (1) < (3) < (2) < (4)

Cu 40: Nhit si ca C4H10 (1), C2H5 NH2 (2), C2H5OH (3) tng dn theo th t:
A. (1) < (2) < (3)
B. (1) < (3) < (2)
C. (2) < ( 3) < (1)
D. ( 2) < ( 1) < (3)
Trong cc cht sau, cht no tan trong nc nhiu nht ?
A. C 6H6
B. C2H5Br
C. C2H5OH
D. C6H5-CH3
Cu 41: Sp xp cc hp cht sau theo th t tng dn nhit si: axit axetic (1), ru n-propylic (2), ru
isopropylic (3), metyl etyl ete (4):
A. (1) < (2) < (3 ) < (4)
B. (4) < (3) < (2) < (1)
C. (1) < (4) < (3) < (2)

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D. (2) < (3) < (4) < (1)

-5-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

Cu 42: So snh tnh axit ca cc cht sau y:
Cl-CH2COOH (1) ,

CH3COOH (2) ,

Ti liu luyn thi H-C

HCOOH (3) ,

A. (4) > (2) > (1) > (3)

B. (3) > (4) > (1) > (2)

C. (4) > (1) > (3) > (2)

D. (4) > (3) > (1) > (2)

CHCl2 -COOH (4)

Cu 43: Sp xp cc hp cht: CH3COOH, C2H5OH v C6H5OH theo th t tng axit. Trng hp no sau y ng
A. C2H5OH < CH3 COOH < C6H5OH

B. C6H5OH < CH3COOH < C2H5OH

C. CH3COOH < C6H5OH < C2H5OH

D. C2H5OH < C6H5OH < CH3COOH

Cu 44: Sp xp cc hp cht: CH3COOH, C2H5 OH v C6H5OH theo th t tnh axit tng dn. Trng hp no sau
y ng?
A. C 2H5OH < CH3COOH < C6H5OH
C. CH3COOH < C6H5 OH < C2H5OH

B. C6H5OH < CH3COOH < C2H5OH

D. C2H5OH < C6H5OH < CH3COOH

Cu 45: Hp cht no sau y c tnh axit mnh nht ?

A. CCl3-COOH

B. CH3COOH

C. CBr3COOH

D. CF3COOH

Cu 46: .Cho 4 axit: CH3COOH, H2CO3, C6H5OH, H2SO4. mnh ca cc axit c sp theo th t tng dn
A. CH3COOH < H2CO3 < C6H5OH < H2SO4 B. H2CO3 < C6H5OH < CH3COOH < H2SO4
C. H2CO3 < CH3COOH < C6H5OH < H2SO4 D. C6H5OH < H2CO3 < CH3COOH < H2SO4
Cu 47: . mnh baz xp theo th t tng dn ng trong dy no:
A. CH3-NH2 , NH3 , C2H5NH2 , C6H5NH2

B. NH3 ,CH3-NH2 , C2 H5NH2 , C6H5NH2

C. NH3 ,C6H5NH2 , CH3-NH2 , C2H5 NH2 ,

D. C6 H5NH2 , NH3 , CH3-NH2 , C2H5NH2 ,

Cu 48: . Cho cc cht: (C6 H5)2NH , NH3 , (CH3)2NH ;C6 H5NH2 . Trt t tng dn tnh baz (theo chiu t tri qua
phi) ca 5 cht trn l
A. (C6H5)2NH , C6H5NH2 ; NH3 , (CH3)2NH ;

B. (CH3)2NH ; (C6H5)2NH , NH3 , ;C6H5NH2

C. C6H5NH2 ; (C6H5)2NH , NH3 , (CH3)2 NH

D. NH3 ; (C6H5)2NH , C6H5NH2 , (CH3)2NH

Cu 49: Cho cc cht sau: C6H5 NH2 (1) , C2H5NH2 (2); (C2H5)2NH (3) ; NaOH (4) ; NH3 (5)
Trt t tng dn tnh baz (t tri qua phi) ca 5 cht trn l :
A. (1), (5), (2), (3), (4)

B. (1), (2), (5), (3), (4)

C. (1), (5), (3), (2), (4)

D. (2), (1), (3), (5), (4)

Cu 50: Hy sp xp cc cht sau y theo trnh t tnh baz tng dn t tri sang phi: amoniac, anilin, pnitroanilin, metylamin, imetylamin.
A. O2 NC6H4NH2 < C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH
B. C6H5NH2 < O2NC6H4NH2 < NH3 < CH3NH2 < (CH3)2NH
C. O2NC6H4NH2 < C6H5NH2 < CH3NH2 < NH3 < (CH3)2NH
D. O2NC6H4NH2 < NH3 < C6H5NH2 < CH3NH2 < (CH3)2 NH
Cu 51: . Sp xp cc amin : anilin (1), metyl amin(2), imetyl amin(3) v trimetyl amin (4) theo chiu tng dn tnh
baz
A. (1) < (2) < (3) < (4) B. (4) < (1) < (3) < (2)
C. (1) < (2) < (4) < (3) D. (1) < (4) < (3) < (2)
Cu 52: Anilin t tan trong :
A. Ru.
B.Nc.
C. Ete.
D. Benzen.
Cu 53:. Dy no sp xp cc cht theo chiu tnh baz gim dn ?
A. NH3 , CH3NH2, C6 H5NH2, (CH3)2NH B. CH3NH2, (CH3)2NH, NH3, C6H5NH2
C. C6H5NH2, NH3, CH3NH2, (CH3)2NH D. (CH3)2NH, CH3NH2, NH3, C6H5NH2
Cu 54: Dy no sp xp cc cht theo chiu tnh baz gim dn ?
A. H2 O, NH3, CH3NH2, C6H5NH2
B. C6H5NH2, NH3, C6H5NH2, H2O

Gio vin: Nguyn Cao Chung

-6-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

Ti liu luyn thi H-C
C. CH3NH2, CH3NH2, NH3, H2 O
D. NH3, H2O, CH3NH2, C6H5NH2
Cu 55:. Dy sp xp ng theo tnh axit ca cc cht gim dn :
A.CH3COOH, HCOOH, CH3OH, C6H5OH.
B.HCOOH, CH3COOH, CH3 OH, C6H5 OH.
C.HCOOH, CH3COOH,C6H5OH., CH3 OH.
D. CH3COOH, C6H5OH, CH3COOH, CH3OH.
Cu 56: Phenol(1), p-nitrophenol(2), p-crezol(3), p-aminophenol(4) Tnh axit tng dn theo dy :
A. (3) < (4) < (1) < (2)

C. (4) < (3) < (1) < (2)

B. (4) < (1) < (3) < (2)

D. (4) < (1) < (2) < (3).

Cu 57: linh ng ca nguyn t H trong nhm OH ca cc cht C2H5OH, C6H5OH, HCOOH v CH3COOH tng
dn theo trt t no ?
A. C 2H5OH < C6H5OH < HCOOH < CH3COOH. B. CH3COOH < HCOOH < C6H5OH < C2H5OH.
C. C2H5OH < C6H5 OH < CH3COOH < HCOOH.

D. C6H5OH < C2H5OH < CH3COOH < HCOOH.

Cu 58: Dy cht sau y sp xp ng theo chiu tng dn nhit si ?

A. HCOOH < CH3 - CH2 - OH < CH3 - CH2 - Cl.

B. C2H5Cl < C4H9 Cl < CH3 -CH2 - OH < CH3 - COOH

C. CH3 - COOH < C4H9Cl < CH3CH2OH

D. CH3CH2OH < C4H9 Cl < HCOOH

Cu 59; Chn dy sp xp ng theo th t tng dn tnh axit cc cht sau :

CH3COOH (1), CH2ClCOOH (2), CH3OCH2 COOH (3), CH2FCOOH (4).
A. (2) < (1) < (4) < (3)

C. (1) < (2) < (3) < (4)

B. (2) < (1) < (3) < (4)

D. (1) < (3) < (2) < (4)

Cu 60: Sp xp theo th t tng dn tnh axit : H3CH2COOH (1), CH2=CHCOOH (2), CHCCOOH(3).
A. (1) < (2) < (3)

B (1) < (3) < (2)

C. (2) < (3) < (1)

D. (3) < (1) < (2)

Cu 61: Sp xp theo th t tng dn tnh axit ca cc cht sau :

CH2Cl - COOH (1), CHCl2COOH (2), CCl3COOH (3)
A. (3) < (2) < (1)

C. (1) < (2) < (3)

B. (2) < (1) < (3)

D. (3) < (1) < (2)

Cu 62; Sp xp theo th t tng dn tnh axit ca cc cht sau :

Axit p-metylbenzoic (1), axit p-aminobenzoic (2), axit p-nitrobenzoic(3), axit benzoic(4).
A. (4) < (1) < (3) < (2)

C. (1) < (4) < (2) < (3)

B. (1) < (4) < (3) < (2)

D. (2) < (1) < (4) < (3)

Cu 63: Sp xp theo th t tng dn tnh axit ca cc cht sau :

Axit o-nitrobenzoic (1), axit p-nitrobenzoic (2), axit m-nitrobezoic (3).
A. (1) < (2) < (3)

C. (3) < (2) < (1)

B. (2) < (1) < (3)

D. (2) < (3) < (1)

Cu 64; Trong s cc cht sau :

C2H6; C2H5Cl; C2H5NH2; CH3COOC2H5; CH3COOH; CH3CHO; CH3 OCH3
cht no to c lin kt H lin phn t ?
A. C2H6

B. CH3COOCH3

C. CH3CHO ; C2H5Cl D. CH3COOH ; C2H5NH2

Cu 65: Metylamin d tan trong H2O do nguyn nhn no sau y ?

A. Do nguyn t N cn cp electron t do d nhn H+ ca H2 O. B. Do metylamin c lin kt H lin phn t.
C. Do phn t metylamin phn cc mnh.

D. Do phn t metylamin to c lin kt H vi H2O.

Cu 66: Nguyn nhn gy nn tnh baz ca amin l :

A. Do amin tan nhiu trong H2O.

B. Do phn t amin b phn cc mnh.

C. Do nguyn t N c m in ln nn cp e chung ca nguyn t N v H b ht v pha N.

D. Do nguyn t N cn cp eletron t do nn phn t amin c th nhn proton.
Cu 67: Dy sp xp ng theo th t gim dn tnh baz l dy no ?
(1) C6H5NH2

Gio vin: Nguyn Cao Chung

(2) C2H5NH2
-7-

Chc cc em thnh cng!

Trng THPT K Thut L Thy

(3) (C6H5)2NH

Ti liu luyn thi H-C

(4) (C2H5)2 NH

(5) NaOH

(6) NH3

A. (1) > (3) > (5) > (4) > (2) > (6)

B. (5) > (6) > (2) > (1) > (2) > (4)

C. (5) > (4) > (3) > (5) > (1) > (2)

D. (5) > (4) > (2) > (6) > (1) > (3)

Cu 68: Cho qu tm vo mi dung dch hn hp di y, dung dch no lm qu tm ha ?

(1) H2N - CH2 COOH

(2) Cl - NH3+ - CH2 - COOH

(3) NH2 - CH2 COONa

(4) H 2 N CH 2 CH 2 CH COOH

|
NH2

(5) HOOC CH 2 CH 2 CH COOH

|
NH2

A. (2), (4)

B. (3), (1)

C. (1), (5)

D. (2), (5).

Cu 69; Cho dung dch cha cc cht sau :

X1 : C6H5 - NH2

X2 : CH3 - NH2

X3 : NH2 - CH2 - COOH

X4 : HOOC CH 2 CH 2 CH COOH

X5 : H 2 N CH 2 CH 2 CH 2 CH COOH

|
NH2

|
NH2

Dung dch no lm qu tm ha xanh ?

A. X1 , X2, X5

B. X2, X3, X4

C. X2, X5

D. X1, X3, X5

Cu 70: Amin no sau y c tnh baz ln nht :

A. CH3CH=CH-NH2

C. CH3CH2CH2NH2

B. CH3CC-NH2

D. CH3CH2NH2

Cu 71: Cho cc cht sau : CH3CH2NHCH3(1), CH3CH2CH2NH2(2), (CH3)3N (3). Tnh baz tng dn theo dy :
A. (1) < (2) < (3)

B. (2) < (3) < (1)

B. (3) < (2) < (1)

D. (3) < (1) < (2)

Cu 72: Cho cc cht sau :

p-CH3C6H5NH2(1), m-CH3C6 H5NH2 (2), C6H5NHCH3 (3), C6H5NH2 (4).

Tnh baz tng dn theo dy :

A. (1) < (2) < (4) < (3)

C. (4) < (2) < (1) < (3)

B. (4) < (3) < (2) < (1)

D. (4) < (3) < (1) < (2)

Cu 73; Cho cc cht sau : p-NO2C6 H4NH2 (1), p-ClC6H5NH2 (2), p-CH3 C6H5NH2 (3).
Tnh baz tng dn theo dy :
A. (1) < (2) < (3)

B. (2) < (1) < (3)

C. (1) < (3) < (2)

D. (3) < (2) < (1)

Cu 74; Cht no sau y c tnh baz mnh nht ?

A. NH3

B. C6H5NH2

C. CH3-CH2-CH2 -NH2

D. CH3-CH(CH3)-NH2

Cu 75; L do no sau gii thch tnh baz ca monoetylamin mnh hn amoniac :

A. Nguyn t N cn i electron cha to lin kt

B. nh hng y electron ca nhm -C2H5

C. Nguyn t N c m in ln

D. Nguyn t nit trng thi lai ho

Cu 76: Cho qu tm vo dung dch mi hp cht di y, dung dch no s lm qu tm ho :

(1) H2N - CH2 - COOH
.

(2) Cl NH3 - CH2COOH

(4) H2N(CH2)2 CH(NH2)-COOH

(5) HOOC(CH2)2CH(NH2) - COOH

(3) H2N - CH2 - COONa

Gio vin: Nguyn Cao Chung

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Chc cc em thnh cng!

Trng THPT K Thut L Thy

Ti liu luyn thi H-C
A. (2), (5)
B. (1), (4)
C. (1), (5)
D. (2)
Cu 77: Anilin c cng thc cu to C6H5NH2 . Hy gii thch v sao anilin tc dng d dng vi nc brom.
A. V nhm NH2 ht electron, lm cho mt electron trong vng benzen gim.
B. V nhm NH2 y electron, lm cho mt in tch m trong vng benzen tng ln.
C. Nguyn t nit trong nhm NH2 cn electron t do nn cc electron ny y proton trong vng benzen.
D. A, C u ng.
Cu 78: Tnh axit ca cc hiro halogenua c sp xp theo cc trt t mnh dn. Hy chn mt sp xp ng nht
trong s cc sp xp sau :
A. HCl < HBr < HF < HI
B. HI < HBr < HF < HCl
C. HF < HCl < HBr < HI
D. HBr < HI < HCl < HF
Cu 79. Dy gm cc cht u c kh nng lm i mu dung dch qu tm l
A. CH3NH2, C2H5NH2, HCOOH
B. C6H5NH2, C2H5NH2, HCOOH
C. CH3NH2, C2H5NH2, H2N-CH2-COOH
D. CH3NH2, C6H5 OH, HCOOH
Cu 80. Cho cc cht sau C2H5OH(1), CH3COOH(2), CH2=CH-COOH(3), C6H5OH(4), p-CH3-C6H4OH(5),
C6H5-CH2 OH(6). Sp xp theo chiu tng dn linh ng ca nguyn t H trong nhm -OH ca cc cht trn l :
A. (1), (5), (6), (4), (2), (3)
B. (1), (6), (5), (4), (2), (3)
(1),
(6),
(5),
(4),
(3),
(2)
C.
D. (3), (6), (5), (4), (2), (1)
Cho
cc
cht
sau:
Cu 81.
1) axit 2-hiroxipropan-1,2,3-tricacboxylic (c trong qu chanh)
2) axit 2-hiroxipropanoic (c trong sa chua).
3) axit 2-hiroxibutanioic (c trong qu to).
4) axit 3-hiroxibutanoic (c trong nc tiu ca ngi bnh tiu ng).
5) axit 2,3-ihiroxibutanioic (c trong ru vang).
Th t sp xp cc axit trn theo chiu tnh axit mnh dn t tri sang phi l
A. 2,4,5,3,1.
B. 4,2,3,5,1.
C. 4,3,2,1,5.
D. 2,3,4,5,1.
Cu 82: Sp xp cc hp cht sau theo th t tng dn nhit si: axit axetic (1), ru n-propylic (2), metyl fomiat
(3):
A. (1) < (2) < (3 )
B. (1) < (3) < (2)
C. (3) < (2) < (1)
D. (2) < (3) < (1)
Cu 83: Cho cc cht metanol (X), nc (Y), etanol (Z), axit axetic (T), phenol (U). linh ng ca nguyn t H
trong nhm (-OH) ca phn t mi cht tng dn theo th t sau:
A. X < Y < Z < T < U
B. U < Y < X < Z < T
C. Y < X < Z < T < U
D. Z < X < Y < U < T
Cu 84: Sp xp cc hp cht: CH3COOH, C2H5OH, C6H5OH v H2O theo th t tng dn tnh axit:
A. H2 O < C2H5OH < CH3COOH < C6H5OH
B. H2 O < C6H5OH < CH3COOH < C2H5OH
C. H2O < C2H5OH < C6 H5OH < CH3COOH
D. C2 H5OH < H2O < C6H5OH < CH3COOH
Cu 85: Sp xp cc hp cht sau theo th t tng dn tnh axit: axit axetic (1), axit monoflo axetic (2), axit monoclo
axetic (3), axit monobrom axetic (4):
A. (1) < (2) < (3 ) < (4)
B. (1) < (4) < (3) < (2)
C. (4) < (3) < (2) < (1)
D. (2) < (3) < (4) < (1)
Cu 86: Sp xp cc hp cht sau theo th t tng dn tnh axit: axit picric (1), phenol (2), p-nitrophenol (3), p-cresol
(4):
A. (1) < (2) < (3 ) < (4)
B. (1) < (4) < (3) < (2)
C. (4) < (3) < (2) < (1)
D. (4) < (2) < (3) < (1)
Cu 87: So snh tnh axit ca cc cht sau y: CH3CH2COOH (1), CH2Cl-CH2COOH (2), CH3CHCl-COOH (3),
CH3-CCl2-COOH (4)
A. (1) > (2) > (3 ) > (4)
B. (1) > (4) > (3 ) > (2)
C. (4) > (3) > (2) > (1)
D. (2) > (4) > (3) > (1)
Cu 88: Sp xp cc hp cht sau theo th t tng dn tnh axit: CH C-COOH (1); CH2=CH-COOH (2),
C6H5COOH (3) ; CH3CH2COOH (4)
A. (1) < (2) < (3 ) < (4)
B. (1) < (4) < (3) < (2)
C. (4) < (2) < (3) < (1)
D. (4) < (3) < (2) < (1)
Cu 89: So snh nhit si ca cc cht sau: ru etylic (1), etyl clorua (2), imetyl ete (3) v axit axetic (4): A.
(1 ) > (2) > (3) > (4)
B. (4) > (3) > (2) > (1)
C. (4) > (1) > (2) > (3)
D. (4) > (1) > (3) > (2)
Cu 90: Sp xp cc cht sau y theo trnh t gim dn nhit si: CH3COOH (1), HCOOCH3 (2),
CH3CH2CH2OH (3), CH3CH(CH3)OH (4):
A. (1 ) > (2) > (3) > (4)
B. (4) > (3) > (2) > (1)
C. (4) > (1) > (3) > (2)
D. (1) > (3) > (4) > (2)

Gio vin: Nguyn Cao Chung

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Chc cc em thnh cng!

Trng THPT K Thut L Thy

Ti liu luyn thi H-C
Cu 91: Cho cc hp cht hu c sau: C6H5NH2 (1); C2H5NH2 (2); (C2H5)2NH (3); NaOH (4); NH3 (5). mnh ca
cc baz c sp xp theo th t tng dn:
A. 1 < 5 < 2 < 3 < 4.
B. 1 < 5 < 3 < 2 < 4.
C. 5 < 1 < 2 < 4 <3.
D. 1 < 2 < 3 < 4 < 5.
Cu 92: Hy sp xp cc cht sau y theo th t tng dn tnh axit: etanol (1), phenol (2), axit axetic (3), pmetylphenol (4), axit tricloaxetic (5), p-nitrophenol (6)
a. 1 < 4 < 2 < 6 <3 < 5;
b. 1 < 2 < 3 < 4 <6 < 5;
c. 1 < 4 < 6 < 2 <3 < 5;
d. 1 < 2 < 3 < 6 <4 < 5.
Cu 93: Hy sp xp cc axit sau theo th t tng dn tnh axit ( mnh ) CH2Br-COOH (1),
CCl3-COOH (2), CH3COOH (3), CHCl2-COOH (4), CH2Cl-COOH (5)
a. (1) < (2) < (3) < (4) < (5);
b. (1) < (2) < (4) < (3) < (5);
c. (3) < (1) < (5) < (4) < (2);
d. (3) < (5) < (1) < (4) < (2);
Cu 94. Cho cc cht: natri hiroxit (1), imetylamin (2), etylamin (3),natri etylat (4),p-metylanilin (5), amoniac (6),
anilin (7), p-nitroanilin (8), natri metylat (9) , metylamin (10). Th t gim dn lc baz l:
A. (4), (9), (1), (2), (3), (10), (5), (6), (7), (8).
B. (4), (9), (1), (2), (3), (10), (6), (5), (7), (8).
C. (1), (4), (9), (2), (3), (10), (6), (5), (8), (7).
D. (9), (4), (1), (2), (3), (10), (6), (5), (7), (8).
Cu 95:Cho cc cht imetylamin(1), metylamin(2), amoniac(3), anilin (4), p-metylanilin (5), p-nitroanilin (6)
Tnh baz tng dn theo th t l
A. (3), (2), (1), (4), (5), (6).
B. (1), (2), (3), (4), (5), (6).
(6),
(4),
(5),
(3),
(2),
(1).
D. (6), (5), (4), (3), (2), (1).
C.
Cu 96: mnh tnh axit c xp tng dn theo dy sau :
A. HCOOH < CH3COOH < H2CO3 < HClO
B. CH3COOH < HCOOH < H2CO3 < HClO
C. HClO < H2CO3 < CH3COOH < HCOOH
D. H2CO3 < CH3COOH < HCOOH < HClO
Cu 97. Cho cc dung dch c cng nng mol/lt sau: NH4Cl, CH3NH3Cl, (CH3)2NH2Cl, C6H5NH3Cl. Dung dch
c pH ln nht l
A. NH4 Cl
B. CH3NH3Cl
C. (CH3)2NH2Cl
D. C6H5NH3Cl
Cu 98: Hy cho bit s sp xp no sau y ng vi chiu tng dn v nhit si ca cc cht?
A. ru metylic < axit fomic < metyl amin < ru etylic
B. ru metylic < ru etylic < metyl amin < axit fomic
C. metyl amin < ru metylic < ru etylic < axit fomic
D. axit fomic < metyl amin < ru metylic < ru etylic
Cu 99: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l
A. C4H10, C3H7NH2, C3 H7F, C3H7OH, CH3CH2COOH
B. C4 H10, C3H7Cl, C3H7NH2, C3H7 OH, CH3CH2COOH
C. Benzen, toluen, phenol, CH3COOH
D. (CH3)3N, CH3CH2OH, CH3CH2CH2NH2, HCOOH
Cu 100. Cho dy cc hp cht sau: phenol(1), etanol( 2), nc( 3), axit etanoic(4), axit clohiric( 5), axit metanoic(
6), axit oxalic(7), ancol proylic( 8). Th t tng dn tnh axit l:
A. ( 8),( 2),( 3),(1),(7),( 4),(6),( 5)
B. ( 8),( 2),( 1),(3),(4),( 6),(7),( 5)
C. ( 3),( 8),( 2),(1),(4),( 6),(7),( 5)
D. ( 8),( 2),( 3),(1),(4),( 6),(7),( 5)
Cu 101: So snh tnh baz ca cc cht sau: (a) C6 H5NH2; (b) CH3-NH2; (c) CH3-C6 H4-NH2;
(d) O2N-C6H4 -NH2
A. b > c > a > d
B. b > c > d > a
C. a > b > d > c
D. a> b > c > d
Cu 102: Hy sp xp cc axit di y theo tnh axit gim dn:
CH3 COOH(1), C2H5 COOH(2), CH3CH2CH2COOH(3), ClCH2COOH(4), FCH2COOH (5)
A. 5> 1> 4> 3> 2
B. 5> 1> 3> 4> 2
C. 1> 5> 4> 2> 3
D. 5> 4> 1> 2> 3
Cu 103: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6).
Th t tng dn lc baz ca cc cht l:
A. (3) < (2) < (4) < (1) < (5) < (6)
B. (2) < (3) < (4) < (1) < (5) < (6)
C. (2) > (3) > (4) > (1) > (5) > (6)
D. (3) < (1) < (4) < (2) < (5) < (6)
Cu 104: Cho cc cht sau: HCOOH (1); CH3COOH (2); C6H5COOH (3); p-CH3C6H4COOH (4);
p-NO2C6H4COOH (5). Dy gm cc cht c xp theo chiu gim dn tnh axit l
A. 2, 1, 4, 3, 5.
B. 5, 4, 3, 2, 1.
C. 4, 3, 5, 1, 2.
D. 5, 3, 4, 1, 2.
Cu 105: Axit no trong s cc axit sau c tnh axit mnh nht:
A. CH2F-CH2-COOH
B. CH3-CCl2-COOH
C. CH3CHF-COOH
D. CH3-CF2 -COOH
Cu 106: Cho cc cht sau :
(1) CH3-CH2-CH2-CH3
(2) CH3-CH2 -CH2-CH2-CH2-CH3
(3)CH3-CH (CH3) CH(CH3)-CH3

Gio vin: Nguyn Cao Chung

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Chc cc em thnh cng!

Trng THPT K Thut L Thy

Ti liu luyn thi H-C
(4) CH3-CH(CH3)-CH2-CH2-CH3
Th t gim dn nhit nng chy ca cc cht l :
A. 2>4>3>1
B. 1>2>3>4
C. 3>4>2>1
D. 4>2>3>1
Cu 107. So snh v nhit si ca cp cht no sau y khng ng?
A. C 2H5OH > C2H5NH2 .
B. CH3OH < C2H5NH2 .
D. HCOOH > C2H5OH.
C. CH3COOH > CH3COOCH3.
Cu 108. Cho cc axit c cng thc phn t: (1) H2CO2; (2) H2CO3; (3) H2C2O4 ; (4) H4C2O2. Tnh axit ca chng
gim dn theo th t:
A. (3) > (1) > (4) > (2).
B. (3) > (4) > (1) > (2).
C. (1) > (4) > (3) > (2).
D. (1) > (2) > (4) > (3).
Cu 109. Cho cc cht: CH2 ClCOOH (a); CH3-COOH (b); C6H5OH (c); CO2 (d); H2SO4 (e). Tnh axit ca cc cht
gim theo trt t:
A. e > b > d > c > a
B. e > a > b > d > c
C. e > b > a > d > c
D. e > a > b > c > d
Cu 110: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l
A. C4H10, C3H7NH2, C3 H7F, C3H7OH, CH3CH2COOH
B. C4 H10, C3H7Cl, C3H7NH2, C3H7 OH, CH3CH2COOH
C. Benzen, toluen, phenol, CH3COOH
D. (CH3)3N, CH3CH2OH, CH3CH2CH2NH2, HCOOH
Cu 111: Trong cc cht: p-O2N-C6H4-OH, m-CH3 -C6H4-OH, p-NH2-C6 H4-CHO, m-CH3-C6H4-NH2. Cht c lc
axit mnh nht v cht c lc baz mnh nht tng ng l
B. m-CH3-C6H4 -OH v p-NH2-C6H4-CHO
A. p-O2N-C6H4-OH v p-NH2-C6 H4-CHO
C. m-CH3-C6H4-OH v m-CH3-C6H4 -NH2
D. p-O2N-C6H4-OH v m-CH3-C6H4-NH2
Cu 112: Cho cc cht ClCH2COOH (a); BrCH2 COOH (b); ICH2 COOH (c); FCH2 COOH (d). Chiu tng dn tnh
axit ca cc cht trn l:
A. (c) < (b) < (a) < (d)
B. (a) < (b) < (d) < (c)
C. (a) < (b) < (c) < (d)
D. (b) < (a) < (c) < (d)
Cu 113: Cho cc cht : amoniac (1) ; anilin (2) ; p-nitroanilin (3) ; p-metylanilin (4) ; metylamin (5) ;
imetylamin (6) . Hy chn s sp xp cc cht trn theo th t lc baz tng dn .
A . (3) < (2) < (4) < (1) < (5) < (6)
B . (2) > (3) > (4) > (1) > (5) > (6)
C . (2) < (3) < (4) < (1) < (5) < (6)
D . (3) < (1) < (4) <(2) < (5) < (6)
Cu 114: Dy no sau y c sp xp theo chiu tng tnh baz
A. C2H5ONa, NaOH, NH3, C6H5NH2 , CH3C6H4NH2, CH3NH2
B. C6H5NH2 ,CH3C6H4 NH2, NH3,CH3NH2, C2H5ONa, NaOH.
C. NH3, C6H5NH2, CH3C6H4NH2, CH3NH2, C2 H5ONa, NaOH
D. C6H5NH2,CH3C6H4NH2, NH3,CH3NH2, NaOH, C2H5ONa.
Cu 115: Xt cc cht: (I): Axit axetic; (II): Phenol; (III): Glixerin ; (IV): Axit fomic; (V): Ru metylic; (VI):
Nc; (VII): Axit propionic. mnh tnh axit cc cht tng dn nh sau:
A. (V) < (III) < (VI) < (II) < (VII) < (I) < (IV)
B. (VI) < (V) < (III) < (II) < (VII) < (I) < (IV)
C. (V) < (VI) < (II) < (III) < (VII) < (I) < (IV)
D. (V) < (VI) < (III) < (II) < (VII) < (I) < (IV)
Cu 116: Trong hn hp CH3OH v C2H5OH c cc loi lin kt hir sau:

Loi lin kt hir bn nht v km bn nht ln lt l:

A. (IV) v (III)
B. (III) v (IV)
C. (II) v (II)

D. (I) v (II)

Cu 117. So snh tnh axit ca cc axit sau:

(1) CH2ClCHClCOOH; (2) CH3CHClCOOH; (3) HCOOH; (4) CCl3COOH; (5) CH3COOH.
A. (1)< (2) < (3) < (4) <(5).

B. (4) < (1) < (2) < (3) < (5).

C. (5) < (3) < (1) < (2) < (4).

D. (5) < (3) < (2) < (1) < (4).

Cu 118. So snh tnh baz ca cc cht sau (u l dn xut ca benzen):

(a) C6 H5NH2;

(b) p-CH3C6H4NH2; (c) p-ClC6H4NH2;

A. (a) > (b) > (c) > (d).

B. (b) > (c) > (d) > (a).

C. (a) > (c) > (b) > (d).

D. (b) > (a) > (c) > (d).

Gio vin: Nguyn Cao Chung

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(d) p-O2NC6H4NH2 .

Chc cc em thnh cng!